Oxide-containing Component Patents (Class 428/632)
  • Patent number: 5525431
    Abstract: A zinc-base galvanized sheet steel which comprises zinc-base plated sheet steel and, formed on the plating layer surface, an inorganic covering layer which contains at least one inorganic oxide in an amount of 1-500 mg/m.sup.2 in terms of the weight of metallic elements exclusive of oxygen and optionally contains at least one oxoacid or inorganic oxide colloid in an amount of 1-500 mg/m.sup.2 and further, as desired for improving weldability, a Zn oxide film formed between the inorganic covering layer and the zinc-base plating layer, and the process for producing said galvanized sheet steel.
    Type: Grant
    Filed: August 19, 1993
    Date of Patent: June 11, 1996
    Assignee: Nippon Steel Corporation
    Inventors: Tatsuya Kanamaru, Junichi Morita, Katsutoshi Arai, Shinichi Suzuki
  • Patent number: 5523132
    Abstract: Solar energy absorptive coatings that comprise single cermet layers with a homogeneous metal volume fraction exhibit an absorptance of about 0.8, which is not high enough for practical solar applications. To achieve absorptance greater than 0.9, graded composite films have been developed, but they give rise to higher thermal emittance due to the absorption edge not being sharp enough. This leads to increased thermal emittance at high operating temperatures, in the range of 300.degree. C. to 500.degree. C. There is now disclosed a novel solar selective surface coating which is composed of two cermet layers, with different metal volume fractions in each layer. The two cermet layers have different thicknesses, and the layers have thicknesses and volume fractions such that solar radiation is absorbed by internal absorbing and phase cancellation interference, but the cermet layers are substantially transparent in the thermal infrared region.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: June 4, 1996
    Assignee: The University of Sydney
    Inventors: Qi-Chu Zhang, David Mills, Anthony Monger
  • Patent number: 5523050
    Abstract: A method is described for preparing a refined or reinforced eutectic or hyper-eutectic metal alloy, comprising: melting the eutectic or hyper-eutectic metal alloy, adding particles of non-metallic refractory material to the molten metal matrix, mixing together the molten metal alloy and the particles of refractory material, and casting the resulting mixture under conditions causing precipitation of at least one intermetallic phase from the molten metal matrix during solidification thereof such that the intermetallics formed during solidification wet and engulf said refractory particles. The added particles may be very small and serve only to refine the precipitating intermetallics in the alloy or they may be larger and serve as reinforcing particles in a composite with the alloy. The products obtained are also novel.
    Type: Grant
    Filed: March 15, 1993
    Date of Patent: June 4, 1996
    Assignee: Alcan International Limited
    Inventors: David J. Lloyd, Iljoon Jin
  • Patent number: 5520323
    Abstract: Contacts such as contact points, contact strips, or contact sections are usually provided with hard solder on a copper-silver basis in the form of a flat solder layer. The contact is then connected over this solder layer with a contact carrier. The solder layer is melted, whereupon the free surface of the solder layer (13, 130) is covered during melting with a material (1, 5, 15) that has no solubility with silver or copper. The material can, during melting of the solder, form a covering (1, 15) beneath the contact (10, 12, 100) provided on its solder side with the solder layer (13, 130) or can also form a covering over the contact (10, 12, 100) provided on its solder side with the solder layer (13, 130). As materials for covering the solder layer (13, 130), high-melting metals, preferably tantalum, or a ceramic are used.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: May 28, 1996
    Assignee: Siemens Aktiengesellschaft
    Inventors: Franz Hauner, Manfred Schneider
  • Patent number: 5518793
    Abstract: A cast-iron pipework element adapted to be buried has an external coating made up of an inner layer of zinc, a porous intermediate layer of zinc/aluminium alloy containing from 5 to 55% of aluminium, and a porous outer layer, or pore-blocking layer, comprising an organic binder, especially a water-based paint, a bitumen varnish or an epoxy resin.
    Type: Grant
    Filed: July 27, 1994
    Date of Patent: May 21, 1996
    Assignee: Pont-A-Mousson S.A.
    Inventors: Jean-Marc Pedeutour, Jean Bello, Gerard Nouail, Rio Bellocci
  • Patent number: 5514483
    Abstract: The improved organic composite coated steel plate includes a zinc or zinc alloy plated steel plate as a substrate that has on its surface a chromate film the Cr.sup.6+ content of which is no more than 70% of the total Cr content and which is deposited in an amount of 5-500 mg/m.sup.2 in terms of metallic chromium, the chromate film being overlaid with a resin layer that is deposited in an amount of 0.1-3 g/m.sup.2 on a dry weight basis and which is formed primarily of water-dispersed silica and one organic resin member as selected from the group consisting of an anionic aqueous resin, a nonionic aqueous resin and an anionic aqueous urethane resin. This steel plate is adapted for not contaminating the environment of the earth in the process of its manufacture.
