Abstract: A nonaqueous electrolyte secondary battery disclosed in the present application includes: a positive electrode capable of absorbing and releasing lithium, containing a positive electrode active material composed of a lithium-containing transition metal oxide having a layered crystalline structure; and a negative electrode capable of absorbing and releasing lithium, containing a negative electrode active material composed of a lithium-containing transition metal oxide obtained by substituting some of Ti element of a lithium-containing titanium oxide having a spinel crystalline structure with one or more element different from Ti, wherein a retention of the negative electrode is set to be greater than a retention of the positive electrode, and an irreversible capacity rate of the negative electrode is set to be greater than an irreversible capacity rate of the positive electrode, whereby a discharge ends by negative electrode limitation.

Abstract: Electrochemical systems for harvesting heat energy, and associated electrochemical cells and methods, are generally described.

Abstract: An electrode for a battery includes a plurality of electrochemically active conversion-based particles coated by multilayer graphene, a plurality of carbon fibers, and a carbonaceous binder. The carbonaceous binder binds the active particles coated with the multilayer graphene to the plurality of carbon fibers. A battery containing the electrode and a method of making an electrode and a battery containing the electrode are also disclosed.

Abstract: To achieve a power storage unit that can be repeatedly bent without a large decrease in charge and discharge capacity. In the flexible power storage unit, the content of a binder in an active material layer containing an active material is greater than or equal to 1 wt % and less than or equal to 10 wt %, preferably greater than or equal to 2 wt % and less than or equal to 8 wt %, and more preferably greater than or equal to 3 wt % and less than or equal to 5 wt %.

Abstract: A positive electrode active material includes LiMn1?xMxPO4 (wherein M represents at least one element selected from Mg, Fe, Ni, Co, Ti, and Zr; and 0?x<0.5); and 0.03% by weight or more and not more than 0.5% by weight of S (sulfur) and 0.03% by weight or more and not more than 0.5% by weight of N (nitrogen) relative to the weight of LiMn1?xMxPO4.

Abstract: A positive electrode active material includes LiMn1-xMxPO4 (wherein M represents at least one element selected from Mg, Fe, Ni, Co, Ti, and Zr; and 0?x<0.5) and has an average pore diameter of 8 nm or more and not more than 25 nm and a total pore volume of 0.05 cm3/g or more and not more than 0.3 cm3/g.

Abstract: The present invention provides an electrode material in which unevenness in a supporting amount of a carbonaceous film is less when using an electrode-active material having a carbonaceous film on a surface thereof as the electrode material, and which is capable of improving conductivity, and a method for producing the electrode material. The electrode material includes an aggregate formed by aggregating an electrode-active material in which a carbonaceous film is formed on a surface. In the electrode material, an average particle size of the aggregate is 0.5 to 100 ?m, a volume density of the aggregate is 50 to 80 vol % of a volume density in a case in which the aggregate is a solid, and 80% or more of the surface of the electrode-active material is covered with the carbonaceous film. Alternatively, the electrode material includes an aggregate formed by aggregating electrode-active material particles in which a carbonaceous film is formed on a surface.

Abstract: According to one embodiment, a negative electrode active material for nonaqueous electrolyte battery includes a titanium oxide compound having a crystal structure of monoclinic titanium dioxide. When a monoclinic titanium dioxide is used as the active material, the effective capacity is significantly lower than the theoretical capacity though the theoretical capacity was about 330 mAh/g. The invention comprises a titanium oxide compound which has a crystal structure of monoclinic titanium dioxide and a (001) plane spacing of 6.22 ? or more in the powder X-ray diffraction method using a Cu-K? radiation source, thereby making an attempt to improve effective capacity.

Abstract: A cathode active material of the present invention is a cathode active material having a composition represented by General Formula (1) below, LiFe1-xMxP1-ySiyO4??(1), where: an average valence of Fe is +2 or more; M is an element having a valence of +2 or more and is at least one type of element selected from the group consisting of Zr, Sn, Y, and Al; the valence of M is different from the average valence of Fe; 0<x?0.5; and y=x×({valence of M}?2)+(1?x)×({average valence of Fe}?2). This provides a cathode active material that not only excels in terms of safety and cost but also can provide a long-life battery.

Abstract: A Li-ion battery is disclosed, the Li-ion battery including an anode, a cathode, a lithium donor formed from a Li-containing material, and an electrolyte in communication with the anode, the cathode, and the lithium donor. The lithium donor may be incorporated into the anode, incorporated into the cathode, a layer formed on either an anode side or a cathode side of a separator of the battery. The lithium donor is formed from Li-containing material insensitive to oxygen and aqueous moisture.

