Utilizing Solid Sorbent, Catalyst, Or Reactant Patents (Class 423/239.1)
  • Patent number: 8562929
    Abstract: A method for producing ammonia suitable for use as a reductant in a combustion exhaust gas treatment system is provided that includes the electrolytic hydrolysis of urea under mild conditions. The ammonia generator, which includes an electrolysis apparatus including an electrolytic flow cell, an alkaline electrolyte composition, and a recirculation system, may be operatively coupled to an exhaust gas treatment system to provide an apparatus for reducing nitrogen oxides (NOx) and/or particulate in exhaust gases.
    Type: Grant
    Filed: August 23, 2011
    Date of Patent: October 22, 2013
    Assignee: Ohio University
    Inventor: Gerardine G. Botte
  • Publication number: 20130272942
    Abstract: Disclosed is a vanadium/titania-based catalyst including natural manganese ore for removing nitrogen oxides and dioxin in a wide operating temperature range and a method of using the same. Specifically, this invention pertains to a vanadium/titania (V/TiO2)-based catalyst, including natural manganese ore, and a method for removing nitrogen oxides and dioxin over a wide operating temperature range, in which the WTiO2 catalyst for selective catalytic reduction of nitrogen oxides and removal of dioxin contained in flue gas includes 5-30 wt of natural manganese ore.
    Type: Application
    Filed: April 12, 2013
    Publication date: October 17, 2013
    Inventors: Sung Ho HONG, Jun Yub LEE, Seok Joo HONG, Sung Pill CHO, Sung Chang HONG, Do Gyong LEE, Sang Hyun CHOI
  • Patent number: 8557203
    Abstract: A device is described which provides thermally durable NO2 generation in conjunction with efficient heat-up performance for filter regeneration, and low temperature HC (hydrocarbon) and CO activity. Importantly, it provides both functions while minimizing PGM (platinum group metals) utilization and its associated impact on catalyst cost.
    Type: Grant
    Filed: November 3, 2009
    Date of Patent: October 15, 2013
    Assignee: Umicore AG & Co. KG
    Inventors: Owen Herman Bailey, Matthew Hedgecock, Frank-Walter Schuetze, Anke Woerz
  • Patent number: 8557207
    Abstract: A method and apparatus for reducing the quantity of pollutant in waste gases, in particular for reducing the quantity of nitrogen oxide in the flue gas of a coal-fired power plant is provided. The process includes the steps of, introducing the waste gas into a catalyzer, to which a quantity of catalytic reduction agent is supplied, measuring the quantity of pollutant at the outlet of the catalyzer, and setting the quantity of pollutant to a setpoint value smaller than a limit value to be complied with, by varying the quantity of reduction agent supplied, wherein the setting of the quantity of pollutant is dynamically regulated as a function of mean values over time, for example half-hour or quarter-hour mean values, of the measured quantity of pollutant determined regularly beforehand.
    Type: Grant
    Filed: August 16, 2012
    Date of Patent: October 15, 2013
    Assignees: Siemens Aktiengesellschaft, STEAG GmbH
    Inventors: Jürgen Endemann, Jörg Gadinger
  • Patent number: 8551430
    Abstract: A method for the selective catalytic reduction of nitrogen oxides (NOx) in the exhaust gas from an internal combustion engine includes providing an exhaust system having: an SCR catalytic converter, a reagent addition point upstream of the SCR catalytic converter for adding at least one of a reducing agent and a reducing agent precursor, and a structure which the exhaust gas can at least flow around and is disposed immediately downstream of the reagent addition point.
    Type: Grant
    Filed: January 16, 2008
    Date of Patent: October 8, 2013
    Assignee: EMITEC Gesellschaft fuer Emissionstechnologie mbH
    Inventor: Rolf Brück
  • Patent number: 8546296
    Abstract: An exhaust gas-purifying catalyst includes a substrate, and a catalytic layer supported by the substrate. The catalytic layer includes a support made of alumina, an oxygen storage material, an alkaline earth metal and/or a compound of alkaline-earth metal selectively supported by a surface of the support and dispersed on the surface of the support, and a precious metal supported by the surface of the support. A ratio of a number of moles of the alkaline-earth metal in the catalytic layer with respect to a volumetric capacity of the exhaust gas-purifying catalyst falls within a range of 0.0004 mol/L to 0.35 mol/L.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: October 1, 2013
    Assignee: Cataler Corporation
    Inventors: Yuji Yabuzaki, Akimasa Hirai, Kenichi Taki, Tomohito Mizukami, Satoshi Matsueda
  • Patent number: 8545779
    Abstract: A method for catalytic oxidation of NO to NO2 in the sulfur-containing exhaust gases of lean-burn engines, such as diesel engines is disclosed. The catalysts are oxide perovskites with a credible likelihood of being sulfur-tolerant.
