Next To Group Viii Metal-base Component Patents (Class 428/648)
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Patent number: 5677025Abstract: Disclosed are a phthalocyanine near infrared absorbing material having a phthalocyanine skeleton whose benzene rings contain a silyl group as a bulky substituent and an optical information recording medium containing the material.The phthalocyanine near infrared absorbing material has excellent association-preventing property and light resistance and exhibits a high index of refraction at a wave length of 770-830 nm and high stability, an optical information recording medium (CD-R recording medium) containing the phthalocyanine has high reflectance, excellent storage stability and excellent reproduction stability. The recording medium also shows strong light absorptivity and light reflectivity in a wave length of 630-700 nm and, thus, is applicable for the pick up with a semiconductor laser of 630-700 nm, permitting such high density recording as to provide 1.6-1.7 times as high recording density as that attained by currently employed recording media which are adapted to 780-810 nm.Type: GrantFiled: June 12, 1995Date of Patent: October 14, 1997Assignee: Ricoh Company, Ltd.Inventors: Tatsuya Tomura, Tsutomu Sato, Noboru Sasa
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Patent number: 5667860Abstract: The present invention discloses an optical recording element having, in the following order, a transparent substrate, a recording layer and a light reflecting layer wherein the recording layer(A) has a real refractive index (N) at 780 nm not less than 1.8 and an imaginary part (k) is not greater than 0.15;(B) comprises a polymeric cyanine dye that (i) has both a weight-average molecular weight greater than 50,000 and a glass transition temperature (Tg) of less than 150.degree. C.; or (ii) has either (a) a weight-average molecular weight greater than 50,000 or (b) a glass transition temperature (Tg) of less than 150.degree. C.; and(C) a thickness greater than 200 nm.Type: GrantFiled: November 14, 1995Date of Patent: September 16, 1997Assignee: Eastman Kodak CompanyInventors: Elizabeth G. Burns, James C. Fleming
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Patent number: 5667904Abstract: An article is coated with a multilayer coating comprising a nickel layer deposited on the surface of the article, a tin-nickel alloy layer deposited on the nickel layer, and a refractory metal compound, preferably zirconium nitride, deposited on the tin-nickel layer. The coating provides the color of polished brass to the article and also provides abrasion and corrosion protection.Type: GrantFiled: May 22, 1995Date of Patent: September 16, 1997Assignee: Baldwin Hardware CorporationInventors: Stephen R. Moysan, III, Rolin W. Sugg
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Patent number: 5654108Abstract: An article is coated with a multilayer coating comprising a tin-nickel alloy layer deposited on the surface of the article, and a refractory metal compound, preferably zirconium nitride, deposited on the tin-nickel layer. The coating provides the color of polished brass to the article and also provides abrasion and wear protection.Type: GrantFiled: May 22, 1995Date of Patent: August 5, 1997Assignee: Baldwin Hardware CorporationInventors: Stephen R. Moysan, III, Rolin W. Sugg
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Patent number: 5650238Abstract: A zinc-electroplated steel sheet comprises a steel sheet; a tin layer which is formed on the steel sheet, the tin layer having a deposition amount of 0.5 mg/m.sup.2 to less than 10 mg/m.sup.2 ; and a zinc-electroplating layer which is formed on the tin layer.A method for producing a zinc-electroplated steel sheet comprising the steps of: pickling a steel sheet with a pickling solution so as to deposit a tin of an amount of 0.5 mg/m.sup.2 to less than 10 mg/m.sup.2 on the steel sheet; and zinc-electroplating the pickled steel sheet.Type: GrantFiled: July 12, 1995Date of Patent: July 22, 1997Assignee: NKK CorporationInventors: Takayuki Urakawa, Hideharu Koga, Toru Imokawa, Toyofumi Watanabe
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Patent number: 5648197Abstract: An optical disk is provided for recording data thereon as optically readable pits formed thereon and for reading data from the pits by means of a reproducing laser beam. The disk has a substrate of a light transmissive material. A reflective layer of a light reflective material is formed on one of the surfaces of the substrate. A light absorbing layer is formed on the other surface of the substrate on which the reproducing laser beam is projected. The light absorbing layer containing a coloring substance exhibiting light absorption characteristics that is small for the reproducing laser beam but large for a laser beam of a specific light wavelength band shifted from the reproducing laser beam wavelength band to a longer light wavelength side. The substrate may be of a colored substrate including the coloring substance. The light absorbing layer is not required in this case.Type: GrantFiled: January 31, 1996Date of Patent: July 15, 1997Assignee: Victor Company of Japan, LTD.Inventor: Mikiya Kuroda