Abstract: A lithium-ion secondary battery allowed to improve cycle characteristics and initial charge-discharge characteristics is provided. The lithium-ion secondary battery includes a cathode; an anode; and an electrolytic solution. The anode includes an anode active material layer including a plurality of anode active material particles. The anode active material particles each include a core section and a coating section applied to a part or a whole of a surface of the core section, and the core section includes a silicon-based material (SiOx: 0?x<0.5) and the coating section includes an amorphous or low-crystalline silicon-based material (SiOy: 0.5?y?1.8).

Abstract: A positive electrode active material for a non-aqueous electrolyte secondary battery according to an embodiment of the present disclosure is represented by a general formula of Li,NiyM1-yO2 (where M includes at least one metal element selected from Co and Mn, 0.1?x?1.2, 0.3<y<1), has a volumetric average particle size (D50) of 7 ?m or more and 30 ?m or less, and has an average surface roughness of 4% or less.

Abstract: A sodium manganese composite oxide represented by Formula 1: NaxMayMnzMbvO2+d ??Formula 1 wherein, 0.2?x?1, 0<y?0.2, 0<z?1, 0?v<1, 0<z+v?1, ?0.3?d<1, Ma is an electrochemically inactive metal, and Mb is different from Ma and Mn, and is at least one transition metal selected from elements in Groups 4 to 12 of the periodic table of the elements.

Abstract: A power storage device including a positive electrode in which a positive electrode active material is formed over a positive electrode current collector and a negative electrode which faces the positive electrode with an electrolyte interposed therebetween is provided. The positive electrode active material includes a first region which includes a compound containing lithium and one or more of manganese, cobalt, and nickel; and a second region which covers the first region and includes a compound containing lithium and iron. Since a superficial portion of the positive electrode active material includes the second region containing iron, an energy barrier when lithium is inserted into and extracted from the surface of the positive electrode active material can be decreased.

Abstract: Provided is a lithium metal compound oxide having a layered structure, which is very excellent as a positive electrode active material of a battery that is mounted on, particularly, an electric vehicle or a hybrid vehicle. Suggested is a lithium metal compound oxide having a layered structure which is expressed by general formula of Li1+xM1?xO2 (M represents metal elements including three elements of Mn, Co, and Ni). In the lithium metal compound oxide having a layered structure, D50 is more than 4 ?m and less than 20 ?m, a ratio of a primary particle area to a secondary particle area of secondary particles having a size corresponding to the D50 (“primary particle area/secondary particle area”) is 0.004 to 0.035, and the minimum value of powder crushing strength that is obtained by crushing a powder using a microcompression tester is more than 70 MPa.

Abstract: A positive electrode composition is presented. The composition includes at least one electroactive metal; at least one alkali metal halide; and at least one additive including a plurality of nanoparticles, wherein the plurality of nanoparticles includes tungsten carbide. An energy storage device, and a related method for the preparation of an energy storage device, are also presented.

Abstract: A battery with the high capacity, the superior cycle characteristics, and the superior initial charge and discharge efficiency, and an anode active material used for it are provided. The anode active material contains at least tin, cobalt, carbon, and phosphorus as an element. A carbon content is from 9.9 wt % to 29.7 wt %, a phosphorus content is from 0.1 wt % to 2.2 wt %, and a cobalt ration to the total of the tin and the cobalt is from 24 wt % to 70 wt %.

Abstract: Disclosed is a powder comprising a lithium-containing compound and a nickel-containing mixed metal compound, and satisfying the following requirements of (1) and (2) when the powder is analyzed by plasma emission spectrometry of particles: (1) an absolute deviation of a synchronous distribution chart against an approximated straight-line is 0.10 or less, wherein the approximated straight-line is evaluated from a synchronous distribution chart obtained by plotting an emission intensity of lithium and an emission intensity of nickel of each particle composing of the powder, and (2) a release rate of lithium evaluated by the following formula is 80 or less: Release rate of lithium=(nb/na)×100 wherein, na is the number of particles containing lithium in the powder, and nb is the number of particles containing lithium and not containing nickel in the powder.

Abstract: An anode in which an anode active material layer is arranged on an anode current collector. The anode active material layer includes anode active material particles made of an anode active material including at least one of silicon and tin as an element. An oxide-containing film including an oxide of at least one kind selected from the group consisting of silicon, germanium and tin is formed in a region in contact with an electrolytic solution of the surface of each anode active material particle by a liquid-phase method such as a liquid-phase deposition method. The region in contact with the electrolytic solution of the surface of each anode active material particle is covered with the oxide-containing film, to thereby improve the chemical stability of the anode and the charge-discharge efficiency. The thickness of the oxide-containing film is preferably within a range from 0.1 nm to 500 nm both inclusive.

