Nickel (ni) Containing Patents (Class 423/594.3)
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Patent number: 12136733Abstract: The cathode active material according to embodiments of the present invention includes a lithium composite oxide particle having a form of secondary particle in which a plurality of primary particle are aggregated, wherein the primary particles respectively include a lithium conduction pathway through which lithium ions are diffused. Wherein the primary particles include a first particle, and the first particle has an angle of 45° to 90° formed by a direction from a center of the first particle to a center of the lithium composite oxide particle and a direction of the lithium conduction pathway included in the first particle, wherein a ratio of the number of the first particles among the primary particles located on a surface of the lithium composite oxide particle is 20% or more.Type: GrantFiled: October 22, 2021Date of Patent: November 5, 2024Assignee: SK ON CO., LTD.Inventors: Sung Soon Park, Ji Hoon Choi, Jik Soo Kim, Kwang Ho Lee, Jeong Hoon Jeun
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Patent number: 10854870Abstract: The present invention provides a method of preparing a positive electrode active material for a secondary battery including preparing a first transition metal-containing solution including a nickel raw material, a cobalt raw material, and a manganese raw material and a second transition metal-containing solution including a nickel raw material, a cobalt raw material, and a manganese raw material in a concentration different from that of the first transition metal-containing solution; preparing a reaction solution, in which nickel manganese cobalt-based composite metal hydroxide particles are formed, by adding an ammonium cation-containing complexing agent and a basic compound as well as the second transition metal-containing solution to the first transition metal-containing solution and performing a co-precipitation reaction in a pH range of 11 to 13.Type: GrantFiled: January 18, 2019Date of Patent: December 1, 2020Inventors: Sang Wook Lee, Wang Mo Jung, Seong Hoon Kang, Byung Chun Park, Ju Kyung Shin, Sang Min Park
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Patent number: 10781531Abstract: A method for producing a nickel-containing hydroxide is provided that includes a nucleation step of generating nuclei of nickel-containing hydroxide particles by neutralization crystallization in an aqueous solution accommodated in an agitation tank. In the nucleation step, a volume fraction of a highly supersaturated region in the aqueous solution where the molar concentration of the nickel-containing hydroxide dissolved in the aqueous solution is greater than or equal to 5.0 mol/m3 is less than 0.100% of the aqueous solution.Type: GrantFiled: June 12, 2017Date of Patent: September 22, 2020Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Shuhei Nakakura, Kazuhiko Tsuchioka, Koichiro Maki, Motoaki Saruwatari, Kazuomi Ryoshi, Yoshihiko Nakao, Masafumi Yoshida
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Patent number: 10347913Abstract: The present invention provides a method for preparing a core-shell structured particle, the method using a continuous Couette-Taylor crystallizer in which a core reactant inlet, a shell reactant inlet, and a product outlet are sequentially formed on an outer cylinder along a flow direction of a fluid flowing in a Couette-Taylor fluid passage between the outer cylinder and an inner cylinder, wherein a core particle is primarily formed in the fluid passage by a core reactant supplied through the core reactant inlet; a shell layer is formed on a surface of the core particle to cover the core particle by a shell reactant supplied through the shell reactant inlet; and a core-shell structured particle in which the shell layer is formed on the circumference of the core particle, is discharged to the outside through the product outlet.Type: GrantFiled: October 23, 2014Date of Patent: July 9, 2019Assignees: LG Chem, Ltd., University-Industry Cooperation Group of Kyung Hee UniversityInventors: Woo Sik Kim, Khuong Dien Thai, Byung Chun Park, Seong Hoon Kang, Wang Mo Jung, Hong Kyu Park
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Patent number: 9972843Abstract: A carbonate precursor compound of a lithium manganese based oxide powder for a positive electrode of a rechargeable battery, the oxide having the general formula Li1+vM1?vO2, wherein ?0.03?v?0.25, wherein M is a composition comprising at least 50 mol % of manganese, and wherein the carbonate precursor compound has a secondary particle size D50 expressed in ?m, and a tap density TD expressed in g/cm3, with either 1?TD?(2.78*D50)/(D50+7.23) and the compound having a particle size distribution having a span S?1.8 with S=(D90?D10)/D50; or 1?TD?(2.78*D50)/(D50+7.50).Type: GrantFiled: August 21, 2014Date of Patent: May 15, 2018Assignees: Umicore, Umicore Korea Ltd.Inventors: Randy De Palma, JiHye Kim, Kris Driesen, Jens Paulsen, Jin Hu
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Patent number: 9028710Abstract: The invention is directed to a pulverulent compound of the formula NiaM1bM2cOx(OH)y where M1 is at least one element selected from the group consisting of Fe, Co, Zn, Cu and mixtures thereof, M2 is at least one element selected from the group consisting of Mn, Al, Cr, B, Mg, Ca, Sr, Ba, Si and mixtures thereof, 0.3?a?0.83, 0.1?b?0.5, 0.01?c?0.5, 0.01?x?0.99 and 1.01?y?1.99, wherein the ratio of tapped density measured in accordance with ASTM B 527 to the D50 of the particle size distribution measured in accordance with ASTM B 822 is at least 0.2 g/cm3·?m. The invention is also directed to a method for the production of the pulverulent compound and the use as a precursor material for producing lithium compounds for use in lithium secondary batteries.Type: GrantFiled: July 23, 2008Date of Patent: May 12, 2015Assignee: H.C. Starck GmbHInventors: Matthias Jahn, Gerd Maikowske, Stefan Malcus, Juliane Meese-Marktscheffel, Armin Olbrich, Rüdiger Zertani
