Abstract: According to one embodiment, a ceramic metal circuit board is a ceramic metal circuit board formed by bonding metal circuit plates to at least one surface of a ceramic substrate. At least one of the metal circuit plates has an area of not less than 100 mm2 and includes a concave portion having a depth of not less than 0.02 mm within a range of 1% to 70% of a surface of the at least one of the metal circuit plates. The concave portion is provided not less than 3 mm inside from an end of the metal circuit plate.

Abstract: The present disclosure relates to an aluminum member including a mother material containing aluminum or an aluminum alloy, and an anodic oxide film on the surface of the mother material. The anodic oxide film has a barrier layer on the surface of the mother material, and a porous layer on the barrier layer), and the BET specific surface area of the anodic oxide film is 0.1 to 10.0 m2/g.

Abstract: The present disclosure belongs to the field of preparation technology and provides an ultralimit alloy and a preparation method therefor. The ultralimit alloy comprises an alloy matrix. A bonding layer and a ceramic layer are successively deposited on a surface of the alloy matrix. The alloy matrix includes one of a magnesium alloy matrix, an aluminium alloy matrix, a titanium alloy matrix, an iron alloy matrix, a nickel alloy matrix, a copper alloy matrix, a zirconium alloy, and a tin alloy. For an ultralimit magnesium alloy, an ultralimit aluminium alloy, an ultralimit nickel alloy, an ultralimit titanium alloy, an ultralimit iron alloy and an ultralimit copper alloy, the bonding layer is a composite bonding layer, the ceramic layer is a composite ceramic layer, and the outside of the composite ceramic layer is further successively deposited with a reflecting layer, a catadioptric layer, an insulating layer and a carbon foam layer.

Abstract: A thermal barrier coating for an internal combustion engine includes an insulating thermal spray coating, where a chosen material of the insulating thermal spray coating has a thermal conductivity lower than 2 W/mK in fully dense form and the chosen material includes a coefficient of thermal expansion within 5 ppm/K of a coefficient of thermal expansion of a material of a component of the internal combustion engine upon which the coating is placed.

Abstract: A method for conditioning ceramic coating on a part for use in a plasma processing chamber is provided. The ceramic coating is wetted with a solution, wherein the solution is formed by mixing a solvent with an electrolyte, wherein from 1% to 10% of the electrolyte dissociates in the solution. The ceramic coating is blasted with particles. The ceramic coating is rinsed.

Abstract: When a slurry s obtained by dispersing a rare-earth-compound powder in a solvent is applied to sintered magnet bodies m, and dried to remove the solvent in the slurry and cause the surfaces of the sintered magnet bodies to be coated with the powder, and the sintered magnet bodies coated with the powder are heat treated to cause the rare-earth element to be absorbed by the sintered magnet bodies, the sintered magnet bodies m are warmed or heated before the slurry s is applied. As a result, the rare-earth-compound powder can be efficiently and uniformly applied to the surfaces of the sintered magnet bodies.

Abstract: A dual wall liner for a gas turbine engine may comprise a shell having a first side and a second side, a panel contacting the shell, the panel at least partially defining a hot gas path through which a hot gas flows, wherein the first side of the shell faces the panel, wherein the shell includes a thermal barrier coating (TBC) disposed on the first side of the shell. The TBC may thermally protect the shell from heat from a hot gas path.

Abstract: A hot-dip zinc-based plated steel sheet includes: a base steel sheet that is a metal substrate; a hot-dip zinc-based plating layer provided on the base steel sheet; and a surface treatment layer formed on at least one surface of the hot-dip zinc-based plating layer, in which the surface treatment layer contains more than or equal to 0.1 g/m2 and less than or equal to 1.2 g/m2 of granular oxide per one surface on a metal basis in which, in a temperature range of 900 to 1300 K, standard free energy of formation (?G0) of oxide is smaller than standard free energy of formation (?G0Zn) of zinc oxide and larger than standard free energy of formation (?G0Al) of aluminum oxide at an identical temperature, and the granular oxide has a particle size of more than or equal to 3 nm and less than or equal to 100 nm.

