Abstract: A lithium-nickel complex oxide material for active material for positive electrode of a lithium secondary battery is provided and expressed by the general formula Lix(Ni1-yCoy)1-zMzO2 (where, 0.98?x?1.10, 0.05?y?0.4, 0.01?z?0.2, M=at least one element selected from the group of Al, Zn, Ti and Mg), wherein according to Rietveld analysis, the Li site occupancy rate for the Li site in the crystal is 98% or greater, and the average particle size of the spherical secondary particles is 5 ?m to 15 ?m, and wherein the difference in specific surface area between before and after the washing process is 1.0 m2/g or less.

Abstract: To provide a cathode active material for a lithium secondary battery, which is low in gas generation and has high safety and excellent durability for charge and discharge cycles even at a high charge voltage. A process for producing a lithium-containing composite oxide represented by the formula LipLqNxMyOzFa (wherein L is at least one element selected from the group of B and P, N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, alkaline earth metal elements and transition metal elements other than N, 0.9?p?1.1, 1.0?q<0.03, 0.97?x<1.00, 0?y?0.03, 1.9?z?2.1, q+x+y=1 and 0?a?0.

Abstract: The present invention relates to a conductive agent/positive active material composite for a lithium secondary battery. The composite includes a positive active material capable of reversibly intercalating/deintercalating lithium ions, and a conductive agent on the surface of the positive active material. The conductive agent comprises a first conductive agent having a specific surface area ranging from about 200 to about 1500 m2/g and a second conductive agent having a specific surface area of about 100 m2/g or less.

Abstract: A lithium nickel manganese cobalt composite oxide used as a cathode active material for a lithium rechargeable battery, the composite oxide shown by the below general formula (1): LixNi1?y?zMnyCozO2??(1) (wherein 0.9?x?1.3, 0<y<1.0, and 0<z<1.0; and wherein y+z<1), the lithium nickel manganese cobalt composite oxide having an average particle size of 5-40 ?m, a BET ratio surface area of 5-25 m2/g, and a tap density of equal to or higher than 1.70 g/ml.

Abstract: There is provided a process for preparing lithium cobaltate and to lithium-containing cobalt oxides which is used in lithium battery cathodes. Also, there is provided cathodes for lithium batteries.

Abstract: A non-aqueous secondary battery contains a positive electrode, a negative electrode, a separator and a non-aqueous electrolytic solution. The positive electrode contains a layered structure lithium-containing compound oxide, or a spinel lithium-containing compound oxide containing manganese as an active material. The non-aqueous electrolytic solution contains at least one additive selected from a sulfonic acid anhydride, a sulfonate ester derivative, a cyclic sulfate derivative and a cyclic sulfonate ester derivative, and a vinylene carbonate or a derivative of the vinylene carbonate.

Abstract: Disclosed herein is a method for producing a lithium composite oxide for use as a positive electrode active material for lithium secondary batteries by a spray pyrolysis process. The method comprises the steps of: subjecting an inorganic acid salt solution of metal elements constituting a final composite oxide other than lithium to a spray pyrolysis process to obtain an intermediate composite oxide powder; and solid state-mixing the intermediate composite oxide powder and a hydroxide salt of lithium, followed by thermally treating the mixture.

Abstract: A lithium-ion rechargeable cell is described which contains an electrolyte comprising a pyrazolium cation, an imidazolium cation, or a combination thereof, as well as lithium ion, and at least one non-Lewis acid derived counter-ion and which has a ratio of cathode capacity to anode capacity of 1 or less, 1 or greater, and preferably about 1.3 or greater. Electrochemical cells containing an anode, a cathode, and the ionic liquid electrolytes preferably have effective charge/discharge capacity and charging efficiency at low temperatures and at high temperatures.

