Abstract: A coated electrically conductive substrate has particular utility where there are multiple closely spaced leads and tin whiskers constitute a potential short circuit. Such substrates include leadframes, terminal pins and circuit traces such as on printed circuit boards and flexible circuits. This electrically conductive substrate has a plurality of leads separated by a distance capable of bridging by a tin whisker, a silver or silver-base alloy layer coating at least one surface of at least one of the plurality of leads, and a fine grain tin or tin-base alloy layer directly coating said silver layer. An alternative coated electrically conductive substrate has particular utility where debris from fretting wear may oxidize and increase electrical resistivity, such an in a connector assembly. This electrically conductive substrate has a barrier layer deposited on the substrate that is effective to inhibit diffusion of constituents the substrate into a plurality of subsequently deposited layers.

Abstract: A coating suitable for use as a bondcoat for a thermal barrier coating system includes about 5 to about 10 weight percent of aluminum (Al), about 10 to about 18 weight percent of cobalt (Co), about 4 to about 8 weight percent of chromium (Cr), about 0 to about 1 weight percent of hafnium (Hf), about 0 to about 1 weight percent of silicon (Si), about 0 to about 1 percent of yttrium (Y), about 1.5 to about 2.5 weight percent of molybdenum (Mo), about 2 to about 4 weight percent of rhenium (Re), about 5 to about 10 weight percent of tantalum (Ta), about 5 to about 8 weight percent of tungsten (W), about 0 to about 1 weight percent of zirconium (Zr), and a remainder of nickel (Ni).

Abstract: A thermal barrier coating comprises a bond coating 12 made of high temperature corrosion resistance superior to a substrate 11 and a thermal barrier coating 13 made of ZrO2 series ceramics formed on the bond coating. The thermal barrier coating has cracks extending in the direction of the thickness of the barrier coat. Substantially all of the tips of the cracks have a distance between the tips and the boundary at the substrate side.

Abstract: A coating material for a thermal barrier coating having excellent corrosion resistance and heat resistance comprises a substrate, an undercoat made of an aluminum-containing heat-resistant alloy, Cr2O3 layer as a middle layer on the undercoat, and a top coat made of ZrO2 based ceramic on the middle coat.

Abstract: A heat-insulating layer system for a metallic structural component, especially for a structural component of a gas turbine such as an aircraft engine, includes an adhesion promoting layer (12), an inner contact layer (14), and an outer cover layer (15) , whereby the adhesion promoting layer (12). is disposed on a surface (11) of the gas turbine structural component (10). The inner contact layer (14) is formed of a zirconium oxide partially stabilized with yttrium or yttrium oxide, and the outer cover layer (15) is formed of a material that consists of at least one component with at least one phase, which stoichiometrically comprises 1 to 80 Mol-% Mx2O3, 0.5 to 80 Mol-% MyO and Al2O3 as a remainder with incidental impurities, wherein Mx is selected from the elements chromium and barium or mixtures thereof, and wherein My is selected from the alkaline earth metals, the transition metals and the rare earths or mixtures thereof.

Abstract: An article comprising a silicon-containing substrate, a silicide-containing bond coat layer overlying the substrate, and typically an environmental barrier coating overlaying the bond coat layer. An article is also provided wherein the environmental barrier coating comprises: (1) an optional inner silica scale layer overlaying the bond coat layer; (2) intermediate layer overlaying the inner silica scale layer, or the bond coat layer in the absence of the inner silica scale layer, and comprising mullite, or a combination of mullite with a barium strontium aluminosilicate, a yttrium silicate, or a calcium aluminosilicate; and (3) an outer steam-resistant barrier layer overlaying the intermediate layer and consisting essentially of an alkaline earth silicate/aluminosilicate. Processes are also provided for forming the silicide-containing bond coat layer over the substrate, followed by forming the environmental barrier coating over the bond coat layer.