Abstract: The present disclosure provides insulated electrical conductors, e.g., wires, and methods for producing such insulated electrical conductors to combat partial discharge by enhancing bond strength between the electrical conductor and a base insulating thermoplastic layer (e.g., including a PAEK). Such insulated electrical conductors can include: an electrical conductor; an insulating coating on at least a portion of a surface of the electrical conductor; and an oxide layer between the electrical conductor and the insulating coating. Methods for producing such insulated electrical conductors can involve extrusion of an insulating polymer onto the electrical conductor under ambient atmosphere and a subsequent heat treatment step, which can also be conducted under ambient atmosphere.

Abstract: Disclosed herein is an article comprising one or more channels and a multi-layer protective coating on the one or more channels. The multi-layer protective coating includes an anodization layer comprising a plurality of cracks and a plurality of pores, a sealing layer on the anodization layer, and a top layer on the sealing layer. The sealing layer comprises a metal oxide, the seals the plurality of cracks and the plurality of pores, and has a porosity of approximately 0%. The top layer comprises a rare earth oxide, a rare earth fluoride, or a rare earth oxyfluoride, has a different material composition than the sealing layer, and has a porosity of approximately 0%.

Abstract: An HPF molding member having a melted aluminum plating layer formed on the surface of a base steel sheet and excellent delamination resistance. The base steel sheet comprises: 0.18-0.25% by weight of C; 0.1-1.0% by weight of Si; 0.9-1.5% by weight of Mn; 0.03% by weight or less of P; 0.01% by weight or less of S; 0.01-0.05% by weight of Al; 0.05-0.5% by weight of Cr; 0.01-0.05% by weight of Ti; 0.001-0.005% by weight of B; 0.009% by weight or less of N; and the balance Fe and other impurities. The plating layer consists of a soft diffusion layer and a hard alloy layer, the hard alloy layer having a tau layer irregularly and non-continuously dispersed and distributed on the inside thereof at 10% or more of the entire area fraction. The difference in hardness between the alloy layer and the diffusion layer is 400 (Hv) or less.

Abstract: Techniques for forming an enclosure comprised of aluminum zirconium alloy layer are disclosed. In some embodiments, aluminum ions and zirconium ions can be dissolved in a non-aqueous ionic liquid in an electrolytic plating bath. A reverse pulsed electric current can facilitate in co-depositing the aluminum ions and the zirconium ions onto a metal substrate. The resulting aluminum zirconium alloy layer can include nanocrystalline grain structures, which can impart the alloy layer with increased hardness and increased resistance to scratching, denting, and abrasion. In some embodiments, the aluminum zirconium alloy layer can be anodized to form an aluminum oxide layer. Subsequent to the anodization operation, the oxidized layer is able to retain its substantially neutral color.

Abstract: Techniques for forming an enclosure comprised of an aluminum alloy are disclosed. In some embodiments, aluminum ions and metal element ions can be dissolved in a non-aqueous ionic liquid in an electrolytic plating bath. A reverse pulsed electric current can facilitate in co-depositing the aluminum ions and the metal element ions onto a metal substrate. The resulting aluminum alloy layer can include nanocrystalline structures, which can impart the alloy layer with increased hardness and increased resistance to scratching, corrosion, and abrasion. In some embodiments, the metal element ion is chromium and the aluminum alloy layer includes a chromium oxide passivation layer formed via a passivation process. Subsequent to the passivation process, the formation of the chromium oxide layer does not impart a change in color to the aluminum alloy layer. In some embodiments, hafnium ions are co-deposited with aluminum ions to form an aluminum hafnium alloy.

