Entirely Inorganic Patents (Class 428/552)
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Patent number: 4844988Abstract: A diamond composite combined with a cobalt-containing substrate, comprising: a sintered mass of diamond, in which practically all the diamond particles are joined immediately with adjacent particles, a mass of cobalt-containing carbide, said latter mass being larger than the former and said first and latter masses being of a same cross section at the opposed ends, and an intermediate layer of a solid material which consists of Mo, Co and C with a minor proportion of inevitable impurities and which comprises a molybdenum carbide exhibiting a melting point within 200 degrees C. of that of the first said carbide material, said layer intervening between the masses and having a total radial cross sectional area of at least 80% but not greater than 97% of that of the diamond mass and carbide masses at the joint and a thickness of, at least, 25 microns over the whole cross sectional area and method for producing the same.Type: GrantFiled: December 22, 1987Date of Patent: July 4, 1989Assignee: The Ishizuka Research Institute, Ltd.Inventors: Hiroshi Ishizuka, Satoshi Hayakawa
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Patent number: 4837089Abstract: A composite sintered compact consisting of a sintered body portion, which contains at least one of high density boron nitride and diamond, and a cermet or metal portion bonded to the sintered body portion through an amorphous metal interposed between the sintered body portion and the cermet or metal portion at their bonding area, has high hardness and strength, and further has excellent handleability, heat resistance and toughness during the whole processes ranging from its production to its consumption.Type: GrantFiled: December 14, 1987Date of Patent: June 6, 1989Assignee: Nippon Oil and Fats Company, LimitedInventors: Masatada Araki, Yutaka Kuroyama
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Patent number: 4833039Abstract: A process for producing an hermetic feedthrough in a ceramic substrate by providing a sheet of liquid phase sinterable ceramic composition having a feedthrough hole, filling the feedthrough hole with refractory metal metallization material, firing the resulting structure to produce a sintered substrate and adherent metallization wherein the metallization is comprised of continuous phases of refractory metal and glass, contacting the refractory metal with electrically conductive intrusion metal and heating the resulting structure to a temperature at which the glassy phase is fluid, the refractory metal is solid, and the intrusion metal is liquid whereby the liquid metal preferentially wets the refractory metal, migrates into the metallization displacing glass and, upon subsequent solidification, partially or wholly occupies the volume space originally containing the continuous glass phase.Type: GrantFiled: November 25, 1987Date of Patent: May 23, 1989Assignee: General Electric CompanyInventors: Stephan P. Mitoff, Richard J. Charles, Wayne D. Pasco
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Patent number: 4830931Abstract: Diffusion aluminizing with chromium or silver chloride, bromide or iodide that is not significantly soluble in or reactive with water. Hydrogen can be excluded from diffusion aluminizing atmosphere when aluminizing maraging steels or other substrates sensitive to hydrogen. Aluminized iron powders can be boronized to increase their exothermic heat upon exposure to air after leaching out aluminum.Type: GrantFiled: October 3, 1983Date of Patent: May 16, 1989Assignee: Alloy Surfaces Company, Inc.Inventor: Alfonso L. Baldi
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Patent number: 4830930Abstract: There are disclosed a surface refined sintered alloy body which comprises a hard phase containing at least one selected from the group consissting of carbides, carbonitrides, carbooxides, carbonitrooxides of the metals of the groups 4a, 5a and 6a of the periodic table and a binding phase containing at least one selected from iron group metals, characterized in that the concentration of the binding phase in the surface layer (of from 10 .mu.m to 500 .mu.m from the surface of the sintered alloy) is highest at the outermost surface thereof and approaches the concentration of the inner portion, the concentration of the binding phase decreasing from the outermost surface to a point at least 5 .mu.m from the surface; and a method for making the same by applying decarburization treatment at the surface of the sintered alloy at temperatures within the solid-liquid co-existing region of the binding phase after sintering or in the process of sintering.Type: GrantFiled: April 7, 1988Date of Patent: May 16, 1989Assignee: Toshiba Tungaloy Co., Ltd.Inventors: Yasuro Taniguchi, Ko Sasaki, Mitsuo Ueki, Keiichi Kobori
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Patent number: 4812370Abstract: A surface coated tungsten carbide-base sintered hard alloy material for inserts of cutting tools having excellent wear resistance and toughness comprising(1) a substrate having an internal portion consisting essentially of 5-30 percent by weight of one composite metal carbo-nitride, as a compound forming a hard dispersion phase, selected from the group consisting of (Ti, W)CN, (Ti, Nb, W)CN, (Ti, Ta, W)CN, and (Ti, Nb, Ta, W)CN; 4-10 percent Co as a component forming a binder phase, and the balance of WC as a component forming the hard disperse phase and inevitable impurities; the substrate having a surface portion formed with a Co-enriched layer being substantially free of the composite metal carbo-nitride; and(2) a hard surface layer coated over the surface of the substrate, comprising an innermost layer consisting essentially of TiC, the innermost layer containing one of a W component and W and Co components diffused from the substrate; a diffusion preventing layer formed by one of a single layer of one coType: GrantFiled: September 25, 1987Date of Patent: March 14, 1989Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Yoshikazu Okada, Jun Sugawara, Sumiyoshi Takizawa