    Type: Grant
    Filed: January 13, 2011
    Date of Patent: October 1, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Richard J. Blint, Chang H. Kim
  • Publication number: 20130251612
    Abstract: An exhaust gas purification catalyst contains titanium oxide as a main component and an oxide of one element or two or more elements selected from the group consisting of tungsten (W), molybdenum (Mo), and vanadium (V) as an active component, wherein the exhaust gas purification catalyst contains phosphoric acid or a water soluble phosphoric acid compound so that the atomic ratio of phosphorus (P) to a catalytically active component represented by the following formula is more than 0 and 1.0 or less; P/catalytically active component (atomic ratio)=number of moles of P/(number of moles of W+number of moles of Mo+number of moles of V).
    Type: Application
    Filed: May 7, 2013
    Publication date: September 26, 2013
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: YASUYOSHI KATO, NAOMI IMADA, KEIICHIRO KAI
  • Patent number: 8539760
    Abstract: An exhaust aftertreatment system that receives an exhaust flow from a lean-burn engine and a method for treating the exhaust flow are described. The exhaust aftertreatment system may include a three-way-catalyst, an oxidation catalyst, and a NH3—SCR catalyst. The three-way-catalyst passively generates NH3 from native NOX contained in the exhaust flow when an A/F mixture supplied to the engine is cycled from lean to rich. The generated NH3 is then stored in the NH3—SCR catalyst to facilitate NOX reduction when the A/F mixture supplied to the engine is cycled back to lean. The oxidation catalyst is located upstream of the NH3—SCR catalyst and operates to lower the NO to NO2 molar ratio of the NOX fed to the NH3—SCR catalyst. The oxidation catalyst comprises perovskite oxide particles.
    Type: Grant
    Filed: September 14, 2010
    Date of Patent: September 24, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Wei Li, Chang H Kim, Kevin L. Perry, Paul M. Najt, Kushal Narayanaswamy
  • Patent number: 8535626
    Abstract: An exhaust gas treatment apparatus according to the present invention generates post-mercury oxidation exhaust gas by denitrating exhaust gas of a combustion apparatus, generates desulfurization drainage by desulfurizing the post-mercury oxidation exhaust gas, supplies the desulfurization drainage to the combustion apparatus, and controls a return amount, which is the amount of the desulfurization drainage reused for the desulfurization, based on a concentration of halogens in the desulfurization drainage. Such exhaust gas treatment apparatus can appropriately remove mercury from the exhaust gas, and can desulfurize the post-mercury oxidation exhaust gas more appropriately.
    Type: Grant
    Filed: November 28, 2012
    Date of Patent: September 17, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Shintaro Honjo, Satoru Sugita
  • Patent number: 8535629
    Abstract: Provided is a catalyst comprising (a) a zeolite material having a mean crystal size of at least about 0.5 ?m, having a CHA framework that contains silicon and aluminum, and having a silica-to-alumina mole ratio (SAR) of about 10 to about 25; and (b) an extra-framework promoter metal (M) disposed in said zeolite material as free and/or exchanged metal, wherein the extra-framework promoter metal is copper, iron, and mixtures thereof, and is present in a promoter metal-to-aluminum atomic ratio (M:Al) of about 0.10 to about 0.24 based on the framework aluminum; and optionally comprising (c) at least about 1 weight percent of cerium in said zeolite material, based on the total weight of the zeolite, wherein said cerium is present in a form selected from exchanged cerium ions, monomeric ceria, oligomeric ceria, and combinations thereof, provided that said oligomeric ceria has a particle size of less than 5 ?m.
    Type: Grant
    Filed: December 2, 2011
    Date of Patent: September 17, 2013
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Todd Howard Ballinger, Philip Gerald Blakeman, Guy Richard Chandler, Hai-Ying Chen, Julian Peter Cox, Joseph M. Fedeyko, Alexander Nicholas Michael Green, Paul Richard Phillips, Stuart David Reid, Erich C. Weigert, James Alexander Wylie
  • Patent number: 8535632
    Abstract: The present invention relates to a catalyst-containing nanofiber composition, comprising a ceramic nanofiber having a plurality of metal catalysts wherein the metal catalysts exist as dispersed particles partially embedded in the nanofiber and cover from about 1% to about 90% of the surface area of the ceramic nanofiber.
    Type: Grant
    Filed: March 19, 2009
    Date of Patent: September 17, 2013
    Assignee: The University of Akron
    Inventors: George G. Chase, George R Newkome, Sphurti Bhargava, Soo-Jin Park, Sneha Swaminathan
  • Patent number: 8535627
    Abstract: The present invention is directed at ketone/water mixtures for treating gas mixtures containing nitric oxides (NOx). The chemical reduction of NOx by the ketone/water mixture affords a relatively less objectionable combustion waste product for discharge into the atmosphere. The gas mixture for treatment of the ketone/water mixture may be preferably regulated to have a level of oxygen of at or below 5.0 vol. %.
