Nickel (ni) Containing Patents (Class 423/594.3)
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Patent number: 7964175Abstract: A procedure for obtaining mixed multimetallic oxides derived from hydrotalcite type compounds, characterized in that the laminar metallic hydroxides obtained are constituted by three or four metallic cations, forming part of the sheets of the hydrotalcite type material represented by the formula: [M(II)1?x?y?zM(II)?xM(III)yM(III)?z(OH)2](An?y+z/n).mH2O. by a process comprising: (1) preparing an aqueous or organic solution containing three or more cations; (2) preparing an alkaline solution; (3) slowly combining solutions (1) and (2) to cause the co-precipitation of the cations in the form of hydroxides; (4) washing the precipitate containing the hydrotalcites with water, until removal of the non-precipitated ions; (5) drying; and (6) calcining the hydrotalcites.Type: GrantFiled: January 6, 2006Date of Patent: June 21, 2011Assignee: Instituto Mexico del PetroleoInventors: Jaime Sánchez Valente, Esteban López Salinas, Manuel Sánchez Cantú, Francisco Hernández Beltrán
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Publication number: 20110140036Abstract: Provided is a cathode active material which is lithium transition metal oxide having an ?-NaFeO2 layered crystal structure, wherein the transition metal is a blend of Ni and Mn, an average oxidation number of the transition metals except lithium is +3 or higher, and lithium transition metal oxide satisfies the Equation m(Ni)?m(Mn) (in which m (Ni) and m (Mn) represent an molar number of manganese and nickel, respectively). The lithium transition metal oxide has a uniform and stable layered structure through control of oxidation number of transition metals to a level higher than +3, thus advantageously exerting improved overall electrochemical properties including electric capacity, in particular, superior high-rate charge/discharge characteristics.Type: ApplicationFiled: July 9, 2010Publication date: June 16, 2011Applicant: LG CHEM, LTD.Inventors: Sung kyun CHANG, Hong-Kyu Park, Hyo-Shik Kil, Jin-hyung Lim
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Publication number: 20110104469Abstract: Provided here is a method of producing a monolithic body from a porous matrix, comprising: (i) providing a porous matrix having interstitial spaces and comprising at least a first reactant; (ii) contacting the porous matrix with an infiltrating medium that carries at least a second reactant; (iii) allowing the infiltrating medium to infiltrate at least a portion of the interstitial spaces of the porous matrix under conditions that promote a reaction between the at least first reactant and the at least second reactant to provide at least a first product; and (iv) allowing the at least first product to form and fill at least a portion of the interstitial spaces of the porous matrix, thereby producing a monolithic body, wherein the monolithic body does not comprise barium titanate.Type: ApplicationFiled: January 4, 2011Publication date: May 5, 2011Inventors: Richard E. Riman, Vahit Atakan
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Publication number: 20110091371Abstract: Soluble homo and heterometallic coordination polymers based on the oxalate ligand and method for obtaining spinels from them. Homo or heterometallic coordination polymers comprising at least one oxalate ligand are characterised by comprising also at least one organic molecule that can stabilise extended structures of metal complexes by the formation of supramolecular interactions so that this polymer is substantially water-soluble and insoluble in organic solvents.Type: ApplicationFiled: April 24, 2009Publication date: April 21, 2011Applicant: Universitat De Valencia, Estudi GeneralInventors: Eugenio Coronado Miralles, Carlos Marti Gastaldo, Jose Ramon Galan Mascaros
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Patent number: 7897136Abstract: A method is described for the manufacture of hydrotalcites by using at least one compound of a bivalent metal (Component A) and at least one compound of a trivalent metal (Component B), wherein at least one of these components is not used in the form of a solution, characterized in that a) at least one of the Components A and/or B which is not used in the form of a solution, shortly before or during mixing of the components, and/or b) the mixture containing the Components A and B is subjected to intensive grinding until an average particle size (D50) in the range of approx. 0.1 to 5 ?m is obtained, and optionally, after aging treatment or hydrothermal treatment, the resulting hydrotalcite product is separated, dried, and optionally calcinated.Type: GrantFiled: April 30, 2007Date of Patent: March 1, 2011Assignee: Sud-Chemie AGInventors: Max Eisgruber, Jürgen Ladebeck, Jürgen Koy, Hubert Schiessling, Wolfgang Buckl, Herrmann Ebert
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Publication number: 20110002831Abstract: A sol-gel process for preparing a mixture of metal-oxide-metal compounds wherein at least one metal oxide precursor is subjected to a hydrolysis treatment to obtain one or more corresponding metal oxide hydroxides, the metal oxide hydroxides so obtained are subjected to a condensation treatment to form the metal-oxide-metal compounds, which process is carried out in the presence of an encapsulated catalyst, whereby the catalytically active species is released from the encapsulating unit by exposure to an external stimulus, and wherein the catalytically active species released after exposure to such external stimulus is capable of catalyzing the condensation of the metal-hydroxide groups that are present in the metal oxide hydroxides so obtained.Type: ApplicationFiled: December 15, 2008Publication date: January 6, 2011Inventors: Nanning Joerg Arfsten, Pascal Jozef Paul Buskens, Jens Christoph Thies