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Patent number: 4797155Abstract: A metal matrix composite is produced by plastically deforming a metal powder, either or after blending the powder with ceramic fibers, and compacting the mixture at elevated temperatures to achieve substantially full density. Imparting strain energy to the metal allows reduction of the compaction temperature to eliminate reaction between the fibers and the metal or degradation of the fibers. Silicon nitride fibers are thermodynamically superior for use in aluminum or titanium metal matrix composites, since silicon nitride fibers are more stable at the temperatures required for full compaction. Secondary phase reactions are avoided.Type: GrantFiled: February 27, 1987Date of Patent: January 10, 1989Assignee: The Boeing CompanyInventor: K. Bhagwan Das
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Patent number: 4797326Abstract: Disclosed is a process for fabricating a composite polycrystalline diamond or cubic boron nitride (CBN) compact. Briefly, the process is conducted by mating a pre-formed sintered polycrystalline diamond or CBN compact and a plastically deformable support, and subjecting the mated composite compact to elevated temperature and pressure conditions sufficient to plastically deform the support into attachment with the compact. The temperature, pressure and time of application are inadequate to cause degradation of the diamond or CBN compact. The product configuration may be a conventional layered compact or may be a wire drawing die having a polycrystalline diamond or CBN core with a support jacket of a material such as a cemented metal carbide.Type: GrantFiled: January 14, 1986Date of Patent: January 10, 1989Assignee: The General Electric CompanyInventor: Frank J. Csillag
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Patent number: 4781989Abstract: A surface-coated cutting member includes a substrate, a metal layer vapor-deposited on a surface of the substrate and a hard coating vapor-deposited on the metal layer. The substrate is made of hard material selected from the group consisting of tungsten carbide-based cemented carbide, titanium carbo-nitride based cermet and high speed steel. The metal layer is made of metal selected from Group IVa of the Periodic Table and has an average thickness of 0.1 to 1 .mu.m. The hard coating has an average thickness of 1 to 9 .mu.m, and includes an inner layer of an average thickness of 0.2 to 4 .mu.m vapor-deposited on the metal layer, an intermediate layer of an average thickness of 0.2 to 4 .mu.m vapor-deposited on the inner layer and an outer layer of an average thickness of 0.2 to 3 .mu.m vapor-deposited on the intermediate layer.Type: GrantFiled: March 5, 1987Date of Patent: November 1, 1988Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Hironori Yoshimura, Munenori Kato
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Patent number: 4780274Abstract: A method of manufacturing by a powder metallurgy process a rotary drill bit including a bit body having a plurality of cutting elements mounted on the outer surface thereof comprises the steps of forming a hollow mould for moulding at least a portion of the bit body, packing the mould with powdered matrix material, and infiltrating the material with a metal alloy in a furnace to form a matrix. Before packing the mould with powdered matrix material, there are postioned in spaced locations on the interior surface of the mould a plurality of cutting element, each of which is formed of a material, such as a polycrystalline diamond material, which is thermally stable at the temperature necessary to form the matrix. Also positioned in the mould, adjacent the rearward side of each cutting element, is a support material such that, at least after formation of the matrix, the support material has a higher modulus of elasticity than the matrix.Type: GrantFiled: October 24, 1986Date of Patent: October 25, 1988Assignee: Reed Tool Company, Ltd.Inventor: John D. Barr
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Patent number: 4778730Abstract: The working surface of a tool such as the tip of a screwdriver is provided with a non-slip coating by means of hard abrasive particles which are bonded to the tool with a brazing alloy.Type: GrantFiled: September 9, 1987Date of Patent: October 18, 1988Assignee: RemGrit CorporationInventor: Jerry Zucker
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Patent number: 4775598Abstract: A process is described in which hollow spheres or hollow-sphere composites (moldings) having high-strength walls are produced. Additional layers are applied to metallized spherical lightweight particles having a core of foamed polymer. In order to increase the strength of the wall of the spherical particle and the strength of the molding, metallized lightweight spherical particles having a metal wall thickness of 5 to 20 microns are treated (coated) with a dispersion of particulate metal or metal oxide or particulate ceramic or refractory material, the lightweight spherical particles coated in a thickness from 15 to 500 microns are dried, the dried particles are heated to a temperature of about 400.degree. C. to effect a pyrolysis of the polymer core, and the particles are subsequently sintered at a temperature from 900.degree. to 1400.degree. C.Type: GrantFiled: November 25, 1987Date of Patent: October 4, 1988Assignee: Norddeutsche Affinerie AkitiengesellschaftInventor: Manfred Jaeckel
