Abstract: A magnetic optical recording element including a rare earth-transition metal recording layer, a barrier layer and a self-passivating active metal layer.

Abstract: A composite material suitable for providing insulation for the nozzle structure of the Space Shuttle and other similar surfaces is disclosed which comprises an outer skin layer of nickel chromium and an interleaved inner region comprising a top layer of nickel chromium foil which acts as a primary convective shield, at least two layers of alumina batting adjacent to layers of silicon carbide fabric, and an additional layer of nickel chromium foil to be used as a secondary convective shield. The composite is particularly advantageous for use as nozzle insulation because of its ability to withstand high reentry temperatures, its flexibility, oxidation resistance, low conductivity, and light weight.

Abstract: There is disclosed a wear resistant surface layer composed of 40 to 70 wt. % cobalt or cobalt base alloy as binder and the balance is substantially chromium oxide particles.

Abstract: Disclosed is a steel sheet having an organic composite plating layer excellent in press workability, spot weldability, electrodeposition coatability and corrosion resistance which comprises a zinc plated, aluminum plated or zinc base composite alloy plated steel sheet, a first layer of an insoluble chromate film of 5% or less in the content of water-soluble matter formed on the surface of the steel sheet at a coverage of 10-150 mg/m.sup.2 in terms of chromium content and a second layer of a coating composition having the following composition coated at a thickness of 0.3-5 .mu.

Abstract: A thin film type magnetic recording medium having a durability close to that of the coating type magneting recording medium is provided by a metal oxide protective layer which is formed by a physical vapor deposition.

Abstract: Composite-coated flat-rolled steel can stock processing and product for fabrication of sheet metal cans, in particular for three-piece, welded or cemented side seam cans. Single or double-reduced, low carbon, flat-rolled steel of a gage in the range of about 55 to 110 pounds per base box is flash coated with tin (0.05 #/bb), which is alloyed with the steel base metal; at least 0.20 #/bb of tin is added to one surface only, flow brightened and water quenched; chemical treatment chrome oxide coating of about 100 to 750 milligrams per square foot is added to both surfaces and an organic coating of 2.5 to 15 milligrams per square inch is added to the surface which is free of flow-brightened tin for disposition internally of a can fabricated from such coated can stock. The equivalent of quarter-pound and higher coating weight tinplate protection is provided while decreasing tin requirements and maintaining three-piece can fabrication properties not available with coating metal substitutes for tin.

Abstract: Bronze-grey films for window glazing structures are disclosed. The subject bronze-grey films are characterized by having a layer of reactive-sputtered titanium suboxide of controlled composition between the bronze-grey metal layer and the plastic sheet which makes up the substrate of the film. The process by which these films can be made is also disclosed. These films offer superior resistance to failure by delamination.

Abstract: A corrosion resistant metal pipe having an outer surface coated with a zinc film, a chromate film, an intermediate layer consisting substantially of an epoxy resin, and a polyvinyl fluoride film formed one upon another in the order listed.

Abstract: In the electroplated steel sheets for automobile use, the chipping resistance, water-resistant adhesion, unpainted corrosion resistance, post-painted corrosion resistance, and resistance to secular exposure are improved by superimposing a chemical conversion layer between electroplated layers of zinc and iron, nickel, cobalt, or alloys thereof.

Abstract: A thin film noble metal temperature sensor includes adjacent layers of metals and metal oxides on the surface of a component. The most preferred sequence of layers are: a NiCoCrAlY layer applied directly to the component surface; a thermally grown aluminum oxide layer on the NiCoCrAly layer; a sputtered layer of aluminum oxide on the thermally grown layer of aluminum oxide; a FeCrAl layer on the sputtered aluminum oxide layer; and layer of platinum and platinum-rhodium on the FeCrAl layer.

Abstract: A solder bonding technique for bonding discrete circuit elements to conductors on an alumina substrate. The conductors are composed of palladium and silver, and atop each conductor at a bonding site, a layer of silver is provided. A layer of solder is disposed over the layer of silver. The compliancy of the silver layer absorbs stresses created by thermal cycles and thereby improves the peel strength of the solder bond.

