Abstract: Patterned surfaces for the selective adhesion and outgrowth of cells are useful in cell culture devices, prosthetic implants, and cell-based microsensors. Such surfaces may be prepared by a deep ultraviolet photolithographic technique.

Abstract: A copper powder-free friction material which is made by sintering and intended for friction surfaces of couplings or brakes contains powdery and/or granular metallic and non-metallic components, at least 50% by weight of the non-ferrous heavy metal component being brass powder.

Abstract: A copper foil for an inner layer circuit of a multi-layered printed circuit board, which comprises a black metal plated layer formed on at least the rough surface which becomes a surface of an inner layer circuit of a copper foil having both sides roughened in advance, in order to enhance the bonding strength to a prepreg, make it safe from haloing and facilitate optical checking of the copper foil.

Abstract: The present invention relates to a rapid, low-temperature method of forming a ceramic or ceramic-like coating on a substrate. It comprises coating the substrate with a solution comprising a solvent and one or more hydrolyzed or partially hydrolyzed preceramic silicon alkoxides and, optionally, a ceramic oxide precursor. The solvent is evaporated and a preceramic coating thereby deposited on the substrate. The coated substrate is heated to a temperature of between about 40.degree. to about 400.degree. C. in the presence of ozone to ceramify the ceramic or ceramic-like coating. Additional protective coatings may be applied onto the coating thus produced.

Abstract: A novel self-brazing aluminum laminated structure is described, as well as a method of making the laminated structure and a brazed product produced therefrom. The laminated structure consists of a thin layer of a powder mixture consisting of eutectic-forming metal powder and a flux powder sandwiched between an aluminum alloy sheet and an aluminum foil. The laminate is fabricated by roll bonding to provide adequate adhesion of the foil to the underlying sheet through and around the powder layer. This can be done by arranging the powder layer into clusters of powder with spaces therebetween so that roll bonding between the foil and the aluminum alloy substrate takes place by way of direct metal contact between the clusters. These clusters may be created by the method of applying the powder, e.g. silk screen, or by providing depressions in the surface of the substrate by a process of roughening or of embossing within which clusters of the powder are located.

Abstract: An object of the present invention is to provide a method for forming connector terminal electrodes of a lamination capacitor which has firm connection between the internal electrodes and the connector terminal electrode. The ceramic main body part (10) having internal electrodes of palladium is put into a mixture of two powders, one being a silver powder (3) with a diffusion coefficient different from the internal electrodes and the other being a zirconium powder (2) which is inactive to both the internal electrode and the silver powder (3). The ceramic main body part (10) in the mixture is subjected to a heat treatment at a heat temperature. Thereafter a connector terminal electrode (20) is formed on each of the sides of the ceramic main body part (10).

Abstract: A sintered body of titanium based carbonitride alloy containing hard constituents based on, in addition to titanium, one or more of the metals Zr, Hf, V, Nb, Ta, Cr, No or W in 5-30% binder phase based on Co and/or Ni is disclosed. The body has a binder phase enriched surface zone with a higher binder phase content than in the inner portion of the body in combination with an enrichment of simple hard constituents, i.e., the share of grains with core-rim structure is lower in the surface zone than in the inner of the body.

Abstract: A beryllium metal matrix phase includes up to 70% by volume of beryllium oxide single crystals dispersed therein. The composites are useful for electronics applications because of their light weight, high strength and effective thermal properties.

Abstract: A Cu--Sn based sintered material, which has an improved corrosion-resistance, is provided by setting the Pb content at 1 to less than 10% and adding from 0.1 to 30% of a hard matter(s) selected from the groups (a), (b), (c) and (d). The hard matter is(a) Fe.sub.2 P, Fe.sub.3 P, FeB, Fe.sub.2 B and Mo.(b) Fe--Cr, Fe--Mn, Fe--Ni, Fe--Si, Fe--W, Fe--Mo, Fe--V, Fe--Ti, Fe--Nb, CuP, Cr, and W;(c) SiC, TiC, WC, B.sub.4 C, TiN, cubic BN, Si.sub.3 N.sub.4, SiO.sub.2, ZrO.sub.2, and Al.sub.2 O.sub.3 ;(d) Si--Mn, Cu--Si, and FeS.Most of said hard matter being dispersed in Cu particles, grain boundaries between Cu particles, and between the Cu and Pb particles.

