Aluminum Patents (Class 423/625)
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Patent number: 6302926Abstract: The invention relates to preparations of monodisperse spherical oxide particles in the form of free-flowing powders of agglomerates in which the particles are bonded to one another by a binder. With these preparations, the oxide particles can be homogeneously dispersed in polymer systems with particular ease.Type: GrantFiled: June 7, 1995Date of Patent: October 16, 2001Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Ralf Anselmann, Carsten Griessmann, Manuela Loch, Kurt Marquard
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Publication number: 20010029229Abstract: The present invention concerns a moulded microcrystalline spherical Al2O3- sintered body, process for its production as well as its use.Type: ApplicationFiled: November 23, 1998Publication date: October 11, 2001Inventors: PAUL MOELTGEN, PIRMIN WILHELM, MARTIN LUETTE
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Publication number: 20010023271Abstract: Aluminum hydroxide having specific characteristics, and a tire tread rubber composition and a pneumatic tire employing the aluminum hydroxide, which allow grip performance and abrasion resistance to increase and rolling resistance to decrease and are superior in processibility, are provided.Type: ApplicationFiled: December 27, 2000Publication date: September 20, 2001Inventors: Naohiko Kikuchi, Takeshi Ota, Satoru Nippa, Mamoru Uchida
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Patent number: 6284694Abstract: The present invention concerns a moulded microcrystalline spherical Al2O3- sintered body, process for its production as well as use.Type: GrantFiled: November 23, 1998Date of Patent: September 4, 2001Assignee: Korund Laufenburg GmbHInventors: Paul Moeltgen, Pirmin Wilhelm, Martin Luette
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Patent number: 6281277Abstract: The present invention provides homogeneously surface-fluorinated metal oxide particulates, characterized in that a metal oxide particulate such as Ti, Al, Si, Ag, Cu, Fe, Zr, Ce, Mn, Sn, Ge and Ta is surface reacted with fluorine gas while allowing the metal oxide particulate to flow, and also provides a process for manufacturing the metal oxide particulates. The homogeneously surface-fluorinated metal oxide particulates according to the present invention are useful as an additive for a weatherproof coating material, a weatherproof resin or a cosmetic material. Furthermore, according to the process of the present invention, the surface of a metal oxide particulate can be homogeneously fluorinated at any ratio in a very simple and efficient manner.Type: GrantFiled: April 22, 1999Date of Patent: August 28, 2001Assignee: Showa Denko Kabushiki KaishaInventors: Nobuaki Ishii, Koichi Wada, Kazuo Sekiguchi, Hiroyuki Takahashi
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Patent number: 6274110Abstract: The present invention relates to complex oxides used as raw materials for fine ceramic materials, and more particularly to complex oxide precursors in the form of a fine powder which are readily converted to complex oxides with low energy and also a process for preparing the same.Type: GrantFiled: March 11, 1997Date of Patent: August 14, 2001Inventors: Yeun Shik Kim, Geon Bae Kim, Min Young Jo
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Patent number: 6254940Abstract: The present invention related to methods of manufacturing oxide, nitride, carbide, and boride powders and other ceramic, organic, metallic, carbon and alloy powders and films and their mixtures having well-controlled size and crystallinity characteristics. This invention relates, more particularly, to a development in the synthesis of the ceramic, metallic, composite, carbon and alloy nanometer-sized particles with precisely controlled specific surface area, or primary particle size, crystallinity and composition. The product made using the process of the present invention and the use of that product are also claimed herein.Type: GrantFiled: May 26, 1999Date of Patent: July 3, 2001Assignee: University of CincinnatiInventors: Sotiris E. Pratsinis, Srinivas Vemury
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Patent number: 6238701Abstract: An alumina solid, obtainable by a process comprising the step of contacting in a liquid medium at least one alumina precursor with at least one template comprising a dendrimeric molecular nanosystem a mixture of two or more thereof.Type: GrantFiled: July 13, 1998Date of Patent: May 29, 2001Assignee: BASF AktiengesellschaftInventors: Ulrich Müller, Wolfgang Paulus, Lukas Häussling
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Patent number: 6224846Abstract: A process for making a modified boehmite alumina comprising reacting at elevated temperatures a boehmite alumina with a compound having the formula: X(SO3M)n wherein X is an organic moiety, M in a monovalent cation, and n is an integer reflecting the number of SO3M groups bonded to said organic moiety to produce a reaction mixture containing modified boehmite alumina and recovering solid, modified boehmite alumina from the reaction mixture.Type: GrantFiled: August 21, 1999Date of Patent: May 1, 2001Assignee: Condea Vista CompanyInventors: Paul K. Hurlburt, Daniel T. Plummer
