Abstract: Methods for making an environmental barrier coating using a sintering aid involving: applying a bond coat layer to the ceramic component; combining at least water, and a primary transition material selected from a rare earth disilicate, or a doped rare earth disilicate to produce a transition layer slurry; applying the transition layer slurry to the bon coat layer; drying the component having the applied transition layer slurry; infiltrating a sol-gel solution including an aqueous solution of a water soluble salt sintering aid, or an organic solvent solution of a solvent soluble salt sintering aid into the applied slurry; and sintering the component to produce the environmental barrier coating having at least the bond coat layer, and a transition layer wherein during sintering a reaction between the primary transition material and the sintering aid results in the transition layer having a porosity of from 0% to about 15% by volume of the transition layer.

Abstract: A method of preparing a coating solution, comprising the steps of providing a first solution comprising a lower alcohol; a polyethylene glycol; a complexing agent; and water; providing a second solution comprising a higher alcohol; and at least one metal alkoxide, wherein the metal in said at least one metal alkoxide is selected from the group consisting of zirconium, aluminium, titanium, tantalum and yttrium; forming a sol-gel solution by mixing said first and second solutions and thereby hydrolyzing said at least one metal alkoxide to a metal oxide and an alcohol; forming a concentrated solution by removing said lower alcohol and the alcohol resulting from the hydrolysis of said at least one metal alkoxide; and forming a coating solution by adding a medium alcohol to said concentrated solution.

Abstract: In the annealing step of the method for manufacturing a piezoelectric actuator, the annealing in conducted in two steps: a first annealing step; and a second annealing step conducted at a temperature lower and for a time longer than those of the first annealing step. With such treatment, first, grain growth inside the piezoelectric film can be sufficiently induced, while minimizing the diffusion layer growth, by the first annealing step conducted at a high temperature within a short interval, and then lattice defects in the particles can be sufficiently corrected, while preventing the diffusion layer growth, by the second annealing step conducted at a temperature lower and for a time longer than those of the first annealing step. Accordingly, the piezoelectric characteristic can be improved by sufficiently conducting annealing, while restricting the thickness of the diffusion layer to a range where the piezoelectric characteristic is not affected.

Abstract: The present invention relates to an inert, non-asbestos separator and method of making same, the separator comprising an inorganic/polymer fibrid and agglomeration composite material containing from about 5 weight percent to about 70 weight percent of organic halocarbon polymer fibers together with from about 30 wt percent to about 95 weight percent of a finely divided non-organic particulate, which non-organic particulate is firmly bound in said composite fibrids and agglomerates; a natural gum thickening agent in an amount to provide a viscosity of about 6270 to about 590 cP at 0.22 sec?1; and an inert inorganic particulate powder whereby the inert inorganic particulate remains unbound from the inorganic/polymer fibrid and agglomeration composite, the inorganic particulate powder having a mean particle size of not greater than 1.0 ?m and being present in an amount to provide a ratio of polymer fiber composite to unbound inorganic particulate in a range from about 1 to 25.

Abstract: A coating system and a method for forming the coating system, the method including coating a surface of a gas turbine engine turbine component having a metallic surface that is outside the combustion gas stream and exposed to cooling air during operation of the engine. A gel-forming solution including a ceramic metal oxide precursor is provided. The gel-forming solution is heated to a first preselected temperature for a first preselected time to form a gel. The gel is then deposited on the metallic surface. Thereafter the gel is fired at a second preselected temperature above the first preselected temperature to form a ceramic corrosion resistant coating comprising a ceramic metal oxide is selected from the group consisting of zirconia, hafnia and combinations thereof. The ceramic corrosion resistant coating having a thickness of up to about 127 microns and remaining adherent at temperatures greater than about 1000° F.

Abstract: Provided is a nano structure composite and a method of manufacturing the same. More specifically, a nano structure composite that includes a substrate, a first layer formed of carbon nano structures on the substrate, and a second layer formed of metal oxide nano structures on the first layer, and a method of manufacturing the same are provided. When the nano structure composite according to the present invention is used, a device having a field emission characteristic higher efficiency than a conventional device can be realized, and also, the device can be manufactured at a lower temperature and at a lower pressure. Thus, manufacturing cost can be reduced and a large scale process can be performed.

