With Salt Or Acid Component Patents (Class 429/207)
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Publication number: 20110189539Abstract: A nonaqueous electrolyte composition includes: an electrolyte salt; a nonaqueous solvent; a matrix polymer; and a ceramic powder having a thermal conductivity of 50 W/m° C. or more.Type: ApplicationFiled: January 27, 2011Publication date: August 4, 2011Applicant: SONY CORPORATIONInventor: Masaki Machida
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Publication number: 20110189548Abstract: An electrochemical cell comprising a cathode comprising an electrode active material that reversibly intercalates and de-intercalates any of cations and molecules; an anode comprising an electrode active material that reversibly intercalates and de-intercalates any of cations, anions, and molecules; a separator material that separates the cathode from the anode; and an electrolyte comprising a base electrolyte composition, an ionic compound additive, and a solvent comprising any of aqueous and non-aqueous electrolyte solvents, wherein the additive dissolves in the base electrolyte composition as well a majority of the aqueous or non-aqueous electrolyte solvents, wherein the additive comprises a solubility of at least approximately 0.01 in the base electrolyte composition, wherein the additive dissociates into corresponding cations and anions upon dissolution, and wherein the cations originate from a metal element and reduce to an elemental form at a potential that is at least approximately 0.Type: ApplicationFiled: February 3, 2010Publication date: August 4, 2011Applicant: US Government as represented by Secretary of ARMYInventor: Kang Conrad Xu
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Publication number: 20110171539Abstract: The invention relates to a positive electrode/electrolyte pair for lithium batteries operating at a voltage above 4.2 V versus Li+/Li. The electrolyte of the lithium battery used in the invention includes at least a first additive chosen from optionally substituted, cyclic or acyclic, carboxylic or dicarboxylic anhydrides and carboxylic or dicarboxylic acids, and mixtures thereof, and optionally a second additive which is a lithium salt, the total content of additive(s) being greater than or equal to 0.01% by weight and less than or equal to 30% by weight, relative to the total weight of electrolyte, and the positive electrode is made of a material having a spinel structure. The lithium batteries of the invention are applicable in particular in the field of portable equipment, such as telephones, computers, camcorders, cameras and tooling.Type: ApplicationFiled: June 11, 2009Publication date: July 14, 2011Inventors: Sébastien Patoux, Carole Bourbon, Sébastien Martinet, Carole Pagano
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Publication number: 20110159379Abstract: An object of this invention is to provide a highly safe secondary battery employing a non-flammable electrolyte solution. The secondary battery has a positive pole comprising an oxide for storing and releasing lithium ions, a negative pole comprising a carbon material for storing and releasing lithium ions, and an electrolyte solution. The electrolyte solution comprises 1.5 mol/L or more of a lithium salt, or 1.0 mol/L or more of a lithium salt and 20% by volume or more of a phosphate ester derivative.Type: ApplicationFiled: September 11, 2009Publication date: June 30, 2011Applicants: NEC CORPORATION, NEC ENERGY DEVICES, LTD.Inventors: Kazuaki Matsumoto, Kentaro Nakahara, Shigeyuki Iwasa, Kaichiro Nakano, Koji Utsugi, Hitoshi Ishikawa, Shinako Kaneko
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Publication number: 20110151321Abstract: The present disclosure relates to energy storage or collection devices and methods for making such devices having electrode materials containing exfoliated nanotubes with attached electro- or photoactive nanoscale particles or layers. The exfoliated nanotubes and attached nanoscale particles or layers may be easily fabricated by methods such as coating, solution or casting or melt extrusion to form electrodes. Electrolytes may also be used for dispersing nanotubes and also in a polymeric form to allow melt fabrication methods.Type: ApplicationFiled: December 14, 2010Publication date: June 23, 2011Applicant: Designed Nanotubes, LLCInventors: Clive P. Bosnyak, Kurt W. Swogger
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Publication number: 20110143197Abstract: An electrode active material for a power storage device of the invention includes an organic compound having, in the molecule, a plurality of electrode reaction sites and a linker site. The electrode reaction sites are residues of a 9,10-phenanthrenequinone compound that contributes to an electrochemical redox reaction. The linker site is disposed between the plurality of electrode reaction sites, does not contain any ketone group, and does not contribute to the electrochemical redox reaction. The electrode active material for a power storage device of the present invention is inhibited from being dissolved in an electrolyte and has a high energy density. By using the electrode active material, it is possible to obtain a power storage device having a high energy density and excellent charge/discharge cycle characteristics.Type: ApplicationFiled: February 16, 2009Publication date: June 16, 2011Inventors: Yu Ohtsuka, Nobuhiko Hojo, Junichi Yoshida, Toshiki Nokami