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Patent number: 4766040Abstract: Temperature resistant abrasive polycrystalline diamond bodies are described, intended for use as tools in various mechanical operations like turning, milling, drilling, sawing and drawing, having different additions, i.e. amount and composition, of binding, fluxing, catalyst metals at different distances from the working surface. Preferably the metal concentration of the polycrystalline diamond body is decreasing towards the working surface while the metal composition is varied in a way that gives a mechanically stiffer matrix that also has a lower thermal expansion.In one embodiment the diamond body is high pressure-high temperature-bonded to a supporting body, e.g. of cemented carbide, in order to facilitate the clamping of the tool. In another embodiment the diamond body is brazed to a supporting body or used in a surface-set rock drill bit, i.e. held by a braze metal.Type: GrantFiled: June 26, 1987Date of Patent: August 23, 1988Assignee: Sandvik AktiebolagInventors: Lars H. Hillert, Mats G. Waldenstrom
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Patent number: 4764341Abstract: The bonding of nickel, cobalt, copper or any number of metals to oxide ceramics is achieved whereby the substrate and associated metallurgy are co-sintered. The invention teaches the use of an intermediary oxide such as Al2O3, Cr2O3, TiO2 or ZrO2 which will adhere to the substrate and in the presence of firing ambients form a complex ternary oxide with the overlying metal thereby creating the desired bond. The eutectic can be created during the firing cycle without the undesired consequence of oxidizing the metal. The so-called intermediary oxides can be oxidized in situ, deposited as oxides, or introduced into either the ceramic composition or the metal paste.Type: GrantFiled: April 27, 1987Date of Patent: August 16, 1988Assignee: International Business Machines CorporationInventors: Philip L. Flaitz, Raj N. Master, Paul H. Palmateer, Srinivasa S. N. Reddy
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Patent number: 4762754Abstract: Shock wave formation of superconductive ceramic oxide electric and magnetic circuit elements with improved microstructures and mechanical properties.Type: GrantFiled: October 23, 1987Date of Patent: August 9, 1988Assignee: The United States of America as represented by the United States Department of EnergyInventors: William J. Nellis, M. Brian Maple, Theodore H. Geballe
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Patent number: 4761344Abstract: A rocker arm of a valve mechanism of an automotive internal combustion engine is composed of a rocker arm tip secured to a rocker arm main body. The rocker arm tip includes a sheet type sintered alloy adhered to a steel substrate. The sintered alloy includes a joining phase of martensite stainless steel, and a hard phase of boride and/or multiple boride of at least one, including iron, of elements capable of forming boride and/or multiple boride. The hard phase is homogeneously dispersed in the joining phase. The sintered alloy contains boron ranging from 3.0 to 5.0% by weight, and the hard phase ranging from 40 to 62% by weight. Additionally, the sintered alloy has a maximum grain size of the boride and/or multiple boride ranging not larger than 50 .mu.m, a Rockwell A-scale hardness number ranging not less than 80, and a deflective strength ranging not lower than 175 kgf/mm.sup.2.Type: GrantFiled: April 9, 1987Date of Patent: August 2, 1988Assignee: Nissan Motor Co., Ltd.Inventors: Yoshihiro Maki, Makoto Kano, Akira Fujiki, Ichiro Tanimoto
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Patent number: 4761345Abstract: There is disclosed an aluminum nitride substrate which comprises a substrate composed of an aluminum nitride sintered product; an electroconductive metallized layer composed of titanium nitride and at least one selected from the group consisting of molybdenum, tungsten, tantalum, an element in group III of the periodic table, an element in group IVa of the same, a rare earth element, an actinide element and a compound containing these elements; and an electroconductive protective layer laminated in this order on the aluminum nitride sintered product.Type: GrantFiled: February 20, 1987Date of Patent: August 2, 1988Assignee: Kabushiki Kaisha ToshibaInventors: Hideki Sato, Nobuyuki Mizunoya, Mitsuhiro Nagata
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Patent number: 4752535Abstract: Described are an aluminium-based article having a heat and corrosion protective coating, especially engine parts such as piston crown or cylinder head, and a method of preparing said article. The coating consists of an aluminium-based bonding layer, preferably having a thickness in the range 0.1-0.6 mm, and an outer top layer of stabilized or partially stabilized zirconium dioxide, preferably having a thickness in the range 0.5-2.5 mm, and optionally a cermet layer, comprising zirconium dioxide and an aluminium-based metal component, between the bonding layer and the outer zirconium dioxide top layer. The bonding layer is applied to the substrate by thermal spraying of a rapidly solidified powder, substantially consisting of 60-80% by weight of Al and 40-20% by weight of Si, the particles of the powder having a frozen unstable micro-structure.Type: GrantFiled: September 10, 1986Date of Patent: June 21, 1988Assignee: Norsk Hydro a.sInventor: Ingard Kvernes
