Next To Fe-base Component (e.g., Galvanized) Patents (Class 428/659)
  • Patent number: 9994939
    Abstract: A high-strength galvanized steel sheet comprising a cold-rolled steel sheet, an intermetallic compound formed on the cold-rolled steel sheet, and a galvanizing layer formed on the intermetallic compound, the cold-rolled steel sheet having a specific composition and a microstructure having a martensite area ratio of 7% or more and less than 25% and a ferrite area ratio of 50% or more and which includes a base metal surface portion in which the amount of internal oxides per single side is 0.05 g/m2 or less.
    Type: Grant
    Filed: August 19, 2015
    Date of Patent: June 12, 2018
    Assignee: JFE STEEL CORPORATION
    Inventor: Yoshitsugu Suzuki
  • Patent number: 9988700
    Abstract: The present invention provides a high-strength steel sheet excellent in shape fixability. The high-strength steel sheet contains C, Si, Mn, P, S, Al, N, and O with predetermined contents, in which a retained austenite phase of 5 to 20% in volume fraction is contained, an amount of solid-solution C contained in the retained austenite phase is 0.80 to 1.00% in mass %, WSi? is 1.10 times or more WSi*, WMn? is 1.10 times or more WMn*, and when a frequency distribution is measured with respect to a sum of a ratio between WSi and WSi* and a ratio between WAl and WAl*, a mode value of the frequency distribution is 1.95 to 2.05, and a kurtosis is 2.00 or more.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: June 5, 2018
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Akinobu Minami, Hiroyuki Kawata, Akinobu Murasato, Yuji Yamaguchi, Natsuko Sugiura, Takuya Kuwayama, Naoki Maruyama, Takamasa Suzuki
  • Patent number: 9970092
    Abstract: A galvanized steel sheet includes a steel sheet and a plating layer on the surface of the steel sheet, in which the steel sheet includes, as a steel chemical composition, by mass %, C: 0.05 to 0.40%, Si: 0.5 to 3.0% and Mn: 1.5 to 3.0%, a microstructure of the steel sheet includes ferrite, bainite, by volume fraction, 30% or more of a tempered martensite, and 8% or more of an austenite, and tensile strength of the steel sheet is 980 MPa or more, and the plating layer includes an oxide including at least one chemical element selected from Si, Mn and Al, and when seen at a cross section including the steel sheet and the plating layer in a plate thickness direction, a projection area fraction of the oxide is 10% or more.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: May 15, 2018
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Takayuki Nozaki, Manabu Takahashi, Nobuhiro Fujita, Masafumi Azuma, Chisato Wakabayashi
  • Patent number: 9963771
    Abstract: A high-strength galvanized steel sheet comprising a cold-rolled steel sheet, an intermetallic compound formed on the cold-rolled steel sheet, and a galvanizing layer formed on the intermetallic compound, the cold-rolled steel sheet having a specific composition and a microstructure having a martensite area ratio of 7% or more and less than 25% and a ferrite area ratio of 50% or more and which includes a base metal surface portion in which the amount of internal oxides per single side is 0.05 g/m2 or less.
    Type: Grant
    Filed: August 19, 2015
    Date of Patent: May 8, 2018
    Assignee: JFE STEEL CORPORATION
    Inventor: Yoshitsugu Suzuki
  • Patent number: 9932659
    Abstract: A hot-dip galvanized steel sheet having a good appearance and good adhesion to a coating, the hot-dip galvanized steel sheet having a composition containing, on a mass basis: C: 0.08% or more and less than 0.20%, Si: 0.1% to 3.0%, Mn: 0.5% to 3.0%, P: 0.001% to 0.10%, Al: 0.01% to 3.00%, and S: 0.200% or less, a remainder being Fe and incidental impurities, wherein the hot-dip galvanized steel sheet includes an internal oxidation layer and a decarburized layer, the internal oxidation layer having a thickness of 5 ?m or less, the decarburized layer having a thickness of 20 ?m or less, and 50% or more by area of the internal oxidation layer is composed of a Si oxide containing Fe and/or Mn represented by Fe2XMn2-2XSiOY, wherein X ranges from 0 to 1, and Y is 3 or 4.
    Type: Grant
    Filed: September 11, 2014
    Date of Patent: April 3, 2018
    Assignee: JFE Steel Corporation
    Inventors: Minoru Tanaka, Yoshitsugu Suzuki, Yasunobu Nagataki
  • Patent number: 9914992
    Abstract: The present invention provides a process for manufacturing a metal strip having a metallic corrosion protection coating. The process includes making the metal strip pass through a bath of molten metal having between 2 and 8 wt. % aluminum, 0 to 5 wt. % magnesium and up to 0.3 wt. % addition elements, the balance being zinc and inevitable impurities. The bath is maintained at a temperature between 350 and 700° C. Nozzles wipe the coated metal strip spraying a gas on either side of the strip. The coating is cooled in a controlled manner until it has completely solidified. A metal strip and a metal part obtained by deformation of this strip are also provided.
    Type: Grant
    Filed: May 14, 2009
    Date of Patent: March 13, 2018
    Assignee: Arcelormittal Investigacion Y Desarrollo SL
    Inventors: Luc Diez, Jean-Michel Mataigne
  • Patent number: 9896737
    Abstract: A hot-rolled steel sheet consists of, in mass %, C: 0.03-0.2%, Mn: 0.1-3.0%, P: 0.10% or less, S: 0.03% or less, Al+Si: 0.2-3.0%, N: more than 0% to 0.01%, O: more than 0% to 0.01%, and balance: iron and impurities. A microstructure contains ferrite and hard phases of martensite and/or austenite in an amount of, in area fraction, 3% to less than 20%. Hard phases with an aspect ratio of 3 or more account for 60% or more of the hard phases present in a sheet-thickness central portion. A length in a rolling direction of the hard phases is less than 20 ?m. An average aspect ratio of ferrite grains is less than 5. The sum of X-ray random intensity ratios of <011> and <111> orientation from the rolling direction is 3.5 or more, and an X-ray random intensity ratio of <001> orientation from the rolling direction is 1.0 or less.