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Publication number: 20110123870Abstract: An electrolyte for a rechargeable lithium battery, including a lithium salt, an organic solvent, lithium bis(oxalato)borate (LiBOB), and at least one kind of tris(trialkylsilyl)borate represented by following Chemical Formula 1. In the above Chemical Formula 1, R1 to R9 are the same as described in the detailed description.Type: ApplicationFiled: September 7, 2010Publication date: May 26, 2011Applicant: Samsung SDI Co., Ltd.Inventors: Mi-Hyeun OH, Jin-Sung Kim, Na-Rae Park, Su-Hee Han, Jin-Hyunk Lim
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Publication number: 20110117430Abstract: A rechargeable lithium battery includes a positive active material for intercalating and deintercalating lithium ions; a negative electrode including a negative active material for intercalating and deintercalating lithium ions; and a polymer electrolyte including a polymer, a non-aqueous organic solvent and a lithium salt. The rechargeable lithium battery has a battery capacity per unit area of the positive electrode from about 3.3 mAh/cm2 to about 2.8 mAh/cm2. The polymer includes a first monomer represented by the following Chemical Formula 1 and a second monomer represented by at least one of the following Chemical Formulae 2 to 7 at a weight ratio of about 85:15 to about 50:50 of the first monomer to the second monomer. In the above Chemical Formulae 1 to 7, each compound is as described in the detailed description.Type: ApplicationFiled: October 22, 2010Publication date: May 19, 2011Inventors: Kwang-Jo Cheong, Yong-Beom Lee, Hee-Sun Yun, Soo-Mi Eo
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Publication number: 20110117448Abstract: An object of the invention is to provide an inexpensive non-aqueous electrolyte secondary battery that allows reversible charge and discharge to be carried out. The non-aqueous electrolyte secondary battery according to the invention includes a positive electrode, a negative electrode containing carbon capable of storing and releasing potassium, and a non-aqueous electrolyte including potassium ions.Type: ApplicationFiled: January 20, 2006Publication date: May 19, 2011Inventors: Takao Inoue, Masahisa Fujimoto
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Publication number: 20110111306Abstract: A non-aqueous electrolyte solution for a lithium secondary battery includes a lithium salt and an organic solvent. Based on 100 parts by weight of the non-aqueous electrolyte solution, the non-aqueous electrolyte solution includes 1 to 5 parts by weight of sultone-based compound having a carbon-carbon unsaturated bond in a cyclic structure; 1 to 5 parts by weight of cyclic carbonate compound with a vinyl group; 5 to 10 parts by weight of cyclic carbonate compound that is substituted with halogen; and 1 to 5 parts by weight of dinitrile-based compound. This non-aqueous electrolyte solution improves stability of a SEI film formed on a surface of an anode of a lithium secondary battery and thus improves normal temperature cycle performance and high temperature cycle performance.Type: ApplicationFiled: April 24, 2009Publication date: May 12, 2011Applicant: LG CHEM, LTD.Inventors: So-Young Park, Hee-Gyoung Kang, Joon-Sung Bae
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Publication number: 20110111289Abstract: A rechargeable lithium battery includes a positive electrode including a current collector, a positive active material layer on the current collector and including a lithium manganese-based positive active material, and a protective layer on the positive active material layer and including a phosphite-based compound; a negative electrode; and an electrolyte coupled with the positive electrode and the negative electrode and including a lithium salt, a non-aqueous solvent, and an additive.Type: ApplicationFiled: July 20, 2010Publication date: May 12, 2011Inventors: Nam-Soon Choi, Sae-Weon Roh, Man-Seok Han, Sung-Soo Kim
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Publication number: 20110111290Abstract: A battery-dedicated electrode foil (32) includes an aluminum electrode foil (33) in which metal aluminum is exposed, and corrosion-resistant layers (34A, 34B) that are formed on surfaces (33a, 33b) of the aluminum electrode foil, and that are in direct contact with the metal aluminum that forms the aluminum electrode foil, and that is made of tungsten carbide.Type: ApplicationFiled: July 1, 2009Publication date: May 12, 2011Inventors: Yozo Uchida, Tadashi Teranishi
