Abstract: A method for eliminating carbonaceous contaminants and preventing the hydration/solubilization of the alumina protective coating of a phosphor is described. The method involves the heating a fluidized alumina coated phosphor in a fluidized bed at a temperature and for a period of time sufficient to preclude adversely affecting the protective oxide coating on the phosphor during subsequent water-based suspension processing without detrimentally altering the phosphor. After heating the fluidized phosphor is cooled and then added to a water-based suspension. The conditions for treating a manganese activated zinc silicate phosphor having a protective alumina coating are heating the fluidized phosphor at a temperature between about 700.degree. C. and about 850.degree. C. for a period of time from about 15 minutes to about 20 hours.A fluorescent lamp containing the phosphor prepared by the above described method is also described.

Abstract: In a treatment chamber (12) having a gas inlet (16) and gas outlet (18) to produce a general flow of gas (E) directed from the bottom to the top a hollow lance (40) extends transversely of the general flow of gas (E) between two pairs of guide vanes (42,44). The outline of the lance (40) is symmetrical with respect to a vertical center plane (A), and it includes a conveyor channel (60) which extends in longitudinal direction of the lance and to which discharge nozzles (80) for material are connected. A pair of semishells (52) are arranged above the guide vanes (42,44) and, together with the guide vanes (42,44), they form a straight trough (53) which is at least approximately symmetrical with respect to the center plane (A). A pressure gradient can be produced between the gas inlet (16) and the gas outlet (18) at which gradient a rectilinear fluidized bed (F) is formed within the trough (53).

Abstract: This invention relates to a process for treatment of pigments and the compositions of treated pigments using the disclosed process. Particularly, this invention describes a process for producing non-dusty, free flowing, granular pigment materials in which the pigment is treated by a water-dissipatable polyester. The treated pigment materials generally exhibit high dispersibility in water and polar solvent systems. Dispersions of such materials provide film-forming characteristics, water-resistivity and excellent adhesion when applied to the skin. The pigment materials prepared by the disclosed process are suitable for incorporation in paints, inks, cosmetic bases, liquid make-ups or other cosmetic preparations such as mascara.

Abstract: A low temperature process for coating polymer granules with additives in order to modify the properties of the polymer comprises contacting a fluidized bed of the polymer granules with an aqueous dispersion of additives.

Abstract: An improved fluidized bed reactor and a method for utilizing the fluidized bed reactor in the production of, for example, high purity polycrystalline silicon, by the pyrolysis of silane containing gas. The reactor being characterized by an entrainment zone located above a lower reaction zone. The entrainment zone having a cross-sectional area less than or equal to the cross-sectional area of the reaction zone and being capable of maintaining a fluidization gas velocity sufficient to entrain silicon powder particles, yet not sufficient to entrain silicon particles.

Abstract: Particles of active substance are encapsulated by spraying them with a thermoplastic silicone copolymer in solution in an organic solvent or in an aqueous dispersion or emulsion and removing the solvent or water by drying with hot air. The spraying/drying process employed is, for example, the Wurster process. The copolymer employed can be made up of a succession of polydiorganosiloxane segments or blocks and of organic segments or blocks (polyesters, polyethers, polyurethanes, polystyrenes, and the like). It can also be a polydiorganosiloxane grafted with organic chains. The active substance is in the form of particles with a particle size of between 50 .mu.m and 5 mm. It may be a catalyst, a perfume, a colorant, a cosmetic product, a medication, a plant-protection product, plant seeds, and the like.The invention is especially useful for controlling the release of active substance in an aqueous medium.

Abstract: A method for coating finely divided material with titania is disclosed. The method involves the fluidization of the finely divided material in an inert carrier gas containing vaporized titanium isopropoxide. The isothermal fluidized bed is kept at a temperature equal to or below approximately 300.degree. C. The vaporized titanium isopropoxide reacts to form a coating of titania on the surfaces of the particles within the fluidized bed. The greatest coating efficiency occurs when the fluidized bed is kept at approximately 300.degree. C. for approximately the first 10 minutes of the reaction and thereafter at approximated 250.degree. C. The titania coating process is particularly useful for electroluminescent phosphors such as copper doped zinc sulfide phosphor. The titania coated electroluminescent phosphors are relatively insensitive to moisture. Lamps made from the coated electroluminescent phosphor are also relatively insensitive to moisture.

