Abstract: A method of forming a graphene-based material includes: (1) treating a mixture including an etchant and graphene oxide sheets to yield formation of holey graphene oxide sheets; (2) dispersing the holey graphene oxide sheets in a re-dispersal solvent to yield a holey graphene oxide dispersion including the holey graphene oxide sheets; and (3) treating the holey graphene oxide dispersion under reducing conditions to yield self-assembly of the holey graphene oxide sheets into a graphene-based material.

Abstract: According to one embodiment, there is provided an active material. The active material includes a composite oxide having an orthorhombic structure. The composite oxide is represented by the general formula Ti2(Nb1-xTax)2O9 (0?x?1). The composite oxide has an average valence of niobium and/or tantalum of 4.95 or more.

Abstract: Provided is a Ni—Fe battery comprising an iron electrode which is preconditioned prior to any charge-discharge cycle. The preconditioned iron electrode used in the Ni—Fe battery is prepared by first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with an oxidant to thereby create an oxidized surface.

Abstract: A positive active material for a rechargeable lithium battery and a rechargeable lithium battery including the same are provided. The positive active material includes a lithium intercalation compound and a Si-containing TiO2 present on the surface of the compound. When TiO2 is present on the surface of the lithium intercalation compound, the rate characteristics and low temperature characteristics of batteries including the lithium intercalation compound may be improved. Further, when Si-containing TiO2 is present on the surface of the lithium intercalation compound, the cycle-life characteristic and high temperature storage characteristics of batteries including the lithium intercalation compound may be further improved, compared to batteries having only TiO2. As such, the positive active material including Si-containing TiO2 provides a rechargeable lithium battery having excellent rate capability, low temperature characteristics, cycle-life characteristics and high temperature storage characteristics.

Abstract: The present invention addresses the problem of providing an electrically conductive composition which can be used for producing an electric storage device such as a non-aqueous electrolyte secondary battery (e.g., a lithium ion secondary battery) having excellent electric conductivity during an ordinary operation and therefore having excellent battery output properties and the like and also having a function of increasing internal resistance when the internal temperature of the battery is increased, and which enables the production of an electric storage device such as a non-aqueous electrolyte secondary battery having excellent electric conductivity and safety-related functions.

Abstract: Provided is a method of producing multiple anode particulates, comprising: a) dispersing an electrically conducting material, primary particles of an anode active material, an optional electron-conducting material, and a sacrificial material in a liquid medium to form a precursor mixture; b) forming the precursor mixture into droplets and drying the droplets; and c) removing the sacrificial material or thermally converting the sacrificial material into a carbon material to obtain multiple particulates, wherein a particulate comprises one or a plurality of anode active material particles having a volume Va, an electron-conducting material, and pores having a volume Vp which are encapsulated by a thin encapsulating layer having a thickness from 1 nm to 10 ?m and a lithium ion conductivity from 10?8 S/cm to 5×10?2 S/cm and the volume ratio Vp/Va in the particulate is from 0.3/1.0 to 5.0/1.0.

Abstract: In an example of a method for making a sulfur-based positive electrode active material, a carbon layer is formed on a sacrificial nanomaterial. The carbon layer is coated with titanium dioxide to form a titanium dioxide layer. The sacrificial nanomaterial is removed to form a hollow material including a hollow core surrounded by a carbon and titanium dioxide double shell. Sulfur is impregnated into the hollow core.

Abstract: The present invention provides a novel carbon material comprising a three-dimensional graphene network constituting a plurality of cells interconnecting as a whole, where at least one of the cells has single-layer graphene wall. The carbon material is suitable for a lithium ion battery.

Abstract: An energy storage device including: an electrode assembly having a body portion and a first tab portion projecting from the body portion; and a container housing the electrode assembly, wherein a first current collector electrically connected to the first tab portion or the first tab portion, and the container have a swaged joint portion having a concavo-convex structure projecting toward the other side from one side.