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Publication number: 20110104551Abstract: The present invention provides a composite material suitable for use in an anode for a lithium ion battery, the composite material comprising a layer of a lithium-alloying material on the walls of an aligned nanotubular base material. Preferably, the lithium-alloying material comprises a material selected from the group consisting of Si, Sn, Pb, Al, Au, Pt, Zn, Cd, Ag, Mg, and a combination of two or more of the foregoing.Type: ApplicationFiled: November 3, 2010Publication date: May 5, 2011Applicant: UCHICAGO ARGONNE, LLCInventors: Junbing YANG, Wenquan LU
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Patent number: 7923157Abstract: Disclosed is a lithium secondary battery comprising a cathode including a lithium-containing transition metal oxide, an anode including a carbon-based material, and a non-aqueous electrolyte with addition of a compound of formula (1). Incorporation of the compound (1) into the electrolyte significantly improves the high-temperature performance and cycle life characteristics of the battery.Type: GrantFiled: December 27, 2007Date of Patent: April 12, 2011Assignee: LG Chem, Ltd.Inventors: Jonghwan Kim, Jisang Yu, Jeong-Ju Cho, Hochun Lee, Joomi Jeon, Yongsu Choi, Ra Young Hwang
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Patent number: 7923147Abstract: A layered lithium-nickel-based compound oxide powder for a positive electrode material for a high density lithium secondary cell, capable of providing a lithium secondary cell having a high capacity and excellent in the rate characteristics also, is provided. A layered lithium-nickel-based compound oxide powder for a positive electrode material for a lithium secondary cell, characterized in that the bulk density is at least 2.0 g/cc, the average primary particle size B is from 0.1 to 1 ?m, the median diameter A of the secondary particles is from 9 to 20 ?m, and the ratio A/B of the median diameter A of the secondary particles to the average primary particle size B, is within a range of from 10 to 200.Type: GrantFiled: October 31, 2007Date of Patent: April 12, 2011Assignee: Mitsubishi Chemical CorporationInventor: Kenji Shizuka
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Publication number: 20110059372Abstract: To provide a positive electrode for a nonaqueous electrolyte secondary battery having excellent flexibility and capable of increasing the reliability and productivity, and a nonaqueous electrolyte secondary battery using the positive electrode. The positive electrode for a nonaqueous electrolyte secondary battery includes an active material layer that contains: a positive-electrode active material; a binder made of a fluorine-contained resin containing a vinylidene fluoride unit; and an electrolyte represented by one of the following general formulae (1) and (2): wherein M represents a metal element, R1 and R2 each represent fluorine or a fluorinated alkyl group having one to three carbon atoms and are identical to or different from each other, and n represents an integer of 1 to 3; wherein M represents a metal element, R3 represents a fluorinated alkylene group having two to four carbon atoms, and n represents an integer of 1 to 3.Type: ApplicationFiled: August 31, 2010Publication date: March 10, 2011Applicant: SANYO ELECTRIC CO., LTD.Inventors: Takanobu Chiga, Naoki Imachi
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Publication number: 20110059371Abstract: It is aimed at providing: a negative electrode material for a nonaqueous secondary battery, which has a higher capacity, is low in irreversible capacity upon initial charge and discharge, and has excellent cycle characteristics; and a nonaqueous secondary battery adopting the negative electrode material. The object is achieved by: a multi-layer structured carbonaceous material obtained by mixing graphitic carbon particles with an organic compound and by thermally treating the mixture, wherein loop structures are present at an edge portion of each of the graphitic carbon particles, and wherein the graphitic carbon particles have carbonized products of the organic compound affixed to surfaces of the particles, respectively, while maintaining the loop structures; and a nonaqueous secondary battery adopting the multi-layer structured carbonaceous material.Type: ApplicationFiled: February 2, 2009Publication date: March 10, 2011Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Tomiyuki Kamada, Kengo Okanishi, Keita Yamaguchi, Hideharu Satou, Hiroyuki Uono
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Publication number: 20110050178Abstract: In an embodiment of the invention, an electrolytic solution for a lithium battery including a cathode having a nickel (Ni)-cobalt (Co)-manganese (Mn)-based active material includes a nonaqueous organic solvent, a lithium salt, and adiponitrile. A lithium battery employs the electrolytic solution. A method of operating the battery includes charging the battery to a final charge voltage of about 4.25V or greater.Type: ApplicationFiled: October 16, 2009Publication date: March 3, 2011Inventors: Jin-Sung Kim, Mi-Hyeun Oh, Jin-Hyuk Lim, Su-Hee Han, Na-Rae Park
