Abstract: Described is an electrode comprising and preferably consisting of electronically active material (EAM) in nanoparticulate form and a matrix, said matrix consisting of a pyrolization product with therein incorporated graphene flakes and optionally an ionic lithium source. Also described are methods for producing a particle based, especially a fiber based, electrode material comprising a matrix formed from pyrolized material incorporating graphene flakes and rechargeable batteries comprising such electrodes.

Abstract: A system and method producing electrodes in an aqueous electrolyte battery that maximizes energy storage, reduces electrochemical decomposition of the electrolyte, and uses Prussian Blue analogue materials for both electrodes, with an anode electrode including an electrochemically active hexacyanometalate group having two possible redox reactions of different potentials. These potentials may be tuned by substituting different electrochemically inactive components.

Abstract: A storage element for a solid electrolyte battery is provided, having a main member including a porous ceramic matrix in which particles that are made of a first metal and/or a metal oxide and jointly form a redox couple are embedded. The storage element further includes particles made of another metal and/or an associated metal oxide, the other metal being electrochemically more noble than the first metal.

Abstract: A family of electrolytes for use in a lithium ion battery. The genus of electrolytes includes ketone-based solvents, such as, 2,4-dimethyl-3-pentanone; 3,3-dimethyl 2-butanone(pinacolone) and 2-butanone. These solvents can be used in combination with non-Lewis Acid salts, such as Li2[B12F12] and LiBOB.

Abstract: In some examples, a primary battery comprising a cathode comprising at least one active material and at least one of a metal oxide and metal fluoride, wherein the active material exhibits a first discharge capacity and the at least one of metal oxide and metal fluoride exhibits a second discharge capacity at a voltage lower than the first discharge capacity; an anode comprising a metal as an electron source; and an electrolyte between the cathode and anode. The metal reacts with the electrolyte below a third discharge capacity at a voltage lower than the second discharge capacity to form a gas, where the metal reacts with the active material at the first discharge capacity, and, following the consumption of the active material of the cathode, the metal reacts with the at least one of metal oxide and metal fluoride of the cathode prior to reacting with the electrolyte below the third discharge capacity.

Abstract: An as-prepared cathode for a secondary battery, the cathode including an alkaline source material including an alkali metal oxide, an alkali metal sulfide, an alkali metal salt, or a combination of any two or more thereof.

Abstract: A composite anode active material, an anode including the composite anode active material, a lithium battery including the anode, and a method of preparing the composite anode active material, the composite anode active material including a core including a ternary alloy, the ternary alloy being capable of intercalating and deintercalating lithium; and a carbonaceous coating layer on the core.

Abstract: A system and method of forming a thin film battery includes a substrate, a first current collector formed on the substrate, a cathode layer formed on a portion of the first current collector, a solid layer of electrolyte material formed on the cathode layer, a silicon-metal thin film anode layer formed on the solid layer of electrolyte material and a second current collector electrically coupled to the silicon-metal thin film anode layer. A method and a system for forming the thin film battery are also disclosed.

Abstract: An electrode material for use in an electrochemical cell, like a lithium-ion battery, is provided. The electrode material may be a negative electrode comprising graphite, silicon, silicon-alloys, or tin-alloys, for example. By avoiding deposition of transition metals, the battery substantially avoids charge capacity fade during operation. The surface coating is particularly useful with negative electrodes to minimize or prevent deposition of transition metals thereon in the electrochemical cell. The coating has a thickness of less than or equal to about 40 nm. Methods for making such materials and using such coatings to minimize transition metal deposition in electrochemical cells are likewise provided.

Abstract: A lithium-ion battery includes a positive electrode having a first active material and a second active material and a negative electrode including a third active material. The second active material includes a lithiated form of a material that does not include electrochemically cyclable lithium in the as-provided state.

Abstract: A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a nonaqueous electrolyte. The negative electrode contains a lithium compound and a negative electrode current collector supporting the lithium compound. A log differential intrusion curve obtained when a pore size diameter of the negative electrode is measured by mercury porosimetry has a peak in a pore size diameter range of 0.03 to 0.2 ?m and attenuates with a decrease in pore size diameter from an apex of the peak. A specific surface area (excluding a weight of the negative electrode current collector) of pores of the negative electrode found by mercury porosimetry is 6 to 100 m2/g. A ratio of a volume of pores having a pore size diameter of 0.05 ?m or less to a total pore volume is 20% or more.

