Abstract: A complex metal oxide powder having at least two metal elements, which contains polyhedral particles each having at least 6 planes, a number average particle size of from 0.1 to 500 .mu.m, and a D.sub.90 /D.sub.10 ratio of 10 or less in which D.sub.10 and D.sub.90 are particle sizes at 10% and 90% accumulation, respectively from the smallest particle size side in a cumulative particle size curve of the particles, and an yttrium-aluminum garnet powder containing polyhedral particles each having at least 6 planes, and a number average particle size of 20 to 500 .mu.m. These complex metal oxides contain less agglomerated particles, and have a narrow particle size distribution and a uniform particle shape.

Abstract: A method for the decomposition of chromium ore in a directly heated revolving tube is described, in which oxygen-containing gases are introduced into the revolving tube by means of below-bed nozzles.

Abstract: Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented bySr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta.where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Abstract: A method for manufacturing Li.sub.2 M.sub.b Mn.sub.2-b O.sub.4 which comprises the steps of providing LiM.sub.b Mn.sub.2-b O.sub.4 ; providing a lithium salt; forming a mixture of the LiM.sub.b Mn.sub.2-b O.sub.4 and lithium salt in a liquid medium; adding a reducing agent to the mixture; heating for sufficient time to effect substantially complete conversion; and separating the product Li.sub.2 M.sub.b Mn.sub.2-b O.sub.4.

Abstract: This invention relates to novel crystalline metallo manganese oxides that has the hollandite structure. The composition is represented by the formulaA.sub.y Mn.sub.8-x M.sub.x O.sub.16where A is a templating agent such as potassium, ammonium, and y varies from about 0.5 to about 2.0, M is a metal such as chromium, vanadium, gallium, antimony and x varies from about 0.01 to about 4.0. These oxides have a three-dimensional structure with manganese and the M metals forming the framework. Finally, these novel oxides are capable of catalyzing hydrocarbon conversion processes such as oxidation and oxidative dehydrogenation.

Abstract: A method for producing a cathode active material for a non-aqueous electrolyte secondary battery, which comprises the step of heating a mixture of .beta.-Ni(OH).sub.2 and a lithium salt in the presence of oxygen at a temperature ranging from 600.degree. C. to 800.degree. C. to obtain LiNiO.sub.2.

Abstract: A method for manufacturing Li.sub.2 M.sub.b Mn.sub.2-b O.sub.4 comprising the steps of providing LiM.sub.b Mn.sub.2-b O.sub.4 ; providing a source of lithium; dissolving lithium from the lithium source in a liquid medium in which lithium generates solvated electrons or the reduced form of an electron-transfer catalyst; and contacting the LiM.sub.b Mn.sub.2-b O.sub.4 with the liquid medium containing the dissolved lithium and the solvated electrons or the reduced form of the electron-transfer catalyst, wherein M is selected from the group Al, Ti, V, Cr, Fe, Co, Ni, and Cu.

Abstract: A process for recovery of chromium in an aqueous solution comprising converting the chromium to chromyl chloride, separating the chromyl chloride from the aqueous solution, either as a heavy underlayer, or by extraction into a solvent, purifying the chromyl chloride, hydrolyzing the purified chromyl chloride to form a solution, and drying or precipitating the solution to form chromium, either as chromic acid or a chromate salt.

Abstract: The invention provides a method of manufacturing stoichiometric potassium-lithium niobate crystals. Such crystals exhibit a high degree of double refraction and can suitably be used to double the frequency of a light wave with noncritical phase matching. By virtue of the temperature dependence of the nonlinear optical properties and the possibility of doubling the frequency at room temperature and at wavelengths from 800 to 850 nm the material according to the invention is very suitable for use in cooperation with semiconductor lasers.

Abstract: A La.sub.1-x Sr.sub.x Cr.sub.1-y Mn.sub.y O.sub.3 ceramic oxide gel obtainable by the process comprising the steps of:(a) providing a colloidal solution of polyhydroxy organic chelating agents selected from the group consisting of ethylene glycol and citric acid and metal salts selected from the group consisting of lanthanum, strontium, chromium, and manganese, each salt being present in an amount necessary to provide the stoichiometric amount of metal ions required in the ceramic oxide gel;(b) heating the colloidal solution to hydrolyze and polymerize the metal ions in the solution to a mixed metal oxide precursor of the ceramic oxide gel; and(c) adding organic acid, water or both to the precursor of the ceramic oxide gel to peptize the metal ions; and(d) heating the peptized precursor to evaporate solvent to form a thick, viscous, flexible, ductile, handleable gel that can be cast, extruded, or drawn; wherein x and y are independently 0 or 1.