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Publication number: 20110052982Abstract: A non-aqueous electrolyte battery comprising a negative electrode containing a carbon material capable of doping and dedoping lithium ions as a negative electrode active material; a positive electrode containing a composite oxide of lithium and a transition metal as a positive electrode active material; and a non-aqueous electrolytic solution; wherein the non-aqueous electrolytic solution contains 0.001% by weight or more and 5% by weight or less of a diamine compound having two tertiary amino groups capable of interacting with a proton.Type: ApplicationFiled: August 27, 2010Publication date: March 3, 2011Inventor: Yuki WATANABE
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Publication number: 20110052999Abstract: An electrolyte includes an eutectic mixture composed of (a) a hetero cyclic compound having a predetermined chemistry figure, and (b) an ionizable lithium salt. An electrochemical device having the electrolyte. The eutectic mixture included in the electrolyte exhibits inherent characteristics of an eutectic mixture such as excellent thermal stability and excellent chemical stability, thereby improving the problems such as evaporation, ignition and side reaction of an electrolyte caused by the usage of existing organic solvents.Type: ApplicationFiled: December 30, 2008Publication date: March 3, 2011Applicant: LG CHEM, LTD.Inventors: Byoung-Bae Lee, Jae-Seung Oh, Ji-Won Park, Shin-Jung Choi, Jae-Duk Park, Dong-Su Kim, Hyo-Jin Lee
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Publication number: 20110045358Abstract: A non-aqueous electrolyte for a lithium battery includes a non-aqueous organic solvent, the organic solvent including one or more of a carbonate-based solvent, an ester-based solvent, an ether-based solvent, and/or a ketone-based solvent, a lithium salt, and a hexafluoroacetylacetone in an amount of about 0.02 parts by weight to about 10 parts by weight, based on 100 parts by weight of the non-aqueous organic solvent.Type: ApplicationFiled: October 19, 2010Publication date: February 24, 2011Applicant: PANAX ETEC CO., LTDInventors: Jung Kang OH, Young Jai CHO, Ho Seok YANG, Kab Youl LEE
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Publication number: 20110043965Abstract: The instant article of manufacture is made by applying optical energy to one or more layers of nanoparticulate materials under predetermined conditions to produce a nanostructure. The nanostructure has layers of optically fused nanoparticles including a predetermined pore density, a predetermined pore size, or both. The predetermined conditions for applying the optical energy may include a predetermined voltage, a predetermined duration, a predetermined power density, or combinations thereof.Type: ApplicationFiled: July 14, 2010Publication date: February 24, 2011Applicant: Applied Nanotech, Inc.Inventors: Zvi Yaniv, Nan Jiang, James P. Novak, Richard L. Fink
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Publication number: 20110039149Abstract: A battery is described. The battery includes an anode, a cathode, a separator disposed between the cathode and the anode, and an electrolyte. The cathode further includes manganese.Type: ApplicationFiled: August 14, 2009Publication date: February 17, 2011Inventors: Yichun Wang, James Joseph Cervera, Tatjana Mezini, Kirakodu S. Nanjundaswamy, Fan Zhang
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Publication number: 20110039150Abstract: A battery is described. The battery includes an anode, a cathode, a separator disposed between the cathode and the anode, and an electrolyte. The electrolyte further includes manganese. The manganese is selected from the group consisting of: cesium permanganate (CsMnO4), cesium manganate (Cs2MnO4), magnesium permanganate (Mg(MnO4)2), magnesium manganate (MgMnO4), silver manganate (Ag2MnO4), silver permanganate (AgMnO4), barium manganate (BaMnO4), and barium permanganate (Ba(MnO4)2).Type: ApplicationFiled: August 14, 2009Publication date: February 17, 2011Inventors: Yichun Wang, James Joseph Cervera, Tatjana Mezini, Kirakodu S. Nanjundaswamy, Fan Zhang
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Publication number: 20110027647Abstract: A battery including an electrolytic solution. The electrolytic solution including a compound having a sulfonyl group and at least one peak of ions is selected from the group consisting of Li3SO4+, Li3SO3+, Li2SO3+, and Li2SO2+ as a positive secondary ion and LiSO4?, LiSO3?, SO3?, and SO2? as a negative secondary ion is obtained by surface analysis of the anode using Time of Flight Secondary Ion Mass Spectrometry after charge and discharge.Type: ApplicationFiled: October 11, 2010Publication date: February 3, 2011Applicant: SONY CORPORATIONInventors: Hideki Nakai, Masayuki Ihara, Hiroyuki Yamaguchi