Abstract: A positive electrode active material is produced by firing, as a cobalt source, a mixture of a) substantially spherical large particle size cobalt hydroxide or tricobalt tetraoxide having a sharp particle size distribution, and b) small particle size cobalt hydroxide or tricobalt tetraoxide, in a proportion of from 9:1 to 1:2 as the cobalt atomic ratio, at a temperature of from 700° C. to 1050° C. in an oxygen-comprising atmosphere.

Abstract: The present invention relates to Lithium Metal batteries. In particular, it is related to lithium metal batteries containing a polyimide-based electrolyte. The present invention concerns a new concept of polyimide-based electrolytic component having an electrolyte comprising of at least one solvent and at least one alkali metal salt, with specific amounts of solvents, to optimize the properties of conductivity of the polyimide-based electrolyte and the mechanical properties of the polyimide-based electrolyte separator towards metallic lithium anode to prevent dendrites growths.

Abstract: An electrode and an electrode material for lithium electrochemical cells are disclosed. The electrode material is in powder form and has a particle size distribution wherein the measured particle size distribution of the electrode material has a median size D50 ranging from 1.5 ?m and 3 ?m, a D10?0.5 ?m, a D90?10.0 ?m, and a calculated ratio (D90/D10)/D50?3.0 which is indicative of a peak of the measured particle size distribution on the left of the median D50 which improves the loading and energy density of the electrode produced with this electrode material powder.

Abstract: A lithium-ion battery includes a positive electrode that includes a current collector that includes a positive electrode comprising a current collector and an active material comprising a material selected from the group consisting of LiCoO2, LiMn2O4, LiNixCoyNi(1?x?y)O2, LiAlxCoyNi(1?x?y)O2, LiTixCoyNi(1?x?y)O2, and combinations thereof. The battery also includes a negative electrode that includes a current collector and an active material comprising a lithium titanate material. The current collector of the negative electrode includes a material selected from the group consisting of aluminum, titanium, silver, and combinations thereof. The battery is configured for cycling to near-zero-voltage conditions without a substantial loss of battery capacity.

Abstract: A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and an electrolyte, wherein the positive electrode comprises a positive electrode active material comprising a particle of a composite oxide represented by a general formula: LixMe1-y-zMyLzO2. In the general formula, the element Me is at least one transition metal element except Ti, Mn, Y and Zr, the element M is at least one selected from the group consisting of Mg, Ti, Mn and Zn, and the element L is at least one selected from the group consisting of Al, Ca, Ba, Sr, Y and Zr, and 1?x?1.05, 0.005?y?0.1 (with a proviso that 0.005?y?0.5 is satisfied in the case of the element M being Mn) and 0?z?0.05 are satisfied.

Abstract: A lithium-ion battery includes a positive electrode including a positive current collector, a first active material, and a second active material. The battery also includes a negative electrode having a negative current collector and a third active material, the third active material including a lithium titanate material. The first active material, second active material, and third active materials are configured to allow doping and undoping of lithium ions. The second active material exhibits charging and discharging capacity below a corrosion potential of the negative current collector and above a decomposition potential of the first active material.

Abstract: A compound for use as active material of a positive electrode of a lithium-ion cell. This compound has an average discharge voltage above 4.5V in relation to the Li+/Li couple of approximately 4.7V. The compound includes: a) a spinel-type crystalline phase of formula LiaNiII0.5?xMnIII2xMnIV1.5?x?yMyO4 in which elements Ti and Al, or a mixture of these; 0.8<a<1.3; 0<x?0.15; 0<y?0.15; b) a cubic crystalline phase of formula Li1?tNi1+tO in which 0?t?1; and c) a rhomboedric crystalline phase of formula Li1?ZNi1+zO2 in which 0?z?1.

Abstract: A method and system for planning the journey of a submarine are provided using at least one electrical drive with a battery for energy supply and a charging device for the battery. For a selected future point in time, the remaining available energy reserve of the battery is predicted on the basis of the travel duration up to this point in time, of at least of one consumption profile selected for the travel duration, and of the type and duration of the charging cycles of the battery being effected up to this point in time.