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Patent number: 5648135Abstract: An information recording medium has a recording layer which comprises a composition containing:I) at least one organic polymer selected from the group consisting of:(a) conjugated polymers whose conformations change by thermal energy, for example, polythiophene, and(b) polymers containing as a component a diene monomer and/or an aromatic-ring-containing vinyl monomer, for example, polystyrene; andII) a dye having light-absorbing ability, for example, naphthalocyanine. Despite the recording layer is of the organic type that features non-toxicity and low manufacturing cost as advantages, the recording layer makes it possible to produce a rewritable optical disc which can be recorded by a semiconductor laser (830,780 nm) employed widely.Type: GrantFiled: June 7, 1995Date of Patent: July 15, 1997Assignee: Hitachi Chemical Company, Ltd.Inventors: Itsuo Watanabe, Atsushi Kuwano, Jun Taketatsu, Nobuaki Takane, Mitsuo Yamada, Seiji Tai
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Patent number: 5648179Abstract: An article is coated with a multilayer coating comprising a nickel layer deposited on the surface of the article, a tin-nickel alloy layer deposited on the nickel layer, and a refractory metal compound, preferably zirconium nitride, deposited on the tin-nickel alloy layer. The coating provides the color of polished brass to the article and also provides abrasion and corrosion protection.Type: GrantFiled: June 21, 1996Date of Patent: July 15, 1997Assignee: Baldwin Hardware CorporationInventors: Stephen R. Moysan, III, Rolin W. Sugg
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Patent number: 5645907Abstract: There is provided a WORM type organic optical recording media comprising a recording layer, a reflective layer and a protective layer which are formed in sequence on a substrate, the recording layer consisting of near infrared absorbing dye able to absorb a laser beam and to generate heat and of a thermosetting or photocuring resin. The organic optical recording medium can be prevented from being rewritten by heating up to 50.degree. C. or irradiating with a UV light, said dye being capable of absorbing near infrared rays and generating heat.The medium exhibits stable reading characteristics of at least 45 dB even after irradiating with a light with a short wavelength. In addition, it also has a function of record locking by curing the resin of the recording layer, so that, once recorded, rewrite or additional recording is not allowed therein.Type: GrantFiled: December 22, 1994Date of Patent: July 8, 1997Assignee: Cheil Synthetics, Inc.Inventors: Jung Hoi Kim, Young Jae Heo, Tae Young Nam
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Patent number: 5645910Abstract: A copolymer comprising 70 to 100 mole percent of repeating units comprising a formazan dye radical and a cyanine dye radical. The copolymers are useful in recording layers of optical recording elements.Type: GrantFiled: March 22, 1996Date of Patent: July 8, 1997Assignee: Eastman Kodak CompanyInventors: Elizabeth Gertrude Burns, Ramanuj Goswami, Csaba Andras Kovacs
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Patent number: 5635268Abstract: An optical recording medium is provided with: a first substrate of optically transparent type; a first recording layer formed on one surface of the first substrate, which includes phthalocyanine dye; a second substrate of optically transparent type; a second recording layer formed on one surface of the second substrate which includes phthalocyanine dye; a first elastic body layer formed on a surface of the first recording layer at a side opposite to the first substrate; a second elastic body layer formed on a surface of the second recording layer at a side opposite to the second substrate; and a bonding layer formed between the first elastic body layer and the second elastic body layer.Type: GrantFiled: June 19, 1995Date of Patent: June 3, 1997Assignee: Pioneer Electronic CorporationInventors: Takako Miyake, Shingo Iwasaki, Yasushi Araki, Takashi Chuman, Satoru Tanaka, Atsushi Yoshizawa, Fumio Matsui
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Patent number: 5633060Abstract: An optical disk substrate formed substantially of an aromatic polycarbonate from an aromatic dihydroxy component containing at least 20 mol % of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane,wherein:(A) the aromatic polycarbonate has a specific viscosity of 0.2 to 0.5,(B) the aromatic polycarbonate shows a water absorption percentage of 0.2 % by weight or less,(C) the aromatic polycarbonate has an oligomer content of 10 % or less, and(D) the number of undissolved particles having a diameter of 0.5 .mu.m or greater is 25,000 pieces or less per g of the polycarbonate resin, and the number of undissolved particles having a diameter of 1 .mu.m or greater is 500 pieces or less per g of the polycarbonate resin, and an optical disk from the above substrate.Type: GrantFiled: June 16, 1995Date of Patent: May 27, 1997Assignee: Teijin Chemicals, Ltd.Inventors: Toshimasa Tokuda, Kuniyuki Hayashi, Tatsumi Horie