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Patent number: 9028726Abstract: The present invention provides a sputtering target suitable for producing an amorphous transparent conductive film which can be formed without heating a substrate and without feeding water during the sputtering; which is easily crystallized by low-temperature annealing; and which has low resistivity after the crystallization. An oxide sintered compact containing an indium oxide as a main component, while containing tin as a first additive element, and one or more elements selected from germanium, nickel, manganese, and aluminum as a second additive element, with the content of tin which is the first additive element being 2-15 atom % relative to the total content of indium and tin, and the total content of the second additive element being 0.1-2 atom % relative to the total content of indium, tin and the second additive element.Type: GrantFiled: September 18, 2009Date of Patent: May 12, 2015Assignee: JX Nippon Mining & Metals CorporationInventors: Masakatsu Ikisawa, Masataka Yahagi
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Patent number: 8992794Abstract: A method for preparing a layered oxide cathode using a two step calcination procedure, wherein the first step includes pre-calcination utilizing a rotary calciner.Type: GrantFiled: June 24, 2011Date of Patent: March 31, 2015Assignee: BASF CorporationInventors: Ivan Petrovic, Anthony Thurston, Stephen Sheargold
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Publication number: 20150048281Abstract: An oxide film according to this invention is a film of an oxide (possibly including inevitable impurities) containing silver (Ag) and nickel (Ni). This oxide film is an aggregate of microcrystals, an amorphous form including microcrystals, or an amorphous form and has p-type conductivity, which exhibits no clear diffraction peak with the XRD analysis, as seen in a chart in FIG. 3 indicating X-ray diffraction (XRD) analysis results of a first oxide film and a second oxide film. This oxide film achieves a broader bandgap than that of a conventional oxide film as well as high p-type conductivity. This oxide film is an aggregate of microcrystals, an amorphous form containing microcrystals, or an amorphous form as described above, and is thus easily formed on a large substrate and is suitable also for industrial production.Type: ApplicationFiled: March 1, 2013Publication date: February 19, 2015Applicant: Ryukoku UniversityInventors: Seiji Yamazoe, Takahiro Wada
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Publication number: 20150034861Abstract: In at least one embodiment, a rechargeable battery is provided comprising an anode having an active material including MSb2O4 having a purity level of greater than 93 percent by weight, wherein M is a metal. The metal may have an oxidation state of 2+ and may include transition metals and/or alkali-earth metals. The anode active material may be synthesized using metal acetates or metal oxides. The synthesis may include heating at a first temperature to remove oxygen and water and reacting at a second temperature to form the MSb2O4 structure, which may be a spinel crystal structure.Type: ApplicationFiled: July 30, 2013Publication date: February 5, 2015Applicant: Ford Global Technologies, LLCInventor: Kevin James Rhodes
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Publication number: 20150037676Abstract: Provided is a cathode active material for a non-aqueous electrolyte secondary battery that has a uniform particle size and high packing density, and that is capable of increased battery capacity and improved coulomb efficiency. When producing a nickel composite hydroxide that is a precursor to the cathode active material by supplying an aqueous solution that includes at least a nickel salt, a neutralizing agent and a complexing agent into a reaction vessel while stirring and performing a crystallization reaction, a nickel composite hydroxide slurry is obtained while controlling the ratio of the average particle size per volume of secondary particles of nickel composite hydroxide that is generated inside the reaction vessel with respect to the average particle size per volume of secondary particles of nickel composite hydroxide that is finally obtained so as to be 0.2 to 0.Type: ApplicationFiled: February 22, 2013Publication date: February 5, 2015Applicant: Sumitomo Metal Mining Co., Ltd.Inventors: Mitsuru Yamauchi, Kazuomi Ryoshi, Kensaku Mori
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Publication number: 20150030522Abstract: To obtain metal agglomerate having stable particle sizes and substantially spherical shapes, the method allows, by a circulation unit, a flow of a liquid containing metal to pass through a processing vessel and an external circulation path, and a part of the liquid from the processing vessel to be extracted to an outside in a substantially continuous manner so as to return to the processing vessel after it goes through the external circulation path, sets a flow velocity in the external circulation path to be 1 m/second or more, and injects at least a part of a liquid concentrate containing a reactant to be newly added into the external circulation path.Type: ApplicationFiled: December 21, 2012Publication date: January 29, 2015Applicant: TSUKISHIMA KIKAI CO., LTD.Inventors: Yo Doya, Hidenori Goto