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Publication number: 20100266485Abstract: A process comprises (a) combining (1) at least one base and (2) at least one metal carboxylate salt comprising (i) a metal cation selected from metal cations that form amphoteric metal oxides or oxyhydroxides and (ii) a lactate or thiolactate anion, or metal carboxylate salt precursors comprising (i) at least one metal salt comprising the metal cation and a non-interfering anion and (ii) lactic or thiolactic acid, a lactate or thiolactate salt of a non-interfering, non-metal cation, or a mixture thereof; and (b) allowing the base and the metal carboxylate salt or metal carboxylate salt precursors to react.Type: ApplicationFiled: December 16, 2008Publication date: October 21, 2010Inventor: Timothy D. Dunbar
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Patent number: 7816440Abstract: A flame retardant includes magnesium-hydroxide particles that contain at least one transitional metal compound. The at least one transitional metal compound is at least one compound selected from a group consisting of copper compound, cobalt compound, nickel compound, zinc compound and titanium compound. The at least one transitional metal compound is contained in the magnesium-hydroxide particles with the content of 100 to 1000 mass ppm in terms of metals. In addition, the total content of the copper compound, the cobalt compound and the nickel compound is 1000 mass ppm in terms of metals or less while the total content of the zinc compound and the titanium compound is 1000 mass ppm or less.Type: GrantFiled: October 24, 2006Date of Patent: October 19, 2010Assignee: Konoshima Chemical Co., Ltd.Inventor: Seiji Matsui
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Publication number: 20100254875Abstract: A material comprising a plurality of nanoparticles. Each of the plurality of nanoparticles includes at least one of a metal phosphate, a metal silicate, a metal oxide, a metal borate, a metal aluminate, and combinations thereof. The plurality of nanoparticles is substantially monodisperse. Also disclosed is a method of making a plurality of substantially monodisperse nanoparticles. The method includes providing a slurry of at least one metal precursor, maintaining the pH of the slurry at a predetermined value, mechanically milling the slurry, drying the slurry to form a powder; and calcining the powder at a predetermined temperature to form the plurality of nanoparticles.Type: ApplicationFiled: October 5, 2006Publication date: October 7, 2010Inventors: Kalaga Murali Krishna, Sergio Paulo Martins Loureiro, Mohan Manoharan, Geetha Karavoor, Shweta Saraswat
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Patent number: 7803348Abstract: Oxygen is reduced in the presence of a catalyst at the cathode of an alkaline-electrolyte fuel cell. Catalysts of the formula Sr3?xA1+xCo4?yByO10.5?z wherein ?0.6?x?1.0; 0?y?3; and ?1.5?z?0.5; wherein A represents Eu, Gd, Tb, Dy, Ho, or Y; and wherein B represents Fe, Ga, Cu, Ni, Mn, and Cr, demonstrate high catalytic activity and high chemical stability when used as the oxygen-reduction catalyst in alkaline fuel cells.Type: GrantFiled: February 10, 2006Date of Patent: September 28, 2010Assignee: Horizon Fuel Cells, LLCInventors: Evgeny V. Antipov, Galina A. Tsirlina, Sergey Y. Istomin, Oleg A. Drozhzhin, Eduard E. Levin
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Patent number: 7759007Abstract: A lithium ion secondary battery is provided. The battery includes a positive electrode having at least a cathode active material and a binder, a negative electrode, an electrolyte, and a separator which are arranged between the positive electrode and the negative electrode, and in which an open circuit voltage per unit cell in a full charging state lies within (4.25V?voltage?6.00V). The cathode active material includes either a lithium-cobalt composite oxide expressed by a general formula: LiaCo1-xMexO2-b (Me denotes metal elements of at least one, two or more kinds selected from V, Cu, Zr, Zn, Mg, Al, and Fe; 0.9?a?1.1; 0?x=0.3; and ?0.1?b?0.1) or a lithium-cobalt-nickel-manganese oxide expressed by a general formula: LiaNi1-x-y-zCoxMnyMezO2-b (0.9?a?1.1; 0<x<0.4; 0<y<0.4; 0<z<0.3; and ?0.1?b?0.1). The binder includes a polyacrylonitrile resin.Type: GrantFiled: December 19, 2006Date of Patent: July 20, 2010Assignee: Sony CorporationInventors: Takashi Tokunaga, Yoshiaki Obana, Hiroyuki Akashi
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Patent number: 7749321Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).Type: GrantFiled: June 28, 2007Date of Patent: July 6, 2010Assignee: E. I. du Pont de Nemours and CompanyInventors: Jerome D. Smith, Pedro A. Jimenez, Tony Jackson
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Publication number: 20100135896Abstract: The present invention involves a process and materials for simultaneous desulfurization and water gas shift of a gaseous stream comprising contacting the gas stream with a nickel aluminate catalyst. The nickel aluminate catalyst is preferably selected from the group consisting of Ni2xAl2O2x+3, Ni(2?y)Ni0yAl2O(5?y), Ni(4?y)Ni0yAl2O(7?y), Ni(6?y)Ni0yAl2O(9?y), and intermediates thereof, wherein x?0.5 and 0.01?y?2. Preferably, x is between 1 and 3. More preferably, the nickel containing compound further comprises Ni2xAl2O2x+3?zSz wherein 0?z?2x.Type: ApplicationFiled: December 4, 2008Publication date: June 3, 2010Inventors: Manuela Serban, Lisa M. King, Alakananda Bhattacharyya, Kurt M. Vanden Bussche
