Oxide-containing Component Patents (Class 428/632)
  • Publication number: 20040247926
    Abstract: Oxidation resistant sealant system comprising a honeycomb component coated with an aluminum oxide layer.
    Type: Application
    Filed: June 3, 2003
    Publication date: December 9, 2004
    Inventors: Dalero W. Berkeley, Chek Beng Ng, Raymond Edward Chupp, Jeffrey R. Thyssen, Don Mark Lipkin, Farshad Ghasripoor
  • Publication number: 20040247929
    Abstract: A coating composition that contains at least one degradable coating layer and at least one layer of barrier coating is disclosed. The coating composition can be used to make a coated substrate having improved performance over conventional coated substrates after exposure to heat and certain chemicals like halides such as chlorides, sulfur, salt, chlorine, alkali, and enamels.
    Type: Application
    Filed: April 1, 2004
    Publication date: December 9, 2004
    Inventors: Harry Buhay, James J. Finley, James P. Thiel
  • Patent number: 6828041
    Abstract: The bearing rings 1 and 2 of a rolling bearing is formed of one kind of titanium alloys of &bgr; type titanium alloys, near &bgr; type titanium alloys and &agr;+&bgr; type titanium alloys. The titanium alloy has a surface hardness of Hv 400 or more and less than Hv 600 for increasing the corrosion resistance and wear resistance of the bearing ring. Spherical rolling elements 3 rolling on the raceway surfaces 1a and 2a of the bearing rings 1 and 2 are formed of ceramics such as silicon nitride. When &bgr; type titanium alloys or &agr;+&bgr; type titanium alloys after a solution treatment and applied with an oxidation treatment at a low temperature of 400 to 600° C. are used as the material for the bearing ring, a bearing ring made of titanium alloy suitable to use under a circumstance requiring corrosion resistance is obtained.
    Type: Grant
    Filed: February 21, 2002
    Date of Patent: December 7, 2004
    Assignee: NSK Ltd.
    Inventors: Koji Ueda, Hideyuki Uyama, Tsuyoshi Saito
  • Patent number: 6828039
    Abstract: A magnetoresistive sensor including a lower electrode layer, a nanotube structure film composed of an insulator matrix and a plurality of nanotubes dispersively arranged in the insulator matrix, a magnetoresistive film provided on the nanotube structure film, and an upper electrode layer provided on the magnetoresistive film. Each nanotube is composed of a circular tubular nonmetal and a circular cylindrical metal surrounded by the circular tubular nonmetal. The nanotube structure film is partially etched at its central region to make conduction of the upper electrode layer and the lower electrode layer through the magnetoresistive film and the circular cylindrical metal of each nanotube present at the central region.
    Type: Grant
    Filed: March 13, 2002
    Date of Patent: December 7, 2004
    Assignee: Fujitsu Limited
    Inventor: Takahiko Sugawara
  • Publication number: 20040241488
    Abstract: The present invention provides for a zinc-based coated steel sheet having a zinc-based coating layer and a lubricant film, which is formed on the zinc-based coating layer, containing zinc phosphate particles in an amount of 50 wt. % or more, and having substantially no reaction layer formed by reaction between the zinc-based coating and the zinc phosphate particles, and a method for the manufacture thereof. The zinc-based coated steel sheet according to the present invention has an excellent anti-peeling property, excellent frictional property, even in the non-lubricated condition which occurs at areas where the press oil film is broken, and excellent anti-galling property.
    Type: Application
    Filed: April 12, 2004
    Publication date: December 2, 2004
    Inventors: Seiji Nakajima, Tomokatsu Katagiri, Yoichi Tobiyama, Chiaki Kato
  • Patent number: 6821656
    Abstract: The invention relates to a material, in particular for a thermal insulation layer, with increased thermal stability, a low heat conductivity and a large thermal coefficient of expansion. According to the invention, said material comprises lanthanides, in particular the elements La, Ce, Nd, Yb, Lu, Er or Tm, which preferably occur as a mixture in a Perovskite structure. Said thermal insulation layer is particularly suitable for replacing thermal insulation layers comprising yttrium stabilized zirconium oxides (YSZ) as the thermal stability thereof is given as well over 1200° C.
    Type: Grant
    Filed: May 6, 2003
    Date of Patent: November 23, 2004
    Assignee: Forschungszentrum Julich GmbH
    Inventors: Markus Dietrich, Robert Vassen, Detlev Stöver
  • Publication number: 20040229074
    Abstract: A coated article is provided that may be heat treated in certain example embodiments. A coating of the coated article includes zinc oxide inclusive layer(s) located under infrared (IR) reflecting layer(s) of a material such as silver. In certain example embodiments, coated articles are designed so as to realize higher visible transmission and/or lower sheet resistance values.