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Patent number: 5631056Abstract: There is disclosed an optical recording medium for high density recording without degradation of reproducing output signals. The optical recording medium includes a transparent substrate made of resin having an information recorded portion on which optically readable information signals are recorded, a thermochromic layer provided over the transparent substrate, the thermochromic layer having a larger light transmittance when the thermochromic layer has a higher temperature than a threshold value by absorbing heat off a laser beam spot and the thermochromic layer having a smaller light transmittance when the thermochromic layer has a lower temperature than the threshold value by being cooled down, and a reflecting layer provided on the thermochromic layer, wherein a heat radiating layer made of transparent inorganic material is further provided in contact with the thermochromic layer so as to absorb heat generated in the thermochromic layer by being irradiated with the laser beam spot.Type: GrantFiled: March 30, 1995Date of Patent: May 20, 1997Assignee: Victor Company of Japan, Ltd.Inventors: Toshinori Kawanishi, Mikiya Kuroda
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Patent number: 5616424Abstract: A corrosion-resistant metal strip and method for making the same which is essentially lead free and is not highly reflective. The coating on the metal strip is a metallic coating comprised of tin and a very low weight percentage of lead. The coating alloy may also include antimony, bismuth, copper, zinc to improve the coating process and/or improve the properties of the tin coating. A metal layer may also applied to the surface of the metal strip prior to applying the metallic alloy coating.Type: GrantFiled: November 1, 1995Date of Patent: April 1, 1997Assignee: The Louis Berkman CompanyInventors: Jay F. Carey, II, Mehrooz Zamanzadeh
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Patent number: 5616390Abstract: An optical information recording medium is configured so that grooves and lands formed spirally or concentrically on a disk substrate are used as recording tracks. Identification signal areas are provided in which identification signals including positional information are formed in advance on the disk substrate. Information signal areas are formed separately from the identification signal areas so that information signals are recorded by irradiation with a light beam. The identification signals are formed on the grooves and lands not independently of each other, but so that each identification signal is formed so as to be shared by a respective adjacent groove and land. The period of arrangement of the identification signals in the radial direction of the recording tracks is twice the period of the recording tracks and crosstalk at the time of reproduction of the identification signals is suppressed.Type: GrantFiled: July 18, 1995Date of Patent: April 1, 1997Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Naoyasu Miyagawa, Yasuhiro Gotoh
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Patent number: 5607739Abstract: An optical disk is disclosed which includes a substrate and a reflector layer disposed on the substrate. At least one temperature sensitive layer disposed on the reflector layer, the sensor material being selected such that its reflectivity changes as a function of the disk temperature. Finally, a transparent overcoat over the substrate or reflector layer disposed so that incident light passes through the transparent overcoat and interacts with the temperature sensitive layer so that it provides a reflected light component, the intensity of which is temperature dependent.Type: GrantFiled: March 7, 1995Date of Patent: March 4, 1997Assignee: Eastman Kodak CompanyInventor: Brian J. Bartholomeusz
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Patent number: 5605732Abstract: An aminium salt compound has the structure expressed by the following formula (I) or (II), and an optical recording layer has a recording layer containing the aminium salt compound. ##STR1## wherein X.sup.- indicates a monovalent metal complex anion; and R.sub.1 through R.sub.8 each indicate a hydrogen atom or a monovalent organic residue, and at least one of R.sub.1 through R.sub.8 is a monovalent organic residue selected from the group consisting of a substituted or unsubstituted alkoxyalkyl group, substituted or unsubstituted alkenyl group, substituted or unsubstituted alkynyl group and substituted or unsubstituted aralkyl group; and n is 1 or 2; and ##STR2## wherein X.sup.- indicates a monovalent metal complex anion; and R.sub.1 ' through R.sub.8 ' indicate the atoms that, when taken together in combination R.sub.m ' and R.sub.Type: GrantFiled: December 29, 1992Date of Patent: February 25, 1997Assignee: Canon Kabushiki KaishaInventors: Chieko Mihara, Hiroyuki Sugata, Tsuyoshi Santoh
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Patent number: 5604002Abstract: An optical recording medium includes a recording layer, and a masking layer which is converted to a state having small absorption at the wavelength of a reproducing beam due to progress of decoloration caused by a thermal reaction upon irradiation with the reproducing beam, or due to facilitation of decoloration caused by a photon mode photochromic reaction through temperature rise upon irradiation with the reproducing beam.Type: GrantFiled: March 21, 1995Date of Patent: February 18, 1997Assignee: Sanyo Electric Co., Ltd.Inventors: Tsuyoshi Tsujioka, Toshio Harada, Kazuhiko Kuroki, Fumio Tatezono