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Publication number: 20100135937Abstract: Nanocrystalline forms of metal oxides, including binary metal oxide, perovskite type metal oxides, and complex metal oxides, including doped metal oxides, are provided. Methods of preparation of the nanocrystals are also provided. The nanocrystals, including uncapped and uncoated metal oxide nanocrystals, can be dispersed in a liquid to provide dispersions that are stable and do not precipitate over a period of time ranging from hours to months. Methods of preparation of the dispersions, and methods of use of the dispersions in forming films, are likewise provided. The films can include an organic, inorganic, or mixed organic/inorganic matrix. The films can be substantially free of all organic materials. The films can be used as coatings, or can be used as dielectric layers in a variety of electronics applications, for example as a dielectric material for an ultracapacitor, which can include a mesoporous material. Or the films can be used as a high-K dielectric in organic field-effect transistors.Type: ApplicationFiled: September 24, 2009Publication date: June 3, 2010Applicant: The Trustees of Columbia University in the City of New YorkInventors: Stephen O'Brien, Limin Huang, Zhuoying Chen, Ioannis Kymissis, Zhang Jia
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Publication number: 20100124531Abstract: The present invention relates to nickel-manganese (Ni—Mn) binary compounds useful as an electrode material for electrochemical supercapacitors, which is one of nickel-manganese coprecipitated hydroxides having a spinel-like structure, nickel-manganese coprecipitated hydroxocarbonates having a calcite-like structure and nickel-manganese oxides having an ilmenite-like structure. The present invention also relates to a method of preparing the above nickel-manganese (Ni—Mn) binary compounds by chemical coprecipitation and freeze-drying. Since the nickel-manganese binary compounds according to the present invention show high electrochemical efficiency, good reversibility, excellent specific capacity per unit area, a low capacity fade rate and improved cycle life, they can be effectively used as an electrode material for electrochemical supercapacitors.Type: ApplicationFiled: June 25, 2009Publication date: May 20, 2010Inventors: Young Jei Oh, Oleg Shlyakhtin
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Publication number: 20100111803Abstract: Disclosed herein is a spinel article. The article comprises a spinel material, wherein the spinel material has a monomodal grain size distribution with average grain sizes of less than or equal to about 15 micrometers, and a biaxial flexural strength of greater than or equal to about 300 megapascals when measured by a ring-on-ring flexural test as per ASTM Standard C1499-08. Disclosed herein too is a spinel article manufactured by a method comprising calcining a spinel powder; milling the powder in a milling medium; granulating the powder; screening the powder to a mesh size of about 40 to about 200 mesh; pressing the powder to form an article; burning out organics from the article; sintering the article; and hot isostatically pressing the article.Type: ApplicationFiled: November 6, 2008Publication date: May 6, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Milivoj Konstantin Brun, Anteneh Kebbede, Sean Michael Sweeney, Timothy James Yosenick
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Patent number: 7700067Abstract: A crystallographically-oriented ceramic including first regions, in which crystal nuclei remain and which contain a specific element in a predetermined concentration range and extend at least partially in a layered shape along a crystal plane, and second regions, which contain the specific element in a different concentration range from the first regions and extend at least partially in a layered shape along the crystal plane. The regions are alternately repeated, and a compositional distribution exists in a direction orthogonal to the crystal plane. In the first region, the concentration of Na is higher, the concentration of K is lower, the concentration of Nb is lower, and the concentration of Ta is higher than the second region, and in the second region, the concentration of Na is lower, the concentration of K is higher, the concentration of Nb is higher, and the concentration of Ta is lower than the first region.Type: GrantFiled: February 22, 2008Date of Patent: April 20, 2010Assignee: NGK Insulators, Ltd.Inventors: Shohei Yokoyama, Nobuyuki Kobayashi, Tsutomu Nanataki
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Patent number: 7695866Abstract: Material for the positive electrode of batteries is provided that has good conductivity and can be manufactured more cheaply than AgNiO2. The battery positive electrode material is a conductive chemical compound represented by the general formula AgxNiyO2 (wherein X/Y is smaller than 1 and not smaller than 0.25). The conductive chemical compound is constituted of a crystal that has an X-ray diffraction main peak that is the same as that of AgNiO2 (wherein X=Y=1), and does not exhibit a Ag2O or AgO peak. This conductive compound can be used as an additive to impart conductivity to the silver oxide (Ag2O) of the positive electrode material.Type: GrantFiled: March 24, 2006Date of Patent: April 13, 2010Assignee: Dowa Electronics Materials Co., Ltd.Inventor: Koji Tanoue