Abstract: Provided are: a potassium ion secondary battery which is not susceptible to deterioration of charge/discharge capacity even if charging and discharging are repeated, and which has a long service life as a secondary battery; a potassium ion capacitor; a negative electrode for the potassium ion secondary battery; and a negative electrode for the potassium ion capacitor. A negative electrode for potassium ion secondary batteries and a negative electrode for potassium ion capacitors, each of which contains a carbon material that is capable of absorbing and desorbing potassium and a binder that contains a polycarboxylic acid and/or a salt thereof. A potassium ion secondary battery which is provided with the negative electrode or the capacitor. A binder for negative electrodes of potassium ion secondary batteries or negative electrodes of potassium ion capacitors, which contains a polycarboxylic acid and/or a salt thereof.

Abstract: A positive electrode for a lithium battery includes a lithium salt, a carbonaceous material, and a coating on a surface of the carbonaceous material, the coating including a polymer electrolyte including a hydrophilic material and a hydrophobic material, wherein a portion of the polymer electrolyte is anchored to the surface of the carbonaceous material by a chemical bond.

Abstract: The present invention relates to a method for preparing a lithium iron phosphate nanopowder, including the steps of (a) preparing a mixture solution by adding a lithium precursor, an iron precursor and a phosphorus precursor in a glycerol solvent, and (b) putting the mixture solution into a reactor and heating to prepare the lithium iron phosphate nanopowder under pressure conditions of 10 bar to 100 bar, and a lithium iron phosphate nanopowder prepared by the method. When compared to a common hydrothermal synthesis method and a supercritical hydrothermal synthesis method, a reaction may be performed under a relatively lower pressure. When compared to a common glycothermal synthesis method, a lithium iron phosphate nanopowder having effectively controlled particle size and particle size distribution may be easily prepared.

Abstract: A hybrid solid state electrolyte (SSE) can include a plurality of SSE particles suspended in a salt-in-solvent (SIS). A battery can include the hybrid SSE. The battery can be formed by at least forming the hybrid SSE in situ. Forming the hybrid SSE in situ can include: depositing, on a surface of an electrode of the battery, a mixture comprising the SSE particles and at least a portion of salt for the SIS; filling the battery with a solvent; and heating the battery to form the SIS by at least melting and/or dissolving the portion of the salt into the solvent.

Abstract: A positive electrode active material for a nonaqueous electrolyte secondary battery is used for a nonaqueous electrolyte secondary battery. The positive electrode active material includes a composite oxide containing at least lithium, nickel, and manganese and contains aggregated particles of primary particles having an average particle diameter of 1.0 ?m or more. The primary particles have a layered crystal structure and a spinel crystal structure.

Abstract: According to one embodiment, a nonaqueous electrolyte battery is provided. The nonaqueous electrolyte battery includes a positive electrode, a negative electrode including a negative electrode active material layer, a separator layer, an intermediate region, and a gel nonaqueous electrolyte. The separator layer and the intermediate region hold at least a part of the gel nonaqueous electrolyte. The nonaqueous electrolyte battery satisfies a volume ratio VA/VB of 5 or more. VA is a volume of the intermediate region. VB is an average volume of gaps among the particles of the niobium-and-titanium-containing composite oxide in the negative electrode active material layer.

Abstract: A composite material comprising graphene or reduced graphene oxide and a polymer-derived ceramic material, such as SiOC, is provided. The composite materials can be used to construct anodes (16), which can be used in batteries (10), particularly lithium ion batteries. The anodes exhibit relatively high charge capacities at various current densities. Moreover, the charge capacity of the anodes appears exceptionally stable even after numerous charging cycles, even at high current densities.

Abstract: An electrode material for a lithium ion battery including an active material represented by LiMPO4 (M is at least one selected from the group consisting of Fe, Mn, Co, Ni, Zn, Al, Ga, Mg, and Ca), in which an oil absorption amount for which diethyl carbonate is used (DEC oil absorption amount) is 50 cc/100 g or more and 80 cc/100 g or less, and a ratio (DEC/NMP) of the DEC oil absorption amount to an oil absorption amount for which N-methyl-2-pyrrolidinone is used (NMP oil absorption amount) is 1.3 or more and 1.8 or less.