Abstract: According to one embodiment, a nonaqueous electrolyte battery including a positive electrode, a negative electrode, a separator, a copper-containing member, and a nonaqueous electrolyte is provided. The negative electrode includes a negative electrode current collector and a negative electrode active material-containing layer. The negative electrode current collector includes aluminum or aluminum alloy. The negative electrode active material-containing layer is formed on the negative electrode current collector. The copper-containing member includes copper or copper alloy. The copper-containing member is electrically connected to the negative electrode current collector to prevent from over-discharge.

Abstract: A rechargeable battery includes an iron electrode comprising carbonyl iron composition dispersed over a fibrous electrically conductive substrate. The carbonyl iron composition includes carbonyl iron and at least one additive. A counter-electrode is spaced from the iron electrode. An electrolyte is in contact with the iron electrode and the counter-electrode such that during discharge. Iron in the iron electrode is oxidized with reduction occurring at the counter-electrode such that an electric potential develops. During charging, iron oxides and hydroxides in the iron electrode are reduced with oxidation occurring at the counter-electrode (i.e., a nickel electrode or an air electrode).

Abstract: A cathodal material for lithium cells comprises a porous lithium oxide microparticle is provided. The porous lithium oxide microparticle comprises a plurality of porous lithium oxide nanoparticles formed with a first conductive layer therein, a pore defined by connecting the lithium oxide nanoparticles, a second conductive layer covering at least a surface of one of the lithium oxide nanoparticles contacting the first conductive layer and forming a three-dimensional conductive network between the lithium oxide nanoparticles, and a conductive fiber connecting with the second conductive layer.

Abstract: Disclosed are a cathode active material for high voltage and a lithium secondary battery including the same. More particularly, a cathode active material including spinel-type compound particles having a composition represented by Formula 1 below; and metal oxides or metal hydroxides present on surfaces of the spinel-type compound particles, and a lithium secondary battery including the same. Li1+aMxMn2?xO4?zAz ??(1) where a, x and z are defined in a specification of the present invention.

Abstract: The present disclosure provides a lithium-ion battery positive electrode material and a preparation method thereof.

Abstract: Disclosed herein is a high voltage cathode active material and a method for preparing the same. The cathode active material includes particles of a spinel-type compound having a composition represented by Formula (1) and a carbon-based material present on surfaces of the particles of the spinel-type compound: Li1+aMxMn2?xO4?zAz ??(1) where ?0.1?a?0.1, 0.3?x?0.8 and 0?z?0.1.

Abstract: To provide a power storage device including an electrode material having a large capacity. First heat treatment is performed on a mixture of a compound containing lithium; a compound containing a metal element selected from manganese, iron, cobalt, and nickel; and a compound containing phosphorus. A cleaning step is performed on the mixture subjected to the first heat treatment. Second heat treatment is performed on the mixture subjected to the cleaning step, so that a lithium phosphate compound is produced. With the use of the lithium phosphate compound, an electrode is formed.

Abstract: In a lithium-ion secondary battery (100), positive electrode active material particles (610) each include a shell portion (612) made of a layered lithium-transition metal oxide, a hollow portion (614) formed inside the shell portion (612), and a through-hole (616) penetrating through the shell portion (612). A positive electrode active material layer (223) has a density A of 1.80 g/cm3?A?2.35 g/cm3, and a negative electrode active material layer (243) has a density B of 0.95 g/cm3?B?1.25 g/cm3.

Abstract: A negative active material and a lithium battery including the same are disclosed. The negative active material includes a primary particle including a silicon nanowire formed on a non-carbonaceous conductive core to increase the capacity and cycle lifespan properties of the lithium battery.

Abstract: Provided is a Ni-Fe battery comprising a positive electrode, a negative electrode, electrolyte, and a polyolefin separator/inlay interposed between the positive and negative electrodes, with the separator/inlay having channels that allow movement of gas. In one embodiment, the separator/inlay has channels that exist in at least two planes.

Abstract: Provided is an anode active material including a transition metal-metaphosphate of Chemical Formula 1: M(PO3)2??<Chemical Formula 1> where M is any one selected from the group consisting of titanium (Ti), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), ruthenium (Ru), palladium (Pd), and silver (Ag), or two or more elements thereof. Since the anode active material of the present invention is stable and has excellent conversion reactivity while including only transition metal and phosphate without using lithium in which the price thereof is continuously increased, the anode active material of the present invention may improve capacity characteristics.

