Oxide-containing Coating Patents (Class 427/419.2)
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Patent number: 6761927Abstract: Method for coating a non-oxidised stainless steel support plate and a MCFC fuel cell stack provided with a separator plate coated in this way. First a diffusion barrier layer and then a nickel layer are applied to the anode side of the support plate. The diffusion barrier layer consists of titanium oxide and the adhesion between titanium oxide and the support plate can be improved by providing an adhesion layer.Type: GrantFiled: June 7, 2001Date of Patent: July 13, 2004Assignees: Stichting Energieonderzoek Centrum Nederland, Gemeenschappelijk Centrum voor Onderzoek PettenInventors: Robert Christiaan Makkus, Edward Bullock, Arnoldus Hermannus Henderikus Janssen, Michel Cassir
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Patent number: 6759084Abstract: It is important for a CPP GMR read head that it have both high resistance as well as high cross-sectional area. This has been achieved by inserting a NOL (nano-oxide layer) though the middle of one or both of the two non-magnetic conductive layers. A key feature is that the NOL is formed by first depositing the conductive layer to about half its normal thickness. Then a metallic film is deposited thereon to a thickness that is low enough for it to still consist of individual islands. The latter are then fully oxidized without significantly oxidizing the conductive layer on which they lie. The remainder of the conductive layer is then deposited to a thickness sufficient to fully enclose the islands of oxide.Type: GrantFiled: June 5, 2003Date of Patent: July 6, 2004Assignee: Headway Technologies, Inc.Inventors: Kochan Ju, Min Li, Simon Liao, Jeiwei Chang
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Patent number: 6760396Abstract: The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.Type: GrantFiled: February 4, 1946Date of Patent: July 6, 2004Assignee: The United States of America as represented by the United States Department of EnergyInventors: Ernest R. Boller, Lowell D. Eubank
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Patent number: 6739928Abstract: A mercury-containing material, a method for producing the same and a fluorescent lamp using the same that can enclose a minimal amount of mercury in a glass bulb precisely, prevent flaws in a fluorescent coating while suppressing a noise during a lamp transportation, and prevent deterioration in appearance are provided. A surface of liquid mercury is coated with a continuous film made of metal oxide or metal complex oxide by dipping the mercury in a metal alkoxide solution and then heating the mercury on which the metal alkoxide solution adheres. Accordingly, the minimal amount of the mercury can be enclosed in the fluorescent lamp precisely, thus achieving friendliness to the environment. It also is possible to prevent flaws in the fluorescent coating while suppressing a noise during the lamp transportation and further to prevent deterioration in appearance.Type: GrantFiled: February 24, 2003Date of Patent: May 25, 2004Assignee: Matsushita Electric Industrial Co., Ltd.Inventor: Kouji Honda
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Patent number: 6740363Abstract: Provided is a method to produce high-temperature lubricious glassy films on silicon-based ceramics. The method comprises the steps of (a) oxidizing a silicon-based component, (b) coating the oxidized component with an alkali metal compound, and (c) heating the component to a high temperature in a sulfur-rich oxidizing environment. The steady state sliding friction coefficient values obtained with this system in 600° C. air are similar to those obtained with liquid lubricants operating under boundary lubrication conditions at much lower temperatures.Type: GrantFiled: April 17, 2003Date of Patent: May 25, 2004Assignee: The United States of America as represented by the Secretary of the Air ForceInventor: Lewis Rosado
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Patent number: 6737105Abstract: A multi-layer coating for a transparent substrate, such as glass, plastic, or other transparent material, which increases the durability and weatherability of the substrate. The coating includes a surface-hardening layer of organo-siloxane formed over the substrate. An abrasion-resistant coating comprising a multi-layer stack of alternating layers of silicon dioxide and zirconium dioxide is formed over the surface-hardening layer. The multi-layer coating further includes a hydrophobic outer layer of perfluoroalkylsilane formed over the abrasion-resistant coating to form an outer moisture-resistant surface. This multi-layer coating configuration increases the abrasion resistance and mechanical strength of the transparent substrate on which it is formed without imparting color to the transparent substrate.Type: GrantFiled: July 27, 2001Date of Patent: May 18, 2004Assignee: VTEC Technologies, Inc.Inventor: David A. Richard
