Alkalated Cobalt (co) Chalcogenide Patents (Class 429/231.3)
  • Publication number: 20110305947
    Abstract: Disclosed are a positive active material for a lithium rechargeable battery and a lithium rechargeable battery using the same, and the positive active material is represented by the following Chemical Formula 1, and has an effective magnetic moment of about 2.4 ?B/mol or greater at a temperature of more than or equal to a Curie temperature. Chemical Formula 1: LiMeO2. In Chemical Formula 1, Me is NixCOyMnzM?k, 0.45?x?0.65, 0.15?y?0.25, 0.15?z?0.35, 0.9?a?1.2, 0?k?0.1, x+y+z+k=1, and M? is Al, Mg, Ti, Zr, or a combination thereof. The positive active material may have an a-axis lattice constant of the positive active material of about 2.865 ? or greater, and may have a c-axis lattice constant of the positive active material of about 14.2069 ? or greater. A mole ratio of Li to Me of Chemical Formula 1 may range from about 0.9 to about 1.2.
    Type: Application
    Filed: June 13, 2011
    Publication date: December 15, 2011
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Yu-Mi SONG, Do-Hyung PARK, Seon-Young KWON, Ji-Hyun KIM, Min-Han KIM, Kyoung-Hyun KIM
  • Patent number: 8066913
    Abstract: The present invention relates to Li—Ni composite oxide particles for a non-aqueous electrolyte secondary cell which have a large charge/discharge capacity, an excellent packing density and excellent storage performance. The Li—Ni composite oxide particles for a non-aqueous electrolyte secondary cell which have a composition represented by the formula: LixNi1-y-zCoyAlz02 in which 0.9<x<1.3; 0.1<y<0.3; and 0<z<0.3, wherein the composite oxide particles have a rate of change in specific surface area of not more than 10% as measured between before and after applying a pressure of 1 t/cm2 thereto, and a sulfate ion content of not more than 1.0%, can be produced by mixing Ni—Co hydroxide particles having a sulfate ion content of not more than 1.0% whose surface is coated with an Al compound having a primary particle diameter of not more than 1 ?m, with a lithium compound; and calcining the resulting mixture.
    Type: Grant
    Filed: June 5, 2009
    Date of Patent: November 29, 2011
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuhiko Kikuya, Osamu Sasaki, Teruaki Santoki, Hiroshi Yamamoto
  • Publication number: 20110287321
    Abstract: To provide a surface modified lithium-containing composite oxide having excellent discharge capacity, volume capacity density, safety, durability for charge and discharge cycles, and high rate property. A surface modified lithium-containing composite oxide, comprising particles of a lithium-containing composite oxide having a predetermined composition and a lithium titanium composite oxide containing lithium, titanium and element Q (wherein Q is at least one element selected from the group consisting of B, Al, Sc, Y and In) contained in the surface layer of the particles, wherein the lithium titanium composite oxide is contained in the surface layer of the particles in a proportion of the total amount of titanium and element Q in the lithium titanium composite oxide contained in the surface layer to the lithium-containing composite oxide particles is from 0.01 to 2 mol %, and the lithium titanium composite oxide has a peak at a diffraction angle 2? within a range of 43.8±0.
    Type: Application
    Filed: August 3, 2011
    Publication date: November 24, 2011
    Applicant: AGC Seimi Chemical Co., Ltd.
    Inventors: Remi HIRAKI, Takeshi Kawasato
  • Publication number: 20110281166
    Abstract: An electrode composition containing a first conducting agent and a second conducting agent, an electrode for lithium secondary batteries, a method of manufacturing the electrode, and a lithium secondary battery including the electrode. The second conducting agent is an agglomerate formed of a conducting material and a fluorine-based polymer.
    Type: Application
    Filed: December 30, 2010
    Publication date: November 17, 2011
    Inventors: Chae-Woong Cho, Woon-Suk Jang, Bum-Jin Chang, Ki-Jun Kim, Kwi-Seok Choi
  • Publication number: 20110281157
    Abstract: An electrode material is created by forming a thin conformal coating of metal oxide on a highly porous carbon meta-structure. The highly porous carbon meta-structure performs a role in the synthesis of the oxide coating and in providing a three-dimensional, electronically conductive substrate supporting the thin coating of metal oxide. The metal oxide includes one or more metal oxides. The electrode material, a process for producing said electrode material, an electrochemical capacitor and an electrochemical secondary (rechargeable) battery using said electrode material is disclosed.
    Type: Application
    Filed: July 25, 2011
    Publication date: November 17, 2011
    Inventor: Fraser W. SEYMOUR
  • Publication number: 20110281167
    Abstract: A high-performance and inexpensive thin film solid state lithium ion secondary battery that is able to be charged and discharged in the air and is able to be manufactured stably at a favorable yield, and a method of manufacturing the same are provided. The thin film solid state lithium ion secondary battery has an electric insulating substrate 10 formed from an organic resin, an inorganic insulating film provided on the substrate face, a cathode-side current collector film 30, a cathode active material film 40, a solid electrolyte film 50, an anode-side current collector protective film 68, and an anode-side current collector film 70. In the thin film solid state lithium ion secondary battery, the cathode-side current collector film and/or the anode-side current collector film is formed on the inorganic insulating film face.