Abstract: Using metal foams for the electrode of secondary lithium battery, preparing method thereof, and secondary lithium battery including the metal foam. A metal foam is used in an electrode of secondary lithium battery where the surface and the inner pore walls are coated with the active materials, a method of manufacturing such metal foam, and secondary lithium battery including the metal foam.

Abstract: Provided is a nickel-iron battery comprising a positive electrode, a negative electrode, electrolyte, and a polymeric separator/inlay interposed between the positive and negative electrodes, with the separator/inlay having channels that allow movement of gas. In one embodiment, the separator/inlay has channels that exist in at least two planes. In one embodiment, the separator inlay is comprised of a polyester, polyamide, polyvinyl chloride or fluorocarbon polymer.

Abstract: A positive electrode for a rechargeable lithium ion battery includes a mixture layer including a positive-electrode active material, a conducting agent, and a binder and a collector having the mixture layer formed on the surface thereof. The positive-electrode active material is a composite oxide having an olivine structure expressed by a formula LiaMxPO4 (where M represents a transition metal including at least one of Fe and Mn and a and x satisfy 0<a?1.1 and 0.9?x?1.1). The conducting agent includes fibrous carbon. A carbon coating layer is formed on the surface of the collector. A part of the positive-electrode active material and a part of the fibrous carbon enter pits formed in the carbon coating layer.

Abstract: Provided are a cathode active material including lithium transition metal phosphate particles, wherein the lithium transition metal phosphate particles include a first secondary particle formed by agglomeration of two or more first primary particles, and a second secondary particle formed by agglomeration of two or more second primary particles in the first secondary particle, and a method of preparing the same. Since the cathode active material according to an embodiment of the present invention may include first primary particles and second primary particles having different average particle diameters, the exfoliation of the cathode active material from a cathode collector may be minimized and performance characteristics, such as high output characteristics and an increase in available capacity, of a secondary battery may be further improved. In addition, since the first secondary particles are porous, the secondary particles are collapsed and fractured due to rolling when used in a cathode.

Abstract: To provide an active material having high capacity and excellent cycle characteristics. An active material has a layered crystal structure and is expressed by a compositional formula (1) LiyNiaCobMncMdOx (1), where the element M is at least one kind of element selected from the group consisting of Al, Si, Zr, Ti, Fe, Mg, Nb, Ba, and V; 1.9?(a+b+c+d+y)?2.1; 1.05?y?1.35; 0<a?0.3; 0<b?0.25; 0.3?c?0.7; 0?d?0.1; and 1.9?x?2.1, and wherein 0.69?Ni?/Ni??0.85, where Ni? is the Ni composition amount at a center portion of the active material primary particle, and Ni? is the Ni composition amount in the vicinity of a surface (in a width of 30 nm from the surface).

Abstract: An electrode active material including an ordered mesoporous metal oxide; and at least one conductive carbon material disposed in a pore of the ordered mesoporous metal oxide. Also, an electrode including the electrode active material, and a lithium battery including the electrode.

Abstract: Compositions and methods of making compositions are provided for nitride- and/or oxide-modified electrode compositions. In certain embodiments, the nitride- and/or oxide-modified compositions have the general formula M1?zM?zOaF3?xNy. Such compositions may be used as bulk or surface compositions, and used in a battery as the anode or cathode. In other embodiments, the electrode includes a surface coating composition selected from metal nitrides and metal oxides, and a core composition having the formula M1?zM?zOaF3?x, or an oxide fluoride.

Abstract: An electrode-active material, a lithium-ion battery, and a method for detecting a discharge state of an electrode-active material that make it possible to realize high load characteristics, high cycle characteristics, and high energy density, have a high degree of safety and stability, and make it possible to easily detect the state of a late stage of discharge are disclosed. The electrode-active material is obtained by coating the surface of a particle containing LiwAxDO4 with a coating layer containing LiyEzGO4. In a discharge curve of the electrode-active material, a second region which follows a first region showing a substantially constant discharge potential and shows a drop in a discharge potential includes a third region in which a rate of change in a discharge potential is lower than an average rate of change in a discharge potential of the second region.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with an oxidant to thereby create an oxidized surface. The resulting iron electrode is preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: Provided is a novel negative electrode for nonaqueous electrolyte secondary batteries, which is capable of improving cycle characteristics and is also capable of suppressing aggregation of active material particles in a slurry. The negative electrode active material for nonaqueous electrolyte secondary batteries, which contains silicon and has a D50 of 0.1 ?m to 5 ?m, and the amount of water measured at 120° C. to 300° C. by the Karl-Fischer method (referred to as “amount of water”) per specific surface area (referred to as “CS”), that is, the amount of water/CS, of 0.1 to 80 ppm/(m2/cc).

