Oxide-containing Coating Patents (Class 427/419.2)
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Publication number: 20100098865Abstract: A turbine engine component is provided which has a substrate and a thermal barrier coating applied over the substrate. The thermal barrier coating comprises at least one layer of a first material selected from the group consisting of a zirconate, a hafnate, a titanate, and mixtures thereof, which first material has been mixed with, and contains, from about 25 to 99 wt % of at least one oxide. The at least one oxide comprises at least one oxide of a material selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, indium, and yttrium. If desired, a metallic bond coat may be present between the substrate and the thermal barrier coating system. A method for forming the thermal barrier coating system of the present invention is described.Type: ApplicationFiled: December 18, 2009Publication date: April 22, 2010Applicant: UNITED TECHNOLOGIES CORPORATIONInventors: David A. Litton, Kevin W. Schlichting, Melvin Freling, John G. Smeggil, David B. Snow, Michael J. Maloney
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Patent number: 7691452Abstract: A multi-layer insulation (MLI) blanket with enhanced contamination inhibiting properties and a method for inhibiting the formation of organic residues on the outer surface of a MLI blanket are provided. In one embodiment, a MLI blanket (10) attachable to a spacecraft or other structure includes a plurality of metallized layers (20, 30, 40, 50) separated by mesh layers (60, 62, 64). An anti-contamination coating (80) comprised of a photocatalytic material is disposed between a high emittance layer (70) that overlies the outer surface (20A) of the outer metallized layer (20) and an outer electrically conductive layer (90).Type: GrantFiled: May 17, 2007Date of Patent: April 6, 2010Assignee: Lockheed Martin CorporationInventor: Hamilton Wong
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Patent number: 7683293Abstract: A domestic appliance, particularly a cooking appliance, having a metallic surface, is provided with a coating based on silicon oxide. Such coating is deposited on the metallic surface by plasma enhanced chemical vapor deposition (PECVD). The coating protects the metallic surface from scratching, staining and thermal yellowing.Type: GrantFiled: March 25, 2005Date of Patent: March 23, 2010Assignee: Whirlpool CorporationInventors: Ermanno Buzzi, John Doyle, Thomas Friesen
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Publication number: 20100068507Abstract: An article having a thermal barrier coating includes a superalloy substrate having a columnar grained ceramic coat formed thereon. The ceramic coat includes a nanolaminate region comprising repeating layers of ceramic material with each layer being less than 500 nm in thickness, with dispersions of metal oxide doping material situated between each of the layers. The ceramic coat further includes a non-doped region having a thickness greater than 500 nm adjacent to the nanolaminate region, the non-doped region including one layer or a plurality of adjacent layers of ceramic material without dispersions of metal oxide doping material situated between each of the layers. In one embodiment, and by way of example only, a bond coat is formed between the substrate and the columnar grained ceramic coat. According to another embodiment, the superalloy substrate forms an adherent alumina scale, and no bond coat is necessary.Type: ApplicationFiled: September 6, 2006Publication date: March 18, 2010Inventors: Thomas E. Strangman, Derek Raybould
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Publication number: 20100068427Abstract: The present invention relates to an inkjet recording material comprising: a) a substrate b) at least one ink-accepting layer applied to at least one side of the substrate, containing at least one pigment selected from the group consisting of calcium carbonate, calcined clay, satin white or mixtures thereof, the mean particle size of the pigment being from 0.1 ?m to 1.5 ?m, c) at least one surface layer applied to the at least one ink-accepting layer, the surface layer containing cationic inorganic particles, the inkjet recording material having a gloss in the range from 10 to 60, measured according to DIN 54502 R? (45°) (measuring angle 45°), on the side to which the at least one surface layer was applied, and the density of the inkjet recording material being greater than or equal to 0.95 g/cm3, and to a process for its production.Type: ApplicationFiled: August 10, 2007Publication date: March 18, 2010Applicant: M-real OyjInventors: Andre Becker, David Croll, Dominik Fuchs, Friedhelm Halfenberg
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Patent number: 7673541Abstract: Colored razor blades are provided. Methods for manufacturing such blades are also provided, including methods involving depositing an oxide coating prior to heat treatment of the blade material and heat treating under conditions selected to enhance the color of the coating.Type: GrantFiled: June 3, 2004Date of Patent: March 9, 2010Assignee: The Gillette CompanyInventors: Kenneth J. Skrobis, Alfred Porcaro, Ronald J. Swanson, Eric Liu
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Patent number: 7674520Abstract: The present invention describes a cutting tool with improved properties for metal machining having a substrate of cemented carbide and a hard and wear resistant coating on the surface of said substrate. The coating is deposited by Physical Vapor Deposition (PVD). The coating is composed of metal nitrides in combination with alumina (Al2O3). The coating is composed of a laminar multilayered structure. The insert is further treated to have different outer layers on the rake face and flank face respectively.Type: GrantFiled: August 31, 2006Date of Patent: March 9, 2010Assignee: Sandvik Intellectual Property ABInventor: Veit Schier
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Patent number: 7670680Abstract: A device having a substrate, a pair of ferromagnetic leads on a surface of the substrate, laterally separated by a gap, and one or more ferromagnetic microparticles comprising a conductive coating at least partially within the gap. The conductive coating forms at least part of an electrical connection between the leads. A molecular junction may connect the leads to the microparticle.Type: GrantFiled: December 19, 2007Date of Patent: March 2, 2010Assignee: The United States of America as represented by the Secretary of the NavyInventors: David P Long, James G Kushmerick, Jr.