    Type: Application
    Filed: January 28, 2010
    Publication date: November 17, 2011
    Applicant: SONY CORPORATION
    Inventors: Yuichi Sabi, Koichiro Hinokuma, Katsunori Takahara, Hiroyuki Morioka, Tatsuya Furuya
  • Publication number: 20110281173
    Abstract: Electrode assemblies for use in electrochemical cells are provided. The negative electrode assembly comprises negative electrode active material and an electrolyte chosen specifically for its useful properties in the negative electrode. These properties include reductive stability and ability to accommodate expansion and contraction of the negative electrode active material. Similarly, the positive electrode assembly comprises positive electrode active material and an electrolyte chosen specifically for its useful properties in the positive electrode. These properties include oxidative stability and the ability to prevent dissolution of transition metals used in the positive electrode active material. A third electrolyte can be used as separator between the negative electrode and the positive electrode.
    Type: Application
    Filed: November 6, 2009
    Publication date: November 17, 2011
    Applicant: SEEO, INC.
    Inventors: Mohit Singh, Ilan Gur, Hany Basam Eitouni, Nitash Pervez Balsara
  • Publication number: 20110274974
    Abstract: In one embodiment, a thin film solid state lithium ion secondary battery is able to be charged and discharged in the air and manufactured stably at a favorable yield. The thin film solid state lithium ion secondary battery has an electric insulating substrate formed from an organic resin, an inorganic insulating film provided on the substrate face, a cathode-side current collector film, a cathode active material film, a solid electrolyte film, an anode potential formation layer, and an anode-side current collector film. The cathode-side current collector film and/or the anode-side current collector film is formed on the inorganic insulating film face. The anode potential formation layer is a layer formed from the same material as that of the cathode active material film or a material different from that of the cathode active material film and is a layer provided for forming anode potential at the time of discharge.
    Type: Application
    Filed: January 28, 2010
    Publication date: November 10, 2011
    Applicant: SONY CORPORATION
    Inventors: Yuichi Sabi, Katsunori Takahara, Hiroyuki Morioka, Tatsuya Furuya, Koichiro Hinokuma, Reina Ichikawa, Yui Senda, Momoe Adachi
  • Publication number: 20110274973
    Abstract: The positive active material for a rechargeable lithium battery includes a composite material of a microporous carbon-based material and a lithium composite compound and a carbon layer on the surface of the composite material.
    Type: Application
    Filed: January 24, 2011
    Publication date: November 10, 2011
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Kyeu-Yoon SHEEM, Sumihito ISHIDA, Bok-Hyun KA
  • Patent number: 8053109
    Abstract: A non-aqueous electrolyte secondary battery has a high initial capacity and excels in cycle characteristics and storage characteristics even when charged until the potential of the positive electrode active material exceeds as high as 4.3V versus lithium. The non-aqueous electrolyte of the secondary battery contains both 1,3-dioxane and a sulfonic acid ester compound.
    Type: Grant
    Filed: November 14, 2008
    Date of Patent: November 8, 2011
    Assignees: Sanyo Electric Co., Ltd., Ube Industries, Ltd.
    Inventors: Masato Iwanaga, Noriko Yamashita, Koji Abe, Kazuhiro Miyoshi
  • Publication number: 20110269012
    Abstract: An electrochemical element includes at least one individual cell having electrodes arranged on a sheet-like separator, wherein the electrodes have been applied to the separator by at least one adhesive.
    Type: Application
    Filed: December 7, 2007
    Publication date: November 3, 2011
    Applicant: Varta Microbattery GmbH, a Corporation of Germany
    Inventors: Arno Perner, Thomas Woehrle, Markus Kohlberger, Rainer Hald, Markus Pompetzki, Peter Haug, Calin Wurm, Dejan Ilic
  • Patent number: 8048561
    Abstract: Process for the preparation of electrodes from a porous material making it possible to obtain electrodes that are useful in electrochemical systems and that have at least one of the following properties: a high capacity in mAh/gram, a high capacity in mAh/liter, a good capacity for cycling, a low rate of self discharge, and a good environmental tolerance.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: November 1, 2011
    Assignee: Hydro-Quebec
    Inventors: Karim Zaghib, Abdelbast Guerfi, Patrick Charest, Robert Kostecki, Kimio Kinoshita, Michel Armand
  • Publication number: 20110262796
    Abstract: A lithium secondary battery positive electrode according to the present invention is a lithium secondary battery positive electrode including a positive electrode material mixture layer containing a positive electrode active material and a conductivity enhancing agent on one or both sides of a current collector, wherein the positive electrode active material contains a lithium-containing composite oxide, the conductivity enhancing agent contains carbon fibers having an average fiber length of 10 nm or more and less than 1000 nm and an average fiber diameter of 1 nm or more and 100 nm or less, and the content of the carbon fibers in the positive electrode material mixture layer is 0.25 mass % or more and 1.5 mass % or less.