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Patent number: 4745033Abstract: A molybdenum article is disclosed in which the substrate thereof has adherently bonded thereto a thermally self-healing plasma-sprayed coating consisting essentially of a composite of molybdenum and a refractory oxide material capable of reacting with molybdenum oxide under oxidizing conditions to form a substantially thermally stable refractory compound of molybdenum. The plasma-sprayed coating is formed of a plurality of interbonded plasma-sprayed layers of a composite of molybdenum/refractory oxide material produced from a particulate mixture thereof. The coating comprises a first layer of molybdenum plasma-sprayed bonded to the substrate of said molybdenum element and a second layer of plasma-sprayed mixture of particulate molybdenum/refractory oxide consisting essentially of predominantly molybdenum bonded to the first layer.Type: GrantFiled: March 24, 1987Date of Patent: May 17, 1988Assignee: AMAX Inc.Inventor: George A. Timmons
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Patent number: 4743512Abstract: A method of manufacturing a flat form from blended metallic powder including a major constituent by weight having a high melting point and a minor constituent by weiht having a substantially lower melting point includes selection of the powder to provide continuous and reproducible compacted flat forms. Powder is selected on the basis of compressibility and flowability. The selected powder is compacted to a flat green form and then liquid phase sintered. The flat form may be stacked to provide a flat article of a desired thickness which will result in a monolithic or composite cross section when subsequently sintered. Liquid phase sintering is carried out in a manner designed to avoid undesirable embrittlement and to provide a uniform microstructure in the fully consolidated article. The process is especially useful in the production of tungsten heavy alloy plate.Type: GrantFiled: June 30, 1987Date of Patent: May 10, 1988Assignee: Carpenter Technology CorporationInventors: David T. Marlowe, Gregory J. Del Corso, Robert E. Carnes, David Esposito, William J. Burns, II, Edward F. Holland, David L. Strobel
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Patent number: 4731296Abstract: A diamond-coated tungsten carbide-base sintered hard alloy material for inserts of cutting tools, which has greatly improved bond strength or degree of bonding of the diamond coating layer to the matrix and therefore is capable of exhibiting excellent cutting performance over a long period of time.The sintered hard alloy material comprises:(1) a matrix of a sintered hard alloy consisting essentially of 1-4 percent by weight cobalt, and the balance of tungsten carbide and inevitable impurities, the tungsten carbide having a coarse grain structure having an average grain size of 2-10 microns; and(2) a diamond coating layer formed over surfaces of the matrix by forming an etching layer over the matrix surfaces and then forming the diamond coating layer over the matrix surfaces via the etching layer by a low pressure vapor-phase synthesization method.If required, the matrix may further contain CO1-CO8 (ISO) free carbon.Type: GrantFiled: June 24, 1987Date of Patent: March 15, 1988Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Noribumi Kikuchi, Tetsuro Komatsu, Hiroaki Yamasita, Hironori Yoshimura
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Patent number: 4717627Abstract: Shock wave formation of thin layers of materials with improved superconducting and permanent magnetic properties and improved microstructures.Type: GrantFiled: December 4, 1986Date of Patent: January 5, 1988Assignee: The United States of America as represented by the United States Department of EnergyInventors: William J. Nellis, Theodore H. Geballe, M. Brian Maple
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Patent number: 4715892Abstract: The present invention is directed to a cermet material comprising a matrix of metal or alloy with ceramic particles distributed therein. The cermet includes a glass binder for bonding between the metal or alloy and the ceramic particles.Type: GrantFiled: October 30, 1986Date of Patent: December 29, 1987Assignee: Olin CorporationInventor: Deepak Mahulikar
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Patent number: 4714641Abstract: A ferromagnetic film for magnetic recording comprises a copper substrate having particles of iron and iron oxides dispersed in the surface layer of the copper. The particles have maximum dimensions in the range between 50 and 500 Angstroms. The ferromagnetic film can be formed by ion implantation of iron ions into the copper substrate followed by heat treatment to permit growth of ferromagnetic particles to the desired size. As an alternative to ion implantation, the iron can be deposited on the copper substrate by sputtering or evaporation and mixed with the copper by ion beam mixing.Type: GrantFiled: March 4, 1985Date of Patent: December 22, 1987Assignee: Varian Associates, Inc.Inventor: Bernhard F. Cordts