    Type: Grant
    Filed: July 13, 2015
    Date of Patent: February 20, 2018
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Hiroshi Shuto, Tatsuo Yokoi, Daisuke Maeda, Eisaku Sakurada, Takeshi Toyoda
  • Patent number: 9873934
    Abstract: A hot-dip galvanized steel sheet having a good appearance and good adhesion to a coating, the hot-dip galvanized steel sheet having a composition including, on a mass basis: C: 0.20% to 0.50%, Si: 0.1% to 3.0%, Mn: 0.5% to 3.0%, P: 0.001% to 0.10%, Al: 0.01% to 3.00%, and S: 0.200% or less, a remainder being Fe and incidental impurities, wherein the hot-dip galvanized steel sheet includes an internal oxidation layer and a decarburized layer, the internal oxidation layer having a thickness of 4 ?m or less, the decarburized layer having a thickness of 16 ?m or less, and 50% or more by area of the internal oxidation layer is composed of a Si oxide containing Fe and/or Mn represented by Fe2XMn2-2XSiOY, wherein X ranges from 0 to 1, and Y is 3 or 4.
    Type: Grant
    Filed: September 11, 2014
    Date of Patent: January 23, 2018
    Assignee: JFE Steel Corporation
    Inventors: Minoru Tanaka, Yoshitsugu Suzuki, Yasunobu Nagataki
  • Patent number: 9783878
    Abstract: Provided is a high-strength hot-dip galvanized steel sheet having excellent plating adhesion, formability, and hole expandability with an ultimate tensile strength of 980 MPa or more, the hot-dip galvanized steel sheet comprising a hot-dip galvanized layer formed on a surface of a base steel sheet. The base steel sheet contains, by mass %, C: 0.05% to 0.4 %; Si: 0.01% to 3.0%; Mn: 0.1% to 3.0%; Al: 0.01 to 2.0%; in which Si+Al >0.5%, P: limited to 0.04% or less; S: limited to 0.05% or less; N: limited to 0.01% or less; and a balance including Fe and inevitable impurities, a microstructure of the base steel sheet contains 40% or more by total volume fraction of martensite and bainite, 8% or more by volume fraction of residual austenite, and a balance of the microstructure being ferrite or ferrite and 10% or less by volume fraction of pearlite.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: October 10, 2017
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Chisato Wakabayashi, Masafumi Azuma, Nobuhiro Fujita, Kohichi Sano
  • Patent number: 9752221
    Abstract: A steel sheet which uses steel sheet which contains the easily oxidizable elements Si and Mn as a base material and which is provided with a hot dip galvanized layer which is excellent in plating wettability and plating adhesion and a method of production of the same are provided. A hot dip galvanized steel sheet which is comprised of a steel sheet having a hot dip galvanized layer A on the surface of the steel sheet, characterized by having the following B layer right under the steel sheet surface and in the steel sheet: B layer: Layer which has thickness of 0.001 ?m to 0.5 ?m, which contains, based on mass of the B layer, one or more of Fe, Si, Mn, P, S, and Al oxides in a total of less than 50 mass %, which contains C, Si, Mn, P, S, and Al not in oxides in C: less than 0.05 mass %, Si: less than 0.1 mass %, Mn: less than 0.5 mass %, P: less than 0.001 mass %, S: less than 0.001 mass %, and Al: less than 0.005 mass % and which contains Fe not in oxides in 50 mass % or more.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: September 5, 2017
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Soshi Fujita, Shintaro Yamanaka, Koichi Sato
  • Patent number: 9745654
    Abstract: Provided is a hot dip zinc alloy plated steel sheet which is widely used in vehicles, domestic appliances, construction materials or the like and a method for manufacturing the same. A Zn—Al—Mg hot dip zinc alloy plating bath is used for manufacturing the hot dip zinc alloy plated steel strip, and a small amount of Ga or In is added to the plating bath for inhibiting an oxidation reaction of Mg in the plating bath so as to obtain excellent corrosion resistance and external surface of the plated steel sheet which is manufactured at this point.
    Type: Grant
    Filed: July 23, 2013
    Date of Patent: August 29, 2017
    Assignee: POSCO
    Inventors: Min-Suk Oh, Young-Sool Jin, Sang-Heon Kim, Su-Young Kim, Bong-Hwan Yoo
  • Patent number: 9708703
    Abstract: A high-manganese hot-rolled galvanized steel sheet having no surface defects and improved galvanizing and alloying characteristics is manufactured by using a high-manganese hot-rolled steel sheet. Provided are the high-manganese hot-rolled galvanized steel sheet and a method of manufacturing the high-manganese hot-rolled galvanized steel sheet. The high-manganese hot-rolled galvanized steel sheet includes: a hot-rolled steel sheet including 5 wt % to 35 wt % manganese; and a zinc coating layer formed on the hot-rolled steel sheet, wherein an internal oxide layer is formed in an internal region of the hot-rolled steel sheet facing the zinc coating layer.
    Type: Grant
    Filed: December 27, 2012
    Date of Patent: July 18, 2017
    Assignee: POSCO
    Inventors: Sun-Ho Jeon, Kwang-Geun Chin
  • Patent number: 9631282
    Abstract: A method for depositing nickel-metal layers for colouring surfaces, and a bath for depositing such a layer. This is made possible by depositing a nickel-metal layer from a bath for the electroless deposition of nickel which contains at least one further metal compound, a voltage being additionally applied enable the metal of the metal compound to be incorporated while forming a nickel-metal layer.