Abstract: A ceramic top coat is formed over a heat resistant alloy including Ni as a main component through a bond coat which contains Ni essentially as a main component, Cr, and Al. The alloy for the bond coat can include Si in the range from 0 to 10 wt. %. As a result, in a long time operation, the spalling damage of a ceramic top coat is not easily created and the deterioration of the mechanical properties is small.

Abstract: A highly charged ion modified device is provided that includes a first metal layer or layers deposited on a substrate and an insulator layer, deposited on the first metal layer, including a plurality of holes therein produced by irradiation thereof with highly charged ions. The metal of a further metal layer, deposited on the insulator layer, fills the plurality of holes in the insulator layer.

Abstract: Getter multilayer structures are disclosed, embodiments of which include at least a layer of a non-evaporable getter alloy having a low activation temperature over a layer of a different non-evaporable getter material having high specific surface area, both preferably obtained by cathodic deposition. The multilayer NEG structures exhibit better gas sorbing characteristics and lower activation temperature lower than those of deposits made up of a single material. A process for manufacturing such structures includes depositing a first, high surface area NEG film on a support, and then depositing a thin over layer of low activation NEG film.

Abstract: A phosphate bonded ceramic is used to provide a protective coating on a rare earth-transition metal (RE-TM) alloy substrate, conferring degradation resistance to the alloy by being oxidation resistant and acting as a diffusion barrier, thereby minimising/preventing oxygen diffusion and elemental depletion. The alloy substrate may, for example, be a permanent magnetic alloy component and may be used in aerospace applications.

Abstract: A hot press-formed article having improved corrosion resistance and coating adhesion when coated is obtained by hot press forming of a zinc-based plated steel material. It has a zinc-based plating layer comprising an iron-zinc solid solution phase and atop it a zinc oxide layer. The average thickness of the zinc oxide layer which is the outermost layer is at most 2 ?m. A hot press-formed article having a good appearance and excellent corrosion resistance, coating adhesion, post-coating corrosion resistance, and weldability has a layer (2) consisting essentially of an iron-zinc solid solution phase atop a base material steel sheet (1). It also has a zinc oxide layer (3) with an average thickness of at most 5 ?m as an uppermost layer, but it does not have a substantial amount of an iron-zinc intermetallic compound phase. The total amount of Al contained in the iron-zinc solid solution layer (2) and the zinc oxide layer (3) is at most 0.

Abstract: The invention relates to a component having a coating system, which comprises at least one bonding coat applied directly onto the component and at least one thermal barrier coat formed on the bonding coat, the bonding coat comprising from 22 to 36 wt. % Cr, from 15 to 30 wt. % Ni, at most 55 ppm Al, and Fe as a basis.

Abstract: The present invention provides a process for providing on the surface of a substrate an adherent phorphorous acid-based coating layer, the method comprising contacting said surface with a carrier conveying a coating composition comprising an acid selected from the group consisting of phosphoroic acids, organo-phosphoric acids, phosphonic acids, and mixtures thereof, at a sufficient temperature and for a sufficient time to bond at least a portion of the acid in the compositon to the oxide surface.

Abstract: One embodiment includes: a copper substrate; a catalyst on top of a single surface of the copper substrate; and a thermal interface material on top of the single surface of the copper substrate. The thermal interface material comprises: a layer of carbon nanotubes that contacts the catalyst, and a filler material located between the carbon nanotubes. The carbon nanotubes are oriented substantially perpendicular to the single surface of the copper substrate. The thermal interface material has: a bulk thermal resistance, a contact resistance between the thermal interface material and the copper substrate, and a contact resistance between the thermal interface material and a solid-state device. The summation of the bulk thermal resistance, the contact resistance between the thermal interface material and the copper substrate, and the contact resistance between the thermal interface material and the solid-state device has a value of 0.06 cm2K/W or less.