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Patent number: 6218335Abstract: A porous spinel type oxide shows a large surface area and a uniform micro-porous structure. The oxide is expressed by general formula MO—Al2O3 and shows a surface area per unit weight of not less than 80 m2/g. Such a porous spinel type compound oxide is obtained by impregnating a specific &ggr;-alumina carrier with a solution of a compound of metal element M capable of taking a valence of 2, drying the impregnated carrier and calcining it at a temperature of 600° C. or higher. The specific &ggr;-alumina carrier shows a surface area per unit weight of not less than 150 m2/g, a micro-pore volume per unit weight of not less than 0.55 cm3/g and an average micro-pore diameter between 90 and 200 angstroms. The micro-pores with a diameter between 90 and 200 angstroms occupy not less than 60% of the total micro-pore volume of the carrier.Type: GrantFiled: July 23, 1999Date of Patent: April 17, 2001Assignee: Chiyoda CorporationInventors: Yoshimi Okada, Kenichi Imagawa, Susumu Yamamoto
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Patent number: 6207611Abstract: A catalyst for hydrodemetalization of heavy oil, especially residuum oil, and a process for preparing the same, wherein said catalyst comprises the metal elements of Groups VIII and/or VIB as active components supported on an alumina carrier having large pores. The total pore volume of said carrier is in the range of 0.80˜1.20 ml/g (by mercury porosimetry method), the specific surface area in the range of 110˜200 m2/g, the peak pore diameter in the range of 15˜20 nm, and the bulk density in the range of 0.50˜0.60 g/ml. In the process of the invention, a physical pore-enlarging agent and a chemical pore-enlarging agent are added simultaneously during the mixing of the pseudoboehmite to a plastic mass, then extruding, drying, calcining, the carrier is obtained, then impregnating with active components by spraying onto the carrier, after drying and calcining, the catalyst is obtained.Type: GrantFiled: July 22, 1998Date of Patent: March 27, 2001Assignees: China Petro-Chemical Corporation, Fushun Research Institute of Petroleum and Petrochemicals, SINOPECInventors: Suhua Sun, Weiping Fang, Jiahuan Wang, Guolin Wu, Jianan Sun, Gang Wang, Zemin Fu, Hao Zhang, Yonglin Wang
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Patent number: 6203768Abstract: A new, cost effective process for the production of ultrafine particles which is based on mechanically activated chemical reaction of a metal compound with a suitable reagent. The process involves subjecting a mixture of a metal compound and a suitable reagent to mechanical activation to increase the chemical reactivity of the reactants and/or reaction kinetics such that a chemical reaction can occur which produces a solid nano-phase substance. Concomitantly, a by-product phase is also formed. This by-product phase is removed so that the solid nano-phase substance is left behind in the form of ultrafine particles. During mechanical activation a composite structure is formed which consists of an intimate mixture of nano-sized grains of the nano-phase substance and the reaction by-product phase.Type: GrantFiled: October 5, 1998Date of Patent: March 20, 2001Assignee: Advanced Nano Technologies Pty LtdInventors: Paul Gerard McCormick, Jun Ding, Wie-Fang Miao, Robert Street
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Patent number: 6200680Abstract: A process for producing zinc oxide fine particles comprising heating a mixture comprising a zinc source, a carboxyl-containing compound, and an alcohol; a process for producing zinc oxide-polymer composite particles, which comprises heating a mixture comprising a zinc source, a carboxyl-containing compound, a polymer, and an alcohol at a temperature of 100° C. or higher; a process for producing inorganic compound particles having on their surface a cluster of thin plate like zinc oxide crystals with their tip projecting outward, which comprises heating a mixture comprising a zinc source, a carboxyl-containing compound, lactic acid or a compound thereof, and an alcohol at a temperature of 100° C.Type: GrantFiled: April 3, 1997Date of Patent: March 13, 2001Assignee: Nippon Shokubai Co., Ltd.Inventors: Mitsuo Takeda, Tatsuhito Matsuda
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Patent number: 6197276Abstract: Hydrated aluminium compounds of the present invention are represented by the general formula nS, mM, Al2O3, xH2O where S is a surfactant or a group of surfactants, n is the number of moles of S, M is an alkaline cation, preferably selected from the group formed by Na+, K+, NH4+, m is the number of moles of M and x is the number of moles of water. The hydrated compounds are obtained from inorganic aluminium sources which are in the form of cation-monomers and/or cation-oligomers. The surfactants are anionic and/or non-ionic surfactants. When the group of surfactants comprises at least one anionic surfactant, at least one cationic surfactant can optionally be added.Type: GrantFiled: February 12, 1999Date of Patent: March 6, 2001Assignee: Institut Francais du PetroleInventors: Frédéric Kolenda, Jean-Louis Guth, Sabine Valange, Zelimir Gabelica, Eric Benazzi