Abstract: A process for protecting a thermal barrier coating (TBC) on a component used in a high-temperature environment, such as the hot section of a gas turbine engine. The process applies a protective film on the surface of the TBC to resist infiltration of contaminants such as CMAS that can melt and infiltrate the TBC to cause spallation. The process generally entails applying to the TBC surface a metal composition containing at least one metal whose oxide resists infiltration of CMAS into the TBC. The metal composition is applied so as to form a metal film on the TBC surface and optionally to infiltrate porosity within the TBC beneath its surface. The metal composition is then converted to form an oxide film, with at least a portion of the oxide film forming a surface deposit on the TBC surface.

Abstract: The invention relates to a process for the formation of a coating of metal oxides comprising at least one precious metal from Group VIII of the Periodic Table of the elements, optionally in combination with titanium and/or zirconium, on an electrically conductive substrate made of steel or of iron, which consists in applying a sole solution of acetylacetonate(s) of the said metal(s) dissolved in a (plurality of) solvent(s) which specifically dissolve(s) each metal acetylacetonate; and in then drying and calcining the coated substrate. The invention also relates to an activated cathode obtained from the electrically conductive substrate coated with metal oxides and to its use in the electrolysis of aqueous solutions of alkali metal chlorides.

Abstract: A constructional board has a coat formed on the surface, and is characterized in that carbodihydrazide are included on the surface of the coat and a coat layer containing colloidal silica as a main component is formed.

Abstract: Process for the preparation and the deposition of vitreous films on substrates comprising: the dissolution of one or more metal alkoxides in aprotic solvent, the hydrolysis of the resulting solution, the eventual removal of the formed alcohol, the deposition of the resulting sol on the substrate surface of interest and the final drying of the film.

Abstract: To provide a process for producing a filter catalyst which can produce a filter catalyst in which the closure of ventilation holes by a catalytic layer is inhibited.

Abstract: A mesostructured material, which has plural tubular pores and is arranged on a polymer surface, characterized in that the pores are uniaxially oriented. The mesostructured material can be developed to functional devices.

Abstract: A surface modified quartz glass crucible and a process for modifying the crucible includes a layer of a metal oxide on the whole or a part of the inside and/or outside of the crucible, and baking it. At least an inside surface of the crucible is coated with a said metal oxide of magnesium, calcium, strontium or barium. The coated layer of the crucible does not abrade easily and provides a high dislocation free ratio of silicon single crystals pulled by using the crucible.

Abstract: Dry mix for treating refractory substrates, comprising combustible particles of at least one oxidisable substance which, in the presence of oxygen, gives rise to an exothermic reaction, and particles of at least one other substance, wherein these particles form together, during said exothermic reaction, a coherent mass capable of adhering to and/or interacting with the treated substrate, characterised in that it comprises, as particles of at least one other substance, particles of at least one expanding substance, in that the dry mix without the particles of this at least one expanding substance has a first bulk density and in that the mix comprising said at least one expanding substance has a second bulk density lower than said first bulk density.

Abstract: A far infrared emitting nano glazed comprised of a mixture of 35˜65% solvent, 1˜35% solubilizing agent, 0˜25% refractory agent but not including 0%, 0.1˜5% adhesive agent, 0.5˜30% far infrared powder, and 0.5˜10% nano material, added with water to be ground into a solution with of 350±20 g/200 cc concentration and 200˜325 mesh fineness; then applied to surface of ceramic body or biscuit and then sintered at 1120° C.˜1350° C. into a finished ceramic product provided with far infrared function and nano characteristics to maintain clean, bright and attractive surface, antibiotic and activate the substance contained therein.

Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).

Abstract: A method of making and improving a coating formulation which includes a hydraulic binder. To the formulation is added a quantity of dewatering agent. The resultant slurry produced from said formulation may be applied to the product to be coated and dewatered through said product. Dewatering can be accomplished with or without vacuum assistance.

Abstract: Disclosed are processes and compositions for fabricating irradiation targets from slurry compositions using a slip casting method to form a layer of the slurry composition on a substrate. The layer of slurry is allowed to dry on the substrate to produce a green cast layer that may then be cut, milled or otherwise machined to form intermediate targets having one or more predetermined configurations. These intermediate targets are subsequently subjected to a thermal process by which organic components remaining in the green cast layer are driven off and/or oxidized to form a densified, substantially inorganic, layer that has a density below that of the primary particles.