    Type: Application
    Filed: March 9, 2011
    Publication date: October 27, 2011
    Inventors: Toshiharu SHIMOOKA, Itaru Gosho, Akira Inaba, Masayuki Yamada, Kazutaka Matsuo, Satoshi Kono
  • Patent number: 8043387
    Abstract: A production method for a positive electrode for a nonaqueous electrolyte secondary battery that includes a positive electrode active material capable of intercalating and deintercalating a lithium ion, a conductive agent and a binder, in which the positive electrode active material is produced by coating cobalt-based lithium composite oxide represented by a general formula: LiaCO1-sM1sO2 with lithium nickel cobalt manganese oxide of general formula: LibNitCOuMnvO2, ratio r1/r2 of the average particle diameter r1 of the cobalt-based lithium composite oxide and the average particle diameter r2 of the lithium nickel cobalt manganese oxide being 2?r1/r2?50, and the average particle diameter r2 of the lithium nickel cobalt manganese oxide is 0.5 ?m?r2?20 ?m. A positive electrode produced by such method results in a nonaqueous electrolyte secondary battery having enhanced energy density and capacity and retention characteristic when charging/discharging is repeated at a high potential of 4.5 V based on lithium.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: October 25, 2011
    Assignee: Sanyo Electric Co., Ltd.
    Inventor: Hideki Morishima
  • Publication number: 20110256442
    Abstract: The present invention provides an electrode mixture, an electrode and a nonaqueous electrolyte secondary battery. The electrode mixture includes a lithium mixed metal oxide represented by formula (1): Liz(Ni1-x-yMnxMy)O2??(1), an electrically conductive material, and a water-dispersible polymeric binder, wherein x is 0.30 or more and less than 1, y is 0 or more and less than 1, x+y is 0.30 or more and less than 1, z is 0.5 or more and 1.5 or less, and M represents one or more members selected from the group consisting of Co, Al, Ti, Mg and Fe.
    Type: Application
    Filed: December 21, 2009
    Publication date: October 20, 2011
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Jun-ichi Kageira, Takitaro Yamaguchi
  • Publication number: 20110244330
    Abstract: An electrode for an electrochemical cell including a polymer substrate, a conductive material in contact with the polymer substrate, a conductive ink in contact with the conductive material, and an active electrode material in contact with the conductive ink. The conductive ink is configured to enhance the adhesion between the conductive material and the active electrode material.
    Type: Application
    Filed: April 13, 2011
    Publication date: October 6, 2011
    Inventors: Jeffrey L. Swoyer, Thomas J. Dougherty
  • Patent number: 8029930
    Abstract: A positive electrode material for a lithium secondary battery, which is high in safety, high in capacity, excellent in cycle performance, and high in charge/discharge efficiency, is provided. The positive electrode material for a lithium secondary battery is a powder containing a Li—Ni—Co—O or Li—Ni—Co—Ba—O system component as a main component and having an amorphous phase of an oxide mixed in each of particles or formed at the surface of the particle.
    Type: Grant
    Filed: November 17, 2003
    Date of Patent: October 4, 2011
    Assignee: Kawatetsu Mining Co., Ltd.
    Inventors: Yoshiaki Hamano, Hidefumi Konnai
  • Patent number: 8026002
    Abstract: A battery cathode including a current collector and a cathode material coated on and/or filled in the current collector, said cathode material including a cathode active substance, a conductive additive and an adhesive, wherein said cathode material is coated with a layer of lithium cobaltate on the surface thereof and the content of lithium cobaltate is 0.1-15 wt % (weight percent) based on the weight of the cathode active substance. The lithium ion battery using the cathode provided by the present invention has a higher specific capacity and improved cycling performance.
    Type: Grant
    Filed: April 20, 2006
    Date of Patent: September 27, 2011
    Assignee: BYD Company Limited
    Inventors: Qiang Rong, Zhanfeng Jiang, Huiquan Liu, Gang Hu, Meihong Sun
  • Patent number: 8026000
    Abstract: A nonaqueous electrolyte secondary battery of the invention has a positive electrode having a positive electrode active material, a negative electrode, and a nonaqueous electrolyte having electrolyte salt in a nonaqueous solvent. The electric potential of the positive electrode active material is 4.4 to 4.6 V relative to lithium, and the nonaqueous electrolyte contains a compound expressed by structural formula (I) below. The quantity of compound added is preferably 0.1% to 2% by mass. Also, the positive electrode active material preferably comprises a mixture of a lithium-cobalt composite oxide which is LiCoO2 containing at least both zirconium and magnesium and a lithium-manganese-nickel composite oxide that has a layer structure and contains at least both manganese and nickel. Thanks to such structure, a nonaqueous electrolyte secondary battery can be provided that is charged to charging termination potential of 4.4 to 4.6 V relative to lithium and that has enhanced overcharging safety.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: September 27, 2011
    Assignees: Sanyo Electric Co., Ltd., UBE Industries, Ltd.