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Patent number: 6197277Abstract: Alumina particles having high dispersibility and plasticity, at least on the surface of which a phosphoric acid or phosphate is present and suitable for use as a material for pigments for paints, precision abrasives or ceramics. The alumina particles are produced by adding a crystallization inhibitor containing at least phosphate ion to aluminum hydroxide or alumina hydrate and then conducting a hydrothermal synthesis treatment. The amount of the phosphate ion to be added is in the range of 3.0×10−3 to 2.5×10−2 mol per mol of aluminum hydroxide or alumina hydrate. The particle size of aluminum hydroxide or alumina hydrate is 0.1 to 5.0 &mgr;m. The hydrothermal synthesis is preferably conducted at 350° C. or above under a pressure of 50 to 200 atm and at a temperature elevation rate of 5° C./min to 0.3° C./min. The thus obtained alumina is &agr;-alumina in the form of hexagonal plate single crystal having a particle size of 0.Type: GrantFiled: May 4, 1999Date of Patent: March 6, 2001Assignee: YKK CorporationInventors: Takeshi Fukuda, Ryuichi Shido
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Patent number: 6194489Abstract: The present invention provides a resin additive obtained by subjecting inorganic particles of silica or alumina to surface treatment with tannic acid and further subjecting them to surface treatment with a coupling agent, or subjecting inorganic particles to surface treatment with tannic acid and then subjecting them to surface treatment with a phenone compound or saccharides, followed by further subjecting them to surface treatment with a coupling agent. The above resin additive has an effect to provide a thermoplastic resin with heat stability in heating and melting the resin and prevent a reduction in the IZOT impact strength.Type: GrantFiled: August 18, 1999Date of Patent: February 27, 2001Assignee: Tohoku Munekata Co LtdInventors: Susumu Nikkeshi, Maki Kanno
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Patent number: 6183719Abstract: An alumina solid is obtainable by a process comprising the step of contacting in a liquid medium at least one alumina precursor with at least one template comprising a membrane lipid or a mixture of two or more thereof.Type: GrantFiled: February 8, 1999Date of Patent: February 6, 2001Assignee: BASF AktiengesellschaftInventors: Ulrich Müller, Roger Ruetz
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Patent number: 6171573Abstract: An alumina sol, containing a small amount of water of crystallization inside the crystal lattice of boehmite, having high mechanical strength, properties suitable for use as an alumina adsorbent or carrier, and the ability to be formed without additional concentration. The alumina sol comprises a fibrous boehmite having the molecular formula Al2O3.1.05-1.30 H2O with the weight average diameter and the weight average length being respectively in the range of 3 to 50 nm and in the range of 30 to 3000 nm, and has an alumina concentration of 15 to 60% by weight.Type: GrantFiled: September 4, 1998Date of Patent: January 9, 2001Inventor: Goro Sato
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Patent number: 6165437Abstract: .alpha.-Alumina comprising .alpha.-alumina single crystal particles which are homogeneous containing no crystal seed inside the particles; have an octa- or higher polyhedral shape; have a D/H ratio of from 0.5 to 3.0, wherein D represents a maximum particle diameter parallel to a hexagonal lattice plane of a hexagonal close-packed lattice of the particles, and H represents a diameter perpendicular to the hexagonal lattice plane; have a number average particle diameter of more than 5 .mu.m and not more than 30 .mu.m; have a sodium content of less than 5 ppm in terms of Na.sub.2 O; and have an alumina purity of not less than 99.90% by weight. .alpha.-Alumina in a powder form composed of .alpha.-alumina single crystal particles having a high punity, a fine and uniform composition, a narrow particle size distribution, and an octa- or higher polyhedral shape which are not aggromerates. The .alpha.Type: GrantFiled: February 24, 1997Date of Patent: December 26, 2000Assignee: Sumitomo Chemical Co., Ltd.Inventors: Masahide Mohri, Yoshio Uchida, Yoshinari Sawabe, Hisashi Watanabe
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Patent number: 6162413Abstract: A powdery .alpha.-alumina having an alumina purity of at least 99.8 wt. %, a sodium content of 40 ppm or less and an iron content of 20 ppm or less, which is obtained by grinding aluminum hydroxide which is produced by the Bayer process or a transition alumina which is obtained by precalcining aluminum hydroxide produced by the Bayer process, and calcining the aluminum hydroxide or transition alumina in an atmosphere containing 1 vol. % or more of a hydrogen chloride gas, or an atmosphere containing 1 vol. % or more of a chlorine gas and 0.1 vol. % or more of steam, at a temperature of 600 to 1400.degree. C.Type: GrantFiled: September 8, 1997Date of Patent: December 19, 2000Assignee: Sumitomo Chemical Company, LimitedInventors: Shinji Fujiwara, Hiroshi Tabuchi, Masahide Mohri