Abstract: A protected article has a substrate and a protective structure overlying a surface of the substrate. The protective structure includes a protective layer overlying the surface of the substrate and having an aluminum content greater than that of the substrate, and a bond-coat layer of a bond-coat-layer metal. The bond-coat-layer metal has a bond-coat initial composition having at least about 60 percent by weight platinum, rhodium, palladium, or combinations thereof. There may be a diffusion-barrier layer between the surface of the substrate and the protective layer, and there may be a ceramic thermal barrier coating overlying the bond-coat layer.

Abstract: According to an embodiment of the invention, disclosed is a composite comprising a porous thermal barrier coating on a metallic part and an impermeable barrier coating adjacent to the outer surface of the thermal barrier coating. The impermeable barrier coating is dense and non-porous and comprises a rare earth silicate, the impermeable barrier coating thereby preventing infiltration of the contaminant composition into the thermal barrier coating.

Abstract: A skin is coated on a shell of a parallel device. With the skin, the parallel device becomes more beautiful. The skin is made of enamel. Hence, the shell is kept from scrape and corrosion. At the same time, the shell is more easily cleaned.

Abstract: A ceramic material suitable for use as a coating, such as a porous thermal barrier coating (TBC) on a component intended for use in a hostile thermal environments. The coating material consists essentially of zirconia stabilized by at least one rare-earth metal oxide and further alloyed to contain a limited amount of titania. Rare-earth metal oxides of particular interest are lanthana, ceria, neodymia, europia, gadolinia, erbia, dysprosia, and ytterbia, individually or in combination. Zirconia, the rare-earth metal oxide, and titania are present in the coating material in amounts to yield a predominantly tetragonal phase crystal structure. The amount of titania in the coating is tailored to allow higher levels of stabilizer while maintaining the tetragonal phase, i.e., avoiding the cubic (fluorite) phase.

Abstract: Interconnect structures possessing an organosilicate glass based material for 90 nm and beyond BEOL technologies in which a multilayer hardmask using a line-first approach are described. The interconnect structure of the invention achieves respective improved device/interconnect performance and affords a substantial dual damascene process window owing to the non-exposure of the OSG material to resist removal plasmas and because of the alternating inorganic/organic multilayer hardmask stack. The latter feature implies that for every inorganic layer that is being etched during a specific etch step, the corresponding pattern transfer layer in the field is organic and vice-versa.

Abstract: A component capable of being exposed to a plasma in a process chamber has a structure having an electroplated coating comprising yttrium-containing species. The electroplated coating is resistant to corrosion in the plasma, and can have a compositional gradient of yttrium-containing species through a thickness of the coating. In one embodiment, the coating is formed by electroplating a layer comprising yttrium onto the surface, and then electroplating a second layer onto the first layer, and annealing the first and second layers. The second layer can comprise aluminum or zirconium. In another embodiment, the coating is formed by electroplating a layer comprising a mixture of aluminum and yttrium onto the surface and annealing the layer.

Abstract: A coated article comprises a substrate; and a multilayer thermal barrier coating disposed on the substrate, the multilayer thermal barrier coating comprising at least a first layer comprising a first ceramic composition having a thermal conductivity less than 1 W/m° K; a second layer having an erosion resistance greater than or equal to dense vertically cracked 8% yttrium stabilized zirconia, wherein percent is based on a total weight of yttrium and zirconia, and a third layer comprising the first ceramic composition or the second composition, wherein the first, second, and third layers are arranged such that the first ceramic composition and the second composition are in alternating layers.

Abstract: An oxidation resistant component is disclosed comprising a substrate and a protective layer.

Abstract: A modified platinum group metal coating composition comprising a phase having a solid solution face-centered cubic (fcc) crystal structure, rich in platinum group materials. In order to be effective, the platinum group metal coating material was modified based on the chemical composition and chemical activity of the substrate material. The platinum group metal coating material was modified to include, in solid solution, elements of the superalloy substrate, specifically nickel (Ni) and cobalt (Co). Depending on the substrate material, the modified platinum group metal coating material may not even include Ni or Co, but may be modified to include amounts of different elements that are consistent with the chemical composition of the substrate. The modified platinum metal coating material also includes aluminum (Al). The composition may include small amounts of a second phase isolated within the fcc phase matrix.