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Patent number: 8906553Abstract: A cathode electrode material for use in rechargeable Li-ion batteries, based on the integration of two Li-based materials of NASICON- and Spinel-type structures, is described in the present invention. The structure and composition of the cathode can be described by a core material and a surface coating surrounding the core material, wherein the core of the cathode particle is of the formula LiMn2-xNixO4?? (0.5?x?0 & 0???1) and having a spinel crystal structure, the surface coating is of the formula Li1+xMxTi2-x(PO4)3 (M: is a trivalent cation, 0.5?x?0) having a NASICON-type crystal structure.Type: GrantFiled: February 28, 2011Date of Patent: December 9, 2014Assignee: NEI CorporationInventors: Nader Marandian Hagh, Farid Badway, Ganesh Skandan
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Patent number: 8900537Abstract: A template-free reverse micelle (RM) based method is used to synthesize pyrochlore nanostructures having photocatalytic activity. In one embodiment, the method includes separately mixing together a first acid stabilized aqueous solution including pyrochlore precursor A and a second acid stabilized aqueous solution including pyrochlore precursor B with an organic solution including a surfactant to form an oil-in-water emulsion. Next, equimolar solutions of the first and second acid stabilized oil-in-water emulsions are mixed together. Then, the mixture of the first and second acid stabilized oil-in-water emulsion is treated with a base to produce a precipitate including pyrochlore precursors A and B. After which, the precipitate is dried to remove volatiles. The precipitate is then calcined in the presence of oxygen to form a pyrochlore nanostructure, such as a bismuth titanate (Bi2Ti2O7) pyrochlore nanorod. The method of synthesizing the pyrochlore nanorod is template-free.Type: GrantFiled: May 11, 2011Date of Patent: December 2, 2014Assignee: Board of Regents of the Nevada System of Higher Education, on behalf of the University of Nevada, RenoInventors: Vaidyanathan Subramanian, Sankaran Murugesan
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Publication number: 20140272568Abstract: A compound MjXp which is particularly suitable for use in a battery prepared by the complexometric precursor formulation methodology wherein: Mj is at least one positive ion selected from the group consisting of alkali metals, alkaline earth metals and transition metals and j is an integer representing the moles of said positive ion per moles of said MjXp; and Xp, a negative anion or polyanion from Groups IIIA, IV A, VA, VIA and VIIA and may be one or more anion or polyanion and p is an integer representing the moles of said negative ion per moles of said MjXp.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: PERFECT LITHIUM CORP.Inventor: PERFECT LITHIUM CORP.
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Patent number: 8835055Abstract: Disclosed is a lithium secondary battery, which is low in capacity loss after overdischarge, having excellent capacity restorability after overdischarge and shows an effect of preventing a battery from swelling at a high temperature.Type: GrantFiled: September 14, 2012Date of Patent: September 16, 2014Assignee: LG Chem, Ltd.Inventors: Sung Kyun Chang, Seung Tae Hong, Hyeong Jin Kim, Duk Hyun Ryu, Eun Young Goh, Ho Chun Lee, Jun Yong Jeong, Jin Hee Yeon, Hyung Keun Lee
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Publication number: 20140234203Abstract: Disclosed is a reactor for preparing a precursor of lithium composite transition metal oxide for lithium secondary batteries, the reactor having a closed structure including a stationary hollow cylinder; a rotary cylinder having the same axis as the stationary hollow cylinder and an outer diameter smaller than an inner diameter of the stationary hollow cylinder, an electric motor to generate power, enabling rotation of the rotary cylinder, a rotation reaction area disposed between the stationary hollow cylinder and the rotary cylinder, wherein ring-shaped vortex pairs that are uniformly arranged in a rotation axis direction and rotate in opposite directions are formed in the rotation reaction area, and an inlet through which a reactant fluid is fed into the rotation reaction area and an outlet through which the reactant fluid is discharged from the rotation reaction area.Type: ApplicationFiled: April 8, 2014Publication date: August 21, 2014Applicant: LG CHEM, LTD.Inventors: ByungChun Park, Seong Hoon Kang, HoSuk Shin, SangMin Park, Hong Kyu Park
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Publication number: 20140227594Abstract: Disclosed are a precursor of a positive active material for a rechargeable lithium battery and a preparation method thereof, and a positive active material and a rechargeable lithium battery including the same, and specifically a precursor for a rechargeable lithium battery is represented by the following Chemical Formula 1, wherein a manganese ion concentration deviation in the precursor is within 3 wt %. NixCoyMn1-x-y-zMz(OH)2??[Chemical Formula 1] (0<x<1, 0?y<1, 0.5?1?x?y?z, 0?z<1, and M is at least one kind of metal selected from the group consisting of Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, and Zr.Type: ApplicationFiled: September 24, 2012Publication date: August 14, 2014Applicant: KOREA ELECTRONICS TECHNOLOGY INSTITUTEInventors: Jun Ho Song, Young Jun Kim, Jae-Hun Kim