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Patent number: 4713300Abstract: This invention provides a shaped, graded, cermet article comprising at least one continuous ceramic phase and at least one discontinuous metal phase, the ratio of ceramic/metal being controlled and varied over the thickness of the article. The ceramic phase preferably is microcrystalline.Type: GrantFiled: December 13, 1985Date of Patent: December 15, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventors: Harold G. Sowman, David R. Kaar
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Patent number: 4704336Abstract: A solid particle erosion resistant coating includes angular titanium carbide particles uniformly dispersed through a high chromium iron matrix. In one form, the aggregate comprises, by weight, about 30-50% TiC, about 10-30% Cr, about 1.5-5% C and the balance essentially iron in the form of ferrite. The matrix also includes metallurgically identifiable amounts of high chromium content M.sub.7 C.sub.3 carbides therethrough. The coating does not exhibit austenitic or martensitic structure therethrough. A powder alloy consolidated body also includes a surface adjacent region having a similar TiC and high chromium iron matrix. Further, a method for obtaining the coating includes heating above the austenitization temperature of the matrix alloy and below the melting temperature of iron, and cooling the aggregate so as to attain iron in the form of ferrite in the matrix.Type: GrantFiled: March 5, 1986Date of Patent: November 3, 1987Assignee: General Electric CompanyInventor: Donald R. Spriggs
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Patent number: 4702884Abstract: A method of producing a glass-lined metal pipe in which an unconsolidated tal or metal alloy powder is loaded into a sealable glass mold comprising a graphite core, a glass sleeve slipped over the graphite core with a sliding fit, a sealable outer glass envelope surrounding the graphite core and glass sleeve forming with them a sealable chamber for the metal or metal alloy powder, wherein the glass is a type which becomes plastic when heated. The air in the mold is removed under vacuum and the mold is sealed and placed into a free flowing refractory powder in a crucible and consolidated by sintering under atmospheric pressure (CAP.RTM. process). Removal of the glass envelope and the graphite core produces a glass-lined pipe in which the glass liner is slightly fused into and is under compressive force from the surrounding metal pipe.Type: GrantFiled: July 3, 1986Date of Patent: October 27, 1987Assignee: The United States of America as represented by the Secretary of the NavyInventor: David Goldstein
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Patent number: 4698269Abstract: A porous, sintered powdered metal article having excellent corrosion resistance is provided. A porous metal such as prepared from a sintered iron powder and suitable for further treatment is phosphatized with a solvent phosphatizing composition. The phosphatized metal is then coated with a chromium-containing coating composition. The thus treated powdered metal part may be further topcoated and, in either case, exhibits outstanding corrosion resistance.Type: GrantFiled: May 8, 1986Date of Patent: October 6, 1987Inventors: Michael J. Narusch, Jr., Stanley G. LeBail
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Patent number: 4696352Abstract: A coated insert for such drilling tool bits as mine tool roof bits or masonry drill bits. A hard, fracture resistant substrate is coated with one or more thin adherent layers of refractory coating material. The material of each layer is a carbide, nitride, or carbonitride of titanium, hafnium, vanadium, tantalum, or niobium, or an oxide of aluminum or zirconium or a mixture or solid solution of these compounds. Methods for drilling holes in a mine roof or other hard materials are also disclosed.Type: GrantFiled: March 17, 1986Date of Patent: September 29, 1987Assignee: GTE Laboratories IncorporatedInventors: Sergej-Tomislav Buljan, J. Gary Baldoni
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Patent number: 4695321Abstract: This invention relates to high-hardness, high-toughness, high-density composite materials containing diamond, and a process for making such materials comprising applying shock compression to the composite powders and inducing an exothermic chemical reaction. The process is useful in making metal, ceramic and cermet diamond composite materials.Type: GrantFiled: May 1, 1986Date of Patent: September 22, 1987Assignee: New Mexico Tech Research FoundationInventors: Tamotsu Akashi, Akira Sawaoka
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Patent number: 4689197Abstract: A denture with a metallic microstructure and with low shrinkage and porosity is produced by metallurgical sintering by providing a multimodal size distribution of coarse and fine fractions of metal powder, optionally also with glass or ceramic powder, converting this powder mixture with water into a slip, modelling the denture with this, and sintering the slip at a temperature which exceeds the solidus temperature of at least one component of the powder mixture.Type: GrantFiled: April 4, 1986Date of Patent: August 25, 1987Assignee: Degussa AktiengesellschaftInventors: Werner Groll, Josef Rothaut, Angela Klaus, Rudi Steinke
