Metal Coating Patents (Class 427/217)
  • Patent number: 7482059
    Abstract: A semiconductor nanocrystal complex including a metal layer formed on the outer surface of a semiconductor nanocrystal core after synthesis of the semiconductor nanocrystal core and a method for preparing a nanocrystal complex comprising forming a metal layer on a semiconductor nanocrystal core after synthesis of the semiconductor nanocrystal core. The metal layer may passivate the surface of the semiconductor nanocrystal core and protect the semiconductor nanocrystal core from the effects of oxidation. Also provided is a semiconductor nanocrystal complex with a shell grown onto the metal layer formed on the semiconductor nanocrystal core. In this embodiment, the metal layer may prevent lattice mismatch between the semiconductor shell and the semiconductor nanocrystal core.
    Type: Grant
    Filed: May 10, 2005
    Date of Patent: January 27, 2009
    Assignee: Evident Technologies
    Inventors: Adam Peng, Wei Liu
  • Publication number: 20090022994
    Abstract: A composite powder product suitable for hardmetal cutting tools and wear resistance applications is described. The product comprises a hard particulate phase chosen from a range of metallic carbides, nitrides, carbonitrides and the like, onto which hard phase is deposited a coating of cobalt or nickel, or a mixture of cobalt and nickel. The hard particulate phase has a particle size between 0.1 and 10 ?m, and preferably between 0.1 and 2 ?m.
    Type: Application
    Filed: November 29, 2005
    Publication date: January 22, 2009
    Inventors: Hossein Aminian, Ding Yuan
  • Publication number: 20080305257
    Abstract: The invention relates a method for the production of stabilised suspensions of nanometric or submicrometric particles, which is a method contained in a continuous flow that includes a step (20) for the placing in suspension, dispersion and/or functionalisation of these particles produced in a gaseous stream containing the particles at the output of a reactor in a stream of at least one liquid. The invention also relates a device that implements this method.
    Type: Application
    Filed: December 13, 2005
    Publication date: December 11, 2008
    Applicant: COMMISSARIAT A LENERGIE ATOMIQUE
    Inventors: Francois Tenegal, Benoit Guizard
  • Publication number: 20080278181
    Abstract: The present invention is directed toward oxidation-resistant, ligand-capped nanoparticles, each comprising one or more capping ligands on a copper-containing core. Methods of making and using these nanoparticles are also disclosed.
    Type: Application
    Filed: March 7, 2008
    Publication date: November 13, 2008
    Applicant: Research Foundation of State University of New York
    Inventors: Chuan-Jian ZHONG, Derrick MOTT
  • Publication number: 20080241543
    Abstract: The invention relates to a process for producing a material based on silver-carbon, comprising the steps of: (i) providing a suspension of carbon particles; and (ii) supplying a solution of a silver compound and of a reducing agent, such that a silver-containing precipitate is deposited onto the carbon particles, where the carbon particles have a mean diameter of 200 nm or greater. The invention further relates to a material obtainable by this process and to the use of the material in circuit breakers for low-voltage power engineering.
    Type: Application
    Filed: August 10, 2006
    Publication date: October 2, 2008
    Applicant: UMICORE AG & CO. KG
    Inventors: Bernd Kempf, Roger Wolmer, Carsten Boehme, Werner Roth, Andreas Koffler
  • Publication number: 20080226958
    Abstract: In a method of producing a particulate electrocatalyst composition, a precursor medium comprising at least a first metal precursor, a liquid vehicle, and a substrate precursor to substrate particles is atomized into precursor droplets. The droplets are then heated to a reaction temperature of not greater than 700° C. to form composite particles comprising said first metal at least partly in an oxide form dispersed on said substrate particles. The composite particles are then collected and are heated at a first treatment temperature no greater than 250° C. in the presence of a reducing atmosphere to at least partly convert said oxide form to the metal.
    Type: Application
    Filed: March 13, 2007
    Publication date: September 18, 2008
    Applicant: CABOT CORPORATION
    Inventors: Yipeng SUN, Paolina ATANASSOVA, James BREWSTER, Leonard P. PEREZ, Hanwei LEI, Berislav BLIZANAC
  • Publication number: 20080190323
    Abstract: A process for the formation of particles of a target material is disclosed, comprising: (i) introducing the target material into a particle formation vessel, and forming a continuous liquid surface of the target material in the particle formation vessel, and an interface between said liquid surface of the target material and additional gaseous contents of said particle formation vessel; (ii) introducing a stream of cryogenic material including solid particles of cryogenic material into the particle formation vessel and into contact with the target material in a liquid state below the continuous liquid surface; (iii) allowing rapid volumetric expansion of the cryogenic material into a gaseous state while in contact with the target material in a liquid state, and release of the expanded gaseous cryogenic material through the continuous liquid surface, and forming liquid droplet particles of the target material; and (iv) collecting the formed particles of the target material.