Abstract: Multilayered coated corrosion resistant steel material having a galvanized layer on one surface thereof, an electro-deposited layer on said galvanized layer formed from a zinc-based alloy containing nickel and having a thickness of one to six microns; and a resin layer on said electrodeposited layer.

Abstract: A process is provided for protecting metallic surfaces such as stainless steel, against vanadosodic corrosion which utilizes at least one metal such as the alkaline earth metals which oxidizes in situ into a protective layer. The layer forms a compound with vanadium and/or sodium oxide which has a softening point higher than that of the oxide.

Abstract: A pressure sensor element is disclosed which essentially comprises a high-strength electric insulating ceramic substrate and a silver coating tightly deposited on the surface of the substrate. When a region of the element is subjected to a high pressure, the electric resistance in the region concerned changes in proportion to the magnitude of the pressure.

Abstract: A chromate surface treated steel sheet having very excellent paintability, corrosion resistance, and workability, more specifically surface treated steel sheets for paint coating, having very excellent properties, specifically with respect to corrosion resistance after paint coating, paint adhesion in services long after the paint coating (so-called secondary paint adhesion), corrosion resistance of paint coating defect portions, and resistance to secondary work cracking. The steel sheet contains not more than 0.15% carbon, 0.005 to 0.10% acid soluble aluminium, 0.5 to 20% chromium with the balance being iron and unavoidable impurities, and the chromate coating applied on the steel substrate comprises a metallic chromium layer in an amount ranging from 1 to 300 mg/m.sup.2, and a hydrated chromium oxide layer in an amount ranging from 5 to 50 mg/m.sup.2 in term of the metallic chromium contained therein.

Abstract: A metallic coating (20) is produced on a non-weldable inorganic substrate (6) by hot-spraying on a hot-sprayed intermediate layer (19) of refractory metal alloy chosen from nickel-chromium alloys and nickel and titanium aluminides. This intermediate layer itself may be deposited on an undercoat (18) of a ceramic chosen from aluminium and zirconium oxides and titanium hydrides, which is formed by hot-spraying on the inorganic substrate (6).

Abstract: Hydrogenated boron-silicon alloy films having unexpected properties permitting in one embodiment the bonding together of metal and ceramic substrates by coating the surfaces to be bonded with the film mating the surfaces and heat treating the mated surfaces to expell hydrogen therefrom and to react to resulting boron-silicon alloy film with the substrates to form a liquid reaction product which forms a surface bond with the substrates or is at least partially absorbed in the substrates. In another embodiment, at least one surface of an intermetallic compound formed from elements selected from groups III and V of the periodic table is sealed against structural degradation by forming on the surface a solid boron-silicon-hydrogen alloy film. In still another embodiment, metal and organic resin substrates are protected against attack by water vapor, dissociated oxygen and molecular oxygen by forming a solid boron-silicon-hydrogen alloy film on the substrates.

Abstract: A plated composite steel strip having a high corrosion resistance comprises a steel strip substrate, a base electroplating layer comprising a Zn or Zn alloy matrix, substantially water-insoluble chromate particles, and additional fine or colloidal particles of SiO.sub.2, TiO.sub.2, Cr.sub.2 O.sub.3, Al.sub.2 O.sub.3, ZrO.sub.2,SnO.sub.2 and/or Sb.sub.2 O.sub.5, and optionally, an additional electroplating layer formed on the base layer and consisting of Zn, Fe, Co, Ni, Mn and/or Cr and/or a surface coating layer containing at least an organic resinous surface layer and formed on the base, or an additional electroplating layer.

Abstract: A buried conductive and/or reflective layer is provided in an optical element including at least one chemically vapor deposited material layer. Over a first layer of material is provided an intermediate region. The intermediate region in one embodiment includes at least one layer of a refractory-type material. In an alternate embodiment, the intermediate region is a composite intermediate region including a first passivating layer comprising a layer of a refractory-type of material such as one of the borides, carbides, nitrides, oxides and silicides, or a refractory-type of metal such as tungsten, molybdenum, tantalum, titanium and rhodium or a refractory-type of metal alloy. A conductive layer is then provided over at least a portion of the first passivating layer. Said conductive layer may comprise any of the highly conductive/reflective metals such as copper, gold, silver, palladium, platinum and aluminum, for example.