    Inventors: Masato Iwanaga, Yukihiro Oki, Koji Abe, Kazuhiro Miyoshi
  • Publication number: 20110229758
    Abstract: A nonaqueous electrolyte battery includes a negative electrode including a current collector and a negative electrode active material having a Li ion insertion potential not lower than 0.4V (vs. Li/Li+). The negative electrode has a porous structure. A pore diameter distribution of the negative electrode as determined by a mercury porosimetry, which includes a first peak having a mode diameter of 0.01 to 0.2 ?m, and a second peak having a mode diameter of 0.003 to 0.02 ?m. A volume of pores having a diameter of 0.01 to 0.2 ?m as determined by the mercury porosimetry is 0.05 to 0.5 mL per gram of the negative electrode excluding the weight of the current collector. A volume of pores having a diameter of 0.003 to 0.02 ?m as determined by the mercury porosimetry is 0.0001 to 0.02 mL per gram of the negative electrode excluding the weight of the current collector.
    Type: Application
    Filed: June 2, 2011
    Publication date: September 22, 2011
    Inventors: Hiroki INAGAKI, Norio Takami
  • Publication number: 20110229762
    Abstract: The traditional method of building a CFx/current collector/SVO assembly is by the application of a static pressing force. However, the density of the electrode and, particularly the CFx component, can be increase by using a cyclic pressing protocol. That is where the active materials are formed into a blank or contacted to a current collector by the use of at least two pressing events separated by a period when the pressure is removed. Not only does this cyclic pressing protocol increase the density of the CFx material, it also provides an electrode that is relatively flat, and not cupped. Conventional pressing techniques often result in badly cupped electrodes, especially when disparate active materials are contacting opposite sides of the current collector. Cupping consequently reduces the effective volumetric energy density of the electrode or necessitates the addition of a process step of flattening of the cathode, if at all possible.
    Type: Application
    Filed: July 23, 2010
    Publication date: September 22, 2011
    Applicant: Greatbatch Ltd.
    Inventor: Ashish Shah
  • Patent number: 8021786
    Abstract: A non-aqueous electrolyte secondary cell superior in resistance against continuous charging at high potential is provided. The non-aqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material comprising lithium cobalt oxide containing at least one selected from Mg, Al, Ti, and Zr; and a separator having pores having an average diameter of 0.05 to 0.2 ?m.
    Type: Grant
    Filed: March 31, 2008
    Date of Patent: September 20, 2011
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Atsushi Kaiduka, Masato Iwanaga, Yukihiro Oki
  • Patent number: 8021785
    Abstract: Provided are a cathode active material with high safety, with high discharge capacity even at high operating voltage, and with excellent cyclic charge and discharge properties, its production method and a non-aqueous electrolyte secondary battery containing the cathode active material. The cathode active material for a non-aqueous electrolyte secondary battery comprises a surface-modified lithium-containing composite oxide particle, wherein the particle is a lithium-containing composite oxide particle represented by the general formula LipNxO2 (wherein N?NiyM1-y-zLz, M contains at least one element selected from Co and Mn, L is an element selected from alkaline earth metal elements, aluminum and transition metal elements other than Ni, Co and Mn, 0.9?p?1.1, 0.9?x<1.1, 0.2?y?0.9, and 0?z?0.3), and a surface layer of the particle contains aluminum, said surface layer within 5 nm having an aluminum content of at least 0.8 as an atomic ratio to a total of Ni and the element M.
    Type: Grant
    Filed: April 10, 2008
    Date of Patent: September 20, 2011
    Assignee: AGC Seimi Chemical Co., Ltd.
    Inventors: Yukimitsu Wakasugi, Takeshi Kawasato, Yukiko Amagasaki, Nozomi Honda
  • Patent number: 8021787
    Abstract: The preservation performance of a nonaqueous electrolyte secondary cell charged to high potential is improved while the initial capacity and the cycle property of the cell are also improved. The nonaqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material containing lithium cobalt compound oxide and lithium manganese nickel compound oxide having a layer structure, the lithium cobalt compound oxide having at least zirconium and magnesium added in LiCoO2; a negative electrode having a negative electrode active material; and a nonaqueous electrolyte having a nonaqueous solvent and an electrolytic salt. The potential of the positive electrode is more than 4.3 V and 5.1 V or less based on lithium. The nonaqueous electrolyte contains vinylene carbonate as the nonaqueous solvent and, as the electrolytic salt, at least one of lithium bis(pentafluoroethane sulfonyl)imide and lithium bis(trifluoromethane sulfonyl)imide at 0.1 M or more and 0.
    Type: Grant
    Filed: May 30, 2007
    Date of Patent: September 20, 2011
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Masato Iwanaga, Kentaro Takahashi, Yukihiro Oki, Yoshihiko Ikeda, Akira Kinoshita, Nobumichi Nishida
  • Publication number: 20110223487
    Abstract: An electrochemical cell has an anode of electrochemically-active material; a cathode of electrochemically-active, porous, liquid-permeable, sintered, ceramic material; and a solid-state, liquid-impermeable electrolyte medium disposed between the anode and the cathode. The electrolyte may be a layer of glass or a layer of glass ceramic, or may be a combination of a layer of glass and a layer of glass ceramic. The cell may further contain a liquid electrolyte diffused throughout the cathode.