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Patent number: 7670674Abstract: There is described a cutting tool with improved properties for metal machining having a substrate of cemented carbide and a hard and wear resistant coating on the surface of said substrate. The coating is deposited by Physical Vapor Deposition (PVD). The coating is composed of metal nitrides in combination with alumina (Al2O3). The coating is composed of a laminar multilayered structure. The insert is further treated to have different outer layers on the rake face, and flank face respectively.Type: GrantFiled: August 31, 2006Date of Patent: March 2, 2010Assignee: Sandvik Intellectual Property ABInventor: Veit Schier
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Patent number: 7666752Abstract: The present invention relates to a method for depositing a dielectric material comprising a transition metal compound. After providing a substrate, a first pre-cursor comprising a transition metal compound and a second pre-cursor predominantly comprising at least one of water vapour, ammonia and hydrazine are successively applied on the substrate for forming a first layer of transition metal containing material. In a next step the first pre-cursor and a third pre-cursor comprising at least one of ozone and oxygen are successively applied on the first layer for forming a second layer of the transition metal containing material.Type: GrantFiled: January 19, 2007Date of Patent: February 23, 2010Assignee: Qimonda AGInventors: Stephan Kudelka, Lars Oberbeck, Uwe Schroeder, Tim Boescke, Johannes Heitmann, Annette Saenger, Joerg Schumann, Elke Erben
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Patent number: 7663075Abstract: Disclosed is a layer for use in a domestic appliance, based on a sol-gel precursor. This layer can be obtained by screen-printing and comprises an organosilane compound. The layer is obtained from a concentrated pre-polymerized sol-gel precursor. The layer can be used as an insulating layer or as a conductive layer in a heating element. Furthermore, the layer can be used for decorative purposes.Type: GrantFiled: May 13, 2005Date of Patent: February 16, 2010Assignee: Koninklijke Philips Electronics N.V.Inventors: Poh Loo Lee, Gerard Cnossen, Marcel Rene Boehmer, Sandor Nemeth, Pieter Johannes Werkman
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Publication number: 20100035030Abstract: A layer of material, such as crystalline indium tin oxide (ITO), is formed on top of a substrate by heating the material to a high temperature, while a temperature increase of the substrate is limited such that the temperature of the substrate does not exceed a predetermined temperature. For example, a layer including amorphous ITO can be deposited on top of the substrate, and the amorphous layer can be heated in a surface anneal process using radiation while limiting substrate temperature. Another process can pass electrical current through the amorphous ITO. In another process, the substrate is passed through a high-temperature deposition chamber quickly, such that a portion of a layer of crystalline ITO is deposited, while the temperature increase of the substrate is limited.Type: ApplicationFiled: August 8, 2008Publication date: February 11, 2010Inventors: Lili Huang, John Z. Zhong
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Patent number: 7648783Abstract: A cadmium tin oxide (Cd1?xSnxO) multi-layer laminate is disclosed. The laminate comprises: a substrate; and a layer of Cd1?xSnxO which is not an epitaxial structure; wherein, the composition of Sn/(Cd+Sn) is 1˜20%. The method for producing the Cd1?xSnxO multi-layer laminate is also described here. The method comprises steps of: (a) providing metal or oxide targets for sputtering films of Cd1?xSnxO; and (b) sputtering films of Cd1?xSnxO from the targets onto the substrate; wherein the composition of Sn/(Cd+Sn) is 1˜20%.Type: GrantFiled: December 20, 2005Date of Patent: January 19, 2010Assignees: Industrial Research Technology Institute, Toth Information System, Inc.Inventors: Tien-Heng Huang, Ren-Jye Wu, Wen-Hsuan Chao, Lih-Ping Wang, Hung-Chiao Cheng, Jassy Shian-Jy Wang, Shu-Hei Wang, John R. Rodgers
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Patent number: 7648768Abstract: A coating includes a functional coating, such as a solar control coating having at least one metal layer. A topcoat is formed over at least a portion of the functional coating. The topcoat includes a first topcoat layer having a thickness in the range of 0.5 QWOT to 1.5 QWOT with respect to a reference wavelength of 550 nm and a first refractive index, and a second topcoat layer having a thickness in the range of 0.5 QWOT to 1.5 QWOT with respect to a reference wavelength of 550 nm and a second refractive index different from the first refractive index.Type: GrantFiled: June 1, 2007Date of Patent: January 19, 2010Assignee: PPG Industries Ohio, Inc.Inventor: James P. Thiel