    Type: Application
    Filed: March 15, 2004
    Publication date: November 18, 2004
    Inventors: Philip J. Lingle, Anton Dietrich, Jens-Peter Muller
  • Publication number: 20040229073
    Abstract: A coated article is provided that may be heat treated in certain example embodiments. A coating of the coated article includes a zinc oxide inclusive layer located over and contacting a contact layer that is in contact with an infrared (IR) reflecting layer of a material such as silver. It has been found that the use of such a zinc oxide inclusive layer results in improved thermal stability upon heat treatment, increased visible transmission, and/or lower sheet resistance (Rs).
    Type: Application
    Filed: March 11, 2004
    Publication date: November 18, 2004
    Applicants: Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.), Guardian Industries Corp
    Inventors: Anton Dietrich, Philip J. Lingle, Jens-Peter Muller, Jean-Marc Lemmer
  • Publication number: 20040229075
    Abstract: An alloy including a Pt-group metal, Ni and Al in relative concentration to provide a &ggr;-Ni+&ggr;′-Ni3Al phase constitution, and a coating including the alloy.
    Type: Application
    Filed: May 16, 2003
    Publication date: November 18, 2004
    Inventors: Brian Gleeson, Daniel Sordelet, Wen Wang
  • Patent number: 6818321
    Abstract: A high-temperature strength member comprises a substrate of Ni-based single crystal alloy or a Ni-based unidirectional solidified alloy and a coating of a B-containing alloy having a specified B content formed on the surface thereof by a spraying process or a vapor deposition process.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: November 16, 2004
    Assignee: Tocalo Co., Ltd.
    Inventors: Masakazu Okazaki, Yoshio Harada, Tatsuo Suidzu
  • Patent number: 6811875
    Abstract: The prevent invention provides a partial discharge-resistant wire enamel composition wherein at least one fine particle sol selected from the group of metal oxide fine particle sol and silicon oxide fine particle sol is dispersed, and 3 to 100 parts by weight of at least one fine particle selected from the group of a metal oxide fine particle and a silicon oxide fine particle is contained per 100 parts by weight of wire enamel resin. Accordingly, the partial discharge-resistant wire enamel composition having excellent dispersibility of inorganic fine particle can be obtained.
    Type: Grant
    Filed: February 16, 2001
    Date of Patent: November 2, 2004
    Assignee: Hitachi Cable, Ltd.
    Inventors: Hideyuki Kikuchi, Yoshiyuki Tetsu
  • Patent number: 6811894
    Abstract: A nickel base single crystal compliant layer on a ceramic blade has the capability to sustain high stresses and high operating temperature. Layers of nickel and platinum bonded on a single crystal superalloy over a sputtered gold-chromium layer support the high stress levels at elevated temperature without extrusion of the soft platinum or nickel layer and without destruction of an NiO compliant surface. The compliant layers have survived stress and temperature conditions without failure to the ceramic blade and the system can be stressed/heated and unloaded/cooled repeatedly without damage to the ceramic blades. A single crystal nickel base superalloy (i.e., SC180) has high strength properties at elevated temperature. Thin layers of chromium followed by gold are e-beam evaporated on one side of a polished surface of the alloy. Pure nickel is electroplated over this e-beam gold-chromium layer. Platinum is either electroplated or plated electrolessly over the nickel layer.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: November 2, 2004
    Assignee: Honeywell International, Inc.
    Inventors: Dave Narasimhan, Alexander S. Kozlov, Margaret Eagan, Milton Ortiz
  • Publication number: 20040209109
    Abstract: The present invention provides a surface treated copper foil with improved adhesion to the insulating resin of a copper-clad laminate for higher frequency applications.
    Type: Application
    Filed: February 5, 2004
    Publication date: October 21, 2004
    Inventors: Katsuyuki Tsuchida, Masashi Kumagai, Fumiaki Akase
  • Publication number: 20040209110
    Abstract: A beta-phase NiAl overlay coating containing a dispersion of ceramic particles and a process for depositing the overlay coating. If the coating is used to adhere a thermal barrier coating (TBC), the TBC exhibits improved spallation resistance as a result of the dispersion of ceramic particles having a dispersion-strengthening effect on the overlay coating. The overlay coating contains at least one reactive element and is deposited so that the some of the reactive element deposits as the ceramic particles dispersed in the overlay coating.