Abstract: An improved hermetically sealed semiconductor casing and a process for producing the casing are disclosed. This casing includes a lead frame having an electrical device affixed thereto. A base member is glass bonded to a matching surface of the lead frame. A metal window frame shaped device is provided having one surface with a refractory oxide coating and a second opposite readily solderable surface. The refractory oxide layer of the window frame device is glass bonded to the lead frame and the base member. The semiconductor or electrical device is connected to the lead frame after the window frame has been glass bonded into place. A metal lid having a solderable surface is solder bonded to the solderable surface of the window frame to hermetically seal the electrical device within the casing.

Abstract: An electrically conductive glass sheet used as a fog-resistant automotive window glass sheet. The electrically conductive glass sheet comprises a glass sheet, a pair of busbars, an electrically conductive thin film, and protective coatings. The busbars are formed in spaced relation on the surface of the glass sheet by baking electrically conductive paste printed on the surface of the glass sheet. The electrically conductive thin film formed on the surface of the glass sheet has ends or junctions connected to the busbars in overlapping relation to the surfaces of the busbars, the junctions being covered with the protective coatings. Since the junctions are covered with the protective coatings, good electric conductivity through the junctions is ensured for increased fog resistance, and variations from glass sheet to glass sheet are reduced.

Abstract: A semiconductor window which is transparent to light in the infrared range and which has good electrical conductivity is formed with a substrate of semi-conductor material which has a conduction modifying dopant diffused, grown or deposited on one surface thereof to a substantial depth so that a layer thereof exhibits reduced resistance to a value below 10 ohms/square. Anti-reflection dielectric layers are stacked on both outer surfaces thereof. The dielectric substrate may be of silicon, germanium or gallium arsenide depending on the transparency bandwidth of interest. The thickness of the substrate and the doping of the surface thereof is closely controlled to obtain both low electrical resistivity and high optical transmissivity.

Abstract: Hydrogenated boron-silicon alloy films having unexpected properties permitting in one embodiment the bonding together of metal and ceramic substrates by coating the surfaces to be bonded with the film mating the surfaces and heat treating the mated surfaces to expell hydrogen therefrom and to react to resulting boron-silicon alloy film with the substrates to form a liquid reaction product which forms a surface bond with the substrates or is at least partially absorbed in the substrates. In another embodiment, at least one surface of an intermetallic compound formed from elements selected from groups III and V of the periodic table is sealed against structural degradation by forming on the surface a solid boron-silicon-hydrogen alloy film. In still another embodimemt, metal amd organic resin substrates are protected against attack by water vapor, dissociated oxygen and molecular oxygen by forming a solid boron-silicon-hydrogen alloy film on the substrates.

Abstract: The present invention relates to a highly corrosion-resistant surface-treated steel plate. The steel plate of the present invention comprises a zinc deposition or zinc alloy deposition film as the undercoat deposition layer, a chromate film formed on the undercoat deposition layer and a film of a resin composition formed on the chromate film. This resin composition comprises a base resin formed by adding at least one basic nitrogen atom and at least two primary hydroxyl groups to terminals of an epoxy resin. The resin composition may comprise a polyisocyanate compound as the curing agent. Furthermore, the resin composition may comprise silica or a hardly soluble chromium compound as the additive for improving the corrosion resistance. Moreover, the resin composition may comprise a silane compound as the crosslinking agent for the base resin and silica.

Abstract: A buried conductive and/or reflective layer is provided in an optical element including at least one chemically vapor deposited material layer. Over a first layer of material is provided an intermediate region. The intermediate region in one embodiment includes at least one layer of a refractory-type material. In an alternate embodiment, the intermediate region is a composite intermediate region including a first passivating layer comprising a layer of a refractory-type of material such as one of the borides, carbides, nitrides, oxides and silicides, or a refractory-type of metal such as tungsten, molybdenum, tantalum, titanium and rhodium or a refractory-type of metal alloy. A conductive layer is then provided over at least a portion of the first passivating layer. Said conductive layer may comprise any one of the highly conductive/reflective metals such as copper, gold, silver, palladium, platinum and aluminum, for example.