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Patent number: 6159441Abstract: A process for producing .alpha.-alumina powder comprising the step of calcining at least one of transition alumina and a transition alumina precursor capable of becoming transition alumina on heating, in a gas atmosphere containing (1) a hydrogen halide, (2) a component prepared from a halogen and steam or (3) a halogen, in the presence of at least one of a seed crystal and a shape-controlling agent. The .alpha.-alumina powder is particularly useful as a raw material for abrasives, fillers, sinters or spacers which comprises .alpha.-alumina particles having a substantially octahedral or eicosahedral shape, a specific structure, and a narrow primary particle size distribution.Type: GrantFiled: April 6, 1999Date of Patent: December 12, 2000Assignee: Sumitomo Chemical Company, LimitedInventors: Masahide Mohri, Yoshio Uchida, Yoshinari Sawabe, Hisashi Watanabe
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Patent number: 6153157Abstract: A process which allows the conversion of clay minerals of the kalonite group, to a relatively pure form of alumina and silica respectively comprising the steps of (a) heating the kaolinite group minerals to greater than 500.degree. C., which causes dehydroxylation of the crystallographic lattice and formation of an intermediate meta-kaolin; (b) reacting the intermediate with only one of a selection of reagents including acids, alkalines or metalliferous compounds followed by heating of the mixture to form an aluminium salt in solution and residue of silica; (c) separation of the aluminium salt solution from the residue of silica by filtration and further treatment of the silica residue to produce a relatively pure form of fine particled silica; (d) formation of an alum by addition of ammonium sulphate in solution to the aluminium salt solution and further treatment of the alum to produce a relatively pure form of aluminium hydroxide.Type: GrantFiled: December 31, 1998Date of Patent: November 28, 2000Assignee: McLaughlin Geosurveys Pty. LimitedInventor: Robert Joseph McLaughlin
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Patent number: 6143816Abstract: A fire-retardant plastic mixture contains 55%-75% by weight of boehmite which has an orthorhombic crystal structure and has the general formula AlO.sub.x (OH).sub.3-2x with x-values ranging between 0.8 and 0.99, and has a mean grain diameter d.sub.50 ranging between 0.4 and 0.7 .mu.m, a d.sub.10 value ranging between 0.7 and 1.2 .mu.m and a d.sub.90 value ranging between 0.2 and 0.4 .mu.m. The filler material is used in the form of a finely-crystallized hydrargillite which is obtained during a precipitation process according to Bayer with a grain diameter of 0.5 to 3 .mu.m, which is suspended and which, without any mechanical working, is transformed directly in a hydro-thermal process at temperatures ranging between 220.degree. C. and 240.degree. C. under turbulent conditions into a boehmite of the general formula AlO.sub.x (OH).sub.3-2x with x-values ranging between 0.8 and 0.99.Type: GrantFiled: March 19, 1999Date of Patent: November 7, 2000Assignee: Nabaltec-Nabwerk Aluminiumhydroxid Technologie GmbHInventors: Klaus-Dieter Prescher, Johann Trettenbach, Josef Fischer, Stefan Ross, Josef Brandl
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Patent number: 6136288Abstract: Fine powders of ceramic materials can be obtained by firing a precursor powder in a rotary kiln while carried on coarse carrier particles.Type: GrantFiled: December 16, 1993Date of Patent: October 24, 2000Assignee: Norton CompanyInventors: Ralph Bauer, Thomas Edward Cottringer, Martin Bradley Barnes
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Patent number: 6129904Abstract: An aluminum oxide mass characterized by a specific surface area greater than or equal to 70 m.sup.2 /g and a narrow pore radius distribution, with at least 90% of the pore radii being approximately 0.5 to 2.5 nm, preferably approximately 1.7 to 2.2 nm.Type: GrantFiled: March 16, 1999Date of Patent: October 10, 2000Assignee: Sud-Chemie A.G.Inventors: Norbert Von Thienen, Hansjorg Sinn
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Patent number: 6123912Abstract: A process for producing an alumina material with high strength is disclosed. The process for producing an alumina material includes the steps of (a) providing a solution containing a dispersing agent, (b) mixing a .theta.-alumina powder and an .alpha.-alumina powder with the solution to form a slurry, (c) filtering the slurry to form a green part, (d) drying the green part, and (e) densifying the dried green part to form the alumina material.Type: GrantFiled: January 19, 1999Date of Patent: September 26, 2000Assignee: National Science CouncilInventors: Wen-Cheng J. Wei, Shui-jin Cheng, Chang-Li Hsieh, Hung-Chan Kao
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Patent number: 6117572Abstract: Compounds of the general formula Ca.sub.2 MeSbO.sub.6 where Me is a 3+ ion selected from the group consisting of aluminum (Al), scandium (Sc), indium (In), gallium (Ga), or a rare earth metal have been prepared and included as the substrate or barrier dielectric in high critical temperature thin film superconductors, ferroelectrics, pyroelectrics, piezoelectrics, and hybrid device structures.Type: GrantFiled: November 25, 1997Date of Patent: September 12, 2000Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Steven C. Tidrow, Arthur Tauber, William D. Wilber, Robert D. Finnegan