    Type: Application
    Filed: February 13, 2007
    Publication date: August 14, 2008
    Inventors: Rajesh V. Mehta, Robert Link, Michael A. Marcus
  • Publication number: 20080187769
    Abstract: A method of making metal-coated superabrasive material comprises heating components comprising: superabrasive material, a metal-containing compound that comprises a metal capable of forming at least one of a carbide, boride or nitride, and a reducing agent capable of reducing the metal-containing compound. The components are heated in an inert atmosphere to sufficient temperature and for sufficient time to form metal-coated superabrasive material. The metal-coated superabrasive material is useful in the manufacture of various superabrasive tools.
    Type: Application
    Filed: March 27, 2007
    Publication date: August 7, 2008
    Inventors: Gary M. Huzinec, Richard M. Andrews, Christopher P. Bieniasz
  • Publication number: 20080160191
    Abstract: This invention releases the preparation method and equipment of graphite and catalyst composite for a kind of synthetic diamond. Firstly the clean graphite particle shall be placed into the heating chamber for pre-heating, the lower limit of the heating temperature shall be higher than the boiling point of the coated carbonyl metal complex and the upper limit of the heating temperature shall be set according to the thickness of the coating needed; secondly, the heated graphite particle will be fed into the coating room with vibrator or agitator and the steam of carbonyl metal complex shall be input for coating; finally the coated graphite particle shall be fed into the cooling and passivation room for cooling and passivation of the discharging materials or enter the next round circle of heating and coating.
    Type: Application
    Filed: December 28, 2007
    Publication date: July 3, 2008
    Applicant: JIANGSU TIANYI MICRO METAL POWDER CO., LTD.
    Inventors: Weixing Gao, Bin Wang, Zunbin Ke
  • Publication number: 20080135407
    Abstract: In one embodiment, a protective coating for an electrode of a sensor is described, the protective coating comprising an annealed catalyst, said annealed catalyst comprising at least one metal that has been subjected to thermal energy that is at least equivalent to or greater than that received from calcining the at least one metal for 24 hours at a temperature of 930 degrees C. in air. In another embodiment, the annealed catalyst will comprise at least one metal that has been subjected to thermal energy that is equal to or less than that received from calcining the at least one metal for 24 hours at 1030 degrees C. in air. In one exemplary embodiment, the annealed catalyst will comprise at least one metal that has been subjected to thermal energy that is equal to that received from calcining the at least one metal for 24 hours at 980 degrees C. in air.
    Type: Application
    Filed: October 10, 2007
    Publication date: June 12, 2008
    Inventors: Carlos A. Valdes, Marsha Nottingham, Earl W. Lankheet, Eric P. Clyde
  • Patent number: 7361430
    Abstract: The present invention discloses a carbon nanotube (SWNT)-polymer composite actuator and method to make such actuator. A series of uniform composites was prepared by dispersing purified single wall nanotubes with varying weight percents into a polymer matrix, followed by solution casting. The resulting nanotube-polymer composite was then successfully used to form a nanotube polymer actuator.
    Type: Grant
    Filed: April 8, 2004
    Date of Patent: April 22, 2008
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Thomas Gennett, Ryne P. Raffaelle, Brian J. Landi, Michael J. Heben
  • Patent number: 7338686
    Abstract: The present invention provides a low-cost method for producing conductive particles in a short period of time by simplifying pretreatment in electroless plating. The method for producing conductive particles includes the steps of: introducing a solution composed mainly of palladium chloride and hydrochloric acid into an electroless plating bath containing particles of an organic material or an inorganic material while stirring the bath; and simultaneously applying an electroless plating to the surface of the particles and allowing the palladium catalyst to be carried on the surface of the particles to give conductive particles having an electroless plate coating.
    Type: Grant
    Filed: April 13, 2004
    Date of Patent: March 4, 2008
    Assignee: Kiyokawa Plating Industry Co., Ltd.