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Publication number: 20110020702Abstract: The present invention relates to iron-doped vanadium(V) oxides of formula FeyV2O5, a process for their preparation and their uses as positive electrodes, especially in microbatteries.Type: ApplicationFiled: April 10, 2008Publication date: January 27, 2011Applicant: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.)Inventors: Brigitte Pecquenard, Alain Levasseur, Astrid Gies
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Patent number: 7875386Abstract: The invention relates to an energy converter cell, consisting of a negative metal electrode, preferably a tin electrode, a positive electrode consisting of graphite and an electrolyte that is positioned between the electrodes and is in contact with the latter, the electrolyte containing in the charged state a manganate(IV) salt that is dissolved in water and an alkali hydroxide. The energy converter cell forms a galvanic element, which can be discharged by delivering electrical energy to an ohmic consumer resistor that is connected to the electrodes and can be charged by a supply of thermal energy. In addition, supplied electrical energy can be electrochemically stored in the cell.Type: GrantFiled: February 17, 2006Date of Patent: January 25, 2011Inventor: Werner Henze
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Publication number: 20110014517Abstract: Provided is a secondary battery containing polyalkyleneglycol diglycidylether represented by formula I added in a predetermined amount to an electrolyte for the battery. The secondary battery containing the above additive exhibits remarkably improved high-temperature characteristics, prevents deterioration in rate characteristics and cycle characteristics, and considerably reduces thickness swelling of the battery so as to prevent battery leakage, ultimately enhancing safety of the battery.Type: ApplicationFiled: November 7, 2008Publication date: January 20, 2011Applicant: LG Chem, LtdInventors: Suyoung Ryu, Dongmyung Kim, Eun young Kim
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Publication number: 20110014518Abstract: A secondary battery, a cathode, an anode, and an electrolyte are provided. For example, a secondary battery is provided including an anode; a cathode; and an electrolyte, wherein the anode includes an anode active material and a coat including a substance selected from the group consisting of metal barium and barium compounds.Type: ApplicationFiled: July 12, 2010Publication date: January 20, 2011Applicant: SONY CORPORATIONInventors: Hideki Nakai, Tomoyo Ooyama, Masayuki Ihara, Shunsuke Saito, Shinichi Katayama
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Publication number: 20110014523Abstract: An electrolyte includes a eutectic mixture composed of (a) an alkoxy alkyl group-containing amide compound having a specific chemistry formula; and (b) an ionizable lithium salt. The eutectic mixture contained in the electrolyte has excellent high temperature stability as well as inherent characteristics of eutectic mixtures such as excellent thermal stability and excellent chemical stability, so it contributes to improvement of high temperature stability and decrease the lowest limit of a electrochemical window. Thus, the electrolyte may be usefully applied to electrochemical devices using various anode materials.Type: ApplicationFiled: January 9, 2009Publication date: January 20, 2011Applicant: LG CHEM, LTD.Inventors: Ji-Won Park, Byoung-Bae Lee, Jae-Seung Oh, Shin-Jung Choi, Jae-Duk Park, Dong-Su Kim, Hyo-Jin Lee
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Publication number: 20110008675Abstract: Embodiments of the present invention are directed to electrode assemblies and secondary batteries using the same. The secondary battery includes an electrode assembly including a positive electrode having a positive active material, a negative electrode including a negative active material, and a separator between the positive and negative electrodes. The positive active material includes a lithium composite oxide represented by LiCO1?x?yMgxTiyO2 where 0.0056?x?0.0089, and 0.0029?y?0.0045. The electrode assembly and the lithium secondary battery including the same show good discharge efficiency even with increases in C-rate, and substantially prevent reductions in battery capacity resulting from battery deterioration, thereby improving battery lifespan.Type: ApplicationFiled: July 8, 2010Publication date: January 13, 2011Inventor: Seung-Beob Yi