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Patent number: 6113873Abstract: To hydrous titanium dioxide obtained by hydrolysis of titanium sulfate was added a predetermined amount of a water-soluble aluminum compound and/or a water-soluble zinc compound, the mixture is calcined, and a suitable amount of aluminum and/or zinc is introduced into the crystals to make up the crystal defects of anatase-type titanium dioxide, so that it has increased stability and excellent color stability.Type: GrantFiled: July 29, 1998Date of Patent: September 5, 2000Assignee: Sakai Chemical Industry Co., Ltd.Inventors: Makoto Tunashima, Kazuyoshi Muraoka, Kohji Yamamoto, Masaru Mikami, Suzuo Sasaki
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Patent number: 6106800Abstract: Alpha alumina powder is produced by granulating at least one alumina starting material selected from group consisting of transition alumina and alumina compound to obtain particles and calcining the particles in a halogen-containing atmosphere which comprises a hydrogen halide gas, a halogen gas or a mixture of a halogen gas and steam and contains at least 0.1 % by volume of at least one halogen-containing gas selected from the group consisting of hydrogen halide gas and halogen gas.By granulating the alumina starting material powder in the form of particles to increase a bulk density and calcining them in the presence of halogen, .alpha.-alumina powder having a regulated particle size and shape and a narrow particle size distribution and containing fewer agglomerated particles is produced at a high calcining efficiency.Type: GrantFiled: June 23, 1997Date of Patent: August 22, 2000Assignee: Sumitomo Chemical Co., Ltd.Inventors: Masahide Mohri, Norio Matsuda, Shinichiro Tanaka, Yoshio Uchida, Yoshinari Sawabe, Hisashi Watanabe, Hiroshi Ogawa
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Patent number: 6103660Abstract: A method of depositing catalytically active components on high-surface carrier materials is disclosed by dispersing the carrier materials in water and mixing this dispersion with an aqueous solution of soluble precursors of the catalytically active components. The pH of the dispersion is adjusted to a value between 6 and 8 before the aqueous solution of the precursors is supplied by capillary injection under constant agitation of the dispersion and thereafter, if necessary, the precursors of the catalytically active components are precipitated on the carrier material by capillary injection of a dilute base.Type: GrantFiled: April 7, 1998Date of Patent: August 15, 2000Assignee: Degussa Huls AktiengesellschaftInventors: Renee Van Yperen, Dieter Lindner, Lothar Mussmann, Egbert Lox, Thomas Kreuzer
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Patent number: 6083622Abstract: Sol-gel alumina that is dried but unfired can be explosively comminuted by feeding the dried gel into a furnace held at temperatures above those at which vaporizable materials are eliminated from the particles of gel. At suitably elevated temperatures the firing is sufficient to form fully densified alpha alumina particles of a size suitable for direct use as abrasive grits.Type: GrantFiled: October 31, 1997Date of Patent: July 4, 2000Assignee: Saint-Gobain Industrial Ceramics, Inc.Inventors: Ajay K. Garg, Arup K. Khaund, Lawrence E. Orne, Mark R. Young
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Patent number: 6080380Abstract: The present invention provides a process for producing fine flaky alumina particles which are suitable as a raw material for ceramics, a pigment for paint, etc., wherein aluminum hydroxide or alumina hydrate having a particle size regulated to the order of submicron is subjected to a hydrothermal treatment in water or an aqueous alkali solution at a temperature of 350.degree. C. or above and under a pressure of 200 kg/cm.sup.2 or below. The present invention further provides an alumina-based plastic material which is produced by kneading the aforesaid fine flaky particles with an organic water holding material and water. Methylcellulose, polyvinyl alcohol, carboxymethylcellulose, polyethylene glycol, etc. are preferably used as the organic water holding agent. The alumina-based plastic material has a high plasticity, so that there is no need of using a large amount of a binder. Thus a dense molded article having stable properties can be prepared.Type: GrantFiled: September 7, 1994Date of Patent: June 27, 2000Assignees: Agency of Industrial Science and Technology, Ministry of International Trade and Industry, YKK CorporationInventors: Yasuo Shibasaki, Kiichi Oda, Takeshi Fukuda
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Patent number: 6066305Abstract: This invention relates to a generic process for producing a refractory oxide which comprises reacting liquid water with: at least one metal fluoride reactant; or at least one metal fluoride reactant and at least one metal oxide reactant; or at least one metal oxide reactant and an aqueous hydrogen fluoride solution, to produce either a colloidal mixture or a solution; drying either the colloidal mixture or solution; heating the dried product to produce a solid state metal hydroxyfluoride; heating the hydroxyfluoride to a temperature at which it chemically decomposes into a cationically-homogeneous and nanostructured solid state metal oxyfluoride; and performing one of the following heating steps: (i) to a solid state decomposition-temperature where the oxyfluoride chemically decomposes into a refractory oxide; or, (ii) to a molten state decomposition-temperature where the oxyfluoride chemically decomposes into a refractory oxide; or, (iii) to a vapor state decomposition-temperature where the oxyfluoride chemiType: GrantFiled: December 15, 1997Date of Patent: May 23, 2000Inventor: Cortland Otis Dugger