    Type: Grant
    Filed: August 16, 1993
    Date of Patent: May 7, 1996
    Assignee: Kawasaki Steel Corporation
    Inventors: Shigeko Sujita, Ryoichi Muko, Kyoko Hamahara, Kazuo Mochizuki, Nobuyuki Morito
  • Patent number: 5513040
    Abstract: A solar control film having low visible light transmittance and low visible light reflectance is comprised of two or more transparent substrates each bearing a thin, transparent, discontinuous, incoherent film of metal having low visible light reflectance and a degree of visible light blocking capacity, the substrates being so assembled and laminated into a composite that the visible light blocking capacities of the metal films are effectively combined to provide a composite having low visible light transmittance. Performance characteristics are enhanced by providing on one or more of the substrates a transparent coating of high refractive index underlying the metal film. The material of high refractive index is preferably a synthetic high oxygen content oxide of bismuth, which facilitates efficient and economical production of the solar control film.
    Type: Grant
    Filed: November 1, 1994
    Date of Patent: April 30, 1996
    Assignee: Deposition Technologies, Inc.
    Inventor: Peter Y. Yang
  • Patent number: 5512382
    Abstract: A thermal barrier coating for superalloy turbine engine vanes and blades that are exposed to high temperature gas is disclosed. The coating includes a ceramic layer applied to an Aluminide or MCrAlY bond coat by electron beam physical vapor deposition. The ceramic layer has a first portion having unstabilized porosity, a second portion, overlying the first portion, with stabilized porosity, and an outer portion wherein the pores are coated with a noble metal. The stabilized porosity portion along with the noble metal coating reduce the thermal conductivity of the ceramic layer. Stabilizing the porosity renders it more resistant to sintering densification at high temperatures.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: April 30, 1996
    Assignee: AlliedSignal Inc.
    Inventor: Thomas E. Strangman
  • Patent number: 5506058
    Abstract: A multilayer glass ceramic substrate includes a glass ceramic layer and a plurality of conductive layers laminated via the glass ceramic layer. The glass ceramic layer is composed of inorganic compound consisting of aluminum oxide, borosilicate glass, anorthite crystal and celsian crystal wherein the aluminum oxide is contained in the range of 12 to 59.6 weight percent, the borosilicate glass is contained in the range of 18 to 69.6 weight percent, the anorthite crystal is contained in the range of 1 to 40 weight percent and the celsian crystal is contained in the range of 1 to 5 weight percent so that the total is 100 weight percent.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: April 9, 1996
    Assignee: NEC Corporation
    Inventors: Kazuhiro Ikuina, Mitsuru Kimura
  • Patent number: 5498484
    Abstract: A thermal barrier coating system for high temperature nickel-based and cobalt-based superalloys includes a hardenable metallic coating on the substrate and a ceramic topcoat. The metallic coating is preferably a gamma/gamma prime hardenable nickel-based superalloy, and the ceramic topcoat is preferably zirconium oxide having from about 6 to about 20 percent yttrium oxide or from about 15 to about 40 percent cerium oxide. Optionally, there may be provided between the hardenable metallic layer and the ceramic topcoat an intermetallic coating such as a nickel aluminide.
    Type: Grant
    Filed: May 7, 1990
    Date of Patent: March 12, 1996
    Assignee: General Electric Company
    Inventor: Edward C. Duderstadt
  • Patent number: 5494760
    Abstract: The object comprises a glass-metal film (1) with a metal matrix (2) which has solidified in an at least partly glass-like form and which may comprise hard particles (3, 3a) in the form of primary precipitates from the molten mass. The glass-metal film (1) is provided on at least one side (4) with a top layer (5) comprising a hard material which is harder than the glass-metal film (1). The top layer (5) may be formed by a base layer (7) with embedded hard material particles (8), e.g. of diamond or cubic boron nitride, or by a homogeneous hard material, e.g. diamond-like carbon. The result is a surface quality which can be separately influenced by the composition of the alloy of the glass-metal film (1). The object may be formed either as a parting tool or as a structural part with special wear and/or sliding properties.
    Type: Grant
    Filed: October 9, 1992
    Date of Patent: February 27, 1996
    Assignee: Gebrueder Sulzer Aktiengesellschaft
    Inventors: Giorgio Arnosti, Werner Straub, Erich Bolle
  • Patent number: 5482787
    Abstract: An organic composite coated steel strip having well-balanced corrosion resistance, coating properties including adaptability to electrophoretic coating and water resistant secondary coating adherence, and spot weldability is provided. The organic composite coated strip comprises a zinc or zinc base alloy plated steel substrate; a chromate later on the substrate containing up to 70% by weight of Cr.sup.6+ based on the total chromium quantity, the chromate layer being coated in a weight of 5 to 500 mg/m.sup.2 in terms of elemental chromium; and an organic composite layer on the chromate layer mainly comprising silica and an organic high molecular weight resin. In the organic composite coated steel strip, (a) silica has an average primary particle diameter of 5 to 30 nm; (b) silica is agglomerated into agglomerates of an average thickness of 0.2 to 2 .mu.m and an average apparent diameter of 5 to 300 .mu.m; and (c) the organic composite layer has been coated to a dry weight of 0.1 to 3 g/m.sup.2.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: January 9, 1996
    Assignee: Kawasaki Steel Corporation
    Inventors: Shigeko Sujita, Nobuyuki Morito
  • Patent number: 5478655
    Abstract: Painted metal sheet pretreated with a composite coating including an insoluble, inorganic inner layer and an organic outer layer. The inorganic layer is formed by rinsing the sheet with an alkaline solution containing at least 0.005M of at least one of a dissolved silicate or a dissolved aluminate. The sheet is dried to form an inorganic layer having a thickness of at least 2 .ANG.. The inorganically coated sheet then is rinsed with a solution containing at least 0.1 vol.-% of a hydrolyzed silane and at least 0.02 vol.-% of a hydrolyzed crosslinking agent. The silane treated sheet is dried to form a siloxane layer having an average thickness at least 5 .ANG.. After being painted, the siloxane layer forms an adherent bond between the paint and the metal substrate. The metal preferably is a chromium alloyed steel and may be etched prior to being rinsed with the alkaline solution to remove chromium oxide to further enhance the paint adhesion.