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Patent number: 6733837Abstract: A method including forming a first layer comprising a chemical conversion coating on a metal surface; and forming a second layer on the first layer through a sol gel process. An apparatus including a metal component having at least one surface; a first layer comprising a chemical conversion coating on the at least one surface; and a second layer derived from a sol gel composition on the first layer.Type: GrantFiled: April 11, 2003Date of Patent: May 11, 2004Assignee: Allfast Fastening Systems, Inc.Inventor: Robert J. Dees
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Patent number: 6733828Abstract: A method of confined synthesis of nanostructured material inside a mesoporous material. The method includes the step of providing mesoporous material having uniform and ordered mesopores. Next, a monolayer of charged functional group is attached on the pore surface of mesoporous host material by reacting with functional molecule. A oppositely-charged molecule is incorporated into the confined space of mesoporous material by either ion exchange or incipient wetness impregnation. Finally, the incorporated molecule is reduced or oxidized or further reacted with secondarily-incorporated molecule to form nanostructured material in mesoporous material.Type: GrantFiled: January 29, 2002Date of Patent: May 11, 2004Inventors: Kuei-Jung Chao, Chia-Min Yang
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Patent number: 6730362Abstract: A multi-layer vapor deposited protective and decorative coating a polymeric basecoat layer wherein the polymer of the basecoat layer is cured at subatmospheric pressure.Type: GrantFiled: August 26, 2002Date of Patent: May 4, 2004Assignee: Masco CorporationInventors: John G. Finch, Joseph A. Elmer, Daniel E. Ford, Patrick A. Sullivan, Robert C. Bishop
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Patent number: 6726814Abstract: A process for producing an optical article includes laminating a first optically transparent thin layer and a second optically transparent thin layer having a higher refractive index than that of the first optically transparent thin layer on a surface of a substrate. At least one of the first and second optically transparent thin layers is deposited by sputtering using a sputtering gas comprising atoms of at least one selected from the group consisting of krypton, xenon and radon.Type: GrantFiled: January 28, 2002Date of Patent: April 27, 2004Inventors: Tadahiro Ohmi, Kazuyuki Harada, Nobuyoshi Tanaka
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Patent number: 6726813Abstract: The invention relates to a security device having at least one plastic layer and one specularly reflecting metal layer. An inorganic auxiliary layer is disposed between the plastic layer and the metal layer.Type: GrantFiled: February 28, 2002Date of Patent: April 27, 2004Assignee: Giesecke & Devrient GmbHInventors: Wittich Kaule, Gregor Grauvogl, Jürgen Schützmann, Friedrich Kretschmar
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Patent number: 6723177Abstract: A process for treating a chromium coating and/or the surface of a chromium alloy to increase hardness, and/or to decrease coefficient of friction; chromium alloys and/or chromium coatings with surfaces having increased hardness and/or decreased coefficient of friction; and, components comprising chromium alloys and/or chromium coatings with surfaces having increased hardness and/or decreased coefficient of friction.Type: GrantFiled: July 9, 2001Date of Patent: April 20, 2004Assignee: Southwest Research InstituteInventors: Geoffrey Dearnaley, Kevin C. Walter
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Patent number: 6720034Abstract: A heat-rejection coating is applied to a metallic component of a gas turbine engine, preferably made of a nickel-base superalloy. A component surface is preferably pre-treated, as by polishing the component surface, thereafter pre-oxidizing the component surface, and thereafter applying a ceramic barrier coating onto the component surface. A reflective-coating mixture is air sprayed onto the pre-treated component surface. The reflective-coating mixture includes a metallic pigment, such as platinum, gold, palladium, and alloys thereof, and a reflective-coating-mixture carrier. The component with the reflective-coating mixture sprayed thereon is fired.Type: GrantFiled: April 23, 2002Date of Patent: April 13, 2004Assignee: General Electric CompanyInventors: Andrew Jay Skoog, Jane Ann Murphy, John Frederick Ackerman, Paul Vincent Arszman, Bryan Thomas Bojanowski, Timothy Ray Lattire