    Type: Grant
    Filed: December 12, 2012
    Date of Patent: September 17, 2013
    Assignee: Southwest Research Institute
    Inventors: Maoqi Feng, Rijing Zhan
  • Patent number: 8535628
    Abstract: To overcome the problem of a conventional catalyst and to provide an exhaust gas purifying catalyst that meets the requirement concerning Hg oxidation activity and SO2 oxidation activity; i.e., an exhaust gas purifying catalyst which specifically reduces percent SO2 oxidation, while maintaining percent Hg oxidation at a high level. The invention provides an exhaust gas purifying catalyst which comprises a composition containing oxides of (i) titanium (Ti), (ii) molybdenum (Mo) and/or tungsten (W), (iii) vanadium (V), and (iv) phosphorus (P), wherein the catalyst contains Ti, Mo and/or W, and V in atomic proportions of 85 to 97.5:2 to 10: 0.5 to 10, and has an atomic ratio of P/(sum of V and Mo and/or W) of 0.5 to 1.
    Type: Grant
    Filed: December 31, 2012
    Date of Patent: September 17, 2013
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Yasuyoshi Kato, Keiichiro Kai, Naomi Imada
  • Publication number: 20130236381
    Abstract: A denitration catalyst composition to efficiently and reductively remove nitrogen oxides from exhaust gas of a boiler or an internal combustion engine operated in lean-combustion, such as a gasoline engine, a diesel engine, by carbon monoxide and hydrocarbons; and a denitration method using the catalyst composition. In the denitration catalyst composition, a precious metal element having Rh as an essential component is supported on a zirconium oxide-based carrier formed by condensing or mixing primary particles having a zirconium oxide as a main component, and further a cerium-containing oxide (B) is present at the surface of the zirconium oxide-based carrier and at the gap of the secondary particles; and a denitration method characterized in that exhaust gas containing NO, CO and O2 is contacted with the denitration catalyst composition, under oxidative atmosphere having an air/fuel ratio of 14.7 or higher, at a temperature of 400 to 800° C.
    Type: Application
    Filed: October 13, 2011
    Publication date: September 12, 2013
    Applicant: N.E. CHEMCAT CORPORATION
    Inventors: Takehiro Fujimura, Yasuharu Kanno
  • Patent number: 8529853
    Abstract: The present invention relates to application of catalysts for the Selective Catalytic Reduction of oxides of Nitrogen using N-containing reductant. The catalysts are characterized as phase pure lattice oxide materials into which catalytically active cations are incorporated at high levels of dispersion such that conventional analysis reveals a highly phase pure material. The materials are further characterized by high activity, hydrothermal durability and poison tolerance in the intended application.
    Type: Grant
    Filed: March 19, 2011
    Date of Patent: September 10, 2013
    Assignee: Umicore AG & Co. KG
    Inventors: Barry W. L. Southward, John G. Nunan
  • Patent number: 8529858
    Abstract: A process for the energy efficient, environmentally friendly recovery of liquid and gaseous products from solid or semi-solid hydrocarbon resources, in particular, oil shale or tar sands. The process involves non-oxidative pyrolysis to recover fluid energy values, oxidative combustion to recover energy values as recoverable heat, and environmental sequestration of gases produced.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: September 10, 2013
    Assignee: JWBA, Inc.
    Inventor: Richard C. Russell
  • Publication number: 20130230443
    Abstract: Disclosed is a method for the selective catalytic reduction of NOx in waste/exhaust gas by using ammonia provides by heating one or more salts of formula Ma(NH3)nXz, wherein M represents one or more cations selected from alkaline earth metals and transition metals, X represents one or more anions, a represents the number of cations per salt molecule, z represents the number of anions per salt molecule, and n is a number of from 2 to 12, the one or more salts having been compressed to a bulk density above 70% of the skeleton density before use thereof.
    Type: Application
    Filed: February 26, 2013
    Publication date: September 5, 2013
    Inventors: Claus Hviid Christensen, Tue Johannessen, Ulrich Quaade, Jens Kehlet Norskøv, Rasmus Zink Sørensen
  • Patent number: 8524181
    Abstract: The invention relates to a device for the qualitative and/or quantitative determination of at least one component of a chemically reducible gas mixture, an exhaust gas catalytic converter utilizing such a device, a vehicle including such a catalytic converter, a process for preparing such a device, a process for monitoring the NOx emissions of a vehicle, and the use of such a device.
    Type: Grant
    Filed: July 14, 2009
    Date of Patent: September 3, 2013
    Assignee: Deutsches Zentrum Fuer Luft-und Raumfahrt e.V.