    Type: Application
    Filed: April 18, 2003
    Publication date: October 21, 2004
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Jeffrey Allan Pfaendtner, Ramgopal Darolia, William Scott Walston, Brett Allen Rohrer Boutwell, Irene Spitsberg, James Anthony Ruud, Joseph David Rigney
  • Publication number: 20040209111
    Abstract: There are provided a magnetic thin film utilizing a granular film and having excellent high frequency characteristics and a method of manufacturing the same, and a multilayered magnetic film and magnetic components and electronic equipment utilizing the same.
    Type: Application
    Filed: May 11, 2004
    Publication date: October 21, 2004
    Applicant: TAIYO YUDEN CO., LED.
    Inventors: Kazuyoshi Kobayashi, Kenji Ikeda, Masayuki Fujimoto
  • Patent number: 6805975
    Abstract: Steel sheet for porcelain enameling capable of realizing excellent enamel adhesion with the steel sheet by direct-on enameling once is provided by using a Ti-added steel sheet; there are also a method for producing the same, as well as a porcelain enamel product and the method for producing the same. A steel sheet for porcelain enameling is produced by providing a Ni—Mo alloy plating film on a Ti-added steel sheet containing 0.01% by weight (wherein, % represents “% by weight” hereinafter) or less of C, 0.5% or less of Mn, 0.04% or less of P, 0.04% or less of S, 0.01 to 0.50% of Ti, and balance Fe accompanied by unavoidable impurities, and by then performing heat treatment thereto to control the content of Ni, Mo, and Fe present in the surface of the steel sheet in a predetermined range, porcelain enamel is applied once and fired.
    Type: Grant
    Filed: January 16, 2003
    Date of Patent: October 19, 2004
    Assignees: Ferro Enamels (Japan) Limited, Toyo Kohan Co., Ltd.
    Inventors: Fumiaki Sato, Toshihira Hamada, Shuzo Oda, Yoshihiro Jono, Takahiro Hayashida, Junichi Fujimoto, Masao Komai
  • Publication number: 20040202886
    Abstract: A method (50) of instrumenting a component (10) having a barrier coating (14). A sensor (76) is embedded within or below the coating. Material forming the sensor is deposited within a trench (80) formed into the barrier coating. The trench is then backfilled with material (70) to protect the sensor from the environment within which the component is operating. In this manner, the sensor may be embedded at any desired location and any desired depth within a barrier coating on a previously fabricated component. An array of sensors (98, 100, 102) may be embedded across the depth of the coating to provide signals indicative of operating conditions across the coating. The signals may be, conducted to a connection location (24) by conductors (62, 64) that are deposited within the trench. The trench may be formed with a laser engraving process (54) and the material for the sensor and conductors may be deposited with a selective laser melting process (58).
    Type: Application
    Filed: September 23, 2002
    Publication date: October 14, 2004
    Applicant: Siemens Westinghouse Power Corporation
    Inventor: Ramesh Subramanian
  • Patent number: 6803135
    Abstract: This invention provides a thermal barrier ceramic coating for application to a metallic article, with the ceramic coating having a formula of RexZr1−xOy wherein Re is a rare earth element selected from the group consisting of Ce, Pr, Nd, Pm, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb and Lu where O<X<0.5 and 1.75<Y<2. A preferred embodiment is wherein Re is Nd.
    Type: Grant
    Filed: February 24, 2003
    Date of Patent: October 12, 2004
    Assignee: Chromalloy Gas Turbine Corporation
    Inventors: Yourong Liu, Paul Lawton
  • Publication number: 20040197594
    Abstract: A steel material that has on its surface a non-hexavalent-chromium type corrosion-resistant coating film formed by a composite of a metal layer and a resin layer. The steel material having or not having a copper layer is formed with 1) a Zn and/or Zn-based alloy layer, 2) a Zn/Ni alloy layer which is on this Zn and/or Zn-based alloy layer, 3) a de-Zn layer which is on the Zn/Ni alloy layer and is obtained by chemically treating the surface of the Zn/Ni alloy layer, and 4) at least one resin covering layer which is on this de-Zn layer, which are successively formed to make a corrosion-resistant coating film, the corrosion-resistant coating film, which is superior in adhesion between the metal layer and resin layer, being obtained by way of taking into account the use of a trivalent chromium type chromate layer instead of a hexavalent chromium type chromate layer (which is a substance that places a burden on the environment).