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Patent number: 5604004Abstract: A formazan metal complex dye is contained as a light absorbing dye in a recording layer to construct an optical recording medium. The formazan metal complex dye has high solubility and a relatively-low thermal decomposition temperature and the recording medium exhibits high sensitivity, especially high recording sensitivity, and improved light resistance. The formazan metal complex dye can be used as a photo-stabilizer in an optical recording medium. The formazan metal complex dye is also effective for stabilizing conventional dyes against light.Type: GrantFiled: October 3, 1995Date of Patent: February 18, 1997Assignee: TDK CorporationInventors: Takahiko Suzuki, Masahiro Shinkai, Kenryo Namba
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Patent number: 5597656Abstract: A corrosion-resistant metal strip and method for making the same which is essentially lead free and is not highly reflective. The coating on the metal strip is a two-phase metallic coating comprised of tin and zinc and a very low weight percentage of lead. The coating alloy may also include antimony, bismuth and copper to improve the coating process and/or improve the properties of the tin and zinc coating. A metal layer may also applied to the surface of the metal strip prior to applying the metallic alloy coating.Type: GrantFiled: May 8, 1995Date of Patent: January 28, 1997Assignee: The Louis Berkman CompanyInventors: Jay F. Carey, II, Mehrooz Zamanzadeh
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Patent number: 5582891Abstract: A method of making a stamper uses a photoresist disk cut by the application of a laser beam on the land planes thereof, or a stamper which is different in depth between the land plane on the internal peripheral side with respect to the prepit portion and the land plane on the external peripheral side. A method of making an optical disk substrate includes the steps of using a stamper, and molding a transparent plastic material with an injection molding method. A stamper capable of sufficiently transferring the prepits and guide grooves on the optical disk substrate with the correction of right and left inequality of the prepits, and the method of making it, and a superior optical disk substrate and a method of making it can be realized.Type: GrantFiled: June 15, 1993Date of Patent: December 10, 1996Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Motoyoshi Murakami, Masahiro Birukawa, Yoshihiko Kudoh
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Patent number: 5580631Abstract: An optical recording medium comprises a light transmissive substrate, a record film formed on a surface of the base plate, the record film containing phthalocyanine as a coloring matter, a light-reflection film formed on a surface of the record film, and a protection film formed on a surface of the light-reflection film, the protection film having a thickness capable of preventing the light-reflection film from braking by a deformation thereof in directions to the light-reflection film and the protection film due to a formation of a pit in the record film.Type: GrantFiled: November 5, 1993Date of Patent: December 3, 1996Assignee: Pioneer Electronic CorporationInventors: Toshiyuki Miyadera, Takashi Chuman, Takashi Yamada, Fumio Matsui
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Patent number: 5576084Abstract: An optical recording medium for high density recording and reproducing has a transparent substrate formed with at least a series of information pits readable with a laser beam from an apparatus or formed with guide grooves for controlling operation of recording the information pits on the substrate and a masking layer provided on the transparent substrate for minimizing an effective spot diameter of the laser beam to pass through the masking layer. The masking layer has an optical transmittance reversely changeable corresponding to a change of temperature by being irradiated with the laser beam. The masking layer is made of a thermochromic material consisting of an electron donative color compound and an electron acceptant developer without polarized materials and is uniformly provided on the uneven transparent substrate formed with the information pits or the guide grooves by using a vacuum deposition method.Type: GrantFiled: November 8, 1994Date of Patent: November 19, 1996Assignee: Victor Company of Japan, Ltd.Inventor: Mikiya Kuroda
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Patent number: 5573831Abstract: An optical recording medium comprising a transparent substrate; a recording layer on the transparent substrate; a metal reflective layer; and one or more protective layers. These layers are laminated successively on the transparent substrate. The outermost protective layer is formed of an ultraviolet curable resin containing an organic filler and/or an inorganic filler having water absorbency and/or oil absorbency. The protective layer has a printable surface permitting writing characters with writing instruments or ink jet printers.Type: GrantFiled: October 17, 1994Date of Patent: November 12, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Yuko Suzuki, Shin Aihara, Sumio Hirose
