Abstract: A steel sheet for cans which exhibits excellent weldability; and a production method therefor include a steel sheet for cans with the surface of a steel sheet in order from the steel sheet side, a chromium metal layer and a hydrous chromium oxide layer. The deposited amount of the chromium metal layer is 65-200 mg/m2. The deposited amount of the hydrous chromium oxide layer in terms of chromium is 3-30 mg/m2. The chromium metal layer includes: a base part having a thickness of 7.0 nm or higher; and granular protrusions which are on the base part, have a maximum grain size of 100 nm or lower, and have a number density per unit area of at least 200 per ?m2.

Abstract: A method of thermally treating black plate which is coated with a conversion coating. The conversion-coated black plate is heated during a thermal treatment time from 0.1 seconds to 30 seconds to a temperature in the range of 240° C. to 320° C. The heat treatment makes it possible to improve the adhesion of the conversion coating to the black plate surface. In one application of the method, the heat treatment is carried out in a process for the production of corrosion-resistant black plate, in which prior to, during or after the heat treatment, an organic coating in the form of paint or a polymer coating is applied to the conversion coating of the black plate.

Abstract: An adhesion promotion process and composition for enhancing adhesion between a copper conducting layer and a dielectric material during manufacture of a printed circuit board. The composition contains a corrosion inhibitor, an inorganic acid, and an alcohol which is effective to increase copper-loading in the composition.

Abstract: A black-plated steel sheet has a Zn-plating layer containing molten Al and Mg, containing Al in the amount of 1.0-22.0 mass %, containing Mg in the amount of 1.3-10.0 mass %, and having a Zn black oxide distributed in a lamella pattern in the plating layer. The Zn black oxide is a Zn oxide derived from a Zn2Mg phase. The brightness of the surface of the Zn-plating layer containing the molten Al and Mg has an L* value of 60 or less.

Abstract: A method to inhibit corrosion of a substrate. The method includes the steps of contacting a metallic substrate with an aqueous solution comprising permanganate ions and silicate ions, for a time and a temperature sufficient to deposit a corrosion-inhibiting coating on the metallic substrate.

Abstract: A coated article includes a substrate and a color layer formed on the substrate. The color layer is a chromium-aluminum-silicon layer containing chromium atoms, aluminum atoms and silicon atoms. The color layer has an L* value between about 25 to about 28, an a* value between about ?1 to about ?6, and a b* value between about ?5 to about ?9 in the CIE L*a*b* (CIE LAB) color space. A method for making the coated article is also described.

Abstract: A flat steel product which is provided for forming into a component by hot pressing and which has a base layer of steel on which is applied a Zn or a Zn alloy metallic protective coating for protecting against corrosion. On at least one of the free surfaces of the flat steel product, a separate cover layer is applied which contains an oxide, nitride, sulphide, carbide, hydrate or phosphate compound of a base metal. In addition, a method which allows the production of such a flat steel product, and a method which allows the production of a component from such a flat steel product.

Abstract: Disclosed is a chromium-free rust-inhibitive surface treatment agent to form a siliceous film that rarely cracks or peels off and yields an excellent rust-inhibitive performance on zinc surfaces of a metal part. The chromium-free rust-inhibitive surface treatment agent is an alcoholic solution of alkoxysilane oligomer having weight-averaged molecular weight of 1,000 to 10,000, and 2.5 to 15% of silicon in molecules of the alkoxysilane oligomer has been replaced with titanium. To prepare partly titanium-replaced alkoxysilane oligomer, titanium compound, in which about a half of alkoxy groups in titanium tetraalkoxide has been chelated, is reacted with tetraalkoxysilane monomer or alkoxysilane oligomer in the alcoholic solution.

Abstract: A housing is provided which includes an aluminum or aluminum alloy substrate, an aluminum layer and a corrosion resistant layer formed on the aluminum or aluminum alloy substrate in that order. The corrosion resistant layer is an Al—C—N layer. Then, Ce ions are implanted in the Al—C—N layer by ion implantation process. The atomic percentages of N and C in the Al—C—N gradient layer gradually increase from the side of Al—C—N gradient layer near the aluminum or aluminum alloy substrate to the other side of Al—C—N gradient layer, away from aluminum or aluminum alloy substrate. Therefore the housing has a high corrosion resistance. A method for making the housing is also provided.