Abstract: A method is provided for producing polyanionic positive electrode active material composite particles, which comprises: a step 1 wherein precursor composite granulated bodies, each of which contains a polyanionic positive electrode active material precursor particle in graphite oxide, are formed by mixing a polyanionic positive electrode active material precursor and graphite oxide; and a step 2 wherein the precursor composite granulated bodies obtained in step 1 are heated at 500° C. or higher in an inert atmosphere or in a reducing atmosphere. The maximum intensity of the X-ray diffraction peak based on the positive electrode active material is less than 50% of the maximum intensity of the X-ray diffraction peak based on the materials other than the positive electrode active material.

Abstract: A device and method of generating an electrical potential including an electrochemical cell, and at least one heat source, cooling source or both. The electrochemical cell includes an anode and a cathode connected by a polymer electrolyte layer, preferably a dry polymer electrolyte layer. The heat source, if present, is placed in direct thermal contact with one of the anode or cathode, while the cooling source, if present, is placed in direct thermal contact with one of the anode or cathode not in contact with the heat source. The resulting temperature differential between the anode and cathode induces a concentration gradient between the anode and the cathode generating the electrical potential.

Abstract: The present invention relates to a negative electrode including a multi-protective layer and a lithium secondary battery including the same, and the multi-protective layer prevents lithium dendrite growth on a surface of the electrode, and does not cause overpotential during charge and discharge since the protective layer itself does not function as a resistive layer, and therefore, is capable of preventing battery performance decline and securing stability when operating a battery.

Abstract: A zinc anode material for secondary cells includes zinc-containing particles that are coated with a coating composition containing at least one oxide of a metal selected from titanium, zirconium, magnesium, tin and yttrium. The surface localization ratio of the coating composition of Equation (1) ranges from 1.6 to 16. In Equation (1), the surface metal atomic ratio of the coating composition is represented by Equation (2), and the bulk metal atomic ratio of the coating composition is represented by Equation (3).

Abstract: The invention provides a nitrogen-doped graphene coated nano sulfur positive electrode composite material, a preparation method, and an application thereof. The composite material includes: an effective three-dimensional conductive network formed by overlapping of nitrogen-doped graphenes, and nano sulfur particles coated by nitrogen doped graphene layers evenly. The preparation method includes: dispersing nitrogen-doped graphenes in a liquid-phase reaction system including at least sulfur source and acid, and depositing nano sulfur particles by an in-situ chemical reaction of the sulfur source and the acid, thereby preparing the positive electrode composite material. The positive electrode composite material of the invention has a high conductivity, a high sulfur utilization rate, and a high rate, thereby restraining the dissolution and shuttle effect in the lithium sulfur batteries, and enhancing the cyclic performance of the batteries.

Abstract: Composite cathode materials are provided herein. Disclosed composite cathode materials include those comprising an aluminum borate coating. Systems making use of the cathode active materials are also described, such as electrochemical cells and electrodes for use in electrochemical cells. Methods for making and using the composite cathode materials are also disclosed.

Abstract: According to the present invention, a nonaqueous electrolyte secondary battery that includes a positive electrode, a negative electrode and a nonaqueous electrolyte is provided. The positive electrode has an operation upper limit potential of 4.3 V or more based on metal lithium and includes a positive electrode active material and an inorganic phosphate compound that has ion conductivity. The inorganic phosphate compound is in a particle state. A ratio of particles having a particle size of 20 ?m or more is 1% by volume or less when an entirety of the inorganic phosphate compound is set to 100% by volume. Further, a ratio of particles having a particle size of 10 ?m or more may be 10% by volume or less when an entirety of the inorganic phosphate compound is set to 100% by volume.

Abstract: A conductive sheet according to an aspect of the present invention includes a first nanostructure and a second nanostructure disposed to intersect each other. A thickness of an intersect region of the first nanostructure and the second nanostructure is 0.6 to 0.9 times the sum of thicknesses of non-intersection regions of the first nanostructure and the second nanostructure.