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Patent number: 5569504Abstract: A phthalocyanine dye of specific structure represented by the following general formula (1) or (2): ##STR1## where Y is O or S attached to the phthalocyanine ring, Z is the group of atoms recurred to complete a carbon or heterocyclic ring together with C, A.sub.1 is a monovalent substituent bulkier than a hydrogen atom, and each of X.sub.1 and X.sub.2 is H or a monovalent substituent or, in the alternative, X.sub.1 and X.sub.2, taken together, form a single bond, ##STR2## where Y and Z.sub.1 have the same meanings as defined for Y and Z in formula (1), All is a monovalent substituent having a branched alkyl group, which is attached to the ring completed by Z.sub.1, and s1 is the number of A.sub.11, is used for the recording layer of an optical recording layer. This phthalocyanine dye is unlikely to attack a substrate material such as PC, can be handled with ease, and has a high solubility in a coating solvent advantageous for film formation, for instance, an alcoholic solvent, e.g.Type: GrantFiled: March 30, 1995Date of Patent: October 29, 1996Assignee: TDK CorporationInventors: Sumiko Kitagawa, Masahiro Shinkai, Kenryo Namba
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Patent number: 5556681Abstract: An optical information recording medium is disclosed. The optical information recording medium has a transparent substrate having pits and lands corresponding to information signals formed therein, and a reflective layer formed on the transparent substrate. The reflective layer is composed mainly of a dye material and a polymeric material and has a reflectance of 15 to 25%. The polymeric material forming the reflective layer is a silicon varnish.Type: GrantFiled: September 2, 1994Date of Patent: September 17, 1996Assignee: Sony CorporationInventors: Yoko Matsuzawa, Shin-Ichiro Tamura, Katsuya Shirai
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Patent number: 5552233Abstract: An article is coated with a multilayer coating comprising a nickel layer deposited on the surface of the article, a tin-nickel alloy layer deposited on the nickel layer, a refractory metal, preferably zirconium, strike layer deposited on the tin-nickel alloy layer, and a refractory metal compound, preferably zirconium nitride, deposited on the refractory metal strike layer. The coating provides the color of polished brass to the article and also provides abrasion and corrosion protection.Type: GrantFiled: May 22, 1995Date of Patent: September 3, 1996Assignee: Baldwin Hardware CorporationInventors: Stephen R. Moysan, III, Rolin W. Sugg
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Patent number: 5547728Abstract: An optical recording element having a transparent substrate and on the surface of said substrate, a recording layer and a light reflecting layer wherein recording layer comprises a mixture of a metallized formazan dye and cyanine dye and the unrecorded layer is such that the real part of the refractive index (N) at 780 nm is not less than 1.8 and the imaginary part (k) is not greater than 0.2.Type: GrantFiled: January 30, 1995Date of Patent: August 20, 1996Assignee: Eastman Kodak CompanyInventors: Michael P. Cunningham, Steven Evans
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Patent number: 5547727Abstract: An optical recording element having a transparent substrate and on the surface of said substrate, a recording layer and a light reflecting layer wherein recording layer comprises a dye selected from the group consisting of cationic azocyanine dyes and mixtures of such dyes and the unrecorded layer is such that the real part of the refractive index (N) at 780 nm is at least 1.8 and the imaginary part (k) is 0.01 to 0.15.Type: GrantFiled: December 13, 1994Date of Patent: August 20, 1996Assignee: Eastman Kodak CompanyInventors: Leslie Shuttleworth, Charles H. Weidner, Michael P. Cunningham
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Patent number: 5536548Abstract: In an optical recording disk comprising a reflective layer in close contact with a recording layer, the recording layer contains a phthalocyanine dye and a second dye having a lower heat decomposition temperature than the phthalocyanine dye. By virtue of a depression of heat decomposition temperature, recording sensitivity is improved.Type: GrantFiled: March 20, 1995Date of Patent: July 16, 1996Assignee: TDK CorporationInventors: Yasukawa Koji, Toshiki Aoi, Hiroyuki Arioka
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Patent number: 5534358Abstract: A process for plating aluminum alloy substrates (10), such as 390 aluminum alloy pistons (12), with iron comprises (a) plating on the aluminum substrate a layer of zincate from a zincate bath; (b) plating on the zincate layer a layer (14) of nickel from an electroless nickel bath; (c) plating on the nickel layer a layer (16) of iron from an iron ammonium sulfate bath; and (d) plating on the iron layer a layer (18) of tin from an alkaline tin bath. During the electroless plating, the zincate layer, which protects the underlying aluminum against oxidation, is sacrificed. All of these baths are environmentally much safer than cyanide and chloride. They are also cost effective and can be utilized in a totally closed loop plating system.Type: GrantFiled: February 2, 1994Date of Patent: July 9, 1996Assignee: Hughes Aircraft CompanyInventor: Sue Troup-Packman
