Silicon Containing Patents (Class 429/252)
  • Patent number: 12074289
    Abstract: Articles and methods including additives in electrochemical cells, are generally provided. As described herein, such electrochemical cells may comprise an anode, a cathode, an electrolyte, and optionally a separator. In some embodiments, at least one of the anode, the cathode, the electrolyte, and/or the optional separator may comprise an additive and/or additive precursor. For instance, in some cases, the electrochemical cell comprises an electrolyte and an additive and/or additive precursor that is soluble with and/or is present in the electrolyte. In some embodiments, the additive precursor comprises a disulfide bond. In certain embodiments, the additive is a carbon disulfide salt. In some cases, the electrolyte may comprise a nitrate.
    Type: Grant
    Filed: December 21, 2022
    Date of Patent: August 27, 2024
    Assignee: Sion Power Corporation
    Inventors: Yuriy V. Mikhaylik, Igor P. Kovalev, Thomas Weiss
  • Patent number: 11862769
    Abstract: Disclosed herein are novel or improved separators, battery separators, lead battery separators, batteries, cells, and/or methods of manufacture and/or use of such separators, battery separators, lead battery separators, cells, and/or batteries. In accordance with at least certain embodiments, the present disclosure or invention is directed to novel or improved battery separators for lead acid batteries. In addition, disclosed herein are methods, systems and battery separators for enhancing battery life, reducing active material shedding, reducing grid and spine corrosion, reducing failure rate reducing acid stratification and/or improving uniformity in at least lead acid batteries, in particular batteries for electric rickshaws. In accordance with at least particular embodiments, the present disclosure or invention is directed to an improved separator for lead acid batteries wherein the separator includes improved membrane profiles, improved coatings, improved configurations, and/or the like.
    Type: Grant
    Filed: January 11, 2017
    Date of Patent: January 2, 2024
    Assignee: Daramic, LLC
    Inventors: Surendra Kumar Mittal, Naveen Prabhu Shanmugam
  • Patent number: 11699830
    Abstract: A secondary battery includes an electrode assembly disposed within a constraint. The electrode assembly comprises a population of unit cells comprising an electrode current collector layer, an electrode layer, a separator layer, a counter-electrode layer, and a counter-electrode current collector layer in stacked succession. A subset of the unit cell population includes extended spacer members between the electrode current collector layer and the counter-electrode current collector layer. One of the spacer members is spaced in a transverse direction from the other extended spacer member, at least a portion of the counter-electrode active material of the counter-electrode layer being located between the spacer members such that the portion of the counter-electrode active material and the spacer members lie in a common plane defined by x and z axes, wherein each of the extended spacer members extend a distance SD in the x-axis direction beyond an x-axis edge of the constraint.
    Type: Grant
    Filed: June 13, 2022
    Date of Patent: July 11, 2023
    Assignee: Enovix Operations Inc.
    Inventors: Robert S. Busacca, Aditya Mandalam, Jeffrey G. Buck, Anthony Calcaterra, Kim Han Lee, Prajanya Sunil Kendrekar
  • Patent number: 11631921
    Abstract: A secondary battery includes an electrode assembly disposed within a constraint. The electrode assembly comprises a population of unit cells comprising an electrode current collector layer, an electrode layer, a separator layer, a counter-electrode layer, and a counter-electrode current collector layer in stacked succession. A subset of the unit cell population includes extended spacer members between the electrode current collector layer and the counter-electrode current collector layer. One of the spacer members is spaced in a transverse direction from the other extended spacer member, at least a portion of the counter-electrode active material of the counter-electrode layer being located between the spacer members such that the portion of the counter-electrode active material and the spacer members lie in a common plane defined by x and z axes, wherein each of the extended spacer members extend a distance SD in the x-axis direction beyond an x-axis edge of the constraint.
    Type: Grant
    Filed: June 13, 2022
    Date of Patent: April 18, 2023
    Assignee: Enovix Operations Inc.