Abstract: A thermal barrier coating system consists of two layers of a zirconia-yttria ceramic. The first layer is applied by low pressure plasma spraying. The second layer is applied by conventional atmospheric pressure plasma spraying. This facilitates the attachment of a durable thermally insulating ceramic coating directly t the surface of a highly oxidation resistant NiAl-based intermetallic alloy after the alloy has been preoxidized to promote the formation of a desirable Al.sub.2 O.sub.3 scale.

Abstract: The present invention provides a multilayer composite sliding material with excellent seizure resistance property having a steel plate or a steel plate having surfaces plated with copper or the like; a bond layer having a thickness of 0.05 to 0.5 mm, formed on the steel plate, and made of a sintered powder material consisting of 5 to 16% Sn, 0 to 15% Pb, 0 to 0.5% P and balance essentially Cu; and an alloy layer having a thickness of 0.1 to 1.0 mm, formed on the bond layer, and made of a sintered powder material consisting of 5 to 16% Sn, 1 to 12% MoS.sub.2 and balance essentially Cu. In a modified form of the alloy layer, not more than 20% Pb, not more than 1% P or not more than 12% Ni may be added. MoS.sub.2 powder may be coated with Cu or Ni.

Abstract: A heat-resistant metallic monolith, manufactured by forming metal powders into a honeycomb structure and by sintering the structure, has a heat-resistant metal oxide coated on the surface of the cell walls and that of the pores thereof. Such a heat-resistant metallic monolith is manufactured by mixing metal powders, an organic binder and water to prepare a mixture, by forming the mixture into a shape of a desired honeycomb configuration, by sintering the shape in a non-oxidizing atmosphere at a temperature between 1000.degree. and 1450.degree. C. and then by coating a heat-resistant metal oxide on a surface of the cell walls and that of the pores of the obtained sintered body.

Abstract: The present invention relates to cemented carbide bodies preferably for wear demanding rock drilling and mineral cutting. The bodies are built up of a core of eta-phase-containing cemented carbide surrounded by a surface zone free of eta-phase where the binder phase content in the outer part of said zone is lower than the nominal and, in addition, constant or near constant, and the binder phase content in the inner part of the eta-phase free zone closer to the eta-phase core is higher than the nominal. According to the method of the invention, bodies comprising evenly distributed eta-phase are subjected to a partly carburizing treatment with a carbon activity, a.sub.c, close to 1.

Abstract: Coated components are produced to withstand high stresses and are composed of the intermetallic phase titanium aluminide material for use, in particular, in piston engines, gas turbines and exhaust gas turbochargers. This material has good technical properties but otherwise only a low resistance to oxidation and wear as a result of friction processes. These disadvantages are overcome in that the components are coated, at least on the parts of their surface which are at risk of hot corrosion and/or wear, with a sheet of a solderable nickel-based alloy soldered on under vacuum. A coating thickness of 0.1 to 0.4 mm is adequate. The nickel-based alloys, of which the soldered-on sheet is composed, preferably have a melting point of below 1180.degree. C.

Abstract: An improved thermal barrier coating is disclosed. The coating is formed on a metal part to be exposed to high temperature gases. The metal part is first coated with an adherent sublayer of MCrAlY alloy. In this case, the M of the MCrAlY is nickel, cobalt, iron, or some combination of these metals. A diffused layer of MCrAlY combined with a low concentration of mullite is formed over the MCrAlY subcoating and the mullite is increased in concentration as the thickness of the layer increases. The outer surface of the layer is all mullite. Improved life expectancy and decreased thermal conductivity is achieved.

Abstract: A method of producing self-supporting ceramic bodies having a modified metal-containing component includes first providing a a self-supporting ceramic body comprising (i) a polycrystalline oxidation reaction product formed upon oxidation of a molten parent metal precursor with an oxidant, and (ii) an interconnected metal-containing component at least partially accessible from one or more surfaces of said ceramic body. The surface or surfaces of the ceramic body is contacted with a quantity of foreign metal different from said interconnected metal-containing component at a temperature and for a time sufficient to allow for interdiffusion, whereby at least a portion of said metal-containing component is displaced by said foreign metal. The resulting ceramic body, having an altered metal-containing component, exhibits modified or improved properties.

Abstract: An impregnated thermionic cathode includes a porous matrix of sintered tungsten-alloy particles containing less than six percent iridium and/or other platinum-group metal. The pores of the matrix are impregnated with a temporary process impregnant such as molten copper or an organic monomer, and upon solidification is machined to a desired shape. Thereafter the temporary process impregnant is removed, and the matrix pores again infiltrated with a barium oxide such as molten barium aluminate, or other alkaline earth. A thin, iridium-rich surface activating layer, preferably of about 50% iridium, is then applied to the emitting surface. The diffusion of surface activating iridium is substantially blocked; superior emission and lifetime is provided; and the cathode is relatively low cost and easy to fabricate.