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Patent number: 5532032Abstract: An optical recording medium has a substrate and a recording film, which containes coloring matter, provided on the substrate. The recording film is irradiated with a laser beam passing through the substrate so that substances of the coloring matter are aggregated with each other.Type: GrantFiled: January 19, 1994Date of Patent: July 2, 1996Assignee: Pioneer Electronic CorporationInventors: Kumi Kawano, Fumio Matsui
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Patent number: 5532031Abstract: A ceramic substrate having an improved I/O pad adhesion layer. The ceramic substrate has an I/O pad for joining to an I/O pin. The I/O pad includes an improved adhesion layer of TiO, followed by layers of Ti (or Ti and Ni) and a solder wettable layer which may be Au or Pt. Also disclosed are low yield stress solders of Sn/Sb, Sn/Ag, Sn/Cu and Sn/Cu/Ti.Type: GrantFiled: January 29, 1992Date of Patent: July 2, 1996Assignee: International Business Machines CorporationInventors: Shaji Farooq, Sampath Purushothaman, Srinivasa S. N. Reddy, Vivek M. Sura
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Patent number: 5532033Abstract: An optical information recording medium is disclosed which includes a substrate, and an information recording layer provided on the substrate and containing a specific metallophthalocyanine having a substituent which prevents the molecular association of the metallophthalocyanine and which contains at least one of O, S and N atoms.Type: GrantFiled: April 19, 1995Date of Patent: July 2, 1996Assignees: Ricoh Company, Ltd., Yamada Chemical Co., Ltd.Inventor: Toru Yashiro
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Patent number: 5516568Abstract: There is disclosed an organic optical recording medium with high data storage density, high data rates and long data archival capabilities, useful as a medium for recording a variety of information or pictures.In a preferred embodiment, the optical recording medium according to the present invention comprises a substrate, a reflective layer, a charge-generating layer containing at least one charge-generating material, a charge-transferring layer containing at least one charge-transferring material, a recording layer containing at least one electric field-discoloring element, a plurality of spacers, an air layer and a protective layer.A laser beam is absorbed to the charge-generating material contained in the charge-generating layer, to generate charges, which are subsequently transferred to the surface of the recording layer by the charge-transferring layer.With the influence of the charge generated, the illuminated area having the charges puts on a color different from that in the other areas.Type: GrantFiled: June 7, 1995Date of Patent: May 14, 1996Assignee: Cheil Synthetics, Inc.Inventor: Hee-Tae Jung
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Patent number: 5503889Abstract: An optical recording medium has a substrate, a recording layer having a bare portion at the end face, and a protecting layer. The bare portion of the recording layer and the vicinity thereof are resinified so as to be substantially incapable of optical recording.Type: GrantFiled: November 12, 1993Date of Patent: April 2, 1996Assignee: Canon Kabushiki KaishaInventor: Hiroyuki Imataki
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Patent number: 5503913Abstract: For the improvement of the wear properties of tools with cutting edge of cubic boron nitride (CBN) or polycrystalline cubic boron nitride (PCBN) it is proposed to coat the CBN or PCBN body with a 0.5 to 6 .mu.m thick layer of one or more oxides of the metals zirconium and/or yttrium and/or magnesium and/or titanium and/or aluminum, preferably aluminum oxide. The wear-resistant coating is deposited from the gas phase at gas-phase temperatures up to 800.degree. C. Preferably for the coating the pulse-plasma CVD process is used. The so-coated tools are particularly suitable for the chip-forming precision machining of hard iron and hard steel materials.Type: GrantFiled: December 30, 1993Date of Patent: April 2, 1996Assignee: Widia GmbHInventors: Udo Konig, Ralf Tabersky
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Patent number: 5503890Abstract: There is disclosed an organic optical recording medium with high data storage density, high data rates and long data archival capabilities, useful as a medium for recording a variety of information or pictures.In a preferred embodiment, the optical recording medium according to the present invention comprises a substrate, a reflective layer, a charge-generating layer containing at least one charge-generating material, a charge-transferring layer containing at least one charge-transferring material, a recording layer containing at least one electric field-discoloring element, a plurality of spacers, an air layer and a protective layer.A laser beam is absorbed to the charge-generating material contained in the charge-generating layer, to generate charges, which are subsequently transferred to the surface of the recording layer by the charge-transferring layer.With the influence of the charge generated, the illuminated area having the charges puts on a color different from that in the other areas.Type: GrantFiled: December 30, 1993Date of Patent: April 2, 1996Assignee: Cheil Synthetics Inc.Inventor: Hee T. Jung