    Type: Grant
    Filed: January 25, 1994
    Date of Patent: December 26, 1995
    Assignee: Armco Inc.
    Inventors: Ashok Sabata, Wim J. van Ooij
  • Patent number: 5474282
    Abstract: Disclosed is a composite material for handling molten metal, the material having a tensile strength of greater than 30 ksi and being resistant to attack by the molten metal. The composite comprises a base layer of titanium base alloy having bonded thereto a protective refractory coating resistant to attack by the molten metal.
    Type: Grant
    Filed: July 13, 1993
    Date of Patent: December 12, 1995
    Inventor: C. Edward Eckert
  • Patent number: 5472795
    Abstract: Layers of zirconium oxide and another ceramic, such as alumina or silicon carbide, are sequentially deposited on a support to form a nanolaminate containing a thin layer of polycrystalline metastable tetragonal zirconia deposited on the support. A process for making a nanolaminate material of the invention is carried out by sputter deposition. Zirconia is deposited on the chosen support by vacuum sputter deposition under conditions effective to form a thin layer of polycrystalline, metastable tetragonal zirconia on the support. A hard ceramic such as alumina is then deposited on the support by vacuum sputter deposition under conditions effective to form a thin layer of hard ceramic superposed on the zirconia layer.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: December 5, 1995
    Assignee: Board of Regents of The University of The University of Wisconsin System, on Behalf of The University of Wisconsin-Milwaukee
    Inventor: Carolyn R. Atita
  • Patent number: 5465898
    Abstract: A process is provided where a ceramic metal substrate is produced by attaching metal foils on either side a ceramic layer to form metal layers and for producing a through connection by placing metal in an opening to form a bridge so that the metal layers are electrically connected together by direct bonding, and a metal body is inserted into the opening to almost fill it, while a surface of the metal body is provided with a layer with chemical compound of metal and reactive gas.
    Type: Grant
    Filed: May 31, 1994
    Date of Patent: November 14, 1995
    Inventors: Jurgen Schulz-Harder, Peter H. Maier
  • Patent number: 5455119
    Abstract: A coating composition comprising an alloy having the formula RCrAlR'R" wherein R is nickel, cobalt or the like; R' is yttrium or hafnium and R" is tantalum, rhenium and/or platinum, preferably mixed with an oxide dispersion such as alumina, to provide an improved class of coatings suitable for operating in high temperature oxidizing environments.
    Type: Grant
    Filed: November 8, 1993
    Date of Patent: October 3, 1995
    Assignees: Praxair S.T. Technology, Inc., Rolls-Royce PLC
    Inventors: Thomas A. Taylor, David F. Bettridge, Robert C. Tucker, Jr.
  • Patent number: 5437937
    Abstract: A process for improving the ability of a metal surface to adhere comprising contacting the metal surface with an aqueous medium comprising a solution of a salt of at least one metal selected from the group consisting of yttrium and metals of the lanthanum series having atomic numbers from 57 to 71 inclusive, and subsequently contacting the metal surface with a solution of organosilane.
    Type: Grant
    Filed: May 12, 1993
    Date of Patent: August 1, 1995
    Assignee: Richard A. Cayless
    Inventor: Richard A. Cayless
  • Patent number: 5429880
    Abstract: An organic composite coated steel sheet having a high cosmetic corrosion resistance and excellent image clarity which is desired on, for example, the outside of an outer plate forming an automobile body. The steel sheet has a chromate layer formed on the surface of a zinc or a zinc alloy plate steel sheet, and containing a specific weight of chromium, and an organic resin film formed on the chromate layer from a mixture in specific proportions of a blocked urethane-modified epoxy resin and a rust-preventing additive, and having a thickness of 0.2 to 2 microns. The resin is a mixture in specific proportions of a modified epoxy resin (A) which consists of an epoxy resin and a polyfunctional amine, and may further contain a monoisocyanate, or phosphoric acid, and a blocked urethane (B) which consists of a high molecular weight polyol having a molecular weight of 400 or more, a polyisocyanate and a blocking agent. A process for manufacturing the strip is also disclosed.