Abstract: A buried conductive and/or reflective layer is provided in an optical element including at least one chemically vapor deposited material layer. Over a first layer of material is provided an intermediate region. The intermediate region in one embodiment includes at least one layer of a refractory-type material. In an alternate embodiment, the intermediate region is a composite intermediate region including a first passivating layer comprising a layer of a refractory-type of material such as one of the borides, carbides, nitrides, oxides and silicides, or a refractory-type of metal such as tungsten, molybdenum, tantalum, titanium and rhodium or a refractory-type of metal alloy. A conductive layer is then provided over at least a portion of the first passivating layer. Said conductive layer may comprise any one of the highly conductive/reflective metals such as copper, gold, silver, palladium, platinum and aluminum, for example.

Abstract: A method for depositing a protective coating by cathode sputtering of an alloy of aluminum and silicon in a reactive gas is disclosed. The sputtering target contains sufficient silicon to produce an amorphous coating; 6 to 18 percent silicon is preferred. Targets of approximately 88% aluminum and 12% silicon are especially preferred. Oxygen, nitrogen, compounds of oxygen and compounds of nitrogen are preferred reactive gases. A range of combinations of oxygen and nitrogen are particularly preferred. The method provides durable transparent coatings which may be used as an overcoating for a metal or dielectric coating to provide increased resistance to abrasion and corrosion. In particular, the protected coating may be a metal, dielectric or dielectric-metal-dielectric coating as used in double-glazed window units for buildings or vehicles.

Abstract: The invention is an oxalloy consisting essentially of about 5 to about 57 weight percent magnesium or aluminum and about 0.5 to about 10 weight percent of one or more alloying materials selected from the group consisting of B, Al, Si, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ge, As, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, Ga, In, Sn, Sb, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, Pb, Bi, Th, and rare earths; and the remainder oxygen.The invention also includes a method for forming the above oxalloys and a substrate coated with the oxalloys of the present invention.

Abstract: The bonding of nickel, cobalt, copper or any number of metals to oxide ceramics is achieved whereby the substrate and associated metallurgy are co-sintered. The invention teaches the use of an intermediary oxide such as Al2O3, Cr2O3, TiO2 or ZrO2 which will adhere to the substrate and in the presence of firing ambients form a complex ternary oxide with the overlying metal thereby creating the desired bond. The eutectic can be created during the firing cycle without the undesired consequence of oxidizing the metal. The so-called intermediary oxides can be oxidized in situ, deposited as oxides, or introduced into either the ceramic composition or the metal paste.

Abstract: Shock wave formation of superconductive ceramic oxide electric and magnetic circuit elements with improved microstructures and mechanical properties.

Abstract: Erosion resistance is imparted to a metallic substrate without an attendant loss of fatigue life in the substrate in one embodiment by applying to the substrate a first ductile layer comprising a metal from Group VI to Group VIII elements as well as the noble metal group of elements, and a second hard erosion-resistant layer applied on the first layer comprising a boride, carbide, nitride or oxide of a metal selected from Group III to Group VI elements, the first layer capable of retaining substrate integrity and preventing diffusion of material from the second layer into the substrate. Another embodiment defines another layer of a substantially pure metal from Group III to Group VI between the first and second layers. Still another embodiment defines that in the second layer the content of either the carbide, nitride, boride or oxide is graded, i.e.

Abstract: Herein is disclosed a magnetic recording member having a high mechanical durability and an improved resistance to wear. The magnetic recording member comprises a substrate, a magnetic layer formed on the surface of the substrate and a first non-magnetic layer of a metal having a low melting point, preferably lower than 400.degree. C. and formed on the magnetic layer, at least the surface of the first non-magnetic layer being oxidized. The magnetic recording member may further contain a lubricant layer.The surface of the magnetic recording member of the invention presents a roughness lower than 25 nm and includes fine protrusions having a linear density higher than 1.times.10.sup.3 /mm.The process for the preparation of the magnetic recording member is also disclosed.