    Type: Grant
    Filed: June 30, 2011
    Date of Patent: April 25, 2017
    Assignee: Schauenburg Ruhrkunststoff GmbH
    Inventor: Stefan Koppe
  • Patent number: 9499697
    Abstract: A coating composition is substantially free from chromate and comprises a resin, a metal salt, and an interference pigment. The interference pigment includes mica which has a solar reflective coating disposed thereon. A reflective coating system comprises a cured film formed from the coating composition disposed on a substrate. The cured film has a transparency of at least 75%, as measured according to ASTM 1746. In addition, the cured film has a solar reflectivity of at least 55%, as measured according to ASTM E 1918 and ASTM E 903. The cured film has excellent corrosion resistance properties and adhesion to the substrate.
    Type: Grant
    Filed: September 15, 2008
    Date of Patent: November 22, 2016
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Mark Slawikowski, Donald J. Algrim
  • Patent number: 9481148
    Abstract: The present invention provides a high-corrosion-resistance hot-dip galvanized steel sheet having excellent appearance uniformity. The steel sheet includes: a coating layer containing Al: 4 to 22 mass %, Mg: 1 to 6 mass %, and Si: 0.001 to 1 mass %, and a balance being composed of Zn and inevitable impurities formed on a surface, in which at an interface between the coating layer and a base steel sheet, Mg2Si phases and Ca phases each mainly composed of Ca or a Ca compound exist, and at least part of the Mg2Si phases precipitate by using the Ca phases as a nucleus.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: November 1, 2016
    Assignee: NIPPON STEEL AND SUMITOMO METAL CORPORATION
    Inventors: Takeshi Yasui, Tooru Oohashi, Nayuta Kawazu, Satoru Tanaka, Akio Saito
  • Patent number: 9333727
    Abstract: A steel manufacturing process can include forming an iron oxide layer on a hot band during hot rolling; reducing the iron oxide layer on the hot band to form a sponge iron layer that includes pores; the sponge-iron layer having a thickness in a range of about 0.05 ?m to about 1000 ?m, about 0.1 ?m to about 100 ?m, or about 5 ?m to about 25 ?m; and depositing an alloying element into the pores of the sponge iron layer to form an impregnated sponge-iron layer. The process can further include annealing the impregnated sponge-iron layer to produce an iron alloy layer carried by the substrate.
    Type: Grant
    Filed: October 31, 2013
    Date of Patent: May 10, 2016
    Assignee: Arcanum Alloy Design Inc.
    Inventor: Daniel E. Bullard
  • Patent number: 9315876
    Abstract: There is provided a useful method for producing a press-formed product without causing disadvantages such as hardness variation, which product has favorable formability in a level so as to be able to be produced by deep drawing, and which method is carried out by heating a thin steel sheet to a temperature not lower than an Ac3 transformation point thereof; and then cooling the thin steel sheet at a rate not lower than a critical cooling rate, during which the thin steel sheet is formed into the press-formed product, wherein the forming is started from a temperature higher than a martensitic transformation start temperature Ms thereof, the cooling rate is kept to be 10° C./sec. or higher during the forming, and the forming is finished in a temperature range not higher than the martensitic transformation start temperature Ms.
    Type: Grant
    Filed: September 30, 2011
    Date of Patent: April 19, 2016
    Assignee: Kobe Steel, Ltd.
    Inventors: Keisuke Okita, Junya Naitou, Shushi Ikeda
  • Patent number: 9309586
    Abstract: Provided is a method for manufacturing a high-strength galvanized steel sheet, made from a steel sheet containing Si and/or Mn, having excellent exfoliation resistance during heavy machining. When a steel sheet containing 0.01% to 0.18% C, 0.02% to 2.0% Si, 1.0% to 3.0% Mn, 0.001% to 1.0% Al, 0.005% to 0.060% P, and 0.01% or less S on a mass basis, the remainder being Fe and unavoidable impurities, is annealed and galvanized in a continuous galvanizing line, a temperature region with a furnace temperature of A° C. to B° C. (600?A?780 and 800?B?900) is performed at an atmosphere dew-point temperature of ?5° C. or higher in a heating process.
    Type: Grant
    Filed: March 30, 2010
    Date of Patent: April 12, 2016
    Assignee: JFE Steel Corporation
    Inventors: Yusuke Fushiwaki, Yoshiharu Sugimoto, Masahiro Yoshida, Yoshitsugu Suzuki
  • Patent number: 9284655
    Abstract: A method by which a steel component can be produced, which is provided with a metallic coating which adheres well and which provides protection against corrosion, from a flat steel product produced from a steel material containing 0.3-3 wt.-% manganese and having a yield point of 150-1100 MPa and a tensile strength of 300-1200 MPa coated with an anti-corrosion coating which comprises a coating of ZnNi alloy which is electrolytically deposited on the flat steel product, which coating is composed in a single phase of ?-ZnNi phase and which contains, as well as zinc and unavoidable impurities, 7-15 wt.-% nickel.
    Type: Grant
    Filed: February 24, 2010
    Date of Patent: March 15, 2016
    Assignee: ThyssenKrupp Steel Europe AG
    Inventors: Patrick Kuhn, Manfred Meurer, Jens Kondratiuk, Wilhelm Warnecke, Werner Schuler
  • Patent number: 9243315
    Abstract: Disclosed is a high-strength Zn—Al coated steel wire for bridges with excellent corrosion resistance and fatigue properties, the Zn—Al coated steel wire includes: a steel wire; and a Zn—Al coating having a coating body layer and an Fe—Al alloy layer formed in an interface between a surface layer of the steel wire and the coating body layer, wherein a chemical composition of a core material of the steel wire includes, by mass %: C: 0.70% to 1.2%; Si: 0.01% to 2.5%; Mn: 0.01% to 0.9%; P: limited to 0.02% or less; S: limited to 0.02% or less; N: limited to 0.01% or less; and the balance including Fe and unavoidable impurities, wherein wire-drawn pearlite is most abundant microstructure among microstructures of the core material of the steel wire; wherein an average composition of the Zn—Al coating includes, by mass %, Al: 3.0 to 15.0%; and Fe: limited to 3.0% or less, and wherein the Fe—Al alloy layer has a thickness of 5 ?m or less.