    Inventors: Bilge Saruhan-Brings, Mathias Christian Stranzenbach, Christoph Leyens
  • Publication number: 20130224095
    Abstract: The invention includes a process for reducing the amount of NOx discharged to atmosphere from a FCC unit, having a regenerator and a means for collecting and supporting catalyst particles. The process comprises adding a catalyst to the regenerator flue gas prior to entering the collecting means and precipitating the catalyst in the collecting means to form a catalyst bed. Ammonia or ammonia precursor is added to the flue gas prior to and/or within the collecting means. The flue gas NOx is reacted with the ammonia or ammonia precursor at 200° C. to 800° C. in the presence of the catalyst bed to reduce the NOx amount, and the flue gas containing a reduced amount of NOx is discharged to atmosphere. The catalyst is one or more supported transition or lanthanide metal catalysts. The process can also be utilized in any combustion process.
    Type: Application
    Filed: February 22, 2013
    Publication date: August 29, 2013
    Applicant: INTERCAT, INC.
    Inventor: INTERCAT, INC.
  • Publication number: 20130224096
    Abstract: A photocatalyst coated body includes a base and a photocatalyst layer provided on the base. The photocatalyst coated body is characterized in that photocatalyst layer contains 1-20 (inclusive) parts by mass of photocatalyst particles, 30-98 (inclusive) parts by mass of silica particles and 1-50 (inclusive) parts by mass of zirconia particles, so that the total all of these particles is 100 parts by mass. The photocatalyst coated body is also characterized in that the zirconia particles are at least one kind of particles selected from the group consisting of crystalline zirconia particles having an average crystallite diameter of 10 nm or less and amorphous zirconia particles. Such photocatalyst coated body has excellent photocatalytic degradation function and excellent weather resistance; and also it is capable of suppressing the formation of intermediate products such as NO2, while increasing the amount of NOx removed during removal of NOx in the air.
    Type: Application
    Filed: July 26, 2011
    Publication date: August 29, 2013
    Applicant: TOTO LTD.
    Inventors: Hiroyuki Fujii, Junji Kameshima, Koji Omoshiki, Satoru Kitazaki, Susumu Adachi
  • Patent number: 8512662
    Abstract: The present invention relates to a method of adsorbing and reducing nitrogen oxides using a mixed metal oxide catalyst, and more particularly, to a method of improving the efficiency of adsorption and desorption of nitrogen oxides using a mixed metal oxide catalyst prepared from a hydrotalcite precursor. According to the invention, NOx and N2O, which coexist with oxygen (O2) known to be very difficult to reduce and decompose, are efficiently decomposed by adsorbing and separating NOx and N2O from oxygen and then decomposing the adsorbed NOx and N2O using a reducing agent.
    Type: Grant
    Filed: October 19, 2010
    Date of Patent: August 20, 2013
    Assignee: Sangmyung University, Council for Industry Academic Cooperation
    Inventors: Kil Sang Chang, Xiaoshan Peng, Ki Seon Yang
  • Publication number: 20130210617
    Abstract: A composition based on cerium and niobium oxide in a proportion of niobium oxide of 2% to 20% is described. This composition can include zirconium oxide, optionally 50% of cerium oxide, 2% to 20% of niobium oxide, and at most 48% of zirconium oxide. Also described, is the use of the composition for treating exhaust gases.
    Type: Application
    Filed: July 5, 2011
    Publication date: August 15, 2013
    Applicant: Rhodia Operations
    Inventors: Julien Hernandez, Rui Jorge Coelho Marques, Emmanuel Rohart
  • Patent number: 8505285
    Abstract: A catalyst system includes a first catalytic composition and a second catalytic composition. The first catalytic composition includes a homogeneous solid mixture, which includes a first catalytic material disposed on a first substrate. The pores of the solid mixture have an average diameter of greater than about 45 nanometers. The second catalytic composition includes at least one of a zeolite or a second catalytic material disposed on a second substrate. The second catalytic material includes an element selected from the group that includes tungsten, titanium, and vanadium.
    Type: Grant
    Filed: October 6, 2010
    Date of Patent: August 13, 2013
    Assignee: General Electric Company
    Inventors: Benjamin Hale Winkler, Dan Hancu, Daniel George Norton, Ashish Balkrishna Mhadeshwar
  • Patent number: 8506917
    Abstract: In a circulating fluidized-bed gasification system, an ammonia-off gas 30 from an ammonia remover 25 is fed to a catalytic denitrator 15 with a flow rate regulated such that a molar ratio of the ammonia in the ammonia off-gas 30 from the ammonia recover 25 to nitrogen oxides in an exhaust gas 6 from a combustion furnace 1 is kept within a setting range, and a reminder of the ammonia off-gas 30 is fed to the combustion furnace 1.