    Inventors: Hajime Kiyokawa, Kiyoto Fukuoka
  • Patent number: 7335418
    Abstract: Disclosed is a semiconductor nanoparticle having excellent chemical durability and high luminescence properties. The chemical durability of the particle is provided by coating the semiconductor nanoparticle having high luminescence properties dispersed in an organic solvent using a surface-active agent, an amphipathic molecule, and a lipid composed of a combination of two or more layers selected from a polar group, a hydrophobic group, a hydrophilic group, and a functional group (herein, the hydrophobic group is a necessary element and the hydrophilic group and the functional group are optional).
    Type: Grant
    Filed: November 9, 2005
    Date of Patent: February 26, 2008
    Assignee: Hitachi Software Engineering Co., Ltd.
    Inventors: Keiichi Sato, Susumu Kuwabata
  • Patent number: 7306823
    Abstract: CIGS absorber layers fabricated using coated semiconducting nanoparticles and/or quantum dots are disclosed. Core nanoparticles and/or quantum dots containing one or more elements from group IB and/or IIIA and/or VIA may be coated with one or more layers containing elements group IB, IIIA or VIA. Using nanoparticles with a defined surface area, a layer thickness could be tuned to give the proper stoichiometric ratio, and/or crystal phase, and/or size, and/or shape. The coated nanoparticles could then be placed in a dispersant for use as an ink, paste, or paint. By appropriate coating of the core nanoparticles, the resulting coated nanoparticles can have the desired elements intermixed within the size scale of the nanoparticle, while the phase can be controlled by tuning the stochiometry, and the stoichiometry of the coated nanoparticle may be tuned by controlling the thickness of the coating(s).
    Type: Grant
    Filed: September 18, 2004
    Date of Patent: December 11, 2007
    Assignee: Nanosolar, Inc.
    Inventors: Brian M. Sager, Dong Yu, Matthew R. Robinson
  • Patent number: 7294289
    Abstract: Disclosed are conductive powder having a packing density of 68% by volume or more with a relative value preferably comprising 60 to 92% by weight of roughly spherical and silver-plated copper powder part of the surface of which has been coated with 3 to 30% by weight of silver based on an amount of roughly spherical copper powder with exposing at least a surface of a portion of an alloy of copper with silver, and the surface of which is coated with 0.02 to 1.0% by weight of an aliphatic acid based on an amount of the roughly spherical and silver-plated copper powder, and 8 to 40% by weight of silver powder, and a method for preparing the same.
    Type: Grant
    Filed: June 16, 2006
    Date of Patent: November 13, 2007
    Assignee: Hitachi Chemical Co., Ltd.
    Inventor: Hideji Kuwajima
  • Patent number: 7261752
    Abstract: A superabrasive particle coated with a solidified coating of a molten braze alloy that is chemically bonded to the superabrasive particle is disclosed and described. In one aspect, the reactive metal alloy may be chemically bonded to at least about 80% of an outer surface of the superabrasive particle. Various methods for making and using such a coated superabrasive particle are additionally disclosed and described.
    Type: Grant
    Filed: July 25, 2003
    Date of Patent: August 28, 2007
    Inventor: Chien-Min Sung
  • Patent number: 7253104
    Abstract: The invention includes methods of forming particle-containing materials, and also includes semiconductor constructions comprising particle-containing materials. One aspect of the invention includes a method in which a first monolayer is formed across at least a portion of a semiconductor substrate, particles are adhered to the first monolayer, and a second monolayer is formed over the particles. Another aspect of the invention includes a construction containing a semiconductor substrate and a particle-impregnated conductive material over at least a portion of the semiconductor substrate. The particle-impregnated conductive material can include tungsten-containing particles within a layer which includes tantalum or tungsten.
    Type: Grant
    Filed: December 1, 2003
    Date of Patent: August 7, 2007
    Assignee: Micron Technology, Inc.
    Inventors: Garo J. Derderian, Gurtej S. Sandhu
  • Patent number: 7247259
    Abstract: A process for making an aerogel-electrolyte-metal composite includes contacting an aerogel with an electrolyte to form an aerogel-electrolyte composite; contacting the aerogel-electrolyte composite with a metal precursor to form an aerogel-electrolyte-precursor composite; and converting the metal precursor of the aerogel-electrolyte-precursor composite to metal crystals to form the aerogel-electrolyte-metal composite. In addition, an aerogel-electrolyte-metal composite is formed by the process, wherein the average longest dimension of the metal crystals is about 1 to about 3 nanometers, and wherein the metal crystals are about 30% to about 100% dispersed.