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Publication number: 20140213441Abstract: The present invention provides an electrocatalytic material and a method for making an electrocatalytic material. There is also provided an electrocatalytic material comprising amorphous metal or mixed metal oxides. There is also provided methods of forming an electrocatalyst, comprising an amorphous metal oxide film.Type: ApplicationFiled: September 4, 2012Publication date: July 31, 2014Inventors: Simon Trudel, Curtis Berlinguette
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Patent number: 8765305Abstract: The present invention relates to a cathode active material for a lithium secondary battery and a process for preparing the same. In accordance with the present invention, the cathode active material having a high packing density was designed and synthesized and thus provided is a cathode active material for a lithium secondary battery exhibiting structural stability such as improved characteristics for charge/discharge, service life and high-rate and thermal stability, by modifying surface of the electrode active material with amphoteric or basic compounds capable of neutralizing acid produced around the cathode active material.Type: GrantFiled: November 17, 2004Date of Patent: July 1, 2014Assignee: Industry-University Cooperation Foundation, Hanyang UniversityInventors: Yang Kook Sun, Myoung Hun Lee, Yoon Jung Kang, Gil Ho Kim
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Patent number: 8759249Abstract: A method for the production of nanocrystalline nickel oxides as well as the nickel oxides produced by the method according to the invention and the use thereof as catalyst following reduction to nickel metal, in particular for hydrogenation reactions.Type: GrantFiled: May 29, 2009Date of Patent: June 24, 2014Assignee: SUED-Chemie IP GmbH & Co. KGInventors: Hans-Jörg Wölk, Alfred Hagemeyer, Frank Groβmann, Silvia Neumann
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Patent number: 8709300Abstract: The present invention relates to a nickel oxide-stabilized zirconia composite in which nickel oxide is dispersed uniformly, a process for readily producing the composite oxide, and an anode for a solid oxide fuel cell having excellent output characteristics. More specifically, the present invention provides a nickel oxide-stabilized zirconia composite that is produced by sintering a mixture of nickel hydroxide and/or nickel carbonate and a hydroxide of stabilized zirconium.Type: GrantFiled: August 7, 2009Date of Patent: April 29, 2014Assignee: Daiichi Kigenso Kagaku Kogyo Co., Ltd.Inventors: Kyosuke Domae, Takeshi Usui, Tadashi Yasui, Satoshi Watanabe
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Publication number: 20140065058Abstract: Provided are an apparatus for preparing a cathode active material precursor for lithium secondary batteries including a cylindrical outer chamber, an inner cylinder that has the same central axis as the outer chamber and is mounted to rotatably move along the central axis, an electric motor to transfer power to rotate the inner cylinder, a reactant inlet disposed on the outer chamber, to add reactants to a space between the outer chamber and the inner cylinder, and an outlet disposed in the outer chamber, to obtain reaction products after reaction in the space between the outer chamber and the inner cylinder, and a method for preparing a cathode active material precursor for lithium secondary batteries using the apparatus.Type: ApplicationFiled: September 6, 2012Publication date: March 6, 2014Applicants: University-Industry Cooperation Group of Kyung Hee University, LG CHEM, LTD.Inventors: ByungChun PARK, Woosik KIM, HoSuk SHIN, Soonho AHN, Hong Kyu PARK, Joon Hyun CHANG
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Positive electrode active material and non-aqueous electrolyte secondary battery containing the same
Patent number: 8658125Abstract: The present invention relates to a positive electrode active material comprising a lithium-containing composite oxide containing nickel with an oxidation state of 2.0 to 2.5 and manganese with an oxidation state of 3.5 to 4.0, the oxidation state determined by the shifts of energy at which absorption maximum is observed in the X-ray absorption near-K-edge structures, and to a non-aqueous electrolyte secondary battery using the same, the positive electrode active material being characterized in having a high capacity, a long storage life and excellent cycle life.Type: GrantFiled: October 23, 2002Date of Patent: February 25, 2014Assignees: Panasonic Corporation, Osaka City UniversityInventors: Tsutomu Ohzuku, Hiroshi Yoshizawa, Masatoshi Nagayama -
Patent number: 8632694Abstract: Disclosed is a cathode active material for secondary batteries comprising, a compound having a transition metal layer containing lithium as at least one compound selected from the following Formula 1: Li(Li3x±yM1?yPx)O2+z (1) wherein M is an element stable for a six-coordination structure, which is at least one selected from transition metals that belong to the first and second period elements; 0<x<0.1; 0<y<0.3; ?4x<z?4x; and 3x>y is satisfied in a case of 3x?y.Type: GrantFiled: June 27, 2012Date of Patent: January 21, 2014Assignee: LG Chem, Ltd.Inventors: Sung-Kyun Chang, DongHun Lee, HoSuk Shin, Hong Kyu Park, JiEun Lee