    Type: Grant
    Filed: March 9, 1993
    Date of Patent: July 4, 1995
    Assignee: NKK Corporation
    Inventors: Takahiro Kubota, Masaaki Yamashita, Toyofumi Watanabe, Yoshio Kikuta, Kimio Kobori, Hideaki Ogata
  • Patent number: 5429881
    Abstract: Surface-treated Al or Al alloy materials which excel in adhesive property, formability, weldability, phosphatability, paint adhesion, and post-painting corrosion resistance are provided by forming a coated layer containing Zn and Fe or one or more of Si oxides, Al oxides and Al hydroxides together therewith, on the surface of Al or Al alloy base. The surface-treated Al or Al alloy materials are useful as metallic material to be painted and used after press forming and other processing, spot or laser welding and phosphating, including panel materials for automobiles and other various vehicles, shells for housefold electrical apparatus, and building materials.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: July 4, 1995
    Assignees: Toyota Jidosha Kabushiki Kaisha, Kabushiki Kaisha Kobe Seiko Sho
    Inventors: Masamichi Aono, Toshihiro Chikada, Souichi Hayashi, Asao Mochizuki, Hiroshi Sato, Kouki Ikeda, Jun Hisamoto, Nagisa Takee, Toshiki Ueda, Masao Takemoto, Hideo Fujimoto, Akihiro Tsuruno, Kikuo Toyose
  • Patent number: 5427601
    Abstract: A sintered metal body is disclosed of composition consisting essentially of in weight percent about 5 to 40 Cr, about 2 to 30 Al, 0 to about 5 special metal, 0 to about 4 rare earth oxide additive, and the balance Fe group metal and unavoidable impurities,the composition including at least one component selected from component A and/or component B, component A being special metal, and component B being at least an effective amount of rare earth oxide additive,the special metal being a first special metal component, and optionally, a second special metal component when rare earth oxide additive is 0, the first special metal component consisting of at least one of: Y, lanthanides, Zr, Hf, Ti, Si, and B, and the second special metal component consisting of at least one of: alkaline earth metal, Cu, and Sn, and the special metal being a third special metal component when rare earth oxide additive is >0, the third special metal component consisting of at least one of Y, lanthanides, Zr, Hf, Ti, Si, alkaline ear
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: June 27, 1995
    Assignees: NGK Insulators, Ltd., Corning Inc.
    Inventors: Takashi Harada, Yoshihiro Fujiwara, Fumio Abe, Tsuneaki Ohashi, Hiroshige Mizuno, Kevin R. Brundage, Srinivas H. Swaroop, David F. Thompson, Raja R. Wusirika, David S. Weiss
  • Patent number: 5422192
    Abstract: A steel product (or copper-plated steel product) with heat-resistant, corrosion-resistant plating layers which are composed of a 0.2-10 .mu.m thick nickel plating layer formed on said steel product, a Zn-Ni alloy plating layer formed on said nickel plating layer, and a chromate film formed on said Zn-Ni alloy plating layer.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: June 6, 1995
    Assignee: Usui Kokusai Sangyo Kaisha Ltd.
    Inventors: Teruhisa Takahashi, Seiya Takahata
  • Patent number: 5419971
    Abstract: An article having a substrate is protected by a thermal barrier coating system. An interfacial layer contacts the upper surface of the substrate. The interfacial layer may comprise a bond coat only, or a bond coat and an overlay coat. The interfacial layer has on its upper surface a preselected, controllable pattern of three-dimensional features, such as grooves in a parallel array or in two angularly offset arrays. The features are formed by an ablation process using an ultraviolet laser such as an excimer laser. A ceramic thermal barrier coating is deposited over the pattern of features on the upper surface of the interfacial layer.
    Type: Grant
    Filed: March 3, 1993
    Date of Patent: May 30, 1995
    Assignee: General Electric Company
    Inventors: David W. Skelly, Bangalore A. Nagaraj, David J. Wortman, David V. Rigney, Seetha R. Mannava, Rudolfo Viguie, Robert W. Bruce, Warren A. Nelson, Curtis A. Johnson, Bhupendra K. Gupta
  • Patent number: 5401715
    Abstract: A semiconductor substrate having a silicon substrate and a superconducting thin film layer composed of compound oxide such as Ln.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-.delta. (Ln is lanthanide) and stratified on the silicon substrate, characterized in that an intermediate semiconductor layer composed of compound semiconductor material such as GaAs is interposed between the silicon substrate and the superconducting thin film layer.
    Type: Grant
    Filed: November 6, 1992
    Date of Patent: March 28, 1995
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Hideo Itozaki, Keizo Harada, Naoji Fujimori, Shuji Yazu, Tetsuji Jodai
  • Patent number: 5364708
    Abstract: A recording layer 3 including shape-memory alloy thin films 311, 312 and a hydrogen storage alloy thin film 32, a dielectric thin film 4, and a reflective thin film 5 are stacked on a surface of a substrate 2 in the described order. Irradiation of recording light causes the hydrogen storage alloy thin film 32 to release hydrogen gas and contract in volume at the same time, creating a space 321 in the film. The shape-memory alloy thin films 311, 312 are deformed by the gas pressure in space 321, allowing space 321 to enlarge its thickness. Upon exposure to erasing light, shape-memory alloy thin films 311, 312 tend to restore their shape prior to deformation, applying pressure to the hydrogen gas in space 321 so that the hydrogen gas is occluded again and space 321 is substantially extinguished. Reversible release and occlusion of hydrogen gas enables to rewrite the recording information.
    Type: Grant
    Filed: February 14, 1992
    Date of Patent: November 15, 1994
    Assignee: TDK Corporation
    Inventor: Junji Tominaga
  • Patent number: 5361172
    Abstract: A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: November 1, 1994
    Assignee: Midwest Research Institute
    Inventors: Paul O. Schissel, Cheryl E. Kennedy, Gary J. Jorgensen, Yvonne D. Shinton, Rita M. Goggin
  • Patent number: 5352537
    Abstract: A metal matrix composite is produced by forming a rapidly solidified aluminum base alloy into powder. The powder is plasma sprayed onto at least one substrate having thereon a fiber reinforcing material to form a plurality of preforms. Each of the preforms has a layer of the alloy deposited thereon, and the fiber reinforcing material is present in an amount ranging from about 0.1 to 75 percent by volume thereof. The preforms are bonded together to form an engineering shape.