    Type: Grant
    Filed: April 4, 2005
    Date of Patent: July 24, 2007
    Assignees: Aerogel Composite, LLC, University of Connecticut
    Inventors: Can Erkey, Hiroaki S. Hara
  • Patent number: 7226636
    Abstract: A process of preparing gold-coated magnetic nanoparticles is disclosed and includes forming a suspension of magnetic nanoparticles within a suitable liquid, adding an amount of a reducible gold compound and a reducing agent to the suspension, and, maintaining the suspension for time sufficient to form gold-coated magnetic nanoparticles.
    Type: Grant
    Filed: July 31, 2003
    Date of Patent: June 5, 2007
    Assignee: Los Alamos National Security, LLC
    Inventors: Douglas E. Berning, Robert H. Kraus, Jr., Robert W. Atcher, Jurgen G. Schmidt
  • Patent number: 7217318
    Abstract: In a method for the manufacture of a nacreous pigment, in which a multi-layer film is produced by vacuum evaporation coating on a substrate and, after release from the substrate, the particles thus produced are comminuted to pigment particles of a desired size, vapor deposition of a plurality of layers taking place at separate locations within an evacuable container and the substrate being passed along the sources of evaporation, it is provided that at least a backing (A), in particular a silicon oxide layer, and at least a metal oxide layer (B), in particular a titanium oxide layer, are vapor-deposited on the substrate, in particular a circulating metal belt.
    Type: Grant
    Filed: July 28, 2004
    Date of Patent: May 15, 2007
    Assignee: Eckart GmbH & Co. KG
    Inventor: Günter Sommer
  • Patent number: 7172791
    Abstract: Methods for synthesizing luminescent nanoparticles and nanoparticles prepared by such methods are provided. The nanoparticles are prepared by a method in which an additive is included in the reaction mixture. The additive may be a Group 2 element, a Group 12 element, a Group 13 element, a Group 14 element, a Group 15 element, or a Group 16 element. In additions, a luminescent nanoparticle is provided that comprises a semiconductive core surrounded by an inorganic shell, an interfacial region and an additive present in the interfacial region or both the interfacial region and the shell.
    Type: Grant
    Filed: November 9, 2004
    Date of Patent: February 6, 2007
    Assignee: Invitrogen Corp.
    Inventors: Joseph A. Treadway, Donald A. Zehnder, Marc D. Schrier
  • Patent number: 7112369
    Abstract: A polymer nanoparticle is provided. The nanoparticle includes an inner layer having alkenylbenzene monomer units. The nanoparticle further includes an outer layer having monomer units selected from conjugated dienes, alkylenes, alkenylbenzenes, and mixtures thereof. The nanoparticle has at least one functional group associated with the outer layer. The nanoparticle further has at least one metal complexed with said functional group. The nanoparticles can be used as a templates for preparation of nano-sized metal crystals and polymer-metal nanocomposite.
    Type: Grant
    Filed: March 2, 2004
    Date of Patent: September 26, 2006
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, James E. Hall, Georg G. A. Böhm, Chenchy Jeffrey Lin
  • Patent number: 7048965
    Abstract: A surface-covering article and method of installing the same are described. The surface-covering article includes a top layer, a bottom layer, and reinforcing layer. The top layer is made of a first type of resin. The bottom layer is made of a second type of resin. The second type of resin of the bottom layer chemically bonds with the first type of resin of the top layer to join the bottom layer and the top layer. The reinforcing layer is disposed between the top layer and bottom layer and includes a material to distribute a load force throughout the reinforcing layer when the load force is applied to the surface-covering article.
    Type: Grant
    Filed: May 28, 2004
    Date of Patent: May 23, 2006
    Inventor: Felisa Blazek
  • Patent number: 6977097
    Abstract: A particle forming method includes feeding a first set of precursors to a first energy application zone. Energy is applied to the first set of precursors in the first energy application zone effective to react and form solid particles from the first set of precursors. The application of any effective energy to the solid particles is ceased, and the solid particles and a second set of precursors are fed to a second energy application zone. Energy is applied to the second set of precursors in the second energy application zone effective to react and form solid material about the solid particles from the second set of precursors. At least one precursor is fed to at least one of the first and second energy application zones as a liquid. Other aspects are contemplated.
    Type: Grant
    Filed: July 23, 2003
    Date of Patent: December 20, 2005
    Assignee: Micron Technology, Inc.