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Patent number: 8574540Abstract: A method for producing prefluxed metal oxide from a metal salt selected from nickel hydroxide, cobalt hydroxide, mixed nickel-cobalt hydroxide, nickel carbonate, cobalt carbonate, mixed nickel-cobalt carbonate and combinations thereof includes providing a mixture of at least one slag making oxide and a metal salt selected from the group consisting of nickel hydroxide, cobalt hydroxide, mixed nickel-cobalt hydroxide, nickel carbonate, cobalt carbonate, mixed nickel-cobalt carbonate and combinations thereof, blending with a binder, blending in a flux additive to form a slag-making mixture, forming the slag-making mixture into prefluxed agglomerates, and calcining the prefluxed agglomerates to produce a prefluxed metal oxide. An agglomerate is provided which includes a metal salt selected from nickel hydroxide, cobalt hydroxide, mixed nickel-cobalt hydroxide, nickel carbonate, cobalt carbonate, mixed nickel-cobalt carbonate and combinations thereof, a slag making oxide, and a flux additive.Type: GrantFiled: February 6, 2009Date of Patent: November 5, 2013Assignee: Vale S.A.Inventors: Geoffrey Edwin Osborne, Ahmed Vahed, Samuel Walton Marcuson
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Patent number: 8545794Abstract: The invention relates to a powder compound of the formula NiaMbOx(OH)y, wherein M represents Co and at least one element selected from the group consisting of Fe, Zn, Al, Sr, Mg, or Ca and mixtures thereof, or M represents Co Mn and Fe, wherein 0.6?a<1.0, 0<b?0.4, 0<x?0.60, and 1.4?y<2, wherein the powder compound has a particle size distribution d50 value, measured in accordance with ASTM B 822, of <5 ?m, and wherein a ratio of tap density, measured in accordance with ASTM B 527, to the particle size distribution d50 value is at least 0.4 g/cm3. The invention also relates to a process for preparing the compound and its uses.Type: GrantFiled: September 2, 2008Date of Patent: October 1, 2013Assignee: H.C. Starck GmbHInventors: Matthias Jahn, Gerd Malkowske, Stefan Malcus, Juliane Meese-Marktscheffel, Armin Olbrich, Rüdiger Zertani
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Publication number: 20130240802Abstract: This oxide for a semiconductor layer of a thin-film transistor contains Zn, Sn and In, and at least one type of element (X group element) selected from an X group comprising Si, Hf, Ga, Al, Ni, Ge, Ta, W and Nb. The present invention enables a thin-film transistor oxide that achieves high mobility and has excellent stress resistance (negligible threshold voltage shift before and after applying stress) to be provided.Type: ApplicationFiled: November 28, 2011Publication date: September 19, 2013Applicants: Samsung Display Co., Ltd., KABUSHIKI KAISHA KOBE SEIKO SHO (Kobe Steel ,Ltd.)Inventors: Aya Miki, Shinya Morita, Toshihiro Kugimiya, Satoshi Yasuno, Jae Woo Park, Je Hun Lee, Byung Du Ahn
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Patent number: 8486564Abstract: Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.Type: GrantFiled: September 14, 2012Date of Patent: July 16, 2013Assignees: Toyota Jidosha Kabushiki Kaisha, Sumitomo Metal Mining Co., Ltd.Inventors: Hiroki Nagai, Masahiro Morita, Kensaku Mori, Shin Imaizumi, Kenji Ikeuchi, Toshiyuki Osako, Hiroyuki Toya
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Patent number: 8435473Abstract: Disclosed is a superconducting compound which has a structure obtained by partially substituting oxygen ions of a compound, which is represented by the following chemical formula; LnTMOPh [wherein Ln represents at least one element selected from Y and rare earth metal elements (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu), TM represents at least one element selected from transition metal elements (Fe, Ru, Os, Ni, Pd and Pt), and Pn represents at least one element selected from pnictide elements (N, P, As and Sb)] and has a ZrCuSiAs-type crystal structure (space group P4/nmm), with at least one kind of monovalent anion (F?, Cl? or Br?). The superconducting compound alternatively has a structure obtained by partially substituting Ln ions of the compound with at least one kind of tetravalent metal ion (Ti4+, Zr4+, Hf4+, C4+, Si4+, Ge4+, Sn4+ or Pb4+) or a structure obtained by partially substituting Ln ions of the compound with at least one kind of divalent metal ion (Mg2+, Ca2+, Sr2+ or Ba2+).Type: GrantFiled: February 17, 2009Date of Patent: May 7, 2013Assignee: Japan Science and Technology AgencyInventors: Hideo Hosono, Yoichi Kamihara, Masahiro Hirano, Toshio Kamiya, Hiroshi Yanagi
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Publication number: 20130095348Abstract: An optical information recording medium includes a recording layer capable of recording information signals on the basis of application of light, wherein the recording layer contains an oxide of metal X and an oxide of metal Y, the metal X is at least one type selected from the group consisting of tungsten and molybdenum, and the metal Y is at least one type selected from the group consisting of copper, manganese, nickel, and silver.Type: ApplicationFiled: October 10, 2012Publication date: April 18, 2013Applicant: SONY CORPORATIONInventor: SONY CORPORATION
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Patent number: 8419983Abstract: The present invention relates to a nickel oxide-stabilized zirconia composite in which nickel oxide is dispersed uniformly, a process for readily producing the composite oxide, and an anode for a solid oxide fuel cell having excellent output characteristics. More specifically, the present invention provides a nickel oxide-stabilized zirconia composite that is produced by sintering a mixture of nickel hydroxide and/or nickel carbonate and a hydroxide of stabilized zirconium.Type: GrantFiled: August 7, 2009Date of Patent: April 16, 2013Assignees: Tanaka Chemical Corporation, Daiichi Kigenso Kagaku Kogyo Co., Ltd.Inventors: Kyosuke Domae, Takeshi Usui, Tadashi Yasui, Satoshi Watanabe