Abstract: A piston ring includes: a refined steel including: carbon C in a range of 0.20% mass to 0.90% mass, silicon Si in a range of 0.10% mass to less than 0.60% mass, manganese Mn in a range of 0.20% mass to 1.50% mass, chromium Cr in a range of 0.30% mass to 2.00% mass, and a remnant including: iron Fe, and an unavoidable impurity. A parameter A calculated from the following expression (1) based on contents of the Si, Mn and Cr is 9.0 or less: parameter A=8.8 Si+1.6 Mn+1.7 Cr—expression (1). A parameter B calculated from the following expression (2) based on contents of the C, Si, Mn and Cr is 10.8 or more: parameter B=36 C+4.2 Si+3.8 Mn+4.5 Cr—expression (2).

Abstract: Provided is a rolled copper foil or electrolytic copper foil for an electronic circuit to be used for forming a circuit by etching, wherein the copper foil comprises a heat resistance layer composed of zinc or zinc alloy or its oxide formed on an etching side of the rolled copper foil or electrolytic copper foil, and a layer of nickel or nickel alloy, which is a metal or alloy with a lower etching rate than copper, formed on the heat resistance layer.

Abstract: A housing is provided which includes an aluminum or aluminum alloy substrate, an aluminum layer and a corrosion resistant layer formed on the aluminum or aluminum alloy substrate in that order. The corrosion resistant layer is an Al—C—N layer. Then, Gd ions is implanted in the Al—C—N layer by ion implantation process. The atomic percentages of N and C in the Al—C—N gradient layer gradually increase from the side of Al—C—N gradient layer near the aluminum or aluminum alloy substrate to the other side of Al—C—N gradient layer, away from aluminum or aluminum alloy substrate. Therefore the housing has a high corrosion resistance. A method for making the housing is also provided.

Abstract: A housing is provided which includes an aluminum or aluminum alloy substrate, an aluminum layer and a corrosion resistant layer formed on the aluminum or aluminum alloy substrate in that order. The corrosion resistant layer is an Al—C—N layer. Then, La ions is implanted in the Al—C—N layer by ion implantation process. The atomic percentages of N and C in the Al—C—N gradient layer gradually increase from the side of Al—C—N gradient layer near the aluminum or aluminum alloy substrate to the other side of Al—C—N gradient layer, away from aluminum or aluminum alloy substrate. Therefore the housing has a high corrosion resistance. A method for making the housing is also provided.

Abstract: A housing is provided which includes an aluminum or aluminum alloy substrate, an aluminum layer and a corrosion resistant layer formed on the aluminum or aluminum alloy substrate in that order. The corrosion resistant layer is an Al—C—N layer. Then, Nd ions are implanted in the Al—C—N layer by ion implantation process. The atomic percentages of N and C in the Al—C—N gradient layer gradually increase from the side of Al—C—N gradient layer near the aluminum or aluminum alloy substrate to the other side of Al—C—N gradient layer, away from aluminum or aluminum alloy substrate. Therefore the housing has a high corrosion resistance. A method for making the housing is also provided.

Abstract: A dielectric device comprises a substrate made of a metal and an oxide dielectric layer mounted on a surface of the substrate. The surface of the substrate has metal oxide regions distributed like islands, while the oxide dielectric layer is in close contact with the substrate through the metal oxide regions. Since adhesion is higher in an area where the substrate and the oxide dielectric layer are in close contact with each other through the metal oxide regions distributed like islands on the surface of the substrate, the adhesion between the substrate and oxide dielectric layer in the dielectric device is enhanced. As compared with a case where a rough surface is formed on a metal foil, the metal oxide region and the substrate are inhibited from forming a rough surface, whereby leakage characteristics can be kept from being deteriorated by the rough surface.

Abstract: A composition and process for forming an electrodeposited coating comprising a co-deposit of a metal and MCrAlY particles. The composition includes a metal and a MCrAlY particles, and the electrodeposited coating comprises a metal matrix and MCrAlY particles dispersed in the matrix. In one aspect, a coating is provided that exhibits excellent oxidation resistance and tribological characteristics at high temperatures, including up to at least about 1350° F. A high temperature coating may comprise a nickel/cobalt alloy matrix comprising MCrAlY particles and chromium carbide particles dispersed in the nickel/cobalt matrix.

Abstract: A coated article includes a substrate, a catalyst layer, a bonding layer and a hydrophobic layer. The catalyst layer made of tin is formed on the substrate. The bonding layer is formed on the catalyst layer, including titanium, tin, stannic oxide and titanium dioxide. The hydrophobic layer made of silicon-nitrogen is formed on the bonding layer.