Abstract: The sliding member of the invention comprises a steel backing and a sintered Cu-alloy layer mounted integrally on one surface of the backing metal, wherein the sintered Cu-alloy comprises 1 to 15% Sn, 1 to 20% Ni-B compound, 1% or less phosphorus, and the balance of Cu and impurities. Cu-alloy may further contain 1 to 30% Pb and/or 0.5 to 8% graphite. Pb and graphite provide the sliding alloy layer with good lubrication property. Preferably the Ni-B compound is used, which is composed of 7 to 15% B and the balance of Ni and impurities.

Abstract: A coating for a metallic substrate has a metallic bond coat, a metallic seal coat and a centrally disposed layer of ceramic material. Transition layers comprising a controllably positioned mixture of metallic and ceramic materials are interposed, respectively, between the bond coat and the central layer of ceramic material, and between the seal coat and the central layer of ceramic material. The coating provides a desirable thermal barrier for internal engine components. Further, the coating is graded to avoid harmful internal thermal stress between dissimilar materials in the coating, and has a sealed external surface that is resistant to corrosion, erosion, hot gas infiltration, and wear during operation in an internal combustion engine.

Abstract: A cast product made from metallic material and ceramic material with the ceramic material being an insert, comprises an aggregated body of capsule particles, the capsule particle including a ceramic particle coated with metallic particles, and metallic material cast over the aggregated body.

Abstract: A discontinuously casting copper alloy mold is provided. The mold consists of an Ni-plating layer formed on an inner surface of a mold blank formed of copper or a copper alloy. An intermediate layer is provided of a spray coating of a powdered material consisting of two or more of Ni, Cr and Co and 0.1% to 1.0% by weight of Y.

Abstract: A ternary-alloy/glass composite suitable for use in vias in glass-ceramic electronic structures includes gold, palladium, and either platinum or silver in the alloy where the gold is less than 50% by weight of the alloy. The alloy is combined with glass frit where the glass is present as 5-50% by volume in the composition. The ternary-alloy glass composite is sintered in the glass-ceramic structure and provides a hermetic seal. Chips and pins can be bonded directly to the ternary-alloy/glass composite using a eutectic braze without causing cracks in the glass-ceramic. The ternary-alloy/glass composite has good adhesion with glass-ceramics and is useful in vias in electronic structures.

Abstract: A method of making at least one low electrical resistance connection between a metal and a high T.sub.c superconducting ceramic part, said part being made from a ceramic powder which is placed in a mold, compressed, and sintered, wherein at least one volume of silver or gold powder corresponding to the shape of said connection and situated at the desired location is placed inside said mold in juxtaposition with said ceramic powder but without being mixed therewith, after which the compression and the sintering are performed under an atmosphere containing oxygen and at a temperature that is lower than the melting temperature of silver or gold.

Abstract: The present invention resides in an optically black article comprising a substrate and an optically black coating adhered to the substrate. The coating has an absorptivity of at least about 0.92 and an emissivity of at least about 0.85, obtained by plasma spraying onto the substrate a composition comprising about 20% to about 50% by weight of a carbonyl metal and about 80% to about 50% by weight of a ceramic metal oxide. A preferred carbonyl metal is carbonyl iron. A preferred ceramic metal oxide is a yttria stabilized zirconia, having an average particle size in the range of about 10 microns to about 106 microns (140 mesh).

Abstract: A composite material (20) comprises a matrix layer (21) having a plurality of interspersed reinforcing whiskers (23) and a plurality of continuous reinforcing fibers (25) embedded within the matrix layer (21). The preferred embodiment includes a matrix layer (21) which may be a ceramic, intermetallic or metallic material having interspersed reinforcing whiskers (23) upon which a second layer of the matrix (24) having embedded continuous reinforcing fibers (25) is placed, and a third layer (22) of the matrix material having the interspersed reinforcing whiskers (23) on the second layer (24). The composite exhibits improved fracture toughness due to the crack deflection ability of whiskers (23) and crack bridging and fiber pull out due to continuous fibers (25) and minimizes creep associated with known ceramic and intermetallic composites.