Abstract: Provided herein are media for storing information and methods of forming such media. A strontium ruthenate (SRO) layer is provided. In certain embodiments, a titanium terminated (Ti-terminated) surface is formed on the SRO layer, and a lead zirconate titanate (PZT) layer is formed on the Ti-terminated surface. In other embodiments, a Ti-terminated surface is formed on the SRO layer, a lead titanate (PTO) layer is formed on the Ti-terminated surface, and a PZT layer is formed on the PTO layer. Preferably, the PZT layer is grown on the Ti-terminated surface, or the PTO layer, by step-flow or layer-by-layer growth, so that the resulting media has an atomically smooth surface.

Abstract: The invention relates to a glass for dental applications which can be used as a glazing material of dental restorations and resists high temperatures, and thus does not tend to flow.

Abstract: A phosphate bonded ceramic is used to provide a diffusion barrier on a titanium alloy substrate, conferring degradation (eg oxidation) resistance to the alloy. The substrate may, for example, be an aerospace component such as a part of a gas turbine engine.

Abstract: The invention relates to the production and use of a gray hue palette for decorative coatings based on a sol-gel method for glass and glass-ceramic articles, wherein flake-form pigments and solid lubricant are used in specific mass ratios as decorative pigments. The pigmentation provides a high-temperature-stable decorative layer, has good adhesive strength between the substrate and the decorative layer, has good impermeability relative to fluids and gases during use, as well as a high resistance to scratching. The invention further relates to glass or glass-ceramic articles with decorative coatings which are produced, in particular, according to the method of the invention, which are suitable particularly for use as glass-ceramic cooktops due to the named good layer properties of the decorative layer.

Abstract: A method of forming a dielectric film that includes nitrogen. The method includes incorporating nitrogen into a dielectric film using a nitridation gas and a rapid thermal annealing process, wherein an ultra-low pressure of equal to or less than about 10 Torr is used for the rapid thermal annealing process.

Abstract: The present invention relates to a titania composite membrane for separating water/alcohol mixtures and a method of preparation thereof, and more particularly to the titania composite membrane and the method of preparation thereof, wherein a surface of a porous support is modified with silica xerogel and ?-alumina sol and titania sol is coated on the modified surface to form a titania surface layer and then the obtained titania surface layer is dried and calcined to optimize performance of separation and promote thermal stability. The titania composite membrane of the present invention has excellent properties such as thermal stability, mechanical strength and good perm-selectivity for water molecule in water/alcohol mixtures due to the hydrophilic property of the titania surface layer, thus being applicable to the membrane for separating water/alcohol mixtures.

Abstract: A method of forming a turbine component that includes a ceramic matrix composite-ceramic insulation composite with a vapor resistant layer is disclosed. The method includes providing an inner tool and an outer tool, wherein the inner and outer tools define a mold for forming a turbine component. A vapor resistant layer can be applied to the inner tool, and a ceramic insulation layer can be applied over the vapor resistant layer in the mold. The vapor resistant layer and the ceramic insulation layer can be partially fired to form a bisque turbine component, and the outer tool can be removed. The inner tool can include a transitory material. A layer of ceramic matrix composite material can be applied to the outside of the bisque turbine component to form a component, and the component can be fired to form a turbine component.

Abstract: This invention relates to lead free, cadmium free, bismuth free low melting high durability glass and enamel compositions. The compositions comprise silica, zinc, titanium, and boron oxide based glass frits. The resulting compositions can be used to decorate and protect automotive, beverage, architectural, pharmaceutical and other glass substrates.

Abstract: This invention relates to lead free, cadmium free, bismuth free low melting high durability glass and enamel compositions. The compositions comprise silica, zinc, titanium, and boron oxide based glass frits. The resulting compositions can be used to decorate and protect automotive, beverage, architectural, pharmaceutical and other glass substrates.

Abstract: In certain example embodiments, a coated article includes a Zn-doped zirconium based layer before heat treatment (HT). The coated article is heat treated sufficiently to cause the Zn-doped zirconium based layer to transform into a Zn-doped zirconium oxide based layer that is scratch resistant and/or chemically durable. The doping of the layer with Zn has been found to improve scratch resistance and/or corrosion resistance.