    Type: Grant
    Filed: December 7, 1992
    Date of Patent: October 4, 1994
    Assignee: AlliedSignal Inc.
    Inventors: Santosh K. Das, Michael S. Zedalis, Paul S. Gilman
  • Patent number: 5350639
    Abstract: Dielectric ceramics a microwave device made of (Bi.sub.2 O.sub.3).sub..times. (Nb.sub.2 O.sub.5).sub.1-x includes at least one of subcomponents of CuO and V.sub.2 O.sub.5, wherein the composition ratio x is fallen into a range of 0.48.ltoreq..times..ltoreq.0.51, an atomic ratio AR1 defined by the following equation:AR1=(the number of Cu atoms of the CuO)/ARO,whereARO=(the number of Bi atoms of the (Bi.sub.2 O.sub.3).sub.x (Nb.sub.2 O.sub.5).sub.1-x)+(the number of Nb atoms of the (Bi.sub.2 O.sub.3).sub.x (Nb.sub.2 O.sub.5).sub.1-x)is fallen into a range of 0<AR1< 0.01, and another atomic ratio AR2 defined by the following equation:AR2=(the number of V atoms of the V.sub.2 O.sub.5)/AROis fallen into a range of 0<AR2.ltoreq. 0.02.
    Type: Grant
    Filed: September 8, 1992
    Date of Patent: September 27, 1994
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Tatsuya Inoue, Hiroshi Kagata, Junichi Kato, Ichiro Kameyama
  • Patent number: 5338619
    Abstract: A copper foil for printed circuits having a rust-preventive and heat-discoloration resistant coat, comprising a first layer of zinc or an alloy or a compound or a composition including zinc mainly, and a second layer including a silane coupling agent and phosphorus or a phosphorus compound, said second layer being positioned on the first layer. A method of producing a copper foil for printed circuits comprising the steps of treating the shiny side of a copper foil in a manner of cathode electrolysis in an alkaline solution including zinc ions and chrome ions, or providing the shiny side of a copper foil with a thin plating layer of zinc or a zinc alloy, and thereafter applying onto the treated surface of the copper foil a solution including a silane coupling agent and phosphorus or a phosphorus compound.
    Type: Grant
    Filed: August 4, 1992
    Date of Patent: August 16, 1994
    Assignee: Fukuda Metal Foil and Powder Co., Ltd.
    Inventors: Katsuhito Fukuda, Masato Takami, Hirokazu Hasegawa, Chiaki Nakajima, Kenji Isihara
  • Patent number: 5336341
    Abstract: An infrared radiation element and a process for producing the same. An aluminum alloy material consists essentially of 0.3 to 4.3 weight % of Mn, balance Al, and impurities. The alluminum alloy material is heated for dispersing a precipitate of an Al--Mn intermetallic compound at a density of at a minimum 1.times.10.sup.5 /mm.sup.3 for a size of 0.1 .mu.m to 3 .mu.m. The heated aluminum alloy material is anodized to form an anodic oxide layer thereon.
    Type: Grant
    Filed: August 30, 1991
    Date of Patent: August 9, 1994
    Assignees: Fujikura Ltd., Sky Aluminium Co., Ltd.
    Inventors: Masatsugu Maejima, Koichi Saruwatari, Akihito Kurosaka, Mamoru Matsuo, Hiroyoshi Gunji, Toshiki Muramatsu
  • Patent number: 5330851
    Abstract: A corrosion resistant Al or Al alloy material on the surface of which multi-layer deposits for improved corrosion resistance. The deposits are obtained by laminating more than five layers of unit periodic layers with a thickness of 100 .ANG. or less in which two, or three or more layers of unit deposits, comprised of specific elements, are laminated. Such multi-layer structure can prevent water, chloride and other corrosion accelerating substances from passing through the deposits and reaching the surface of the base material, thus effectively preventing the corrosion of Al or Al alloy.
    Type: Grant
    Filed: April 22, 1993
    Date of Patent: July 19, 1994
    Assignee: Kabushiki Kaisha Kobe Seiko Sho
    Inventors: Takenori Nakayama, Toyohiko Konno
  • Patent number: 5330826
    Abstract: A metal substrate, e.g. titanium, having a calcium phosphate coating, particularly hydroxylapatite, and containing a metal such as cobalt, codeposited on the substrate by electrolyzing a cobalt salt, particularly cobalt sulfate, liquid electrolyte having a calcium phosphate material, particularly hydroxylapatite, suspended therein, employing a cobalt anode and the metal substrate as cathode. The particles of cobalt so codeposited with the particles of calcium phosphate material, e.g. hydroxylapatite, hold the latter particles strongly on the substrate metal. If desired, a second coating of the pure calcium phosphate material, e.g. "hydroxylapatite", optionally can be applied over the codeposited hydroxylapatite-cobalt coating. The calcium phosphate coated metal substrate of the invention, particularly the codeposited "hydroxylapatite"-cobalt coating, on a titanium or cobalt-chromium substrate, has particular value for application as medical implants, e.g.