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Patent number: 6709757Abstract: The invention concerns composites with excellent barrier properties to gases and water vapor. Such composites can be used, e.g., in foodstuff packaging or as technical membranes. The outstanding barrier effect is achieved by arranging on a substrate material, which, for example, may consist of biodegradable polymers, at least two films. At least one of these films consists of an organic-inorganic hybrid polymer (ORMOCER), at least one further film of a further barrier material or of a substrate material.Type: GrantFiled: September 25, 2002Date of Patent: March 23, 2004Assignee: Fraunhofer-Gesellschaft zur Forderung der angewandten Forschung e.V.Inventors: Helmar Utz, Sabine Amberg-Schwab, Gerhard Schottner
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Patent number: 6706330Abstract: The invention relates to a process for coating a surface through graft polymerization, characterized in that before graft polymerization, the surface is modified, in the presence of an amine of formula: wherein R1 is hydrogen or a group R4, R2 and R3 are each independently a group R4, and R4 is [-1,2-C2-C3alkylen-T-]n-H wherein T is O or NH and n is a number from 1 to 3, by a compound having a functional group: wherein R5 to R7 are each C1-C4alkyl. The amount of amine is preferably from 5 to 500 g/m2 of surface of the substrate particle. The amount of the trialkoxysilane compound is preferably from 0.1 to 2 g/m2 of surface of the substrate particle. The process for coating a surface is particularly useful for effect pigments.Type: GrantFiled: May 17, 2002Date of Patent: March 16, 2004Assignee: Ciba Specialty Chemicals CorporationInventors: Ryuichi Takahashi, Adrian Schulthess, Kimiya Takeshita, Fritz Herren, Patrice Bujard
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Patent number: 6699529Abstract: A method for coating vehicular radiators with an ozone depleting manganese oxide catalyst in slurry form utilizes a robotic arm with multiple spray heads for spraying the face of the radiator. Each head is in fluid communication with its own dedicated peristaltic pump. The pumps are independently valved into and out of fluid communication with select heads as a function of the spray pattern effected by robotic arm movement.Type: GrantFiled: May 20, 2002Date of Patent: March 2, 2004Assignee: Engelhard CorporationInventors: James William Garner, Donald Allan Craig, Jeffrey Barmont Hoke, Dieter Lischitzki
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Patent number: 6695931Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220° F.) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).Type: GrantFiled: January 2, 2003Date of Patent: February 24, 2004Assignee: Birchwood Laboratories, Inc.Inventors: Keith N. Ravenscroft, William V. Block
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Patent number: 6696104Abstract: A substrate carrying a mixed organic conductive polymer coating, has a high index of refraction. On a substrate having SiO2 as a major component, the coating comprises two layers each having SiO2 as a major component. One of the layers comprises a conducting polymer, the other a material having a high index of refraction.Type: GrantFiled: January 25, 2002Date of Patent: February 24, 2004Assignee: Koninklijke Philips Electronics N.V.Inventors: Henricus X. Willems, Bauke H. Zwerver, Gerardus V. A. Aben, Johannes M. A. A. Compen
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Patent number: 6689476Abstract: A hydrophobic coating is provided. The coating has a high contact angle &thgr; which does not significantly decrease or degrade upon lengthy exposure to ultraviolet (UV) radiation. In certain embodiments, the coating has a contact angle &thgr; of at least 70 degrees both before and after significant exposure to UV radiation.Type: GrantFiled: June 27, 2001Date of Patent: February 10, 2004Assignee: Guardian Industries Corp.Inventors: Vijayen S. Veerasamy, Rudolph Hugo Petrmichl
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Patent number: 6682640Abstract: Disclosed herein is a method for producing a gas sensor, comprising disposing a reference electrode on a side of an electrolyte, disposing a measuring electrode on a side of the electrolyte opposite the reference electrode, disposing a first protective coating on a side of the measuring electrode opposite the electrolyte, treating the sensor with an aqueous salt solution comprising chloride and carbonate salts comprising elements selected from the group consisting of Group IA and IIA elements of the Periodic Table to form a treated sensor comprising the chloride and the carbonate salt mixture, drying the treated sensor, and disposing a second protective coating on a side of the first protective coating opposite the measuring electrode.Type: GrantFiled: June 13, 2002Date of Patent: January 27, 2004Assignee: Delphi Technologies, Inc.Inventors: Kailash C. Jain, Eric Clyde, Da Yu Wang, Paul Kikuchi