Abstract: The invention relates to a of manufacturing a silicon dioxide layer of low roughness, that includes depositing a layer of silicon dioxide over a substrate by a low pressure chemical vapor deposition (LPCVD) process, the deposition process employing simultaneously a flow of tetraethylorthosilicate (TEOS) as the source material for the film deposition and a flow of a diluant gas that it not reactive with TEOS, so that the diluant gas/TEOS flow ratio is between 0.5 and 100; and annealing the silicon dioxide layer at a temperature between 600° C. and 1200° C., for a duration between 10 minutes and 6 hours.

Abstract: The invention relates to a corrosion resistant reactor tube, method for providing a passivating or corrosion resistant coating to the inside of the reactor tube, and a method of making high bismuth glass powders using the corrosion resistant reactor tube.

Abstract: A method of producing a silica or silica-like coating by forming a precursor formulation from oligomeric organosilicate. The precursor formulation is coated on a substrate as a continuous liquid phase. The precursor formulation is then cured in an ammoniacal atmosphere to produce a continuous, interconnected, nano-porous silica network.

Abstract: A method for forming interphase layers in ceramic matrix composites. The method forms interphase layers in ceramic matrix composites thereby enabling higher matrix densities to be achieved without sacrificing crack deflection and/or toughness. The methods of the present invention involve the use fugitive material-coated fibers. These fibers are then infiltrated with a ceramic matrix slurry. Then, the fugitive material is removed and the resulting material is reinfiltrated with an interphase layer material. The ceramic matrix composite is then fired. Additional steps may be included to densify the ceramic matrix or to increase the strength of the interphase layer. The method is useful for the formation of three dimensional fiber-reinforced ceramic matrix composites envisioned for use in gas turbine components.

Abstract: The present invention relates to (1) a transparent coating film containing a layered titanate containing an organic cation derived from amines having a boiling point of 300° C. or lower as measured under an ambient pressure, and having an atomic ratio of nitrogen to titanium of 0.01 to 0.3; and (2) a process for producing a transparent coating film having an atomic ratio of nitrogen to titanium of 0.01 to 0.3, containing the steps of applying a solution containing an organic cation derived from amines having a boiling point of 300° C. or lower as measured under an ambient pressure, and a layered titanate onto a substrate; and heat-treating the thus applied solution at a temperature less than 450°C. The coating film exhibits a high hardness, an excellent transparency, a low photocatalytic activity and an excellent stability as well as a good adhesion property to a substrate.

Abstract: An article comprising a turbine component other than an airfoil having a metal substrate and a ceramic corrosion resistant coating overlaying the metal substrate. This coating has a thickness up to about 5 mils (127 microns) and comprises a ceramic metal oxide selected from the group consisting of zirconia, hafnia and mixtures thereof. This coating can be formed by a method comprising the following steps: (a) providing a turbine component other than an airfoil comprising the metal substrate; (b) providing a gel-forming solution comprising a ceramic metal oxide precursor; (c) heating the gel-forming solution to a first preselected temperature for a first preselected time to form a gel; (d) depositing the gel on the metal substrate; and (e) firing the gel at a second preselected temperature above the first preselected temperature to form the ceramic corrosion resistant coating comprising the ceramic metal oxide.

Abstract: Disclosed is a method for producing surface-modified materials, such as core-shell materials with the core and the shell(s) being different distinct phases, or materials with a concentration gradient of one or more dopant or substituent element(s) from the surface to the bulk. The method comprises (i) treating the bulk of material with a solution containing a first solvent and at least one flocculant comprising a soluble polymer so that the flocculant adheres to the bulk; (ii) subsequently contacting the flocculant-treated bulk of step (i) with a dispersion containing a second solvent and the particulate solid particles to deposit the particulate solid particles on the flocculant-treated bulk; and (iii) subsequently treating the resultant of step (ii) with heat. This method can in particular be applied to produce surface-modified cathode materials for Li batteries with improved performance.