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Patent number: 7695649Abstract: Disclosed are primary materials, precursor materials and final materials as well as methods to prepare these materials. The final materials are mixed lithium transition metal oxides, useful as performance optimized cathode materials for rechargeable lithium batteries. The transition metal is a solid solution mixture of manganese, nickel and cobalt, M=(Mn1-uNiu)1-u-yCoy, with 0.2.Type: GrantFiled: October 30, 2003Date of Patent: April 13, 2010Assignee: LG Chem, Ltd.Inventors: Jens Martin Paulsen, Ki Young Lee, Joon Sung Bae, Mun Ju Kim
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Patent number: 7691352Abstract: A new set of additives to be sued in the preparation of inorganic materials; especially of perovskite nature is proposed. The chemical compositions of the perovskites prepared in the presence of the mentioned additives are found to be more homogenous, leading to better catalytic behavior, including higher selectivity and yields as compared to catalysts of identical formulations prepared through the conventional method of using EDTA/citrate (or other organic additive) method.Type: GrantFiled: April 2, 2009Date of Patent: April 6, 2010Assignee: Research Institute of Petroleum Industry (RIPI)Inventors: Khodadad Nazari, Zahra Taheri, Naser Seyed Matin, Reza Ahmadi, Saeed Zarrinpashneh, Morteza Rezapour
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Positive electrode active material and non-aqueous electrolyte secondary battery containing the same
Patent number: 7682747Abstract: The present invention provides a high-capacity and low-cost non-aqueous electrolyte secondary battery, comprising: a negative electrode containing, as a negative electrode active material, a substance capable of absorbing/desorbing lithium ions and/or metal lithium; a separator; a positive electrode; and an electrolyte, wherein the positive electrode active material contained in the positive electrode is composed of crystalline particles of an oxide containing two kinds of transition metal elements, the crystalline particles having a layered crystal structure, and oxygen atoms constituting the oxide forming a cubic closest packing structure.Type: GrantFiled: October 25, 2007Date of Patent: March 23, 2010Assignee: Panasonic CorporationInventors: Tsutomu Ohzuku, Hiroshi Yoshizawa, Masatoshi Nagayama -
Patent number: 7666526Abstract: Non-volatile resistance-switching oxide films, and devices therewith, are disclosed. One embodiment of a suitable device is composed of a SRO-CZO thin film having a thickness of from about 6 to about 30 nm, and composed of from about 3 to about 10 molar % of a SrRuO3 conducting oxide dopant and from about 90 to about 97 molar % of a CaZrO3 insulating oxide material.Type: GrantFiled: April 26, 2007Date of Patent: February 23, 2010Assignee: The Trustees of the University of PennsylvaniaInventors: I-Wei Chen, Yudi Wang, Soo Gil Kim
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Publication number: 20100040531Abstract: A non-lead composition for use as a thick-film resistor paste in electronic applications. The composition comprises particles of Li2RuO3 of diameter between 0.5 and 5 microns and a lead-free frit. The particles have had the lithium at or near primarily the surface of the particle at least partially exchanged for atoms of other metals.Type: ApplicationFiled: October 23, 2009Publication date: February 18, 2010Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: PAUL DOUGLAS VERNOOY, ALFRED T. WALKER, KENNETH WARREN HANG
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Patent number: 7645907Abstract: This invention relates to a Polyoxometalate (POM) represented by the formula: (An)m+[HqM16X8W48O184(OH)32]m? or solvates thereof, wherein: A represents a cation, n is the number of the cations A, m is the charge of the polyoxoanion, q is the number of protons and varies from 0 to 12, M represents a transition metal, and X represents a heteroatom selected from P, As and mixtures thereof. This invention also relates to a process to produce such POMs and to a process for the homogeneous or heterogeneous oxidation of organic substrates comprising contacting the organic substrate with such POMs.Type: GrantFiled: March 23, 2007Date of Patent: January 12, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ulrich Kortz, Sib Sankar Mal
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Patent number: 7632477Abstract: This invention relates to a process for preparing zirconium oxide, in its various forms, including zirconium-based mixed oxides. There is described a process for preparing a zirconium oxide in the absence of a cerium salt which comprises precipitating a zirconium hydroxide from an aqueous solution of a zirconium salt by reaction with an alkali in the presence of a controlled amount of sulphate anions at a temperature not greater than 50° C. and then calcining the hydroxide to form an oxide, wherein the oxide thus formed is essentially sulphate free. Catalysts and ceramics can be produced from the product oxides having improved thermal stability and improved sinterability, respectively. A particular use of the product oxide is as a promoter or catalyst support in automobile exhaust systems.Type: GrantFiled: April 29, 2004Date of Patent: December 15, 2009Assignee: Magnesium Elektron, Ltd.Inventors: Yasuhide Takao, Colin Norman, Gavin Edwards, Ian Chisem, Clare Jones