Abstract: A method for manufacturing alkali chromates by the reacting of chromium ore with alkali compounds and oxidation in an atmosphere containing at least 50% oxygen is described, in which the mixture consisting of chromium ore, alkali compound and optionally leaning materials is heated in a first stage in an atmosphere containing not more than 5 vol. % oxygen to a temperature between 1000.degree. and 1 400.degree. C., and in a second stage is oxidized at a lower temperature of 900.degree. to 1 070.degree. C. with supply of an atmosphere containing at least 50% oxygen.

Abstract: The invention relates to a process for the low-waste production of sodium dichromate from the mineral chromite with simultaneous recovery of low-carbon ferrochromium.

Abstract: A method of producing active cathode material for lithium secondary battery is provided. In accordance with this invention, a mixture of a lithium salt and a transition metal salt is baked in oxygen atmosphere, wherein the oxygen pressure during baking is about 147.1 kPa or more. The lithium transition metal compound oxides prepared have the composition, Li.sub.x Ni.sub.y M.sub.1-y O.sub.2, wherein M is one kind of transition metal or more, and x and y respectively have the values 0.05.ltoreq.x.ltoreq.1.10 and 0.5.ltoreq.y.ltoreq.1.0. The active cathode material for a lithium secondary battery according to this invention, provides lithium transition metal compound oxides which are uniform in composition and characteristic, and exhibit excellent functioning as an active cathode material. Lithium secondary batteries produced therewith exhibit excellent cycle characteristics, high energy densities and low material costs, are of uniform quality and exhibit no unevenness of battery capacity.

Abstract: An oxide type solid lubricant is formed of a powder of a fired composite ceramic material resulting from heating a mixture of BaZrO.sub.3 and Cr.sub.2 O.sub.3 powders in which the Cr.sub.2 O.sub.3 content is up to 80% by weight.

Abstract: The oxide superconductor according to the present invention is represented by (Hg.sub.1-x Pb.sub.x)Ba.sub.2 Ca.sub.2 Cu.sub.3 O.sub..delta. (0.08.ltoreq.x.ltoreq.0.41, 7.625.ltoreq..delta..ltoreq.9.15), and has a crystal structure in which a lamination unit of (Hg, Pb)O.sub.z -BaO-CuO.sub.2 -Ca-CuO.sub.2 -Ca-CuO.sub.2 -BaO is laminated in a c-axial direction of the crystal structure (0.625.ltoreq.z.ltoreq.2.15). Further, the method of manufacturing an oxide superconductor, according to the present invention, includes the steps of: mixing material powders of HgO, PbO, BaO, CaO and CuO at a mole ratio of (Hg.sub.1-x Pb.sub.x):Ba:Ca:Cu=a:2:b:c (1.ltoreq.a.ltoreq.2.5, 2.ltoreq.b.ltoreq.3, 2.5.ltoreq.c.ltoreq.4) and compression-molding the mixture powder into a compact; and subjecting the compact to a thermal treatment at 600.degree.-750.degree. C.

Abstract: Disclosed is an improvement on a process in which sodium chromate is reacted with sulfuric acid to produce sodium bichromate and sodium sulfate, and the sodium bichromate is reacted with sulfuric acid to produce chromic acid and sodium bisulfate. In the improvement, the sodium sulfate and sodium bisulfate are reacted with hydrogen chloride to produce sulfuric acid, which is recycled, and sodium chloride.

Abstract: A process for the production of alkaline chromates by means of oxidative disaggregation in a reactor of substances containing trivalent chromium compounds in admixture with alkali. The oxidative disaggregation is carried out in dry phase by moving the mixture within the reactor while heating the mixture by indirect heat exchange in the absence of combustion gases and under mechanical stress, and feeding to the interior of the reactor oxidizing gas. The mixture is heated to a temperature of between 500.degree. and 1500.degree. C. The oxidizing gas is fed with an oxygen concentration in a range between 8 and 100%. Gases leaving the reactor are used for the acidification of an aqueous solution of alkaline chromates which is then dried and supplied to the reactor. The reactor is a rotating tubular reactor and the mixture moves continuously through the rotating reactor.