    Type: Application
    Filed: February 11, 2004
    Publication date: October 7, 2004
    Inventors: Kazuo Suzuki, Iyoshi Watanabe
  • Patent number: 6800376
    Abstract: A method is provided for refurbishing a service operated metallic coating on a substrate alloy, the coating including at least within a coating outer surface at least one oxide chemically grown from at least one coating element, for example Al, and chemically bonded with the coating outer surface as a result of thermal exposure during service operation. Growth of the oxide has depleted at least a portion of the coating element from the coating. The method comprises removing the oxide from the coating outer surface while substantially retaining the metallic coating, thereby exposing in the coating outer surface at least one surface void that had been occupied by the oxide. The retained metallic coating is mechanically worked, substantially without removal of the retained coating, to close the void, providing a treated metallic coating surface over which a refurbishing coating is applied.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: October 5, 2004
    Assignee: General Electric Company
    Inventors: Bhupendra Kumar Gupta, Nripendra Nath Das, Lyle Timothy Rasch, Jeffrey Allen Conner, Michael James Weimer
  • Patent number: 6797408
    Abstract: A coated article is prepared by furnishing an nickel-base article substrate having a free sulfur content of more than 0 but less than about 1 part per million by weight. A protective layer is formed at a surface of the article substrate. The protective layer includes a platinum aluminide diffusion coating. The protective layer may be substantially yttrium-free, or have a controlled amount of yttrium. A ceramic layer may overlie the protective layer.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: September 28, 2004
    Assignee: General Electric Company
    Inventors: William S. Walston, Jon C. Schaeffer, Wendy H. Murphy
  • Patent number: 6797411
    Abstract: The method for manufacturing galvanized steel sheet has a step of adjusting the surface texture thereof by blasting solid particles against the surface thereof. The surface texture is defined by at least one parameter selected from the group of parameters consisting of mean roughness Ra on the surface of steel sheet, peak count PPI on the surface of steel sheet, and filtered centerline waviness Wca on the surface of steel sheet. The galvanized steel sheet has a surface in dimple-pattern texture.
    Type: Grant
    Filed: June 18, 2003
    Date of Patent: September 28, 2004
    Assignee: NKK Corporation
    Inventors: Yasuhiro Sodani, Yukio Kimura, Masayasu Ueno, Shogo Tomita, Hisato Noro, Kaoru Sato, Yoshiharu Sugimoto, Satoru Ando, Masaki Tada, Junichi Inagaki, Masaaki Yamashita, Yuji Yamasaki
  • Patent number: 6794059
    Abstract: The present invention relates to a thin impermeable top coat on a thermal barrier coating for a metal part, such as a turbine blade, wherein the composite thin top coat is porous, inert, non-sacrificial, less permeable ceramic layer that eliminates the infiltration of environmental contaminants into the thermal barrier coating during operation of the metal part, thereby extending the life of the underlying thermal barrier coating and metal part thereunder.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: September 21, 2004
    Assignee: Standard Aero Limited
    Inventor: Kartik Shanker
  • Patent number: 6780520
    Abstract: There is provided a method for producing a metal/ceramic bonding article, the method including the steps of: bonding a metal plate 12 of an alloy containing copper and nickel directly to at least one side of a ceramic substrate 10; applying a resist 14 on a predetermined portion of the metal plate 12 to remove an undesired portion of the metal plate 12 by etching; and removing the resist 14 to form a pattern having a predetermined shape of the alloy on the ceramic substrate 10. According to this method, it is possible to reduce the displacement failure of parts to improve productivity and to prevent bonding failure during the mounting of a semiconductor device or the like thereon.
    Type: Grant
    Filed: January 27, 2003
    Date of Patent: August 24, 2004
    Assignee: Dowa Mining Co., Ltd.
    Inventors: Nobuyoshi Tsukaguchi, Takayuki Takahashi, Yukihiro Kitamura, Masami Kimura
  • Patent number: 6780524
    Abstract: Disclosed is a spin-valve sensor disposed between first and second gap layers and formed of one or more in-situ oxidized films. The improved spin valve sensor helps eliminate electrical shorting between the spin-valve sensor and shield layers. A fabrication method of the gap layers comprises repeatedly depositing a metallic films on a wafer in a DC-magnetron sputtering module of a sputtering system, and then transferring the wafer in a vacuum to an oxidation module where in-situ oxidation is conducted. This deposition/in-situ oxidation process is repeated until a designed thicknesses of gap layers is attained. Smaller, more sensitive spin-valve sensors may be sandwiched between thinner gap layers formed of in-situ oxidized films, thus allowing for greater recording data densities in disk drive systems.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: August 24, 2004
    Assignee: Hitachi Global Storage Technologies Netherlands B.V.