Abstract: An encapsulated breaker chemical composition used in an oil or gas stimulation operation which comprises: a breaker chemical; and a pinhole free coating of an ionically and covalently crosslinked neutralized sulfonated elastomeric polyer of about 2 to about 80 microns thick deposited onto the surface of the breaker chemical, wherein said polymer encapsulates the breaker chemical, wherein the polymer is permeable to the breaker chemical and the polymer is non-reactive to the breaker chemical.

Abstract: A granular pharmaceutical composition containing 85 to 99 percent ibuprofen, 0.9 to 15.0 percent binder, and 0.1 to 5.0 percent polyvinylpyrrolidone, wherein the polyvinylpyrrolidone forms a film with a portion of said binder to form agglomerates, is disclosed. Ibuprofen may be fluidized with a portion of the binder in a fluid bed apparatus and sprayed with an aqueous dispersion of polyvinylpyrrolidone and the remainder of the binder. This granulation may be subsequently blended with additional excipients and, optionally, additional active pharmaceutical ingredients for direct compression into tablets.

Abstract: An encapsulated breaker chemical composition used in a fracturing process in an oil or gas stimulation operation which comprises: (a) a breaker chemical; (b) a water soluble sealing layer, such as urea, having a thickness within the range of about 1 to about 30 microns deposited on the surface of said breaker chemical and encapsulating said breaker chemical; and (c) a pinhole free coating of a neutralized sulfonated elastomeric polymer of about 2 to about 80 microns thick deposited onto the surface of the coated breaker chemical, wherein said neutralized sulfonated polymer encapsulates the breaker chemical and is permeable to the breaker chemical.

Abstract: An encapsulated breaker chemical composition used in a fracturing process in the protection of an oil or gas stimulation operation which comprises: a breaker chemical; and a pinhole free coating of a neutralized sulfonated elastomeric polymer of about 2 to about 80 microns thick deposited onto the surface of the breaker chemical, wherein said neutralized sulfonated polymer encapsulates the breaker chemical, wherein the neutralized sulfonated polymer is permeable to the breaker chemical and the neutralized sulfonated polymer is non-reactive to the breaker chemical.

Abstract: A process for coating wet rubber pellets including coating the pellets with an inorganic partitioning agent, a thickener and binder, and an anionic water soluble dispersant, air conveying the pellets to a dryer, and compressing the pellets to form a bale. By virtue of the coating, the bales are rendered more friable.

Abstract: A method of performing granulating, coating, drying of a powdry or granular material having a relatively minute particle diameter and an apparatus therefor. A nozzle for supplying the powdery or granular material and a nozzle for supplying a coating liquid are parallelly provided at adjacent positions where air streams dispersed from the both nozzles are not in contact with each other and directed to the interior of a processing cylinder. The two nozzles are connected to compressed air sources independently of each other. Drying air-stream blow-in openings are provided on the way from collision of the powdery or granular material and the coating material to catching thereof. Drying air streams are supplied from a direction tangent to the processing cylinder having a circular section.

Abstract: A coated product comprising a water soluble core material having a water insoluble polymeric coating encapsulating said core and a process for the production thereof. The encapsulating coating comprising a water-borne, polyvinylidene chloride-based latex composition which provides for the release of the water soluble core material over an extended period of time.

Abstract: In a container (12) a treatment space (14) for substance (16) is arranged and therebelow a wind chamber (22). The wind chamber (22) is defined upwardly by a circular rotor disc (42) which is rotatable drivably about an upright central (42) which is rotatable drivably about an upright central axis (A) and has at least one opening (44) which is elongated in approximately radial direction and which allows a gas stream (50) from the wind chamber (22) into the treatment space (14). The rotor disc (42) forms the sole partition between wind chamber (22) and treatment space (14). Associated with the or each opening (44) of the rotor disc (42) is a closure means which is opened in normal operation but is closable for stopping the apparatus. Stationarily arranged above the rotor disc (42) is at least one retaining blade (98) which prevents substance lying on the rotor (40) from rotating with the latter.