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Patent number: 6679978Abstract: A photocatalytically-assisted self-cleaning (“PASC”) coating on a substrate enables the substrate to shed dirt simply by rinsing with water. A method of making a PASC coating includes depositing by chemical vapor deposition an alkali metal diffusion barrier layer on a substrate; sputtering an ultraviolet radiation activated layer on the alkali metal diffusion barrier layer at a temperature of 100° C. or less; and, without heating above 100° C., exposing the ultraviolet radiation activated layer to ultraviolet radiation to form the self-cleaning substrate. The sputter deposition of the ultraviolet radiation activated layer on the chemical vapor deposited alkali metal diffusion barrier layer allows the ultraviolet radiation activated layer to be activated upon exposure to UV radiation without first having been heated during and/or after deposition.Type: GrantFiled: February 22, 2002Date of Patent: January 20, 2004Assignee: AFG Industries, Inc.Inventors: Herb Johnson, Mark Ford
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Patent number: 6677063Abstract: Hydrophilic and/or rutile and anatase titanium oxide are obtained by sputter depositing titanium metal oxide on a film of zirconium oxide in the cubic phase. Another technique is to deposit a titanium metal on a film of zinc oxide in the cubic phase and heating the coating in an oxidizing atmosphere to provide an anatase and/or rutile phase(s) of titanium oxide.Type: GrantFiled: August 30, 2001Date of Patent: January 13, 2004Assignee: PPG Industries Ohio, Inc.Inventor: James J. Finley
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Patent number: 6667072Abstract: This invention provides a concept of using porous materials on ceramic substrate planarization. This planarized substrate consists of a ceramic substrate, a buffer layer, and a nanostructure layer. The ceramic substrate provides structural strength and surface-mount capability. The buffer layer provides the adhesion between the substrate and the nanostructure layer. The nanostructure layer provides the required surface smoothness of the ceramic substrates for performing thin-film processing techniques and enhances adhesion for metallization and electronic materials.Type: GrantFiled: December 21, 2001Date of Patent: December 23, 2003Assignee: Industrial Technology Research InstituteInventors: Geoffrey Wen-Tai Shuy, Jong-Hong Lu, Sheng-Ju Liao, Huai-Luh Chang, Song-Wein Hong, Ruey-Cheng Huang
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Publication number: 20030224124Abstract: A process for depositing a ceramic coating system for Si-containing materials, particularly those for articles exposed to high temperatures. The process is particularly applicable to depositing a compositionally-graded coating system comprising multiple ceramic layers with differing compositions, including a dense, strain-tolerant, vertically-cracked YSZ-containing ceramic layer deposited on a ceramic layer having a composition that is a mixture of YSZ and either mullite or BSAS. The process entails depositing the YSZ-containing ceramic layer using a plasma spraying technique while maintaining the substrate at a temperature so as not to form horizontal cracks in the coating system, but still maintain the dense vertically-cracked structure of the YSZ-containing ceramic layer for strain tolerance.Type: ApplicationFiled: May 30, 2002Publication date: December 4, 2003Applicant: General Electric CompanyInventors: Yuk-Chiu Lau, Hongyu Wang, David Joseph Mitchell
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Patent number: 6656522Abstract: The invention includes a bilayer antireflection coating, multilayer antireflection coatings, and a method for making a multilayer antireflective coated substrate. The bilayer and multilayer coatings include layers having metallic oxides, at least one layer in each of such coatings having as a material with an index of refraction at least about 1.90, a layer comprising oxides of zirconium such that when subjected to heat treatments, such as tempering, the coatings substantially retain their optical properties. The coatings further include layers having materials of low index of refraction which include oxides of aluminum which provide coating stability and increased precursor storage life. In the method, the layers are applied by successive dip coating techniques using solvent-based solutions and the resulting coatings can be used to coat large sized substrates which can be later cut, trimmed and/or otherwise shaped and later heat treated with substantial retention of optical properties.Type: GrantFiled: May 6, 2002Date of Patent: December 2, 2003Assignee: Denglas Technologies, LLCInventors: Nanning J. Arfsten, Axel Reich, Frank Rodriguez, James F. Gavlas
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Patent number: 6656533Abstract: A coated article is prepared by furnishing an nickel-base article substrate having a free sulfur content of more than 0 but less than about 1 part per million by weight. A protective layer is formed at a surface of the article substrate. The protective layer includes a platinum aluminide diffusion coating. The protective layer may be substantially yttrium-free, or have a controlled amount of yttrium. A ceramic layer may overlie the protective layer.Type: GrantFiled: December 10, 2001Date of Patent: December 2, 2003Inventors: William S. Walston, Jon C. Schaeffer, Wendy H. Murphy