    Type: Application
    Filed: March 2, 2011
    Publication date: September 15, 2011
    Applicant: EXCELLATRON SOLID STATE LLC
    Inventors: Lonnie G. Johnson, Stephen Buckingham
  • Patent number: 8012625
    Abstract: The present invention aims to provide a non-aqueous electrolyte secondary cell having high capacity and capable of preventing elution of cobalt and decomposition of the electrolyte. This aim can be accomplished by providing a non-aqueous electrolyte secondary cell comprising a positive electrode having a positive electrode active material, an negative electrode having an negative electrode active material, and non-aqueous electrolyte, wherein the positive electrode active material comprises lithium cobalt oxide to which at least one material selected from the group consisting of Mg, Al, Ti, and Zr was added, and the positive electrode comprises lithium phosphate.
    Type: Grant
    Filed: November 16, 2007
    Date of Patent: September 6, 2011
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Satoshi Yamamoto, Nobumichi Nishida
  • Publication number: 20110212363
    Abstract: The present invention relates to a power storage system including a negative electrode which has a crystalline silicon film provided as a negative electrode active material on the surface of a current collector and contains a conductive oxide in a surface layer section of the crystalline silicon film. Alternatively, the present invention relates to a method for manufacturing a power storage system, which includes the step of forming an amorphous silicon film on a current collector, adding a catalytic element for promoting crystallization of the amorphous silicon, onto a surface of the amorphous silicon film, heating the amorphous silicon film with the catalytic element added to crystallize the amorphous silicon film and thereby form a crystalline silicon film, and using the crystalline silicon film as a negative electrode active material layer.
    Type: Application
    Filed: February 24, 2011
    Publication date: September 1, 2011
    Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
    Inventors: Shunpei YAMAZAKI, Tamae MORIWAKA, Kazutaka KURIKI, Mikio YUKAWA
  • Patent number: 8007936
    Abstract: An electric storage device 10 has a first electric storage component 29 and a second electric storage component 30. The first component 29 and the second component 30 are connected in parallel. A positive-electrode mixture layer 22 contains a lithium cobaltate to increase a capacity. A positive-electrode mixture layer 27 contains an activated carbon to increase an output. A current collector 16 having through holes 16a is provided between the layers 22 and 27. A positive electrode terminal 25 is connected to a positive-electrode current collector 21 of the first component 29 through an electricity supply path 24 provided with a resistor 23. By this configuration, the electric current flowing through the first electric storage component 29 can be restricted when the device is charged or discharged with high current.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: August 30, 2011
    Assignee: Fuji Jukogyo Kabushiki Kaisha
    Inventors: Nobuo Ando, Kenji Kojima
  • Patent number: 8007941
    Abstract: A positive active material for a rechargeable lithium battery. The positive active material includes a core and a surface-treatment layer on the core. The core includes at least one lithiated compound and the surface-treatment layer includes at least one coating material selected from the group consisting of coating element included-hydroxides, oxyhydroxides, oxycarbonates, hydroxycarbonates and any mixture thereof.
    Type: Grant
    Filed: May 23, 2006
    Date of Patent: August 30, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Ho-Jin Kweon, Joon-Won Suh
  • Patent number: 8003256
    Abstract: A positive electrode active material for a lithium secondary battery according to an aspect of the present invention is a lithium-transition metal compound oxide which is produced by mixing a lithium compound, a transition metal compound, a magnesium compound, and a sulfate and conducting firing and which contains magnesium atoms and sulfate groups, wherein a magnesium halide is used as the magnesium compound.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: August 23, 2011
    Assignee: Nippon Chemical Industrial Co., Ltd
    Inventor: Yoshihide Ohishi
  • Patent number: 8003252
    Abstract: An electrode, for a rechargeable lithium battery, including a current collector; an active material layer disposed on the current collector; and a coating layer disposed on the active material layer. The coating layer includes a lithium ion conductive polymer and an inorganic material represented by Formula 1: MwHxPyOz, wherein M is an element selected from the group consisting of an alkali metal, an alkaline-earth metal, a Group 13 element, a Group 14 element, a transition element, a rare earth element, and a combination thereof; and 1?w?4, 0?x?4, 1 ?y?7, and 2?z?30.
    Type: Grant
    Filed: May 22, 2007
    Date of Patent: August 23, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Euy-Young Jung, Duck-Chul Hwang, Yong-Chul Park, Jeom-Soo Kim, Jong-Hwa Lee, Jae-Yul Ryu, So-Hyun Hur
  • Publication number: 20110200877
    Abstract: A non-aqueous electrolyte secondary battery has a positive electrode (17) containing positive electrode active material, a negative electrode containing a negative electrode active material, a non-aqueous electrolyte, and a separator (18) disposed between the positive electrode (17) and the negative electrode. An inorganic particle layer (19) containing inorganic particles is formed between the positive electrode (17) and the separator (18), and the inorganic particle layer (19) contains a chelating agent (15) that forms a complex with transition metal ions.