    Type: Grant
    Filed: August 13, 1990
    Date of Patent: July 19, 1994
    Assignee: McDonnell Douglas Corporation
    Inventors: Timothy E. Taylor, Clyde Riley, William R. Lacefield, Jr., Harold D. Coble, George W. Maybee
  • Patent number: 5320909
    Abstract: A thermal barrier coating for metal articles subjected to rapid thermal cycling includes a metallic bond coat deposited on the metal article, at least one MCrAlY/ceramic layer deposited on the bond coat, and a ceramic top layer deposited on the MCrAlY/ceramic layer. The M in the MCrAlY material is Fe, Ni, Co, or a mixture of Ni and Co. The ceramic in the MCrAlY/ceramic layer is mullite or Al.sub.2 O.sub.3. The ceramic top layer includes a ceramic with a coefficient of thermal expansion less than about 5.4.times.10.sup.-6 .degree.C.sup.-1 and a thermal conductivity between about 1 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1 and about 1.7 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1.
    Type: Grant
    Filed: July 13, 1993
    Date of Patent: June 14, 1994
    Assignees: United Technologies Corporation, Cummins Engine Co.
    Inventors: Alan J. Scharman, Thomas M. Yonushonis
  • Patent number: 5316866
    Abstract: A superalloy component includes a substrate article of a superalloy, and a strengthenable, adherent coating on the substrate. The coating is preferably a nickel-base superalloy that is strengthened by the formation of gamma and gamma-prime phases. The coating is stronger than conventional MCrAlX coatings, and, therefore, more resistant to thermal fatigue. One operable coating has a composition, in weight percent, of about 7.5 percent cobalt, about 9 percent chromium, about 6 percent aluminum, about 1 percent titanium, about 1.5 percent molybdenum, about 4 percent tantalum, about 3 percent tungsten, about 3 percent rhenium, about 0.5 percent hafnium, about 0.3 percent yttrium, about 0.5 percent columbium, about 0.05 percent carbon, about 0.015 percent boron, about 0.015 percent zirconium, and balance nickel.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: May 31, 1994
    Assignee: General Electric Company
    Inventors: Edward H. Goldman, Ramgopal Darolia
  • Patent number: 5314304
    Abstract: In a gas turbine engine having a laybrinth seal between an annular rotor and stator therein, in which the stator is surmounted by a honeycomb structure and the rotor has a knife edge which is mounted to rotate in close annular proximity with said honeycomb structure, an improvement is provided wherein such labyrinth seal has a layer of abradeable coating atop the honeycomb structure for the rotor knife edge to rotate proximate thereto and to rub in, without substantially damaging the knife edge nor the honeycomb structure. In one embodiment the layer of abradeable coating is mounted on a metalic foil which is mounted in turn, atop the honeycomb structure. The abradeable coating thus provided, is more yieldable and less damaging to a rotor knife edge than is the honeycomb structure of the prior art, to better preserve rotor and stator and thus the labryrinth seal.
    Type: Grant
    Filed: August 15, 1991
    Date of Patent: May 24, 1994
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventor: David J. Wiebe
  • Patent number: 5302580
    Abstract: An oxide superconductor lamination member has a base, precious metal plates and an oxide superconductor layer. The precious metal plates and the oxide superconductor layer are successively laminated on the base, and the precious metal plates overlap each other at their ends. Another oxide superconductor lamination member has precious metal bases, and an oxide superconductor layer lamination on the precious metal bases. The precious metal bases overlap each other at their ends. End portions of the precious metal plates (bases) are connected by an adhesive so as to form a lap joint. The lap joint of the precious metal plates (bases) are covered with a precious metal foil.
    Type: Grant
    Filed: March 13, 1991
    Date of Patent: April 12, 1994
    Assignee: NGK Insulators, Ltd.
    Inventors: Hideki Shimizu, Takeyoshi Togashi, Hitoshi Higuchi, Toshio Oda, Hitoshi Yoshida
  • Patent number: 5298323
    Abstract: A long-life bearing steel and a long-life rolling bearing made of the steel are disclosed. In the steel, the number of oxide or oxide-based inclusion particles in a given unit area A of 160 mm.sup.3 with an average particle size of 3 to 30 .mu.m is 80 or less and an abundance of oxide or oxide-base inclusion particles with 10 .mu.m or more average particle size to oxide or oxide-based inclusion particles having an average particle size of 3 to 30 .mu.m is below 2%. An electron beam melting extraction evaluation method irradiating electron beam under the following condition guarantees the cleanness of the steel: 350 V+100.ltoreq.J.ltoreq.700 V+200, wherein J represents electric charge power in W provided by electron beam and V represents a sample volume in cm.sup.3.
    Type: Grant
    Filed: October 9, 1990
    Date of Patent: March 29, 1994
    Assignee: Nippon Seiko Kabushiki Kaisha
    Inventors: Hiroshi Narai, Tsutomu Abe, Shigeru Okita
  • Patent number: 5296456
    Abstract: Disclosed herein is a ceramic superconductor comprising a ceramic superconductive member, and a high-conductivity metal layer covering the ceramic superconductive member. At least one portion of the metal layer having low electrical conductivity or low thermal conductivity. Also disclosed is a method of manufacturing a ceramic superconductor, comprising the steps of filling a ceramic superconductor or a precursor thereof in a high-conductivity metal pipe, thereby forming a composite member, rolling the composite member into a ceramic superconductor element of a desired shape, which comprises a ceramic superconductive member and a high-conductivity metal layer covering the ceramic superconductive member, performing a predetermined heat treatment on the ceramic superconductor element, and alloying a predetermined portion of the high-conductivity metal layer, thereby rendering the portion less conductive either electrically or thermally.