    Inventors: Robert S. Busacca, Aditya Mandalam, Jeffrey G. Buck, Anthony Calcaterra, Kim Han Lee, Prajanya Sunil Kendrekar
  • Patent number: 11322795
    Abstract: To carry out accurate defect inspection over a wide area, a defect inspection device includes: a radiation source section configured to emit an electromagnetic wave to a separator roll; and a sensor section configured to detect the electromagnetic wave that the radiation source section has emitted to the separator roll, the sensor section being configured to detect the electromagnetic wave before and after the separator roll is moved relative to the radiation source section.
    Type: Grant
    Filed: March 31, 2020
    Date of Patent: May 3, 2022
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Yoshitaka Shinomiya, Koji Kashu, Yasuyuki Kondo
  • Patent number: 11292882
    Abstract: A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer and an acid scavenger. In accordance with the present disclosure, the acid scavenger is an inorganic compound that is insoluble in the plasticizer and/or any extractions solvents used during the process. In one embodiment, the acid scavenger is a magnesium aluminum hydroxide carbonate.
    Type: Grant
    Filed: March 21, 2019
    Date of Patent: April 5, 2022
    Assignee: Celanese Sales Germany GmbH
    Inventors: Christian Ohm, Dominik Schreiber
  • Patent number: 11108089
    Abstract: The present disclosure relates to a cell, a battery and an electronic device. The cell includes a first electrode sheet and a second electrode sheet. The first electrode sheet includes a first current collector. The second electrode sheet includes a second current collector. The second current collector includes a starting section and a first bending segment connected to the starting section. A current collector opposite to the starting section and the first bending segment is configured as the second current collector. Thus, the cell is not internally provided with an opposite region between the first current collector and the second current collector, which may enhance the energy density of the cell and improve the safety of the cell.
    Type: Grant
    Filed: January 22, 2019
    Date of Patent: August 31, 2021
    Assignee: NINGDE AMPEREX TECHNOLOGY LIMITED
    Inventors: Jinhua He, Xiangrong Chen, Xuan Chen, Jiaxin An
  • Patent number: 11031654
    Abstract: Disclosed in present invention are a high-wettability separator and a preparation method therefor. The separator comprises an ethylene copolymer, a grafting polyolefin, an ultrahigh molecular weight polyethylene having a molecular weight ranging from 1.0×106 to 10.0×106, and a high-density polyethylene having a density ranging from 0.940 g/cm3 to 0.976 g/cm3, the content of the ethylene copolymer is 1-5 parts by weight, and the content of the grafting polyolefin is 0-5 parts by weight, on the basis that the total weight of the ultrahigh molecular weight polyethylene and the high-density polyethylene is 100 parts. The separator has a contact angle with lithium ion battery electrolyte of 20° to 40°.
    Type: Grant
    Filed: April 13, 2017
    Date of Patent: June 8, 2021
    Assignee: Shanghai Energy New Materials Technology Co., Ltd.
    Inventors: Alex Cheng, Lei Xiong, Honggui Deng, Fangbo He, Weiqiang Wang
  • Patent number: 10637028
    Abstract: Disclosed are a separator and an electrochemical device comprising the same, the separator comprising: a porous substrate having a plurality of pores; and a porous coating layer formed on at least one surface of the porous substrate and in at least one type of region of the pores of the porous substrate, the porous coating layer containing a plurality of inorganic particles and a binder polymer disposed on a part or the entirety of the surface of the inorganic particles to connect and fix the inorganic particles, wherein the binder polymer contains a copolymer including a vinylidene fluoride-derived repeat unit, a hexafluoropropylene-derived repeat unit, and a maleic acid monomethyl ester-derived repeat unit.
    Type: Grant
    Filed: July 11, 2016
    Date of Patent: April 28, 2020
    Assignee: LG Chem, Ltd.