    Type: Application
    Filed: February 16, 2011
    Publication date: August 18, 2011
    Applicant: SANYO ELECTRIC CO., LTD.
    Inventors: Nobuhiro Sakitani, Hroshi Minami, Hiroyuki Fujimoto
  • Publication number: 20110200876
    Abstract: A positive electrode having a surface on which a positive electrode active material composition including a positive electrode active material is formed. The positive electrode includes a first lithium compound having an open-circuit voltage less than 3V with respect to lithium metal, and a second lithium compound having an open-circuit voltage of 3 V or greater with respect to lithium metal. The first lithium compound includes a solid solution represented by Formula 1: xLizM1-yM?yO2-(1?x)LiaM?bMocO3.
    Type: Application
    Filed: February 16, 2011
    Publication date: August 18, 2011
    Inventor: Kyu-Sung Park
  • Publication number: 20110195310
    Abstract: A production method for an electrode for a battery includes preparing a conductive substrate, and electrode material particles having ion conduction anisotropy; and producing an electrode by attaching the electrode material particles onto the conductive substrate, and applying a magnetic field in a predetermined direction.
    Type: Application
    Filed: February 3, 2011
    Publication date: August 11, 2011
    Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Koji KAWAMOTO, Masato HOZUMI, Yoshio SAKKA, Tetsuo UCHIKOSHI, Tohru SUZUKI, Hideto YAMADA
  • Patent number: 7993783
    Abstract: The storage characteristics in a charged state are improved in a non-aqueous electrolyte secondary battery containing a lithium cobalt oxide as a positive electrode active material. The non-aqueous electrolyte secondary battery includes a positive electrode containing a positive electrode active material; a negative electrode containing a negative electrode active material other than metallic lithium; and a non-aqueous electrolyte. The positive electrode active material contains a lithium cobalt oxide as its main component. The non-aqueous electrolyte contains 0.1 to 10 volume % of a compound having an ether group. The positive electrode active material and the negative electrode active material are contained so that the charge capacity ratio of the negative electrode to the positive electrode is from 1.0 to 1.2 when the battery is charged until the potential of the positive electrode reaches 4.4 to 4.5 V (vs.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: August 9, 2011
    Assignee: SANYO Electric Co., Ltd.
    Inventors: Yasufumi Takahashi, Akira Kinoshita, Shingo Tode, Tatsuyuki Kuwahara, Kazuhiro Hasegawa, Hiroyuki Fujimoto, Shin Fujitani
  • Publication number: 20110183210
    Abstract: A lithium-ion battery includes a positive electrode having a current collector and a first active material and a negative electrode comprising a current collector, a second active material, and a third active material. The second active material comprises a lithium titanate material and the third active material comprises V6O13. The third active material exhibits charging and discharging capacity below a corrosion potential of the current collector of the negative electrode and above a decomposition potential of the first active material.
    Type: Application
    Filed: April 6, 2011
    Publication date: July 28, 2011
    Inventors: William G. Howard, Craig L. Schmidt, Erik R. Scott
  • Patent number: 7985495
    Abstract: An assembled battery comprises mainly multiple non-aqueous secondary cells A and at least one electric device B for voltage detection containing a non-aqueous electrolyte connected to the multiple non-aqueous secondary cells A in series. When a difference in the non-aqueous secondary cell A between a voltage per cell (VA1) at a depth of discharge of 25% and a voltage per cell (VA2) at a depth of discharge of 75% is designated as ?VA, and a difference in the electric device B between a voltage per cell (VB1) at a depth of discharge equivalent to the depth of discharge of 25% of the non-aqueous secondary cell A and a voltage per cell (VB2) at a depth of discharge equivalent to the depth of discharge of 75% of the non-aqueous secondary cell A is designated as ?VB, the ?VB of electric device B is greater than the ?VA of non-aqueous secondary cell A.
    Type: Grant
    Filed: January 18, 2007
    Date of Patent: July 26, 2011
    Assignee: Panasonic Corporation
    Inventors: Yukihiro Okada, Masatoshi Nagayama
  • Patent number: 7981544
    Abstract: A positive electrode for a nonaqueous electrolyte secondary battery using a positive electrode active material mixture according to an embodiment of the invention includes a positive electrode active material capable of intercalating and deintercalating a lithium ion, a conductive agent and a binder, in which the positive electrode active material is produced by coating cobalt-based lithium composite oxide represented by a general formula: LiaCo1-sM1sO2 with lithium nickel cobalt manganese oxide represented by a general formula: LibNitCouMnvO2, the ratio r1/r2 of the average particle diameter r1 of the cobalt-based lithium composite oxide and the average particle diameter r2 of the lithium nickel cobalt manganese oxide is 2?r1/r2?50, and the average particle diameter r2 of the lithium nickel cobalt manganese oxide is 0.5 ?m?r2?20 ?m.
    Type: Grant
    Filed: February 12, 2008
    Date of Patent: July 19, 2011
    Assignee: Sanyo Electric Co., Ltd.