    Inventor: Trung Tri Doan
  • Patent number: 6974601
    Abstract: Disclosed is a positive active material for a rechargeable lithium battery. The positive active material includes at least one compound represented by formulas 1 to 4: LixNi1-yMnyF2??(1) LixNi1-yMnyS2??(2) LixNi1-y-zMnyMzO2-aFa??(3) LixNi1-y-zMnyMzO2-aSa??(4) where M is selected from the group consisting of Co, Mg, Fe, Sr, Ti, B, Si, Ga, Al, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ac, Th, Pa, U, Np, Pu, Am, Cm, Bk, Cf, Es, Fm, Md, No and Lr, 0.95?x?1.1, 0<y?0.99, 0?z?0.5, and 0?a?0.5; and a metal oxide or composite metal oxide layer formed on the compound.
    Type: Grant
    Filed: March 23, 2004
    Date of Patent: December 13, 2005
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Ho-Jin Kweon, Hyun-Sook Jung, Yong-Chul Park, Geun-Bae Kim
  • Patent number: 6972134
    Abstract: A method of preparing for a positive active material for a rechargeable lithium battery is provided. In this method, a lithiated compound to be coated and an organic solution or aqueous solution including a coating-element source are putted into a mixer, the mixture is continuously stirred to mix the contents thoroughly, and a hot dry gas is introduced into the mixer to evaporate the solvent while the powder is continuously agitated. The resulting dry coated powdery compound is heat-treated at an elevated temperature to obtain an oxide coating on the lithiated compound.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: December 6, 2005
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Ho-Jin Kweon, Jun-Won Suh, Won-Il Jung, Jeong-Joon Park
  • Patent number: 6958308
    Abstract: A method for producing dispersed metal particles on a substrate and the compositions produced is disclosed. A method for producing the particles comprises exposing an organometallic and a particulate substrate to supercritical or near supercritical fluid under conditions to form a mixture of the fluid and the organometallic, allowing the mixture to remain in contact with the substrate for a time sufficient to deposit dispersed organometallic onto the substrate, venting the mixture, thereby adsorbing the organometallic onto the substrate, and reducing the dispersed organometallic to dispersed metal particles with a reducing agent.
    Type: Grant
    Filed: March 16, 2004
    Date of Patent: October 25, 2005
    Assignee: Columbian Chemicals Company
    Inventor: Garth Desmond Brown
  • Patent number: 6926964
    Abstract: Disclosed is a fuel tank for a motor vehicle whose inner face is processed with an inorganic coating agent comprising (A) fine particles carrying silver and/or copper and (B) inorganic fine particles, and the tank inhibits oxidation of the fuel such as gasoline or light oil, and further decreases the cluster of gasoline or light oil to make finer the particle size of atomized fuel, thereby improving ignitionability and combustibility, which makes it possible to decrease imperfect combustion and to decrease substantially the consumption of the fuel.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: August 9, 2005
    Assignee: Kabushiki Kaisha Nippankenkyusho
    Inventor: Yoshio Ichikawa
  • Patent number: 6905814
    Abstract: The invention concerns the use of a film-forming titanium dioxide dispersion for cleaning and disinfecting surfaces exposed to light, by depositing a film of titanium dioxide nanoparticles on said surfaces, the continuous phase of said dispersion comprising water and/or at least an alcohol with boiling point at less than 120° C., said dispersion having, when it comprises water, a pH different by at least 1 unit of the value of the titanium dioxide isoelectric pH in said dispersion. The invention also concerns a film-forming titanium dioxide dispersion further comprises a film-forming polymer. The invention further concerns a method for cleaning and disinfecting surfaces exposed to light which consists in depositing and then drying on said surfaces a titanium oxide film-forming dispersion.
    Type: Grant
    Filed: February 15, 2000
    Date of Patent: June 14, 2005
    Assignee: Rhodia Chimie
    Inventors: Eric Aubay, Thierry Chopin, Cédric Geffroy, Véronique Guillou, Corinne Lehaut
  • Patent number: 6855273
    Abstract: The present invention concerns electrode materials capable of redox reactions by electrons and alkaline ions exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, super capacitors and light modulating system of the super capacitor type.
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: February 15, 2005
    Assignees: ACEP, Inc., Centre National de la Recherche Scientifique, Universite de Montreal
    Inventors: Nathalie Ravet, Simon Besner, Martin Simoneau, Alain Vallée, Michel Armand, Jean-François Magnan
  • Patent number: 6821314
    Abstract: An electrolyte capacitor containing a niobium anode, a niobium oxide barrier layer, a semiconducting cathode and an electrolyte is described, where the niobium oxide barrier comprises a least one metal from the group consisting of Al, Si, Ti, Zr, Mo, W, Y and Ta.