Abstract: A sliding member having a supporting layer composed of an iron-based metallic material and a sliding layer formed on a surface of the supporting layer and composed of a copper-based metallic material. The surface of the supporting layer and the sliding layer have non-flat surfaces. A sliding surface having a non-flat surface is formed on the surface of the sliding layer. The sliding layer is formed on the roughened surface of the supporting layer by thermal spraying. The surface of the sliding layer is then subjected to a shot blasting treatment to form the sliding surface which has an uneven surface having an arithmetic average roughness (Ra) of more than 0 ?m and 2.0 ?m or less, a ten-point average roughness (Rz) of more than 0 ?m and 7.5 ?m or less and a surface hardness (Hv) of 150-250, and which slidably supports an object to be slid.

Abstract: A color converter comprising at least one layer comprising at least one organic fluorescent colorant and at least one barrier layer having a low permeability to oxygen.

Abstract: The invention relates to a steel part coated with a compound consisting, over more than 90% of its thickness, of at least one Fe/Zn-based phase, the iron weight content of which is equal to 65% or higher and the Fe/Zn ratio of which is between 1.9 and 4, said compound being formed by at least one heat treatment for alloying between said steel and a precoat, said precoat consisting of a zinc alloy comprising, the contents being expressed by weight, between 0.5 and 2.5% aluminum and, optionally, one or more elements chosen from: Pb?0.003%; Sb?0.003%; Bi?0.003%; 0.002%?Si?0.070%; La<0.05%; Ce<0.05%, the balance consisting of zinc and inevitable impurities.

Abstract: A high-manganese hot-dip coated steel sheet is disclosed which provides high corrosion resistance, high ductility and high strength, mainly used for inner and outer panels of automobiles, and a method of manufacturing the same. The high-manganese hot-dip coated steel sheet includes a substrate steel sheet having a composition of (in weight %) 0.1 to 1.5% of C, 5 to 35% of Mn, and the remainder includes Fe and other unavoidable impurities, and a hot-dip zinc coating layer formed on the substrate steel sheet, the hot-dip zinc coating layer having a composition of (in weight %) 0.1 to 10% of Mn, 5 to 15% of Fe, and the remainder including Zn and other unavoidable impurities.

Abstract: Methods for fabricating an integrated circuit are provided herein. In an embodiment, a method for fabricating an integrated circuit includes forming a gate electrode structure overlying a semiconductor substrate. A first sacrificial oxide layer is formed overlying the semiconductor substrate and a first implant mask is patterned overlying the first sacrificial oxide layer to expose a portion of the first sacrificial oxide layer adjacent the gate electrode structure. Conductivity determining ions are implanted into the semiconductor substrate, through the first sacrificial oxide layer. The first implant mask and the first sacrificial oxide layer are removed after implanting the conductivity determining ions into the semiconductor substrate.

Abstract: A method embodiment includes forming a sacrificial film layer over a top surface of a die, the die having a contact pad at the top surface. The die is attached to a carrier, and a molding compound is formed over the die and the sacrificial film layer. The molding compound extends along sidewalls of the die. The sacrificial film layer is exposed. The contact pad is exposed by removing at least a portion of the sacrificial film layer. A first polymer layer is formed over the die, and a redistribution layer (RDL) is formed over the die and electrically connects to the contact pad.

Abstract: A heat treated galvannealed steel material having excellent post-painting corrosion resistance and a high strength which is suitable for use as an automotive part and a method for its manufacture are provided. A galvannealed steel material having a galvannealed coating on at least one side thereof is heat treated by heating at least a portion thereof to a temperature range in which hardening is possible. The coating remaining on the surface of at least a part of the portion which underwent heat treatment has a coating weight of at least 20 g/m2 and at most 80 g/m2 per side and an Fe content of at least 15% and at most 35%, an ? phase is present in the coating, and the centerline average roughness Ra of the surface of the coating is at most 1.5 ?m.