    Inventors: Su-Jin Yoon, Min-Ji Kim
  • Patent number: 10607790
    Abstract: The capability of directly gelling an electrolyte within a lithium ion (or similar type) battery cell through the reaction of the electrolyte solution with a present battery separator is provided. Such a procedure results generally from the presence of suitable nanofibers within the battery separator structure that exhibit the potential for swelling in the presence of a suitable electrolyte formulation. In this manner, the capability of providing an entrenched gel within the battery separator for longer term viability and electrical generation is possible without externally gelling the electrolyte prior to battery cell introduction. The method of use of such a resultant battery, as well as the battery including such an automatic gelling battery separator/electrolyte combination, are also encompassed within this invention.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: March 31, 2020
    Assignee: Dreamweaver International, Inc.
    Inventor: Brian G. Morin
  • Patent number: 10541399
    Abstract: The present invention relates to a secondary battery separator, and a manufacturing method therefor. The secondary battery separator according to the present invention comprises an organic/inorganic composite porous layer for improving thermal resistance and physical strength, and since the organic/inorganic composite porous layer uses polymer particles as a binder, the secondary battery separator, compared with a separator using a solvent-type binder resin using organic solvents, exhibits excellent permeability.
    Type: Grant
    Filed: October 26, 2015
    Date of Patent: January 21, 2020
    Assignee: LG Chem, Ltd.
    Inventors: Joo-Sung Lee, Ji-Eun Kim, In-Gyoung Yu, Sun-Mi Jin, Da-Kyung Han
  • Patent number: 10270074
    Abstract: Non-woven webs that can be used as battery separators for batteries, such as lead acid batteries, are generally provided. In some embodiments, battery separators comprising a non-woven web including one or more chemical additives are provided. The chemical additives may impart beneficial properties, such as enhanced separator stability and/or battery performance. In some embodiments, the chemical additive(s) may confer resistance to oxidation, heavy metal deposition, and/or formation of short circuits during cycling of a battery including the battery separator. The respective characteristics and/or amounts of the chemical additive(s) may be selected to impart desirable properties while having relatively minimal or no adverse effects on another property of the battery separator and/or the battery.
    Type: Grant
    Filed: February 19, 2016
    Date of Patent: April 23, 2019
    Assignee: Hollingsworth & Vose Company
    Inventors: Gubbi Krishnappa Natesh, Mahadevaswamy Kodimole Mahadevappa, Krishna Marchigowda, Harish Moddegowdru Ramaswamy, Akshay Ashirgade, Nicolas Clement, John A. Wertz, Richard O. Angus, Jr., Zhiping Jiang
  • Patent number: 10014501
    Abstract: In some embodiments, a battery separator described herein may comprise a layer having a relatively low apparent density; for example, the density that includes any unoccupied space within the outermost boundaries of the layer may be relatively low. The low apparent density may be attributed to, at least in part, the geometry of the layer. For instance, in some embodiments, the layer may include undulations and/or have at least one non-planar surface (e.g., a corrugated layer; an embossed layer). In some embodiments, a battery comprising a layer having a relatively low apparent density may have desirable properties, including relatively low electrical resistance and/or relatively high capacity. The battery separators described herein may be well suited for a variety of battery types, including lead acid batteries.
    Type: Grant
    Filed: March 20, 2015
    Date of Patent: July 3, 2018
    Assignee: Hollingsworth & Vose Company
    Inventors: Gubbi Krishnappa Natesh, Krishna Marchigowda, Basavaraju Girisha, Kameswara Rao Patchigolla Venkata, Nicolas Clement, Akshay Ashirgade, Sachin Kumar, John A. Wertz, Richard O. Angus, Jr., Zhiping Jiang
  • Patent number: 9847518
    Abstract: A separator with a heat-resistant insulation layer for an electric device includes a resin porous substrate and a heat-resistant insulation layer containing heat-resistant particles and a binder, the heat-resistant insulation layer being formed on at least one surface of the resin porous substrate. The heat-resistant particles contain alumina and a parameter X is 0.018 to 0.336. Parameter X is represented by X=Ca×Rzjis/D, wherein C? is a ratio of the alumina, which occupies the heat-resistant particles, Rzjis is surface roughness of a surface of the heat-resistant insulation layer, the surface being opposite the resin porous substrate, and D is a thickness of the heat-resistant insulation layer.