Abstract: An environmental coating suitable for use on turbine components, such as turbine disks and turbine seal elements, formed of alloys susceptible to oxidation and hot corrosion. The environmental coating is predominantly a solid solution phase of nickel, iron, and/or cobalt. The coating contains about 18 weight percent to about 60 weight percent chromium, which ensures the formation of a protective chromia (Cr2O3) scale while also exhibiting high ductility. The coating may further contain up to about 8 weight percent aluminum, as well as other optional additives. The environmental coating is preferably sufficiently thin and ductile to enable compressive stresses to be induced in the underlying substrate through shot peening without cracking the coating.

Abstract: The oxidation behavior of the bond coat is improved using a HVOF nanostructured NiCrAlY coating. NiCrAlY powder is mechanically cryomilled and HVOF sprayed onto Ni-based alloy to form a nanocrystalline bond coat. Oxidation is performed on the coating to form the thermally grown oxide layer (thermally grown oxide). After heat treatment at 1000° C. for 24 and 95 hour, a homogeneous ?-Al2O3 layer is formed on top of the bond coat. The nanostructured characteristic of the coating and the presence of Al2O3 within the cryomilled powders (oxidation occurred during cryomilling process) affects the nucleation of the alumina layer on the top of the coating. The formation of a continuous thermally grown oxide layer protects the coating from further oxidation and avoids the formation of mixed oxide protrusions, such as those presented in the coating sprayed using the as-received powder.

Abstract: An article comprising a silicon-containing substrate, a silicide-containing bond coat layer overlying the substrate, and an environmental barrier coating (EBC) overlying the bond coat layer, wherein the EBC comprises a corrosion resistant outer layer comprising a corrosion resistant metal silicate. A process is also provided for forming the corrosion resistant outer layer over the silicide-containing bond coat layer.

Abstract: A hot-dip galvanized steel sheet includes a plating layer substantially composed of the ? phase and an oxide layer disposed on a surface of the plating layer. The oxide layer has an average thickness of 10 nm or more and includes a Zn-based oxide layer and an Al-based oxide layer. A method for producing the hot-dip galvanized steel sheet includes a hot-dip galvanization step, a temper rolling step, and an oxidation step.

Abstract: A coating system for reducing the tendency for hydrocarbon fluids, such as fuels and oils, to form carbonaceous deposits that adhere to fluid containment surfaces. The coating system combines an outermost layer of platinum with an inner ceramic barrier layer of silica and/or tantala. The platinum layer catalyzes the hydrocarbon fluid to form particles of carbonaceous gum substances, and the ceramic barrier layer seals the containment surface from the hydrocarbon fluid to eliminate attachments points for deposits and inhibit interdiffusion between the platinum layer and the containment surface. The invention also encompasses a coating apparatus and process for depositing the coating system.

Abstract: A composition comprising a particulate corrosion resistant component, and a glass-forming binder component. The particulate corrosion resistant component comprises from 0 to about 95% alumina particulates, and from about 5 to 100% corrosion resistant non-alumina particulates having a CTE greater than that of the alumina particulates. Also disclosed is an article comprising a turbine component comprising a metal substrate and a corrosion resistant coating having thickness up to about 10 mils (254 microns) overlaying the metal substrate. At least the layer of this coating adjacent to the metal substrate comprises a glass-forming binder component and the particulate corrosion resistant component adhered to the glass-forming binder component.

Abstract: A high pressure turbine component for use in a gas turbine engine and a method for coating a high pressure turbine component. The gas turbine engine turbine component is coated with an amorphous phosphate-containing coating disposed on a surface of the component. The coating has a thickness of from about 0.10 microns to about 10 microns and provides resistance to oxidation and hot corrosion at temperature greater than about 1000° F.