Abstract: A process is disclosed for coating phosphors with hydrolyzed alkylaluminum. The hydrolyzed alkylaluminum coating renders the phosphors insensitive to atmospheric moisture. the coating process involves vaporizing an aluminum-containing precursor such as trimethylaluminum or triethylaluminum in an inert gas stream and passing this through a fluidized bed containing the phosphor particles. Water vapor is also passed through the fluidized bed and the water and aluminum precursor react on the surface of the phosphor particles to form hydrolyzed trimethylaluminum or other alkylaluminum. The hydrolyzed trimethylaluminum or other alkylaluminum phosphors are particularly useful in electroluminescent lamps.

Abstract: A process for the production of PVP-H.sub.2 O.sub.2 products in the form of free-flowing powders is described in which a fluidized bed maintained at a reaction temperature of about room temperature to 60.degree. C. is contacted with finely divided droplets of a 30 to 85% by weight aqueous H.sub.2 O.sub.2 solution. Preferably the fluidized bed temperature is about 35.degree.-45.degree. C., a 50-70% H.sub.2 O.sub.2 solution is used, and the feed rate of introduction of the H.sub.2 O.sub.2 solution is about 5-50 g/minute/kg PVP present. The PVP-H.sub.2 O.sub.2 product preferably contains about 15-24%, preferably 18-22%, H.sub.2 O.sub.2 (1:1 molar ratio) and less than about 5% water.

Abstract: A method of manufacturing high-purity silicon crystals, which comprises depositing silicon on the surface of high-purity silicon particles, while feeding into a fluidized bed reactor at a high temperature a material gas consisting of high purity chlorosilane and a diluting gas, said method having a silicon deposition rate in excess of about 0.4 .mu.m/min.

Abstract: A granulating and coating method using the drying air streams to effectuate granulating, coating and drying and apparatus therefore wherein:a nozzle for supplying an article to be coated and another nozzle for supplying a coating material are provided at such positions that the article to be coated and the coating material collide with each other before the article to be coated and the coating material are dispersed by the drying air streams.

Abstract: Cellulose fibers are entrained in a gaseous medium and sized while entrained with a sizing material. The sizing material may comprise a nonaqueous solution of alkyl ketene dimer or other sizing material. Also, immersions of fibers in such a nonaqueous sizing solution is another approach for sizing fibers.

Abstract: This invention concerns the addition of fibrous alumina material to a phosphor or phosphor mixture before fluidization as a means of increasing the cohesiveness of the phosphor or phosphor mixture. The increase in cohesiveness can be controlled by varying the concentration of the fiber in the mixture.

Abstract: Described is a device for obtaining a foam spray-dried product of predetermined bulk density. Thereto a nozzle for spraying a foaming gas comprising liquid is surrounded by a tube for supplying a gas which comprises dry particulate material to the jet of nozzle.Means are present to accurately control the ratio of solids in the liquid to be sprayed and the dry particulate material.The method described that the dry particulate material is made to collide with the jet from the nozzle and that the speed of the gas transporting said dry material is lower than 20 m/sec and preferably from 6 to 12 m/sec.

Abstract: An apparatus and process for maintaining the purity of solid/granular product and dispensing high purity granular product from a vessel. A noncontaminating surface is provided by a cup, cylinder, or other structure having a surface of silicon, silicon carbide, silicon nitride, sialon, or similar materials and preferably operates as an angle of repose valve in a pressurized system to prevent contamination by undue contact of the high purity product with conventional gastight valves such as ball valves, butterfly valves, pinch valves, etc.

Abstract: The invention relates to electrically conducting solid plastics, the conductivity of which is attributable to their containing finely divided particulate, conducting substances. The electrically conducting solid plastics are comprised of or contain a polymer such as polymethyl methacrylate having a discrete fine-particle structure, and the polymer particles of the polymer are "doped", at least on their surface, with at least one electrically conducting substance such as carbon black in an amount which establishes electrical conductivity. The conducting substance(s) are present in the form of a plurality of conducting particulate solid bodies, and wherein the condition is imposed that the glass temperature (Tg) of the polymer is not exceeded when the conducting substance is mixed with the polymer particles.

