Abstract: A fluorine-containing resin molded article can be obtained by putting it between smooth molds having a surface roughness (Ra) of not more than 50 .ANG. and compression-molding it under molding conditions of a molding temperature of 270.degree. to 340.degree. C., a molding pressure of not less than 10 kg/cm.sup.2 and compression time of not less than 2 minutes, to give smoothed fluorine-containing resin molded article having a surface roughness of not more than 500 .ANG.. Particles, metal impurities, organic impurities or the like are difficult to adhere to the surface of the article, and can be removed significantly by washing.

Abstract: A metal article is protected from corrosion under prolonged exposure to normal ambient atmospheric conditions which cause such corrosion by coating the metal article, optionally in the presence of an adherent organic resinous coating, which comprises treating the metal with an effective amount of effective amount of one or more hydrocarbyl-substituted sulfonyl amido diphenylamine compounds for the corrosion protection of the metal article. These compound(s) are of the formula p-(R--SO.sub.2 --NH--C.sub.6 H.sub.4 --NH)--C.sub.6 H.sub.5, where R is a substituted or unsubstituted hydrocarbyl group selected from the group consisting of alkyl, aryl, alkaryl, aralkyl, alkenyl, and cycloalkyl. A particularly preferred compound is p-(p-toluene sulfonyl amido)-diphenylamine.

Abstract: A modification method of functional group on the surface of a pressure-sensitive adhesive by fixing a functional group to the surface of the pressure-sensitive adhesive by an interfacial contact reaction between the pressure-sensitive adhesive phase and the phase containing a functional group-containing compound.By the modification method, a functional group effective for the improvement and control of an adhesive property can stably be introduced at high density to the surface of the pressure-sensitive adhesive.

Abstract: The invention relates to a process for making the surface of polymeric substrates hydrophilic, which includes coating the surface of a polymeric substrate with a solution of a macroinitiator, wherein the macroinitiator includes a polymer framework and side chains attached to the polymer framework, and wherein at least one of the side chains includes at least one free-radical-forming group. Optionally, a hydrophilic vinyl monomer or monomers may then be free-radical polymerized or graft polymerized onto the macroinitiator-coated substrate. A crosslinking vinyl monomer may optionally be used together with the macroinitiator or the hydrophilic vinyl monomer. The invention also relates to polymeric substrates having hydrophilic surfaces obtained by the process, and articles that include the hydrophilic polymeric substrates.

Abstract: A time and labour saving multiple coating system for porous substrates which involves the application of a mono or poly isocyanate catalysed UV curable acrylate composition in such circumstances as to penetrate at least part of the surface of the substrate, at least a partial surface curing of the applied composition prior to any substantial degree of self curing, and thereafter applying (whether subsequent to any sanding or not) a further surfacing composition which preferably also is an acrylate composition that is both self curing and UV curable.

Abstract: An oil-based ink for a printing plate by an ink jet process comprising spraying an oil-based ink comprising at least resin particles dispersed in a nonaqueous carrier liquid having an electric resistance of 10.sup.9 .OMEGA.cm or more and a dielectric constant of 3.5 or less on an image receiving layer of a lithographic printing plate precursor dropwise from a nozzle to form an image, and then desensitizing a non-image area of the image receiving layer by a chemical reaction to prepare a lithographic printing plate, the image receiving layer being formed on a water-resistant support and comprising zinc oxide and a binding resin; and a surface of the image receiving layer having a contact angle with water of 50.degree.

Abstract: A method is provided for preparing the surface of a cyanate ester resin composite for metal plating. More particularly, a layer consisting essentially of cyanate ester resin is applied to the surface of the composite. Thereafter, the surface of the resin layer is etched, preferably by treatment with an etching solution containing either a quaternary ammonium hydroxide or a primary amine. Upon completion of the etching process, the cyanate ester resin layer may be successfully plated with metal. The method of the invention operates to improve adhesion between the cyanate ester resin composite and a subsequently-plated metal by providing the composite with a homogenous distribution of mechanical anchoring sites for a subsequently-plated metal, such that uniformity of adhesion is achieved.