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Patent number: 6656605Abstract: A coated article is prepared by furnishing an article substrate having a free sulfur content of less than about 1 part per million. The low-sulfur article may be made of a material selected to have a low sulfur content, provided with a scavenging element that reacts with free sulfur to produce a sulfur compound, or desulfurized by contact with a reducing gas such as hydrogen. A platinum-group metal layer is deposited over the article substrate, and a ceramic coating is applied over the platinum-group metal layer.Type: GrantFiled: March 3, 1995Date of Patent: December 2, 2003Assignee: General Electric CompanyInventors: Jon C. Schaeffer, Mark A. Rosenzweig, Norman R. Lindblad, Wendy H. Murphy
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Patent number: 6656520Abstract: A non-carbon, metal-based, high temperature resistant, electrically conductive and electrochemically active anode of a cell for the production of aluminum has a metal-based substrate to which an adherent coating is applied prior to its immersion into the electrolyte and start up of the electrolysis by connection to the positive current supply. The coating is obtainable from one or more layers applied from: a liquid solution, a dispersion in a liquid or a paste, a suspension in a liquid or a paste, and a pasty or non-pasty slurry, and combinations thereof with or without one or more further applied layers, with or without heat treatment between two consecutively applied layers when at least two layers are applied.Type: GrantFiled: March 14, 2002Date of Patent: December 2, 2003Assignee: Moltech Invent-SAInventor: Vittorio de Nora
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Patent number: 6652906Abstract: A magnetoresistance sensor structure is fabricated by providing a substrate structure, depositing a magnetic pinning structure on the substrate structure, and depositing an oxidized copper spacer layer overlying the magnetic pinning structure. The deposition of the oxidized copper spacer layer includes depositing a first copper sublayer, oxidizing the first copper sublayer, depositing a second copper sublayer, and oxidizing the second copper sublayer. More deposition and oxidation steps may be used as necessary. A sensing structure is deposited overlying the oxidized copper spacer layer.Type: GrantFiled: November 19, 2002Date of Patent: November 25, 2003Assignee: Hitachi Global Storage Technologies Netherlands B.V.Inventor: Mustafa Pinarbasi
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Patent number: 6652905Abstract: A piezoelectric element includes a ceramic substrate, a piezoelectric ceramic composition composed mainly of a PbMg1/3Nb2/3O3—PbZrO3—PbTiO3 ternary system solid solution composition containing 0.05 to 10.0% by weight NiO, based on the ceramic composition. Electrodes are electrically connected to the piezoelectric. The piezoelectric is solidly attached to the ceramic substrate directly or via part of or all of the electrodes. The piezoelectric ceramic composition is represented by the following general formula: Pbx(Mgy/3Nb2/3)aTibZrcO3, wherein 0.95≦x≦1.05; 0.8≦y≦1.0; a, b and c are decimals falling in a range surrounded by (a,b,c)=(0.550, 0.425, 0.025), (0.550, 0.325, 0.125), (0.375, 0.325, 0.300), (0.100, 0.425, 0.475), (0.100, 0.475, 0.425) and (0.375, 0.425, 0.200), and a+b+c=1.000.Type: GrantFiled: January 30, 2003Date of Patent: November 25, 2003Assignee: NGK Insulators, Ltd.Inventor: Toshikatsu Kashiwaya
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Patent number: 6649214Abstract: A copper containing component and a manganese containing component are applied onto the surface of a substrate to form a coating having a selected ratio of copper to manganese to form a desired color. For a brown color, the film molar ratio of copper to manganese is above 1; for an amber color, the molar ratio is below 1, and for a blue color the film molar ratio is about 1. Further, color shifting of a multi-component coating upon subsequent heat treatment is minimized or prevented by determining the most mobile species in the coating and then placing a concentration gradient layer of an oxide of that mobile species between the substrate and the coating.Type: GrantFiled: March 17, 1999Date of Patent: November 18, 2003Assignee: PPG Industries Ohio, Inc.Inventors: Patricia Ruzakowski Athey, Luke A. Kutilek, John B. Slobodnik
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Patent number: 6638630Abstract: Coating solutions having anti-reflective and anti-static properties, a coating derived therefrom, a substrate coated with the coating and methods for their preparation. A coating includes a sol-gel alkoxide polymeric material and a conductive colloidal metal compound material.Type: GrantFiled: November 21, 2001Date of Patent: October 28, 2003Assignee: Chemat Technology, Inc.Inventors: Sung-Soon Park, Haixing Zheng