Abstract: A free-flowing granular bitumen product containing from 0.5 to 6% by weight of a powdery coating and separating agent such as synthetic silica or carbon black is prepared by atomizing hot, liquid bitumen in a spray mixer while simultaneously introducing the powdery coating and separating agent by means of the cold air flow into the spray mixer.

Abstract: The method of making a bi-layer coating on phosphor particles is disclosed. The first layer surrounding the phosphor is silica. The second layer surrounding the phosphor is alumina. The bi-layer phosphor is useful in fluorescent lamps providing improved maintenance and brightness. The bi-layer phosphor can also be used in high color rendition lamps employing blends of phosphors.

Abstract: Disclosed is a method for applying a continuous protective coating to the surface of individual phosphor particles. The method involves chemical vapor deposition of an aluminum oxide coating on individual particles of a phosphor powder while the particles are suspended in a fluidized bed. The particles in the fluidized bed are exposed to vaporized coating precursor material, preferably aluminum isopropoxide at a temperature above 300.degree. C. The bed is kept at as nearly an isothermal condition as possible. Prior to entering the fluidized bed the aluminum isopropoxide is vaporized and kept at a temperature less than the decomposition temperature of aluminum isopropoxide. Mechanical means are used to help increase the fluidization efficiency of the fluidized bed. After coating the phosphor particles for approximately 30 minutes the vaporized precursor material is shut off from the bed entrance and the oxygen flow rate to the fluidized bed is increased.

Abstract: An apparatus for heating polycrystalline silicon, in which polycrystalline silicon of semiconductor grade placed in the reaction vessel is directly heated by means of a heater outside of the reaction vessel where the inner surface of the reaction vessel is formed of graphite coated with highly pure silicon and having a thickness of 100 microns or more.

Abstract: By agglomeration in a high speed mixer spherical granules having a desired granule size distribution are obtained by supplying the agglomeration liquid by means of an atomizer wheel axially positioned in the high speed mixer and by controlling the quantity and evaporation of said liquid in consideration of the changes occurring with respect to water binding ability of the agglomerates during compaction. An apparatus for carrying out the method includes a mixer bowl with an impeller on a central shaft through the bottom of the bowl and an atomizer with an atomizer wheel with its shaft in alignment with the shaft of the impeller.

Abstract: Closed system and process for the conversion of gaseous or vaporizable organic and/or organo-metallic compound to inert solid which is resistant to solvent extraction, and is itself essentially nontoxic or convertible through oxidation or other natural processes to a toxic material. This process involves a low temperature, low energy conversion in a close system, of an organic and/or organo-metallic material by initially fragmenting such material into its basic elements follow thereafter by randomly recombining such elements as a solid coating or deposit upon a substrate. In the preferred embodiments of this invention, the toxic and/or potentially toxic material is injected as a gaseous phase into a chamber where it is subjected to an RF energy source, thereby forming a plasma which is contained within the chamber by a magnetic field.

Abstract: A luster pigment is described which is made up of a metal oxide film on a colored platelet-like support. The support is a pigment having a length of 3-150 .mu.m, a width of 3-150 .mu.m, and a thickness of 0.1-2 .mu.m. A process is described for the preparation of the pigment in which an organic platelet-like pigment is coated with a metal-oxide film by chemical vapor deposition. The preferred platelet-like organic pigment is .beta.-copper phthalocyanine.

Abstract: Method and apparatus for coating mouldings consisting of fluidizing the mouldings by means of a rotating spiral gas flow. A holder (A) containing the mouldings is provided with gas inlets (3). A gas flow through the gas inlet (3) brings the mouldings in a spiral rotating movement in a sphere (C) placed on holder (A). Coating material is sprayed in the apparatus by a tube (D), oscillated by the gas flow, on the whirling mouldings.