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Patent number: 4689270Abstract: To permit firing a composite carrier for a printed circuit in which the carrier has a base of metal, typically steel, and thus is highly vibration and bending resistant, the coating or cover layer is a glass ceramic of BaO-Al.sub.2 O.sub.3 -SiO.sub.2, typically 25 to 40%, preferably 35% of BaO, 5 to 20%, preferably 10% Al.sub.2 O.sub.3 and 40 to 65%, preferably about 55% SiO.sub.2. Rather than using 40 to 65% SiO.sub.2, a lesser quantity of SiO.sub.2, e.g., 30 to 65% may be used and then 0 to 15% MgO, 0 to 15% CaO, 0 to 5% SrO, 0 to 2% B.sub.2 O.sub.3, 0 to 4% PbO, 0 to 3% ZnO and 0 to 4% TiO.sub.2 may be applied. The glass ceramic may be dyed, for example by an inorganic dye, such as cobalt silicate, and standard resistor and conductor pastes, such as Cermalloy or Heraprint may be applied and fired at temperatures below 980.degree. C., and entirely suitable for firing temperatures above 850.degree. C. The coating or cover layer has a thickness of above 20 micrometers, preferably of between about 0.03 to 0.Type: GrantFiled: July 16, 1985Date of Patent: August 25, 1987Assignee: W. C. Heraeus GmbHInventors: Karl Deckelmann, Jurgen Hornung, Graham S. Jones, Roland Kersting, Quentin Reynolds, Ino Taitl
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Patent number: 4681817Abstract: This piston ring has a composite plated layer at least on its outwardly facing sliding surface. The composite plated layer includes a quantity of hard particles of a granular dispersion material dispersed in a matrix of matrix metal consisting essentially of nickel-cobalt-phosphorous alloy containing about 10% to about 40% by weight of cobalt, about 2% to about 15% by weight of phosphorous, and remainder substantially nickel. It may also further include a quantity of lubricating particles having average particle diameter of from about 0.5 microns to about 20 microns and having a content of from about 5% to about 3% by volume. Yet further, the composite plated layer may include a quantity of short fibrous dispersion material dispersed in the matrix of matrix metal. Thereby, the wear on the piston ring, and also the wear on the cylinder bore in which it slides, are reduced.Type: GrantFiled: December 23, 1985Date of Patent: July 21, 1987Assignee: Kabushiki Kaisha RikenInventor: Manabu Shinada
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Patent number: 4680161Abstract: A method of producing a sliding composite material. The method comprises the step of: forming an adhesive layer bonded to the surface of a metal strip by sintering a powder for the adhesive layer which contains no solid lubricant and which is disposed onto the surface of the metal strip; forming a surface layer by sintering another powder for the surface layer which contains a solid lubricant and which is disposed onto the sintered adhesive layer; and rolling the resulting layers and the metal strip to obtain the composite material.Type: GrantFiled: August 13, 1986Date of Patent: July 14, 1987Assignee: Daido Metal Company Ltd.Inventor: Takashi Muto
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Patent number: 4678633Abstract: A process for forming a sintered layer on a substrate of an iron-based material containing carbon. A sheet of powders of an alloy is prepared by mixing the powders with a solution of resin and rolling the mixture into a sheet. The sheet is then heated to a sintering temperature. In order to prevent carbon content in the substrate from diffusing to the powder sheet during the sintering process, a lamina is provided beneath the powder sheet for example by a metal plating, a metal oxide layer, an intermediate alloy powder sheet, a decarbonized layer.Type: GrantFiled: October 11, 1985Date of Patent: July 7, 1987Assignee: Mazda Motor CorporationInventors: Sigemi Osaki, Norio Yousina, Tsuyoshi Morishita, Yasuhumi Kawado
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Patent number: 4659547Abstract: The invention resides in a process of preparing an inhomogeneous sintered body by adjoining metal powder with refractory ceramic powder at normal powder metallurgical pressures and sintering conditions. The invention is characterized thereby that the sintered body is manufactured in one layer or several layers having displaced mixing ratio between the ceramics and the metal and that the binding between ceramics and metal is strengthened with monoaluminium phosphate or a monoaluminium phosphate former. The sintered body can be used for example as heat shielding.Type: GrantFiled: January 8, 1986Date of Patent: April 21, 1987Assignee: Hoganas ABInventors: Lars-Erik Svensson, Ove Thornblad
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Patent number: 4657822Abstract: Alloy powder is packed into a mold which comprises a complex-shaped solid aphite inner core and a similarly complex-shaped thin glass outer wall. The mold is evacuated, sealed, and then heated to the alloy sintering temperature, the glass softens and applies an isostatic pressure on the alloy as the alloy particles consolidate. After the consolidation step, the mold and its contents are cooled and the glass and graphite materials are removed from the alloy object. This method is particularly useful for preparing complex fittings of Nitinol shape memory alloys.Type: GrantFiled: July 2, 1986Date of Patent: April 14, 1987Assignee: The United States of America as represented by the Secretary of the NavyInventor: David Goldstein
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Process for adhering an oxide coating on a cobalt-enriched zone, and articles made from said process