Abstract: The invention disclosed relates to a novel compound of molecular formula Li.sub.2 Cr.sub.x Mn.sub.2-x O.sub.4, wherein 0<X<2. This compound may be used as the active cathode material in secondary lithium ion cells. Secondary lithium ion cells including such cathodes are also described.

Abstract: A flux process is disclosed for producing a single orthorhombic crystal of Cs.sub.1-x M.sub.x TiOAsO.sub.4 (where M is Na, K, Rb, and/or Tl and x is from 0 to 0.4) wherein the dimension of the crystal along each axis is at least about 2 mm, and wherein the product at the dimensions along the three axes is at least about 15 mm.sup.3. The process involves preparing a homogeneous melt containing the components for forming said crystal and a flux comprising oxides of Cs and As at a temperature no higher than the decomposition temperature of said orthorhombic crystal, the mole fraction of M relative to the total Cs+M in the melt being within the range of from 0 to about 0.2; introducing a seed crystal for said single crystal in the melt; activating the controlled crystallization on the seed crystal; and continuing the crystallization until formation of the single crystal is completed. Single crystals of Cs.sub.1-x M.sub.x TiOAsO.sub.4 (including crystals at least about 5 mm.times.5 mm 5 mm) are also disclosed.

Abstract: Perovskite materials have a composition of the formula La.sub.1-x Sr.sub.x Cr.sub.1-y Ru.sub.y O.sub.3 wherein 0.1.ltoreq.x.ltoreq.0.5 and 0.01.ltoreq.y.ltoreq.0.10. The materials are used in catalysts for carbon monoxide oxidation, unsaturated hydrocarbon oxidation and/or nitrogen oxide reduction.

Abstract: The ferrates in solid state have the formula:M (Fe, X)O.sub.4in which M designates two atoms of Na or K or one atom of Ca or Ba, and X is an atom whose cation has the electronic structure of a rare gas. These ferrates are isomorphs of ferrates of the formula M FeO.sub.4, in which M has the same definition as above. Used particularly for the treatment of water, by oxidation.

Abstract: A process for the preparation of sodium dichromate and sodium dichromate solutions by alkaline oxidizing roasting of chromium ores, leaching resulting roast with water, adjustment of the pH to 7 to 9.5, removal of the insoluble constituents by filtration, a sodium monochromate solution containing 300 to 400 g/l of Na.sub.2 CrO.sub.4 being obtained, conversion of the monochromate ions of this solution into dichromate ions by addition of an acid and/or by electrolysis and/or by reaction with carbon dioxide under pressure and crystallization of sodium dichromate by concentration of this solution. The improvement wherein before the conversion into a sodium dichromate solution, the sodium monochromate solution is concentrated to contents of 700 to 1000 g/l of Na.sub.2 CrO.sub.4, the monochromatic ions, the solution is subsequently freed as far as possible from sodium sulphate by cooling to a temperature of below 0.degree. C.

Abstract: The invention relates to a process for the production of sodium dichromate and sodium dichromate solutions by oxidative roasting of chrome ores under alkaline conditions, leaching of the furnace clinker obtained with water or an aqueous chromate-containing solution, adjustment of the pH to from 7 to 9.5, removal of the insoluble constituents by filtration, a sodium monochromate solution being obtained, conversion of the monochromate ions of this solution into dichromate ions by acidification and crystallization of sodium dichromate by concentration of this solution, characterized in that the acidification is carried out with carbon dioxide under pressure with removal of sodium hydrogen carbonate, the remaining solution is then very largely freed from sodium monochromate by cooling to a temperature below 10.degree. C.

Abstract: According to the present invention, when a super-conductive thin film is formed on a substrate of a single crystal, a compound having a composition of SrNdGaO.sub.4 and a K.sub.2 NiF.sub.4 type crystal structure is used as a material employable for the substrate. Alternatively, a single crystal composed of an oxide in which Ca, La and Cr are added to the foregoing compound is used as a material employable for the substrate. Then, a super-conductive thin film composed of an oxide is formed on the substrate by employing an epitaxial growing method. Thus, the present invention makes it possible to provide a super-conductive material having an excellent property of lattice alignment, a stable and high critical superconductivity temperature and a stable critical superconductivity electric current.