Abstract: A process for producing silver-coated potassium titanate fibers comprises admixing the potassium titanate fibers with a silver ion solution containing a reducing agent. The resulting silver-coated potassium titanate fibers can, if desired, be provided with one or more additional metal coatings superimposed on the silver coat wherein the additional metal is other than silver.

Abstract: Described are an aluminium-based article having a heat and corrosion protective coating, especially engine parts such as piston crown or cylinder head, and a method of preparing said article. The coating consists of an aluminium-based bonding layer, preferably having a thickness in the range 0.1-0.6 mm, and an outer top layer of stabilized or partially stabilized zirconium dioxide, preferably having a thickness in the range 0.5-2.5 mm, and optionally a cermet layer, comprising zirconium dioxide and an aluminium-based metal component, between the bonding layer and the outer zirconium dioxide top layer. The bonding layer is applied to the substrate by thermal spraying of a rapidly solidified powder, substantially consisting of 60-80% by weight of Al and 40-20% by weight of Si, the particles of the powder having a frozen unstable micro-structure.

Abstract: A ceramic-metal composite body including (a) a ceramic member, (b) a ferrous metal member bonded to the ceramic member, (c) an intermediate metallic member joined to the iron base member, and (d) an aluminum member bonded to the intermediate metallic member. The ceramic member and the aluminum member are integrally joined through the ferrous metal member and the intermediate metallic member.

Abstract: A combination ceramic sealing cover for a semiconductor package has a flat ceramic lid member with metallization applied as a foundation for a seal ring or frame portion. On the metallized layer is a gold-tin solder layer, in the form of either a solder ring that is tack welded on, or solder paste that is screened onto the base metallization and furnace reflowed.

Abstract: A molybdenum article is disclosed in which the substrate thereof has adherently bonded thereto a thermally self-healing plasma-sprayed coating consisting essentially of a composite of molybdenum and a refractory oxide material capable of reacting with molybdenum oxide under oxidizing conditions to form a substantially thermally stable refractory compound of molybdenum. The plasma-sprayed coating is formed of a plurality of interbonded plasma-sprayed layers of a composite of molybdenum/refractory oxide material produced from a particulate mixture thereof. The coating comprises a first layer of molybdenum plasma-sprayed bonded to the substrate of said molybdenum element and a second layer of plasma-sprayed mixture of particulate molybdenum/refractory oxide consisting essentially of predominantly molybdenum bonded to the first layer.

Abstract: Metal-ceramic joined articles having a splendid joint strength can be provided easily, even when the metallic member has a largely different thermal expansion coefficient from that of the ceramic member of the metal-ceramic article.

Abstract: A method of joining ceramics and metals to themselves and to one another at about 800.degree. C. is described using a brazing filler metal consisting essentially of 35 to 50 at. % copper, 40 to 50 at. % silver, 1 to 15 at. % titanium, and 2 to 8 at. % tin. This method produces strong joints that can withstand high service temperatures and oxidizing environments.

Abstract: A composite magnetic material and a magnetic head made from this composite magnetic material formed of a combination of a body of a magnetic metal material and a magnetic oxide material joined together in such a manner as to provide improved strength while attaining an improved manufacturability and regenerative sensitivity at high frequencies. In accordance with the invention, the two bodies are joined together with a thin magnetic metal film initially formed on the oxide material body by vapor deposition or sputtering. The thin magnetic metal film can be made of the same material as the magnetic metal material body.

Abstract: This application is directed to a process of forming a laminate. The steps include providing a glass and a metal foil of either deoxidized copper alloy or oxygen-free copper alloy. The glass is heated at a temperature of between about 600.degree. to about 1025.degree. C. with a viscosity between about 10.sup.3 to about 10.sup.8 poise. Then it is pressed against the foil and cooled to chemically bond it to the foil and form a laminate of a metal foil and a substantially pore-free glass.

