Abstract: A composition comprising: (1) a susceptor of magnetically coupled radio frequency energy comprising a non-magnetic particulate substrate, e.g., an electrically insulative material in particulate form, bearing a thin magnetic coating, e.g., a magnetic inorganic film, and (2) a matrix that is substantially non-reflective of radio frequency energy, e.g., silicone rubber, which matrix can be heated upon the composition's being subjected to magnetically coupled radio frequency energy. It has been discovered that thin magnetic coatings on non-magnetic particles provide energy transfer with induction heaters equal to or better than many commonly used solid susceptor particles. It has also been discovered that the temperature of the composition of this invention can be regulated so as not to exceed a predetermined temperature.

Abstract: The invention is a method for making a metal containing article, comprising the steps of: providing a layer of a porous ground in a selected area; exposing selected regions of the layer of porous ground to light, thereby metallizing the selected regions; repeating the foregoing steps a selected number of times to produce a selected number of layers; and selectively modifying the metallized regions of the layers. The initial metallization can be by electroless or semiconductor photo deposition plating. The subsequent modification of the metallized regions can be by electroless plating, electroplating or sintering. It is also possible, in some instances, to forego the second phase modification, the initial phase having provided the desired parameters. In a third preferred embodiment, the invention is a method using an initial metallization phase effected by exposure of a metal salt, such as a metal halide, to light, thereby inducing activation of the halide.

Abstract: A doped magnetic iron oxide particle suitable for use in magnetic recording media, and methods of preparing the doped magnetic iron oxide particle, are disclosed. The doped magnetic iron oxide particle has the general formula:Co.sub.x Fe.sup.+2.sub.1-x Fe.sub.2.sup.+3 O.sub.4, wherein O<x.ltoreq.1,wherein essentially all of the cobalt(II) and iron(II) dopants are present in a shell surrounding a core of a magnetic iron oxide particle. The doped magnetic iron oxide particle has a narrow switching distribution, high squareness, high coercivity and high remanence.

Abstract: Hollow microspheres produced by the present method each have a hollow interior evacuated of gases to a predetermined pressure. A reflective material layer coats the exterior of each microsphere and, optionally, an outer layer of a protective material is applied over the reflective material layer. Permeant gases are dissolved into glass or plastic frit particles prior to heating of the frit particles to form hollow microspheres having the permeant gases contained therein. The permeant gases are subsequently out-permeated in a non-permeant gas atmosphere to substantially evacuate the interior of each microsphere. The exterior layers of reflective material and protective material are then coated about each evacuated microsphere.

Abstract: A particle of an inorganic or metallic material which is coated on the surface with ultrafines of an inorganic or metallic material. The coated particle is produced by introducing the particles of the inorganic or metallic material to be coated into a stream carrying the ultrafines of the inorganic or metallic material formed in a vapor phase and bringing the particles to be coated into contact with said ultrafines in a fluidized state. The coated particles are used for the production of a sintered product.

Abstract: A method for producing microcomposite powders for use in superconducting and non-superconducting applications.

Abstract: A method of manufacturing an Ni--Al intermetallic compound matrix composite comprising steps of a) providing an aluminum powder, b) providing a reinforced material, c) providing a reducing solution containing a reducing agent and nickel ions to be reduced, d) adding the aluminum powder and the reinforced material into the reducing solution, and e) permitting the reducing agent to reduce the nickel ions to be respectively deposited on the aluminum powder and the reinforced material. Such method permits the Ni--Al, Ni--Al+B intermetallic compound matrix composite to be produced inexpensively/efficiently/fastly.

Abstract: A process of coating the internal surface of a hollow body by depositing a coating on a substrate having an external surface similar to the internal surface of the hollow body; inserting the coated substrate to mate within and contact the internal surface of the hollow body; and then removing the substrate while leaving the coating secured to the internal surface of the hollow body.