Abstract: An active material comprises a core particle containing LiCo(1-x)MxO2 and/or Li(Mn(1-y)My)2O4, and a coating part covering at least part of a surface of the core particle, while the coating part contains LiVOPO4. Here, M is at least one element selected from the group consisting of Al, Mg, and transition elements, 0.95?x?0, 0.2?y?0, and V in LiVOPO4 may partly be substituted by at least one element selected from the group consisting of Ti, Ni, Co, Mn, Fe, Zr, Cu, Zn, and Yb.

Abstract: In an aspect, a positive active material composition for a rechargeable lithium battery including a positive active material coated with a vanadium pentaoxide (V2O5) and an aqueous binder, a positive electrode including the same, and a rechargeable lithium battery including the positive electrode is disclosed.

Abstract: A lithium secondary battery including an anode active material including mesoporous TiO2 doped with a heteroatom.

Abstract: A method is provided for fabricating a battery using an anode preloaded with consumable metals. The method forms an ion-permeable membrane immersed in an electrolyte. A preloaded anode is immersed in the electrolyte, comprising MeaX, where X is a material such as carbon, metal capable of being alloyed with Me, intercalation oxides, electrochemically active organic compounds, and combinations of the above-listed materials. Me is a metal such as alkali metals, alkaline earth metals, and combinations of the above-listed metals. A cathode is also immersed in the electrolyte and separated from the preloaded anode by the ion-permeable membrane. The cathode comprises M1YM2Z(CN)N.MH2O. After a plurality of initial charge and discharge operations are preformed, an anode is formed comprising MebX overlying the current collector in a battery discharge state, where 0?b<a.

Abstract: A protected active metal electrode and a device with the electrode are provided. The protected active metal electrode includes an active metal substrate and a protection layer on a surface of the active metal substrate. The protection layer at least includes a metal thin film covering the surface of the active metal substrate and an electrically-conductive thin film covering a surface of the metal thin film. A material of the metal thin film is Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, or W. A material of the electrically-conductive thin film is selected from nitride of a metal in the metal thin film, carbide of a metal in the metal thin film, a diamond-like carbon (DLC), and a combination thereof.

Abstract: A method is presented for fabricating an anode preloaded with consumable metals. The method provides a material (X), which may be one of the following materials: carbon, metals able to be electrochemically alloyed with a metal (Me), intercalation oxides, electrochemically active organic compounds, and combinations of the above-listed materials. The method loads the metal (Me) into the material (X). Typically, Me is an alkali metal, alkaline earth metal, or a combination of the two. As a result, the method forms a preloaded anode comprising Me/X for use in a battery comprising a M1YM2Z(CN)N·MH2O cathode, where M1 and M2 are transition metals. The method loads the metal (Me) into the material (X) using physical (mechanical) mixing, a chemical reaction, or an electrochemical reaction. Also provided is preloaded anode, preloaded with consumable metals.

Abstract: A composite material comprising graphene oxide and an electrochemically active ingredient, in particular H4?xV3O8 with x ranging from 0.1 to 2.2, as well as a method for its manufacture were developed. The composite material is suitable for being used as electrode in an electrochemical cell.

Abstract: A composition comprising at least one graphene-supported metal oxide monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds, wherein the graphene sheets are coated by at least one metal oxide such as iron oxide or titanium oxide. Also provided is an electrode comprising the aforementioned graphene-supported metal oxide monolith, wherein the electrode can be substantially free of any carbon-black and substantially free of any binder.

Abstract: A lithium-titanium complex oxide containing Li4Ti5O12 is characterized in that, based on SEM observation, the number-based percentage of particles whose size is less than 0.1 ?m is 5 to 15% or 40 to 65%, the number-based percentage of particles whose size is 0.3 to 1.5 ?m is 15 to 30%, the specific surface area measured by the BET method is 5.8 to 10.1 m2/g, and the average particle size D50 according to the particle size distribution measured by laser diffraction measurement is preferably 0.6 to 1.5 ?m.

Abstract: This invention provides a positive electrode material having high capacity and safety, and a lithium ion secondary battery using the positive electrode material, the lithium ion secondary battery using a positive electrode active substance comprising a first transition metal oxide represented by the compositional formula: Lix1Nia1Mnb1Coc1Md1O2; a second transition metal oxide represented by the compositional formula: Lix2Nia2Mnb2Coc2Md2O2; and a third transition metal oxide represented by the compositional formula: Lix3Nia3Mnb3Coc3Md3O2; in which a3<a2<a1.