    Type: Grant
    Filed: October 14, 2010
    Date of Patent: August 13, 2013
    Assignee: IHI Corporation
    Inventors: Hiroaki Ohara, Koki Hamada
  • Patent number: 8506916
    Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: August 13, 2013
    Assignee: C-Quest Technologies LLC
    Inventor: Douglas C. Comrie
  • Patent number: 8506923
    Abstract: The present invention is a method and material for using a sorbent material to capture and stabilize mercury. The method for using sorbent material to capture and stabilize mercury contains the following steps. First, the sorbent material is provided. The sorbent material, in one embodiment, is nano-particles. In a preferred embodiment, the nano-particles are unstabilized nano-Se. Next, the sorbent material is exposed to mercury in an environment. As a result, the sorbent material captures and stabilizes mercury from the environment. In the preferred embodiment, the environment is an indoor space in which a fluorescent has broken.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: August 13, 2013
    Assignee: Brown University
    Inventors: Robert H. Hurt, Steven P. Hamburg, Love Sarin, Indrek Kulaots
  • Publication number: 20130202513
    Abstract: Disclosed is a Ce-based composite oxide catalyst for selective catalytic reducing nitrogen oxides with ammonia, which comprises Ce oxide and at least one oxide of transition metal except Ce. The Ce-based composite oxide catalyst is prepared by a simple method which uses non-toxic and harmless raw materials, and it has the following advantages: high catalytic activity, and excellent selectivity for generating nitrogen etc. The catalyst can be applied in catalytic cleaning plant for nitrogen oxides from mobile and stationary sources.
    Type: Application
    Filed: November 9, 2011
    Publication date: August 8, 2013
    Applicant: Research Center For Eco-Environmental Sciences Chinese Academy of Sciences
    Inventors: Hong He, Wenpo Shan, Fudong Liu, Xiaoyan Shi, Changbin Zhang, Shaoxin Wang
  • Patent number: 8501132
    Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNOx catalyst applications.
    Type: Grant
    Filed: December 5, 2011
    Date of Patent: August 6, 2013
    Assignee: Cristal USA Inc.
    Inventors: Guoyi Fu, Steven M. Augustine
  • Patent number: 8501133
    Abstract: A catalyst for treating exhaust gases containing nitrogen monoxide, carbon monoxide and volatile organic compounds includes a plurality of layers, an upper layer of which has an active component contained uniformly therein and a lower layer of which has no active component contained therein. The catalyst is obtained through the steps of: forming the lower layer by coating the surface of substrate with a slurry of a porous inorganic compound, followed by drying; and forming the upper layer, which is to be the top surface of the catalyst, by coating the surface of the lower layer with a slurry of a porous inorganic compound that has the active component composed of one or more precious metals supported thereon, followed by drying. The oxidation power of the resulting catalyst is enhanced without increasing the amount of precious metal supported thereon.
    Type: Grant
    Filed: March 13, 2012
    Date of Patent: August 6, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Katsumi Nochi, Masanao Yonemura, Yoshiaki Obayashi, Hitoshi Nakamura
  • Patent number: 8501131
    Abstract: An apparatus to introduce a reagent to reduce nitrogen oxides in flue gas including: nozzles mounted to a passage for the flue gas, wherein the nozzles are mounted downstream of a SNCR system and upstream of a SCR system, wherein the nozzles are mounted on one or more walls of the passage and are configured to inject a pressurized fluid into the flue gas; a source of the pressurized fluid which is in fluid communication with the nozzles such that the pressurized fluid flows to the nozzles; a source of a NOx reducing reagent and a mixing device which mixes the reagent with the pressurized fluid such that the pressurized fluid flowing to the nozzles includes the reagent.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: August 6, 2013
    Assignee: General Electric Company
    Inventors: David Kelly Moyeda, Wei Zhou, Antonio Marquez, Xu Guang, Santosh Nareddy
  • Patent number: 8496895
    Abstract: Disclosed are an exhaust gas treating apparatus and a treating method for a carbon dioxide capture process, in which harmful substances remaining in the exhaust gas discharged from the conventional flue-gas desulfurization process are additionally removed for efficient performance of the carbon dioxide capture process. According to the exhaust gas treating apparatus for a carbon dioxide capture process, it has the effects of minimizing the installation space of desulfurization equipment and reducing the process cost. In addition, by keeping the contaminants contained in the gas introduced in the carbon dioxide capture equipment below a proper level, absorption performance can be improved as degradation of the absorbent used in the carbon dioxide capture process is prevented. After all, it has an advantage of preventing the pollution by the exhaust gas discharged into the atmosphere.
    Type: Grant
    Filed: January 27, 2012
    Date of Patent: July 30, 2013
    Assignee: Korea Institute of Energy Research
    Inventors: Hyung-Keun Lee, Won-Kil Choi, Hang-Dae Jo, Chang-Keun Yi, Sung-Ho Jo, Young-Cheol Park
  • Patent number: 8496899
    Abstract: An exhaust gas purifying catalyst 1 has a catalyst substrate 3 and catalyst coating layers 5, 7 that are formed on the catalyst substrate 3 and contain (a) Rh, (b) Pt, (c) an alkali metal or alkaline earth element, and (d) an inorganic oxide. The catalyst coating layers 5, 7 has a layered structure including an inside layer 5 where the component (a) is substantially locally existing, and an outside layer 7 where the component (b) is substantially locally existing. The inside layer 5 also contains a zirconia oxide.