    Inventor: Hideki Morishima
  • Patent number: 7981547
    Abstract: A positive electrode active material for a lithium secondary battery containing a lithium-cobalt composite oxide is produced by firing, as a cobalt source, a mixture of substantially spherical cobalt hydroxide or tricobalt tetraoxide having such a sharp particle size distribution that the average particle size D50 is from 7 to 20 ?m, and cobalt oxyhydroxide having an average particle size of secondary particles formed by agglomeration of primary particles of from 7 to 20 ?m, in a proportion of from 5:1 to 1:5 as the cobalt atomic ratio, at a temperature of from 700° C. to 1050° C. in an oxygen-comprising atmosphere.
    Type: Grant
    Filed: August 3, 2010
    Date of Patent: July 19, 2011
    Assignee: Seimi Chemical Co., Ltd.
    Inventors: Manabu Suhara, Naoshi Saito, Kazushige Horichi, Megumi Uchida
  • Patent number: 7981546
    Abstract: A lithium-containing composite oxide represented by the formula 1: LixNi1-y-z-v-wCoyAlzM1vM2wO2 is used as a positive electrode active material for a non-aqueous electrolyte secondary battery. The element M1 is at least one selected from the group consisting of Mn, Ti, Y, Nb, Mo, and W. The element M2 includes at least two selected from the group consisting of Mg, Ca, Sr, and Ba, and the element M2 includes at least Mg and Ca. The formula 1 satisfies 0.97?x?1.1, 0.05?y?0.35, 0.005?z?0.1, 0.0001?v?0.05, and 0.0001?w?0.05. The primary particles have a mean particle size of 0.1 ?m or more and 3 ?m or less, and the secondary particles have a mean particle size of 8 ?m or more and 20 ?m or less.
    Type: Grant
    Filed: April 17, 2006
    Date of Patent: July 19, 2011
    Assignees: Panasonic Corporation, Sumitomo Metal Mining Co., Ltd.
    Inventors: Takashi Takeuchi, Akihiro Taniguchi, Shuji Tsutsumi, Kensuke Nakura, Hiroshi Matsuno, Hideo Sasaoka, Satoshi Matsumoto
  • Publication number: 20110171529
    Abstract: An electrode active material includes particles of a lithium-containing composite oxide represented by the general compositional formula: Li1+xMO2, where ?0.15?x?0.15, and M represents an element group of three or more elements including at least Ni, Co and Mn, wherein the ratios of Ni, Co and Mn to the total elements constituting M satisfy 45?a?90, 5?b?30, 5?c?30 and 10?b+c?55, where the ratios of Ni, Co and Mn are represented by a, b and c, respectively, in units of mol %, the average valence A of Ni in the whole particles is 2.2 to 3.2, the valence B of Ni on the surface of the particles has the relationship: B<A, the average valence C of Co in the whole particles is 2.5 to 3.2, the valence D of Co on the surface of the particles has the relationship: D<C, and the average valence of Mn in the whole particles is 3.5 to 4.2.
    Type: Application
    Filed: March 10, 2010
    Publication date: July 14, 2011
    Inventors: Satoshi Kono, Mitsuhiro Kishimi, Atsushi Hatakeyama
  • Publication number: 20110165460
    Abstract: A lithium secondary battery has a positive electrode (1) containing a positive electrode active material having particles of lithium cobalt oxide, a negative electrode (2) containing a negative electrode active material having silicon particles, a separator interposed between the positive electrode (1) and the negative electrode (2), and a non-aqueous electrolyte. Particles of erbium hydroxide or erbium oxyhydroxide are adhered to a surface of the lithium cobalt oxide particles in a dispersed form.
    Type: Application
    Filed: January 4, 2011
    Publication date: July 7, 2011
    Applicant: SANYO ELECTRIC CO., LTD.
    Inventors: Daizo Jito, Takeshi Ogasawara, Atsushi Fukui
  • Publication number: 20110165459
    Abstract: In a lithium ion battery, one or more chelating agents may be attached to a microporous polymer separator for placement between a negative electrode and a positive electrode or to a polymer binder material used to construct the negative electrode, the positive electrode, or both. The chelating agents may comprise, for example, at least one of a crown ether, a podand, a lariat ether, a calixarene, a calixcrown, or mixtures thereof. The chelating agents can help improve the useful life of the lithium ion battery by complexing with unwanted metal cations that may become present in the battery's electrolyte solution while, at the same time, not significantly interfering with the movement of lithium ions between the negative and positive electrodes.
    Type: Application
    Filed: January 12, 2011
    Publication date: July 7, 2011
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Ion C. Halalay, Timothy J. Fuller, Lijun Zou, Stephen J. Harris
  • Publication number: 20110151328
    Abstract: Provided is a cathode active material composed of lithium nickel oxide represented by Formula 1, wherein the lithium nickel oxide contains nickel in an amount of 40% or higher, based on the total weight of transition metals, and the cathode active material comprises a first coating layer provided on the surface thereof and a second coating layer provided on the surface of the first coating layer, wherein the first coating layer is composed of a non-reactive material selected from the group consisting of oxides, nitrides, sulfides and mixtures or complexes thereof and the second coating layer is composed of a carbon-based material.