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Publication number: 20130089739Abstract: Embodiments of the present disclosure provide for nanoparticles, methods of making nanoparticles, methods of using the nanoparticles, and the like. Nanoparticles of the present disclosure can have a variety of morphologies, which may lead to their use in a variety of technologies and processes. Nanoparticles of the present may be used in sensors, optics, mechanics, circuits, and the like. In addition, nanoparticles of the present disclosure may be used in catalytic reactions, for CO oxidation, as super-capacitors, in hydrogen storage, and the like.Type: ApplicationFiled: October 1, 2012Publication date: April 11, 2013Applicant: King Abdullah University of Science and Technology (KAUST)Inventor: King Abdullah University of Science and Technolo
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Publication number: 20130045421Abstract: The present invention relates to nickel-cobalt-manganese-based compound particles which have a volume-based average secondary particle diameter (D50) of 3.0 to 25.0 ?m, wherein the volume-based average secondary particle diameter (D50) and a half value width (W) of the peak in volume-based particle size distribution of secondary particles thereof satisfy the relational formula: W?0.4×D50, and can be produced by dropping a metal salt-containing solution and an alkali solution to an alkali solution at the same time, followed by subjecting the obtained reaction solution to neutralization and precipitation reaction. The nickel-cobalt-manganese-based compound particles according to the present invention have a uniform particle size, a less content of very fine particles, a high crystallinity and a large primary particle diameter, and therefore are useful as a precursor of a positive electrode active substance used in a non-aqueous electrolyte secondary battery.Type: ApplicationFiled: October 21, 2010Publication date: February 21, 2013Inventors: Masashi Kobino, Katsuhiro Fujita, Shoichi Fujino, Akihisa Kajiyama, Ryuta Masaki, Daisuke Morita, Takayuki Yamamura, Tetsuya Kodaira, Minoru Yamasaki, Seiji Okazaki, Toshiaki Hiramoto, Akino Sato, Wataru Oda, Kenji Okinaka
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Publication number: 20130009111Abstract: Disclosed is an oxide for a semiconductor layer of a thin film transistor, which, when used in a thin film transistor that includes an oxide semiconductor in the semiconductor layer, imparts good switching characteristics and stress resistance to the transistor. Specifically disclosed is an oxide for a semiconductor layer of a thin film transistor, which is used for a semiconductor layer of a thin film transistor and contains at least one element selected from the group consisting of In, Ga and Zn and at least one element selected from the group X consisting of Al, Si, Ni, Ge, Sn, Hf, Ta and W.Type: ApplicationFiled: April 7, 2011Publication date: January 10, 2013Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Shinya Morita, Toshihiro Kugiyama, Takeaki Maeda, Satoshi Yasuno, Yasuaki Terao, Aya Miki
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Positive electrode active material and non-aqueous electrolyte secondary battery containing the same
Patent number: 8349287Abstract: The present invention relates to a positive electrode active material comprising a lithium-containing composite oxide containing nickel with an oxidation state of 2.0 to 2.5 and manganese with an oxidation state of 3.5 to 4.0, the oxidation state determined by the shifts of energy at which absorption maximum is observed in the X-ray absorption near-K-edge structures, and to a non-aqueous electrolyte secondary battery using the same, the positive electrode active material being characterized in having a high capacity, a long storage life and excellent cycle life.Type: GrantFiled: May 1, 2007Date of Patent: January 8, 2013Assignees: Panasonic Corporation, Osaka City UniversityInventors: Tsutomu Ohzuku, Hiroshi Yoshizawa, Masatoshi Nagayama -
Patent number: 8349286Abstract: A lithium-transition metal complex compound has an nth order hierarchical structure in which n type structures represented by at least one unit of ath order units in a range of 1×10?(a+5) m to 10×10?(a+5) m exist in a complex form, wherein n is a natural number that is 2 or greater, and a is a natural number in a range of 1 to 5. The lithium-transition metal complex may be prepared by heat-treating a mixture including a lithium source, a transition metal source, and solvent in contact with a natural material having a hierarchical structure. A lithium battery includes an electrode including the lithium-transition metal complex compound having the nth order hierarchical structure. The lithium battery can have improved rapid charging characteristics, high power characteristics, and cycle characteristics.Type: GrantFiled: March 6, 2009Date of Patent: January 8, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Yoonsok Kang, Joungwon Park, Guesung Kim, Jaegu Yoon