    Type: Grant
    Filed: January 25, 2008
    Date of Patent: July 30, 2013
    Assignee: Cataler Corporation
    Inventor: Hiroto Imai
  • Patent number: 8491865
    Abstract: The present invention is a method and material for using a sorbent material to capture and stabilize mercury. The method for using sorbent material to capture and stabilize mercury contains the following steps. First, the sorbent material is provided. The sorbent material, in one embodiment, is nano-particles. In a preferred embodiment, the nano-particles are unstabilized nano-Se. Next, the sorbent material is exposed to mercury in an environment. As a result, the sorbent material captures and stabilizes mercury from the environment. In the preferred embodiment, the environment is an indoor space in which a fluorescent has broken.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: July 23, 2013
    Assignee: Brown University
    Inventors: Robert H. Hurt, Steven P. Hamburg, Love Sarin, Indrek Kulaots
  • Patent number: 8491844
    Abstract: The invention relates to a method for removing nitrogen monoxide (NO) and nitrogen oxides (NOx with x>1) from a gas stream, implementing a device including a catalytic bed for converting a portion at least a part of the NO into NOx with x>1, and a unit for reducing the NOx with x>1, and in which the gas stream is placed into contact with the catalytic bed before entering the unit for reducing the NOx with x>1.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: July 23, 2013
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Alain Briglia, Ludovic Granados, Christian Monereau, Elise Renou
  • Patent number: 8480985
    Abstract: A method and device for the catalytic decomposition of laughing gas in a laughing-gas-bearing gas. The method includes diluting the laughing-gas-bearing gas with a diluting gas, while forming a laughing-gas-bearing charge gas. The laughing-gas bearing charge gas is passed through a heat-exchange step where heat exchange occurs with an exhaust. A heating step occurs for occasional heating of the laughing-gas-bearing charge gas in a fixed-bed reactor for catalytic decomposition of the laughing gas. In some embodiments the diluting gas is dried, and at least a part of the exhaust from the catalytic decomposition of the laughing gas is mixed with the laughing-gas-bearing charge gas upstream of the catalytic decomposition of the laughing gas.
    Type: Grant
    Filed: January 5, 2010
    Date of Patent: July 9, 2013
    Assignee: Linde Aktiengesellschaft
    Inventors: Ulrike Wenning, Hans-Jörg Zander, Anton Wellenhofer, Karl-Heinz Hofmann, Wibke Korn, Franz Beran, Nicole Schödel, Wolfgang Schmehl
  • Patent number: 8480984
    Abstract: A selective catalytic reduction system and method for reducing nitrogen oxide (NOx) emissions comprising a boiler producing flue gas emissions, a particulate control device receiving flue gas emissions from the boiler, a selective catalytic reduction unit (SCR) receiving flue gas emissions from the particulate control device and reducing nitrogen oxide (NOx) emissions, and a heat exchanger located downstream of the selective catalytic reduction unit (SCR) for removing heat from the flue gas for preheating at least one of boiler feed water and combustion air for the boiler.
    Type: Grant
    Filed: June 19, 2012
    Date of Patent: July 9, 2013
    Assignee: 2E Environmental, LLC
    Inventor: Robert Ellery
  • Patent number: 8480986
    Abstract: A system for NOx reduction in combustion gases, especially from diesel engines, incorporates an oxidation catalyst to convert at least a portion of NO to NO2, tparticulate filter, a source of reductant such as NH3 and an SCR catalyst. Considerable improvements in NOx conversion are observed.
    Type: Grant
    Filed: August 5, 2011
    Date of Patent: July 9, 2013
    Assignees: Daimler AG, HJS Fahrezeutechnik GmbH & Co. KG, Johnson Matthey Public Ltd. Co.
    Inventors: Anders Andreasson, Guy Richard Chandler, Claus Friedrich Goersmann, James Patrick Warren, Georg Huethwohl
  • Publication number: 20130164205
    Abstract: The present invention concerns the selective removal of nitrogen oxides (NOx) from gases. In particular, the invention concerns a process, a highly alkali metal resistant heteropoly acid promoted catalyst and the use of said catalyst for removal of NOx from exhaust or flue gases, said gases comprising alkali or earth alkali metals. Such gases comprise for example flue gases arising from the burning of biomass, combined biomass and fossil fuel, and from waste incineration units. The process comprises the selective catalytic reduction (SCR) of NOx, such as nitrogen dioxide (NO2) and nitrogen oxide (NO) with ammonia (NH3) or a nitrogen containing compound selected from ammonium salts, urea or a urea derivative or a solution thereof as reductant.