Abstract: The invention concerns a composite material consisting of intermetallic phases and ceramic, in particular in the form of a coating on metallic substrates, as well as an arc wire spraying process for production of the composite material in which the intermetallic phases and the ceramics to be deposited are newly formed during the deposit process from the components of the supplied wires by chemical reaction. The invention further concerns wear resistant layers formed by the composites, tribologic layers and plating or hard-facing materials.

Abstract: Methods and apparatus provide for: applying an inorganic barrier layer to at least a portion of a flexible substrate, the barrier layer being formed from a low liquidus temperature (LLT) material; and sintering the inorganic barrier layer while maintaining the flexible substrate below a critical temperature.

Abstract: A method of forming a hydrogen transport membrane to separate hydrogen from a hydrogen containing feed in which a porous ceramic support is formed to support a dense layer of palladium or an alloy of palladium serving as a hydrogen transport material. Isolated deposits of palladium, a palladium alloy or a component of such alloy are produced on a surface of the porous ceramic support that bridge pores within the porous ceramic support without penetrating the pores and without bridging regions of the surface defined between the pores. The isolated deposits of the metal are produced by an electroless plating process.

Abstract: A method of depositing a crystalline ?-Al2O3 layer onto a cutting tool insert by Chemical Vapor Deposition at a temperature of from about 625 to about 800° C. includes the following steps: depositing a from about 0.1 to about 1.5 ?m layer of TiCxNyOz where x+y+z>=1 and z>0, preferably z>0.2; treating said layer at 625-1000° C. in a gas mixture containing from about 0.5 to about 3 vol-% O2, preferably as CO2+H2, or O2+H2, for a short period of time from about 0.5 to about 4 min, optionally in the presence of from about 0.5 to about 6 vol-% HCl; and depositing said Al2O3-layer by bringing said treated layer into contact with a gas mixture containing from about 2 to about 10 vol-% of AlC3, from about 16 to about 40 vol-% of CO2, in H2 and 0.8-2 vol-% of a sulphur-containing agent, preferably H2S, at a process pressure of from about 40 to about 300 mbar. Also included is a cutting tool insert with a coating including at least one ?-Al2O3-layer.

Abstract: In certain example embodiments, a coated article includes respective layers including hydrogenated diamond-like carbon (DLC) and zirconium nitride before heat treatment (HT). During HT, the hydrogenated DLC acts as a fuel which upon combustion with oxygen produces carbon dioxide and/or water. The high temperature developed during this combustion heats the zirconium nitride to a temperature(s) well above the heat treating temperature, thereby causing the zirconium nitride to be transformed into a new post-HT layer including zirconium oxide that is very scratch resistant and durable.

Abstract: A glass ceramic self-supporting film that includes silica (SiO2) matrix glass and fine crystalline zirconia (ZrO2) particles dispersed in the matrix glass. A process for production of a glass ceramic self-supporting film wherein the process includes the steps of combining a colloidal silica sol having a pH of 4 or less, a zirconium-containing compound and an organic binder to produce a mixture, coating the mixture onto a base material, drying the mixture on the coated base material to form a precursor film on the base material, releasing the precursor film from the base material, and firing the released precursor film.

Abstract: The present invention is characterized in that a base material is coated with a ceramic thin film comprising a composite phase composed of a first phase mainly formed of a silicon ceramic component and a second phase mainly formed of a ceramic component other than the silicon ceramic component of the first phase, in which the amount of fine crystal particles of at least one ceramic component that constitutes the second phase slopingly increases toward a surface layer. According to the present invention, there are provided a ceramic thin film coating material having a slope constitution, which not only has an excellent function such as a photocatalyst function, an electrical function, a thermal catalyst function or a catalyst-supporting function or environment resistance such as oxidation resistance, alkaline resistance or wear resistance but also has excellent dynamic properties, and a process for the production thereof.

Abstract: A method for modification of glass-based microchannels, which uses liquid organic-based solution containing siloxane for the modification of microchannels on the glass substrate, such as quartz, boron glass, sodium glass, and the like, to form a solid film to isolate the glass surface of the microchannels from the environment. Therefore, the present invention can be applied for electrophoresis experiment, so that the operation causes no electrical-double-layer effects, and further eliminates the occurrence of electro-osmosis flow, thus the separation efficiency of electrophoresis chips is improved.