Abstract: In a nonaqueous electrolytic secondary battery according to the invention, hexagonal system lithium containing cobalt composite oxide having a crystallite size in a (110) vector direction of 1000 ? or more and having a halogen compound added thereto by burning at time of synthesis is used as a positive electrode active material. By measuring a pH value of a filtrate obtained by dispersing, in water, the lithium containing cobalt composite oxide having the halogen compound added thereto by the burning at time of the synthesis and a crystallite size in the (110) vector direction of 1000 ? or more, a value of 9.6 to 10.1 is obtained. By using the lithium containing cobalt composite oxide as a positive electrode active material, a high temperature cycle property can be enhanced.

Abstract: A battery includes a positive electrode having a current collector and a first active material and a negative electrode having a current collector and a second active material. The battery also includes an auxiliary electrode having a current collector and a third active material. The auxiliary electrode is configured for selective electrical connection to one of the positive electrode and the negative electrode. The first active material, second active material, and third active material are configured to allow doping and undoping of lithium ions. The third active material exhibits charging and discharging capacity below a corrosion potential of the current collector of the negative electrode and above a decomposition potential of the first active material.

Abstract: This invention provides a lithium-oxygen or lithium-air electrochemical cell comprising a negative electrode, an electrolyte, and a porous activated positive electrode comprising lithium-rich electrocatalytic materials suitable for use in lithium-oxygen (air) cells and batteries. The activated positive electrode is produced by activating a precursor electrode formed from a material comprising one or more metal oxide compounds of general formula xLi2O.yMOz, in which 0<x?4, 0<y?1, and 0<z?3, in which M is typically, but not exclusively, a transition metal, excluding Li2MnO3 as a sole metal oxide compound in the precursor electrode. Li2O is extracted from the above-mentioned precursors to activate the electrode either by electrochemical methods or by chemical methods. The invention extends to batteries containing such electrochemical cells.

Abstract: Disclosed in a positive active material for a lithium secondary battery including a compound represented by formula 1 and having a 10% to 70% ratio of diffracted intensity of diffraction lines in 2?=53° (104 plane) with respect to diffracted intensity of diffraction lines in the vicinity of 2?=22° (003 plane) in X-ray diffraction patterns using a CoK?-ray, LixCoO2-yAy??(1) wherein, x is from 0.90 to 1.04, y is from 0 to 0.5, and A is selected from the group consisting of F, S and P.

Abstract: Coagulated particles of nickel-cobalt-manganese hydroxide wherein primary particles are coagulated to form secondary particles are synthesized by allowing an aqueous solution of a nickel-cobalt-manganese salt, an aqueous solution of an alkali-metal hydroxide, and an ammonium-ion donor to react under specific conditions; and a lithium-nickel-cobalt-manganese-containing composite oxide represented by a general formula, LipNixMn1-x-yCoyO2-qFq (where 0.98?p?1.07, 0.3?x?0.5, 0.1?y?0.38, and 0?q?0.05), which is a positive electrode active material for a lithium secondary cell having a wide usable voltage range, a charge-discharge cycle durability, a high capacity and high safety, is obtained by dry-blending coagulated particles of nickel-cobalt-manganese composite oxyhydroxide formed by making an oxidant to act on the coagulated particles with a lithium salt, and firing the mixture in an oxygen-containing atmosphere.

Abstract: The object of the present invention is to provide a method for producing simply a positive electrode active material which can further increase charge-discharge capacity of secondary batteries when the positive electrode active material is used for positive electrode of secondary batteries, particularly non-aqueous electrolyte secondary batteries. A method for producing a positive electrode active material includes the step of heat-treating a lithium mixed metal oxide represented by the formula Li2MO3 in the presence of a hydride wherein M is at least one element selected from the group consisting of Ti, V, Mn, Fe, Co and Ni.