    Type: Application
    Filed: August 6, 2010
    Publication date: June 23, 2011
    Applicant: LG CHEM, LTD.
    Inventors: Sung kyun CHANG, Hong-Kyu Park, Sinyoung Park
  • Patent number: 7964305
    Abstract: A non-aqueous electrolyte battery comprising: a battery case containing aluminum; a positive electrode terminal attached to the battery case; and a negative electrode terminal attached to the battery case and insulated from the battery case, wherein the positive electrode terminal and the battery case are connected through a resistor having resistance of 1 ? to 1 M?. Otherwise, A non-aqueous electrolyte battery comprising: a battery case containing iron; a negative electrode terminal attached to the battery case; and a positive electrode terminal attached to the battery case and insulated from the battery case, wherein the negative electrode terminal and the battery case are connected through a resistor having resistance of 1 ? to 1 M?.
    Type: Grant
    Filed: December 3, 2004
    Date of Patent: June 21, 2011
    Assignee: GS Yuasa International Ltd.
    Inventors: Hiroaki Yoshida, Nobutaka Imamura
  • Publication number: 20110143207
    Abstract: This invention provides a multi-layer article comprising a first electrode material, a second electrode material, and a porous separator disposed between and in contact with the first and the second electrode materials, wherein the porous separator comprises a nanoweb consisting essentially of a plurality of nanofibers of a fully aromatic polyimide. Also provided is a method for preparing the multi-layer article, and an electrochemical cell employing the same. A multi-layer article comprising a polyimide nanoweb with enhanced properties is also provided.
    Type: Application
    Filed: October 7, 2010
    Publication date: June 16, 2011
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: PANKAJ ARORA, Stephane Francois Bazzana, T. Joseph Dennes, Eric P. Holowka, Lakshmi Krishnamurthy, Stephen Mazur, Glen E. Simmonds
  • Patent number: 7960059
    Abstract: Methods for producing an electrode active material precursor, comprising; a) producing a mixture comprising particles of lithium hydrogen phosphate, having a first average particle size, and a metal hydroxide, having a second average particle size; and b) grinding said mixture in a jet mill for a period of time suitable to produce a generally homogeneous mixture of particles having a third average size smaller than said first average size. The precursor may be used as a starting material for making electrode active materials for use in a battery, comprising lithium, a transition metal, and phosphate or a similar anion.
    Type: Grant
    Filed: March 12, 2008
    Date of Patent: June 14, 2011
    Assignee: Valence Technology, Inc.
    Inventors: George Adamson, Jeremy Barker, Allan Dirilo, Titus Faulkner, M. Yazid Saidi, Jeffrey Swoyer
  • Publication number: 20110133699
    Abstract: A lithium-ion battery includes a positive electrode, a negative electrode, and a battery case. The positive electrode includes a positive current collector, a first material of the form Li1?xMO2, where M is a metal, and a second material including carbon. The negative electrode includes a negative current collector, a third material including a lithium titanate material, and a fourth material including carbon. The battery case includes titanium and at least partially surrounds the positive and negative electrodes.
    Type: Application
    Filed: December 6, 2010
    Publication date: June 9, 2011
    Inventors: William G. Howard, Craig L. Schmidt, Erik R. Scott
  • Publication number: 20110129732
    Abstract: Embodiments of the invention contemplate forming an electrochemical device and device components, such as a battery cell or supercapacitor, using thin-film or layer deposition processes and other related methods for forming the same. In one embodiment, a battery bi-layer cell is provided. The battery bi-layer cell comprises an anode structure comprising a conductive collector substrate, a plurality of pockets formed on the conductive collector substrate by conductive microstructures comprising a plurality of columnar projections, and an anodically active powder deposited in and over the plurality of pockets, an insulative separator layer formed over the plurality of pockets, and a cathode structure joined over the insulative separator.
    Type: Application
    Filed: July 19, 2010
    Publication date: June 2, 2011
    Applicant: APPLIED MATERIALS, INC.
    Inventors: Robert Z. Bachrach, Sergey D. Lopatin, Connie P. Wang, Donald J.K. Olgado
  • Patent number: RE42433
    Abstract: A positive active material for a rechargeable lithium battery is provided. The positive active material includes at least one compound selected from the group consisting of lithiated compounds, a metal oxide layer formed on a surface of the compound and metal oxide masses adhered on the metal oxide layer. The positive active material is produced by coating a compound with a metal alkoxide solution, an organic solution of a metal salt or an aqueous solution of a metal salt and heat-treating the coated compound. The compound is selected from the group consisting of lithiated compounds. Thereafter, the heat-treated compound is slow-cooled to 100 to 500° C. and the cooled compound is quenched to room temperature.
    Type: Grant
    Filed: September 10, 2010
    Date of Patent: June 7, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Ho-Jin Kweon, Jung-Joon Park, Jeong-Soon Shin, Kyeong-Min Jeong