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Patent number: 6632513Abstract: An article includes an antireflection composite material, a substrate, and an inorganic layer deposited onto the substrate. The inorganic layer has a thickness of from about 1 nm to about 10 nm. The article includes a polymer layer in contact with the inorganic layer to form an outer surface of the antireflection composite material. The polymer layer has a thickness of from about 70 nm to about 120 nm.Type: GrantFiled: May 15, 2000Date of Patent: October 14, 2003Assignee: 3M Innovative Properties CompanyInventors: Hyung Chul Choi, Edward P. Lindholm, William K. Smyth, Pradnya V. Nagarkar
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Patent number: 6632480Abstract: A nickel-base superalloy article has a surface protective layer comprising nickel, from about 20 to about 35 weight percent aluminum, and from about 0.5 to about 10 weight percent rhenium. The protective layer, which is preferably an overlay coating of the beta (&bgr;) phase NiAl form, is formed by depositing nickel, aluminum, rhenium, and modifying elements onto the substrate surface. A ceramic layer may be deposited overlying the protective layer.Type: GrantFiled: October 3, 2002Date of Patent: October 14, 2003Assignee: General Electric CompanyInventors: Ramgopal Darolia, Joseph D. Rigney
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Publication number: 20030180445Abstract: A method of fabricating a catalytic bead sensor with improved stability by forming a coil of metal wire, depositing onto the coil of wire by CVD, PECVD, thermal spraying or electrophoretic deposition at least one first layer of an insulating, crack-free refractory coating, to form thereby a coil of coated wire, and depositing onto the coated wire coil at least one further layer to convert the coated wire coil to a sensing or compensating bead.Type: ApplicationFiled: March 21, 2002Publication date: September 25, 2003Applicant: Industrial Scientific CorporationInventors: Chuan-Bao Wang, P. Richard Warburton, Beth Tomasovic
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Patent number: 6623608Abstract: A method of manufacturing a display device having two components, an OLED display formed on a film on one side of a substrate and a touch screen formed on a film on the other side of the substrate, the OLED display including components that are sensitive to high temperatures, includes the steps of: partially forming one of the components on one side of the substrate, applying a protector over the partially constructed component; forming the other component of the display device on the other side of the substrate; removing the protector; and completing the formation of the one component on the one side of the substrate.Type: GrantFiled: February 8, 2002Date of Patent: September 23, 2003Assignee: Eastman Kodak CompanyInventors: Andre D. Cropper, Ronald S. Cok, Rodney Feldman
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Publication number: 20030175439Abstract: Provided are low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures. The invention provides solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one embodiment the invention provides techniques for firing of device substrate to form densified electrolyte/membrane films 5 to 20 microns thick. In another embodiment, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe, Cu and Ag, or alloys thereof.Type: ApplicationFiled: December 18, 2002Publication date: September 18, 2003Inventors: Craig P. Jacobson, Steven J. Visco, Lutgard C. DeJonghe
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Patent number: 6620530Abstract: A spin valve structure and a method for manufacturing it are described. The spin valve uses a modified pinned layer that consists of two cobalt iron layers separated by a layer of either ruthenium, iridium, or rhodium. A key feature of the invention is that this spacer layer is significantly thinner (typically 3-4 Angstroms) than similar layers in prior art structures. Normally, when such thin spacer layers are used, annealing fields in excess of 20,000 Oersted are needed to cause the two cobalt iron layers to become antiparallel. The present invention, however, teaches that much lower annealing fields (spanning a limited range) may be used with equal effect. The result is that a very high internal pinning field is created giving devices of this type greater pinned layer stability and reduced pinning reversal. These devices also exhibits a minimum amount of open looping in their hysteresis curves.Type: GrantFiled: January 26, 2001Date of Patent: September 16, 2003Assignee: Headway Technologies, Inc.Inventors: Min Li, Cheng T. Horng, Ru Ying Tong, Simon H. Liao, Kochan Ju