Abstract: Novel superconducting oxide compositions of the formulas (YBa.sub.2 Cu.sub.3.25).sub.a O.sub.z and Y.sub.2 Ba.sub.4 Cu.sub.8 O.sub.20-x (248) are provided which can have an ordered defect structure stacked on one axis. MiThis invention was made with Government support under contracts DMR-8616055 awarded by the National Science Foundation and F49620-88C-0004 awarded by the United States Air Force. The Government has certain rights in this invention.

Abstract: Methods are described for the low temperature preparation of the spinel LiMn.sub.2 O.sub.4 and layered LiCoO.sub.2 phases which are intercalable compounds of interest for use in lithium secondary batteries. These phases can be prepared in bulk or thick film form at temperatures less than 400.degree. C. using acetate precursors.

Abstract: A composite oxide synthesized by a citrating process and utilized in functional ceramics materials is prepared by the following process. Co-precipitants or mixtures of at least one component selected from the group consisting of carbonates, basic copper and/or hydroxides of elements which compose a composite oxide are reacted with citric acid in an aqueous solution or in an organic solvent. The elements are selected from at least one element of the group consisting of Y, rare earth elements, transition elements, and alkali metal or alkaline earth metal elements. The citrate compound formed is baked to complete the composite oxide.The composite oxide synthesized by this invention has superconduction at the most temperature of 93.degree. K. with excellent Meissner effect.

Abstract: Process for the manufacture of a powder of mixed metal oxides by cohydrolysis of metal alcoholates in the presence of an acidic organic compound and mixed metal oxide powders in which the molar relationships R1 and R2 of a metal oxide to the sum of the metal oxides in the powder and in a particle of the powder are such that ##EQU1## The process applies especially well to powders of zirconia doped with yttrium oxide or other oxides.

Abstract: A varistor material is disclosed which has a composition consisting essentially of 93-97 mole % of ZnO and 3-7 mole % of MnO, a non-linear coefficient .alpha. of at least 20 and such a bulk density as to provide a porosity of greater than 15% but not greater than 50%, wherein the porosity is defined as follows:Porosity (%)=(1-d/d.sub.0).times.100wherein d represents the bulk density and d.sub.0 represents the theoretical density of the single phase pure ZnO. The varistor material is produced by sintering a mixture containing ZnO powder and 3-7 mole %, based on ZnO+MnO, of a maganese compound at a temperature of 1100.degree.-1350.degree. C. under a condition so that the resulting sintered body has the above porosity.

Abstract: This invention is directed to the formation of homogeneous, aqueous precursor mixtures of at least one substantially soluble metal salt and a substantially soluble, combustible co-reactant compound, typically an amino acid. This produces, upon evaporation, a substantially homogeneous intermediate material having a total solids level which would support combustion. The homogeneous intermediate material essentially comprises highly dispersed or solvated metal constituents and the co-reactant compound. The intermediate material is quite flammable. A metal oxide powder results on ignition of the intermediate product which combusts same to produce the product powder.

Abstract: The invention concerns sol-gel techniques for making PZT-type ceramics having a perovskite-type structure and ferrite ceramics having a spinel-type structure. Colloidal hydrated oxide sols are mixed with metal salt solutions in the required concentration and the mixed sols dehydrated to form homogeneous gels which are fired at 250.degree. C.-650.degree. C., pressed and sintered at 900.degree.-1300.degree. C. The resulting ceramics include PZT4, PZT5 and lithium ferrites. These have excellent homogeneity, small grain size, high density and improved electrical properties, particularly low dielectric loss, compared with known ceramics of similar composition.

Abstract: This invention relates to homogeneous copper-containing oxide superconductors with improved superconducting properties and a process for preparing them.

Abstract: Electrically conductive oxides of the pyrochlore family based on copper and/or silver, lead, bismuth, and ruthenium, characterized by the formula M.sub.x M'.sub.y (Pb,Bi).sub.2-x-y Ru.sub.2 O.sub.7-z, wherein M=copper and/or silver, M'=calcium, strontium, and/or barium, 0.ltoreq.x.ltoreq.0.6, 0.1.ltoreq.y.ltoreq.1.0, and 0.1.ltoreq.z.ltoreq.1.0.