Abstract: The invention relates to mixtures of preferably from 80 to 99.9% by weight, based on the mixture, of a solution S1 comprising one or more polyamidocarboxylic acids and preferably from 0.1 to 20% by weight, based on the mixture, of a solution S2 comprising one or more, preferably primary, diamines and one or more tetracarboxylic acid diesters, processes for producing polyimide coatings using such mixtures, the use of such mixtures for producing polyimide coatings, and also polyamide-coated articles obtainable using such mixtures.

Abstract: The method relates to a method comprising providing a coating of a cross-linkable polymeric substance on a transparent or translucent substrate, applying a pattern of cross-linker to said coated substrate by ink jet printing to cross-link said polymeric substance in the pattern of the crosslinker, washing the coated substrate to remove cross-linkable polymer in the area not having the pattern of cross-linker applied thereto, and applying a contrasting color layer to the hardened cross-linked polymeric material.

Abstract: Improved sprayable roof coating systems which provide immediate waterproofing of a newly-sprayed latex-based ionic roof coating by applying to the upper surface of such roof coating an ionic catalyst having a pH opposed to the pH of such roof coating, whereby such upper surface of such roof coating coagulates immediately to form a thin waterproof surface layer on such roof coating and the bottom portions of such roof coating are permitted to coagulate and bond to the underlying roof normally. Also, latex-based sprayable roof coating systems permitting use in roof mastics of recycled rubber and spray equipment for such systems which do not clog up when air spraying such recycled-rubber-containing roof mastics.

Abstract: A method for making an anti-microbial article is described, the method comprising: providing a substrate; forming a solution comprising a chelating polymer and a metal ion; depositing the solution on the substrate; drying the substrate to form a coated substrate; and adding a potentiator to the coated substrate to form the antimicrobial article. Forming of the solution comprises (A) selecting a chelating polymer from the group consisting of polyglucosamines, ethylene acrylic acid copolymers, polycarboxylic acids, and polyamines, (B) dissolving the chelating polymer in acid to form an acidic solution, (C) preparing an aqueous solution of the metal ion, preferably by selecting a salt of the metal ion and dissolving the salt in water, and (D) combining the aqueous solution of the metal ion and the acidic solution.

Abstract: The invention is directed to medical devices having a drug-releasing coating and methods for making such coated devices. The coating permits timed or prolonged pharmacological activity on the surface of medical devices through a reservoir concept. Specifically, the coating comprises at least two layers: an outer layer containing at least one drug-ionic surfactant complex overlying a reservoir layer containing a polymer and the drug which is substantially free of an ionic surfactant. Upon exposure to body tissue of a medical device covered with such coating, the ionically bound drug in the outer layer is released into body fluid or tissue. Following release of such bound drug, the ionic surfactant binding sites in the outer layer are left vacant.

Abstract: The use of certain siloxane and silane materials for the conservation of organic and inorganic materials. More specifically, this invention deals with a method of impregnating organic and inorganic materials with siloxanes and silanes and ultimately curing such materials to provide preservation properties to such materials. An especially significant use of the method is to preserve and conserve ancient artifacts. The curable materials are represented by silanol containing polymers crosslinked with trialkoxysilanes.

Abstract: A printing system consisting of at least two reactive components is disclosed, in which one component is a polymer having attached at least one functional group that is reactive with an aziridine, such as a carboxyl, thiocarboxyl, sulfonic, phosphoric, epoxy, or isocyanate group or derivative thereof, and the other component is an aziridine, which printing system can be used to provide printed images of excellent quality that are wet-rub resistant and accent marker resistant. In addition to using the invention two-component system to produce printed images directly, a method for using the two-component system to develop lithographic printing plates is disclosed.

Abstract: A process for the preparation of slippery, hydrophilic polyurethane hydrogel coating compositions, and materials composed of a polymeric plastic or rubber substrate or a metal substrate with a coating of a slippery, hydrophilic polyurethane hydrogel thereon, such that the coating composition tenaciously adheres to the substrate, are disclosed. The coating compositions and coated materials are non-toxic and biocompatible, and are ideally suited for use on medical devices, particularly, catheters, catheter balloons and stents. The coating compositions, coated materials and coated devices demonstrate low coefficients of friction in contact with body fluids, especially blood, as well as a high degree of wear permanence over prolonged use of the device. The hydrogel coating compositions are capable of being dried to facilitate storage of the devices to which they have been applied, and can be instantly reactivated for later use by exposure to water.