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Patent number: 5500266Abstract: When a dye material layer is spin-coated on an optical storage medium of the type having grooves fabricated in a substrate thereof, the dye material layer surface has depressions in the vicinity of the grooves. These depressions have a profile which is a function of the distance from the center of the storage medium. To compensate for the radial dependence of the depressions, the geometry of the grooves is changed by varying the base dimension of the groove as a function of the distance from the center of the storage medium. In this manner, the difference in phase for radiation traversing the storage medium by an optical path that includes a groove as compared to an optical path that does not include an associated groove is constant as a function of distance from the center of the storage medium. The phase difference which is a constant as a function of distance from the center of the storage medium is important in the generation of signals used in tracking the groove.Type: GrantFiled: March 10, 1994Date of Patent: March 19, 1996Assignee: Eastman Kodak CompanyInventor: James E. Durnin
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Patent number: 5492744Abstract: An optical information recording medium is here disclosed which comprises a transparent substrate, a recording layer comprising an organic dyestuff on which information can be written by a laser beam, a reflective layer and a protective layer formed in this order on the substrate, the aforesaid optical information recording medium being characterized by containing a pit.edge control agent for the formation of recording pits, particularly a dyestuff thermal decomposition accelerator in the recording layer. By the addition of the pit.edge control agent, deviation properties and jitter properties can be remarkably improved, whereby a CD-R medium having a low error rate and good recording properties can be provided. In consequence, stable compatibility with a commercial CD player can be secured.Type: GrantFiled: December 1, 1993Date of Patent: February 20, 1996Assignees: Mitsui Toatsu Chemicals Incorporated, Yamamoto Chemicals, IncorporatedInventors: Tadashi Koike, Hideki Umehara, Yuji Inatomi, Takeshi Tsuda, Sumio Hirose
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Patent number: 5492772Abstract: A corrosion-resistant colored architectural material which is essentially lead free and is not highly reflective. The coating on the material is a two-phase metallic coating comprised of a large weight percentage of zinc and a relatively large weight percentage of tin. The tin-zinc coating may also include nickel. The tin-zinc composition provides for both a highly corrosive-resistant coating which protects the surface of the architectural material from oxidation and also produces a gray, earth tone colored which is not highly reflective.Type: GrantFiled: February 13, 1995Date of Patent: February 20, 1996Assignee: The Louis Berkman CompanyInventors: Jay F. Carey, II, Mehrooz Zamanzadeh
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Patent number: 5491036Abstract: A corrosion-resistant metal strip and method for making the same which is essentially lead free and is not highly reflective. The coating on the metal strip is a metallic coating comprised of tin and a very low weight percentage of lead. The coating alloy may also include antimony, bismuth, copper, zinc to improve the coating process and/or improve the properties of the tin coating. A metal layer may also applied to the surface of the metal strip prior to applying the metallic alloy coating.Type: GrantFiled: March 13, 1995Date of Patent: February 13, 1996Assignee: The Louis Berkman CompanyInventors: Jay F. Carey, II, Mehrooz Zamanzadeh
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Patent number: 5491035Abstract: A corrosion-resistant architectural material which is essentially lead free and is not highly reflective. The coating on the material is a two-phase metallic coating comprised of zinc and tin. The tin-zinc coating may also include aluminum, antimony, bismuth, copper, magnesium, nickel and/or titanium to improve the coating process and/or improve the properties of the tin-zinc coating.Type: GrantFiled: November 30, 1994Date of Patent: February 13, 1996Assignee: The Louis Berkman CompanyInventors: Jay F. Carey, II, Mehrooz Zamanzadeh
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Patent number: 5489490Abstract: A corrosion-resistant strip roofing material which is essentially lead free and is not highly reflective. The coating on the roofing material is a two-phase metallic coating comprised of a large weight percentage of tin and a relatively large weight percentage of zinc. The tin-zinc composition provides for both a highly corrosive-resistant coating which protects the surface of the roofing material from oxidation and also a gray surface coloring which is not highly reflective.Type: GrantFiled: November 17, 1994Date of Patent: February 6, 1996Assignee: The Louis Berkman CompanyInventors: Jay F. Carey, II, Mehrooz Zamanzadeh