    Type: Grant
    Filed: June 23, 2010
    Date of Patent: January 26, 2016
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Nobuyuki Shimoda, Toshimi Tarui, Junichi Kodama, Makoto Kosaka, Shingo Yamasaki
  • Patent number: 9238848
    Abstract: A high-strength steel sheet includes, by mass %, C: 0.03% to 0.30%, Si: 0.08% to 2.1%, Mn: 0.5% to 4.0%, P: 0.05% or less, S: 0.0001% to 0.1%, N: 0.01% or less, acid-soluble Al: more than 0.004% and less than or equal to 2.0%, acid-soluble Ti: 0.0001% to 0.20%, at least one selected from Ce and La: 0.001% to 0.04% in total, and a balance of iron and inevitable impurities, in which [Ce], [La], [acid-soluble Al], and [S] satisfy 0.02?([Ce]+[La])/[acid-soluble Al]<0.25, and 0.4?([Ce]+[La])/[S]?50 in a case in which the mass percentages of Ce, La, acid-soluble Al, and S are defined to be [Ce], [La], [acid-soluble Al], and [S], respectively, and a microstructure includes 1% to 50% of martensite in terms of an area ratio.
    Type: Grant
    Filed: May 10, 2011
    Date of Patent: January 19, 2016
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Yoshihiro Suwa, Kenichi Yamamoto, Daisuke Maeda, Satoshi Hirose, Genichi Shigesato, Naoki Yoshinaga
  • Patent number: 9234268
    Abstract: The present invention provides a high-strength galvanized steel sheet with maximum tensile strength of 900 MPa or more. The high-strength galvanized steel sheet has an alloyed galvanized layer formed on a surface of a base steel sheet containing predetermined amounts of C, Si, Mn, P, S, Al, N, O with a balance being constituted of iron and inevitable impurities, in which in a structure of the base steel sheet, retained austenite is limited to 8% or less in volume fraction, kurtosis K* of the hardness distribution between 2% hardness and 98% hardness is ?0.30 or less, a ratio between Vickers hardness of surface layer of the base steel sheet and Vickers hardness of ¼ thickness of the base steel sheet is 0.35 to 0.70, and a content of iron in the alloyed galvanized layer is 8 to 12% in mass %.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: January 12, 2016
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Takuya Kuwayama, Shigeru Yonemura
  • Patent number: 9212428
    Abstract: The present invention provides a steel sheet for a container including a cold-rolled steel sheet and a composite film formed on the cold-rolled steel sheet through an electrolysis process in a solution containing: at least one metal ion of an Sn ion, an Fe ion, and an Ni ion; Zr ion; a nitric acid ion: and an ammonium ion, in which the composite film contains at least one element of: Zr of 0.1 to 100 mg/m2 in equivalent units of metal Zr; Sn of 0.3 to 20 g/m2 in equivalent units of metal Sn; Fe of 5 to 2000 mg/m2 in equivalent units of metal Fe; and Ni of 5 to 2000 mg/m2 in equivalent units of metal Ni.
    Type: Grant
    Filed: June 28, 2011
    Date of Patent: December 15, 2015
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Shigeru Hirano, Akira Tachiki, Hirokazu Yokoya, Morio Yanagihara, Makoto Kawabata
  • Patent number: 9206498
    Abstract: The invention deals with a hot-dip galvanized or galvannealed steel sheet wherein, the composition of the steel sheet comprises, by weight: 0.01?C?0.22%, 0.50?Mn?2.0%, 0.2?Si?3.0%, 0.005?Al?2.0%, Mo<1.0%, Cr?1.0%, P<0.02%, Ti?0.20%, V?0.40%, Ni?1.0%, Nb?0.20%, the balance of the composition being iron and unavoidable impurities resulting from the smelting, and the steel sheet comprises a layer of an internal nitride of at least one type of nitride selected from a Si nitride, Mn nitride, Al nitride, complex nitride comprising Si and Mn, or Al and Si, or Al and Mn, or complex nitride comprising Si, Mn and Al, said steel sheet comprising no further outer layer of iron nitride.
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: December 8, 2015
    Assignees: ArcelorMittal France, Nippon Steel & Sumitomo Metal Corporation
    Inventors: Jean-Michel Mataigne, Florence Bertrand
  • Patent number: 9194030
    Abstract: A high strength thin steel sheet that is mainly used for structural members and inner and outer panels for a vehicle, a galvanized steel sheet, and methods of manufacturing the same. The high strength thin steel sheet for superior press formability includes, by weight percent, 0.06 to 0.4% C, 1.0 to 5.0% Mn, 0.05 to 2.5% Si, 0.01 to 2.0% Ni, 0.02 to 2% Cu, 0.01 to 0.04% Ti, 0.05 to 2.5% Al, 0.005 to 0.1% Sb, 0.0005 to 0.004% B, 0.007% or less N, and balance Fe and inevitable impurities, and meeting relation of Ni+0.5×Mn+0.3×Cu>0.9, which is defined as Ni*, and Al/Ni*<1.3 at a same time, and relation of Ti?0.028×Al. This thin steel sheet is galvanized or galvannealed.
    Type: Grant
    Filed: September 1, 2008
    Date of Patent: November 24, 2015
    Assignee: POSCO
    Inventors: Jai Hyun Kwak, Kwang Geun Chin
  • Patent number: 9181614
    Abstract: One subject of the invention is a process for manufacturing a metal strip having a metal coating for corrosion protection, comprising the steps consisting in: making the metal strip pass through a bath of molten metal, comprising 0.2 to 8% by weight of aluminum and magnesium in the following proportions: 0.1 to 8% by weight of magnesium for an aluminum content equal to or greater than 0.2% but less than 4% by weight or a content greater than 5% but less than or equal to 8% by weight of magnesium for an aluminum content equal to or greater than 4% but less than or equal to 8% by weight, and comprising up to 0.