    Inventors: Tsann Lin, Daniele Mauri
  • Patent number: 6777374
    Abstract: Organic molecules are partially oxidized in that the gas phase on supported and immobilized photocatalysts deposited having a nanostructure. the photocatalysts are semiconductors such as titanium dioxide and are preferentially coated onto a substrate by flame aerosol coating.
    Type: Grant
    Filed: July 18, 2001
    Date of Patent: August 17, 2004
    Assignee: The United States of America as represented by the Environmental Protection Agency
    Inventors: Endalkachew Sahle-Demessie, Pratim Biswas, Michale A. Gonzalez, Zhong-Min Wang, Subhas K. Sikdar
  • Publication number: 20040151924
    Abstract: High temperature composites and thermal barrier coatings, and related methods, using anisotropic ceramic materials, such materials as can be modified to reduce substrate thermal mismatch.
    Type: Application
    Filed: January 20, 2004
    Publication date: August 5, 2004
    Inventors: Sankar Sambasivan, Kimberly Steiner
  • Patent number: 6770384
    Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises a polymer basecoat layer on the surface of said article and vapor deposited at relatively low pressure on the polymer layer a protective and decorative color layer comprised of the reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen wherein the nitrogen and oxygen content of the reaction products are each from about 4 to about 32 atomic percent with the nitrogen content being at least about 3 atomic percent.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: August 3, 2004
    Assignee: Vapor Technologies, Inc.
    Inventor: Guocun Chen
  • Patent number: 6770382
    Abstract: A Spin Valve GMR and Spin Filter SVGMR configuration where in the first embodiment an important buffer layer is composed of an metal oxide having a crystal lattice constant that is close the 1st FM free layer's crystal lattice constant and has the same crystal structure (e.g., FCC, BCC, etc.). The metal oxide buffer layer enhances the specular scattering. The spin valve giant magnetoresistance (SVGMR) sensor comprises: a seed layer over the substrate. An important metal oxide buffer layer (buffer layer) over the seed layer. The metal oxide layer preferably is comprised of NiO or alpha-Fe2O3. A free ferromagnetic layer over the metal oxide layer. A non-magnetic conductor spacer layer over the free ferromagnetic layer. A pinned ferromagnetic layer (2nd FM pinned) over the non-magnetic conductor spacer layer and a pinning material layer over the pinned ferromagnetic layer. In the second embodiment, a high conductivity layer (HCL) is formed over the buffer layer to create a spin filter -SVGMR.
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: August 3, 2004
    Assignee: Headway Technologies, Inc.
    Inventors: Jei-Wei Chang, Bernard Dieny, Mao-Min Chen, Cheng Horng, Kochan Ju, Simon Liao
  • Publication number: 20040146737
    Abstract: An object of the present invention is to provide a joined structure effective for preventing crack formation after thermal cycles. The joined structure has a ceramic member 1, a metal member 4 to be joined, and a metal fixed member 3 fixed to the ceramic member 1 and having an exposed face 3b exposed along the joining face 1d of the ceramic member 1. A joining layer 7 is provided between the ceramic member 1 and the metal member 4 and between the exposed face 3b of the fixed member 3 and the metal member 4. The joining layer 7 has thicker and thinner portions 7a and 7b. Alternatively, the joining layer 7 has a maximum thickness of 0.15 mm or more.
    Type: Application
    Filed: January 13, 2004
    Publication date: July 29, 2004
    Applicant: NGK Insulators, Ltd.
    Inventors: Tomoyuki Fujii, Akiyoshi Hattori
  • Patent number: 6767651
    Abstract: In a magnetic recording medium, a plurality of non-magnetic metallic intermediate layers is laminated between an under-layer and a magnetic layer. One of the intermediate layers is composed of at least an element selected from the group consisting of Ru, Re and Os and contains oxygen, and another is composed of a CoCr alloy containing at least an element selected from the group consisting of Nb, Mo, Ru, Rh, Pd, Ta, W, Re Os, Ir and Pt. The resulting magnetic recording medium provides reduced costs and improved recording characteristics.