Abstract: A coating system and method for reducing the tendency for hydrocarbon fluids, such as fuels and oils, to form carbonaceous deposits that adhere to a wall of a containment article. Of particular concern are carbonaceous deposits that form at temperatures below about 650° F. (about 345° C.). The coating system combines an outermost layer of platinum with a ceramic barrier layer. The coating system significantly reduces the formation of carbonaceous deposits and the adhesion of such deposits. To further reduce wall and hydrocarbon fluid temperatures and formation of carbonaceous deposits, the coating system is preferably applied to the surface of the wall wetted by the fluid, as well as the opposite surface of the wall exposed to a surrounding environment. The outermost layers serve as radiation shields to reduce heat transfer from the surrounding environment to the wall, and from the wall to the hydrocarbon fluid.

Abstract: A gas turbine part comprises a superalloy metal substrate, a bonding underlayer formed on the substrate and comprising an intermetallic compound of aluminum, nickel, and platinum, and a ceramic outer layer anchored on the alumina film formed on the bonding underlayer. The bonding underlayer essentially comprises an Ni—Pt—Al ternary system constituted by an aluminum-enriched ?-NiPt type structure, in particular an Ni—Pt—Al ternary system having a composition NizPtyAlx in which z, y, and x are such that 0.05?z?0.40, 0.30?y?0.60, and 0.15?x?0.40.

Abstract: A composition is disclosed that includes an at least partially stabilized zirconia matrix with a pentavalent oxide first dopant and an oxide second dopant. A coated article is disclosed for use in a high temperature a gas turbine. The coated article can include an yttria-stabilized zirconia, a pentavalent oxide first dopant, and an oxide second dopant. The ratio of the pentavalent oxide second dopant to the oxide third dopant can be less than or equal to about 1. The composition can reduce sintering of the thermal barrier coating.

Abstract: A layered structure includes a substrate comprising a layer of an oxide/oxide ceramic based composite material, a first oxide layer disposed directly on the substrate and formed from a material that has no greater than about 10% porosity and is substantially impermeable by water vapor, and a second oxide layer disposed directly on the first oxide layer and having a greater porosity than the first oxide layer. Either or both the first and second oxide layers of the coating system may be deposited using a plasma spraying process, a slurry deposition process which is followed by a sintering step, or an EB-PVD process.

Abstract: The present invention relates to the use for coating three-dimensionally structured surfaces and/or moldings of melamine resin sheets and/or films produced from cellulosic fiber materials post- or pre- and post-impregnated with an aqueous solution comprising (i) a melamine-formaldehyde condensate, (ii) an etherified melamine-formaldehyde condensate, and (iii) a polymer dispersion.

Abstract: A wire for external exposure, i.e. without chemical binding with a polymer or rubber matrix. The wire has a steel core, a nickel sub-coating and a zinc or zinc alloy top coating above the nickel sub-coating. The steel core has a carbon content exceeding 0.20%. The wire is in a work-hardened state by drawing or rolling. The wire has an excellent corrosion resistance and provides an excellent barrier against hydrogen. Preferable uses are wires in off-shore applications.

Abstract: An erosion resistant protective structure for a turbine engine component comprises a shape memory alloy. The shape memory alloy includes nickel-titanium based alloys, indium-titanium based alloys, nickel-aluminum based alloys, nickel-gallium based alloys, copper based alloys, gold-cadmium based alloys, iron-platinum based alloys, iron-palladium based alloys, silver-cadmium based alloys, indium-cadmium based alloys, manganese-copper based alloys, ruthenium-niobium based alloys, ruthenium-tantalum based alloys, titanium based alloys, iron-based alloys, or combinations comprising at least one of the foregoing alloys. Also, disclosed herein are methods for forming the shape memory alloy onto turbine component.