    Type: Application
    Filed: August 29, 2011
    Publication date: June 27, 2013
    Applicant: DANMARKS TEKNISKE UNIVERSITET
    Inventors: Siva, Sankar, Reddy Putluru, Anders Riisager, Rasmus Fehrmann
  • Publication number: 20130164201
    Abstract: A composition based on cerium, zirconium and tungsten is described. The composition has a content expressed as an oxide, of which cerium is from 5% to 30% of the composition, tungsten is from 2% to 17% of the composition, and the remainder of the composition is zirconium. After aging at 750° C. under an air atmosphere including 10% water, it has a two-phase crystallographic structure having a tetragonal zirconia phase and a monoclinic zirconia phase, with no presence of a crystalline phase including tungsten. The composition can be used as a catalyst, especially in an SCR process.
    Type: Application
    Filed: May 17, 2011
    Publication date: June 27, 2013
    Applicants: MAGNESIUM ELEKTRON LIMITED, RHODIA OPERATIONS
    Inventors: Julien Hernandez, Emmanuel Rohart, Rui Jorge Coelho Marques, Deborah Jane Harris, Clare Jones
  • Patent number: 8470273
    Abstract: A combustion exhaust gas processing device comprises: a dust collector collecting dust in a cement kiln combustion exhaust gas: a wet dust collector as a catalyst-poisoning-substance stripper removing a catalyst-poisoning substance from a combustion exhaust gas which passed the wet dust collector; and a catalyst device from which NOx, a persistent organic pollutant, etc. in the preheated combustion exhaust gas, are removed. A titanium-vanadium catalyst etc. as an oxide catalyst is used upstream of the catalyst device, and a platinum catalyst etc. as a noble-metal catalyst downstream of the catalyst device. The temperature of the combustion exhaust gas after the catalyst-poisoning substance is removed is increased up to 140° C. or more with the preheaters to prevent decline in denitration efficiency of and the decomposition efficiency of a volatile organic compound.
    Type: Grant
    Filed: December 27, 2005
    Date of Patent: June 25, 2013
    Assignees: Taiheiyo Cement Corporation, Nippon Shokubai Co., Ltd.
    Inventors: Shinichiro Saito, Yasuhiro Uchiyama, Junichi Terasaki, Hisashi Kondo, Mitsuharu Hagi, Shinyuki Masaki
  • Patent number: 8470277
    Abstract: A process and an apparatus enhance urea utilization for selective catalytic reduction (SCR) of NOx, by controlled preparation and feed of gasified urea during combustor load variation. The concentration of NOx in the combustion gases and a required total gas flow necessary to supply an SCR reactor with NOx reducing and carrier gases are determined. Urea is gasified by gasification gases in a thermal gasification reactor. The resulting urea gasification products are mixed with carrier gases to provide an injection grid supply stream. Heating is reduced and flue gas enthalpy is efficiently used by controls utilizing monitoring the temperatures of gases fed to the thermal gasification reactor and of the stream of carrier gases.
    Type: Grant
    Filed: August 7, 2012
    Date of Patent: June 25, 2013
    Assignee: Fuel Tech, Inc.
    Inventors: William H. Sun, Paul G. Carmignani
  • Patent number: 8470728
    Abstract: To overcome the problem of a conventional catalyst and to provide an exhaust gas purifying catalyst that meets the requirement concerning Hg oxidation activity and SO2 oxidation activity; i.e., an exhaust gas purifying catalyst which specifically reduces percent SO2 oxidation, while maintaining percent Hg oxidation at a high level. The invention provides an exhaust gas purifying catalyst which comprises a composition containing oxides of (i) titanium (Ti), (ii) molybdenum (Mo) and/or tungsten (W), (iii) vanadium (V), and (iv) phosphorus (P), wherein the catalyst contains Ti, Mo and/or W, and V in atomic proportions of 85 to 97.5:2 to 10:0.5 to 10, and has an atomic ratio of P/(sum of V and Mo and/or W) of 0.5 to 1.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: June 25, 2013
    Assignee: Babcock Hitachi Kabushiki Kaisha
    Inventors: Yasuyoshi Kato, Keiichiro Kai, Naomi Imada
  • Patent number: 8465714
    Abstract: Low temperature activity of a vanadium-free selective catalytic reduction catalyst is provided by a mixed metal oxide support containing oxides of titanium and zirconium, the support having a promoter deposited on the surface of the mixed metal oxide support, and further having an active catalyst component deposited over the promoter on the mixed metal oxide support surface. Suitable promoters include oxides of silicon, boron, aluminum, cerium, iron, chromium, cobalt, nickel, copper, tin, silver, niobium, lanthanum, titanium, and combinations thereof. Suitable active catalyst components include oxides of manganese, iron and cerium.
    Type: Grant
    Filed: February 27, 2012
    Date of Patent: June 18, 2013
    Assignee: Cristal USA Inc.