Abstract: Particles including a first material and having a first value of an intrinsic property such as thermal conductivity or coefficient of thermal expansion are coated, by a method such as electroless plating, electrolytic plating, sputtering, or spraying, with a second material having a second value of the intrinsic property in approximately the ratio of volume of coating to volume of each of the particles which makes the value of the intrinsic property of each of the coated particles equal to a desired value. The first and second materials can be metal or non-metal. A plurality of particles, including the coated particles, can be consolidated to form an article, or the particles and a matrix material can be co-deposited on a surface as a coating by a method such as electrolytic plating.

Abstract: A process for producing finely divided 20 to 500 angstrom metal particles, metals with oxide coatings or metal oxides using an alkalide or electride in a non-reactive solvent is described. The process produces various forms of the metal depending upon the oxidizability of the metal initially produced by the process. The process is useful for producing catalysts, alloys, colloidal solutions, semi-conductors and the like.

Abstract: Disclosed herein are magnetic composite iron oxide particles comprising spinel-type Fe.sub.3 O.sub.4 particles as core particles and spinel-type CoFe.sub.2 O.sub.4 outerlayer of the composite iron oxide particles, a process for producing the same, and a magnetic recording medium comprising a substrate and a magnetic recording layer containing the said magnetic iron oxide particles.

Abstract: A novel inorganic particulate powder coated with an organic polymer is claimed. The product is obtainable by dispersing in water inorganic particles at a pH higher than their isoelectric point in the presence of a polymeric polybasic acid as a dispersing agent to produce particles having a modified isoelectric point. The pH of the dispersion is then adjusted to a value below 9 but above the modified isoelectric point and an ethylenically unsaturated monomer is polymerized in the presence of the dispersion so as to coat the inorganic particles with polymerized monomer. A method for forming the particles is also claimed.The particles prepared by the method have been shown to be uniformly and discretely coated with an organic polymeric coating and can be used in many applications where it is desired to disperse inorganic particles in organic media such as paints, inks and plastics compositions.

Abstract: Zinc-compatible silica particulates, useful for the formulation of a wide variety of improved dentifrice compositions, have an effective compatibilizing amount of zinc values chemically bonded to surface area sites of the particles.

Abstract: A film-forming polyester derived from a monohydric alcohol component having one or more long chain alcohols, the alcohol forming from 5 to 60% by weight of the components from which the polyester is derived. Coating compositions including the polyesters are particularly suitable for applying to cans before the cans are subjected to a spin-necking operation.

Abstract: A process for preparing silane metal oxides comprising reacting a metal oxide with an amine compound to form an amine metal oxide intermediate, and subsequently reacting said intermediate with a halosilane.

Abstract: A simple process for achieving very active passivation of metal pigments against hydroxyl-containing compounds comprises treating the metal pigments with passivators in the gas phase.

Abstract: A method is provided for incorporating lubricant and a sintering aid into a metallurgical powder composition of iron-based powders. A particulate iron-based powder is contacted and wetted with solution of a metal salt of a fatty acid in an organic solvent. The solvent is removed to provide iron-based particles having a coating of the metal salt. The resulting self-lubricated powder composition can be compacted and sintered to produce a compact having superior strength properties.

Abstract: An immunoassay method using magnetic particles comprising a core and a coating layer on the surface thereof, The core comprises an organic polymer and the coating layer comprises an iron oxide type ferrite coating layer. An antigen or an antibody is bound onto the surface of the coating layer and the particle has a particle size of 0.2 to 3 .mu.m.

Abstract: A metal-coated particle is prepared by providing a disintegrator apparatus with a working chamber containing counter-rotating disks equipped with teeth design to accelerate particles towards one another, providing a first material and a second metal as powders, such that the first material is harder than the second metal and introducing the first material and second metal powders into the working chamber of the disintegrator apparatus, whereby the soft second metal collides with the hard material and is coated onto the surface of the hard first material. A metal-coated metal with an intermetallic interface is prepared by introducing a first material and a second metal as powders into a disintegrator working chamber containing counter-rotating disks and teeth designed to accelerate particles towards one another. The first material harder than the second metal and is capable of reacting with the second metal to form an intermetallic compound.