Abstract: A method of producing a fine coated pharmaceutical preparation, which includes cooling fine liquid droplets composed of a liquid medium, a drug dissolved or suspended in the liquid medium, and as required, a binder to a temperature of not higher than the freezing point of the liquid medium to form frozen particles of the drug and as required the binder, adjusting the particle sizes of the fine frozen particles, mixing the fine frozen particles with a fine powder of a coating material having a particle diameter smaller than the particles at a temperature higher than the freezing point of the liquid medium to cause the fine powder of the coating material to adhere to the surfaces of the particles, and then removing the liquid medium from the resulting coated particles.

Abstract: Plastic particles showing improved behavior upon extrusion, comprising coating the particles with a fused layer of certain waxes or polymeric materials; and a method of preparation, comprising heating the plastic particles to a temperature just below the softening or fusing temperature of the additive while blending the particle in a high intensity blender, introducing the additive and maintaining intense blending until the temperature is above the fusing temperature of the additive, and discharging the coated particles from the blender.

Abstract: Disclosed is a method for applying a continuous protective coating to the surface of individual phosphor particles. The method involves chemical vapor deposition of an aluminum oxide coating on individual particles of a phosphor powder while the particles are suspended in a fluidized bed. The particles in the fluidized bed are exposed to vaporized coating precursor material, preferably aluminum isopropoxide at a temperature above 300.degree. C. The bed is kept at as nearly an isothermal condition as possible. Prior to entering the fluidized bed the aluminum isopropoxide is vaporized and kept at a temperature less than the decomposition temperature of aluminum isopropoxide. Mechanical means are used to help increase the fluidization efficiency of the fluidized bed. After coating the phosphor particles for approximately 30 minutes the vaporized precursor material is shut off from the bed entrance and the oxygen flow rate to the fluidized bed is increased.

Abstract: A method of producing submicron nonagglomerated particles in a single stage reactor includes introducing a reactant or mixture of reactants at one end while varying the temperature along the reactor to initiate reactions at a low rate. As homogeneously small numbers of seed particles generated in the initial section of the reactor progress through the reactor, the reaction is gradually accelerated through programmed increases in temperature along the length of the reactor to promote particle growth by chemical vapor deposition while minimizing agglomerate formation by maintaining a sufficiently low number concentration of particles in the reactor such that coagulation is inhibited within the residence time of particles in the reactor. The maximum temperature and minimum residence time is defined by a combination of temperature and residence time that is necessary to bring the reaction to completion.

Abstract: The present invention is directed to processes and apparatus useful for fluidizing small particulate solids having a diameter of less than about 50 microns in average particle size, and at least partially enveloping these small solids with a coating material or a precursor thereto.

Abstract: Disclosed is a method for adjustably controlling the rate of circulation and temperature gradient in a fluidized bed.

Abstract: The granulate detergent enzyme product comprises a core of a microbial enzyme containing material with an enteric coating. Due to the coating the enzymatic stability is enhanced, in the presence of other detergent components, espacially strong bleaching agents. The coating is usually carried out in a fluid bed. Also coatings with antioxidants and acid coatings enhance the enzymatic stability.

Abstract: The invention relates to a detector device for determining components of a sample such as a gaseous sample. The determination is made with reagents which are present in two component quantities separate from each other in the storage condition of the detector device. The component quantities are brought into contact with each other to establish the use condition of the detector device. A simple production and reliable operation of such detector devices is obtained if at least one of the component quantities is contained in a plurality of particles during the storage condition with each particle having a reagent-containing core and an encapsulation surrounding the core. The encapsulation is made of a material which is solid at normal temperature and melts at a higher temperature which is unharmful to the remaining components of the detector device. The detector device is transferred from the storage condition to the use condition by removing the encapsulation by heating.

Abstract: A modified pregelatinized starch which is readily dispersible in water comprising a pregelatinized starch coated with from 0.05 to 20% by weight of a food grade emulsifier. A process for producing a coated pregelatinized starch comprising blending a pregelatinized starch with a mixture of a non-toxic solvent and a food grade emulsifier followed by removing the solvent.