Abstract: Provided is a cathode active material including a lithium metal oxide of Formula 1 below: Li[LixMeyMz]O2+d??<Formula 1> wherein x+y+z=1; 0<x<0.33; 0<z<0.1; 0?d?0.1; Me is at least one metal selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Al, Mg, Zr, and B; and M is at least one metal selected from the group consisting of Mo, W, Ir, Ni, and Mg.

Abstract: A problem to be solved is to enhance the charge and discharge characteristics and rate characteristics of a B-type titanium oxide (TiO2(B)) powder by a simple treatment and to provide a B-type titanium oxide powder that can be suitably used as a negative electrode material for a lithium ion battery. A B-type titanium oxide powder is allowed to undergo a reaction under a fluorine-containing gas atmosphere at 0° C. to 200° C. for 1 minute to 10 days to obtain a surface-fluorinated B-type titanium oxide powder. It is preferred that the fluorination treatment is performed at 0.01 atm to 2 atm. It is preferred that a gas containing a fluorine compound selected from a fluorine (F2) gas, a nitrogen trifluoride (NF3) gas, a perfluorotrimethylamine (N(CF3)3) gas, a chlorine trifluoride (ClF3) gas and the like is used as the fluorine-containing gas.

Abstract: A battery active material includes a crystal phase that is represented by a formula Y2?xScxTi2O5S2 (where 0<x<2), and has a Ruddlesden-Popper structure.

Abstract: A composition is provided that includes mesoporous carbon domains. Each of the mesoporous carbon domains is incorporated with particles of metal or metal oxide in an amount of from 40 to 85 total weight percent of the composition. The metal or metal oxide particles can include tin, cobalt, copper, molybdenum, nickel, iron, or ruthenium, or an oxide thereof. The resulting composition when combined with a binder from a battery electrode. Such a battery electrode operating as an anode in a lithium ion battery has specific capacities of more than 1000 miliAmperes-hour per gram after 15 of the galvanostatic cycles.

Abstract: A positive electrode active material contains a compound represented by a chemical formula LiVOPO4. A crystal system of the compound is an orthorhombic system, and the amount of tetravalent V of the compound is 27.7 mass % or more and 28.2 mass % or less.

Abstract: Some embodiments of the present invention provide a system that adaptively charges a battery, wherein the battery is a lithium-ion battery which includes a transport-limiting electrode governed by diffusion, an electrolyte separator and a non-transport-limiting electrode. During operation, the system determines a lithium surface concentration at an interface between the transport-limiting electrode and the electrolyte separator based on a diffusion time for lithium in the transport-limiting electrode. Next, the system calculates a charging current or a charging voltage for the battery based on the determined lithium surface concentration. Finally, the system applies the charging current or the charging voltage to the battery.

Abstract: An anode electrode for an energy storage device includes both an ion intercalation material and a pseudocapacitive material. The ion intercalation material may be a NASICON material, such as NaTi2(PO4)3 and the pseudocapacitive material may be an activated carbon material. The energy storage device also includes a cathode, an electrolyte and a separator.

Abstract: The current disclosure relates to an anode material with the general formula MySb-M?Ox—C, where M and M? are metals and M?Ox—C forms a matrix containing MySb. It also relates to an anode material with the general formula MySn-M?Cx—C, where M and M? are metals and M?Cx—C forms a matrix containing MySn. It further relates to an anode material with the general formula Mo3Sb7-C, where —C forms a matrix containing Mo3Sb7. The disclosure also relates to an anode material with the general formula MySb-M?Cx—C, where M and M? are metals and M?Cx—C forms a matrix containing MySb. Other embodiments of this disclosure relate to anodes or rechargeable batteries containing these materials as well as methods of making these materials using ball-milling techniques and furnace heating.

Abstract: Disclosed is a positive electrode active material that provides an improved capacity density. Specifically disclosed is a positive electrode active material for a lithium ion battery with a layered structure represented by Lix(NiyM1-y)Oz (wherein M represents at least one element selected from a group consisting of Mn, Co, Mg, Al, Ti, Cr, Fe, Cu, and Zr; x is in the range from 0.9 to 1.2; y is in the range from 0.3 to 0.95; and z is in the range from 1.8 to 2.4), wherein, when a value obtained by dividing an average of peak intensities observed between 1420 and 1450 cm?1 and between 1470 and 1500 cm?1 by the maximum intensity of a peak appearing between 520 and 620 cm?1 in an infrared absorption spectrum obtained by FT-IR is represented by A, A satisfies the following relational formula: 0.20y?0.05?A?0.53y?0.06.