Abstract: The invention provides a lithium secondary battery which is excellent in long-term cycle property and in battery characteristics, such as electric capacity and storage property, and a nonaqueous electrolytic solution usable for such a lithium secondary battery. The present invention relates to a lithium secondary battery including a positive electrode, a negative electrode, and a nonaqueous electrolytic solution containing an electrolyte salt dissolved in a nonaqueous solvent, characterized in that the positive electrode is made of a material including a lithium compound oxide, in that the negative electrode is made of a material including graphite, and in that the nonaqueous electrolytic solution contains dialkyl oxalate and further contains vinylene carbonate and/or 1,3-propanesultone, and a nonaqueous electrolytic solution for use in such a battery.

Abstract: The present invention relates to a cathode active material for lithium secondary batteries with high safety, a method of preparing the same and lithium secondary batteries comprising the same. The cathode active material of the present invention comprises a lithium metal oxide secondary particle core portion formed by aggregation of lithium metal oxide primary particles; and a shell portion formed by coating the secondary particle core portion with an olivine-structured lithium iron phosphate oxide. The cathode active material of the present invention allows to manufacture lithium secondary batteries with improved safety, especially overcharge characteristics.

Abstract: Disclosed is a lithium secondary battery, which is low in capacity loss after overdischarge, having excellent capacity restorability after overdischarge and shows an effect of preventing a battery from swelling at a high temperature.

Abstract: Active materials for positive electrodes of rechargeable batteries and the methods of fabrication for the active materials as well as positive electrodes thereof are provided, where the active material comprises of a mixture of two components, A and B. A are compounds of lithium nickel cobalt metal oxide while B are oxides of lithium cobalt. In a preferred embodiment, a formula for the compounds of lithium nickel metal oxide, A, is LiaNi1-b-cCobMcO2 where 0.97?a?1.05, 0.01?b?0.30, 0?c?0.10, and M is one or more of the following: manganese, aluminum, titanium, chromium, magnesium, calcium, vanadium, iron, and zirconium. The weight ratio of A:B is between 20:80 and 80:20.

Abstract: A nonaqueous electrolyte secondary battery including a negative electrode containing a graphite material as the negative active material, a positive electrode containing lithium cobalt oxide as a main component of the positive active material and a nonaqueous electrolyte solution, the battery being characterized in that the lithium cobalt oxide contains a group IVA element and a group IIA element of the periodic table, the nonaqueous electrolyte solution contains 0.2-1.5% by weight of a sulfonyl-containing compound and preferably further contains 0.5-4% by weight of vinylene carbonate.

Abstract: A non-aqueous electrolyte secondary battery that can restrict lowering of battery performance during battery preservation is provided. A negative electrode that a negative electrode mixture including graphite is applied on a rolled copper foil and a positive electrode that a positive electrode mixture including lithium manganate is applied on an aluminum foil are used. An oxide in which one element selected from Al, Si, Ti, V, Cr, Fe, Ni, Cu, Zn, Zr, Mo, W, Pb and dissimilar to elements constituting the lithium manganate is oxidized is intermixed with the lithium manganate. An intermixture amount of the oxide is set such that a molar number of the dissimilar element contained in one gram of the positive electrode active material to a molar number of lithium contained in one gram of the positive electrode active material is not more than 5/1000. Charge transfer is restricted by the oxide during battery preservation.

Abstract: A cathode active material having a large capacity and improved charge/discharge cycle characteristics is disclosed. A battery has a cathode (2) having a cathode active material, an anode (3) and a non-aqueous electrolyte, and uses a cathode active material composed of a mixture of a first lithium-transition metal composite oxide containing Ni and Co and comprising a layer structure and a second lithium-transition metal composite oxide containing Ni and Mn and comprising a layer structure.