    Type: Grant
    Filed: May 7, 2002
    Date of Patent: November 23, 2004
    Assignee: H. C. Starck GmbH
    Inventors: Karlheinz Reichert, Oliver Thomas, Christoph Schnitter
  • Patent number: 6803073
    Abstract: A submicron particle forming method includes feeding a first set of precursors to a first energy application zone. Energy is applied to the first set of precursors in the first energy application zone effective to react and form solid particles having maximum diameter of no greater than 100 nanometers from the first set of precursors. The application of any effective energy to the solid particles is ceased, and the solid particles and a second set of precursors are fed to a second energy application zone. Energy is applied to the second set of precursors in the second energy application zone effective to react and form solid material about the solid particles from the second set of precursors with the solid particles with solid material thereabout having maximum diameter of no greater than 100 nanometers. Other aspects are contemplated.
    Type: Grant
    Filed: March 11, 2003
    Date of Patent: October 12, 2004
    Assignee: Micron Technology, Inc.
    Inventor: Trung Tri Doan
  • Patent number: 6773763
    Abstract: A method of manufacturing a permanent magnet by the steps of preparing an admixture of magnetic material and binder material, the admixture material having a particle size of less than 325 mesh. Then heating a carrier gas to a temperature substantially below the melting point of either component of the admixture. The admixture is introduced into the carrier gas and the admixture is sprayed atop a ductile carrier. The admixture adheres to the carrier and forms a solid permanent magnet. An electric field is applied to the sprayed admixture to create a permanent magnetic moment.
    Type: Grant
    Filed: July 29, 2002
    Date of Patent: August 10, 2004
    Assignee: Ford Global Technologies, LLC
    Inventors: Franco Leonardi, John Matthew Ginder, Robert Corbly McCune
  • Patent number: 6761971
    Abstract: A protective coating for aluminate phosphors is described. The protective coating comprises at least a partial spinel coating having the general formula Mg1-xAl2(1-y)O4-3y-x, where 0≦x<1 and 0≦y<1. The coating is applied by an aqueous solution method which may be compatible with conventional fluorescent lamp manufacturing techniques.
    Type: Grant
    Filed: September 26, 2001
    Date of Patent: July 13, 2004
    Assignee: Osram Sylvania Inc.
    Inventors: Madis Raukas, Kailash C. Mishra, Thomas H. Reilly III
  • Patent number: 6726964
    Abstract: A process for depositing metal on microparticulate comprising immersing microparticulate in an autocatalytic plating bath comprising the metal; inducing ultrasonic vibration in the plating bath at a frequency corresponding to resonance frequency of the microparticulate; and inducing a turbulent vibration signal in the plating bath in a direction non-parallel to the ultrasonic vibration. This process results in the autocatalytic plating bath depositing the metal on the microparticulate with uniform thickness. The microparticulate can be spheres, flakes or microfibers, and can be made from a number of materials, such as synthetic polymers (nylon, Kevlar™, Zylon™, and aramid fibers) and biodegradable compounds. A method is disclosed for coating a surface with metallized microparticulate fibers with an orientation perpendicular to the surface.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: April 27, 2004
    Inventors: G. Alan Thompson, David E. Marx
  • Patent number: 6706330
    Abstract: The invention relates to a process for coating a surface through graft polymerization, characterized in that before graft polymerization, the surface is modified, in the presence of an amine of formula: wherein R1 is hydrogen or a group R4, R2 and R3 are each independently a group R4, and R4 is [-1,2-C2-C3alkylen-T-]n-H wherein T is O or NH and n is a number from 1 to 3, by a compound having a functional group: wherein R5 to R7 are each C1-C4alkyl. The amount of amine is preferably from 5 to 500 g/m2 of surface of the substrate particle. The amount of the trialkoxysilane compound is preferably from 0.1 to 2 g/m2 of surface of the substrate particle. The process for coating a surface is particularly useful for effect pigments.
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: March 16, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ryuichi Takahashi, Adrian Schulthess, Kimiya Takeshita, Fritz Herren, Patrice Bujard
  • Patent number: 6685986
    Abstract: The present invention is for particulate compositions and methods for producing them that can absorb or scatter electromagnetic radiation. The particles are homogeneous in size and are comprised of a nonconducting inner layer that is surrounded by an electrically conducting material. The ratio of the thickness of the nonconducting layer to the thickness of the outer conducting shell is determinative of the wavelength of maximum absorbance or scattering of the particle. Unique solution phase methods for synthesizing the particles involve linking clusters of the conducting atoms, ions, or molecules to the nonconducting inner layer by linear molecules. This step can be followed by growth of the metal onto the clusters to form a coherent conducting shell that encapsulates the core.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: February 3, 2004
    Assignee: William Marsh Rice University
    Inventors: Steven J. Oldenburg, Richard D. Averitt, Nancy J. Halas
  • Patent number: 6680081
    Abstract: A conductive powder having an organic silicon polymer layer on the surface of each particle and a metal layer enclosing the silicon polymer layer possesses a stronger bond between the particle base and the metal even at elevated temperature and exhibits a high and stable conductivity and heat resistance.