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Patent number: 7641957Abstract: The use of a coating composition comprising: (a) from about 5 to about 50 weight percent solids, the solids comprising from about 10 to about 70 weight percent silica and from about 90 to about 30 weight percent of a partially polymerized organic silanol of the general formula RSi(OH)3, wherein R is selected from methyl and up to about 40% of a group selected from the group consisting of vinyl, phenyl, gamma-glycidoxypropyl, and gamma-methacryloxypropyl, and (b) from about 95 to about 50 weight percent solvent, the solvent comprising from about 10 to about 90 weight percent water and from about 90 to about 10 weight percent lower aliphatic alcohol, wherein the coating composition has a pH of from about 3.0 to about 8.0, for the purpose of improving the surface smoothness of a polymeric substrate, particularly a heat-stabilised, heat-set, oriented polyester substrate, and use of said coated substrate in the manufacture of an electronic or optoelectronic device containing a conjugated conductive polymer.Type: GrantFiled: March 19, 2003Date of Patent: January 5, 2010Assignee: Dupont Teijin Films U.S. Limited PartnershipInventors: Julian Neal Robinson, Robert William Eveson, Karl Rakos
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Publication number: 20090324839Abstract: Process for passivating metallic surfaces, and a preparation suitable for implementing the process, comprising at least water, an acid, and a copolymer of functionalized (meth)acrylic esters, monomers containing phosphoric and/or phosphonic acid groups, monomers having COOH groups, and, if appropriate, further monomers. Copolymer which comprises said monomers.Type: ApplicationFiled: July 18, 2007Publication date: December 31, 2009Applicant: BASF SE Patents, Trademarks and LicensesInventors: Frank Klippel, Alexander Göthlich, Gunnar Schornick, Dietrich Fehringer, Thomas Heidenfelder, Helmut Witteler, Walter Bertkau
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Publication number: 20090324989Abstract: Components (1) have a thermal barrier coating (2-6) on the surface thereof, wherein the thermal barrier coating includes at least one layer (3) having chemically stabilized zirconia, and wherein at least indirectly adjacent to the layer (3) with chemically stabilized zirconia and on its surface facing side, there is provided a protective layer (4) and/or a infiltration zone (5) which does not react with environmental contaminant compositions that contain oxides of calcium and which does not react with the material of the layer (3) having chemically stabilized zirconia. Methods for making such components as well as to uses of specific systems for coating thermal barrier coatings, can prevent CMAS.Type: ApplicationFiled: May 26, 2009Publication date: December 31, 2009Inventors: Gregoire Etienne Witz, Hans-Peter Bossmann, Valery Shklover, Sharath Bachegowda
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Publication number: 20090297408Abstract: In the formation of an oxide film on an aluminum fiber, it has been difficult to form a thick alumina coating film on the aluminum fiber which already has a natural oxide film formed thereon. To overcome this problem, there is provided a method for forming an alumina coating film which enables the deep penetration of oxygen into an aluminum fiber by employing a three-stage heating treatment and an alumina fiber formed by the method. Also provided is a system for producing water by photocatalytic reaction, in which a photocatalyst comprising the alumina fiber coated with titania is irradiated with light from a light source to generate an active oxygen species, diffusing the active oxygen species in water to impart the function of the active oxygen species to water. The system can perform washing by utilizing an oxidation reaction with the resulting water. Further, provided is a gas treatment system which comprises the alumina fiber coated with titania to impart a photocatalytic function to the aluminum fiber.Type: ApplicationFiled: June 30, 2006Publication date: December 3, 2009Inventors: Kenichiro Tanaka, Licca Tanaka, Tsutomu Harada
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Patent number: 7625840Abstract: A nanoporous catalytic membrane which displays several unique features including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations.Type: GrantFiled: September 14, 2004Date of Patent: December 1, 2009Assignee: UChicago Argonne, LLC.Inventors: Michael J. Pellin, John N. Hryn, Jeffrey W. Elam