    Inventor: Steven M. Augustine
  • Patent number: 8465713
    Abstract: A catalyst composition represented by the general formula XVO4/S wherein XVO4 stands for TransitionMetal-Vanadate, or a mixed TransitionMetal-/RareEarth-Vanadate, and S is a support comprising TiO2.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: June 18, 2013
    Assignee: Treibacher Industrie AG
    Inventors: Karl Schermanz, Amod Sagar, Alessandro Trovarelli, Marzia Casanova
  • Patent number: 8460627
    Abstract: A device and method for the decomposition of laughing gas including a gas inlet for supplying a laughing-gas-bearing gas; a first heat-exchanger for the exchange of heat between an exhaust and the laughing-gas-bearing gas; a heating device for occasional heating of the laughing-gas-bearing gas and a fixed-bed reactor in which a catalyst is included in order to decompose the laughing gas. The device also includes a gas outlet, through which exhaust leaving the fixed-bed reactor can be taken away through the heat exchanger. The device may be used to implement a method where the catalyst for decomposition of laughing gas is maintained at temperatures below 800° C. and in which the fixed-bed reactor is arranged as an adiabatic reactor.
    Type: Grant
    Filed: January 5, 2010
    Date of Patent: June 11, 2013
    Assignee: Linde Aktiengesellschaft
    Inventors: Franz Beran, Karl-Heinz Hofmann, Nicole Schödel, Wolfgang Schmehl, Ulrike Wenning, Hans-Jörg Zander
  • Patent number: 8459001
    Abstract: In one embodiment, a system includes an emissions reduction system including a compressor in fluid communication with a catalyst mixing tank. The compressor is configured to output an air flow configured to deliver catalyst from the catalyst mixing tank to a catalyst injection grid. A temperature of the air flow is increased by the compressor.
    Type: Grant
    Filed: August 7, 2009
    Date of Patent: June 11, 2013
    Assignee: General Electric Company
    Inventors: Leslie Yung-Min Tong, Hua Zhang, Diego Rancruel
  • Publication number: 20130142719
    Abstract: An exhaust gas purification catalyst is made as a composition comprising titanium oxide (TiO2), aluminum sulfate (Al2(SO4)3), an oxide of vanadium (V), and an oxide of molybdenum (Mo) and/or tungsten (W), wherein on titanium oxide having sulfate ions and aluminum ions adsorbed thereon obtained by making contact with aluminum sulfate at more than 1 wt % and not more than 6 wt % relative to titanium oxide in the presence of water, an oxo acid salt of vanadium or a vanadyl salt and an oxo acid or an oxo acid salt of molybdenum and/or tungsten are supported in a proportion of more than 0 atom % and not more than 3 atom %, respectively. By this, the degradation of catalyst performance can be suppressed even with exhaust gas containing potassium compounds at a high concentration in combustion ash.
    Type: Application
    Filed: August 4, 2011
    Publication date: June 6, 2013
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Keiichiro Kai, Yasuyoshi Kato, Naomi Imada
  • Patent number: 8454916
    Abstract: A dosing control system for a vehicle includes a current storage module, an adaption triggering module, and an adaption ending module. The current storage module estimates an amount of ammonia stored by a selective catalytic reduction (SCR) catalyst. The adaptation triggering module triggers a reduction of the amount of ammonia stored by the SCR catalyst to zero when a first amount of nitrogen oxides (NOx) measured by a first NOx sensor located downstream of the SCR catalyst is greater than a predicted value of the first amount of NOx. The adaptation ending module selectively ends the reduction and enables injection of dosing agent based on a comparison of the first amount of NOx with a second amount of NOx upstream of the SCR catalyst.
    Type: Grant
    Filed: June 18, 2010
    Date of Patent: June 4, 2013
    Inventors: James M. Perrin, Rebecca J. Darr, Paul Jasinkiewicz, Jason Daniel Mullins, Kyle E. Crawford
  • Patent number: 8449851
    Abstract: According to the present invention, a mercury removing system (A) includes a reaction gas supplier (20) that supplies reaction gas to treatment target gas; de-nitration equipment (2) that reduces nitrogen oxide in the treatment target gas to be removed and oxidizes low water-soluble mercury in the treatment target gas to obtain water-soluble mercury; and desulfurization equipment (7) that removes sulfur oxide and the low water-soluble mercury in the treatment target gas. The mercury removing system further includes an oxidation gas vaporizer (124) that heats an oxidation gas generating liquid to generate oxidation gas and a gas mixer (13) that mixes the oxidation gas with reducing gas to obtain the reaction gas, outside a flue and on the upstream side of the reaction gas supplier (20).
    Type: Grant
    Filed: November 2, 2010
    Date of Patent: May 28, 2013
    Assignee: IHI Corporation
    Inventor: Toshiyuki Naito