Abstract: The present invention describes an improved reverse lamination process for reparing printed circuits with resistors, conductor strips and/or contacts integrated in the circuit. A separating layer is applied on a metallic intermediate carrier. The intermediate carrier thus coated is then printed with a conductive paste in a desired. mirror-inverted layout to provide the resistors, conductor strips and/or contacts. This is followed by the lamination which is carried out under temperature effect and under pressure, the thus laminated package comprising the intermediate carrier, an intermediate layer and the final substrate. The intermediate carrier is subsequently removed, and the separating layer is etched off. The separating layer acts as a parting agent to permit easy mechanical separation and reuse of the metallic intermediate carrier.

Abstract: A multiple layer high transmittance, low emissivity coated article is disclosed with improved chemical resistance as a result of a protective overcoat of titanium oxide.

Abstract: The Sn based multilayer coated steel strip for container-use is improved by the provision of a novel underlying coating of ternary Fe-Ni-P alloy which, mainly because of the Ni component, ensures a uniform deposition of the Sn layer, and mainly because of the P and Fe contents ensure a satisfactory remaining amount of free Sn for improving the weldability. The steel strip has a thin Sn plated layer and a chromate coating layer on the underlying coating.

Abstract: Methods are disclosed for the manufacture of optical conductive transparent windows and coatings having high transparency over a wide bandwidth combined with a large acceptance angle of incidence. Particulars for making windows and coatings with gold films of high transparency and low sheet resistance using specified nucleating and barrier layers are given. Examples include windows and coatings constructed for operation in the infrared and ultraviolet.

Abstract: A surface-coated steel strip having improved corrosion resistance as well as a good surface appearance is disclosed. The steel strip comprises a zinc alloy layer plated on the steel strip, and a passive-state layer 0.005 to 1.0 .mu.m thick which is applied on top of the plated zinc layer. A chromate film and/or an organic resin layer may be applied thereon.

Abstract: A heat resistant precoated steel sheet suitable for use in the manufacture of a muffler of an automobile exhaust gas system comprising:a hot dip aluminized steel sheet,a chromate pretreatment layer formed on at least one surface of said hot dip aluminized steel sheet and having a chromium pickup of 10 to 50 mg/m.sup.2,a primer coat formed on said pretreatment layer and comprising a cured polyamide imide resin and 8 to 52 parts by weight, based on 100 parts by weight of said resin, of strontium chromate intimately admixed with said resin, anda top coat formed on said primer coat and comprising a cured silicone-modified polyester resin with a modification degree of from 30 to 50% and 8 to 32 parts by weight, based on 100 parts by weight of said resin, of aluminum scale intimately admixed with said resin.

Abstract: A method of joining ceramics and metals to themselves and to one another is described using a brazing filler metal consisting essentially of 35 to 50 atomic percent copper, 15 to 50 atomic percent silver and 10 to 45 atomic percent titanium. This method produces strong joints that can withstand high service temperatures and oxidizing environments.

Abstract: A heat resistant precoated steel sheet suitable for use in the manufacture of a muffler of an automobile exhaust gas system comprising:a hot dip aluminized steel sheet,a chromate pretreatment layer formed on at least one surface of said hot dip aluminized steel sheet and having a chromium pick-up of 10 to 50 mg/m.sup.2,a primer coat formed on said pretreatment layer and comprising a cured polyamide imide resin and 8 to 52 parts by weight, based on 100 parts by weight of said resin, of strontium chromate intimately admixed with said resin, anda top coat formed on said primer coat and comprising a cured polyamide imide resin and 8 to 32 parts by weight, based on 100 parts by weight of said resin, of aluminum scale intimately admixed with said resin.

Abstract: Hydrogenated boron-silica alloy films having unexpected properties permitting in one embodiment the bonding together of metal and ceramic substrates by coating the surfaces to be bonded with the film mating the surfaces and heat treating the mated surfaces to expell hydrogen therefrom and to react to resulting boron-silicon alloy film with the substrates to form a liquid reaction product which forms a surface bond with the substrates or is at least partially absorbed in the substrates. In another embodiment, at least one surface of an intermetallic compound formed from elements selected from groups III and V of the periodic table is sealed against structural degradation by forming on the surface a solid boron-silicon-hydrogen alloy film. In still another embodiment, metal and organic resin substrates are protected against attack by water vapor, dissociated oxygen and molecular oxygen by forming a solid boron-silicon-hydrogen alloy film on the substrates.