Abstract: A ferritic alloy with a wear resistive oxide scale is obtained through the steps of pressing a ferritic alloy powder containing aluminum into a powder compact of a desired configuration, sintering the powder compact in a non-oxidizing atmosphere to provide a resulting sintered product, and heat-treating the sintered product in an oxidizing gas atmosphere in order to precipitate in the surface thereof alumina in the form of an alumina scale as the wear resistive oxide scale which is responsible for improved surface hardness or wear resistance. Due to the inherent porous nature of the sintered product, the oxidizing gas can readily penetrate deep into the surface of sintered product to facilitate the oxidization of the product surface into the alumina scale, in addition to that the oxidization depth can be controlled such as by the density of the product, which makes it possible to readily control the thickness of the alumina scale.

Abstract: A cermet alloy having a structure comprising a hard phase and a bonding phase, said hard phase comprising (1) at least one of MC, MN and MCN, wherein M is at least one element selected from Ti, Zr, Hf, Th, V, Nb, Ta, Pa, Cr, Mo, U and W and (2) at least one W-Co-B compound; said bonding phase comprising Co. The cermet has superior toughness and hardness, and can be worked by conventional sintering methods. The invention also includes a method for producing the cermet.

Abstract: Extra loss is introduced in coupled cavity and klystron RF circuits by applying a surface coating to selected parts of circuit elements used in the circuits. The coating is applied in the form of a slurry, which is then sintered. The slurry comprises a mixture of an iron-base powder (such as a stainless steel) and a dielectric glass ceramic, suspended in a binder dissolved in a solvent. Circuits with the loss coating are easier to match than by other prior art techniques. The loss coating of the invention reduces the fabrication cost of coupled-cavity traveling wave tubes, while improving the performance by minimizing the gain ripple. Higher average power operation is possible, due to elimination of loss buttons previously employed in the prior art.

Abstract: A sliding material of a single substance made by extruding powder comprises aluminum as a main constituent, and at least one metal compound of 0.5 to 30 wt. % in total selected from the group consisting of metal nitride, metal carbide, metal phosphide, and metal boride, each of which has a hardness not less than 200 in Vicker's hardness, the metal compound being uniformly and finely dispersed in aluminum.

Abstract: Disclosed herein is a (1) A multi-layered sintered sliding member comprising a back metal composed of a steel plate having (i) a plurality of independent protrusions formed at a surface thereof or (ii) a continuous protrusion and a plurality of independent recesses defined with said protrusions at the surface thereof and a sintered alloy layer formed integrally by securing on the surface of said back metal covering the surface of said protrusions, in which said sintered alloy layer is composed of a low density alloy region and a high density alloy region.

Abstract: A metal oxide ceramic composite powder has crystals of a reacted and precipitated metal oxide distributed on fine particles of a ceramic material. The metal oxide is derived from an aqueous solution of metal chloride, which in the presence of a magnetic field, forms a complex ion solution. The complex ion may comprise a proportional blend of metallic and semi-metallic elements to produce specific properties. The complex ion is reacted and precipitated with an alkaline material to deposit a high purity metal oxide on the ceramic material. Each ceramic particle thus has a uniform coating of a high purity metal oxide deposited thereon.

Abstract: A partially hardened sintered body such as a rocker arm comprises powder forming a main body and a capsule-like powder composite disposed adjacent to the powder and composed of core particles made of a material harder than the powder and covering particles covering the core particles and made of the same material as the powder. The powder and the capsule-like powder composite are solidified into the partially hardened sintered body.

Abstract: A metal structure component is provided with a protective coating including three layers. A first layer on the surface of the metal structural component is a bond improving metallic base layer on which an intermediate heat insulating oxidic layer is applied, followed by a titanium fire inhibiting metallic cover layer. Due to this arrangement of three layers, it is possible for the advantageous characteristics of the individual layers to cooperate to provide a good bonding and heat insulating protection of the intermediate layer in combination with the titanium fire inhibiting protection of the outer layer, whereby the structural component achieves a prolonged operational life without a substantial weight increase as compared to conventional protection layers provided only for heat insulation purposes. This layer structure also minimizes any adverse influence on the structural strength of the metal structural component.

Abstract: The present invention relates to a method of fabricating various types of bearing materials and the bearing materials produced thereby. The processes of the invention may be used to produce porous self-lubricating bearings, laminated composite bearings (babbitt bearings) and bearings for high temperature application. The processes of the invention involve the use of micro-pyretic synthesis to achieve bearing materials with improved bearing properties, including higher bearing capacity and toughness.