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Patent number: 7622195Abstract: A process of coating an article includes the steps of (1) applying a ceramic based compound to at least one surface of an article to form a layer of ceramic based compound; (2) applying at least one inert compound upon the ceramic based compound layer to form a protective layer, wherein the at least one inert compound is composed of a first inert compound having a cubic crystalline structure of formula (I) A3B2X3O12, or a second inert compound comprising a hexagonal crystalline structure of formula (II) A4B6X6O26, or a mixture of the first inert compound and the second inert compound; (3) optionally drying the coated article; (4) optionally repeating steps (2) and (3); and (5) heat treating the coated article.Type: GrantFiled: January 10, 2006Date of Patent: November 24, 2009Assignee: United Technologies CorporationInventors: Kevin W. Schlichting, David A. Litton, Michael J. Maloney, Melvin Freling, John G. Smeggil, David B. Snow
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Patent number: 7611750Abstract: A nanocomposite material and a method of manufacturing the same are disclosed. The nanocomposite material includes a plurality of nanoparticles coated with a metal oxide, and a matrix of the metal oxide immobilizing the nanoparticles that are dispersed therein. The nanocomposite material is manufactured such that macro- or macro-scale cracks are prevented or effectively prevented, light stability is enhanced over a light-emitting period, and light brightness is improved.Type: GrantFiled: December 4, 2006Date of Patent: November 3, 2009Assignee: Samsung Electronics Co., Ltd.Inventors: Dong-kee Yi, Byung-ki Kim, Jae-ho Lee, Eun-joo Jang, Seong-jae Choi
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Patent number: 7612015Abstract: A photocatalyst layer (TiO2) is formed on the surface of a substrate (glass plate) through the intermediary of a monoclinic undercoat layer (ZrO2), and no dead layer is substantially present between the photocatalyst layer and the undercoat layer. Also, by providing a peel preventing layer between the substrate and the undercoat layer, it is possible to eliminate film peeling between the photocatalyst layer and the substrate, defects and discoloration. A metal element may be doped in the photocatalyst layer, and it is preferable that the metal element is at least one of Sn, Zn, Mo and Fe. The phrase “no dead layer is substantially present” means that the thickness of the dead layer is 20 nm or less. The thickness of the photocatalyst layer is preferably from 1 nm to 1,000 nm, more preferably from 1 nm to 500 nm.Type: GrantFiled: December 24, 2002Date of Patent: November 3, 2009Assignee: Nippon Sheet Glass Company, LimitedInventors: Toshiaki Anzaki, Yoshifumi Kijima, Kenji Mori
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Patent number: 7608562Abstract: A method of producing a photocatalyst according to the invention comprises forming an amorphous titanium oxide and heat-treating it in an atmosphere containing oxygen, whereby a photocatalyst having a good photocatalysis can be obtained. In particular, the amorphous titanium oxide is obtained by using the reactive sputtering method and via deposition at a low temperature and at a high film formation rate. This apparatus can be provided with cooling means to allow enhancement of the throughput of the film formation process.Type: GrantFiled: November 20, 2008Date of Patent: October 27, 2009Assignee: Shibaura Mechatronics CorporationInventors: Junji Hiraoka, Minoru Takashio, Tetsuya Fukushima, Daisuke Noguchi, Yoshio Kawamata
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Patent number: 7597936Abstract: Disclosed is a method for producing a pigmented composite comprising contacting a microporous material with a tin compound to form a composite then contacting the composite with a pigment comprising an elemental metal, a metal oxide, a metal alloy, a metal salt, or a combination thereof to produce the pigmented composite. The pigmented composites described herein are useful for separating one or more analytes present in a fluid sample.Type: GrantFiled: May 26, 2004Date of Patent: October 6, 2009Assignee: University of Utah Research FoundationInventors: Roger E. Smith, Karl V. Voelkerding, Mark G. Elgort, Jacob Durtschi
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Patent number: 7597951Abstract: The present invention relates to a metal cutting tool insert with a coating comprising a metal oxide multilayer, which exhibits especially high resistance to plastic deformation as well as excellent resistance to flank and crater wear and high resistance to flaking, particular when used for machining of low carbon steel and stainless steel. The invention also relates to a method of making such a cutting tool insert.Type: GrantFiled: March 20, 2006Date of Patent: October 6, 2009Assignee: Sandvik Intellectual Property ABInventors: Carl Björmander, Markus Rodmar