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Publication number: 20110008683Abstract: The invention discloses a method of increasing the cycle life of rechargeable battery with a negative electrode (anode) made of lithium or lithium-containing alloys and electrolyte/salt solution which comprises one or more non-aqueous organic solvents and one or more lithium salts, the method comprising adding to the electrolyte/salt solution a lithium dendrite scavenging additive in an amount sufficient that a rate of lithium dendrite formation is equal to or lower than a rate of lithium dissolution occurring due to interaction with the dendrite scavenging additive dissolved in the electrolyte.Type: ApplicationFiled: September 20, 2010Publication date: January 13, 2011Inventors: Vladimir KOLOSNITSYN, Elena KARASEVA
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Publication number: 20110003201Abstract: An electricity storage material according to the present invention contains a copolymer compound of first units and second units, each first unit having a side chain which is an oxidation-reduction site having a it conjugate electron cloud and being of a structure represented by general formula (1) below, and each second unit having no oxidation-reduction reaction site as a side chain. In general formula (1), X1 to X4 are, independently, a sulfur atom, an oxygen atom, a selenium atom, or a tellurium atom; R1 and R2 are, independently, an acyclic or cyclic aliphatic group including at least one kind selected from the group consisting of a carbon atom, an oxygen atom, a nitrogen atom, a sulfur atom, a silicon atom, a phosphorus atom, and a boron atom, each including at least one or more double bonds; and one of R1 and R2 includes a bonding hand for binding to another portion which is a main chain or a side chain of the copolymer compound.Type: ApplicationFiled: June 25, 2009Publication date: January 6, 2011Inventors: Takafumi Tsukagoshi, Nobuhiko Hojo, Yu Ohtsuka
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Publication number: 20100330418Abstract: A polymer electrolyte comprises a first polymeric matrix, a second polymeric matrix, and a lithium salt. The first polymeric matrix comprises pores. The second polymeric matrix is disposed in at least some of the pores of the first polymeric matrix. The lithium salt is disposed in at least some of the pores of the first polymeric matrix.Type: ApplicationFiled: June 28, 2010Publication date: December 30, 2010Applicant: BYD Co. Ltd.Inventors: Shishuo Liang, Yong Luo, Zhengri Yu
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Publication number: 20100323241Abstract: An electrode structure for a lithium secondary battery including: a main active material layer including a metal powder selected from silicon, tin and an alloy thereof that can store and discharge lithium by electrochemical reaction, and a binder of an organic polymer; and a current collector. The main active material layer includes a powder of a support material for supporting the electron conduction of the main active material layer in addition to the metal powder and the powder of the support material are particles having a spherical, pseudo-spherical or pillar shape with an average particle size of 0.3 to 1.35 times the thickness of the main active material layer. The support material is one or more selected from graphite, oxides of transition metals and metals that do not electrochemically form alloy with lithium. Organic polymer compounded with a conductive polymer is used for the binder.Type: ApplicationFiled: August 25, 2010Publication date: December 23, 2010Applicant: CANON KABUSHIKI KAISHAInventors: Soichiro Kawakami, Akira Morita, Takao Ogura
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Publication number: 20100316898Abstract: A lithium-ion battery includes a positive electrode having a first active material and a second active material and a negative electrode including a third active material. The second active material includes a lithiated form of a material that does not include electrochemically cyclable lithium in the as-provided state.Type: ApplicationFiled: August 26, 2010Publication date: December 16, 2010Inventors: William G. Howard, Craig L. Schmidt, Erik R. Scott
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Publication number: 20100316908Abstract: A nonaqueous electrolyte secondary battery includes: a positive electrode; a negative electrode; a nonaqueous electrolyte containing an electrolyte salt; and a separator, wherein in the electrolyte salt, a molar fraction x of at least one member selected among electrolyte salts represented by the following formulae (1) and (2) occupying in the whole electrolyte salt satisfies a relationship of (0.5<x?1) LiPFaAc ??(1) LiBFbB?d ??(2) wherein a represents an integer of from 0 to 5; b represents an integer of from 0 to 3; each of A and B? independently represents CnF2n+1; n represents an integer of from 1 to 6; c represents an integer of 1 or more and satisfies a relationship of (a+c=6); and d represents a an integer of 1 or more and satisfies a relationship of (b+d=4).Type: ApplicationFiled: June 2, 2010Publication date: December 16, 2010Applicant: SONY CORPORATIONInventors: Kentaro Yoshimura, Masayuki Ihara, Tadahiko Kubota