Abstract: A lithium ion secondary battery is provided. The battery includes a positive electrode having at least a cathode active material and a binder, a negative electrode, an electrolyte, and a separator which are arranged between the positive electrode and the negative electrode, and in which an open circuit voltage per unit cell in a full charging state lies within (4.25V?voltage?6.00V). The cathode active material includes either a lithium-cobalt composite oxide expressed by a general formula: LiaCo1-xMexO2-b (Me denotes metal elements of at least one, two or more kinds selected from V, Cu, Zr, Zn, Mg, Al, and Fe; 0.9?a?1.1; 0?x=0.3; and ?0.1?b?0.1) or a lithium-cobalt-nickel-manganese oxide expressed by a general formula: LiaNi1-x-y-zCoxMnyMezO2-b (0.9?a?1.1; 0<x<0.4; 0<y<0.4; 0<z<0.3; and ?0.1?b?0.1). The binder includes a polyacrylonitrile resin.

Abstract: Disclosed is a compound represented by the following formula 1. A lithium secondary battery using the same compound as electrode active material, preferably as cathode active material, is also disclosed. LiMP1-xAxO4??[Formula 1] wherein M is a transition metal, A is an element having an oxidation number of +4 or less and 0<x<1. The electrode active material comprising a compound represented by the formula of LiMP1-xAxO4 shows excellent conductivity and charge/discharge capacity compared to LiMPO4.

Abstract: The methods and devices described herein generally relate to Li4Ti5O12 negative electrodes for lithium ion batteries, methods of preparing the Li4Ti5O12 negative electrodes, and methods of preparing the lithium ion batteries containing such electrodes. The Li4Ti5O12 negative electrode improves the safety performance of the lithium ion battery by preventing or reducing thermal runaway of the lithium ion battery during overcharging.

Abstract: A nonaqueous electrolyte secondary battery 10 according to an embodiment of the invention includes a positive electrode 11, a negative electrode 12, a separator 13 and a nonaqueous electrolyte liquid in which not only the positive electrode 11 contains a positive electrode active material charged at or higher than 4.3 V based on lithium and a halogenated cyclic carbonate is added in the nonaqueous electrolyte liquid, but also an inorganic insulating material particle layer is formed on the surface of at least either of the positive electrode 11, the negative electrode 12 and the separator 13. By employing such a constitution in the present invention, a nonaqueous electrolyte secondary battery using a positive electrode charged at a high electric potential of 4.3 V or more based on lithium in which the amount of a generated gas is small even when the battery is overcharged at higher temperatures, and the impact safety and reliability thereof are high, can be provided.

Abstract: Disclosed is a rechargeable lithium polymer battery comprising a negative electrode including a negative active material layer deposited on a substrate, a positive electrode including a positive active material; and a polymer electrolyte including a lithium salt, an organic solvent, and a polymer.

Abstract: A method of fabricating fibres of silicon or silicon-based material comprises the steps of etching pillars on a substrate and detaching them. A battery anode can then be created by using the fibres as the active material in a composite anode electrode.

Abstract: A Li-ion battery cell is formed from deposited thin-film layers and comprises a high-surface-area 3-D battery structure. The high-surface-area 3-D battery structure includes a fullerene-hybrid material deposited onto a surface of a conductive substrate and a conformal metallic layer deposited onto the fullerene-hybrid material. The fullerene-hybrid material is made up of chains of fullerene “onions” linked by carbon nanotubes to form a high-surface-area layer on the conductive substrate and has a “three-dimensional” surface. The conformal metallic layer acts as the active anode material in the Li-ion battery and also has a high surface area, thereby forming a high-surface-area anode. The Li-ion battery cell also includes an ionic electrolyte-separator layer, an active cathodic material layer, and a metal current collector for the cathode, each of which is deposited as a conformal thin film.

Abstract: A non-aqueous electrolytic solution secondary battery includes a positive electrode containing, as a positive electrode active material, a compound represented by the following general formula, LixFe1-yMyPO4, wherein M is at least one member selected from the group consisting of Co, Ni, Cu, Zn, Al, Sn, B, Ga, Cr, V, Ti, Mg, Ca and Sr; 0.9<x<1.2; and 0?y<0.3; a negative electrode containing a lithium metal, a lithium alloy or a material capable of doping and dedoping lithium; and a non-aqueous electrolytic solution, the non-aqueous electrolytic solution containing a fluorinated ethylene carbonate FEC.