Abstract: Self-supporting ceramic bodies having a modified metal-containing component are formed by first providing a self-supporting ceramic body comprising (1) a polycrystalline oxidation reaction product formed upon oxidation of a molten parent metal precursor with an oxidant, and (ii) an interconnected metal-containing component at least partially accessible from one or more surfaces of said ceramic body. The surface or surfaces of the ceramic body are contacted with a quantity of foreign metal different from said interconnected metal-containing component at a temperature and for a time sufficient to allow for interdiffusion, whereby at least a portion of said metal-containing component is displaced by said foreign metal. The resulting ceramic body, having an altered metal-containing component, exhibits modified or improved properties.

Abstract: A copper alloy composite material which comprises a copper alloy matrix and at least one additive selected from solid materials having self-lubricity and wear-resistant materials and uniformly dispersed in the alloy matrix is described. The composite material has improved wear resistance and anti-seizing properties.

Abstract: In a laminate material or a laminate workpiece with a functional layer affixed to one surface of a solid backing layer, the functional layer consisting of components which are not soluble in one another, thus normally forming a heterogeneous structure, a finely dispersed distribution of the undissolved components in a matrix of the functional layer is created, due to the fact that the components forming the functional layer are affixed to the backing layer as a fine powder material in the form of a powder mixture or agglomerated powder or predispersed powder formed through air plasma spraying. Thereby the backing layer itself contains a partial layer to be coated having a heterogeneous structure or a crystalline structure, for instance a lead bronze layer or a lead tin bronze layer. This partial layer is created in a surface region by the action of the plasma flame in a strictly defined zone down to a certain depth, for instance 20 to 200 .mu.

Abstract: A highly corrosion-resistant rare earth-, e.g., neodymium-, based sintered permanent magnet is proposed which is characterized by the specific chemical composition of the magnet alloy including cobalt and/or chromium in a specified atomic percentage, by the density of the sintered body of at least 95% of the density of the alloy ingot and by the corrosion-resistant surface film formed on the surface of the sintered body by a specific method. By virtue of the favorable conditions against corrosion including the specific chemical composition of the magnet alloy and the high density of the sintered body, these conditions are also favorable for enhancing the adhesion of the corrosion-resistant coating film to the surface of the sintered body.

Abstract: A microstructurally toughened ceramic-particle-reinforced metal-matrix composite article is disclosed. The article exhibits a complex microstructure. The article exhibits high tensile strength, high elastic modulus and high impact resistance. A process for making the article is also disclosed. The process includes positioning structural elments within a metallic container to define one or more void spaces within the container, introducing a quantity of metallic particles or of a particulate mixture of metallic particles and ceramic particles into the void spaces, and consolidating the container, structural elements and particles to form the microstructurally toughened composite article.

Abstract: Engine components of steel or superalloy subject to wear from alternating friction at medium temperatures in the region of 700.degree. C. are provided with a protective wear-resistant coating bya) electrophoretic deposition of a metal-ceramic structure comprising a mixture of from 85% to 50% of metallic powder and from 15% to 50% of ceramic powder, the metallic powder being a cobalt-based superalloy of type KC 25 NW or of M Cr Al Y wherein M represents at least one metal chosen from the group consisting of Ni, Co and Fe with the possible addition of Ta, and the ceramic powder being an oxide such as Al.sub.2 O.sub.3 or Cr.sub.2 O.sub.3, a carbide such as SiC or Cr.sub.3 C.sub.2, a nitride such as BN or TiN, or a boride such as TiB.sub.2 ;b) electrolytic pre-nickeling said deposit in an electrolysis bath at a pH between 6 and 8, andc) electrolytic nickeling said pre-nickeled deposit in an acid bath of sulphamate type.

Abstract: An improved cutting tool is provided, especially useful for hand shears. The cutting edge of the tool is made of a wear-resistant material of either: (a) 85% to 96% tungsten carbide and 15% to 4% cobalt, (b) 60% to 89% tungsten carbide, 4% to 28% tantalum carbide, 4% to 25% titanium carbide and 3% to 30% cobalt, or (c) 34% to 51% cobalt, 25% to 32% chromium, 14% to 21% tungsten, 2% to 4% carbon and one or more of the metals nickel, silicon, columbium, manganese and iron which, together, comprise no more than 16% of the material. For material "b", preferably the composition contains about 5% to 13% cobalt, 65% to 89% tungsten carbide, titanium carbide and tantalum carbide which, together, are present in an amount no greater than 30% of the composition of the material.