Abstract: An electroless copper plating method is provided having a first catalyst step of forming a first catalyst layer on a ceramic base material containing a glass component using a tin chloride solution and a palladium chloride solution; a pre-copper-plating heat treatment step of heating the ceramic base material in an atmosphere containing oxygen; a laminate catalyst treatment step of forming a laminate catalyst layer on the ceramic base material using a tin chloride solution and a palladium chloride solution; a plating treatment step of forming a copper plating film on the ceramic base material using a copper plating solution containing a small amount of nickel ions; and a post-copper-plating heat treatment step of heating the ceramic base material at a heat treatment temperature not more than the glass transition temperature thereof.

Abstract: The present invention relates to a cationic electrodeposition coating composition substantially free of lead compounds, and more specifically to a method of coating an alloyed hot-dip galvanized steel plate with the composition and a coated article obtained by the method having edge portions and general surfaces excellent in corrosion resistance. The invention provides a method of coating an alloyed hotdip galvanized steel plate with a lead-free cationic electrodeposition coating composition containing a rust preventive pigment to form an electrodeposition coating film excellent in corrosion resistance, and a coated article obtained by the electrodeposition.

Abstract: A ceramic material having particular utility as a thermal insulating or thermal barrier coating on metallic substrates is provided. The ceramic material broadly comprises at least one oxide and the balance comprising a first oxide selected from the group consisting of zirconia, ceria, and hafnia. The at least one oxide has a formula A2O3 where A is selected from the group consisting of La, Pr, Nd, Sm, Eu, Tb, In, Sc, Y, Dy, Ho, Er, Tm, Yb, Lu, and mixtures thereof. The present invention also broadly relates to an article having a metal substrate and a thermal barrier coating as discussed above.

Abstract: The invention is to provide a surface-treated steel sheet of good white rust resistance with no chromium in its surface treatment film, and it has realized a surface-treated steel sheet of higher-level corrosion resistance by forming a reaction layer of plating metal with a barrier layer effective for anticorrosion not in a two-layered film but in a single-layered film.

Abstract: A method for making a transparent electrothermal body includes: a) plating ITO (indium tin oxide) onto a surface of a transparent substrate to form an ITO film, and b) printing a conducting material onto a surface of the ITO film to form two connecting portions each electrically connected to the ITO film, thereby forming a transparent electrothermal body. Thus, the transparent electrothermal body includes a circuit made of ITO material having greater transparency to form a conducting film that allows passage of the electric current, thereby enhancing the transparency of the electrothermal body, and thereby increasing the versatility of the electrothermal body.

Abstract: A TBC system suitable for protecting the surface of a substrate subjected to a hostile thermal environment. The TBC system comprises a bond coat on the substrate surface, an alumina scale on the bond coat, and a multilayer TBC comprising a thermal-sprayed first ceramic layer on the alumina scale and a thermal-sprayed second ceramic layer overlying the first ceramic layer. The first ceramic layer consists essentially of partially stabilized zirconia so as to comprise the tetragonal and cubic phases of zirconia. The second ceramic layer consists essentially of fully stabilized zirconia so as to consist essentially of the cubic phase of zirconia. The second ceramic layer is also characterized by having vertical microcracks that extend through the thickness thereof. The second ceramic layer is thicker and more erosion resistant than the first ceramic layer.

Abstract: An article for use in hostile thermal environments, such as a component of a gas turbine engine. The article includes a nickel-base superalloy substrate that is prone to formation of a deleterious secondary reaction zone (SRZ), and an overlay coating having a predominantly gamma prime-phase nickel aluminide (Ni3Al) composition suitable for use as an environmental coating, including a bond coat for a thermal barrier coating. The coating comprises a chromium-containing nickel aluminide intermetallic overlay coating of predominantly the gamma prime phase, in which aluminum is present in the coating in an amount approximately equal to the aluminum content of the superalloy substrate so as to inhibit diffusion of aluminum from the overlay coating into the superalloy substrate.