    Type: Grant
    Filed: May 7, 2010
    Date of Patent: November 10, 2015
    Assignee: ARCELORMITTAL INVESTIGACIÓN Y DESARROLLO, S.L.
    Inventors: Luc Diez, Jean-Michel Mataigne, Bertrand Orsal, Hubert Saint Raymond
  • Patent number: 9150946
    Abstract: The present invention provides hot dip galvanized high strength steel sheet excellent in plating adhesion and hole expandability and a method of production of the same, that is, hot dip galvanization steel sheet excellent in plating adhesion and hole expandability containing, by mass %, C: 0.08 to 0.35%, Si: 1.0% or less, Mn: 0.8 to 3.5%, P: 0.03% or less, S: 0.03% or less, Al: 0.25 to 1.8%, Mo: 0.05 to 0.35%, and N: 0.010% or less and having a balance of Fe and unavoidable impurities, said hot dip galvanized high strength steel characterized in that the steel sheet has a metal structure having ferrite, bainite, by area percent, 0.5% to 10% of tempered martensite, and, by volume percent, 5% or more of residual austenite, and a method of production comprising annealing by a continuous annealing process at 680 to 930° C. in temperature, then cooling to the martensite transformation point or less, then hot dip galvanizing the steel during which heating the steel to 250 to 600° C., then hot dip galvanizing it.
    Type: Grant
    Filed: February 14, 2011
    Date of Patent: October 6, 2015
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Hirokazu Taniguchi, Kenichiro Matsumura, Toshiki Hattori, Satoshi Kato
  • Patent number: 9080231
    Abstract: The present invention provides a hot-dipped steel 1 that demonstrates favorable corrosion resistance and formability, and has a favorable appearance of a plating layer. The hot-dipped steel of the present invention includes a steel substrate formed thereon with an aluminum-zinc alloy plating layer. The aluminum-zinc alloy plating layer contains Al, Zn, Si and Mg as constituent elements thereof and the Mg content is 0.1% to 10% by weight. The aluminum-zinc alloy plating layer contains 0.2% to 15% by volume of an Si—Mg phase, and the weight ratio of Mg in the Si—Mg phase to the total weight of Mg is 3% or more.
    Type: Grant
    Filed: February 17, 2011
    Date of Patent: July 14, 2015
    Assignees: NIPPON STEEL & SUMIKIN COATED SHEET CORPORATION, NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Shiro Fujii, Yoshikazu Yamanaka, Nobuki Shiragaki, Hiroshi Kanai, Nobuyuki Shimoda, Yasuhide Morimoto, Yoshihiro Suemune, Tooru Oohashi
  • Patent number: 9074275
    Abstract: A galvanized steel sheet includes a basal steel sheet (BSS) containing C: 0.01-0.15%, Si: 0.001-2.0%, Mn: 0.1-3.0%, Al: 0.001-1.0%, P: 0.005-0.060%, and S?0.01% (% by mass), balance Fe and unavoidable impurities, with zinc plating layers on both sides of the BSS. One or more oxides selected from Fe, Si, Mn, Al, and P oxides are in steel sheet superficial portions in direct contact with the zinc plating layers and extending from each surface of the BSS to 100 ?m deep. A crystalline oxide is in the regions from each surface of the BSS to 10 ?m depth, which are also located in direct contact with the zinc plating layers, the crystalline oxide including Fe crystal grains within which Si and Mn atoms are distributed in the regions from grain boundaries to 1 ?m deep inside the grain.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: July 7, 2015
    Assignee: JFE STEEL CORPORATION
    Inventors: Yusuke Fushiwaki, Yoshiharu Sugimoto
  • Publication number: 20150147589
    Abstract: A rolled steel sheet or blank is provided, the composition of which comprises the elements listed below in per cent by weight: C?0.1%; 0.5%?Mn?7%; 0.5%?Si?3.5%; 0.5%<Ti?2%; 2%<Ni?7%; Al?0.10%; Cr?2%; Cu?2%; Co?2%; Mo?2%; S?0.005%; P?0.03%; Nb?0.1%; V?0.1%; B<0.005%; N?0.008%, and the silicon and titanium contents are such that: Si + Ti ? 2.5 ? % , Ti Si ? 0.3 the remainder of the composition consisting of iron and unavoidable impurities resulting from processing. A method for the fabrication of a part for a land motor vehicle from the sheet or blank by hot stamping is also provided. The microstructure of the part consisting essentially of martensite and intermetallic precipitates of type Fe2TiSi with an area percentage between 1 and 5% intermetallic precipitates.
    Type: Application
    Filed: September 6, 2011
    Publication date: May 28, 2015
    Applicant: Arcelormittal Investigacion Y Desarrollo, S.L.
    Inventors: Olivier Bouaziz, David Barbier, Coralie Jung
  • Patent number: 9040169
    Abstract: Disclosed is a hot-dip galvanized steel sheet or an alloyed hot-dip galvanized steel sheet, which has a tensile strength of 980 MPa or more, excellent workability, high yield ratio and high strength. The hot-dip galvanized steel sheet or the alloyed hot-dip galvanized steel sheet is characterized by containing 0.12-0.3% by mass of C, 0.1% by mass or less (excluding 0% by mass) of Si, 2.0-3.5% by mass of Mn, 0.05% by mass or less (excluding 0% by mass) of P, 0.05% by mass or less (excluding 0% by mass) of S, 0.005-0.1% by mass of Al and 0.015% by mass or less (excluding 0% by mass) of N, with the balance made up of iron and unavoidable impurities. The hot-dip galvanized steel sheet or the alloyed hot-dip galvanized steel sheet is also characterized in that the metallic structure thereof contains bainite as a matrix structure, and the area ratio of ferrite is 3-20% and the area ratio of martensite is 10-35% relative to the entire structure.
    Type: Grant
    Filed: March 30, 2011
    Date of Patent: May 26, 2015
    Assignee: Kobe Steel, Ltd.