Abstract: A composition including ethylene glycol and friction particles mixed together in predetermined proportions. The composition is used to aid in the removal of headed fasteners. The composition may also be used in place of a lock washer. The composition is most effective when used with fasteners made of soft metals.

Abstract: A coating for a heat engine part, particularly a turbo-machine part made of superalloy, comprises an electrophoretically deposited metallic structure of cellular form with uniformly disposed cells of predetermined size, the structure preferably being composed of M, Cr, Al, and Y, where M denotes Ni, Co, Fe and mixtures thereof. The cellular metallic structure is consolidated by a sintering treatment, which may be reactive, or metallization, preferably in the vapor phase, and the coating is completed by a ceramic material applied by plasma spraying.

Abstract: A wear-resistant compound roll having a shell portion produced by sintering a uniform mixture of alloy powder consisting essentially, by weight, of 1.2-3.5% of C, 2% or less of Si, 2% or less of Mn, 10% or less of Cr, 3-35%, as W+2Mo, of one or two of W and Mo, 1-12% of V, and balance Fe and inevitable impurities, and 1-15%, based on the weight of said alloy powder, of VC powder dispersed therein. This compound roll is produced by (a) uniformly mixing the alloy powder with the VC powder; (b) charging the resulting mixed powder into a metal capsule disposed around a roll core; and (c) after evacuation and sealing, subjecting said mixed powder to a HIP treatment.

Abstract: A thermally conductive diamond metal composite consisting essentially of 5 to 80 volume percent diamond particles having a particle size ranging from about 1 to 50 .mu.m and a metal matrix comprising a thermally conductive metal. Preferably, a fine metal powder having particle size below 53 microns is utilized as the source for the metal matrix.

Abstract: A multilayered sliding material of lead bronze containing graphite in the form of a bimetal, comprising a steel plate or a steel plate having a copper plating coating and a sintered copper alloy bonded to the steel plate, the sintered copper alloy having a composition consisting of 5 to 16 wt % Sn, 2 to 20 wt % Pb, 0.03 to 1 wt % P, 0.5 to 3.9 wt % graphite, and the balance Cu, wherein hardness of the alloy exceeds Hv 100.

Abstract: A sintered diamond compact or high pressure form boron nitride compact with an improved brazability, suitable for use for wear resisting tools, cutting tools, drill bits, dressers and wire-drawing dies is provided. This compact comprises a compact part containing at least 20% by volume of diamond and/or high pressure form boron nitride and a cemented carbide substrate bonded directly or through an interlayer to the compact part, characterized in that the surface of the compact is coated, at least partly, with a thin film consisting essentially of at least one member selected from the group consisting of carbides, carbonitrides and nitrides and mixtures or solid solutions thereof of at least one element selected from the group consisting of silicon and Group IVa, Va and VIa of Periodic Table, and having a thickness of 1 to 20 .mu.m.

Abstract: Disclosed are coated metal articles having protective coatings which are applied to substrate metals by coating the metal surface, e.g. by dipping the substrate metal in a molten alloy of the coating metals, and then exposing the coating at an elevated temperature to an atmosphere containing a reactive gaseous species which forms an oxide, a nitride, a carbide, a boride or a silicide. The coating material is a mixture of the metals M.sub.1 and M.sub.2, M.sub.1 being zirconium and/or titanium, which forms a stable oxide, nitride, carbide, boride or silicide under the prevailing conditions. The metal M.sub.2 does not form a stable oxide, nitride, carbide, boride or silicide. M.sub.2 serves to bond the oxide, etc. of M.sub.1 to the substrate metal. Mixtures of M.sub.1 and/or M.sub.2 metals may be employed. Eutectic alloys of M.sub.1 and M.sub.2 which melt substantially lower than the melting point of the substrate metal are preferred.

Abstract: Process for the powder-metallurgical production of work pieces, particularly tools, containing high-melting point carbides and/or carbonitrides homogeneously distributed in a matrix, in which an amount of elements of the IVa and Va groups, or secondary groups, of the periodic table is adjusted to at least 3 weight percent of the alloy, a low carbon and/or nitrogen concentration is established, and primary precipitates are prevented; and a desired carbon and/or nitrogen content is created by atomization of the melt into powder vaporizing medium.

Abstract: Cemented carbide substrates having substantially A or B type porosity and a binder enriched layer near its surface are described. A refractory oxide, nitride, boride, and/or carbide coating is deposited on the binder enriched surface of the substrate. Binder enrichment is achieved by incorporating Group IVB or VB transition elements. These elements can be added as the metal, the metal hydride, nitride or carbonitride.