Abstract: Processes for coating substrates, in particular substrates including shielded surfaces, with zinc oxide-containing coatings are disclosed. Such processes comprise contacting a substrate with a zinc oxide precursor, preferably maintaining the precursor coated substrate at conditions to equilibrate the coating, and then oxidizing the precursor to form a substrate containing zinc oxide. Also disclosed are substrates coated with zinc oxide-containing coatings for use in various applications.

Abstract: Non-amalgamated zinc alloy powder is prepared by admixing zinc alloy powder with a predetermined amount of indium and heating the resulting mixture at temperature ranging from 160.degree. C. to 200.degree. C. in inert gas atmosphere.

Abstract: Composite electroluminescent phosphor particles may be made by forming, on a substrate, a composite layer comprising at least one layer of a dielectric or conductive material and at least one layer of an electroluminescent phosphor, physically removing the composite layer from the substrate, and pulverizing the composite layer to obtain composite electroluminescent phosphor particles.

Abstract: Processes for coating substrates, in particular substrates including shielded surfaces, with iron oxide-containing coatings are disclosed. Such processes comprise contacting a substrate with an iron oxide precursor, preferably maintaining the precursor coated substrate at conditions to equilibrate the coating, and then oxidizing the precursor to form a substrate containing iron oxide. Also disclosed are substrates coated with iron oxide-containing coatings for use in various magnetic applications.

Abstract: Processes for coating substrates, in particular substrates including shielded surfaces, with copper oxide-containing coatings are disclosed. Such processes comprise contacting a substrate with a copper oxide precursor, preferably maintaining the precursor coated substrate at conditions to equilibrate the coating, and then oxidizing the precursor to form a substrate containing copper oxide. Also disclosed are substrates coated with copper oxide-containing coatings for use in various applications.

Abstract: Purple pigments based on glass frits having an average particle diameter (D.sub.50 value) of 0.5 to 50 .mu.m, of which the surface has a coating of essentially 0.05 to 5% by weight, based on the pigment, of colloidal gold and, if desired, color-modifying metals from the group consisting of Ag, Cu, Co, Ni, Sn, Ru, Rh, Pd, Os, Ir and Pt in a total quantity below that of the gold. The purple pigments do not require the hitherto necessary calcination step and can be used for pigmenting glazes, enamels, glass colors, decorative colors, plastics, printing inks and lacquers.

Abstract: A method of producing an absorbent composition. A polymeric material characterized as having surface anionic reactive sites is mixed with a source of multivalent metal ions to render the polymeric material sorbent of aqueous liquids. A dispersant is then added to form a wet slurry which is subsequently dried to a granular consistency.

Abstract: Methods for manufacturing compressible and sinterable metal-coated metal powders are provided by this invention which include contacting core metal particles with a sol of a precursor of a coating metal. The sol has a viscosity of from about 10-10.sup.4 centipoise and comprises at least 1.0 weight percent of the precursor in a liquid medium. The final coating is produced by removing the liquid from the sol and then converting the precursor to form a substantially uniform layer of the coating metal on the surfaces of the core metal particles.

Abstract: In situ formation of metal-ceramic oxide microstructures is carried out on a starting oxide phase containing at least a most noble metallic component (e.g., iron) and a least noble metallic component (e.g. manganese) and subjecting the starting oxide phase to a temperature and oxygen partial pressure and for a time period to cause reduction of only part of the most noble metallic component to elemental metal.