    Inventors: Kazuyuki Hamada, Tatsuya Asai
  • Patent number: 9040166
    Abstract: A hot-pressed member includes a steel sheet, a Ni-diffusion region present in a surface layer of the steel sheet, and an intermetallic compound layer and a ZnO layer which are provided in order on the Ni-diffusion region, the intermetallic compound layer corresponding to a ? phase present in a phase equilibrium diagram of a Zn—Ni alloy, wherein a spontaneous immersion potential indicated in a 0.5 M NaCl aqueous air-saturated solution at 25° C.±5° C. is ?600 to ?360 mV based on a standard hydrogen electrode.
    Type: Grant
    Filed: October 28, 2010
    Date of Patent: May 26, 2015
    Assignee: JFE STEEL CORPORATION
    Inventors: Hiroki Nakamaru, Seiji Nakajima, Tatsuya Miyoshi, Hiroyuki Masuoka, Shinji Ootsuka
  • Patent number: 9040168
    Abstract: The galvannealed steel sheet includes: a galvannealed layer formed on at least one surface of a steel sheet and contains includes an amount of 0.05 mass % to 0.5 mass % of Al, an amount of 6 mass % of 12 mass % of Fe, and the balance composed of Zn and inevitable impurities; and a mixed layer formed on a surface of the galvannealed layer and includes a composite oxide of Mn, Zn, and P and an aqueous P compound, wherein the composite oxide includes 0.1 mg/m2 to 100 mg/m2 of Mn, an amount of 1 mg/m2 to 100 mg/m2 of P, and Zn, and a P/Mn ratio is 0.3 to 50, and wherein the total size of an area of the mixed layer in which an attached amount of P is equal to or more than 20 mg/m2 is 20% to 80% of a surface area of the mixed layer.
    Type: Grant
    Filed: July 12, 2010
    Date of Patent: May 26, 2015
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Kazuhiko Honda, Noriyuki Suzuki, Yoichi Ikematsu
  • Patent number: 9040167
    Abstract: A flat steel product having a base layer of a steel material and a multilayer coating applied thereto, and a method for producing the flat steel product. The method having the following steps: providing a steel base layer; applying a zinc layer to the base layer by electrolytic coating; applying an aluminum layer to the surface of the zinc layer, wherein no treatment is made to the surface of the zinc layer in regard to the oxides and sulfides present thereon at the end of the electrolytic zinc coating step or occurring during the course of the aluminum coating step; applying a magnesium layer to the aluminum layer; and subsequently heat treating the flat steel product in such a way that an MgZn2 layer forms in the coating above the Al layer.
    Type: Grant
    Filed: May 20, 2010
    Date of Patent: May 26, 2015
    Assignee: ThyssenKrupp Steel Europe AG
    Inventors: Bernd Schuhmacher, Christian Schwerdt, Nicole Weiher, Richard Weinhold
  • Publication number: 20150140358
    Abstract: In a high strength hot-dip galvannealed hot-rolled steel sheet that has an excellent hole expansibility suitable for a stretch flanging and preferably has a high yield ratio and a tensile strength of at least 650 MPa, a hot-rolled steel sheet used as a base material for plating has a chemical composition comprising: in mass %, C: from at least 0.01 and at most 0.20%; Si: at most 0.50%; Mn: from at least 0.01% to at most 1.30%; P: at most 0.05%; S: at most 0.01%; N: at most 0.01%; Al: at most 0.50%; and Ti: from at least 0.05% to at most 0.50%, and a steel structure consisting of a polygonal ferrite having at least 80 area % and the remainder containing one kind or two or more kinds selected from bainitic ferrite, bainite, pearlite, and cementite.
    Type: Application
    Filed: September 11, 2012
    Publication date: May 21, 2015
    Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Takafumi Yokoyama, Shigeki Nomura
  • Patent number: 9034480
    Abstract: There is provided a hot-dip Al—Zn coated steel sheet that has a steel sheet containing Si and Mn as a base steel sheet and has excellent coating appearance and corrosion resistance. The Al—Zn coating layer has an Al content in the range of 20% to 95% by mass. The Al—Zn coating layer has a Ca content in the range of 0.01% to 10% by mass. Alternatively, the Ca and Mg content is in the range of 0.01% to 10% by mass. A steel sheet surface layer within 100 ?m from a surface of the base steel sheet directly under the Al—Zn coating layer contains 0.06 to 1.0 g/m2 per surface of an oxide of at least one selected from Fe, Si, Mn, Al, P, B, Nb, Ti, Cr, Mo, Cu, and Ni in total.
    Type: Grant
    Filed: November 25, 2011
    Date of Patent: May 19, 2015
    Assignee: JFE Steel Corporation
    Inventors: Masahiro Yoshida, Hiroki Nakamaru
  • Patent number: 9028973
    Abstract: A high strength galvanized steel sheet is provided comprising steel containing C: 0.06% or more and 0.20% or less, Si: less than 0.50%, Mn: 0.5% or more and less than 2.0%, P: 0.05% or less, S: 0.02% or less, Al: 0.60% or more and 2.00% or less, N: less than 0.004%, Cr: 0.10% or more and 0.40% or less and B: 0.003% or less, satisfying the relationships 0.8?Mneq?2.0 and Mneq+1.3[% Al]?2.8, and a microstructure containing a ferrite phase and a second phase whose volume fraction is 15% or less, the second phase having a martensite phase whose volume fraction is 3% or more, a retained austenite phase whose volume fraction is 3% or more and a sum of the volume fractions of a pearlite phase and a bainite phase being equal to or less than the volume fraction of the martensite phase and the volume fraction of the retained austenite phase.