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Publication number: 20090237837Abstract: A method of fabricating a recording head includes depositing an insulator material onto at least a portion of a first member, wherein the insulator material forms an insulator film having a film thickness. The method further includes depositing a writer pole material onto the insulator film, wherein the writer pole material forms a writer pole member, and wherein the insulator film is between the writer pole member and a contact layer. Further, in some embodiments, the film thickness determines the distance between the writer pole member and the first contact member and also determines the distance between the writer pole member and the second contact member.Type: ApplicationFiled: March 19, 2008Publication date: September 24, 2009Applicant: Seagate Technology LLCInventors: Nurul Amin, Ibro Tabakovic, Eric S. Linville, Ming Sun
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Patent number: 7588797Abstract: A chemical composition and method for repairing a thermal barrier coating on a component designed for use in a hostile thermal environment, such as turbine, combustor and augmentor components of a gas turbine engine. The method repairs a thermal barrier coating on a component that has suffered localized damage to the thermal barrier coating. After cleaning the surface area of the component exposed by the localized spallation, a paste-like mixture of a ceramic composition comprising ceramic powders and nano-sized ceramic materials in a binder is applied to the surface area of the component, and is optionally smoothed using mechanical means. The composition is then allowed to dry and cure to form a dried coating having polymeric characteristics. Upon subsequent heating, the dried coating reacts to produce a glassy ceramic repair coating.Type: GrantFiled: April 7, 2004Date of Patent: September 15, 2009Assignee: General Electric CompanyInventors: Andrew Jay Skoog, Jane Ann Murphy, William Randolph Stowell, David E. Caldwell
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Patent number: 7582367Abstract: A ceramic member is provided including a base including an alumina sintered body, an yttria sintered body formed on the alumina sintered body, an intermediate layer including yttrium and aluminum formed between the alumina sintered body and the yttria sintered body, and a metallic member buried in the intermediate layer of the base. A difference between the thermal expansion coefficient of the alumina sintered body and that of the yttria sintered body is equal to or less than about 0.50×10?6/K, and the thermal expansion coefficient of the alumina sintered body is greater than the thermal expansion coefficient of the yttria sintered body. The alumina sintered body, the intermediate layer, the yttria sintered body, and the metallic member are formed into an integrated sintered body, and the content of yttria in the yttria sintered body is 99 wt % or more.Type: GrantFiled: September 27, 2005Date of Patent: September 1, 2009Assignee: NGK Insulators, Ltd.Inventors: Yasufumi Aihara, Hiroto Matsuda, Kazuhiro Nobori, Tsutomu Kato
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Patent number: 7582332Abstract: Particles for an electronic paper display device and a method for preparing the same. Since charged particles have a constant electrification amount, a moving speed and a moving amount of the charged particles are uniformly controlled at the time of an electrophoresis. Also, a response speed and a resolution of an electronic paper display device are improved, and an amount of a voltage applied to the electronic paper display device is precisely controlled.Type: GrantFiled: February 14, 2006Date of Patent: September 1, 2009Assignee: LG Electronics Inc.Inventors: Moon-Bong Song, Soon-Hyung Kwon, Sung-Guk Lee
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Patent number: 7579049Abstract: A method is provided for enhancing corrosion resistance of a metal surface that includes the step of forming a sol-gel coating in which nanostructured zinc phosphate (Zn3(PO4)2) and zinc oxide (ZnO) phases are present in the mixture. The method may include the steps of mixing an organosilane, organometallic, organic acid, water, and alcohol, and allowing the components of the mixture to partially hydrolyze, followed by adding at least one component having zinc functionality and at least one component having phosphate functionality to the partially hydrolyzed mixture, wherein the zinc component and phosphate component are added in a molar ratio of from about 1.5:1 to about 5:1 (Zn:PO4). The resulting mixture can be applied as a coating to a metal surface to improve the corrosion resistance of the metal and to enhance the adhesion of resinous materials to the metal surface.Type: GrantFiled: July 6, 2004Date of Patent: August 25, 2009Assignee: The Boeing CompanyInventors: Young J. Chung, Melitta M. Hon, Martin W. Kendig
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Patent number: 7572345Abstract: Substrates comprising a surface comprising chromium, said surface being adapted to exhibit reduced coefficient of friction and/or increased hardness.Type: GrantFiled: December 14, 2007Date of Patent: August 11, 2009Assignee: Southwest Research InstituteInventors: Geoffrey Dearnaley, Kevin C. Walter