Abstract: There is disclosed a method for forming a ferrite coatings on a substrate, which comprises:(a) bringing a substrate into contact with water or an aqueous solution, and(b) adding a ferrous ion solution, an oxidizer solution and a pH controller so that pH and an oxidation-reduction potential may be included within the range specified by A (6, -440 mV), B (6, -130 mV), C (11, -430 mV) and D (11, -740 mV) in a pH - oxidation-reduction potential graph.

Abstract: A titanium oxide-coated chromatic-color metal flake pigment is prepared by hydrolyzing an organic titanate ester compound, e.g., tetraisopropoxy titanium, in the presence of the base metal flakes suspended in an organic medium having a pH of 4 to 8. The pigment exhibits iridescent color tones of great aesthetic value delicately varying depending on the thickness of the titanium oxide coating layer. The pigment has high chemical stability, for example, against acids, by virtue of the very uniform and dense coating layer of titanium oxide so that the inventive pigment is useful as a coloring agent in a water-borne composition.

Abstract: A method of manufacturing microspherules from activated carbon, including placing active-carbon particles of less than 100 .mu.m in size in a pelletizer equipped with a vortexer, incrementally adding an aqueous dispersion of a water-insoluble synthetic resin until microspherules of the desired size form, turning off the vortexer but allowing the pelletizer to continue operating, immediately powdering the microspherules off, and drying the microspherules.

Abstract: Processes for coating substrates, in particular substrates including shielded surfaces, with tin oxide-containing coatings are disclosed. Such processes comprise contacting a substrate with a tin oxide precursor, preferably maintaining the precursor coated substrate at conditions to equilibrate the coating, and then oxidizing the precursor to form a substrate containing tin oxide. Also disclosed are substrates coated with tin oxide-containing coatings.

Abstract: A method for manufacturing a heat transfer surface is disclosed wherein the surface of powder or string-shaped copper core material is coated with a coating material of a nickel compound or silver so as to form a coat treatment material which is deposited on a substrate. The coating material has a lower fusing point than the core material, and the coat treatment material is heated to a temperature between the fusing points of the core material and the coating material such that only the coating material is caused to fuse to the substrate so as to form a porous heat transfer material which exhibits improved bending strength.

Abstract: This invention relates to a method for eliminating the grayish discoloration which commonly develops when lead-free and cadmium-free glass frits are applied to substrates utilizing an organic medium and thereafter fired to fuse the frit particles into a glaze. The grayish discoloration contains a carbonaceous residue from the organic medium. The method comprises the four general steps:(1) adsorbing a coating of a strongly oxidizing metal ion species onto the surface of the frit particles;(2) mixing the coated frit particles with an organic medium;(3) applying that mixture to a substrate; and(4) firing the mixture to eliminate the organic medium and to oxidize the carbonaceous residue while fusing the frit particles into a glaze.

Abstract: Ferromagnetic metal particles the surface layer of which comprises laminatedly covered films of a ferrite compound having a spinel structure of at least one metal selected from cobalt, zinc, manganese, aluminum, chromium, nickel and copper and iron and a preparation process thereof.The particles can be used as a high density magnetic recording medium.

Abstract: A magnetic metal powder, having a large specific surface are, a high coercive force, a high dispersibility and an excellent corrosion resistance, is produced by converting an aciculate goethite having a silicon and/or aluminum compound layer formed thereon or an aciculate goethite modified with a metal other than iron into magnetite, forming thereon a nonferrous transition metal compound layer, further forming thereon a silicon or aluminum compound layer, and reducing the coated magnetite to prepare a magnetic metal powder mainly composed of iron and having on the surface thereof a layer containing a nonferrous transition metal element, characterized in that the formation of the silicon and/or aluminum compound layer on the aciculate goethite and/or the formation of the nonferrous transition metal layer on the magnetite are conducted while conducting dispersion by means of a disperser.