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Patent number: 6620462Abstract: A new method is provided for the creation of a protective layer over a glass substrate, the glass substrate has a first and a second surface. Under a first embodiment of the invention, a second surface of the glass panel is first coated with a layer of TiN. A first layer of amorphous silicon (A—Si) is deposited over the second surface of the glass panel. A second layer of amorphous silicon (A—Si) is deposited over the layer of TiN. A layer of photoresist is next deposited over the surface of the second layer of A—Si. The first layer of A—Si is removed from the second surface of the glass panel after which the layer of photoresist is removed. Under a second embodiment of the invention, the first and the second surface of the glass panel are coated with a first and a second layer of TiN. A layer of amorphous silicon (A—Si) is deposited over the second layer of TiN. A layer of photoresist is deposited over the layer of A—Si.Type: GrantFiled: May 23, 2002Date of Patent: September 16, 2003Assignee: Taiwan Semiconductor Manufacturing CompanyInventors: Ya-Chien Huang, Bao-Ru Young, Shin-Shiung Chen
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Patent number: 6616978Abstract: A substrate is protected by a multilayer protective coating having an oxide layer, and a phosphate/organic binder layer initially overlying the oxide layer. The multilayer protective coating is cured by first degassing the multilayer protective coating in a pre-cure degassing temperature range of from about 250° F. to about 500° F. for a time of at least about 30 minutes. The multilayer protective coating is thereafter heated to a curing temperature range of from about 1200° F. to about 1400° F. for a time of at least about 30 minutes.Type: GrantFiled: May 9, 2002Date of Patent: September 9, 2003Assignee: General Electric CompanyInventors: Michael James Weimer, Joseph Aloysius Heaney, Bangalore Aswatha Nagaraj, James Andrew Hahn
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Patent number: 6610422Abstract: The method for manufacturing coated steel sheet has the steps of: immersing a steel sheet in a hot-dip coating bath to form an Al—Zn base coating layer containing 20 to 95 mass % Al on the steel sheet, forming a passivated layer on the coating layer; and applying thermal history to the coating layer. The thermal history is applied immediately after the steel sheet left the hot-dip coating bath or in a temperature range of from T(° C.) between 130° C. and 300° C. to 100° C.Type: GrantFiled: September 26, 2002Date of Patent: August 26, 2003Assignee: NKK CorporationInventors: Toshihiko Ooi, Takafumi Yamaji, Keiji Yoshida, Yuichiro Tanaka, Junichi Inagaki, Masaaki Yamashita, Yasuhiro Majima, Nobuyuki Ishida, Yuichi Fukushima, Norio Inoue, Shinji Hori
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Patent number: 6607789Abstract: A method for forming a thermal barrier coating system on an article subjected to a hostile thermal environment, such as the hot gas path components of a gas turbine engine. The coating system is generally comprised of a ceramic layer and an environmentally resistant beta phase nickel aluminum intermetallic (&bgr;-NiAl) bond coat that adheres the ceramic layer to the component surface. A thin aluminum oxide scale forms on the surface of the &bgr;-NiAl during heat treatment. The &bgr;-NiAl may contain alloying elements in addition to nickel and aluminum in order to increase the environmental resistance of the &bgr;-NiAl. The &bgr;-NiAl powder having a size in the range of 20-50 microns is applied using air plasma spray techniques to produce a surface having a roughness of 400 microinches or rougher. The ceramic top coat can be applied using inexpensive thermal spray techniques to greater thicknesses than achievable otherwise because of the rough surface finish of the underlying &bgr;-NiAl bond coat.Type: GrantFiled: April 26, 2001Date of Patent: August 19, 2003Assignee: General Electric CompanyInventors: Joseph David Rigney, Michael James Weimer, Bangalore Aswatha Nagaraj, Yuk-Chiu Lau
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Patent number: 6605147Abstract: The use of surface-coated rutile modification TiO2 pigments having a primary particle grain size d50 of 0.1 to 1.0 &mgr;m as an anticorrosive white pigment, with firstly magnesium phosphate and secondly aluminum oxides and/or aluminum hydroxides being precipitated onto the TiO2 pigments, is described.Type: GrantFiled: June 14, 2002Date of Patent: August 12, 2003Assignee: Sachtleben Chemie GmbHInventors: Thomas Rentschler, Jochen Winkler
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Patent number: 6605316Abstract: Provided are low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures. The invention provides solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one embodiment the invention provides techniques for co-firing of device substrate (often an electrode) with an electrolyte or membrane layer to form densified electrolyte/membrane films 5 to 20 microns thick. In another embodiment, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe, Cu and Ag, or alloys thereof.Type: GrantFiled: July 27, 2000Date of Patent: August 12, 2003Assignee: The Regents of the University of CaliforniaInventors: Steven J. Visco, Craig P. Jacobson, Lutgard C. DeJonghe