    Type: Grant
    Filed: January 3, 2002
    Date of Patent: July 27, 2004
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Hiroyuki Uwazumi, Tadaaki Oikawa, Takahiro Shimizu, Naoki Takizawa
  • Patent number: 6767653
    Abstract: A turbine component comprises a substrate; and a crystalline coating disposed on a surface of the substrate, wherein the crystalline coating comprises tin and yttrium in an amount greater than or equal to about 0.05 atomic percent based upon the total coating. A method of making a turbine component comprises disposing a coating composition on a substrate, wherein the coating composition comprises tin and yttrium in an amount greater than or equal to about 0.1 atomic percent based upon the total coating composition. A crystalline coating comprises tin and yttrium in an amount greater than or equal to about 0.05 atomic percent based upon the total coating.
    Type: Grant
    Filed: December 27, 2002
    Date of Patent: July 27, 2004
    Assignee: General Electric Company
    Inventors: Bernard Bewlay, Melvin Jackson, Ji-Cheng Zhao
  • Publication number: 20040142112
    Abstract: A method for applying a bond coat on a metal-based substrate is described. A slurry which contains braze material and a volatile component is deposited on the substrate. The slurry can also include bond coat material. Alternatively, the bond coat material can be applied afterward, in solid form or in the form of a second slurry. The slurry and bond coat are then dried and fused to the substrate. A repair technique using this slurry is also described, along with related compositions and articles.
    Type: Application
    Filed: December 23, 2003
    Publication date: July 22, 2004
    Inventors: Wayne Charles Hasz, D Sangeeta
  • Publication number: 20040139702
    Abstract: A laminate including a flavorant useful for packaging cigarettes or other products such as food products. The laminate includes crosslinked polymer coatings adhered to at least two metal foils, and a volatile flavor component such as menthol is applied to one of the polymer-coated surfaces. The laminate minimizes loss of volatile and/or heat sensitive flavor components from the package during extended periods at elevated temperature which are often associated with long term storage and/or shipping.
    Type: Application
    Filed: January 12, 2004
    Publication date: July 22, 2004
    Applicant: Philip Morris Incorporated
    Inventor: Sarojini Deevi
  • Patent number: 6764775
    Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises a polymeric basecoat layer on the surface of said article and vapor deposited on the polymeric basecoat layer a stack layer containing layers of refractory metal or refractory metal alloy alternating with layers containing the reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen. Over the stack layer is vapor deposited at relatively low pressures a protective color layer comprised of the reaction products of refractory metal or refractory metal alloy, oxygen and nitrogen wherein the total nitrogen and oxygen content of these reaction products is from about 4 to about 32 atomic percent, with the nitrogen content being at least about 3 atomic percent.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: July 20, 2004
    Assignee: Vapor Technologies, Inc.
    Inventor: Guocun Chen
  • Patent number: 6764779
    Abstract: This invention provides a metallic article with a metallic substrate having a thermal barrier ceramic coating on its surface, the ceramic coating comprising a plurality of first layers of about 6 to 8 wt % yttria stabilized zirconia alternating with a plurality of second layers of about 18 to 22 wt % yttria stabilized zirconia. The alternating layers can be distinct layers or gradient layers.
    Type: Grant
    Filed: February 24, 2003
    Date of Patent: July 20, 2004
    Assignee: Chromalloy Gas Turbine Corporation
    Inventors: Yourong Liu, Paul Lawton
  • Patent number: 6765755
    Abstract: A magnetooptic read head including a magnetooptic transducer with a multilayer structure with at least one thin magnetic layer with a magnetooptic effect, at least one layer made of nonmagnetic material and having a predetermined wear coefficient, and a layer with good magnetic permeability for closing a magnetic circuit. The layer with good magnetic permeability includes alternating first sublayers made of a magnetic material with good magnetic permeability and second sublayers made of a material having a wear coefficient substantially equivalent to the wear coefficient of the layer made of a nonmagnetic material.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: July 20, 2004
    Assignee: Thales
    Inventor: Jean-Claude Jacquet
  • Publication number: 20040137239
    Abstract: The disclosure relates to a process for applying a multilayer protective coating to a substrate having an electrically conductive surface, comprising: (a) a first method of forming a silicate layer upon said electrically conductive surface, said first method comprising contacting at least a portion of said surface with a first medium comprising at least one silicate and having a basic pH and wherein said first medium is substantially free of chromates, to form a silicate layer, and (b) a second method of electrolytically applying a synthetic resin layer upon the surface of said silicate layer, said second method comprising contacting at least a portion of said surface of said silicate layer with a second medium comprising a resinous ingredient, applying an electric current to said second medium wherein said surface is employed as an electrode, to form a synthetic resin layer. The multilayer protective coating exhibits excellent corrosion and adhesion properties and is environmentally acceptable.