Patent number: 4649084Abstract: An improved fabrication process for cobalt-enriched cemented carbide substrates is disclosed, in which an article is generally comprised of tungsten carbide, cobalt, and carbides, nitrides or carbonitrides of titanium, tantalum, and niobium, or mixtures thereof. In one aspect of the invention the article is contacted with nitrogen gas and then sintered in the absence of nitrogen gas to form a cobalt-enriched, B-1 phase-depleted zone. The article is then sintered in nitrogen gas to form a B-1 phase enriched layer on the surface of the article. Additionally, a metal oxide wear layer can be provided on the article.Type: GrantFiled: May 6, 1985Date of Patent: March 10, 1987Assignee: General Electric CompanyInventors: Thomas E. Hale, Warren C. Yohe -
Patent number: 4636252Abstract: A method of manufacturing a cermet having high toughness and high hardness, which exhibits excellent impact resistance and wear resistance when used in cutting tools. A mixed powder is prepared which consists essentially of: titanium nitride, from 25 to 50 percent by weight; titanium carbide, from 10 to 30 percent by weight; at least one selected from the group consisting of tantalum carbide, niobium carbide, and zirconium carbide, from 5 to 25 percent by weight; tungsten carbide, from 10 to 25 percent by weight; and at least one selected from the group consisting of Co and Ni, and Al if required, from 7.5 to 25 percent by weight in total. The above mixed powder is compressed into a green compact. The green compact is sintered in a nitrogen atmosphere under a pressure within a range from 0.1 to 100 torr, and at a temperature within a range from 1400.degree. to 1550.degree. C.Type: GrantFiled: May 14, 1984Date of Patent: January 13, 1987Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Hironori Yoshimura, Jhunichi Toyama
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Patent number: 4624830Abstract: A method of manufacturing by a powder metallurgy process a rotary drill bit including a bit body having a plurality of cutting elements mounted on the outer surface thereof comprises the steps of forming a hollow mould for moulding at least a portion of the bit body, packing the mould with powdered matrix material, and infiltrating the material with a metal alloy in a furnace to form a matrix. Before packing the mould with powdered matrix material, there are positioned in spaced locations on the interior surface of the mould a plurality of cutting elements, each of which is formed of a material, such as a polycrystalline diamond material, which is thermally stable at the temperature necessary to form the matrix. Also positioned in the mould, adjacent the rearward side of each cutting element, is a support material such that, at least after formation of the matrix, the support material has a higher modulus of elasticity than the matrix.Type: GrantFiled: November 30, 1984Date of Patent: November 25, 1986Assignee: NL Petroleum Products, LimitedInventor: John D. Barr
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Patent number: 4622269Abstract: An electrical contact formed of a mixture of finely divided electrically conductive metal doped with graphite or cadmium oxide. A thin coating of the electrically conductive metal is disposed upon the side of the contact which is adapted to be welded or brazed to an electrically conductive support. The electrical contact is made by mixing the finely divided cadmium oxide and pressing the mixture into a desired shape. A slurry of conductive metal is then sprayed on one side of the contact. After coating, the contact is sintered at a temperature less than the melting point of the electrically conductive material, whereby the contact is formed and the coating is firmly attached to it. The invention is particularly useful with silver or copper-based electrical contacts.Type: GrantFiled: December 30, 1985Date of Patent: November 11, 1986Assignee: GTE Products CorporationInventors: Chi H. Leung, Ron J. DeNuccio
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Patent number: 4618540Abstract: Wear parts or cutting tools, in which the part being exposed to wear is essentially an extremely difficultly grindable material (e.g., hard material), but in which the manufacture of the wear part or cutting tool requires considerable grinding operations can, according to the invention, be made better and cheaper forming the wear part or cutting tool of a compound material which is a wear-resistant (or difficult to grind) surface and a supporting surface of high speed steel or tool steel.Type: GrantFiled: May 2, 1984Date of Patent: October 21, 1986Assignee: Santrade LimitedInventors: Johan P. von Holst, Rolf G. Oskarsson
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Patent number: 4610931Abstract: Cemented carbide substrates having substantially A or B type porosity and a binder enriched layer near its surface are described. A refractory oxide, nitride, boride, and/or carbide coating is deposited on the binder enriched surface of the substrate. Binder enrichment is achieved by incorporating Group IVB or VB transition elements. These elements can be added as the metal, the metal hydride, nitride or carbonitride.Type: GrantFiled: March 8, 1984Date of Patent: September 9, 1986Assignee: Kennametal Inc.Inventors: Bela J. Nemeth, George P. Grab
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Patent number: 4602955Abstract: A composite material sensitive to weak variations of oxygen pressure at a low temperature, of the type containing microscopic particles of an ionic conductor of oxygen ions contained in a solid solution, in tetravalent metal oxides, oxides of other metals with a valence less than four, other than the said of such a solid solution, the material contains discrete microscopic particles of an electronic conductor.Type: GrantFiled: December 31, 1984Date of Patent: July 29, 1986Assignee: Electricite de FranceInventors: Michel Gouet, Dominique Especel, Marianne Goge