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Patent number: 8236277Abstract: A process comprises (a) combining (1) at least one base and (2) at least one metal carboxylate salt comprising (i) a metal cation selected from metal cations that form amphoteric metal oxides or oxyhydroxides and (ii) a carboxylate anion comprising from one to four alkyleneoxy moieties, or metal carboxylate salt precursors comprising (i) at least one metal salt comprising the metal cation and a non-interfering anion and (ii) at least one carboxylic acid comprising from one to four alkyleneoxy moieties, at least one salt of the carboxylic acid and a non-interfering, non-metal cation, or a mixture thereof; and (b) allowing the base and the metal carboxylate salt or metal carboxylate salt precursors to react.Type: GrantFiled: December 18, 2007Date of Patent: August 7, 2012Assignee: 3M Innovative Properties CompanyInventor: Timothy D. Dunbar
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Patent number: 8216544Abstract: A ZnO varistor powder can be obtained with high operating voltage and excellent current-voltage nonlinear resistance characteristics. In the ZnO varistor powder, the main ingredient is zinc oxide (ZnO); and at least bismuth (Bi), cobalt (Co), manganese (Mn), antimony (Sb), nickel (Ni), and aluminum (Al), calculated as Bi2O3, CO2O3, MnO, Sb2O3, NiO, and Al3+, are contained as accessory ingredients in amounts of 0.3 to 1.5 mol % Bi2O3, 0.3 to 2.0 mol % Co2O3, 0.3 to 3 mol % MnO, 0.5 to 4 mol % Sb2O3, 0.5 to 4 mol % NiO, and 0.0005 to 0.02 mol % Al3+. ZnO content is greater than or equal to 90 mol %; the bulk density is greater than or equal to 2.5 g/cc; the powder is a spherical powder in which the 50% particle diameter in the particle size distribution is 20 ?m to 120 ?m.Type: GrantFiled: March 5, 2008Date of Patent: July 10, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Hideyasu Ando, Yasunori Kasuga
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Patent number: 8192595Abstract: A transition metal/carbon nanotube composite includes a carbon nanotube and a transition metal oxide coating layer disposed on the carbon nanotube. The transition metal oxide coating layer includes a nickel-cobalt oxide.Type: GrantFiled: December 2, 2009Date of Patent: June 5, 2012Assignees: Samsung Electronics Co., Ltd., Industry-Academic Cooperation Foundation, Yonsei UniversityInventors: Ho-jung Yang, Hyo-rang Kang, Kwang-bum Kim, Jin-go Kim
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Patent number: 8173301Abstract: A positive electrode active material for a non-aqueous electrolyte secondary battery including a lithium-containing transition metal oxide having a closest-packed cubic structure of oxygen, the lithium-containing transition metal oxide having a composition represented by the formula (1): Li[Lip(NixMnyCoz)1-p]O2, where x, y, and z represent element contents of nickel, manganese, and cobalt, respectively, and satisfies 0.2+y?x?0.7, 0.15?y, 0.05?z, x+y+z=1, and 0?p?0.1.Type: GrantFiled: November 5, 2008Date of Patent: May 8, 2012Assignee: Panasonic CorporationInventors: Hidekazu Hiratsuka, Norihiro Yamamoto, Yutaka Kawatate, Hiroaki Furuta, Kensuke Nakura, Hiroshi Yoshizawa
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Patent number: 8147783Abstract: Disclosed are a nickel hydroxide powder and a method for producing the same. The nickel hydroxide powder comprises a particle in the form of sphere, an average particle diameter of 0.1 ?m or more and 30 ?m or less, and the amount of the particles having a diameter of 0.7 times or more and 1.3 times or less the average particle diameter of 80% by weight or more based on the total amount of particles. The method for producing a nickel hydroxide powder comprises the steps of (1) to (4): (1) injecting a solution containing a nickel salt through a pore into a liquid mutually insoluble with the solution to obtain an emulsion including solution as a dispersed phase and the liquid as a continuous phase; (2) gelating the emulsion; (3) separating the dispersed phase from the obtained gel to obtain a cake; and (4) drying the cake.Type: GrantFiled: October 26, 2005Date of Patent: April 3, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshio Uchida, Seiji Tsuji, Ren-De Sun
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Patent number: 8137844Abstract: A method for manufacturing a cathode active material for a lithium rechargeable battery, including: selecting a first metal compound from a group consisting of a halide, a phosphate, a hydrogen phosphate and a sulfate of Mg or Al; selecting a second metal compound from a group consisting of an oxide, a hydroxide and a carbonate of Mg or Al; combining the first metal compound and the second metal compound to obtain a metal compound, the metal compound containing either Mg or Al atoms; mixing a lithium compound, a transition metal compound and the metal compound to obtain a mixture; and sintering the mixture.Type: GrantFiled: November 16, 2007Date of Patent: March 20, 2012Assignee: Nippon Chemical Industrial Co., Ltd.Inventors: Hidekazu Awano, Minoru Fukuchi, Yuuki Anbe
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Patent number: 8088349Abstract: Disclosed is a clean method for preparing layered double hydroxides (LDHs), in which hydroxides of different metals are used as starting materials for production of LDHs by atom-economical reactions. The atom efficiency of the reaction is 100% in each case because all the atoms of the reactants are converted into the target product since only M2+(OH)2, M3+(OH)3, and CO2 or HnAn? are used, without any NaOH or other materials. Since there is no by-product, filtration or washing process is unnecessary. The consequent reduction in water consumption is also beneficial to the environment.Type: GrantFiled: September 11, 2007Date of Patent: January 3, 2012Assignee: Beijing University of Chemical TechnologyInventors: Xue Duan, Dianqing Li, Zhi Lv, Yanjun Lin, Xiangyu Xu