Abstract: Ceramic precursor mixtures containing a metal cation, a carbohydrate, and an anion capable of participating in an anionic oxidation-reduction reaction with the carbohydrate for continuous or batchwise drying and pyrolyzing to provide ceramic powders.

Abstract: This invention provides a process for making metal oxide varistor precursor powder comprising (a) dissolving soluble precursors of the additive metal oxides, e.g. bismuth nitrate as precursor for bismuth oxide, in an aqueous solution, (b) forming a suspension or slurry in the aqueous solution of a powder of the desired primary metal oxide, e.g. zinc oxide, having the desired particle size, (c) adding a precipitating reagent to convert the additive metal from the soluble precursor form to the oxide or hydrous oxide form and precipitate the oxide or hydrous oxide in the presence of the primary metal oxide particles, (d) removing water and by-product salts to form a powder. The resulting varistor precursor powder contains smaller particles of the additive metal oxides evenly distributed throughout larger particles of the primary metal oxide. Varistors prepared from the resulting powder can be sintered at temperatures lower than conventionlly used, for example 900.degree. C.-1000.degree. C.

Abstract: Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. The compounds and structures thus formed are substantially nonsusceptible to variations in their oxygen content when subjected to changing temperatures, thereby forming a temperature-stable substantially single phase crystal.

Abstract: Process for the manufacture of a powder of mixed metal oxides by cohydrolysis of metal alcoholates in the presence of an acidic organic compound and mixed metal oxide powders in which the molar relationships R.sub.1 and R.sub.2 of a metal oxide to the sum of the metal oxides in the powder and in a particle of the powder are such that ##EQU1## The process applies to powders of zirconia doped with yttrium oxide.

Abstract: Process for the manufacture of vitreous metal oxides in which a metal alcoholate derived from an alcohol, the pka of which is less than 15.74, is hydrolysed with an aqueous medium, the pH of which is greater than 1.5. The process is applied especially to the manufacture of vitreous zirconium oxide.

Abstract: A tetragonal system tunnel-structured compound having the formula:A.sub.x [Ga.sub.8 M.sub.y Ga.sub.(8+x)-y Ti.sub.16-x O.sub.56 ](I)wherein A is at least one alkali metal selected from the group consisting of K, Rb and Cs, or a solid solution of such alkali metal with lithium, sodium or barium, M is at least one trivalent metal selected from the group consisting of Al, Fe and Cr, x is a number of from 0.1 to 2.0, and y is a number of from 0 to 10.

Abstract: Ultrafine particles of ceramic or metallic material are obtained at low temperatures from a nitrate source capable of endothermic decomposition by molecularly combining under a nitrogen atmosphere the nitrate source with an inorganic reducing fuel compound, such as hydrazine, to provide a chemical precursor for the ceramic or metallic material and then exothermically decomposing the precursor in a controlled atmosphere by heating to a temperature up to about 200.degree. C. below the endothermic decomposition temperature of the nitrate source. The nitrate source is a metal nitrate or a mixture of nitrate salts. Ferrite particles are recovered when the nitrate source is a mixture of nitrate salts containing ferric nitrate in a 2:1 molar ratio with at least one additional metal nitrate.

Abstract: Disclosed is making an inorganic crystalline vanadium III oxidic compound from a pentavalent vanadium compound, which process comprises (1) reducing a pentavalent vanadium oxidic compound to substantially the V.sup.III state by heating at 100.degree. C. or less an aqueous medium slurry or solution of said pentavalent compound containing a reducing agent selected from hydrazine and hydrocarbylhydrazine, (2) providing in said aqueous medium, either before, during or after said reducing step, other metal cations in solution in the ratio called for by the desired crystalline compound, (3) removing the liquid aqueous medium, and (4) calcining the resulting dry solid at a temperature in the range from 400.degree. to 800.degree. C. in an inert atmosphere.Also disclosed is the vapor phase catalytic dehydrogenation of paraffins using certain spinels and perovskites as catalysts.