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Patent number: 6063358Abstract: A process for producing alumina and other aluminia products where the formation of a Schiff base imine by reaction of a orgaonaluminum amide or imide oligomer with a carbonyl compound is promoted by the Lewis acid character of the oligomer. The water byproduct of the Schiff base serves as an in situ reagent for subsequent hydrolysis and sol-gel condensation of the aluminum species with concomitant production of alkane. The imine then is washed from the alumina with a suitable solvent. Any of a number of primary amines and aldehydes or ketones may be reagents. Calcining of the sol-gels yields high surface area alumina as characterized by scanning electron microscopy, and gas physisorption measurements. Microporous and/or mesoporous alumina is obtained depending on synthesis conditions. Alumina microspheres are obtained under certain conditions.Type: GrantFiled: April 3, 1998Date of Patent: May 16, 2000Assignee: Board of Trustees of the University of ArkansasInventors: David A. Lindquist, Sterling S. Rooke
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Patent number: 6051741Abstract: A process for preparing .gamma.,.delta.-unsaturated ketones of the general formula I ##STR1## by reacting an allyl alcohol of the general formula II ##STR2## in which R.sup.1 is H or a hydrocarbon radical having 1 to 20 carbon atoms, with diketene or an alkyl acetoacetate of the general formula III ##STR3## in which R.sup.2 is alkyl having 1 to 4 carbon atoms in an unmodified or modified Carroll reaction in the presence of an aluminum catalyst, wherein aluminum compounds which are stable liquids at room temperature, or a mixture of such aluminum compounds, which comprise at least one radical formed from an alkyl acetoacetate and 1 or 2 alkoxy radicals, or else comprise exclusively radicals formed from alkyl acetoacetates, which are esterified with sec-butanol or isobutanol, or else are esterified with at least two different alcohols, are used as aluminum catalyst.Type: GrantFiled: October 8, 1998Date of Patent: April 18, 2000Assignee: BASF AktiengesellschaftInventors: Heinz Etzrodt, Dietmar Weller, Carsten Oost, Hagen Jaedicke, Manfred Stroezel, Bernhard Bockstiegel, Lothar Laupichler, Klaus Reimer
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Patent number: 6043187Abstract: The present invention relates to a catalyst comprising an extruded essentially alumina-based support, constituted by a plurality of juxtaposed agglomerates and partially in the form of packs of flakes and partially in the form of needles, and optionally comprising at least one catalytic metal or a compound of a catalytic metal from group VIB, and/or optionally at least one catalytic metal or compound of a catalytic metal from group VIII. The invention also relates to its use in a fixed bed reactor, for hydrorefining and hydroconverting hydrocarbon feeds.Type: GrantFiled: June 10, 1998Date of Patent: March 28, 2000Assignee: Institut Francais du PetroleInventors: Virginie Harle, Slavik Kazstelan, Frederic Morel, Stephane Kressmann, Philippe Courty
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Patent number: 6036930Abstract: The present invention provides a process for producing aluminum oxide fibers and, particularly, a process for producing aluminum fibers that have a high aspect ratio and can be accurately aligned, said process for producing aluminum oxide fibers comprising the steps of: uniformly mixing an aluminum or aluminum alloy powder with a boron oxide powder or a powder which, upon heating, can be converted to a boron oxide powder; and heating the mixed powder, or comprising the steps of: mixing not more than 50% by weight, in terms of titanium, of a titanium or titanium alloy powder to the starting mixture; and heating the mixed powder.Type: GrantFiled: September 17, 1998Date of Patent: March 14, 2000Assignee: Toyota Jidosha Kabushiki KaishaInventors: Yoshitomo Shintani, Yukio Okochi
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Patent number: 6027706Abstract: Semi-crystalline alumina compositions with framework mesopores are disclosed. The compositions are assembled from inorganic aluminum precursors and nonionic polyethylene oxide surfactants. The new assembly pathway introduces several new concepts to alumina mesostructure synthesis. The application of low-cost, non-toxic and biodegradable surfactants and low cost aluminum reagents as alumina precursors which are inorganic and low solution reaction temperatures, introduces efficient and environmentally clean synthetic techniques to the formation of mesostructures. Recovery of the surfactant can be achieved through solvent extraction where the solvent may be water or ethanol or by calcination.Type: GrantFiled: May 5, 1998Date of Patent: February 22, 2000Assignee: Board of Trustees operating Michigan State UniversityInventors: Thomas J. Pinnavaia, Wenzhong Zhang