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Patent number: 7565724Abstract: A method for manufacturing a piezoelectric element includes the steps of forming a first electrode above a substrate, forming, above the first electrode, a piezoelectric layer composed of a piezoelectric material having a perovskite structure, and forming a second electrode above the piezoelectric layer, wherein the step of forming the first electrode includes forming a layer containing nickel, and forming, above the layer containing nickel, a lanthanum nickelate layer that is oriented to a cubic (100).Type: GrantFiled: February 20, 2006Date of Patent: July 28, 2009Assignee: Seiko Epson CorporationInventors: Setsuya Iwashita, Koji Ohashi, Takamitsu Higuchi
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Patent number: 7560173Abstract: An electrically active film and a process for its preparation at low temperatures are described. The electrically active film consists of a support having coated thereon at least one electrically active layer which contains nanocrystalline, nanoporous transition metal oxides, transition metal chalcogenides or their lithium inclusion complexes and, optionally, auxiliary, electrically non-active layers, wherein the electrically active layers still contain a binder or a mixture of binders at the end of the preparation process.Type: GrantFiled: March 15, 2002Date of Patent: July 14, 2009Assignee: Ilford Imaging Switzerland GmbHInventors: Pierre-Alain Brugger, Martin Staiger, Rolf Steiger
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Publication number: 20090169752Abstract: Methods for providing improved resistance to CMAS infiltration for hot section components of a gas turbine engine. Exemplary methods include coating a substrate with a thermal barrier coating system by overlying a bond coated substrate with an inner thermal barrier layer comprised of a thermal barrier material such as yttria-stabilized zirconia. A top layer, including a rare-earth aluminate, is deposited so as to overlie at least a portion of the inner layer. Deposition processes and coating thicknesses may be tailored to the type of component to be coated.Type: ApplicationFiled: December 27, 2007Publication date: July 2, 2009Inventors: Ming Fu, Ramgopal Darolia, Mark Gorman, Bangalore Aswatha Nagaraj
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Publication number: 20090123735Abstract: Components of semiconductor processing apparatus are formed at least partially of erosion, corrosion and/or corrosion-erosion resistant ceramic materials. Exemplary ceramic materials can include at least one oxide, nitride, boride, carbide and/or fluoride of hafnium, strontium, lanthanum oxide and/or dysprosium. The ceramic materials can be applied as coatings over substrates to form composite components, or formed into monolithic bodies. The coatings ca protect substrates from physical and/or chemical attack. The ceramic materials can be used to form plasma exposed components of semiconductor processing apparatus to provide extended service lives.Type: ApplicationFiled: January 7, 2009Publication date: May 14, 2009Applicant: Lam Research CorporationInventor: ROBERT J. O'DONNELL
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Publication number: 20090110915Abstract: A method for a new universal nucleation-layer/diffusion barrier, which is based on amorphous films of Si—O and Si—N for ion-beam-assisted deposition (IBAD) process. Unlike other nucleation layers that were used in the past, this process works on a variety of substrates (glass, Hastelloy tape, Cu), with varying surface roughness, and with a wide range of thickness. In addition, this new material system of Si—O (and Si—N) is ideally suited for oxide (and nitride) based multilayer stacks. As importantly, the flexibility in nucleation layer thickness allows the nucleation layer to be an effective diffusion barrier, and to be grown at room temperature, while the IBAD layer and subsequent epitaxial layers can be grown much thinner than usual.Type: ApplicationFiled: October 24, 2007Publication date: April 30, 2009Applicant: LOS ALAMOS NATIONAL SECURITY, LLCInventor: Alp T. FINDIKOGLU
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Patent number: 7524536Abstract: A method of protecting a surface includes applying to the surface a protective composition containing an aqueous wax emulsion. The composition prevents or reduces degradation of the surface of equipment in a facility where the surface is contacted by alkali metal silicate solutions. The compositions are useful, for example, in facilities for treating poultry or other meat carcasses with alkali metal silicates, in facilities for manufacturing detergents, in paper mills, and in any other facility using liquid alkali metal silicate.Type: GrantFiled: June 21, 2005Date of Patent: April 28, 2009Assignee: PQ CorporationInventor: Edward A. Myszak, Jr.