Abstract: A hot-pressed member includes a steel sheet, a Ni-diffusion region present in a surface layer of the steel sheet, and an intermetallic compound layer and a ZnO layer which are provided in order on the Ni-diffusion region, the intermetallic compound layer corresponding to a ? phase present in a phase equilibrium diagram of a Zn—Ni alloy, wherein a spontaneous immersion potential indicated in a 0.5 M NaCl aqueous air-saturated solution at 25° C.±5° C. is ?600 to ?360 mV based on a standard hydrogen electrode.

Abstract: A flexible multilayer substrate includes a multilayer body including a plurality of laminated resin layers. The multilayer body includes an innermost surface, which is a surface on an inner side when the substrate is bent, and an outermost surface, which is a surface on an outer side when the substrate is bent. Each of the plurality of resin layers includes a skin layer on one surface. Lamination of the multilayer body includes a skin layer joint plane at one location at a central portion in the thickness direction, and the skin layer and other surface come in contact with each other at another location along the central portion in the thickness direction. A skin layer joint plane is arranged on a side closer to the innermost surface than a central plane in the thickness direction of the multilayer body.

Abstract: The present invention relates to a textured substrate for epitaxial film formation, comprising a textured metal layer at least on one side, wherein the textured metal layer includes a copper layer having a cube texture and a nickel layer having a thickness of 100 to 20000 nm formed on the copper layer; the nickel layer has a nickel oxide layer formed on a surface thereof, having a thickness of 1 to 30 nm, and including a nickel oxide; and the nickel layer further includes a palladium-containing region formed of palladium-containing nickel at an interface with the nickel oxide layer. The top layer of the textured substrate, i.e. the nickel oxide layer, has a surface roughness of preferably 10 nm or less.

Abstract: A black-plated steel sheet has a Zn-plating layer containing molten Al and Mg, containing Al in the amount of 1.0-22.0 mass %, containing Mg in the amount of 1.3-10.0 mass %, and having a Zn black oxide distributed in a lamella pattern in the plating layer. The Zn black oxide is a Zn oxide derived from a Zn2Mg phase. The brightness of the surface of the Zn-plating layer containing the molten Al and Mg has an L* value of 60 or less.

Abstract: The present invention relates to a Zn—Mg alloy-coated steel sheet with excellent blackening resistance and excellent coating adhesion and to a method for manufacturing same. Provided are a Zn—Mg alloy-coated steel sheet with excellent blackening resistance and excellent adhesion and a method for manufacturing same, the steel sheet comprising: a substrate steel sheet; a Zn—Fe intermetallic compound layer formed on the substrate steel sheet; a first Zn—Mg coating layer formed on the Zn—Fe intermetallic compound layer and comprising a Zn—Fe intermetallic compound in which the content of Zn is 95% by weight or higher; a second Zn—Mg coating layer formed on the first Zn—Mg coating layer and comprising a Zn—Mg intermetallic compound in which the content of Zn is 80 to 95% by weight; and an oxide film formed on the second Zn—Mg coating layer and comprising a metallic oxide.

Abstract: A conductor for a flexible substrate, used for a flexible flat cable or disposed inside a flexible printed-circuit board, according to the present invention comprises: a base conductor made of Cu or Cu-alloy; a plating film made of Sn or Sn-alloy formed on a surface of the base conductor; and a surface oxide film formed on a surface of the plating film, in which the surface oxide film includes oxide of an element other than Sn or a mixture of Sn oxide and oxide of an element other than Sn.

Abstract: A galvannealed steel sheet having high corrosion resistance after painting includes, on a mass percent basis, C: 0.05% to 0.15%, Si: 0.1% to 1.0%, Mn: 0.5% to 2.7%, Al: ?1.00%, P: ?0.025%, S: ?0.025%, and Cr: 0% to 0.8% as chemical components, the remainder being Fe and incidental impurities. The galvannealed steel sheet includes a galvannealed layer in an amount of 20 to 120 g/m2 per side, a percentage of exposed zinc metal of the galvannealed layer surface being 20% or more and less than 80%, and an amount of internal oxidation in a region disposed not more than 5 ?m from the surface of the steel sheet is 0.02 g/m2 or more and 0.1 g/m2 or less: Si?0.68%, Cr??1.25Si+0.85, and Si>0.68%, Cr=0, wherein Si and Cr denote respective contents (mass %) of Si and Cr.