Abstract: Aspects of the invention relate to a system for monitoring the wear of a component. A conductor can be embedded in the component at a depth from a surface of the component. In one embodiment, the conductor can be operatively connected to a power source to form an electrical circuit. The resistance across the conductor can be measured. As the component contacts a second component, the component can begin to wear. Once the wear progresses to the conductor, changes in the measured resistance can result. Thus, an operator can be alerted that the component has worn to a certain point and that service may be needed. Alternatively, impedance can be measured across the conductor. Because the dielectric permeability of the material surrounding the conductor can affect impedance, changes in impedance can occur as the surface material of the component is worn away.

Abstract: An overlay coating for articles used in hostile thermal environments. The coating has a predominantly gamma prime-phase nickel aluminide (Ni3Al) composition suitable for use as an environmental coating and as a bond coat for a thermal barrier coating. The coating has a composition of, by weight, at least 6% to about 15% aluminum, about 2% to about 5% chromium, optionally one or more reactive elements in individual or combined amounts of up to 4%, optionally up to 2% silicon, optionally up to 60% of at least one platinum group metal, and the balance essentially nickel. A thermal-insulating ceramic layer may be deposited on the coating.

Abstract: A method of depositing a bond coating to a surface of an article includes the steps of depositing an inner layer of the bond coating consisting of ?-NiAl comprising Fe, Ga, Mo, B, Hf or Zr or ?/?-MCrAlY comprising Fe, Ga, Mo, B, Hf or Zr or ?/??- or ?-MCrAlY, and depositing an outer layer of the bond coating, which is more coarse the in the inner layer, consisting of ?-NiAl comprising Fe, Ga, Mo, B, Hf or Zr or ?/?-MCrAlY comprising Fe, Ga, Mo, B, Hf or Zr or ?/??- or ?-MCrAlY, wherein said elements Fe, Ga, Mo, B, Hf or Zr above mentioned are present individually or in combination. The coating also includes a noble metal selected from the group consisting of platinum, palladium and rhodium in the inner and outer layer or as a separate layer.

Abstract: Method for producing novel photochemically-active metal oxide-containing aqueous compositions such as TiO2 compositions coated or sprayed and dried under ambient conditions to form novel photochemically-active, colorless coatings having strong wetability and adhesion to clear substrates such as window glass. Preferably the present compositions include a suitable wetting agent or combination of agents to improve the wetability of the Titanium peroxide-containing amorphous film, allowing thinner films to be readily applied. Also the inclusion of an acrylic aliphatic urethane polymer can replace wholly or partially the titanium peroxide sol and provide additional film forming and wetability properties. The acrylic urethane polymer reduces or eliminates the amount of titanyl peroxide that is required and thereby reduces or eliminates the yellow color.

Abstract: With the objectives of alleviating the property of attacking on the mating member by scratching-off of local agglutinates on the sliding contact surface, achieving improved wear resistance, and achieving improved seizure resistance through restraint of frictional heat generation by a hard phase, a copper based sintered contact material contains shock-resistant ceramics in an amount of 0.05 to less than 0.5 wt % as non-metallic particles composed of one or more substances selected from pulverized oxides, carbides and nitrides. The shock-resistant ceramics are comprised of SiO2 and/or two or more substances selected from SiO2, Al2O3, LiO2, TiO2 and MgO.

Abstract: A reduced thermal conductivity thermal barrier coating having improved impact resistance for an underlying substrate of articles that operate at, or are exposed to, high temperatures. This coating comprises an inner high fracture toughness layer nearest to the underlying substrate and having a thickness up to about 5 mils (127 microns) sufficient to impart impact resistance to the thermal barrier coating, and comprises a zirconia-containing ceramic composition having a c/a ratio of the zirconia lattice in the range of from about 1.011 to about 1.016 and stabilized in the tetragonal phase by a stabilizing amount of a stabilizing metal oxide selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india, lanthana, gadolinia, neodymia, samaria, dysprosia, erbia, ytterbia, europia, praseodymia, and mixtures thereof.