Abstract: Silver-coated copper-based powders are prepared by the steps of dispersing copper powders in a chelating agent solution, adding a silver ion solution to the resulting dispersion to effect a substitution type of deposition reaction and, then, adding a reducing agent to the resulting solution to effect a reduction type of deposition reaction, thereby forming silver coats on the surfaces of the copper powders, wherein the chelating agent solution is prepared in two portions, a first portion thereof being prepared before the addition of the silver ion solution and a second portion thereof being added during the addition of the reducing agent, or in three portions, a first portion thereof being prepared before the addition of the silver ion solution, a second portion thereof being added during the addition of the reducing agent and a third portion thereof being added at the time of the completion of the reaction.

Abstract: Metallic objects such as conductive metal powders comprising metal such as copper, nickel, silver, cobalt and palladium can be treated to remove surface oxide layers by contacting with a combination of a chelating amine compound and a reducing catechol derivative at elevated temperature, preferably in a solution of ethylene glycol.

Abstract: A metal fuel for producing power for propulsion is disclosed. The fuel is made up of a metal core, a metal barrier and an oxidizer layer. The combination of materials disclosed provides a means for melting the metal core so that it can be oxidized in an exothermic reaction to produce power. The metal fuel may also be stabilized with respect to auto-ignition by adding a binder layer. A method for producing the metal fuel is also described herein.

Abstract: A method of providing silver on a calcium carbonate material having fine pores, such as coral sand, oyster shells, and crab shells, including (a) contacting a calcium carbonate material with an aqueous solution of silver nitrate for a time effective for the silver nitrate to react with the calcium carbonate to form silver carbonate on the surface of the calcium carbonate material; (b) dewatering the calcium carbonate material after step (a); and (c) treating the calcium carbonate material after step (b) in an aqueous solution containing from 5 to 15 weight % of a reducing agent selected from the group consisting of ascorbic acid, a derivative of ascorbic acid, erythrobic acid, and a derivative of erythrobic acid to reduce the silver carbonate on the surface of the calcium carbonate to silver. Preferably contacting is by injection of an upward stream of the aqueous solution of silver nitrate through a layer of the calcium carbonate material.

Abstract: Finely divided silicon carbide materials, particularly powders, whiskers and short fibers, are provided with a titanium nitride surface coating by the process of (i) placing a low carbon diffusivity layer atop the silicon carbon, (ii) placing a titanium metal coating atop the low carbon diffusivity layer, and (iii) nitriding the titanium metal.

Abstract: The method of preparing metal-coated metals includes providing a metal powder and a disintegrator with a working chamber equipped with counter-rotating disks. At least one of said disks is made of a material softer than said metal powder. The metal powder is introduced into the working chamber and the disks of the disintegrator are counter-rotated so as to cause the metal powder to strike the disks, whereby the disk is eroded by the colliding metal particles and a coating of the eroded material is formed on the metal powder and the metal-coated metal particles are collected at the exit end of the disintegrator.

Abstract: A method of toughening a fiber/matrix ceramic composite consisting of non-oxide based ceramic fibers immersed in a ceramic matrix. The method includes, prior to immersing the fibers in the matrix, applying a metallo-organic solution of a noble metal to the fibers to form a coating of the solution on the fibers, evaporating the solvent from the solution and oxidizing the residual organic compounds whereby the coating becomes a pure noble metal and immersing the coated fibers in the matrix. The applying, evaporating, oxidizing and immersing steps are characterized by a limited raising of the temperature of the fibers. The coating is ductile so as to blunt advancing cracks in the matrix.

Abstract: Antimicrobial powders are obtained by suppporting at least one antimicrobial metal of copper, zinc and alloys thereof on the surface of hydrous titanium oxide or titanium oxide particles by electroless plating, vapor deposition, compression mixing, mixing and reducing, and thermal decomposition of a compound. These powders are used to provide antimicrobial resin compositions, antimicrobial rubber compositions, antimicrobial glass compositions and antimicrobial coating compositions.