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: January 20, 2004
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Motoo Fukushima, Kunio Itoh, Shigeru Mori, Masaki Kasashima, Yoshitaka Hamada, Mikio Aramata
  • Patent number: 6680128
    Abstract: Solder compositions, solder pastes and methods of manufacturing thereof having a solder material coated with a coating material by an immersion coating process or an electroless plating process. The solder composition and solder pastes are substantially lead-free and have melting temperatures approaching those of traditional tin-lead solders.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: January 20, 2004
    Assignee: Agilent Technologies, Inc.
    Inventor: Zequn Mei
  • Patent number: 6660381
    Abstract: Metal Nanoshells having partial coverage of a substrate or core particle and methods of making them are provided. A method of making a partial metal nanoshell preferably includes asymmetrically confining a substrate particle and selectively layering a metallic material over the substrate particle according to the asymmetry. Confining the substrate particle may include attaching it to a support defining an exposed portion and a contact portion. The method may include either chemically modifying the substrate particle. The solid angle of coverage of the partial metal nanoshell may be influenced by the nature of the chemical modification, such as alternatives of activating and passivating the exposed portion.
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: December 9, 2003
    Assignee: William Marsh Rice University
    Inventors: Nancy J. Halas, Robert K. Bradley
  • Patent number: 6652968
    Abstract: A pressure activated electrically conductive polymeric matrix material that is doped with particulate filler material. Electrical conductivity is pressure activated with a change in electrical resistance; specifically, with no pressure applied, the material is at a high resistance and with pressure the resistance is materially lower. Conductive fillers may be spherical or powder substrate, such as glass, graphite, etc., having plated thereon a metal coating which is electrically conductive and which is more thermally conductive than the substrate. The polymeric matrix materials may include polyurethane, silicone, and many other synthetic or natural rubbers.
    Type: Grant
    Filed: March 22, 2001
    Date of Patent: November 25, 2003
    Inventors: Dorothy H. J. Miller, Brian L. Miller
  • Patent number: 6652773
    Abstract: A polymer dispersion composition obtained by dispersing an electrode active material and a polymer having a gel content of 50% or more in an organic dispersion medium of which boiling point at 760 mmHg is 80° C. or above. The composition is successfully usable as, for instance, a binder composition for batteries, and the battery produced therefrom is high in initial capacity and small in the drop of capacity.
    Type: Grant
    Filed: December 3, 2001
    Date of Patent: November 25, 2003
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Koichiro Maeda, Toshihiro Inoue, Haruhisa Yamamoto, Keiko Imai
  • Patent number: 6651871
    Abstract: A substrate is coated with a conductive layer, which comprises a conductive layer of bonded ultrafine metal particles formed on the top surface thereof. The ultrafine metal particles have a diameter of 1-20 nm, and the substrate is of a flexible high polymer material. Since the conductive layer is formed by bonded layer of the ultrafine metal particles, an extremely thin layer having high conductivity can be formed. This structure enables the formation of a flexible printed circuit board with high-density interconnects or a transparent conductive film provided with both transparency and conductivity. Conventional vacuum equipments and complicated processes are not necessary for forming the conductive layer on the substrate.
    Type: Grant
    Filed: November 18, 2002
    Date of Patent: November 25, 2003
    Assignee: Ebara Corporation
    Inventor: Naoaki Ogure
  • Patent number: 6645625
    Abstract: The invention relates to a stabilized, pulverulent red phosphorus material composed of phosphorus particles whose particle size is not more than 2 mm, and whose surface has been covered with a thin layer of an oxidation stabilizer, wherein the oxidation stabilizer is silver, and also to the use of the same, and to a process for its preparation.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: November 11, 2003
    Assignee: Clariant GmbH
    Inventors: Sebastian Hörold, Jürgen Laubner
  • Patent number: 6641918
    Abstract: Geldhart class C tungsten carbide particles are provided with a discontinuous coating of grain growth inhibitor. Further, the fine tungsten carbide coatings are preferably provided with a continuous coating of another discreet phase material, such as, for example, a continuous coating of cobalt. Compacts produced using such materials are particularly useful as WC—Co hardmetals wherein the compacts are extremely fine grained.