Abstract: According to one embodiment, a nonaqueous electrolyte battery including a negative electrode, a positive electrode, and a nonaqueous electrolyte is provided. The negative electrode contains a negative electrode active material. The positive electrode contains a positive electrode active material. The negative electrode active material contains a titanium-containing composite oxide. The positive electrode active material contains secondary particles of a first composite oxide and primary particles of a second composite oxide. The first composite oxide is represented by a general formula LiMn1?x?yMgxFeyPO4 (0<x?0.1, 0<y?0.3). The second composite oxide is represented by a general formula LiCo1?a?bNiaMnbO2 (0?a, b?0.5).

Abstract: The disclosure relates to a lithium storage element containing a positive electrode that contains a lithium compound other than an active material, a negative electrode, a separator, and a nonaqueous electrolytic solution containing lithium ions, for which an active material is applied on both surfaces of a nonporous positive electrode power collector, and a negative electrode active material capable of storing and releasing lithium ions is applied on both surfaces of a nonporous negative electrode power collector.

Abstract: A positive electrode material includes an active material represented by Li2Mn(1?2x)NixMoxO3 (where 0<x<0.4).

Abstract: A positive electrode active material for alkali-ion secondary batteries is provided which contains 20-55% of Na2O+Li2O, 10-60% of CrO+FeO+MnO+CoO+NiO, and 20-55% of P2O5+SiO2+B2O3 in terms of oxide-equivalent mol % and includes 50 mass % or more of an amorphous phase. According to the present invention, it is possible to provide a positive electrode active material for alkali-ion secondary batteries that enables high energy density and is excellent in the charge and discharge characteristics.

Abstract: Provided herein is a method for preparing a battery electrode based on an aqueous slurry. The method disclosed herein has the advantage that an aqueous solvent can be used in the manufacturing process, which can save process time and facilities by avoiding the need to handle or recycle hazardous organic solvents. Therefore, costs are reduced by simplifying the total process. In addition, the batteries having the electrodes prepared by the method disclosed herein show impressive energy retention.

Abstract: A rolled electrode assembly having a positive electrode plate and a negative electrode plate is housed in a prismatic outer body having as mouth together with non-aqueous electrolyte, and the mouth of the prismatic outer body is sealed by a sealing plate made of metal. The rolled electrode assembly is housed in the prismatic outer body, with the outer surface of the rolled electrode assembly covered by an insulating sheet except for the outer surface facing the sealing plate. The arithmetic mean roughness (Sa) of at least one surface of the insulating sheet disposed between the rolled electrode assembly and the prismatic outer body is 0.3 ?m or more.

Abstract: A lithium ion secondary battery includes a positive electrode including a positive electrode active material layer containing lithium iron phosphate, a negative electrode including a negative electrode active material layer containing graphite, and an electrolyte including a lithium salt and a solvent including ethylene carbonate and diethyl carbonate between the positive electrode and the negative electrode. When the battery temperature of the lithium ion secondary battery or the temperature of an environment in which the lithium ion secondary battery is used is T and given temperatures are T1 and T2 (T1<T2), in the case where T<T1, constant current charge is performed until voltage reaches a given value and then constant voltage charge is performed; in the case where T1?T<T2, only constant current charge is performed; and in the case where T2?T, charge is not performed.

Abstract: A layered composite composition having a general chemical formula of Li?-xADx(Mn?-y-?AlyNi?-?Co?-zAEDz)O2, wherein AD is an alkaline dopant for Li, AED is an alkaline earth dopant for Co or Ni, and Al is a dopant for Mn or Ni, and at least two of AD, AED, and Al are present in the composition, and the dopants, if present, are at an amount that does not result in the formation of new phase.