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Patent number: 6602607Abstract: A titanium dioxide photocatalyst carrier is prepared by coating a surface of a substrate with a titanium dioxide precursor solution prepared from a hydrolyzable titanium compound and an aromatic compound solvent, and then heat-treating the coated substrate thereby preparing a carrier coated with a thin layer of titanium oxide.Type: GrantFiled: March 27, 2001Date of Patent: August 5, 2003Assignees: Japan Carlit Co., Ltd., Shin Nikkei Company, Ltd., Asahi Glass Company, LimitedInventors: Seiichi Rengakuji, Yosuke Hara, Akihiro Shinagawa
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Patent number: 6599568Abstract: A cooling system for cooling of the flow path surface region of an engine component used in a gas turbine engine and a method for making a system for cooling of the flow path surface region of an engine component used in a gas turbine engine. The method comprises the steps of channeling apertures in a substrate to a diameter of about 0.0005″ to about 0.02″ to allow passage of cooling fluid from a cooling fluid source; applying a bond coat of about 0.0005″ to about 0.005″ in thickness to the substrate such that the bond coat partially fills the channels; applying a porous inner TBC layer of at least about 0.01″ in thickness to the bond coat, such that the TBC fills the channels; applying an intermediate ceramic layer that is more dense than the inner TBC layer on top of the porous TBC; applying an outer TBC layer over the intermediate layer; and, passing cooling fluid from a cooling fluid source through the channel into the porous TBC.Type: GrantFiled: September 19, 2002Date of Patent: July 29, 2003Assignee: General Electric CompanyInventors: Ching-Pang Lee, Robert Edward Schafrik, Ramgopal Darolia
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Patent number: 6599581Abstract: A base member is blasted to roughen the surface. Next, a thermal spray member containing for example Al is formed on the blast treated surface of the base member by a thermal spraying. Next, an extremely thin oxide film at an atom layer level is coated on the surface of the thermal spray member, as an uppermost surface. The oxide film is a layer that is formed from stacked layers of about 15 to 23 atoms, and is formed by an O2 or O3 gas plasma, an atmospheric pressure plasma, or a CVD (chemical vapor deposition) method. A nitride film can be coated instead of the oxide film.Type: GrantFiled: January 22, 2002Date of Patent: July 29, 2003Assignee: Seiko Epson CorporationInventor: Masao Shibasaki
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Patent number: 6599587Abstract: Disclosed is an organometallic precursor for forming a metal pattern, having a structure defined by the following Formula 1, and a method of forming the metal pattern using the same, in which the conductive metal pattern is readily formed through an exposing step without using a photo-resist.Type: GrantFiled: September 11, 2002Date of Patent: July 29, 2003Assignee: Samsung Eleectronics Co., Ltd.Inventors: Min Chul Chung, Soon Taik Hwang, Young Hun Byun, Euk Che Hwang
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Publication number: 20030138554Abstract: A method for manufacturing an electrode for a lithium secondary battery includes a step of forming an oxide film other than a natural oxide film on a current collector by oxidizing the surface of the current collector, and a step of forming an active material layer on the oxide film by a method to provide a material for the active material layer by emitting in the vapor phase, such as PVD (physical vapor deposition) including sputtering, vapor evaporation, and the like, and CVD (chemical vapor deposition) including plasma CVD.Type: ApplicationFiled: January 17, 2003Publication date: July 24, 2003Inventors: Hiromasa Yagi, Hisaki Tarui
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Patent number: 6596040Abstract: Coated abrasive particle for use in vitreous bond matrices, which particle is coated with between 1 and about 50 coating layers. Each coating layer ranges in thickness from between about 0.1 and 50 microns. Each layer has the composition, MCxNyBzOw, where, M represents one or more of Ti, Si, V, Cr, Zr, Nb, Mo, Hf, Ta, W, Re or a rare earth metal, and w, x, y, and z, each range from between 0 and 3. The outermost coating layer has a concentration of oxygen that is higher by a factor of at least about 2 than the layer in direct contact with the abrasive particle.Type: GrantFiled: June 19, 2002Date of Patent: July 22, 2003Assignee: General Electric CompanyInventors: Aaron W. Saak, Mark P. D'Evelyn, Chung S. Kim, Michael H. Zimmerman, Steven W. Webb