Abstract: Disclosed is a rechargeable lithium ion battery including a positive electrode comprising a first current collector and a positive active material layer on the first current collector; a negative electrode comprising a second current collector and a negative active material layer on the second current collector; and an electrolyte comprising a non-aqueous organic solvent and a lithium salt. At least one of the first and the second current collectors includes a rigid polymer film with a metal deposited on the rigid polymer film.

Abstract: An uncycled preconditioned electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula xLi2?yHyO.xM?O2.(1?x)Li1?zHzMO2 in which 0<x<1, 0<y<1 and 0<z<1, M is anon-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M? is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. The xLi2?yHy.xM?O2.(1?x)Li1?zHzMO2 material is prepared by preconditioning a precursor lithium metal oxide (i.e., xLi2M?O3.(1?x)LiMO2) with a proton-containing medium with a pH<7.0 containing an inorganic acid. Methods of preparing the electrodes are disclosed, as are electrochemical cells and batteries containing the electrodes.

Abstract: The disclosure herein relates to a lithium ion conducting electrolyte. This electrolytic material has improved ionic conductivity. The material disclosed herein is an amorphous compound of the formula LixSMwOyNz wherein x is between approximately 0.5 and 3, y is between 1 and 6, z is between 0.1 and 1, w is less than 0.3 and M is an element selected from B, Ge, Si, P, As, Cl, Br, I, and combinations thereof. The material can be prepared in the form of a thin film. The electrolyte material can be used in microbatteries and elctronic systems.

Abstract: A cathode active material capable of further improving chemical stability, a method of manufacturing the cathode active material, and a battery using the cathode active material are provided. The cathode includes a cathode active material in which a coating layer made of a compound including Li, at least one selected from Ni and Mg, and O is arranged on complex oxide particles represented by Li1+xCo1?yMyO2?z, where M is at least one kind selected from the group consisting of Mg, Al, B, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Mo, Sn, W, Zr, Y, Nb, Ca and Sr, and the values of x, y and z are within a range of ?0.10?x?0.10, 0?y<0.50 and ?0.10?z?0.20, respectively. A surface layer made of an oxide including at least one kind selected from the group consisting of Ti, Si, Mg and Zr is formed on the coating layer.

Abstract: A nonaqueous secondary battery 10 of the invention has an active material compound layer 14 deposed over at least one face of a collector 12 made of metal foil and is equipped with a positive electrode 11 having a portion 13 in a part of which metal is exposed. The positive electrode 11 together with the exposed-metal portion 13 faces a negative electrode 17 through an interposed separator 23, and on that part of the exposed-metal portion 13 that faces the negative electrode 17 through the interposed separator 23 there is formed a protective layer 16 made of a material whose electronic conductivity is lower than that of the metal and which moreover is non-insulative. With such nonaqueous secondary battery 10, should part of an electrode pierce the separator and contact with the other electrode, the battery will be gently discharged, thereby averting abnormal heat generation by the battery and additionally enabling the battery's abnormality to be sensed by the equipment via the fall in battery voltage.

Abstract: As an alternative technique to lead-acid batteries, the present invention provides an inexpensive 2 V non-aqueous electrolyte secondary battery having excellent cycle life at a high rate by preventing volume change during charge and discharge. The non-aqueous electrolyte secondary battery uses: a positive electrode active material having a layered structure, being represented by chemical formula Li1±?[Me]O2, where 0??<0.2, and Me is a transition metal including Ni and at least one selected from the group consisting of Mn, Fe, Co, Ti and Cu, and including elemental nickel and elemental cobalt in substantially the same ratio; and a negative electrode active material including Li4Ti5O12(Li[Li1/3Ti5/3]O4).