Abstract: Provided are a composite for an anode active material and a method of preparing the same. More particularly, the present invention provides a composite for an anode active material including a (semi) metal oxide and an amorphous carbon layer on a surface of the (semi) metal oxide, wherein the amorphous carbon layer comprises a conductive agent, and a method of preparing the composite.

Abstract: Provided are a composite and a method of preparing an anode slurry including the same. More particularly, the present invention provides a composite including a (semi) metal oxide, a conductive material on a surface of the (semi) metal oxide, and a binder, and a method of preparing an anode slurry including preparing a composite by dispersing a conductive material in an aqueous binder and then mixing with a (semi) metal oxide, and mixing the composite with a carbon material and a non-aqueous binder.

Abstract: A method is provided for fabricating a cyanometallate cathode battery. The method provides a cathode of AXM1YM2Z(CN)N.MH2O, where “A” is selected from a first group of metals, and where M1 and M2 are transition metals. The method provides an anode and a metal ion-permeable membrane separating the anode from the cathode. A third electrode is also provided including “B” metal ions selected from the first group of metals. Typically, the first group of metals includes alkali and alkaline metals. The method intercalates “B” metal ions from the third electrode to the anode, the cathode, or both the anode and cathode to form a completely fabricated battery. In one aspect, a solid electrolyte interface (SEI) layer including the “B” metal ions overlies a surface of the anode, the cathode, or both the anode and cathode. A cyanometallate cathode battery is also provided.

Abstract: A lithium-titanium complex oxide whose total water generation amount and total carbon dioxide generation amount measured by thermal decomposition GC-MS are preferably 1500 wt ppm or less and 2000 wt ppm or less, respectively, is obtained by subjecting a mixture of titanium compound and lithium compound to a heat treatment at 600° C. or above, cooling the obtained reaction product to 50° C. or below, and then subjecting the cooled reaction product to a reheat treatment involving heating to the maximum temperature of 300 to 700° C. and then cooling, wherein the dew point of the ambience of the reheat treatment is controlled at ?30° C. or below at a temperature of 200° C. or above.

Abstract: Provided is an electrode powder and an electrode plate for a lithium ion battery. The electrode powder includes a core and a nano-coating layer. The core contains a lithium compound. The nano-coating layer is disposed on a surface of the core and consists of a plurality of nanosheets.

Abstract: The present invention relates to an electrode of an electrochemical cell, comprising at least a fibrous active electrode material, wherein the fibers of the active material are arranged to form a nonwoven or felt-like self-supporting structure. Moreover the invention relates to a respective electrochemical cell and to a method of making such an electrode.

Abstract: The present invention includes a solvent system comprising a pristine nanoparticle solute suspended in a liquid solvent. The solute is selected from the group consisting of a metal oxide, a mixed metal oxide, a chalcogenide, and a mixed metal chalcogenide; and the solvent system is characterized by a value of chi less than about 0.00.

Abstract: A cathode active material including a lithium metal oxide represented by Formula 1 below: Li[LixMeyM?z]O2+d??Formula 1 wherein x+y+z=1, 0<x<0.33, 0.05?z?0.15, 0?d?0.1, Me includes at least one metal selected from the group consisting of manganese (Mn), vanadium (V), chromium (Cr), iron (Fe), cobalt (Co), nickel (Ni), aluminum (Al), and boron (B), and M? includes at least one metal selected from the group consisting of germanium (Ge), ruthenium (Ru), tin (Sn), titanium (Ti), niobium (Nb), and platinum (Pt).

Abstract: A negative electrode for rechargeable lithium batteries includes a current collector, a porous active material layer having a metal-based active material disposed on the current collector, and a high-strength binder layer on the porous active material layer. The high-strength binder layer has a strength ranging from 5 to 70 MPa. The negative active material for a rechargeable lithium battery according to the present invention can improve cycle-life characteristics by suppressing volume expansion and reactions of an electrolyte at the electrode surface.

Abstract: A nonaqueous electrolyte battery includes a negative electrode including a current collector and a negative electrode active material having a Li ion insertion potential not lower than 0.4V (vs. Li/Li+). The negative electrode has a porous structure. A pore diameter distribution of the negative electrode as determined by a mercury porosimetry, which includes a first peak having a mode diameter of 0.01 to 0.2 ?m, and a second peak having a mode diameter of 0.003 to 0.02 ?m. A volume of pores having a diameter of 0.01 to 0.2 ?m as determined by the mercury porosimetry is 0.05 to 0.5 mL per gram of the negative electrode excluding the weight of the current collector. A volume of pores having a diameter of 0.003 to 0.02 ?m as determined by the mercury porosimetry is 0.0001 to 0.02 mL per gram of the negative electrode excluding the weight of the current collector.