Abstract: A perovskite manganese oxide thin film formed on a substrate that allows a first order phase transition and has A-site ordering. The thin film contains Ba and a rare earth element in the A sites of a perovskite crystal lattice and has an (m10) orientation for which m=2n, and 9?n?1. A method for manufacturing the film includes forming in a controlled atmosphere using laser ablation an atomic layer or thin film that assumes a pyramidal structure having oxygen-deficient sites in a plane containing the rare earth element and oxygen; and filling the oxygen-deficient sites with oxygen. The controlled atmosphere has an oxygen partial pressure controlled to a thermodynamically required value for creating oxygen deficiencies and contains a gas other than oxygen, and has a total pressure that is controlled to a value at which the A sites have a fixed compositional ratio.

Abstract: A method for plating magnets with metal is disclosed. In one embodiment, the metal is aluminum and the aluminum plating provides a number of aesthetic and structural advantages, over brittle magnetic materials, which are only plated with a thin, anti-corrosive metallic layer. More specifically, methods for creating multi-pole bar magnets and structural elements primarily with aluminum coated magnetic material are disclosed.

Abstract: A method of forming a dense oxide coating on an aluminum component of semiconductor processing equipment comprises cold spraying a layer of pure aluminum on a surface of the aluminum component to a predetermined thickness. A dense oxide coating is then formed on the layer of pure aluminum using a plasma electrolytic oxidation process, wherein the plasma electrolytic oxidation process causes the layer of pure aluminum to undergo microplasmic discharges, thus forming the dense oxide coating on the layer of pure aluminum on the surface of the aluminum component.

Abstract: A strip product consists of a metallic substrate, such as stainless steel, and a coating, which in turn comprises at least one metallic layer and one reactive layer. The coated strip product is produced by providing the different layers, preferably by coating, and thereafter oxidizing the coating to accomplish a conductive surface layer comprising perovskite and/or spinel structure.

Abstract: A surface-treated steel plate obtained by forming, on at least one surface of the steel plate by cathodic electrolysis, a surface-treating film which contains a mixed oxide of an oxide of Fe and at least one of an oxide of Zr or an oxide of Ti, and a polycarboxylic acid, the amount of Zr or Ti, or the total amount of Zr and Ti if both of them are present, being from 3 to 300 mg/m2 and the amount of C being from 0.1 to 5.0 mg/m2.

Abstract: In an embodiment of the invention, a method for manufacturing a carrier-attached copper foil is provided. The method includes providing a carrier foil including stainless steel, titanium, aluminum, nickel or alloy thereof with a surface oxide layer, and forming a copper foil onto the carrier foil to prepare the carrier-attached copper foil.

Abstract: A fired heater tube that is resistant to corrosion and fouling is disclosed. The fired heater tube comprises an advantageous high performance coated material composition resistant to corrosion and fouling comprises: (PQR), wherein P is an oxide layer at the surface of (PQR), Q is a coating metal layer interposed between P and R, and R is a base metal layer, wherein P is substantially comprised of alumina, chromia, silica, mullite, spinels, and mixtures thereof, Q comprises Cr, and at least one element selected from the group consisting of Ni, Al, Si, Mn, Fe, Co, B, C, N, P, Ga, Ge, As, In, Sn, Sb, Pb, Sc, La, Y, Ce, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Re, Ru, Rh, Ir, Pd, Pt, Cu, Ag, Au and mixtures thereof, and R is selected from the group consisting of low chromium steels, ferritic stainless steels, austenetic stainless steels, duplex stainless steels, Inconel alloys, Incoloy alloys, Fe—Ni based alloys, Ni-based alloys and Co-based alloys.