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Patent number: 6015539Abstract: A process is disclosed for preparing anhydrous alumina from aluminum hydroxide which comprises feeding aluminum hydroxide into a first suspension preheater and partially dehydrating the aluminum hydroxide with a hot exhaust gas, transporting the partially dehydrated aluminum hydroxide with said exhaust gas to a first separating means and separately withdrawing the exhaust gas and the partially dehydrated aluminum hydroxide, and dividing the partially dehydrated aluminum hydroxide into a first and second partial stream of solids. The process uses a circulating fluidized bed comprising a fluidized bed reactor, a recycle separator connected to the upper portion of said fluidized bed reactor, and a return line for leading solids from said recycle separator to the lower portion of said fluidized bed reactor. The second partial stream of solids is fed into a second suspension preheater and contacted with hot exhaust gas from the recycle separator.Type: GrantFiled: September 3, 1998Date of Patent: January 18, 2000Assignee: Metallgesellschaft AktiengesellschaftInventors: Hans Werner Schmidt, Martin Rahn, Werner Stockhausen, Dietrich Werner, Martin Hirsch
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Patent number: 6015456Abstract: Alumina particles having high dispersibility and plasticity, at least on the surface of which a phosphoric acid or phosphate is present and suitable for use as a material for pigments for paints, precision abrasives or ceramics. The alumina particles are produced by adding a crystallization inhibitor containing at least phosphate ion to aluminum hydroxide or alumina hydrate and then conducting a hydrothermal synthesis treatment. The amount of the phosphate ion to be added is in the range of 3.0.times.10.sup.-3 to 2.5.times.10.sup.-2 mol per mol of aluminum hydroxide or alumina hydrate. The particle size of aluminum hydroxide or alumina hydrate is 0.1 to 5.0 .mu.m. The hydrothermal synthesis is preferably conducted at 350.degree. C. or above under a pressure of 50 to 200 atm and at a temperature elevation rate of 50.degree. C./min to 0.3.degree. C./min. The thus obtained alumina is .alpha.-alumina in the form of hexagonal plate single crystal having a particle size of 0.2 to 15 .mu.Type: GrantFiled: August 23, 1996Date of Patent: January 18, 2000Assignee: YKK CorporationInventors: Takeshi Fukuda, Ryuichi Shido
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Patent number: 6004525Abstract: The present invention provides a hollow oxide particle including a shell wall constituting a hollow room, and the shell wall has a thickness of 20 nm or less. The shell wall may be mainly composed from at least one selected from the group consisting of alumina, spinel, iron oxides, yttrium oxides, and titanium oxides. A process for producing the hollow oxide particle comprises the steps of: forming a Water in Oil (W/O) type emulsion including aqueous microspheres having a each diameter of 100 nm or more, by adding an organic solvent to an aqueous solution dissolving and/or suspending at least one of metal salts and metal compounds; and forming the hollow oxide particle by atomizing the Water in Oil (W/O) type emulsion to burn. When the hollow oxide particle is brought into contact with a water-containing solution, a surface of the shell wall may have a minutely irregular surface.Type: GrantFiled: October 5, 1998Date of Patent: December 21, 1999Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Takao Tani, Kazumasa Takatori, Nobuo Kamiya
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Patent number: 5989515Abstract: A process for producing a stable acidic aqueous alumina sol containing 50 to 300 nm of elongate secondary particles which are elongated in only one plane and formed by edge-to-edge coagulation of rectangular plate-like primary particles having a length of one side of 10 to 30 nm when observed through an electron microscope, the process comprises the steps of:(A) adding an alkali to an aqueous alumina sol containing fibrous colloidal particles of an amorphous alumina hydrate to produce a reaction mixture having a pH of 9 to 12,(B) subjecting the reaction mixture obtained in the step (A) to a hydrothermal treatment at a temperature of 110 to 250.degree. C. to produce an aqueous suspension containing an alumina hydrate having a boehmite structure, and(C) desalting the aqueous suspension obtained in the step (B) by adding water and an acid by ultrafiltration to form an acidic aqueous alumina sol having a pH of 3 to 6.Type: GrantFiled: July 18, 1997Date of Patent: November 23, 1999Assignee: Nissan Chemical Industries, Ltd.Inventors: Yoshitane Watanabe, Yoshiyuki Kashima, Kiyomi Ema
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Patent number: 5972820Abstract: Methods of making substantially phase-pure and thermally stable crystalline alumina compositions stabilized with an oxide of silicon, germanium, phosphorus, arsenic or a mixture thereof. Also provided are crystalline alumina compositions and catalyst supports made using these methods.Type: GrantFiled: January 19, 1999Date of Patent: October 26, 1999Assignee: ASEC Manufacturing, a General PartnershipInventors: Karl C. C. Kharas, Roy T. Mitsche, Heinz J. Robota, Michael G. Gatter