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Patent number: 4599277Abstract: In a process for sintering a metal member bonded to a substrate during which the metal member undergoes densification at a temperature which is different from the curing temperature of the substrate, an improvement is provided which comprises causing the densification temperature of the metal member to be closer to or identical with the curing temperature of the substrate by adding to said metal member prior to sintering an amount of organometallic compound which undergoes decomposition before the densification temperature of the metal member has been reached to provide under the sintering conditions employed a densification temperature-modifying amount of a metal or metal oxide which can be the same as or different from the metal of the aforesaid metal member.The improved sintering process of the present invention is particularly adapted for use in the fabrication of multilayer ceramic substrates which serve as circuit modules for seminconductor chips.Type: GrantFiled: October 9, 1984Date of Patent: July 8, 1986Assignee: International Business Machines Corp.Inventors: James M. Brownlow, Robert Rosenberg
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Patent number: 4594294Abstract: A wear resistant multilayer coating is provided. The wear resistant coating comprises at least one internal layer and a thin, external layer of disordered boron and carbon applied to a substrate. The synergistic interaction of a hard internal layer and a lubricious boron and carbon layer provides a long lived tool coating. In a more specific embodiment, the external layer of the coating is disordered boron carbide. In accordance with one embodiment, the disordered boron and carbon external coating is of a composition B.sub.x C.sub.1-x where x is from about 0.60 to about 0.90.Type: GrantFiled: October 9, 1984Date of Patent: June 10, 1986Assignee: Energy Conversion Devices, Inc.Inventors: Erwin Eichen, James Flasck
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Patent number: 4587174Abstract: A tungsten cermet for use in cutting tools, including a carbonitride, having titanium and tungsten, and aluminum oxide. The cermet contains about 10 to about 50% by weight of the carbonitride, about 0.5 to about 10% by weight of aluminum oxide and tungsten as a binder. The tungsten cermet has excellent properties in toughness, impact resistance and oxidation resistance, combined with wear resistance and plastic deformation resistance, and is useful for cutting tools used in heavy cutting, hot working and the like.Type: GrantFiled: December 23, 1983Date of Patent: May 6, 1986Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Hironori Yoshimura, Naohisa Ito, Kenichi Nishigaki, Katsunori Anzai
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Patent number: 4587095Abstract: A super heatresistant cermet and process of producing the same. A mixture, which contains about 10 to about 65% by weight of a powder of the carbonitride having titanium and tungsten, about 0.5 to about 10.0% by weight of a magnesium oxide powder and a tungsten powder, is pressed to form a compact, which is thereafter sintered in a vacuum or in an atmosphere of a nitrogen gas or an inert gas within the temperature range of about 1800.degree. to 2700.degree. C. to thereby decarburize the carbonitride with the magnesium oxide evaporated during the sintering, whereby there is produced a super heatresistant cermet containing about 10 to about 65% by weight of a carbonitride containing titanium and tungsten, about 0.01 to about 1.0% by weight of magnesium oxide, and tungsten as a binder. The super heatresistant cermet is excellent in impact resistance, wear resistance and plastic deformation resistance, and suitable for cutting tools.Type: GrantFiled: January 12, 1984Date of Patent: May 6, 1986Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Hironori Yoshimura, Naohisa Ito, Kenichi Nishigaki, Katsunori Anzai
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Patent number: 4584020Abstract: In wear parts consisting of sintered cemented carbide and cast alloy on iron base, in which a wear resistant layer of cast-in-carbide is formed in the most exposed parts of the product, the chipping of cemented carbide from the wear layer can be essentially eliminated according to the invention by applying a layer of another metallic material, for example steel, between the cast alloy and the wear layer.Type: GrantFiled: December 5, 1983Date of Patent: April 22, 1986Assignee: Santrade LimitedInventor: Mats G. Waldenstrom
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Patent number: 4582678Abstract: A method of producing rocket combustors wherein in forming an outer cylin by a powder metallurgical method on the outer side of a cylinder provided on its outer periphery with a cooling wall of channel construction having a plurality of grooves (14), an Ni electroforming layer is formed on the outer side of the outer cylinder, and also a method of producing rocket combustors wherein an outer cylinder is of multilayer construction having two or more layers.Type: GrantFiled: September 21, 1984Date of Patent: April 15, 1986Assignees: National Aerospace Laboratories of Science & Technology Agency, Yoshimichi Masuda, Ryuzo Watanabe, Junjiro Takekawa, Sumitoro Electric Industries, Ltd.Inventors: Masayuki Niino, Akio Suzuki, Nobuyuki Yatsuyanagi, Akinaga Kumakawa, Masaki Sasaki, Hiroshi Tamura, Fumiei Ono, Yoshimichi Masuda, Ryuzo Watanabe, Junjiro Takekawa, Yoshihiko Doi, Nobuhito Kuroishi, Yoshinobu Takeda, Shigeki Ochi