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Patent number: 7575735Abstract: The present invention includes pure single-crystalline metal oxide and metal fluoride nanostructures, and methods of making same. These nanostructures include nanorods and nanoarrays.Type: GrantFiled: November 2, 2006Date of Patent: August 18, 2009Assignee: The Research Foundation of State University of New YorkInventors: Stanislaus S. Wong, Yuanbing Mao
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Publication number: 20090196818Abstract: A multiferroic element having a simple structure in which orientation of electric polarization or magnetization of a solid state material can be controlled by applying a magnetic field or an electric field, respectively. By applying an external magnetic field to a multiferroic solid state material that exhibits ferroelectricity and ferromagnetism having a spin structure such that the orientation of spin is rotating along the outside surface of a cone (apex angle ? at the top of the cone is in a range of 0<??90 degrees), an electric polarization with orientation substantially perpendicular to the direction of the externally applied magnetic field can be controlled. Meanwhile, by applying an external electric field to the multiferroic solid state material, a magnetization with an orientation substantially perpendicular to the direction of the externally applied electric field can be controlled.Type: ApplicationFiled: April 12, 2007Publication date: August 6, 2009Applicant: JAPAN SCIENCE AND TECHNOLOGYAGENCYInventors: Yoshinori Tokura, Takahisa Arima, Yoshio Kaneko
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Publication number: 20090192032Abstract: Disclosed herein is a light-responsive photocatalyst composition, which is a composite oxide semiconductor containing tungsten, and which can efficiently absorb visible light emitted from the sun and light emitted from interior lamps, such as fluorescent lamps, etc., and a method of preparing the light-responsive photocatalyst composition. The visible light-responsive photocatalyst composition can decompose volatile organic compounds or harmful organic matter causing sick house syndrome, even indoors, because it can be activated by visible light outdoors and can respond to light emitted from interior lamps, such as fluorescent lamps, etc.Type: ApplicationFiled: March 26, 2008Publication date: July 30, 2009Applicant: Seoul National University Industry FoundationInventors: In Sun Cho, Sang Wook Lee, Jun Hong Noh, Shin Tae Bae, Dong Wook Kim, Chin Moo Cho, Chae Hyun Kwak, Tae Hoon Noh, Duk Kyu Lee, Kug Sun Hong
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Publication number: 20090185971Abstract: A crystallographically-oriented ceramic including first regions, in which crystal nuclei remain and which contain a specific element in a predetermined concentration range and extend at least partially in a layered shape along a crystal plane, and second regions, which contain the specific element in a different concentration range from the first regions and extend at least partially in a layered shape along the crystal plane. The regions are alternately repeated, and a compositional distribution exists in a direction orthogonal to the crystal plane. In the first region, the concentration of Na is higher, the concentration of K is lower, the concentration of Nb is lower, and the concentration of Ta is higher than the second region, and in the second region, the concentration of Na is lower, the concentration of K is higher, the concentration of Nb is higher, and the concentration of Ta is lower than the first region.Type: ApplicationFiled: February 22, 2008Publication date: July 23, 2009Applicant: NGK Insulators, Ltd.Inventors: Shohei Yokoyama, Nobuyuki Kobayashi, Tsutomu Nanataki
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Patent number: 7563431Abstract: A process for preparing nickel hydroxide by alkaline precipitation from nickel salt solutions in the presence of complexing agents, in which the precipitation is carried out at at least two different locations in the same mother liquor with different precipitation kinetics at the different locations and the mother liquor is mixed prior to agglomeration of the precipitated primary crystals, is described.Type: GrantFiled: June 24, 2002Date of Patent: July 21, 2009Assignee: H. C. Starck GmbHInventors: Armin Olbrich, Juliane Meese-Marktscheffel, Viktor Stoller, Michael Erb, Sven Albrecht, Gerhard Gille, Gerd Maikowske, Frank Schrumpf, Josef Schmoll, Matthias Jahn
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Patent number: 7553474Abstract: It is an object to provide a method for producing stable alkaline metal oxide sols having a uniform particle size distribution. The method comprises the steps of: heating a metal compound at a temperature of 60° C. to 110° C. in an aqueous medium that contains a carbonate of quaternary ammonium; and carrying out hydrothermal processing at a temperature of 110° C. to 250° C. The carbonate of quaternary ammonium is (NR4)2CO3 or NR4HCO3 in which R represents a hydrocarbon group, or a mixture thereof. The metal compound is one, or two or more metal compounds selected from a group of compounds based on a metal having a valence that is bivalent, trivalent, or tetravalent.Type: GrantFiled: August 8, 2005Date of Patent: June 30, 2009Assignee: Nissan Chemical Industries, Ltd.Inventors: Yutaka Ohmori, Hirokazu Kato, Yoshinari Koyama, Kenji Yamaguchi