Abstract: An improved process for forming a thin, durable coating of a perfluorosulfonated, salt- or acid-form ionomer on a selected substrate, which comprises contacting the substrate with an aqueous, surface active dispersion of the thermoplastic, sulfonyl fluoride precursor of the perfluorosulfonated, salt- or acid-form ionomer, contacting the dispersion-wetted substrate with a salt solution or a strongly ionizing acid solution of a sufficient ionic strength to cause a thin, adherent coating of the precursor particles in said dispersion to be formed on the substrate, then removing excess dispersion and excess salt or acid solution, annealing the coated substrate at an elevated temperature and thereafter converting the precursor to the desired acid or salt form ionomer.

Abstract: Improved sprayable roof coating systems which provide immediate waterproofing of a newly-sprayed latex-based ionic roof coating by applying to the upper surface of such roof coating an ionic catalyst having a pH opposed to the pH of such roof coating, whereby such upper surface of such roof coating coagulates immediately to form a thin waterproof surface layer on such roof coating and the bottom portions of such roof coating are permitted to coagulate and bond to the underlying roof normally. Also, latex-based sprayable roof coating systems permitting use in roof mastics of recycled rubber and spray equipment for such systems which do not clog up when air spraying such recycled-rubber-containing roof mastics.

Abstract: Polyesterdiols having low viscosities of less than 3500 cps, high content of non-volatile matter in excess of 96 wt %, and narrow molecular weight distribution of less than about 1.4 are prepared by esterification of one or more aliphatic dicarboxylic acids or ester derivatives thereof using at least a 1.5 molar excess of one or more aliphatic diols until an acid number of less than 20 is achieved, and stripping excess diol from the polyesterdiol reaction product. Where esterification catalyst is used, catalyst is substantially removed prior to stripping excess unreacted diol from polyesterdiol reaction product. The polyesterdiols so produced are useful as (i) curable components in thermosettable resin compositions, particularly compositions essentially free of volatile organic solvent and also containing a crosslinking agent and a reactive hardening agent: and/or (ii) useful as coatings, paints and adhesives, providing coatings with very low content of volatile organic compounds.

Abstract: The invention relates to a method of applying a nailwrap to a human nail. The method includes depositing an effective amount of a polymerization catalyst on the nailwrap, placing the nailwrap on a portion of the nail, and depositing a first layer of a monomer over the nailwrap to simulate a human nail. By depositing the polymerization catalyst on the nailwrap, polymerization of the monomer occurs from the bulk, i.e., the surface of the human nail, and proceeds to the surface of the artificial nail structure. The invention also relates to a nailwrap for use on a human nail with a monomer to support an artificial nail structure. The nailwrap includes a woven fiber and an effective amount of a polymerization catalyst embedded in the fiber to substantially polymerize the monomer.

Abstract: The present invention relates to a polyester-based photographic support comprising:a polyester film, anda coating layer formed thereon by applying a coating solution containing an aqueous polyester and an aqueous epoxy group-containing compound so as to be a dry weight ratio of 30/70 to 90/10, on at least one side of said polyester film.

Abstract: The subject of the present invention is a composition comprising:at least one masked or unmasked polyisocyanate in the form of an aqueous emulsion whose mean size is between 0.1 and 10 micrometers and preferably smaller than 2 and larger than 0.2 micrometers,at least one polyhydroxylated polymer, advantageously a polyol, in the form of a second aqueous dispersion whose mean size is between 10 and 200 nanometers.This composition is defined in that the quantity of polyol in the mixture is chosen so as to meet one of the following two constraints:the polyol content, expressed in mass per cent, is at least equal to 35-0.75R, advantageously at least equal to 40-0.75R, preferably to 45-0.75R;the polyol content, expressed in mass per cent, does not exceed 45-2R, advantageously does not exceed 40-2R, preferably 35-2Rwith R equal to the ratio of the mean size (d.sub.50) of the emulsion to that of the polyol dispersion.

Abstract: In the present invention method, the surface of articles made of acrylic polymers and methacrylic polymers are converted into thin biomimetic layers by using the process involving at least the following two steps:(a) The polymer surface is contacted, in the presence of water and for a predetermined reaction time necessary to form a continuous surface layer thinner than about 500 microns, with a solution containing one or more tetraalkylammonium hydroxides of the general formula:R.sub.1 R.sub.2 R.sub.3 R.sub.4 N.sup.+ OH.sup.-where R.sub.1, R.sub.2, R.sub.3, R.sub.4 are the alkyl substituents, in which the sum of the number of carbon atoms is equal to or larger than 8 but smaller than 45; and,(b) The article is removed from the aqueous reaction solution and excess of tetraalkylammonium hydroxide is removed from the polymer surface by washing the polymer with a liquid miscible with the tetraalkylammonium hydroxide.