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Patent number: 5964936Abstract: The invention concerns oxidised aluminium or aluminium alloy pigments having a content of metallic aluminium of not more than 90% by weight with respect to the total weight, wherein the pigments are colored, flake-like, shiny and non-agglomerated, a process for the production thereof and use thereof as special-effect pigments and as base pigments for further colouring with organic or inorganic color pigments.Type: GrantFiled: February 2, 1998Date of Patent: October 12, 1999Assignee: Eckart-Werke Standard Bronzepulver-Werke Carl Eckart GmbH & Co.Inventor: Wolfgang Reisser
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Patent number: 5958361Abstract: Ultrafine metal oxide and mixed metal oxide ceramic particles are prepared by flame spray pyrolysis of a ceramic precursor solution containing one or more gycolato polymetallooxanes dissolved in a volatile organic solvent. Recycle of the nanosized particles disposed in additional ceramic precursor solution leads to larger particles. The metal oxide and mixed metal oxide particles may be converted to the respective nitrides by high temperature ammonolysis. The process produces high quality ceramic particles from inexpensive and relatively non-toxic reagents in high space-time yield.Type: GrantFiled: November 22, 1995Date of Patent: September 28, 1999Assignee: Regents of the University of MichiganInventors: Richard M. Laine, Clint R. Bickmore, David R. Treadwell, Kurt F. Waldner
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Patent number: 5948379Abstract: An apparatus for producing solid fine particulates has a substantially closed reaction vessel and a hollow gas input conduit inside the vessel formed with a multiplicity of similar outlet apertures each having a flow cross section of at most 2 mm.sup.2. The conduit has an overall cross-sectional area equal to at least 100 times the flow cross section of a one of the apertures. A foraminous structure in the vessel surrounds the conduit and an electrode is provided in the vessel outside the foraminous structure. A direct-current power supply has a negative side connected to the foraminous structure and a positive side connected to the electrode while the input conduit is at ground potential so that a glow discharge is created in the vessel between the foraminous structure and the electrode.Type: GrantFiled: August 28, 1995Date of Patent: September 7, 1999Inventors: Udo Konig, Ralf Tabersky
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Patent number: 5946818Abstract: A method and apparatus are disclosed for continuously drying, preferably with agglomeration and/or coating and sizing, and separating a solid product from a liquid feed material, especially bauxite slurry which passes through a very sticky phase during drying, without significant encrustation of the equipment used.Type: GrantFiled: September 23, 1996Date of Patent: September 7, 1999Assignee: Alcan International LimitedInventors: Hamish Baxter, Andrew Nicolson Carruthers, Hans-Peter Elkjaer, Bryan Hiscox, Jens Fenger, Benny E. Raahauge, Jose Gil Fernandez Pulpeiro
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Patent number: 5935550Abstract: A process for producing .alpha.-alumina powder comprising the step of calcining at least one of transition alumina and a transition alumina precursor capable of becoming transition alumina on heating, in a gas atmosphere containing (1) a hydrogen halide, (2) a component prepared from a halogen and steam or (3) a halogen, in the presence of at least one of a seed crystal and a shape-controlling agent. The .alpha.-alumina powder is particularly useful as a raw material for abrasives, fillers, sinters or spacers which comprises .alpha.-alumina particles having a substantially octahedral or eicosahedral shape, a specific structure, and a narrow primary particle size distribution.Type: GrantFiled: February 26, 1996Date of Patent: August 10, 1999Assignee: Sumitomo Chemical Company, LimitedInventors: Masahide Mohri, Yoshio Uchida, Yoshinari Sawabe, Hisashi Watanabe
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Patent number: 5916536Abstract: The invention concerns a process for the production of alumina for ceramics by calcining alumina trihydrate in the presence of a mineralizer such as a halogenated compound and/or a boron compound, the calcined alumina being constituted by friable agglomerates of elementary particles, or crystallites, of alpha alumina, the average size of which can be fixed as required, with a unimodal narrow distribution of crystallite sizes, characterized in that calcining of the alumina trihydrate is carried out in an industrial kiln in a renewed oxidising atmosphere at a temperature in the range 800.degree. C. to 1300.degree. C. for a period of 0.5 hour to 4 hours in the simultaneous presence of a halogenated compound acting as a mineralizer and a silica based alumina recrystallisation modifier which is uniformly and intimately distributed in the alumina trihydrate charge.Type: GrantFiled: October 30, 1997Date of Patent: June 29, 1999Assignee: Aluminium PechineyInventors: Jean Deville, Jean-Michel Lamerant
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Patent number: 5911966Abstract: An alumina solid is obtainable by a process comprising the step of contacting in a liquid medium at least one alumina precursor with at least one template comprising a membrane lipid or a mixture of two or more thereof.Type: GrantFiled: July 13, 1998Date of Patent: June 15, 1999Assignee: BASF AktiengesellschaftInventors: Ulrich Muller, Roger Ruetz