Abstract: Thick film magnetic/insulating nanocomposite materials, with significantly reduced core loss, and their manufacture are described. The insulator coated magnetic nanocomposite comprises one or more magnetic components, and an insulating component. The magnetic component comprises nanometer scale particles (about 1 to about 100 nanometers) coated by a thin-layered insulating phase. While the intergrain interaction between the immediate neighboring magnetic nanoparticles separated by the insulating phase provides the desired soft magnetic properties, the insulating material provides high resistivity, which reduces eddy current loss.

Abstract: A method for producing a ceramic coating of metallic and/or ceramic surfaces and products in reactors, process plants and combustion plants includes applying a mixture of fine-particle boron nitride, at least one inorganic binding agent of medium particle size in the nanometer range, containing substantially Al2O3, AlO(OH), ZrO2, Y—ZrO2, TiO2, Fe2O3 and/or SnO2 or an associated precursor compound and at least one solvent and/or water onto a metallic and/or ceramic surfaces or product, and burning the applied mixture into a coating through heating.

Abstract: Provided is a method for synthesising a substantially size homogenous composition of titanium (IV) oxide (titania) nanoparticles comprising, synthesising a titania inorganic crystalline matrix within a sol gel reaction process under conditions that constrain the growth of the matrix such that a majority of the nanoparticles are of a narrow size distribution in the composition and do not exceed a maximum diameter of around 100 nm. The sol gel reaction process can occur under aqueous conditions, or within an organic polymer matrix under non-aqueous conditions. Aqueous dispersions and pastes comprising the substantially size homogenous composition of titanium (IV) oxide nanoparticles are also provided. The titanium (IV) oxide nanoparticles demonstrate improved photoactivity when exposed to UV irradiation, and can also include visible light absorbing centres such that activity is extended into the visible light range.

Abstract: A ceramic glaze-coating structure of a chip element and a method of forming the same are provided. In the ceramic glaze-coating structure, a high-density, smooth, and high-impedance ceramic glaze is coated on the body of an element. As for the terminal electrode part, the unique firing characteristics between the material of the terminal electrode (e.g., conductive compositions) and the ceramic glaze are utilized, such that the ceramic glaze layer between the surface of the terminal electrode or the terminal electrode and the ceramic body is absorbed and then removed by sintering; thus, the ceramic glaze coating structure of a chip element with only the element body being coated is formed.

Abstract: This invention relates to boron-containing compositions for use in glaze compositions. There is provided a boron-containing composition for use in glaze production, which composition is obtainable by a process which comprises heating to a temperature sufficiently high that calcination occurs but insufficient for the formation of a homogeneous melt a mixture comprising components capable, under the conditions of heating, of forming the oxides B2O3, SiO2, Al2O3, Na2O and optionally CaO in proportions such that the relative percentages by weight of the said oxides, based on the total weight of the said oxides, are as follows: 10 to 18% B2O3, 40 to 65% SiO2, 17 to 32% Al2O3, 4 to 9% Na2O, and 0 to 10% CaO. The boron-containing compositions according to the present invention may be used in glaze compositions, suitably frit-free or boron-free frit-containing glaze compositions.

Abstract: In the invention, a silica sol prepared by hydrolyzing and condensing a silane compound represented by the following formula: Si(OR1)4 or R2nSi(OR3)4-n wherein R1s, R2(s) and R3(s) may be the same or different when a plurality of them are contained in the molecule and each independently represents a linear or branched C1-4 alkyl group in the presence of a hydrophilic basic catalyst and a hydrophobic basic catalyst is used for a conventional porous-film forming composition.

Abstract: An evaporation-induced self-assembly method to prepare a porous, surfactant-templated, thin film by mixing a silica sol, a solvent, a surfactant, and an interstitial compound, evaporating a portion of the solvent to form a liquid, crystalline thin film mesophase material, and then removal of the surfactant template. Coating onto a substrate produces a thin film with the interstitial compound either covalently bonded to the internal surfaces of the ordered or disordered mesostructure framework or physically entrapped within the ordered or disordered mesostructured framework. Particles can be formed by aerosol processing or spray drying rather than coating onto a substrate. The selection of the interstitial compound provides a means for developing thin films for applications including membranes, sensors, low dielectric constant films, photonic materials and optical hosts.