Abstract: An SiC whisker-reinforced Si.sub.3 N.sub.4 composite material comprising a sintered body of an Si.sub.3 N.sub.4 matrix having dispersed therein SiC whiskers, wherein said SiC whiskers are uniaxially orientated; a process for producing an SiC whisker-reinforced Si.sub.3 N.sub.4 composite material which comprises mixing (1) SiC whiskers having a coating comprising an oxide of at least one metallic element selected from the group consisting of Be, Mg, Ca, Sr, and Ba of the group 2A; Sc, Y, and La of the group 3A; Ti, Zr, and Hf of the group 4A; and Li, Al, and Si with (2) Si.sub.3 N.sub.

Abstract: A method for diffusion coating a workpiece with chromium (Cr), silicon (Si), aluminum (Al), or boron (B) by placing coated ceramic alumino-silicate fibers next to the workpiece and heating to diffuse the diffusion coating into the workpiece. A ceramic carrier is fabricated from the alumino-silicate fibers woven into a predetermined fashion. Alternately the ceramic carrier may be an elongated ceramic carrier. The aqueous diffusion coating composition is applied to the ceramic carrier and then the ceramic carrier is heated at a temperature of between about 150.degree. F. to 250.degree. F. prior to positioning the ceramic carrier proximate a surface of the workpiece. The ceramic carrier and the workpiece are subjected to an elevated temperature in a controlled environment for a sufficient time to cause at least one diffusion element to diffuse into the workpiece to provide the diffusion coating for the external, the internal, or both surfaces of the workpiece.

Abstract: Powder which has primary particle size of not larger than 10 .mu.m and is formed of mixture of Ni powder and Cr powder added with hard particles containing carbide is mixed with Cr.sub.3 C.sub.2 powder and granulated and sintered, whereby flame spraying powder having secondary particle size of 5 to 53 .mu.m is formed. The flame spraying powder thus formed is flame-sprayed under conditions which will cause fused Ni.Cr to cover Cr.sub.3 C.sub.2 particles which are not fused, thereby binding the Cr.sub.3 C.sub.2 particles and causes the thickness of one Ni.Cr layer to be smaller than 5 .mu.m. In this manner, flame spray coating the porosity of which is not larger than 2% and the hardness of which is not lower than 700 (Hv: 200 g) can be obtained.

Abstract: Solids that are subject to a deleterious reaction with a dispersion medium in which they are suspended can be safely comminuted in that dispersion medium by providing therein a surfactant capable of reacting with the solid at a faster rate than the dispersion medium can so react to thereby suppress the deleterious reaction. In particular, unsintered silicon nitride or silicon carbide which when contacted with water would decompose to form silica on their surfaces can be milled in water, without producing excessive amounts of silica. The dispersions produced are sufficiently stable to be filtered through openings of 2 microns with loss of no more than 5% of the silicon nitride or carbide. Stable dispersions of solids in liquids can be coated with a different solid by surface precipitation under conditions which preclude the formation of a bulk precipitate.

Abstract: A process for silver coating superconducting ceramic powder by(1) mixing AgNO.sub.3 with the superconducting ceramic powder particles;(2) melting the AgNO.sub.3 so that it wets and forms a uniform coating over he surfaces of the particles; and(3) decomposing the AgNO.sub.3 to form a thin, uniform coating of silver metal on the surfaces of the particles.The product is a loose powder of superconducting ceramic particles which are uniformly coated with silver metal. The powder can be cold worked (e.g., swaged, forged, etc.) to form superconducting structures such as rods or wires.

Abstract: A process for preparing a diamond particle/silver metal matrix composite ucture by coating diamond particles with molten silver nitrate, decomposing the silver nitrate to form a silver metal coating on the surfaces of the diamond particles, consolidating the silver metal coated diamond particles into a composite structure having continuous pores between the silver metal coated diamond particles, infiltrating the continuous pores of the composite with molten silver nitrate and decomposing the silver nitrate to form silver metal which fills the continuous pores of the composite structure.