Abstract: An article may include a substrate, a diffusion barrier layer formed on the substrate, and a protective layer formed on the diffusion barrier coating. The diffusion barrier layer may include iridium.

Abstract: A palladium plated aluminum component of a semiconductor plasma processing chamber comprises a substrate including at least an aluminum or aluminum alloy surface, and a palladium plating on the aluminum or aluminum alloy surface of the substrate. The palladium plating comprises an exposed surface of the component and/or a mating surface of the component.

Abstract: An organic light emitting display apparatus includes a substrate; a display unit formed on the substrate and comprising an organic light emitting device; and a touch panel formed on the display unit, wherein the touch panel further includes a sealing substrate, a ground layer formed on a surface of the sealing substrate, a first pattern layer formed on a surface of the sealing substrate opposite to the surface of the sealing substrate on which the ground layer is formed, a first insulating layer formed on the first pattern layer, a second pattern layer formed on the first insulating layer, and a second insulating layer formed on the second pattern layer.

Abstract: A coating steel component with a pattern of an iron based matrix with crystalline particles metallurgically bound to the surface of a steel substrate for use as disc cutters or other components with one or more abrading surfaces that can experience significant abrasive wear, high point loads, and large shear stresses during use. The coated component contains a pattern of features in the shape of freckles or stripes that are laser formed and fused to the steel substrate. The features can display an inner core that is harder than the steel substrate but generally softer than the matrix surrounding the core, providing toughness and wear resistance to the features. The features result from processing an amorphous alloy where the resulting matrix can be amorphous, partially devitrified or fully devitrified.

Abstract: A hot-pressed member includes a steel sheet, a Ni-diffusion region present in a surface layer of the steel sheet, and an intermetallic compound layer and a ZnO layer which are provided in order on the Ni-diffusion region, the intermetallic compound layer corresponding to a ? phase present in a phase equilibrium diagram of a Zn—Ni alloy, wherein a spontaneous immersion potential indicated in a 0.5 M NaCl aqueous air-saturated solution at 25° C.±5° C. is ?600 to ?360 mV based on a standard hydrogen electrode.

Abstract: A flat steel product which is provided for forming into a component by hot pressing and which has a base layer of steel on which is applied a Zn or a Zn alloy metallic protective coating for protecting against corrosion. On at least one of the free surfaces of the flat steel product, a separate cover layer is applied which contains an oxide, nitride, sulphide, carbide, hydrate or phosphate compound of a base metal. In addition, a method which allows the production of such a flat steel product, and a method which allows the production of a component from such a flat steel product.

Abstract: The present invention relates generally to an antibacterial coating which is composed of silver, to medical tools and to implants comprising such a coating and to a method as well to an apparatus for the production of such a coating. The medical tools or the dental or orthopaedic implant comprises a metal or metal alloy having a treated surface wherein the treated surface is at least partially converted to an oxide film by plasma electrolytic oxidation using a colloid-dispersed system and wherein the converted surface is partially covered by islands formed by colloid-dispersed silver-particles of the colloid-dispersed system. An Ag—TiO2 coating shows excellent properties in terms of antibacterial efficacy (even against multi-resistant strains), adhesion and biocompatibility. The life-time of an implant in a human body is increased. The antibacterial coating can be used in the field of traumatology, orthopaedic, osteosynthesis and/or endoprothesis, especially where high infection risk exists.

Abstract: A transparent conductive thin film comprises at least one stack layer of Ag—Ag3Sn—SnOx, or at least one stack layer of Ag—Ag4Sn—SnOx.