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Publication number: 20100310944Abstract: Provided is a secondary battery electrolyte having improved high temperature properties and overcharge-prevention properties, particularly improved overcharge-prevention properties under high voltage/high current conditions, in conjunction with a minimized deterioration of the battery performance, by adding 3 to 5% 100 by weight of cyclohexyl benzene (CHB) and 0.2 to 1.5% by weight of 2-fluoro biphenyl (2-FBP) as overcharge-preventing additives to an electrolyte of a lithium secondary battery.Type: ApplicationFiled: September 21, 2007Publication date: December 9, 2010Applicant: LG Chem, Ltd.Inventors: Eun Ju Kang, Kyoung-won Kang, Hyang Mok Lee, Jung Kyu Woo
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Publication number: 20100304225Abstract: The invention relates to an electrolyte formulation comprising a) an ionic liquid which is electrochemically stable over a range of at least 4.5 V, has a viscosity of less than 300 mPa·s at 20° C. and has a conductivity of at least 1 mS/cm at 20° C., and b) an aprotic, dipolar solvent in an amount of 20 to 60% by volume based on the electrolyte formulation, wherein the conductivity of the electrolyte formulation is greater at least by a factor of 2 than the conductivity of the ionic liquid.Type: ApplicationFiled: May 28, 2008Publication date: December 2, 2010Applicant: EVONIK DEGUSSA GmbHInventors: Matthias Pascaly, Armin Modlinger, Martin Schuster, Roy Van Hal, Claus Hilgers, Marc Uerdingen
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Publication number: 20100297480Abstract: A lithium battery comprises at least a positive electrode containing a material whose lithium insertion and deinsertion potential is lower than or equal to 3.5 Volts in relation to the potential of the Li+/Li couple, a negative electrode and a non-aqueous electrolyte disposed between the positive and negative electrodes. The electrolyte comprises at least a lithium salt dissolved in an aprotic organic solvent wherein a polymerizable additive is added, chosen from carbazol and the derivatives thereof and being used to prevent the battery from operating as soon as the voltage at the terminal connections of the battery reaches a value resulting in polymerization of the additive.Type: ApplicationFiled: August 6, 2010Publication date: November 25, 2010Applicant: COMMISSARIAT A L'ENERGIE ATOMIQUEInventors: Audrey MARTINENT, Sébastien Martinet, Hélène Lignier, Djamel Mourzagh
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Publication number: 20100297496Abstract: The invention relates to a process for the preparation of a carbon-treated complex oxide having a very low water content and to its use as cathode material. The carbon-treated complex oxide is composed of particles of a compound AMXO4 having an olivine structure which carry, on at least a portion of their surface, a film of carbon deposited by pyrolysis. A represents Li, alone or partially replaced by at most 10% as atoms of Na or K. M represents Fe(II), alone or partially replaced by at most 50% as atoms of one or more other metals chosen from Mn, Ni and Co, and/or by at most 10% as atoms of one or more aliovalent or isovalent metals other than Mn, Ni or Co, and/or by at most 5% as atoms of Fe(III). X4 represents PO4, alone or partially replaced by at most 10 mol % of SO4 and SiO4. Said material has a water content <1000 ppm.Type: ApplicationFiled: October 30, 2007Publication date: November 25, 2010Inventors: Nathalie Ravet, Michel Gauthier, Thorsten Lahrs, Guoxian Liang, Christophe Michot
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Publication number: 20100291443Abstract: A cell suitable for use in a battery according to one embodiment includes a catalytic oxygen cathode; a stabilized zirconia electrolyte for selective oxygen anion transport; a molten salt electrolyte; and a lithium-based anode. A cell suitable for use in a battery according to another embodiment includes a catalytic oxygen cathode; an electrolyte; a membrane selective to molecular oxygen; and a lithium-based anode.Type: ApplicationFiled: May 12, 2010Publication date: November 18, 2010Inventor: Joseph C. Farmer
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Publication number: 20100291437Abstract: Provided are (1) a novel phenyl sulfonate compound, (2) a nonaqueous electrolytic solution comprising an electrolyte salt dissolved in a nonaqueous solvent and containing a phenyl sulfonate compound of the following general formula (II) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution, and (3) a lithium battery containing the nonaqueous electrolytic solution and excellent in low-temperature cycle property. (wherein X1 to X5 each independently represents a fluorine atom or a hydrogen atom, and from one to four of these are fluorine atoms; R2 represents a linear or branched alkyl group having from 1 to 6 carbon atoms, a linear or branched alkyl group having from 1 to 6 carbon atoms in which at least one hydrogen atom is substituted with a halogen atom, or an aryl group having from 6 to 9 carbon atoms).Type: ApplicationFiled: October 24, 2008Publication date: November 18, 2010Applicant: UBE INDUSTRIES, LTD.Inventors: Koji Abe, Kazuhiro Miyoshi