    Type: Grant
    Filed: November 10, 2011
    Date of Patent: May 12, 2015
    Assignee: JFE Steel Corporation
    Inventors: Kenji Takahashi, Kaneharu Okuda, Yoshihiko Ono
  • Publication number: 20150125716
    Abstract: Provided is a method for producing a plated steel sheet with high Si content for hot stamping, which is capable of suppressing the generation of unplated portions, while maintaining high bonding strength in a welded part in cases where a galvanized steel sheet containing a large amount of Si, namely, 0.7% or more of Si is used for hot stamping applications. In this production method, a hot-rolled pickled steel sheet or cold-rolled steel sheet containing 0.10-0.5% by mass of C, 0.7-2.5% by mass of Si, 1.0-3% by mass of Mn, and 0.01-0.5% by mass of Al is annealed in a reducing atmosphere and then plated, thereby producing a galvanized steel sheet for hot stamping. This method for producing a galvanized steel sheet for hot stamping is characterized in that the annealing is carried out within the range of 500 to 700° C. for 30 to 270 seconds.
    Type: Application
    Filed: April 23, 2013
    Publication date: May 7, 2015
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventors: Takeshi Kojima, Hiroshi Irie, Takeshi Minowa
  • Patent number: 9023488
    Abstract: In order to provide a steel sheet for hot pressing from which a hot-pressed part excellent in perforation corrosion resistance is obtainable and a method of manufacturing a hot-pressed part using the steel sheet for hot pressing, provided is a steel sheet for hot pressing having, sequentially on a surface of a base steel sheet: a plating layer I containing 60% by mass or more of Ni and the remainder consisting of Zn and inevitable impurities, a coating mass thereof being 0.01 to 5 g/m2; and a plating layer II containing 10 to 25% by mass of Ni and the remainder consisting of Zn and inevitable impurities, a coating mass thereof being 10 to 90 g/m2.
    Type: Grant
    Filed: August 2, 2011
    Date of Patent: May 5, 2015
    Assignee: JFE Steel Corporation
    Inventors: Seiji Nakajima, Tatsuya Miyoshi, Hiroki Nakamaru
  • Publication number: 20150118518
    Abstract: A steel sheet for electroplating includes, by mass %, C: 0.0005% to 0.0050%, Si: 0.20% to 1.0%, Mn: 0.40% to 2.5%, P: 0.05% or less, Ti: 0.010% to 0.050%, Nb: 0.010% to 0.040%, B: 0.0005% to 0.0030%, S: 0.02% or less, Al: 0.01% to 0.30%, N: 0.0010% to 0.01%, and the balance including Fe and impurities, in which when Si content is represented by [Si] and Mn content is represented by [Mn], “[Mn]+5[Si]” is 2.0 to 7.0, and the steel sheet has surface property in which an average of displacements of a measurement point obtained based on a moving average of continuous 31 points in total including 15 front points and 15 back points in a cross-sectional profile of a surface obtained by measuring the average of displacements in an evaluation length of 10 ?m or more at an interval of 0.07 ?m, is 0.005 ?m to 0.10 ?m.
    Type: Application
    Filed: April 12, 2013
    Publication date: April 30, 2015
    Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Hironori Sato, Masao Kurosaki, Masahiro Fuda, Natsuko Sugiura, Yuji Yamaguchi
  • Publication number: 20150111064
    Abstract: Provided are: a high-strength hot-dip galvanized steel sheet in which bending workability of the high-strength hot-dip galvanized steel sheet is improved, and in which strength difference between a center part and end parts in the sheet width direction is reduced; and a method for manufacturing a high-strength hot-dip galvanized steel sheet. The steel sheet is a hot-dip galvanized steel sheet having a hot-dip galvanizing layer on a surface of a base steel sheet containing: C, Mn, P, S, and Al; Ti and B in amounts satisfying equation (1); and N; and Si as needed; the remainder comprising iron and unavoidable impurities; the metallographic structure of the base steel sheet having martensite, bainite, and ferrite, the ratios of each with respect to the overall metallographic structure being 50 area % or more of the martensite, 15-50 area % of the bainite, and 5 area % or less of the ferrite, 0.005×[Mn]+0.02×[B]1/2+0.025?[Ti]?0.15.
    Type: Application
    Filed: March 22, 2013
    Publication date: April 23, 2015
    Applicant: KABUSHIKI KAISHA KOBE SEIKO SHO(KOBE STEEL, LTD.)
    Inventors: Muneaki Ikeda, Masaaki Miura
  • Patent number: 9012031
    Abstract: To provide a steel fuel conveying pipe which has high resistance to corrosive fuel and maintains reliability without damaging a direct-injection engine, and connects a high-pressure pump and a direct-injection rail with each other in a gasoline direct-injection engine system, and a fuel conveying pipe suitable as a bypass pipe for coupling direct-injection rails with each other in a V-type gasoline engine. A steel fuel conveying pipe for conveying gasoline is characterized in that a Ni-plated layer is provided on the whole inner circumferential face of the fuel conveying pipe, and an anti-rust film layer composed of a Zn-plated layer and a Zn-based alloy-plated layer is further provided on the Ni-plated layer at at least one end of the fuel conveying pipe.
    Type: Grant
    Filed: July 5, 2011
    Date of Patent: April 21, 2015
    Assignee: Usui Kokusai Sangyo Kaisha Limited
    Inventor: Kazuo Takagi
  • Patent number: 9011614
    Abstract: A high-strength galvanized steel sheet has excellent mechanical properties such as a TS of 1200 MPa or more, an El of 13% or more, and a hole expansion ratio of 50% or more and a method for manufacturing the same. A high-strength galvanized steel sheet excellent in formability contains 0.05% to 0.5% C, 0.01% to 2.5% Si, 0.5% to 3.5% Mn, 0.003% to 0.100% P, 0.02% or less S, and 0.010% to 0.5% Al on a mass basis, the remainder being Fe and unavoidable impurities, and has a microstructure which contains 0% to 10% ferrite, 0% to 10% martensite, and 60% to 95% tempered martensite on an area basis as determined by structure observation and which further contains 5% to 20% retained austenite as determined by X-ray diffractometry.