Abstract: Powders of respective metal elements (Mn, Co) constituting a transition metal oxide (MnCo2O4) having a spinel type crystal structure are used as a starting material of the coating film. A film of a paste containing the mixture of the powders is formed on the surface of the interconnector, and with this state, the paste is sintered to form the coating film. In the coating body, a chromia layer including Cr2O3, a first layer including elements of Mn, Co, Fe, Cr, and O, and a second layer including elements of Mn, Co, Fe, and O are provided in this order from the side close to the interconnector at the boundary between the coating film and the interconnector. With this structure, the coating film is difficult to be peeled even if the coating body is placed in a severe temperature change.

Abstract: A piston ring includes: a refined steel including: carbon C in a range of 0.20% mass to 0.90% mass, silicon Si in a range of 0.10% mass to less than 0.60% mass, manganese Mn in a range of 0.20% mass to 1.50% mass, chromium Cr in a range of 0.30% mass to 2.00% mass, and a remnant including: iron Fe, and an unavoidable impurity. A parameter A calculated from the following expression (1) based on contents of the Si, Mn and Cr is 9.0 or less: parameter A=8.8 Si+1.6 Mn+1.7 Cr—expression (1). A parameter B calculated from the following expression (2) based on contents of the C, Si, Mn and Cr is 10.8 or more: parameter B=36 C+4.2 Si+3.8 Mn+4.5 Cr—expression (2).

Abstract: A plating film is provided with enough hardness before anodic oxidation, which is hard to be damaged during handling, and also the production method of the plating film. This problem can be solved by an aluminum plating film with aluminum concentration of 98 wt. % or lower, and with a Vickers hardness of 250 or higher. The hardness is increased by containing oxygen, carbon, sulfur, and a halogen element as impurities. The impurity concentration is controlled by adjusting the current density, the plating temperature, or the plating bath composition.

Abstract: Provided is a rolled copper foil or electrolytic copper foil for an electronic circuit to be used for forming a circuit by etching, wherein the copper foil comprises a heat resistance layer composed of zinc or zinc alloy or its oxide formed on an etching side of the rolled copper foil or electrolytic copper foil, and a layer of nickel or nickel alloy, which is a metal or alloy with a lower etching rate than copper, formed on the heat resistance layer.

Abstract: A method of imparting corrosion resistance to an edge of a multilayer window film having a metal layer arranged between a pair of polymeric layers includes the step of treating the edge of the window film with a corrosion inhibitor.

Abstract: A multilayer coating includes a bond coat layer, a first barrier layer applied on the bond coat layer, and a second barrier layer applied on the first barrier layer. The first barrier layer has a compositional gradient comprising a majority of a first rare earth stabilized zirconia material proximate the bond coat layer to a majority of a second rare earth stabilized zirconia material away from the bond coat layer. The first and second rare earth stabilized zirconia materials are different. The second barrier layer has a compositional gradient comprising a majority of the second rare earth stabilized zirconia material to 100 wt % of a third rare earth stabilized zirconia material away from the first barrier layer.

Abstract: The present invention relates to a metallic laminate and a manufacturing method of a light emitting diode package using the same. The present invention provides a metallic laminate including: a core layer made of an insulating material; a metal layer disposed on one surface of the core layer; a heat radiating metal layer disposed on the other surface of the core layer; and a protective metal oxide layer disposed along an outer surface of the heat radiating metal layer and made of an oxide of the heat radiating metal layer.

Abstract: Monolithic ceramic bodies that have a mixed-oxide marginal region and a metallic surface, where the ceramic body includes an oxide of a first metal (I), while the mixed-oxide marginal region includes the oxide of the first metal (I) and the oxide of a further metal (II) having a high affinity for oxygen, and the metallic surface includes the further metal (II). The mixed oxide marginal region includes a continuous concentration gradient of the first metal (I), from 100% in the core to 0% in the transitional region to the metallic surface of the ceramic body, and a continuous concentration gradient of the further metal (II), starting from 0% in the core to 100% in the transitional region to the metallic surface of the ceramic body, where the oxygen concentration in the mixed-oxide marginal region remains constant, and the monolithic structure of the ceramic body has no phase boundaries.