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Publication number: 20100283429Abstract: An electrochemical cell includes a cathode capable of reversibly releasing and receiving an alkali metal; an anode capable of reversibly releasing and receiving the alkali metal; and a non-aqueous electrolyte including one or more dissolved lithium salts, one or more nitriles, sulfur dioxide, and one or more other polar aprotic solvents.Type: ApplicationFiled: May 19, 2008Publication date: November 11, 2010Applicant: TIAX LLCInventors: David Ofer, Bookeun Oh
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Publication number: 20100279155Abstract: A rechargeable lithium-ion battery includes a positive electrode and a negative electrode that includes a lithium titanate active material. A separator is provided between the positive electrode and the negative electrode. The battery also includes an electrolyte and an electrolyte additive comprising at least one boroxine ring.Type: ApplicationFiled: April 30, 2009Publication date: November 4, 2010Inventors: Erik R. Scott, Gaurav Jain, Kevin W. Eberman
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Publication number: 20100273049Abstract: The invention relates to an electrode comprising (a) an electron collector containing one or more transition metals from the groups 4 to 12 of the Periodic Classification of the Elements, and (b) a material that is electrochemically active, present on the surface of the electron collector in the form of a nano-structured conversion layer containing nano-particles or agglomerates of said nano-particles, wherein the nano-particles have a mean diameter of between 1 and 1000 nm, preferably between 10 and 300 nm, wherein said electrochemically active material contains at least one compound of the transition metal or transition metals present in the electron collector, characterised by the fact that the electrode is a textile formed by metallic wires or fibres. The invention also relates to a half-accumulator and an accumulator containing such a textile electrode.Type: ApplicationFiled: May 18, 2007Publication date: October 28, 2010Applicant: Electricite de FranceInventors: Elodie Vidal, Stephane Lascaud
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Publication number: 20100273050Abstract: A negative electrode for a lithium secondary battery of the present invention includes a negative active material including a plate-shaped carbon powder particle agglomerated in a primary structure in which the plate-shaped particle is oriented in a plane direction and laminated. Fine carbon powder particles are then agglomerated to form a secondary structure on the surface of the primary structure such that the resulting particles include fine pores formed on the surface.Type: ApplicationFiled: July 7, 2010Publication date: October 28, 2010Inventors: Kyou-Yoon Sheem, Sang-Jin Kim, Joon-Sup Kim, Sung-Soo Kim, Yoshiaki Nitta, Sang-Min Lee, Han-Su Kim
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Patent number: 7816030Abstract: Electrodes and electrolytes for nickel-zinc secondary battery cells possess compositions that limit dendrite formation and other forms of material redistribution in the zinc electrode. In addition, the electrolytes may possess one or more of the following characteristics: good performance at low temperatures, long cycle life, low impedance and suitability for high rate applications.Type: GrantFiled: June 1, 2009Date of Patent: October 19, 2010Assignee: Powergenix Systems, Inc.Inventors: Jeffrey Phillips, Samaresh Mohanta
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Publication number: 20100261053Abstract: A storage battery is provided comprising a positive electrode of lead, a negative electrode of palladium, and an electrolyte consisting of an aqueous solution of a sulfate salt. Upon charging, lead is converted to lead dioxide and atomic hydrogen is absorbed by the palladium. During discharge, lead dioxide is reduced to the plumbous state and hydrogen is oxidized to hydrogen ions.Type: ApplicationFiled: April 14, 2009Publication date: October 14, 2010Inventor: John E. STAUFFER
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Publication number: 20100248025Abstract: Provided is a secondary battery exhibiting excellent durability. Also disclosed is an electrolyte possessing a porous particle, an ionic liquid and a supporting electrolyte salt, wherein the electrolyte has a dynamic elastic modulus of at least 105 Pa.Type: ApplicationFiled: March 22, 2010Publication date: September 30, 2010Applicant: KONICA MINOLTA HOLDINGS, INC.Inventors: Akiyoshi KIMURA, Emiko MIKOSHIBA