    Type: Application
    Filed: November 14, 2003
    Publication date: July 15, 2004
    Inventors: Klaus-Peter Klos, Holger Manfred Grolmes
  • Patent number: 6761956
    Abstract: A gas turbine engine component includes a perforate metal wall having pores extending therethrough. The wall has a first surface covered by a thermal barrier coating. The pores have first ends which are covered by the thermal barrier coating, and the pores are ventilated from an opposite second surface of the wall for cooling the thermal barrier coating.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: July 13, 2004
    Assignee: General Electric Company
    Inventors: Ching-Pang Lee, Robert Edwards Schafrik, Ramgopal Darolia
  • Patent number: 6756131
    Abstract: A high temperature corrosion resistant alloy composition comprising, in addition to Ni, 0.1 to 12% by weight of Co, 10 to 30% by weight of Cr, 4 to 15% by weight of Al, 0.1 to 5% by weight of Y, and 0.5 to 10% by weight of Re. The high temperature corrosion resistant alloy composition has an excellent oxidation resistance and ductility and is suitable for use in a bonding layer of a thermal barrier coating material.
    Type: Grant
    Filed: December 11, 2002
    Date of Patent: June 29, 2004
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Hidetaka Oguma, Ikuo Okada, Taiji Torigoe, Kouji Takahashi
  • Patent number: 6753095
    Abstract: The aim of the present invention is to provide a phosphate treated zinc coated steel sheet with excellent workability. A steel sheet coated with a zinc based alloy has a phosphate treated coating on the surface thereof. The phosphate treated coating comprises mainly granulated crystals, specifically, crystals in which the average ratio of the major axis to the minor axis is not less than 1.00 and not more than 2.90. Moreover, the method for producing the phosphate treated coating uses a phosphate treatment solution in which the amount of Mg ions is ≧6 g/l and the amount of Zn ions is ≧0.5 g/l, or a phosphate treatment solution in which the amount of Mg ions is ≧10 g/l, the amount of Zn ions is 0≦ and <0.5 g/l, and the amount of nitric acid ions is ≧40 g/l.
    Type: Grant
    Filed: February 11, 2002
    Date of Patent: June 22, 2004
    Assignee: Nippon Steel Corporation
    Inventors: Hidetoshi Shindou, Kiyokazu Isizuka, Keiichi Sanada, Kazuo Takahashi, Teruaki Yamada, Daisuke Ito, Shigekazu Ooba
  • Publication number: 20040115463
    Abstract: The invention relates to an armoured shaped body comprising a multi-layer composite plate, which has a layer made of high-strength steel and a layer made of titanium or a titanium alloy as well as a layer made of a hard material of great hardness deposited on the titanium or titanium-alloy layer. The production of such an armoured shaped body takes place in such a way that composite plates, which are cut to length from the composite strip made of steel and titanium or a titanium alloy produced by roll-bonding, are shaped into shaped bodies, onto whose titanium or titanium-alloy layer the hard-material layer in the form of powder is then deposited in particular by means of flame spraying. Such a shaped body has a high gunfire resistance, because in the event of gunfire the hard-material layer enlarges the impact area of the bullet, so that the kinetic energy of the bullet is distributed over a large area on the shaped body.
    Type: Application
    Filed: February 3, 2004
    Publication date: June 17, 2004
    Inventor: Heinz Sibum
  • Patent number: 6746782
    Abstract: A barrier coating is disclosed, containing about 15 atom % to about 95 atom % chromium; and about 5 atom % to about 60 atom % of at least one of rhenium, tungsten, and ruthenium. Nickel, cobalt, iron, and aluminum may also be present. The barrier coating can be disposed between a metal substrate (e.g., a superalloy) and an oxidation-resistant coating, preventing the substantial diffusion of various elements at elevated service temperatures. A ceramic overcoat (e.g., based on zirconia) can be applied over the oxidation-resistant coating. Related methods for applying protective coatings to metal substrates are also described.
    Type: Grant
    Filed: June 11, 2001
    Date of Patent: June 8, 2004
    Assignee: General Electric Company
    Inventors: Ji-Cheng Zhao, Melvin Robert Jackson
  • Patent number: 6743532
    Abstract: An article is coated with a multi-layer coating having a bronze color. The coating comprises a nickel basecoat layer, and a color and protective stack layer comprised of layers of carbon-rich refractory metal or refractory metal alloy carbonitride alternating with layers of nitrogen-rich refractory metal or refractory metal alloy carbonitride.