Abstract: The present invention relates to a method of preparing a Li film, wherein said Li film is fabricated by directly decomposing a compound of Li under a vacuum evaporation condition, and said compound is Li3N. Said Li film is fabricated by decomposing Li3N at an evaporation rate of 0.01-0.25 nm/s and an evaporation temperature of 300-450° C., and said Li film has a thickness of 0.3-5.0 nm. The present invention also relates to an organic light emitting device comprising said Li film as an electron injection layer and a method for the preparation thereof, and an organic light emitting device including an electron injection layer comprising an electron transport material doped with Li obtained by decomposing Li3N under a vacuum evaporation condition, and a method for the preparation thereof.

Abstract: A process for joining a brass part and a silicon carbide ceramic part comprising: providing a brass part, a SiC ceramic part, a Ti foil and a Ni foil; placing the SiC ceramic part, the Ti foil, the Ni foil, and the brass part into a mold, the Ti foil and the Ni foil located between the SiC ceramic part and the brass part, the Ti foil abutting against the SiC ceramic part, the Ni foil abutting against the brass part and the Ti foil; placing the mold into a chamber of an hot press sintering device, heating the chamber and pressing the brass part, the SiC ceramic part, the Ti foil, and the Ni foil at least until the brass part, the SiC ceramic part, the Ti foil and the Ni foil form a integral composite article.

Abstract: Disclosed is a chromium-free rust-inhibitive surface treatment agent to form a siliceous film that rarely cracks or peels off and yields an excellent rust-inhibitive performance on zinc surfaces of a metal part. The chromium-free rust-inhibitive surface treatment agent is an alcoholic solution of alkoxysilane oligomer having weight-averaged molecular weight of 1,000 to 10,000, and 2.5 to 15% of silicon in molecules of the alkoxysilane oligomer has been replaced with titanium. To prepare partly titanium-replaced alkoxysilane oligomer, titanium compound, in which about a half of alkoxy groups in titanium tetraalkoxide has been chelated, is reacted with tetraalkoxysilane monomer or alkoxysilane oligomer in the alcoholic solution.

Abstract: Disclosed are a carrier substrate including an insulating base material with a copper foil layer formed on at least one surface thereof, a metal layer formed on the copper layer and having a length shorter than that of the copper foil layer, and an insulating layer formed on the metal layer, a fabrication method thereof, a printed circuit board (PCB) using the same, and a fabrication method thereof. Because there is no land at the via and core in the substrate, because a circuit pattern connected with the via can be formed to be finer, so the circuit pattern can be highly integrated and the substrate can become thinner. Thus, a printed circuit board (PCB) having a smaller size and reduced number of layers can be fabricated.

Abstract: Certain examples disclosed herein are directed to devices that include a substrate and conductor disposed on the substrate. In some examples, each of the conductor and the substrate may include materials that are mutually insoluble in each other. In other examples, the conductor may further comprise a substantially pure metal. In certain examples, the disposed conductor may be configured to pass adhesion tape test ASTM D3359-02. Methods of forming the conductors are also provided.

Abstract: In a method for applying a multilayer wear-resistant coating on metallic, optionally already coated, surfaces, the coating is composed of at least two anti-wear layers (5) and an intermediate layer (10) each arranged between two anti-wear layers (5). The intermediate layer (10) is comprised of a material composition containing the material of the anti-wear layer (5) and a further material, wherein the application of the intermediate layer (10) is effected with a content of the material of the anti-wear layer (5) decreasing over a first transition region (a) and a content of the material of the anti-wear layer (5) increasing over a second transition region (b), the content of the material of the anti-wear layer (5) in the intermediate layer (10) being selected to be at least 5% by weight in every point.

Abstract: Provided is a copper foil for a printed circuit board comprising a layer including nickel, zinc, a compound of nickel and that of zinc (hereinafter referred to a “nickel zinc layer”) on a roughened surface of a copper foil, and a chromate film layer on the nickel zinc layer, wherein the zinc add-on weight per unit area of the nickel zinc layer is 180 ?g/dm2 or more and 3500 ?g/dm2 or less, and the nickel weight ratio in the nickel zinc layer {nickel add-on weight/(nickel add-on weight+zinc add-on weight)} is 0.38 or more and 0.7 or less. This surface treatment technology of a copper foil is able to effectively prevent the circuit corrosion phenomenon in cases of laminating a copper foil on a resin base material and using a sulfuric acid hydrogen peroxide etching solution to perform soft etching to the circuit.