Abstract: A process for producing a molecular sieve silica membrane comprising depositing a hybrid organic-inorganic polymer comprising at least one organic constituent and at least one inorganic constituent on a porous substrate material and removing at least a portion of the at least one organic constituent of the hybrid organic-inorganic polymer, forming a porous film.

Abstract: A process for forming a cured paint film from a paint containing, as a binder, a resin containing a carbonyl group, or a resin, or a resin mixture containing a carbonyl group and a carboxyl group or a paint containing, as a binder, a resin containing a resin or a resin mixture containing a group which forms a carboxyl group in the subsequent contact step with a hydrazine compound or polyhydrazide compound. The uncured paint film, which contains a carbonyl group, or a carbonyl group and a carboxyl group or a group that forms a carboxyl group, is subjected to a step of curing the paint film by allowing the uncured paint film to contact with a hydrazine compound or a polyhydrazide compound.

Abstract: Methods and derivatized supports which are useful in solid-phase synthesis of peptides, oligonucleotides or other small organic molecules as well as arrays of ligands. The methods provide means to control the functional site density on a solid support. Some of the derivatized supports are polymer-coated or glycan-coated. Other methods for regenerating the surface of a used ligand array are also provided.

Abstract: A medical device for partial insertion into a patient and navigating passageways, channels, canals, cavities, and other interior parts of said patient, said medical device comprising an elongate body having an in the body segment which, in normal use, is inserted in the body of a patient. At least a portion of the in-the-body segment is provided with a lubricious coating. The coating displays a gradient of lubricity along the length of thereof.

Abstract: A time and labour saving multiple coating system for porous substrates which involves the application of a mono or poly isocyanate catalysed UV curable acrylate composition in such circumstances as to penetrate at least part of the surface of the substrate, at least a partial surface curing of the applied composition prior to any substantial degree of self curing, and thereafter applying (whether subsequent to any sanding or not) a further surfacing composition which preferably also is an acrylate composition that is both self curing and UV curable.

Abstract: To improve the reduction in tensile strength due to aging as well as the recovery, a weak acid is applied to a glass fiber mat containing a phenolic condensation resin binder before the binder is hardened.

Abstract: The present invention relates a topcoating composition and a film-forming process by use of the topcoating composition, which are capable of forming a coated film having good weather resistance and good stain resistance. The present invention provides a topcoating composition prepared by incorporating a specified organosilicate and/or its condensate into a specified organic coating composition, a film formed from said topcoating composition being such that a surface of the film, which has been subjected to an acid treatment, shows a contact angle to water of 70.degree. or less; and a film-forming process which comprises coating said topcoating composition onto a substrate to form a film, followed by treating the surface of the film with an acid.

Abstract: The process according to the invention consists in bringing the substrate to be coated into contact with a solution of a catalyst of olefin polymerization and in then polymerizing at least one olefin in gaseous phase in the presence of the said substrate. The invention also relates to the use of an item including a coating made of polymer for coming into contact with polyolefin particles, the polymer forming the coating including chain sequences of formula --CH.sub.2 --CHR--.

Abstract: The subject of the present invention is a composition comprising:at least one masked or unmasked polyisocyanate in the form of an aqueous emulsion whose mean size is between 0.1 and 10 micrometres and preferably smaller than 2 and larger than 0.2 micrometres,at least one polyhydroxylated polymer, advantageously a polyol, in the form of a second aqueous dispersion whose mean size is between 10 and 200 nanometres.This composition is defined in that the quantity of polyol in the mixture is chosen so as to meet one of the following two constraints:the polyol content, expressed in mass percent, is at least equal to 35-0.75R, advantageously at least equal to 40-0.75R, preferably to 45-0.75R;the polyol content, expressed in mass percent, does not exceed 45-2R, advantageously does not exceed 40-2R, preferably 35-2Rwith R equal to the ratio of the mean size (d.sub.50) of the emulsion to that of the polyol dispersion.Application to organic synthesis.