Abstract: A composition capable of releasing active enzyme into an aqueous, active chlorine containing media which in a first aspect comprises an enzyme core encapsulated with an initial coating of a time-release substance, a first coating of a bleach-neutralizing substance and a second coating of a time-release substance.In a second aspect, the composition comprises an enzyme encapsulated in a time-release substance designed to delay release of the enzyme in dissolution for a first-time delay, and a bleach-neutralizing substance, present as either a core material and/or a first coating on a diluent core, which is encapsulated in a time-release substance designed to delay release of the bleach-neutralizing substance into solution for a second-time delay; the first-time delay being longer than the second-time delay so that the bleach-neutralizing substance will be released and completely neutralize all active chlorine present in the solution before the enzyme is released.

Abstract: Electroluminescent phosphors, electroluminescent panels and lamps made with such phosphors, and a process and apparatus for treating phosphors are disclosed in which the phosphor particles are coated with a very thin coating of SiO.sub.2, to protect the phosphor particles from aging due to moisture intrusion. The phosphor particles are coated in a cold wall reactor by the pyrolytic decomposition of silane in the presence of heat and oxygen to a coating thickness of approximatley between 0.1 and 3.0 microns. The apparatus and method of coating includes the placement of a quantity of phosphor in a cup-shaped heated reactor bowl and subjecting the particles to a temperature of about 490.degree. C. and an atmosphere of silane and oxygen, while continuously mechanically agitating the particles with a blade arrangement in which the particles are continuously rotated and turned so as to expose the surfaces of the heated particles to the reaction atmosphere.

Abstract: Particles of silicon and a p or n carrier substance which are in spherical or spheroidal form, and suitable for use in the preparation of doped semiconductor devices, can be prepared by a fluidized bed technique for chemical vapor deposition of a carrier substance (B, P, As or Sb). The prepared products have a kernel of high purity polysilicon and a layer of silicon/dopant alloy upon the kernel. Optionally, the particles have a thin outer layer of silicon.

Abstract: A new process for continuously preparing granules having narrow grain size distribution, comprisinga. spraying the product to be granulated in liquid form into a fluidized bed,b. separating the proportions of fine material escaping from the fluidized bed from the off-gas and returning said fine material to the fluidized bed as nuclei for granule formation,c. setting the fluidizing gas flow such that granules are formed which are of a predetermined size, andd. removing the completed granules solely by way of at least one countercurrent gravity classifier inserted into the outflow bottom of the fluidized-bed vessel.A new apparatus for carrying out the process according to the invention and new granules.

Abstract: A process is described for the coating of granules containing wax-like substances, in an apparatus having a rapidly rotating horizontal disk located in a vertical container, in the presence of one or more wax-like substances or a mixture of one or more was-like substances, wherein the wax-like substances in powder form are scattered onto the granules which have been heated until the wax-like substance has softened.

Abstract: The present invention provides methods and materials for coating relatively small quantities of particles including tablets, pellets or granules. The device effectively fluidizes the particles to be coated by controlled vibration of a perforated platform through which drying air is passed during intermittent spraying of the particles with a solution of organic or aqueous-based coating material. The method coats individual tablets having as low a mass as 50 mg and coats quantities ranging from less than about 50 mg to 10 g of tablets, pellets, or granules.

Abstract: A process is disclosed for applying a lubricant to a powdered material to control the fluidity of the powdered material. In the process one first obtains at least x number of samples of the powdered material without lubricant. Thereafter, increasing amounts of lubricant are applied to x-1 number of the samples. The bulk and tap densities of the samples are then measured and the Hausner ratio from the densities is calculated. The Hausner ratio versus the concentration of the lubricant in the powder samples is plotted and the concentrations of the minima lubricant in the powder samples at the point of the plot obtained in step e are determined. The concentration of lubricant determined in step f is applied to the remainder of the powdered material whereby an operational level of fluidity of the powder is achieved.

Abstract: A method of improving the quality of the surface of solid particles is disclosed. The method includes fixing material different from the solid particles to the surface of the solid particles by the use of an impact striking device. The material fixed to the solid particles can be other solid particles or particles contained in a liquid, which forms a film.

Abstract: Method and apparatus for the preparation of high-purity polycrystalline silicon deposited by thermal decomposition or hydrogen reduction of a gaseous halogenated silicon on high-purity silicon particles in a fluidized bed reactor heated by microwave.