    Type: Grant
    Filed: August 3, 1990
    Date of Patent: March 22, 1994
    Assignee: Furukawa Electric Co., Ltd.
    Inventors: Shoji Shiga, Naoki Uno, Hiroyuki Kikuchi
  • Patent number: 5294485
    Abstract: Organic composite coated steel strips having improved corrosion resistance, weldability and coating adherence are obtained when an organic composite layer is applied to a chromate layer on a zinc or zinc base alloy plated steel substrate. The chromate layer containing up to 70% of Cr.sup.6+ based on the total chromium weight is coated in a weight of 5 to 500 mg/m.sup.2 of Cr. The organic composite layer is formed to a dry weight of 0.2 to 3.0 g/m.sup.2 from a coating composition comprising (A) a silica sol having silica dispersed in an organic solvent with a water content of up to 3.0%, the silica having an organic deposit on its surface in an amount of up to 5.0% of C based on the total silica weight, the silica having an average particle size of 0.05 to 3.0 .mu.m and a specific surface area of 50 to 800 m.sup.2 /g, and (B) an organic resin binder having a number average molecular weight of at least 2,000. The coated strips are suitable for use as automobile bodies by press forming.
    Type: Grant
    Filed: October 16, 1990
    Date of Patent: March 15, 1994
    Assignee: Kawasaki Steel Corporation
    Inventors: Kenji Takao, Hideo Ohgishi, Hajime Kimura, Shuichi Sakaguchi
  • Patent number: 5292485
    Abstract: A heat-resistant metallic monolith, manufactured by forming metal powders into a honeycomb structure and by sintering the structure, has a heat-resistant metal oxide coated on the surface of the cell walls and that of the pores thereof. Such a heat-resistant metallic monolith is manufactured by mixing metal powders, an organic binder and water to prepare a mixture, by forming the mixture into a shape of a desired honeycomb configuration, by sintering the shape in a non-oxidizing atmosphere at a temperature between 1000.degree. and 1450.degree. C. and then by coating a heat-resistant metal oxide on a surface of the cell walls and that of the pores of the obtained sintered body.
    Type: Grant
    Filed: October 1, 1992
    Date of Patent: March 8, 1994
    Assignee: NGK Insulators, Ltd.
    Inventors: Takashi Harada, Hiroshige Mizuno, Fumio Abe, Tsuneaki Ohashi
  • Patent number: 5283131
    Abstract: A zinc-plated metallic material resistant to corrosion at elevated temperatures comprising a metallic material; a plating layer consisting of zinc or zinc alloy containing 70% by weight or more of zinc; and a coating layer on the plating layer comprising 10 to 5,000 mg. of magnesium oxide or hydrated magnesium oxide and 50 to 5,000 mg. of chromium oxide or hydrated chromium oxide per square meter of the coating layer.
    Type: Grant
    Filed: January 29, 1992
    Date of Patent: February 1, 1994
    Assignee: Nihon Parkerizing Co., Ltd.
    Inventors: Kazuhiko Mori, Shinji Nomura
  • Patent number: 5283104
    Abstract: Improved via-filling compositions for producing conductive vias in circuitized ceramic substrates, particularly multilayer substrates, without cracking and/or loss of hermetic sealing. The via-filling compositions comprise pastes containing a mixture of (a) ceramic and/or glass spheres of substantially- uniform diameter between about 0.5 and 6 .mu.m, (b) conductive metal particles or spheres having a maximum dimension or diameter between about 1/3 and 1/4 of the diameter of the ceramic and/or glass spheres, and (c) a binder vehicle. The formed conductive via bodies comprise a uniform conductive skeletal network of sintered metal particles densely packed within a uniform matrix of the co-sintered ceramic and/or glass spheres, which matrix is hermetically fused and integrated with ceramic layers forming the wall of the via in the ceramic circuit substrate.
    Type: Grant
    Filed: March 20, 1991
    Date of Patent: February 1, 1994
    Assignee: International Business Machines Corporation
    Inventors: Farid Y. Aoude, Emanuel I. Cooper, Peter R. Duncombe, Shaji Farooq, Edward A. Giess, Young-Ho Kim, Sarah H. Knickerbocker, Friedel Muller-Landau, Mark O. Neisser, Jae M. Park, Robert R. Shaw, Robert A. Rita, Thomas M. Shaw, Rao Vallabhaneni, Jon A. Van Hise, George F. Walker, Jungihl Kim, James M. Brownlow, deceased
  • Patent number: 5277942
    Abstract: An insulating member has an insulating layer in the form of a thin ceramic plate made of at least one of SiC, Si.sub.3 N.sub.4, AlN and Al.sub.2 O.sub.3 ad having a thickness not less than 0.1 mm and not more than 2.0 mm, and cushioning layers provided on both sides of the insulating layer through brazing alloy for relieving thermal stress. An electric part can be made of such an insulating member. The insulating member is disposed between a conductive substrate and a conductive member and brazed thereto.