    Type: Grant
    Filed: May 30, 2000
    Date of Patent: November 4, 2003
    Assignee: Powdermet, Inc.
    Inventors: Andrew J. Sherman, Animesh Bose
  • Publication number: 20030203207
    Abstract: The invention relates to a method for coating particles and particles thus obtained. According to the inventive method, the particles that are to be coated and at least one organo-metallic complex precursor of the coating material are brought into contact with each other in a liquid containing one or several solvents, whereby said particles are maintained in a dispersion in the liquid which is subjected to temperature conditions and supercritical pressure or slightly sub-critical pressure conditions; the precursor of the coating material is transformed in such a way that it is deposited onto the particles, whereupon the liquid is placed in temperature and pressure conditions so that it can eliminate the solvent in a gaseous state. The invention can be used to coat nanometric particles in particular.
    Type: Application
    Filed: April 24, 2003
    Publication date: October 30, 2003
    Applicant: Centre National de la Recherche Scientifique
    Inventors: Vincent Pessey, Francois Cansell, Bernard Chevalier, Francois Weill, Jean Etourneau
  • Patent number: 6599608
    Abstract: Substantially spherical magneto-plumbite ferrite (barium or strontium ferrite) particles are formed from well-dispersed ultra-fine substantially spherical iron-based oxide and/or hydroxide particles as precursor particles. The precursor particles are mixed with a colloidal barium or strontium carbonate (BaCO3 or SrCO3), and with small amounts of a byproduct, such as sodium or potassium chloride (NaCl or KCl) or hydroxide (NaOH or KOH) or nitrate (NaNO3 or KNO3), functioning as a flux to lower the calcination temperature. The particles are filtered out of the mixture, dried, and calcined for a time sufficiently long and/or at a temperature sufficiently high to form magneto-plumbite ferrite from the precursor particles, and for a time sufficiently short and/or a temperature sufficiently low to maintain the general spherical shape of the precursor particles.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: July 29, 2003
    Assignee: Idaho Research Foundation, Inc.
    Inventors: Yang-Ki Hong, Hong Sik Jung, Patrick R. Taylor
  • Patent number: 6596342
    Abstract: A method of coating of mass-produced bulk goods (5) including loading the bulk goods (5) into a rotatable drum (1) through an opening (4) formed in a side surface of the drum (1), heating a coating material in coating apparatus (8), having a spray gun (6) and provided outside of the rotatable drum (1); and thereafter, applying the heated coating material to the bulk goods (5) with the spray gun (6) through the drum opening (4).
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: July 22, 2003
    Assignee: Hilti Aktiengesellschaft
    Inventors: Rainer Batliner, Gerald Felder, Werner Schörghofer
  • Patent number: 6592935
    Abstract: A method of manufacturing electric machines comprised of geometrically patterned arrays of permanent magnets, soft magnetic materials, and electrical conductors deposited by kinetic spraying methods directly atop a carrier. The magnets and planar coils of the present invention may be integrally formed atop carriers to form electrical machines such as motors, generators, alternators, solenoids, and actuators. The manufacturing techniques used in this invention may produce highly defined articles that do not require additional shaping or attaching steps. Very high-purity permanent and soft magnetic materials, and conductors with low oxidation are produced.
    Type: Grant
    Filed: May 30, 2001
    Date of Patent: July 15, 2003
    Assignee: Ford Motor Company
    Inventors: Franco Leonardi, John Matthew Ginder, Robert Corbly McCune
  • Patent number: 6592938
    Abstract: The invention relates to a method for coating particles thus obtained. According to the inventive method, the particles that are to be coated and at least one organo-metallic complex precursor of the coating material are brought into contact with each other in a liquid containing one or several solvents, whereby said particles are maintained in a dispersion in the liquid which is subjected to temperature conditions and supercritical pressure or slightly sub-critical pressure conditions; the precursor of the coating material is transformed in such a way that it is deposited onto the particles, whereupon the liquid is placed in temperature and pressure conditions so that it can eliminate the solvent in a gaseous state. The invention can be used to coat nanometric particles in paticular.
    Type: Grant
    Filed: October 1, 2001
    Date of Patent: July 15, 2003
    Assignee: Centre National de la Recherche Scientifique
    Inventors: Vincent Pessey, François Cansell, Bernard Chevalier, François Weill, Jean Etourneau