Abstract: A coating includes a nano-composite layer including a plurality of films. The films are stacked together one after another. Each film includes a zirconium-copper carbonitride layer and a zirconium carbonitride layer.

Abstract: Sodalite is synthesized in the presence of a stoichiometric quantity of Permanganate ion. After thorough washing to remove trace salts the resulting pigment may be encapsulated with amorphous silica using the Iler process. The resulting pigment has enhanced acid stability and provides excellent corrosion protection on reactive metal substrates such as Aerospace Aluminum or Coil grade Hot-Dip Galvanized Steel.

Abstract: A different materials bonded member includes a ceramic base material and a metallic member which are bonded together through an Au solder material. The solder material is disposed on a bonding surface of the ceramic base through a given active metal layer or a given metalized layer and the solder material is heated and melted to form a pre-coat layer adhering to the bonding surface, the metallic member is disposed on a surface of the pre-coat layer through a barrier layer having a given function. A bonded part is formed by solidifying the pre-coat layer after it has been heated and melted under given temperature conditions to bond the ceramic base and the metallic member to one another.

Abstract: A processing solution for forming a hexavalent chromium free, corrosion resistant trivalent chromate conversion film on zinc or zinc alloy plating layers comprises: trivalent chromium and oxalic acid in a molar ratio ranging from 0.5/1 to 1.5/1, wherein the trivalent chromium is present in the form of a water-soluble complex with oxalic acid; and cobalt ions, which do not form a hardly soluble metal salt with oxalic acid and are stably present in the processing solution without causing any precipitation; wherein the solution reacts with zinc when bringing it into contact with the zinc or zinc alloy plating to form a hexavalent chromium free, corrosion resistant, trivalent chromate conversion film containing zinc, chromium, cobalt, oxalic acid and silicon on the plating.

Abstract: The present invention is directed to a composition useful for making homogeneously mineralized self assembled peptide-amphiphile nanofibers and nanofiber gels. The composition is generally a solution comprised of a positively or negatively charged peptide-amphiphile and a like signed ion from the mineral. Mixing this solution with a second solution containing a dissolved counter-ion of the mineral and/or a second oppositely charged peptide amphiphile, results in the rapid self assembly of the peptide-amphiphiles into a nanofiber gel and templated mineralization of the ions. Templated mineralization of the initially dissolved mineral cations and anions in the mixture occurs with preferential orientation of the mineral crystals along the fiber surfaces within the nanofiber gel. One advantage of the present invention is that it results in homogenous growth of the mineral throughout the nanofiber gel.

Abstract: The present invention relates to a rust-preventive metallic component part in which a steel wire to which wire-drawing processing is performed is adapted into a substrate and which comprises a rust-preventive coating film being free from chromium on a surface of the substrate, and to a manufacturing method for the same; and its object is to provide a rust-preventive metallic component part whose rust-preventive coating film exhibits such good adhesiveness to substrate that it is not come off by elastic deformations in service, by sliding contacts at the time of transportation, and the like, and to provide a manufacturing method for the same.

Abstract: One embodiment includes: a copper substrate; a catalyst on top of a single surface of the copper substrate; and a thermal interface material on top of the single surface of the copper substrate. The thermal interface material comprises: a layer of carbon nanotubes that contacts the catalyst, and a filler material located between the carbon nanotubes. The carbon nanotubes are oriented substantially perpendicular to the single surface of the copper substrate. The thermal interface material has: a bulk thermal resistance, a contact resistance between the thermal interface material and the copper substrate, and a contact resistance between the thermal interface material and a solid-state device. The summation of the bulk thermal resistance, the contact resistance between the thermal interface material and the copper substrate, and the contact resistance between the thermal interface material and the solid-state device has a value of 0.06 cm2K/W or less.

Abstract: A protected article has a substrate and a protective structure overlying a surface of the substrate. The protective structure includes a protective layer overlying the surface of the substrate and having an aluminum content greater than that of the substrate, and a bond-coat layer of a bond-coat-layer metal. The bond-coat-layer metal has a bond-coat initial composition having at least about 60 percent by weight platinum, rhodium, palladium, or combinations thereof. There may be a diffusion-barrier layer between the surface of the substrate and the protective layer, and there may be a ceramic thermal barrier coating overlying the bond-coat layer.