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Patent number: 7547491Abstract: Composite cathode active materials comprising a composite oxide and an acid treated with an organic solvent are provided. The composite cathode active materials are prepared by treating mixtures of nickel-based composite oxides and organic acids with organic solvents. The active materials suppress gelation of the electrode slurries for a long period of time, even when the active materials are mixed with fluorine-based polymers, by decreasing the basicity of the slurries and the amount of lithium present on the surfaces of the active materials. As a result, electrode slurries having high stability can be prepared. Cathodes and lithium batteries comprising the slurries have excellent charge-discharge characteristics, including high capacity and excellent high rate discharge characteristics.Type: GrantFiled: February 21, 2006Date of Patent: June 16, 2009Assignee: Samsung SDI Co., Ltd.Inventors: Yong-nam Ham, Gue-sung Kim, Young-min Choi
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Patent number: 7547400Abstract: A method for making monodispersed magnetic nanoparticles of nickel zinc ferrite (NZFO) at room temperature by mixing together two micelle solutions. The first micelle solution comprises zinc, nickel, and iron metal salts; a surfactant; and a hydrocarbon. The second micelle solution comprises an aqueous hydroxide, a surfactant, and a hydrocarbon. After mixing the two micelle solutions, the ferrite precipitates.Type: GrantFiled: June 1, 2005Date of Patent: June 16, 2009Assignee: The United States of America as represented by the Secretary of the NavyInventors: Everett E. Carpenter, Vincent G. Harris, Shannon A. Morrison
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Patent number: 7534528Abstract: An electrode material for an anode of a rechargeable lithium battery, containing a particulate comprising an amorphous Sn.A.X alloy with a substantially non-stoichiometric ratio composition. For said formula Sn.A.X , A indicates at least one kind of an element selected from a group consisting of transition metal elements, X indicates at least one kind of an element selected from a group consisting of O, F, N, Mg, Ba, Sr, Ca, La, Ce, Si, Ge, C, P, B, Pb, Bi, Sb, Al, Ga, In, Tl, Zn, Be, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, As, Se, Te, Li and S, where the element X is not always necessary to be contained. The content of the constituent element Sn of the amorphous Sn.A.X alloy is Sn/(Sn+A+X)=20 to 80 atomic %.Type: GrantFiled: October 10, 2006Date of Patent: May 19, 2009Assignee: Canon Kabushiki KaishaInventors: Soichiro Kawakami, Masaya Asao
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Patent number: 7488464Abstract: Methods and systems for processing metal oxides from metal containing solutions. Metal containing solutions are mixed with heated aqueous oxidizing solutions and processed in a continuous process reactor or batch processing system. Combinations of temperature, pressure, molarity, Eh value, and pH value of the mixed solution are monitored and adjusted so as to maintain solution conditions within a desired stability area during processing. This results in metal oxides having high or increased pollutant loading capacities and/or oxidation states. These metal oxides may be processed according to the invention to produce co-precipitated oxides of two or more metals, metal oxides incorporating foreign cations, metal oxides precipitated on active and inactive substrates, or combinations of any or all of these forms.Type: GrantFiled: July 28, 2004Date of Patent: February 10, 2009Assignee: EnviroScrub Technologies CorporationInventors: Charles F. Hammel, Richard M. Boren
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Publication number: 20090023972Abstract: Catalytic structures are provided comprising octahedral tunnel lattice manganese oxides ion-exchanged with metal cations or mixtures thereof. The structures are useful as catalysts for the oxidation of alkanes and may be prepared by treating layered manganese oxide under highly acidic conditions, optionally drying the treated product, and subjecting it to ion exchange.Type: ApplicationFiled: June 27, 2008Publication date: January 22, 2009Inventors: Helge Jaensch, Wilfried J. Mortier
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Patent number: 7476467Abstract: The present invention provides a non-aqueous electrolyte-based high power lithium secondary battery having a long-term service life and superior safety at both room temperature and high temperature, even after repeated high-current charging and discharging, wherein the battery comprises a mixture of a particular lithium manganese-metal composite oxide (A) having a spinel structure and a particular lithium nickel-manganese-cobalt composite oxide (B) having a layered structure, as a cathode active material.Type: GrantFiled: March 28, 2005Date of Patent: January 13, 2009Assignee: LG Chem, Ltd.Inventors: Hey Woong Park, Ji-Sang Yu, Sung-Woo Kim, Min Su Kim
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Patent number: 7396379Abstract: A hydrogen storage battery with improved cycle life and a method for making the same. The battery has a negative electrode with an electrochemically active negative material and a negative electrode capacity and a positive electrode electrochemically coupled with the negative electrode, the positive electrode having a positive electrode capacity and an electrochemically active positive material with a precharge. Also described herein is a positive electrode material for a hydrogen storage battery and a method for making the same. The positive electrode material includes a preoxidized positive active material which is partially non-oxidized. The preoxidized positive material may be used to provide precharge to the positive electrode of a hydrogen storage battery to aid in cell balancing.Type: GrantFiled: July 3, 2003Date of Patent: July 8, 2008Assignee: Ovonic Battery Company, Inc.Inventors: Michael A. Fetcenko, Kwo Young, Cristian Fierro