Abstract: Provided is a Ni—Fe battery comprising an iron electrode which is preconditioned prior to any charge-discharge cycle. The preconditioned iron electrode used in the Ni—Fe battery is prepared by first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with an oxidant to thereby create an oxidized surface.

Abstract: A method is employed for producing a positive electrode active material for a lithium secondary battery that comprises mixing lithium phosphate having a particle diameter D90 of 100 ?m or less, an M element-containing compound having a particle diameter D90 of 100 ?m or less (where, M is one type or two or more types of elements selected from the group consisting of Mg, Ca, Fe, Mn, Ni, Co, Zn, Ge, Cu, Cr, Ti, Sr, Ba, Sc, Y, Al, Ga, In, Si, B and rare earth elements) and water, adjusting the concentration of the M element with respect to water to 4 moles/L or more to obtain a raw material, and producing olivine-type LiMPO4 by carrying out hydrothermal synthesis using the raw material.

Abstract: Provided is a Mn—Fe battery comprising an iron based electrode comprising a single layer of a conductive substrate coated on at least one side with a coating comprising an iron active material and a binder. The electrode can be prepared by continuously coating each side of the substrate with a coating mixture comprising the iron active material and binder.

Abstract: To provide a cathode active material for a lithium ion secondary battery, which has high packing properties and high volume capacity density, and a method for its production.

Abstract: Provided is a Mn—Fe battery comprising an iron based anode and a manganese cathode. The manganese cathode comprises a compressed metal foam substrate with the manganese active material present throughout the substrate. The metal foam substrate containing the manganese active material is also compression sized between about 42 and 45%.

Abstract: Disclosed are a negative active material for a rechargeable lithium battery including a silicon-based material including SiOx particles, where 0<x<2, and a Si—Fe-containing alloy positioned on the surface of the SiOx (0<x<2) particles, a method of preparing the same, and a negative electrode and a rechargeable lithium battery including the same.

Abstract: A negative electrode active material for lithium ion secondary batteries of the present invention includes a lithium-titanium composite oxide that has a composition represented by Li4Ti5-xFexO12 (where x satisfies 0<x?0.3) or Li4Ti5-yMnyO12 (where y satisfies 0<y?0.3) and that has an average particle diameter of primary particles which is not less than 1 ?m.

Abstract: A lithium iron phosphate hierarchical structure includes a plurality of lithium iron phosphate nano sheets and has an overall spherical-shaped structure. The overall spherical-shaped structure is constructed by a plurality of lithium iron phosphate nano sheets layered together. A method for making a lithium iron phosphate hierarchical structure includes several steps. In the method, a lithium ion contained liquid solution, a ferrous ion contained liquid solution, and a phosphate ion contained liquid solution are respectively provided. A concentration of lithium ions in the lithium ion contained liquid solution is equal to or larger than 1.8 mol/L. The lithium ion contained liquid solution, the ferrous ion contained liquid solution, and the phosphate ion contained liquid solution are mixed to form a liquid mixture. The liquid mixture is heated in a sealed reactor to form the lithium iron phosphate hierarchical structure.

Abstract: Provided is a cathode mix for lithium secondary batteries, comprising a cathode active material having a composition represented by the following Formula I: LiFe(P1-XO4) (I) wherein a molar fraction (1?x) of phosphorus (P) is in the range of 0.910 to 0.999, to allow operational efficiency of the cathode active material to be leveled to a lower operational efficiency of an anode active material and improve energy density of the cathode active material. The cathode mix maximizes operational efficiency of batteries, minimizes electrode waste and thus reduces manufacturing costs of batteries. Furthermore, The cathode active material, wherein a molar fraction (1?x) of phosphorus (P) is lower than 1, according to the present invention contains both Fe2+ and Fe3+, thus advantageously causing no structural deformation, improving ionic conductivity, exhibiting superior rate properties, inhibiting IR drop upon charge/discharge, thereby imparting high energy density to batteries.

Abstract: An electrochemical cell is presented. The electrochemical cell includes an elongated ion-conducting separator defining at least a portion of a first compartment; a positive electrode composition disposed in the first compartment, the positive electrode composition comprising at least one electroactive metal, at least one alkali metal halide, and at least one electrolyte. A positive current collector is further disposed in the first compartment such that a portion of the positive current collector extends into the positive electrode composition, and a primary dimension of the extended portion of the positive current collector is less than about 20% of a primary dimension of the first compartment. A related method for the preparation of an electrochemical cell is also presented.