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Publication number: 20090104086Abstract: A photocatalytically active titanium dioxide film may be applied onto surfaces of a variety of objects to oxidize matter that comes into contact with those surfaces. Various methods may be used to apply a solution of the photocatalytically active nanoparticles onto surfaces receiving regular human contact or proximate to human presence. An inorganic primer layer may be initially applied to an organic substrate, such as food, plants, flowers and foliage, to prevent the photocatalytically active coating from oxidizing the organic substrate.Type: ApplicationFiled: October 17, 2008Publication date: April 23, 2009Inventors: Adam Zax, Yasser Elassal
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Patent number: 7510779Abstract: A coated article is prepared by furnishing a nickel-base article substrate having a free sulfur content of more than 0 but less than about 1 part per million by weight. A protective layer is formed at a surface of the article substrate. The protective layer includes a platinum aluminide diffusion coating. The protective layer may be substantially yttrium-free, or have a controlled amount of yttrium. A ceramic layer may overlie the protective layer.Type: GrantFiled: September 17, 2004Date of Patent: March 31, 2009Assignee: General Electric CompanyInventors: William Scott Walston, Jon Conrad Schaeffer, Wendy Howard Murphy
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Publication number: 20090060823Abstract: A string for use in a string ribbon crystal has a base portion with a refractory material, and an externally exposed layer radially outward of the refractory material. The base portion has a coefficient of thermal expansion that is generally matched with the coefficient of thermal expansion for silicon. The externally exposed layer has a contact angle with silicon of between about 15 and 120 degrees.Type: ApplicationFiled: August 29, 2008Publication date: March 5, 2009Applicant: EVERGREEN SOLAR, INC.Inventors: Christine Richardson, Weidong Huang, Richard Wallace, Daniel Doble, Scott Reitsma
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Publication number: 20090060747Abstract: A method of manufacturing a gas turbine engine component includes the steps of forming a ceramic workpiece having oriented ceramic reinforcement, and severing the ceramic workpiece to produce a ceramic member having a desired orientation of the ceramic reinforcement. The ceramic member is then attached to a turbine engine component as a thermal barrier layer for the turbine engine component.Type: ApplicationFiled: August 28, 2007Publication date: March 5, 2009Inventors: Christopher W. Strock, Susan M. Tholen
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Publication number: 20090042022Abstract: The present invention relates to a fire-retardant materia and method. More specifically, the present invention relates to an insulating, fire-retardant coating (and method) that shields underlying substrates from thermal and other types of insult. The invented coating is especially applicable to energy transport means including oil pipelines. The invented coating and method is also useful in providing a insulating and fire-resistant coating for a variety of substrates including but not limited to: concrete, metals, foamed polymeric materials (i.e. styrofoam), gypsum, synthetics and other substrates.Type: ApplicationFiled: September 29, 2008Publication date: February 12, 2009Inventor: Thomas J. Lally
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Patent number: 7470296Abstract: A cutting tool insert particularly for turning of steel comprising a body and a coating with a first (innermost) layer system of at least two layers of TiCxNyOz with x+y+z?1 with a total thickness of from about 0.7 to about 4.5 ?m, a second layer system to a large extent consisting of Al2O3 and an outermost layer system comprising one or several layers in sequence of TiCxNy (x+y?1) with individual thicknesses of greater than about 0.15 to about 0.8 ?m and a layer with Al2O3 with a thickness greater than about 0.1 to about 0.4 ?m with a total thickness of the outermost layer system thinner than about 2.5 ?m and a total thickness of the coating in the range of from about 2.0 to about 12.0 ?m.Type: GrantFiled: July 13, 2005Date of Patent: December 30, 2008Assignee: Sandvik Intellectual Property ABInventors: Mikael Lindholm, Markus Rodmar, Anders Jonsson
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Patent number: 7462393Abstract: The spray powder can be used for the manufacture of a thermally insulating layer which is resistant to high temperatures. A coating of this kind, a so-called TBC, can be produced on a substrate by means of a thermal spraying process. The substrate can already be coated with a single- or multi-layered part coating, in particular a primer. At least one thermally insulating functional material is used, which on the one hand has a lower thermal conductivity than the substrate and on the other hand forms a chemically and thermally stable phase at high temperatures. The spray powder comprises particles (1) which respectively have an agglomerate-like micro-structure (2) which is formed by a plurality of granules (3) adhering to each other. These granules are made up of the functional material or the functional materials. At least one further component is present made of an additive (4) or a plurality of additives.Type: GrantFiled: November 10, 2003Date of Patent: December 9, 2008Assignee: Sulzer Metco (US) Inc.Inventors: Rajiv J. Damani, Kaspar Honegger