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Patent number: 7384706Abstract: Coagulated particles of nickel-cobalt-manganese hydroxide wherein primary particles are coagulated to form secondary particles are synthesized by allowing an aqueous solution of a nickel-cobalt-manganese salt, an aqueous solution of an alkali-metal hydroxide, and an ammonium-ion donor to react under specific conditions; and a lithium-nickel-cobalt-manganese-containing composite oxide represented by a general formula, LipNixMn1-x-yCoyO2-qFq (where 0.98?p?1.07, 0.3?x?0.5, 0.1?y?0.38, and 0?q?0.05), which is a positive electrode active material for a lithium secondary cell having a wide usable voltage range, a charge-discharge cycle durability, a high capacity and high safety, is obtained by dry-blending coagulated particles of nickel-cobalt-manganese composite oxyhydroxide formed by making an oxidant to act on the coagulated particles with a lithium salt, and firing the mixture in an oxygen-containing atmosphere.Type: GrantFiled: March 22, 2004Date of Patent: June 10, 2008Assignee: Seimi Chemical Co., Ltd.Inventors: Manabu Suhara, Takuya Mihara, Koichiro Ueda, Yukimitsu Wakasugi
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Patent number: 7381394Abstract: Methods of producing a safe and hygienic method for industrially and efficiently producing a perovskite-type composite oxide are provided that can maintain the catalytic activity of a noble metal at a high level. Methods include preparing a precursor of the perovskite-type composite oxide by mixing organometal salts of elementary components of the perovskite-type composite oxide and heat treating the precursor. The precursor may be prepared by mixing all elementary components constituting the perovskite-type composite oxide, or by mixing one or more organometal salts of part of the elementary components with the other elementary components prepared as alkoxides, a coprecipitate of salts, or a citrate complex of the respective elements.Type: GrantFiled: July 3, 2003Date of Patent: June 3, 2008Assignees: Daihatsu Motor Co., Ltd., Hokko Chemical Industry Co. Ltd.Inventors: Hirohisa Tanaka, Kimiyoshi Kaneko
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Publication number: 20080124265Abstract: An anode in a Direct Carbon Fuel Cell (DCFC) operating in a temperature range between 500 and 1200 degrees Celsius is provided. The anode material has high catalytic activity and selectivity for carbon oxidation, sufficient oxygen non-stoichiometry, rapid oxygen chemical diffusion, wide thermodynamic stability window to withstand reducing environment, sufficient electronic conductivity and tolerance to sulfur and CO2 environments. The anode has doped ruthenate compositions A1?xA?xRuO3, AB1?yRuyO3, or A1?xA?xB1?yRuyO3. A and A? may be divalent, trivalent, or tetravalent cation, and B is a multivalent cation. A is among lanthanide series elements La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Er or Yb, and dopant A? is from Group IIA, IIIB, or IVB elements. The doped ruthenates can also be a (AB1?yRuyO3) structure or an ordered Ruddlesden-Popper series ((A1?xAx?)n+1(B1?yRuy)nO3n+1) structure where n=1 or 2. The dopant B is among Group IVB, VB, VIB, VIII, IB, and IIB elements.Type: ApplicationFiled: October 16, 2007Publication date: May 29, 2008Inventor: Turgut M. Gur
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Patent number: 7368095Abstract: The present invention provides a composite oxide for a high performance solid oxide fuel cell which can be fired at a relatively low temperature, and which has little heterogeneous phases of impurities other than the desired composition. The composite oxide is the one having a perovskite type crystal structure containing rare earth elements, and having constituent elements homogeneously dispersed therein. A homogeneous composite oxide having an abundance ratio of heterogeneous phases of at most 0.3% by average area ratio, and a melting point of at least 1470° C., is obtained by using metal carbonates, oxides or hydroxides, and reacting them with citric acid in an aqueous system.Type: GrantFiled: November 15, 2002Date of Patent: May 6, 2008Assignee: Seimi Chemical Co., Ltd.Inventors: Fumio Munakata, Kenji Furuya, Masaharu Hatano, Yoshinori Fujie, Manabu Suhara
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Patent number: 7364793Abstract: The present invention provides a powdered lithium transition metal oxide useful as a major component for cathode active material of rechargeable lithium batteries, comprising a lithium transition metal oxide particle, a doped interface layer formed near the surface of the particle, and a thermodynamically and mechanically stable outer layer, and a method of preparing the same.Type: GrantFiled: September 24, 2004Date of Patent: April 29, 2008Assignee: LG Chem, Ltd.Inventors: Jens M. Paulsen, Munju Kim, Joon Sung Bae, Jaeup Jang, Hong-Kyu Park