Abstract: A cathode material including an aggregate formed by aggregating active material particles, in which the active material particle is a particle including a cathode active material as a formation material and a carbonaceous material is provided on a surface of the particle, a ratio between a weight ratio of carbon contained in the aggregate to a BET specific surface area of the cathode material is in a range of 0.08 to 0.2, a tap density is in a range of 0.9 g/cm3 to 1.5 g/cm3, and an oil absorption amount for which N-methyl-2-pyrrolidone is used is 70 cc/100 g or less.

Abstract: The present invention aims to provide an electrode for lithium ion batteries which exhibits excellent electrical conductivity even if its thickness is large. The electrode for lithium ion batteries of the present invention includes a first main surface to be located adjacent to a separator of a lithium ion battery and a second main surface to be located adjacent to a current collector of the lithium ion battery. The electrode has a thickness of 150 to 5000 ?m. The electrode contains, between the first main surface and the second main surface, a conductive member (A) made of an electronically conductive material and a large number of active material particles (B). At least part of the conductive member (A) forms a conductive path that electrically connects the first main surface to the second main surface. The conductive path is in contact with the active material particles (B) around the conductive path.

Abstract: A NO2 gas sensing element includes an electrolyte, a reference electrode in contact with the electrolyte, and a sensing electrode selective to NO2 in contact with the electrolyte spaced apart from the reference electrode. The NO2 selective sensing electrode includes an oxide material comprising: (1) a mixed oxide according to the formula (Mn2-u-v-wCovMgwSiO4-u)+?(Mn3Al2Si3O12)+?(SiO2), wherein 0?(u+v+w)?2.0, 0???0.5, and 0???0.1; (2) a mixed oxide according to the formula (Mn2-x-y-zCoyMgzSiO4-x)+?(ZnO)+?(SiO2), wherein 0?(u+v+w)?2.0, 0???0.5, and 0???0.1; or combinations of mixed oxides (1) and (2).

Abstract: A preparation method of battery composite material includes steps of providing a manganese-contained compound, phosphoric acid, a lithium-contained compound, a carbon source, and deionized water; processing a reaction of the manganese-contained compound, the phosphoric acid, and a portion of the deionized water to produce a first product; placing the first product at a first temperature for at least a first time period to produce a first precursor, wherein the chemical formula of the first precursor is written by Mn5(HPO4)2(PO4)2(H2O)4; and processing a reaction of at least the first precursor, the lithium-contained compound, and another portion of the deionized water, adding the carbon source, and then calcining to produce battery composite material. Therefore, the preparation time is shortened, the energy consuming is reduced, the phase forming of the precursor is more stable, and the advantages of reducing the cost of preparation and enhancing the quality of products are achieved.

Abstract: A cathode active material includes a core capable of intercalating and deintercalating lithium ions; and a coating layer on at least a portion of the core, wherein the coating layer includes a composite including a metal oxide compound and a phosphate compound, the metal oxide compound is at least one compound selected from a lithium metal oxide and a metal oxide, the phosphate compound is at least one compound selected from a lithium phosphate, a lithium metal phosphate, and a metal phosphate, and a weight ratio of the metal oxide compound to the phosphate compound is from greater than 0 to about 1.

Abstract: A rechargeable lithium battery includes a negative electrode and a positive electrode, where a specific surface area per a unit area of the positive electrode is twice to seven times larger than a specific surface area per a unit area of the negative electrode. The rechargeable lithium battery has high rate capability and improved cycle-life characteristics.

Abstract: Provided herein are energy storage devices comprising a first electrode comprising a layered double hydroxide, a conductive scaffold, and a first current collector; a second electrode comprising a hydroxide and a second current collector; a separator; and an electrolyte. In some embodiments, the specific combination of device chemistry, active materials, and electrolytes described herein form storage devices that operate at high voltage and exhibit the capacity of a battery and the power performance of supercapacitors in one device.

Abstract: A negative electrode active material for an electricity storage device of the present invention includes TiO2, Na2O, and a network-forming oxide.