Abstract: The process of producing high surface area mixed metal oxides comprising selecting a precursor characterized by the following formula:A.sub.x M.sub.a [M'(CN).sub.c ].sub.b.nH.sub.2 Ox=0-4;a=0-4;b=0.1-4;c=4-8;n=0-30;A=alkali, alkaline earth metal, Al, Si or mixtures;M=rare earth metals, transition metals or mixture thereof; andM'=transition metal capable of forming a cyanide (e.g. Group VIA-VIII A) or mixture thereof,and heating the precursor at a temperature rate of below 1.degree.C/minute in a controlled atmosphere consisting essentially of O.sub.2 and an inert gas to a temperature sufficient to decompose the precursor and produce the mixed metal oxide.

Abstract: A process is disclosed for recovering cobalt from an alloy containing other metals as chromium, tungsten, etc. The process involves first adding the alloy to fused sodium hydroxide at a temperature of from about 750.degree. C. to about 1000.degree. C. to form a reaction mixture, the amount of sodium hydroxide being sufficient to subsequently form sodium salts which are essentially those of chromium and tungsten and hydroxides which are essentially those of cobalt and nickel. The reaction mixture is then heated at a sufficient temperature for a sufficient time while introducing an oxidizing gas into the reaction mixture to form a melt which consists essentially of the sodium salts and the hydroxides, followed by cooling the melt. The cooled melt is then contacted with sufficient water to form a solution containing the major portion of the sodium salts and a solid containing the major portion of the hydroxides, followed by separating the solid from the solution.

Abstract: Iron oxide-chromium oxide catalyst of increased mechanical strength (lateral crushing strength) for high-temperature water-gas shift reaction. The catalyst contains as an additional component magnesium oxide and/or magnesium spinels in the form of discrete particles.

Abstract: A process for preparing a mixed metal oxide, usable as the cathode or intercalation electrode in high energy density primary and secondary batteries, having the formula Li.sub.x M.sub.y O.sub.z where M is at least one metal selected from the group consisting of titanium, chromium, manganese, iron, cobalt and nickel, x is a number from about 0.1 to about 1.1, preferably from about 0.9 to about 1.1, y is a total number from about 1.1 to about 0.1, preferably from about 1.1 to about 0.9, respectively, and z is a number from about 1.9 to about 2.1, such as LiCoO.sub.2 or [Li(Co.sub.0.5 Ni.sub.0.5) O.sub.

Abstract: An inorganic composition adapted for use in bonding a high temperature resistant polymeric material to an aluminum base substrate is provided. The composition is obtained by reacting a first inorganic compound containing chromium and oxygen with a second inorganic compound containing at least one element selected from the group consisting essentially of calcium, barium and strontium to form a reaction product containing chromium, oxygen and at least one element selected from the group essentially consisting of calcium, barium and strontium. A method of bonding a high temperature resistant polymeric material to an aluminum base substrate using the above composition is also provided.

Abstract: A new compound consisting essentially of strontium, iron, boron and oxygen is termed strontium ferrite borate or corabelleite. A fluxed melt for the growth of single crystals and a method for growing single crystals of the corabelleite are disclosed.

Abstract: A new compound consisting essentially of strontium, iron, boron and oxygen is termed strontium ferrite borate or corabelleite. A method for preparing polycrystalline ceramic corabelleite is disclosed.

Abstract: Compositions conforming to the formula A.sub.x.sup.++ B.sub.y.sup.+++ (OH).sub.2x+3y-nz D.sub.z.sup.n-.tH.sub.2 O wherein A is a divalent metal, B is a trivalent metal, D is a polyanion, x, y, z and t are numbers greater than zero and n is a whole number preferably from 1 to 10 and the ratio of x:y is equal to or greater than 0.5 and less than or equal to 10 and a method for preparing said compositions are described.

Abstract: With the fabrication of a substrate material in the form of alkaline-earth gallate single crystals it has become possible to grow monocrystalline barium hexaferrite layers of high quality. These thin barium hexaferrite layers on the alkaline-earth gallate substrates are extremely suited as magnetic devices because of their very high uniaxial anisotropy and their small line width. Such magnetic devices can be used for passive microwave components, e.g. as resonance isolators or filters in the centimeter wavelength range or as components in information storage technology, e.g. in magnetic cylindrical domain devices, especially in the field of very small (submicron) cylindrical domains.