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Patent number: 7462378Abstract: Disclosed herein are methods for coating metal substrates, systems therefore, and articles made therefrom. In one embodiment, the method of coating a metal substrate comprises: disposing a metallic bond coating on the metal substrate, creating ions with a reverse polarity high frequency apparatus at a frequency of greater than or equal to about 2.5 kHz, roughening the surface with the ions to a subsequent average surface roughness of greater than or equal to about 5 ?m, and disposing a ceramic coating on the metallic bond coating surface. The metallic bond coating had a surface with an initial average surface roughness of less than or equal to about 1 ?m.Type: GrantFiled: November 17, 2005Date of Patent: December 9, 2008Assignee: General Electric CompanyInventors: Daniel Anthony Nowak, Paul Stephen DiMascio, David Vincent Bucci
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Patent number: 7462578Abstract: A method of producing a photocatalyst according to the invention comprises forming an amorphous titanium oxide and heat-treating it in an atmosphere containing oxygen, whereby a photocatalyst having a good photocatalysis can be obtained. In particular, the amorphous titanium oxide is obtained by using the reactive sputtering method and via deposition at a low temperature and at a high film formation rate. This apparatus can be provided with cooling means to allow enhancement of the throughput of the film formation process.Type: GrantFiled: November 29, 2002Date of Patent: December 9, 2008Assignee: Shibaura Mechatronics CorporationInventors: Junji Hiraoka, Minoru Takashio, Tetsuya Fukushima, Daisuke Noguchi, Yoshio Kawamata
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Publication number: 20080292803Abstract: In accordance with an embodiment of the invention, a thermal barrier coating for inclusion in a thermal barrier coating/environmental barrier coating system (TBC/EBC system) for use on a silicon based substrate is disclosed. The thermal barrier coating comprising up to about 9 mol percent of a stabilizer and up to 91 mol percent of primary oxide selected from the group consisting of zirconia, hafnia and mixtures thereof. The stabilizer comprises: a first metal oxide selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india and mixtures thereof, a second metal oxide of a trivalent metal atom selected from the group consisting of lanthana, gadolinia, neodymia, samaria, dysprosia, ytterbia, erbia, and mixtures thereof. The first metal oxide is in an amount of from about 3 to about 5 mol %, the second metal oxide is in an amount of from about 0.25 to about 6 mol %.Type: ApplicationFiled: September 20, 2007Publication date: November 27, 2008Inventors: Bangalore A. Nagaraj, Irene Spitsberg, Christine Govern, Brian Thomas Hazel
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Patent number: 7435448Abstract: The present invention is drawn to a media sheet, comprising a substrate and a porous ink-receiving layer deposited on the substrate. The porous ink-receiving layer can comprise inorganic metal or semi-metal oxide particulates bound by a polymeric binder, and the porous ink-receiving layer can further include an effective amount of a sulfur-containing compound that interacts with ozone upon exposure thereto.Type: GrantFiled: February 6, 2004Date of Patent: October 14, 2008Assignee: Hewlett-Packard Development Company, L.P.Inventors: Steven D Looman, Eric L Burch, John R Moffatt, Gary Allan Ungefug, Rolf Steiger, Pierre-Alain Brugger, Urs Fuerholz
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Patent number: 7435446Abstract: A method of producing a gas barrier laminate is disclosed that comprises: preparing a laminate comprising a plastic substrate, a gas barrier layer formed from a gas barrier layer-forming coating material comprising a polyvinyl alcohol and an ethylene-maleic acid copolymer, and a polymer layer comprising a metal compound of a bivalent or higher metal, wherein the polymer layer is laminated to at least one surface of the gas barrier layer; and heat treating the obtained laminate in the presence of water. In addition, another method of producing a gas barrier laminate is disclosed that comprises: applying a gas barrier layer-forming coating material comprising a polyvinyl alcohol and an ethylene-maleic acid copolymer, either directly onto a plastic substrate, or onto a plastic substrate with an undercoat layer disposed therebetween, and then conducting a heat treatment; and heat treating the obtained laminate in the presence of water comprising a metal compound of a bivalent or higher metal.Type: GrantFiled: April 9, 2004Date of Patent: October 14, 2008Assignee: Toyo Ink Mfg. Co., Ltd.Inventor: Miyuki Kamoshita
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Patent number: RE40589Abstract: An aqueous wood preservation composition containing inorganic polymers of one or more of the following metals is disclosed; aluminum (approximately 3.8%-7.0% as Al2O3), zirconium (approximately 5.25%-9.1% as ZrO2), copper (approximately 0.7%-8.8% as CuO) and a fixing agent such as acetic acid or sodium acetate. The pH is adjusted to be between 2.0-4.0 using an inorganic base such as copper carbonate. The invention includes wood and cellulose fibers treated by the composition of the present invention as well as methods of preserving wood and cellulose fibers using the compositions.Type: GrantFiled: August 22, 2007Date of Patent: December 2, 2008Assignee: Sommerville Acquisitions Company, Inc.Inventors: Thomas L. Harper, Boris Reznikov, Allan Rosenberg