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Patent number: 7357910Abstract: Method for producing metal oxide nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone into metal vapor. The metal vapor is directed away from the hot zone and into the cooler plasma afterglow where it oxidizes, cools and condenses to form solid metal oxide nanoparticles.Type: GrantFiled: July 15, 2002Date of Patent: April 15, 2008Assignee: Los Alamos National Security, LLCInventors: Jonathan Phillips, Daniel Mendoza, Chun-Ku Chen
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Patent number: 7294434Abstract: Nickel hydroxide material comprising particles with a microstructure including crystallites of less than 103 ? as measured in the 101 direction by x-ray diffraction. A method of making positive electrode material for use in an alkaline rechargeable electrochemical cell comprising forming a metal ion solution and increasing the pH to precipitate positive electrode material with a crystallite structure of 120 ? or less in the 101 direction.Type: GrantFiled: August 30, 2002Date of Patent: November 13, 2007Assignee: Ovonic Battery Company, Inc.Inventors: Cristian Fierro, Michael A. Fetcenko, Kwo Young, Stanford R. Ovshinsky, Beth Sommers, Craig Harrison
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Patent number: 7232557Abstract: The invention describes a method of preparing magnetic ferrites from layered precursors in which Fe2+ is first introduced into the layers of layered double hydroxides (LDHs) in order to prepare Me-Fe2+—Fe3+ LDHs, and then by utilizing the easily oxidized nature of Fe2+, binary or multi-component ferrite materials containing Fe3+ in a single crystalline phase can be prepared. Values of the saturation magnetization of ferrites prepared by the method are significantly increased compared with ferrites prepared by traditional methods. Because the metal elements in the layered precursor have the characteristics of a high degree of dispersion, high activity and small particle size (average particle size 40-200 nm), no milling is required before calcination, thus simplifying the production process, shortening the production period, reducing capital investment in equipment and economizing on energy costs. In addition, the method does not corrode production equipment and does not pollute the environment.Type: GrantFiled: January 21, 2005Date of Patent: June 19, 2007Assignee: Beijing University of Chemical TechnologyInventors: Xue Duan, Feng Li, Junjie Liu
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Patent number: 7232556Abstract: Nanoparticles comprising titanium, such as nanoscale doped titanium metal compounds, inorganic titanium compounds, and organic titanium compounds, their methods of manufacture, and methods of preparation of products from nanoparticles comprising titanium are provided.Type: GrantFiled: September 24, 2004Date of Patent: June 19, 2007Assignee: NanoProducts CorporationInventor: Tapesh Yadav
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Patent number: 7223377Abstract: The present invention is the method for preparation of transition metal oxide having micro-mesoporous structure whose average fine pores size is not less than 1 nm and not more than 2 nm comprising, adding and dissolving transition metal salt which is a precursor of transition metal oxide and/or metal alkoxide in the solution prepared by dissolving polymer surfactant in organic solvent, hydrolyzing said transition metal salt and/or metal alkoxide and preparing sol solution which is polymerized and self organized, then obtaining gel whose organization is stabilized from said sol solution and removing said polymer surfactant by using water of room temperature or water to which alkali metal or alkaline earth metal ion is added.Type: GrantFiled: October 2, 2002Date of Patent: May 29, 2007Assignee: Japan Science and Technology AgencyInventors: Kazunari Domen, Junko Nomura, Byonjin Ri
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Patent number: 7211238Abstract: Mesoporous aluminum oxides with high surface areas have been synthesized using inexpensive, small organic templating agents instead of surfactants. Optionally, some of the aluminum can be framework-substituted by one or more other elements. The material has high thermal stability and possesses a three-dimensionally randomly connected mesopore network with continuously tunable pore sizes. This material can be used as catalysts for dehydration, hydrotreating, hydrogenation, catalytic reforming, steam reforming, amination, Fischer-Tropsch synthesis and Diels-Alder synthesis, etc.Type: GrantFiled: March 8, 2004Date of Patent: May 1, 2007Assignee: ABB Lummus Global Inc.Inventors: Zhiping Shan, Jacobus Cornelius Jansen, Chuen Y. Yeh, Philip J. Angevine, Thomas Maschmeyer
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Patent number: 7183018Abstract: An electrode material for an anode of a rechargeable lithium battery, containing a particulate comprising an amorphous Sn.A.X alloy with a substantially non-stoichiometric ratio composition. For said formula Sn.A.X, A indicates at least one kind of an element selected from a group consisting of transition metal elements, X indicates at least one kind of an element selected from a group consisting of O, F, N, Mg, Ba, Sr, Ca, La, Ce, Si, Ge, C, P, B, Pb, Bi, Sb, Al, Ga, In, Tl, Zn, Be, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, As, Se, Te, Li and S, where the element X is not always necessary to be contained. The content of the constituent element Sn of the amorphous Sn.A.X alloy is Sn/(Sn+A+X)=20 to 80 atomic %.Type: GrantFiled: April 13, 2005Date of Patent: February 27, 2007Assignee: Canon Kabushiki KaishaInventors: Soichiro Kawakami, Masaya Asao