Abstract: To provide an aluminium composite structure having a highly airtight channel therein, including: a core material having a concave groove on a surface; a covering material made up of aluminium or aluminium alloy which covers the surface of the core material other than an inner surface of the concave groove; and a lid which is firmly fixed to the covering material to close an opening of the concave groove of the core material, forms a channel for running a heat exchange medium therein, and is made up of the aluminium or aluminium alloy, and a method of manufacturing the same.

Abstract: A coating structure for a metal member includes a surface-smoothing layer formed on the metal member for smoothing a surface of the metal member, and a fluorine-based film formed on the surface-smoothing layer. The fluorine-based film can be formed by applying a fluorine-containing solution on the surface-smoothing layer, and by drying the fluorine-containing solution. The coating structure can be suitably used for a fuel injection nozzle.

Abstract: A method of manufacturing electric machines comprised of geometrically patterned arrays of permanent magnets, soft magnetic materials, and electrical conductors deposited by kinetic spraying methods directly atop a carrier. The magnets and planar coils of the present invention may be integrally formed atop carriers to form electrical machines such as motors, generators, alternators, solenoids, and actuators. The manufacturing techniques used in this invention may produce highly defined articles that do not require additional shaping or attaching steps. Very high-purity permanent and soft magnetic materials, and conductors with low oxidation are produced.

Abstract: An electric machine made from kinetically sprayed permanent magnet material and a binder material form a composite admixture having microstructure of permanent magnet material embedded in the binder material. The admixture has a permanent magnetic moment. The magnets of the present invention may be integrally formed atop carriers to form electrical machines such as motors, generators, alternators, solenoids, and actuators. The manufacturing techniques used in this invention may produce highly defined articles that do not require additional shaping or attaching steps. Very high-purity permanent and soft magnetic materials, and conductors with low oxidation are produced.

Abstract: A coating material has a first layer deposited on a base material and a second layer deposited on the first layer. The first layer is made of a Ni-base alloy or a Co-base alloy containing carbon as an unavoidable impurity. The second layer is made of a hard material containing carbide and a metal component. The first layer serves as a barrier for preventing carbon from being diffused from the second layer into the base material to prevent the base material from being carburized.

Abstract: The present invention provides for a zinc-based coated steel sheet having a zinc-based coating layer and a lubricant film, which is formed on the zinc-based coating layer, containing zinc phosphate particles in an amount of 50 wt. % or more, and having substantially no reaction layer formed by reaction between the zinc-based coating and the zinc phosphate particles, and a method for the manufacture thereof. The zinc-based coated steel sheet according to the present invention has an excellent anti-peeling property, excellent frictional property, even in the non-lubricated condition which occurs at areas where the press oil film is broken, and excellent anti-galling property.

Abstract: The present invention relates to a cutting tool insert particularly for turning of steel comprising a cemented carbide body, a coating with a post treatment with a first, innermost layer system of one or several layers of TiCxNyOz with x+y+z?1 with a total thickness of 0.7–4.5 ?m a second multilayer system consisting of a totally 5–31 alternating Al2O3 and TiCxNyOz (x+y+z?1), preferably ?-Al2O3 and TiN, the Al2O3-layers having an individual layer thickness of <0.5 ?m and the TiCxNyOz-layers 0.01–0.2 ?m with a total thickness of the multilayer of 1.0–4.0 ?m. The multilayer is exposed along the edge line and into the rake and flank face, at least 0.02 mm, from the edge line on the rake face, preferably the contact length of the chip at most 0.9 mm, and 0.02–0.20 mm on the flank face.

Abstract: An improved catalyst system that includes a metal support structure and an anti-corrosive layer on the metal support structure, and has improved resistance to corrosion and other degradation under corrosive environments. Typically, a catalyst supporting layer is applied over the anti-corrosive layer.

Abstract: A chromium(VI)-free, chromium(III)-containing and substantially coherent conversion layer on zinc or zinc alloys presenting, even in the absence of further components such as silicate, cerium, aluminum and borate, a corrosion protection of approx. 100 to 1000 h in the salt spray test according to DIN 50021 SS or ASTM B 117-73 until first attack according to DIN 50961 Chapter 10; being clear, transparent and substantially colorless and presenting multi colored iridescence; having a layer thickness of approx. 100 nm to 1000 nm; and being hard, adhering well and being resistant to wiping.