Abstract: A cathode material capable of improving capacity and superior low temperature characteristics, and a battery using the cathode material are provided. A cathode and an anode are layered with an electrolyte layer and a separator in between. The cathode contains a complex oxide containing lithium, manganese, nickel, and cobalt; a complex oxide containing lithium and at least one of nickel and cobalt; and a complex oxide containing lithium and manganese and having a spinel structure or a phosphorus oxide containing lithium and iron at a given ratio.

Abstract: The present invention provides a high-capacity and low-cost non-aqueous electrolyte secondary battery, comprising: a negative electrode containing, as a negative electrode active material, a substance capable of absorbing/desorbing lithium ions and/or metal lithium; a separator; a positive electrode; and an electrolyte, wherein the positive electrode active material contained in the positive electrode is composed of crystalline particles of an oxide containing two kinds of transition metal elements, the crystalline particles having a layered crystal structure, and oxygen atoms constituting the oxide forming a cubic closest packing structure.

Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode containing a positive active material, a negative electrode containing a negative active material and a nonaqueous electrolyte. Characteristically, the positive active material comprises a mixture of a lithium transition metal complex oxide A obtained by incorporating at least Zr and Mg into LiCoO2 and a lithium transition metal complex oxide B having a layered structure and containing at least Ni and Mn as the transition metal.

Abstract: The present invention provides a cathode comprising two or more lithium-containing metal composite oxides, having different potentials versus lithium (Li/Li+) and different impedances, the cathode comprising: (a) a first lithium-containing metal composite oxide; and (b) a second lithium-containing metal composite oxide, which has a high impedance and low potential versus lithium (Li/Li+), compared to those of the first lithium-containing metal composite oxide. In the invention, two or more lithium-containing metal composite oxides are used in combination as cathode components in a battery, whereby, when a short circuit occurs in the battery, the instantaneous flow of a large amount of current can be minimized and, at the same time, the accumulation of heat in the battery can be reduced, thus ensuring the safety of the battery.

Abstract: Positive electrodes for secondary batteries formed with a plurality of substantially aligned flakes within a coating. The flakes can be formed from metal oxide materials and have a number average longest dimension of greater than 60 ?m. A variety of metal oxide or metal phosphate materials may be selected such as a group consisting of LiCoO2, LiMn2O4, Li(M1x1M2x2Co1-x1-x2)O2 where M1 and M2 are selected from among Li, Ni, Mn, Cr, Ti, Mg, or Al, 0?x1?0.5 and 0?x2?0.5, or alternatively, LiM1(1-x)MnxO2 where 0<x<0.8 and M1 represents one or more metal elements. Methods for making positive electrode materials are also provided involving the formation of structures with a desired longest dimension, preferably polycrystalline flakes. A cathode coating containing polycrystalline flakes may be deposited onto a conductive substrate and pressed to a desired final electrode thickness.

Abstract: There is provided a simple and easy method of preparation of a positive electrode active material for a non-aqueous secondary battery which comprises a compound comprising lithium, nickel and manganese and having a layered structure. Said method comprises firing a mixture of (1) at least one member selected from the group consisting of dinickel trioxide and boron compounds and (2) one or more metal compounds comprising lithium, nickel and manganese as their metal elements.

Abstract: A non-aqueous electrolyte secondary battery includes a positive electrode containing a positive electrode active material; a negative electrode containing a negative electrode active material; and a non-aqueous electrolyte containing a non-aqueous solvent and an electrolyte salt. In order to improve the high-temperature storage characteristics and safety against overcharge due to high-rate charging of the battery, the positive electrode active material contains a layered lithium-transition metal composite oxide containing at least one of Mg, Al, Ti, and Zr. Furthermore, the non-aqueous electrolyte contains 3 to 80% by mass of a tertiary carboxylic acid ester expressed by Chemical Formula 2 below, based on the total mass of the non-aqueous solvent: where R1 to R4 are independent of each other and each represents an alkyl group having 4 or less carbon atoms and being able to be branched.