Abstract: A metal article is protected from corrosion under prolonged exposure to normal ambient atmospheric conditions which cause such corrosion by coating the metal article with an adherent organic coating which does not exude corrosive acid, which comprises an effective amount of an aromatic amine compound containing a p-phenylenediamine moiety which is not an epoxy crosslinking agent but which is capable of being oxidized in air, an air oxidation product thereof, or a mixture of the amine and air oxidation product for corrosion protection of the metal article, before the coated metal article is placed in contact with such atmospheric conditions which cause such corrosion.

Abstract: A process is described for metallizing materials such as plastics, glasses, ceramics and metals, in which (a) the material to be metallized is provided with a coating which contains intrinsically conductive polymer, (b) the intrinsically conductive polymer is activated by reduction and (c) the metal is applied to the material in a non-electrochemical manner by bringing the coated material into contact with a solution containing ions of the metal.

Abstract: The invention pertains to a process for throughplating of printed circuit boards using conductive plastics for direct plating, wherein a polymer film with intrinsic electric conductivity is adhesively deposited on non-conductive areas of the printed circuit boards, whereupon a metal film is applied. Selective production of the polymer film has previously been seen as requiring an oxidative pre-treatment of the printed circuit board, though this can negatively affect the further course of the process. With the present invention the potential negative effects are avoided by forgoing the oxidation pre-treatment.

Abstract: Rubber articles are produced by applying a first latex to a former and then applying either a second latex, or a separation material followed by a latex which may be the same as, or different to, the first latex, curing both latices, and removing both layers jointly, so as to make an article with an outer translucent layer and an inner darker layer, with capillary action permitted between the layers.

Abstract: A medical device having a surface graft matrix comprising carboxyl-functional groups located on the device, the surface graft matrix comprising an outer portion; and one or more biomolecules covalently coupled to the surface graft matrix, wherein a majority of the biomolecules are located in the outer portion of the surface graft matrix. The surface graft matrix can also be loaded with a pharmaceutical agent.

Abstract: A method of preserving waterlogged materials and more specifically, preserving artifacts that have been submerged in water for long periods of time. A method of treating waterlogged materials that have been subjected to preservation techniques using polyethylene glycol as the preservative, and a method of restoring such materials from the deleterious effects of the glycol.

Abstract: Thermosetting powder coating compositions include at least one glycidic-ether containing amorphous and/or semi-crystalline copolyester and a cross-linking agent which is an aliphatic and/or cycloaliphatic polybasic acid and/or its anhydride and/or a polyolmodified anhydride of a polybasic acid and/or amorphous or semi-crystalline carboxyl-functional copolyester resins and/or carboxyl-functional acrylate resins.

Abstract: This invention provides a paint solvent mixture well suited for use in cleaning excess paint on minor paint touch-ups performed on vehicle bodies. A syringe with specialized blunt needles is used to apply paint to vehicle body paint without further marring the paint. A method for using such a syringe is also described.

Abstract: A method of making a latex article, by contacting a latex article with water, an aqueous emulsion comprising a high-density, substantially linear hydrocarbon polymer, and an acid-activated oxidizing agent or initiator, mixing in an acid to the reaction mixture to activate the oxidizing agent or initiator, then, after a first selected period of time sufficient to adhere the polymer to the surface of the article, mixing a stopping agent into the activated reaction mixture to substantially reduce or halt the oxidization and, after a second selected period of time sufficient to reduce substantially or halt oxidization, neutralizing the article with a neutralization mixture comprising water and a base.

Abstract: A process for producing a molecular sieve silica membrane comprising depositing a hybrid organic-inorganic polymer comprising at least one organic constituent and at least one inorganic constituent on a porous substrate material and removing at least a portion of the at least one organic constituent of the hybrid organic-inorganic polymer, forming a porous film.

Abstract: The present invention relates to crosslinked resin-coated silica fine particles each of which has a crosslinked resin coating formed of a structure of a single layer or a plurality of layers formed on the surface of each calcined silica fine particle through a vinyl-containing silane coupling agent, and the crosslinked resin-coated silica fine particles of the present invention have characteristic features in that the peeling of the resin coatings substantially do not occur when they are dispersed in a dispersing medium with ultrasonic vibration, and that they substantially do not move after the formation of a liquid crystal cell and substantially do not affect a liquid crystal itself and its orientation when used as a spacer for a liquid crystal display device.