    Type: Grant
    Filed: October 11, 1991
    Date of Patent: January 11, 1994
    Assignees: Sumitomo Electric Industries, Ltd., Japan Atomic Energy Research Institute
    Inventors: Akihiko Ikegaya, Naoji Fujimori, Tetsuo Yashiki, Tetsuya Abe, Yoshio Murakami
  • Patent number: 5275891
    Abstract: The R-TM-B permanent magnet member having an improved corrosion resistance comprising an R-TM-B permanent magnet body provided with a nickel plating layer and then with a chromate coating layer, which may be then subjected to an immersion treatment in an alkali solution.
    Type: Grant
    Filed: October 4, 1991
    Date of Patent: January 4, 1994
    Assignee: Hitachi Metals, Ltd.
    Inventors: Atsushi Tagaya, Motoharu Shimizu
  • Patent number: 5271977
    Abstract: A rubber hose comprising an inner tube of synthetic resin, an optional undercoat of a metal or metal compound dry plated on the inner tube, a metal thin film sputtered or ion plated on the inner tube or undercoat from zinc, copper, cobalt, titanium, or an alloy thereof, and a rubber layer on the metal thin film exhibits low gas and solvent permeability while maintaining flexibility. Also provided is a low permeable rubber hose comprising an inner tube of synthetic resin, a thin film of a metal or metal compound dry plated on the inner tube, and a rubber layer heat cured to the thin film through an adhesive.
    Type: Grant
    Filed: February 8, 1990
    Date of Patent: December 21, 1993
    Assignee: Bridgestone Corporation
    Inventors: Masato Yoshikawa, Hideyuki Niwa, Yukio Fukuura, Hideo Sugiyama, Kazuo Naito
  • Patent number: 5267605
    Abstract: The MTS radiator consists of planar arrays of micro-tube strip modules, each of which contain two or three rows of about 200 properly spaced microtubes per row. The three-dimensional tubular titanium structure with support members between microtubes maximizes stiffness and strength per mass. The working fluid--typically hydrogen at 0.1 to 1 MPa--circulates through the microtubes, and most of the radiation occurs from their walls, which are only 0.2 to 0.4 mm thick. This allows specific mass below 1 kg/m.sup.2. The operating temperature range is typically 200-650 K. The radiator's radiating surface comprises a heavily oxidized, metal alloy with a corrosion resistant, refractory alloy film deposited on it.
    Type: Grant
    Filed: September 6, 1990
    Date of Patent: December 7, 1993
    Assignee: Doty Scientific, Inc.
    Inventors: F. David Doty, Gregory S. Hosford, Jonathan B. Spitzmesser
  • Patent number: 5262247
    Abstract: A thin copper foil for a printed wiring board comprising a copper foil supporter having a surface with a roughness; a parting payer consisting of chrome compound; a thin copper foil layer formed on the parting layer which will be attached to a board as printed wiring. A copper-nickel compound metal layer is interposed between the parting layer and the thin copper foil layer, wherein said copper-nickel compound metal layer is formed to be integral with the thin copper foil layer with a peel strength therebetween such that said copper-nickel compound metal layer will be left on the thin copper layer when the parting layer with the copper foil supporter is peeled off.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: November 16, 1993
    Assignee: Fukuda Kinzoku Hakufun Kogyo Kabushiki Kaisha
    Inventors: Toshiyuki Kajiwara, Yoshinori Tanii, Kazuhiko Hashimoto
  • Patent number: 5258236
    Abstract: A method and apparatus for releasing a workpiece from a substrate including providing a substrate which is transparent to a predetermined wavelength of electromagnetic radiation; forming, on the substrate, a separation layer which degrades in response to the predetermined radiation; providing the workpiece on the separation layer; and directing the predetermined radiation at the separation layer through the transparent substrate so as to degrade the separation layer and to separate the workpiece from the substrate.
    Type: Grant
    Filed: May 3, 1991
    Date of Patent: November 2, 1993
    Assignee: IBM Corporation
    Inventors: Gnanalingam Arjavalingam, Alina Deutsch, Fuad E. Doany, Bruce K. Furman, Donald J. Hunt, Chandrasekhar Narayan, Modest M. Oprysko, Sampath Purushothaman, Vincent Ranieri, Stephen Renick, Jane M. Shaw, Janusz S. Wilczynski, David F. Witman
  • Patent number: 5254413
    Abstract: An aluminide coating is applied to a portion of the surface of an article that already has a thermal barrier coating system in place over another portion of its surface. The portion of the surface to be coated is contacted, at elevated temperature, with an aluminide coating source material that is a mixture of from about 18 to about 45 weight percent of a metallic source of aluminum and the balance ceramic particles. The metallic source of aluminum may be pure aluminum or an aluminum-containing alloy. No halide activator is present in the aluminide coating source material.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: October 19, 1993
    Assignee: General Electric Company
    Inventor: Antonio F. Maricocchi
  • Patent number: 5246786
    Abstract: A steel product (or copper-plated steel product) with heat-resistant, corrosion-resistant plating layers which are composed of a 0.2-10 .mu.m thick nickel plating layer formed on said steel product, a zinc plating layer formed on said nickel plating layer, and a chromate film formed on said zinc plating layer.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: September 21, 1993
    Assignee: Usui Kokusai Sangyo Kaisha Ltd.
    Inventor: Masayoshi Usui