    Type: Grant
    Filed: November 27, 2002
    Date of Patent: June 1, 2004
    Assignee: Vapor Technologies, Inc.
    Inventor: Guocun Chen
  • Patent number: 6742248
    Abstract: A reliable, long-lived soldered electrical connection is made to a ceramic substrate having a thick-film metallization thereon, over which is deposited a joint-structure-stabilizing thin-film metallization. The thin-film metallization is a multilayered structure having an adhesion layer overlying and in contact with the thick-film metallization, a readily wettable base-metal layer overlying and in contact with the adhesion layer, and an oxidation-prevention layer overlying and in contact with the base-metal layer. An electrical conductor is soldered to the thin-film metallization of the ceramic substrate. The electrical conductor may be a bonding pad of a flip chip having a solder bump thereon.
    Type: Grant
    Filed: May 14, 2001
    Date of Patent: June 1, 2004
    Assignee: The Boeing Company
    Inventors: Boon Wong, Robert E. Silhavy, Jennifer Shinno
  • Publication number: 20040101708
    Abstract: An article is coated with a multi-layer coating having a bronze color. The coating comprises a nickel basecoat layer, and a color and protective stack layer comprised of layers of carbon-rich refractory metal or refractory metal alloy carbonitride alternating with layers of nitrogen-rich refractory metal or refractory metal alloy carbonitride.
    Type: Application
    Filed: November 27, 2002
    Publication date: May 27, 2004
    Inventor: Guocun Chen
  • Publication number: 20040096690
    Abstract: A protected article includes a substrate having a substrate surface and made of a substrate nickel-base superalloy that is susceptible to the formation of a secondary reaction zone, as when contacted by an aluminum-containing layer having more than about 20 percent by weight aluminum. A protective layer contacts the substrate surface. The protective layer is of a different composition than the substrate and is made of a protective-layer nickel-base superalloy having from about 7 to about 12 percent by weight aluminum. Preferably, a thermal barrier coating system including a ceramic layer overlies and contacts the protective layer.
    Type: Application
    Filed: November 20, 2002
    Publication date: May 20, 2004
    Inventors: Thomas Joseph Kelly, Philemon Kennard Wright
  • Patent number: 6730422
    Abstract: A ceramic material having particular utility as a thermal insulating or thermal barrier coating on metallic substrates is provided. The ceramic material broadly comprises at least one oxide and the balance comprising a first oxide selected from the group consisting of zirconia, ceria, and hafnia. The at least one oxide has a formula A2O3 where A is selected from the group consisting of La, Pr, Nd, Sm, Eu, Th, In, Sc, Y, Dy, Ho, Er, Tm, Yb, Lu, and mixtures thereof. The present invention also broadly relates to an article having a metal substrate and a thermal barrier coating as discussed above.
    Type: Grant
    Filed: August 21, 2002
    Date of Patent: May 4, 2004
    Assignee: United Technologies Corporation
    Inventors: David A. Litton, Nicholas E. Ulion, Mladen F. Trubelja, Michael J. Maloney, Sunil Govinda Warrier
  • Patent number: 6730413
    Abstract: A thermal insulating ceramic layer for use on metal alloy components exposed to hostile thermal and chemical environment, such as a gas turbine engine used to generate electricity. The preferred thermal barrier layer is formed using dense vertical cracking and formed of zirconia that is partially stabilized by yttria in a preferred amount of less than 4 weight percent and about 1 weight percent Hafnia. The ceramic layer is optimized to protect the underlying superalloy component from erosion, chipping, and handling, while reducing the cost of the protective layer. An alternative method of preparing the thermal barrier coating uses electron beam physical vapor deposition.
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: May 4, 2004
    Assignee: General Electric Company
    Inventors: Jon C. Schaeffer, Robert W. Bruce
  • Publication number: 20040076837
    Abstract: A clear protective coating including a composition having a formula SiOxCyHz, wherein x=0.8-1.5, y=1.0-2.0, and z=1.6-3.7 is provided. The coating may be formed by plasma-enhanced chemical vapor deposition. The coating typically coats a substrate, and more particularly, a metal substrate. In a preferred embodiment, the coating coats an architectural hardware article, thereby providing corrosion and abrasion protection for the architectural hardware article.
    Type: Application
    Filed: October 22, 2002
    Publication date: April 22, 2004
    Applicant: Schlage Lock Co.
    Inventors: Gerald F. Hein, Brad Knapp, Greg Agnew