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Patent number: 5486396Abstract: An optical recording medium comprises a substrate, a recording layer overlying the substrate in a manner such that it is not present at the inner and outer peripheral portions of the substrate, a metal reflective layer overlying the recording layer in a manner such that the inner periphery of the metal reflective layer is coterminous with that of the recording layer while the outer peripheral portion of the reflective layer extends over the outer perphery of the recording layer, and a protective layer wholly covering the metal reflective layer extending over the recording layer, both at the inner and outer peripheral portions. The optical recording medium exhibits an excellent adhesion strength of the protective layer even when stood under high humidity and high temperature conditions for a long period of time, and the protective layer is not peeled off when subjected to a tape peeling test.Type: GrantFiled: April 5, 1995Date of Patent: January 23, 1996Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Tadahiko Mizukuki, Kouichi Yabuuchi, Shinichi Murakami, Tomoyoshi Sasakawa, Kouhei Shizuka, Nobuhisa Kitagawa, Sumio Hirose
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Patent number: 5480731Abstract: Various metal coatings have been used for many years to inhibit oxidation of metals exposed to the natural elements of the atmosphere over a period of time. Terne alloy coatings which normally contain about 20% tin and about 80% lead are some of the most popular metal coating treatments to resist corrosion. The special formulation of the present invention reformulates the terne coating to constitute a tin and lead based coating where tin constitutes at least 90% of the terne and lead amounts to less than 0.1% and preferably less than 0.05% of the terne. The low lead terne coating may also include antimony and bismuth to provide strength and hardness to the low lead terne formulation having corrosion resistive qualities similar to that of standard terne coating formulations.Type: GrantFiled: January 30, 1995Date of Patent: January 2, 1996Assignee: The Louis Berkman CompanyInventors: Jay F. Carey, II, Mehrooz Zamanzadeh
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Patent number: 5478623Abstract: An optical recording medium is provided with: a light transmissive substrate; a recording film formed of an organic dye with 2,2,3,3-tetrafluoro-1-propanol having pH of not less than 6.0 as a solvent, on a surface of the substrate; a reflective film formed on a surface of the recording film; and a protection film formed on a surface of the reflective film.Type: GrantFiled: November 7, 1994Date of Patent: December 26, 1995Assignee: Pioneer Electronic CorporationInventors: Shingo Iwasaki, Taishi Tsuji, Takashi Chuman, Satoru Tanaka, Shuichi Yanagisawa, Fumio Matsui
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Patent number: 5474874Abstract: An optical recording medium has a transparent substrate with a recorded pattern formed thereon and a saturable absorption dye containing layer disposed on the recorded pattern and containing at least a saturable absorption dye. The saturable absorption dye has a molecular extinction coefficient .epsilon. of 10.sup.4 or greater at the wavelength of reproducing light, and a relaxation time .tau. in the range of 1 ns.ltoreq..tau..ltoreq. 100 ns. A reflecting layer having a reflectivity of 70% or higher on an air boundary thereof may be disposed on the saturable absorption dye containing layer. The saturable absorption dye containing layer may have such a thickness that substantially minimizes the intensity of reflected light due to interference with respect to the intensity of the reproducing light. The saturable absorption dye may comprise a naphthalocyanine-based dye.Type: GrantFiled: February 15, 1994Date of Patent: December 12, 1995Assignee: Sony CorporationInventors: Nobutoshi Asai, Kouichi Yasuda
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Patent number: 5474825Abstract: An optical recording medium has a substrate, a recording film of phthalocyanine coloring matter and provided on the substrate, a light reflection film on the recording film, and a protection film on the light reflection film. The light reflection film is made of Au and has a thickness less than 1500 .ANG..Type: GrantFiled: November 4, 1993Date of Patent: December 12, 1995Assignee: Pioneer Electric CorporationInventors: Makoto Okano, Shingo Iwasaki, Toshiyuki Miyadera, Fumio Matsui
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Patent number: 5470626Abstract: An optical recording element comprising, in the following order, a transparent substrate bearing an optical recording layer containing a phthalocyanine dye and a gold reflective layer characterized in that the recording layer comprises sufficient sulfur or sulfur compound to prevent defects in the gold reflective layer.Type: GrantFiled: February 21, 1995Date of Patent: November 28, 1995Assignee: Eastman Kodak CompanyInventors: James C. Fleming, Gerald R. Lange, Donald R. Preuss