Abstract: A rechargeable battery cell having a specific combination of anode, cathode and electrolyte formulation is provided. The electrolyte formulation includes an additive system and a salt system. The additive system includes a first additive containing a sulfonyl group, an anti-gassing agent, and a second additive. The salt system includes a lithium salt and a co-salt. The disclosed electrolyte formulation has reduced gassing and improved performance over a wide temperature range.

Abstract: According to one embodiment, an electrode is provided. This electrode includes a current collector and an electrode layer formed on the current collector. The electrode layer contains an active material represented by LiMn1-x-yFexAyPO4 (where 0<x?0.3, 0?y?0.1, and A is at least one selected from the group consisting of Mg, Ca, Al, Ti, Zn, and Zr). A pore diameter appearing at highest frequency in pore diameter distribution of the electrode layer obtained by mercury porosimetry falls within a range of 10 nm to 50 nm. A pore specific surface area of the electrode layer is from 12 m2/g to 30 m2/g.

Abstract: A cathode material for a lithium-ion secondary battery includes a cathode material A which includes central particles of a cathode active material represented by LixAyMzPO4 and a carbonaceous film with which surfaces of the central particles are coated and a cathode material B which is represented by LixAyMzPO4 and is made of primary particles of a cathode active material having an olivine structure.

Abstract: An electrode for a lithium secondary battery including a silicon-based alloy having an expansion coefficient of 10% or greater and an electrochemically inactive whisker, and a lithium secondary battery using the electrode for a lithium secondary battery.

Abstract: The purpose of the present invention is to provide a positive-electrode active material for non-aqueous electrolyte secondary batteries that is capable of achieving both a high capacity and a high output. This positive-electrode active material contains a lithium-nickel composite oxide represented by the general formula: LibNi1-x-yCoxMyO2 wherein M represents at least one element selected from Al, Ti, Mn and W, b is 0.95?b?1.03, x is 0<x?0.15, y is 0<y?0.07, and x and y is x+y?0.16, wherein c-axis length of the lithium-nickel composite oxide is 14.185 angstrom or greater as determined by a Rietveld analysis of X-ray diffraction.

Abstract: Variations of the invention provide an improved aluminum battery consisting of an aluminum anode, a non-aqueous electrolyte, and a cathode comprising a metal oxide, a metal fluoride, a metal sulfide, or sulfur. The cathode can be fully reduced upon battery discharge via a multiple-electron reduction reaction. In some embodiments, the cathode materials are contained within the pore volume of a porous conductive carbon scaffold. Batteries provided by the invention have high active material specific energy densities and good cycling stabilities at a variety of operating temperatures.

Abstract: The present invention relates to a method for preparing a lithium iron phosphate nanopowder coated with carbon, including the steps of (a) preparing a mixture solution by adding a lithium precursor, an iron precursor and a phosphorus precursor in a glycerol solvent, (b) putting the mixture solution into a reactor and reacting to prepare amorphous lithium iron phosphate nanoseed particle, and (c) heat treating the lithium iron phosphate nanoseed particle thus to prepare the lithium iron phosphate nanopowder coated with carbon on a portion or a whole of a surface of a particle, and a lithium iron phosphate nanopowder coated with carbon prepared by the above method. The lithium iron phosphate nanopowder coated with carbon having controlled particle size and particle size distribution may be prepared in a short time by performing two simple steps.

Abstract: A positive active material for a rechargeable lithium battery includes a lithium intercalation compound; and lithium titanium oxide represented by Chemical Formula 1 on the surface of the lithium intercalation compound surface. Li4-xMxTiyO12-z.??Chemical Formula 1 In the Chemical Formula 1, 0<x?3, 1?y?5, ?0.3?z?0.3, and M is an element selected from Mg, Al, Ga, La, Tb, Gd, Ce, Pr, Nd, Sm, Ba, Sr, Ca, and combinations thereof.

Abstract: A multilayer electrode suitable for use in a secondary battery is disclosed. The major active component of one layer is different to a major active component of an adjacent layer. The use of layered electrodes improves both the capacity retention and cycle life of batteries including such layered electrodes.