Abstract: In the present application, a steel sheet having surface-treated zinc-based plating is provided which comprises a zinc-based plating layer, a chromium-free conductive intermediate layer and an organic resin layer, all of the layers being superimposed one on another in the order mentioned. Even though it is of a so-called chromium-free surface-treated steel sheet, the steel sheet is more conductive and more highly resistant to corrosion than conventional chromium-free steel sheets, the likelihood of water pollution is reduced, and the steel sheet can be used in various applications as a replacement for conventional chromate-treated steel sheets.

Abstract: A device having an improved thermal barrier coating (46) and a process for manufacturing the same. A support structure (28) for retaining a ceramic insulating material (46) on a substrate (16) is formed by the deposition of a support structure material through a patterned masking material (14). The support structure can define cells into which the ceramic insulating material is deposited following removal of the masking material. The masking material may be patterned by known photolithographic techniques (22,24) or by laser etching (48). The support structure (28) may be a composite metal-ceramic material having either discreet layers (30,34) or a graded composition and may be deposited by an electro-desposition process followed by a heat treatment to form a solid state diffusion bond with the substrate.

Abstract: The invention relates to a novel thermal spray process for the deposition of coatings with a graded or layered composition and the coated articles produced thereby. More particularly, the invention relates to feeding mixtures of coating materials to a thermal spray device and continuously or intermittently changing the composition of the deposited coatings by changing the thermal spray operating parameters. The continuous or intermittent change in the composition of the coating material during deposition creates a graded or layered coating structure.

Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises a polymer basecoat layer on the surface of said article and vapor deposited at relatively low pressure on the polymer layer a protective and decorative color layer comprised of the reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen wherein the nitrogen and oxygen content of the reaction products are each from about 4 to about 32 atomic percent with the nitrogen content being at least about 3 atomic percent.

Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises a polymeric basecoat layer on the surface of said article and vapor deposited on the polymeric basecoat layer a stack layer containing layers of refractory metal or refractory metal alloy alternating with layers containing the reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen. Over the stack layer is vapor deposited at relatively low pressures a protective color layer comprised of the reaction products of refractory metal or refractory metal alloy, oxygen and nitrogen wherein the total nitrogen and oxygen content of these reaction products is from about 4 to about 32 atomic percent, with the nitrogen content being at least about 3 atomic percent.

Abstract: The aim of the present invention is to provide a phosphate treated zinc coated steel sheet with excellent workability. A steel sheet coated with a zinc based alloy has a phosphate treated coating on the surface thereof. The phosphate treated coating comprises mainly granulated crystals, specifically, crystals in which the average ratio of the major axis to the minor axis is not less than 1.00 and not more than 2.90. Moreover, the method for producing the phosphate treated coating uses a phosphate treatment solution in which the amount of Mg ions is ≧6 g/l and the amount of Zn ions is ≧0.5 g/l, or a phosphate treatment solution in which the amount of Mg ions is ≧10 g/l, the amount of Zn ions is 0≦ and <0.5 g/l, and the amount of nitric acid ions is ≧40 g/l.

Abstract: An article is coated with a multi-layer coating having a bronze color. The coating comprises a nickel basecoat layer, and a color and protective stack layer comprised of layers of carbon-rich refractory metal or refractory metal alloy carbonitride alternating with layers of nitrogen-rich refractory metal or refractory metal alloy carbonitride.

Abstract: A processing solution for forming a hexavalent chromium free, corrosion resistant trivalent chromate conversion film on zinc or zinc alloy plating layers comprises a silicon compound; trivalent chromium and oxalic acid in a molar ratio ranging from 0.5 to 1.5, wherein the trivalent chromium is present in the form of a water-soluble complex with oxalic acid; and cobalt ions, which form a hardly soluble metal salt with oxalic acid and are stably present in the processing solution without causing any precipitation, wherein the solution reacts with zinc when bringing it into contact with the zinc or zinc alloy plating to form a hexavalent chromium free, corrosion resistant, trivalent chromate conversion film containing zinc, chromium, cobalt, oxalic acid and silicon on the plating. This solution can provide a corrosion resistant trivalent chromate conversion film excellent in the corrosion resistance after heating.

Abstract: A glass pane is provided with a multilayer system having metallic reflection and a high thermal resistance. The multilayer system comprises a dielectric base layer, a metal layer having a high reflection, made of chromium or a metal alloy containing at least 45 wt % chromium, and a nitride top layer. The dielectric base layer is composed of at least one oxide partial layer made of SnO2, ZnO and/or TiO2, close to the surface of the glass, and a nitride partial layer, close to the metal layer.