Abstract: The first aspect of the present invention provides a method of manufacturing an active material capable of improving the discharge capacity of a lithium-ion secondary battery. The method of manufacturing an active material in accordance with the first aspect of the present invention comprises the steps of heating a phosphate source, a vanadium source, and water so as to form an intermediate containing phosphorus and vanadium and having a specific surface area of at least 0.1 m2/g but less than 25 m2/g; and heating the intermediate, a water-soluble lithium salt, and water. The second aspect of the present invention provides a method of manufacturing an active material capable of improving the rate characteristic of a lithium-ion secondary battery.

Abstract: A process for preparing an at least partially lithiated transition metal oxyanion-based lithium-ion reversible electrode material, which includes providing a precursor of said lithium-ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt including an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. Also, lithiated or partially lithiated oxyanion-based-lithium-ion reversible electrode materials obtained by the aforesaid process.

Abstract: Provided are a porous composite expressed by Chemical Formula 1 and having a porosity of 5% to 90%, and a method of preparing the same: MOx??<Chemical Formula 1> where M and x are the same as described in the specification. According to the present invention, since a molar ratio (x) of oxygen to a molar ratio of (semi) metal in the porous composite is controlled, an initial efficiency of a secondary battery may be increased. Also, since the porous composite satisfies the above porosity, a thickness change rate of an electrode generated during charge and discharge of the secondary battery may be decreased and lifetime characteristics may be improved.

Abstract: According to one embodiment, an active material for batteries includes monoclinic ?-type titanium composite oxide containing at least one element selected from the group consisting of V, Nb, Ta, Al, Ga, and In, the at least one element being contained in an amount of 0.03 wt % or more and 3 wt % or less.

Abstract: According to one embodiment, an active material includes a monoclinic system ?-type titanium composite oxide. The monoclinic system ?-type titanium composite oxide includes a first element including at least one of Mo and W and satisfies the following formula (1): B>A??(1) In the formula, A is an intensity of a peak which is derived from (110) plane of the monoclinic system ?-type titanium composite oxide in a wide-angle X-ray diffraction pattern. B is an intensity of a peak which is derived from (002) plane of the monoclinic system ?-type titanium composite oxide in the wide-angle X-ray diffraction pattern.

Abstract: Disclosed is a storage device comprising a positive electrode material containing graphite; a negative electrode material containing an oxide of at least one metal element selected from Ti, Zr, V, Cr, Mo, Mn, Fe, Co, Ni, Cu, Zn, Sn, Sb, Bi, W and Ta, which may preferably contains a metal oxide containing at least Ti as a metal element; and an electrolyte solution. This storage device has high capacitance and high discharge voltage, thereby having high energy. Consequently, this storage device can have high energy density, while being excellent in cycle performances and rate performances.

Abstract: An active material for a secondary battery, a secondary battery including the active material, and a method of preparing an active material, the active material including a silicon-based core; and an aluminum-based coating layer on at least a part of the silicon-based core.

Abstract: A particulate composite of silicon, tin, and aluminum (or other suitable metal) is prepared as a negative electrode composition with increased lithium insertion capacity and durability for use with a metal current collector in cells of a lithium-ion battery or a lithium-sulfur battery. This electrode material is formed such that the silicon is present as a distinct amorphous phase in separate matrix phases of crystalline tin and crystalline aluminum. While the distinct tin and aluminum phases provide electron conductivity, each phase accommodates the insertion and extraction of lithium in the operation of the cell and all phases interact in minimizing mechanical damage to the material as the cell experiences repeated charge and discharge cycles. Other suitable metals for use in the composite with silicon and tin include copper and titanium.

Abstract: [Problem] To provide a catalyst which has high oxygen reduction activity, also has excellent durability, and is inexpensive and excellent in electric power generation cost as compared with noble metal catalysts such as platinum. [Solution to problem] A catalyst for a polymer electrolyte fuel cell, including a graphitized carbon powder and a niobium oxycarbonitride or a titanium oxycarbonitride as an active substance, and a polymer electrolyte fuel cell using the catalyst.

Abstract: A negative active material, a method of preparing the same, and a lithium secondary battery including the negative electrode. The negative active material includes a plurality of titanium oxide nanotubes, wherein the Raman shift of the negative active material includes a characteristic peak located at a Raman shift between about 680 cm?1 and about 750 cm?1.