Abstract: Disclosed is a method for producing a composite reverse osmosis membrane comprising the steps of coating a porous support with (A) a solution containing a compound having at least two reactive amino groups per molecule and bringing (B) a solution containing a polyfunctional acid halide into contact with the solution (A) to induce crosslinking to form a crosslinked polyamide skin layer, in which the crosslinking is carried out in the presence of a substance having a solubility parameter of 8 to 14 (cal/cm.sup.3).sup.1/2. The resulting composite reverse osmosis membrane exhibits high salt rejection and high water permeability.

Abstract: A method for coating the surface of a substrate composed of a hydrophobic polymer with a hydrophobic vinyl polymer. The method includes preparing a solution of the hydrophobic vinyl polymer in a polar nonaqueous solvent, such as 1-methyl-1-pyrrolidinone, in which the hydrophobic vinyl polymer is surface-active. The substrate then is treated with the solution under conditions sufficient to deposit the hydrophobic vinyl polymer on the substrate. The hydrophobic vinyl polymer may have readily hydrolyzable pendant groups which, upon hydrolysis thereof in an aqueous medium, will result in the formation of a hydrophilic vinyl polymer coating on the substrate. For example, the hydrophobic vinyl polymer may be poly(vinyl trifluoroacetate). Also provided are coated substrates, in which the substrate is a shaped article composed of a hydrophobic polymer. The shaped article may be, for example, a film, fiber, or nonwoven web.

Abstract: A coating method is disclosed, which comprises coating a base coating paint on a substrate, coating thereon a clear coating paint of a curing system different from that of the base coating paint in a wet-on-wet state, and then baking the resultant coatings, wherein a curing catalyst for curing the clear coating paint is incorporated into the base coating paint and wherein the curing catalyst has a boiling point of 150.degree. C. or higher, under 760 mmHg. The base coating paint comprising such a curing catalyst is also disclosed.

Abstract: A novel, improved process for forming a thin, adherent coating of a perfluorocarbon ionomer on a polymeric substrate which is typically in powdered form, fibrous form, or a mixture of powdered and fibrous forms, from a colloidal dispersion of the perfluorocarbon ionomer in a liquid medium which consists essentially of water and is substantially free of organic solvents, comprising adding a) the colloidal dispersion and b) a salt or a strongly ionizing acid to a vessel containing the polymeric substrate, and subjecting the dispersion, salt or acid and polymeric material to high shear conditions whereby a thin, durable coating of the perfluorocarbon ionomer is formed on the polymeric substrate.

Abstract: The invention relates to a method of manufacturing a substrate having a modified orientation layer and a liquid-crystalline display device comprising such a substrate. The orientation layer is made from a polymer and is modified with organic groups which induce a pretilt in the liquid-crystalline material when they are used in a liquid-crystalline display device. According to the invention, for modifying the orientation layer use is made of a precursor compound of the organic groups which is vaporized, whereafter the substrate carrying the orientation layer is exposed to the vapour formed in the process. Preferably, the orientation layer comprises hydroxyl groups such as PVA, and a carboxylic acid halogenide such as an alkyloyl chloride is used as the precursor. A further favourable combination comprises orientation layers of polyamide acid and alkylamine precursor compounds.

Abstract: A method for fabricating a water-repellent surface, including steps of preparing a mixture by mixing a curable liquid with a needle-like material, applying the mixture onto a surface of an object, curing a liquid of the applied mixture and forming an applied layer in which the needle-like material has been mixed on a base material of the cured liquid of the mixture, forming pits and projections of the needle-like material on a surface of the applied layer by etching the applied layer under a condition where an etching rate of the base material is larger than that of the needle-like material, and coating the surface of the applied layer with a water-repellent substance.

Abstract: A resin composition useful as a binder is provided comprising a mixture of a formaldehyde-based resin with a resin substitute comprising the reaction product of an amine derivative chosen from melamine, glycolurile or their mixtures with 1 to 2 moles of a C.sub.1 to C.sub.8 dialkoxyethanal, the reaction product is mixed, preferably reacted, with a polyol.

Abstract: A rubber thread includes in cross-section a first rubber portion and a second rubber portion.