    Type: Grant
    Filed: January 28, 2009
    Date of Patent: April 21, 2015
    Assignee: JFE Steel Corporation
    Inventors: Tatsuya Nakagaito, Saiji Matsuoka, Yoshitsugu Suzuki, Yuki Toji
  • Publication number: 20150099140
    Abstract: The invention relates generally to welding and, more specifically, to welding wires for arc welding, such as Gas Metal Arc Welding (GMAW) or Flux Core Arc Welding (FCAW). A disclosed tubular welding wire has a sheath and a core, and the tubular welding wire includes an organic stabilizer component, a rare earth component, and a corrosion resistant component comprising one or more of: nickel, chromium, and copper.
    Type: Application
    Filed: October 8, 2014
    Publication date: April 9, 2015
    Inventors: Mario Anthony Amata, Steven Edward Barhorst, Tre' Dorell Heflin-King
  • Publication number: 20150099139
    Abstract: A high strength hot rolled steel sheet with an excellent combination of tensile strength of at least 550 MPa and formability, including weight percent at most 0.15% of C, at most 0.5% of Si, between 0.5 and 2.0% of Mn, at most 0.06% of P, at most 0.008% of S, at most 0.1% of Al sol, at most 0.02% of N, between 0.02 and 0.45% of V, between 0.05 and 0.7% of Mo, optionally between 0.01 and 0.1% of Nb, balance of Fe and inevitable impurities, wherein the steel sheet has a precipitation strengthened and substantially single-phase ferritic microstructure, wherein the volume fraction of the ferrite phase in said microstructure is not lower than 97%, and wherein the precipitates in the microstructure comprise fine precipitates of composite carbides containing Mo and V and optionally Nb.
    Type: Application
    Filed: May 7, 2013
    Publication date: April 9, 2015
    Inventors: Rolf Arjan Rijkenberg, David Neal Hanlon
  • Patent number: 8999517
    Abstract: A steel pipe has a multi-layer coating including: a plating film formed on the surface of the steel pipe; a chemical conversion coating covering the plating film; a primer coating covering the chemical conversion coating and formed from a curable epoxy resin composition composed mainly of an epoxy compound and having an amide or imide bond introduced; and a polyamide resin coating covering the primer coating. The multi-layer coating can significantly enhance the adhesion force of the polyamide coating compared to the conventional pipe.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: April 7, 2015
    Assignee: Sanoh Kogyo Kabushiki Kaisha
    Inventors: Yoshihisa Tamura, Naoki Kawai
  • Patent number: 8993120
    Abstract: A hot-dip galvanizing layer or an alloyed hot dip galvanizing layer is formed on the surface of a base steel sheet in which in volume fraction, 40 to 90% of a ferrite phase and 5% or less of a retained austenite phase are contained, and a ratio of non-recrystallized ferrite to the entire ferrite phase is 50% or less in volume fraction, and further a grain diameter ratio being a value of, of crystal grains in the ferrite phase, an average grain diameter in the rolling direction divided by an average grain diameter in the sheet width direction is 0.75 to 1.33, a length ratio being a value of, of hard structures dispersed in island shapes, an average length in the rolling direction divided by an average length in the sheet width direction is 0.75 to 1.33, and an average aspect ratio of inclusions is 5.0 or less.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: March 31, 2015
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Hiroyuki Kawata, Naoki Maruyama, Akinobu Murasato, Akinobu Minami, Takeshi Yasui, Takuya Kuwayama, Hiroyuki Ban, Kaoru Hiramatsu
  • Publication number: 20150086808
    Abstract: A high-strength cold-rolled steel sheet has a specific chemical composition and has a steel microstructure meeting conditions: a total content of bainitic ferrite (BF) and tempered martensite (TM) is 65% (in area percent, hereinafter the same for steel microstructure) or more; a fresh martensite (M) content is 3% to 18%; a retained austenite content is 5% or more; and a polygonal ferrite (F) content is 5% or less. The steel sheet has a specific average KAM<1.00° of 0.50° or more and has a tensile strength of 980 MPa or more. The high-strength cold-rolled steel sheet excels in formability and shape fixability.
    Type: Application
    Filed: March 6, 2013
    Publication date: March 26, 2015
    Applicant: KABUSHIKI KAISHA KOBE SEIKO SHO (Kobe Steel, Ltd.)
    Inventors: Kouji Kasuya, Yuichi Futamura, Yukihiro Utsumi
  • Publication number: 20150079420
    Abstract: The steel for hot forming has the following composition in weight %: C: 0.10-0.25, Mn: 1.4-2.8, Si: ?1.0, Cr: ?1.0, Ti: ?0.05, Nb: ?0.05, V: ?0.1, Mo: ?0.1, Al: ?0.05, P: ?0.02, S: ?0.005, Ca: ?0.005, O: ?0.01, N: ?0.02, B: ?0.0004, the remainder being iron and unavoidable impurities. Also disclosed is a strip, sheet or blank produced with such a steel, a method for producing a hot formed product, such a product and the use thereof.
    Type: Application
    Filed: September 17, 2014
    Publication date: March 19, 2015
    Inventors: David Neal HANLON, Stefanus Matheus Cornelis VAN BOHEMEN
  • Publication number: 20150071811
    Abstract: A dual phase or complex phase steel strip showing no tigerstripes. The steel strip includes, in mass percent, the following elements: C 0.08-0.11%; Mn 1.70-2.20%; Si at most 0.1%; Cr 0.40-0.70%; Mo at most 0.3%; Ni at most 1.0%, Al 0.01-1.50%; Nb at most 0.07%; P equal to or more than 0.005%; N equal to or less than 0.015%; Ti equal to or less than 0.1%; V equal to or less than 0.1%; B equal to or less than 0.01%; wherein the sum of Cr, Mo and Ni is at least 0.5%; the balance being Fe and inevitable impurities.
    Type: Application
    Filed: April 5, 2013
    Publication date: March 12, 2015
    Inventors: Egbert Jansen, Edward Anton Frederik Span, Richard Mostert, Theo Arnold Kop