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Publication number: 20110315936Abstract: A sputtering target including an oxide sintered body, the oxide sintered body containing indium (In) and at least one element selected from gadolinium (Gd), dysprosium (Dy), holmium (Ho), erbium (Er) and ytterbium (Yb), and the oxide sintered body substantially being of a bixbyite structure.Type: ApplicationFiled: February 28, 2008Publication date: December 29, 2011Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Kazuyoshi Inoue, Koki Yano, Masashi Kasami
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Publication number: 20110311805Abstract: The invention relates to a cutting tool having a substrate base body and a single or multi-layered coating attached thereupon, wherein at least one layer of the coating is a metal oxide layer produced in the PVD process or in the CVD process and the metal oxide layer has a grain structure wherein there is structural disorder within a plurality of the existing grains that are characterized in that in electron diffraction images of the grains, point-shaped reflections occur up to a maximum lattice spacing dGRENZ and for lattice spacing greater than dGRENZ no point-shaped reflections occur, but rather a diffuse intensity distribution typical for amorphous structures.Type: ApplicationFiled: March 18, 2010Publication date: December 22, 2011Applicant: WALTER AGInventors: Veit Schier, Oliver Eibl, Wolfgang Engelhart
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Publication number: 20110300470Abstract: The invention relates to a device and a method for the production of compounds by precipitation of solids from solutions, the physical and chemical properties of the solid particles formed on precipitation being flexible and can be independently fixable. Custom products can thus be produced with very high space-time yields and a particulate nickel/cobalt mixed hydroxide of formula NixCo1-x(OH)2, with a BET surface area of 20 m2/g and a tap density of greater than 2.4 g/cm3.Type: ApplicationFiled: March 20, 2007Publication date: December 8, 2011Applicant: H.C. STARCK GMBHInventors: Armin Olbrich, Juliane Meese-Marktscheffel, Matthias Jahn, Rüdiger Zertani, Gerd Maikowske, Sven Albrecht, Stefan Malcus, Josef Schmoll, Gabriele Christine Schmoll, Christian Peter Schmoll, Wolfgang Josef Schmoll, Volker Schmoll, Georg Wilhelm Schmoll, Michael Kruft
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Patent number: 8048398Abstract: Process for preparing a mixed metal oxide powder, in which oxidizable starting materials are evaporated and oxidized, the reaction mixture is cooled after the reaction and the pulverulent solids are removed from gaseous substances, wherein as starting materials, at least one pulverulent metal and at least one metal compound, the metal and the metal component of the metal compound being different and the proportion of metal being at least 80% by weight based on the sum of metal and metal component from metal compound, together with one or more combustion gases, are fed to an evaporation zone of a reactor, where metal and metal compound are evaporated completely under nonoxidizing conditions, subsequently, the mixture flowing out of the evaporation zone is reacted in the oxidation zone of this reactor with a stream of a supplied oxygen-containing gas whose oxygen content is at least sufficient to oxidize the starting materials and combustion gases completely.Type: GrantFiled: May 9, 2007Date of Patent: November 1, 2011Assignee: Evonik Degussa GmbHInventors: Stipan Katusic, Guido Zimmermann, Michael Kraemer, Peter Kress, Horst Miess
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Patent number: 7985503Abstract: The invention relates to a method for preparing multiple metal oxides and intermediate compound, i.e. spherical nickelous hydroxide which is lopped. The intermediate compound is prepared by: mixing bivalent nickel salt, cobalt salt, ammonia water and ammonium salt to form solution containing complex; then adding the said solution containing complex with the mixture solution of metal salt(s) and alkali into reaction vessel in parallel flow, stirring to form precipitate of spherical nickelous hydroxide which is dopped, and washing to remove the impurities. The resulting spherical nickelous hydroxide which is dopped, as an intermediate compound, can be used to produce multiple metal oxides. The resulting multiple metal oxides can be used as anode active material. The spherical nickelous hydroxide has advantages of uniform size and narrow size distribution. The multiple metal oxides has high electric conductivity and cycle performance, particularly, is suitable to be used as anode material.Type: GrantFiled: June 27, 2005Date of Patent: July 26, 2011Assignee: Shenzhen Bak Battery Co., LtdInventors: Long Li, Can Ren
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Patent number: RE43276Abstract: Disclosed is a positive active material for a rechargeable lithium battery. The positive active material includes at least one compound represented by formulas 1 to 4 and a metal oxide or composite metal oxide layer formed on the compound. LixNi1?yMnyF2??(1) LixNi1?yMnyS2??(2) LixNi1-?y?2MnyMzO2?aFa??(3) LixNi1?y?zMnyMzO2?aSa??(4) (where M is selected from the group consisting of Co, Mg, Fe, Sr, Ti, B, Si, Ga, Al, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb, Lu, Ac, Th, Pa, U, Np, Pu, Am, Cm, Bk, Cf, Es, Fm, Md, No and Lr, 0.95?x?1.1, 0<y?0.99, 0?z?0.5, and 0?a?0.5).Type: GrantFiled: September 13, 2010Date of Patent: March 27, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Ho-Jin Kweon, Hyun-Sook Jung, Yong-Chul Park, Geun-Bae Kim