    Type: Grant
    Filed: October 2, 2012
    Date of Patent: December 19, 2017
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Tamaki Hirai, Miyuki Nakai, Takashi Honda
  • Patent number: 9782728
    Abstract: The present invention relates to a membrane comprising a flat, flexible substrate having a plurality of openings and having a porous inorganic coating situated on and in said substrate, the material of the substrate being selected from woven or non-woven, electrically non-conductive fibers, characterized in that the substrate comprises polyaramide fibers that are pure or connected to fibers of the further polymer or at least of one of these further polymers, wherein the fibers of at least one of said further polymers comprise a melting point that is lower than the decomposition point of the polyaramide fibers.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: October 10, 2017
    Assignee: Evonik Degussa GmbH
    Inventors: Matthias Pascaly, Rolf-Walter Terwonne, Christian Hying
  • Patent number: 9711772
    Abstract: There is provided a separator used in an electrochemical device and more particularly, to a porous separator in which an organic/inorganic complex coating layer is applied to a porous substrate, a method for preparing the same, and an electrochemical device using the same.
    Type: Grant
    Filed: November 1, 2013
    Date of Patent: July 18, 2017
    Assignee: HANWHA TOTAL PETROCHEMICAL CO., LTD.
    Inventors: Ji Na Yoo, Jae Yong Hyun, Do Hoon Lee, Chang Hyun Choi
  • Patent number: 9562164
    Abstract: Provided is a micro-porous polyolefin composite film, the micro-porous polyolefin composite film including a porous coating layer containing a polymer binder and inorganic particles, the polymer binder simultaneously employing an aqueous polymer and a non-aqueous polymer. The contents of the aqueous polymer and the non-aqueous polymer are controlled, and thus optimize heat resistance, adhesive strength, and the moisture content to thereby improve high-temperature stability, and, further, improve the adhesive strength to thereby improve stability in production, and minimize the moisture content to thereby improve reliability of a battery.
    Type: Grant
    Filed: October 29, 2012
    Date of Patent: February 7, 2017
    Assignee: SK Innovation Co., Ltd.
    Inventors: Yong Kyoung Kim, Jang-Weon Rhee, Dong Jin Joo, Young Jun Woo, Jae Woong Kim
  • Patent number: 9559355
    Abstract: Method for preparing a particulate material including particles of an element of group IVa, an oxide thereof or an alloy thereof, the method including: (a) dry grinding particles from an ingot of an element of group IVa, an oxide thereof or an alloy thereof to obtain micrometer size particles; and (b) wet grinding the micrometer particles dispersed in a solvent carrier to obtain nanometer size particles having a size between 10 to 100 nanometers, optionally a stabilizing agent is added during or after the wet grinding. Method can include further steps of (c) drying the nanometer size particles, (d) mixing the nanometer size particles with a carbon precursor; and (e) pyrolyzing the mixture, thereby forming a coat of conductive carbon on at least part of the surface of the particles. The particulate material can be used in fabrication of an anode in an electrochemical cell or electrochemical storage energy apparatus.
    Type: Grant
    Filed: September 19, 2012
    Date of Patent: January 31, 2017
    Assignee: Hydro-Québec
    Inventors: Karim Zaghib, Abdelbast Guerfi, Dominic Leblanc
  • Patent number: 9413002
    Abstract: Method for preparing a particulate material including particles of an element of group IVa, an oxide thereof or an alloy thereof, the method including: (a) dry grinding particles from an ingot of an element of group IVa, an oxide thereof or an alloy thereof to obtain micrometer size particles; and (b) wet grinding the micrometer particles dispersed in a solvent carrier to obtain nanometer size particles having a size between 10 to 100 nanometers, optionally a stabilizing agent is added during or after the wet grinding. Method can include further steps of (c) drying the nanometer size particles, (d) mixing the nanometer size particles with a carbon precursor; and (e) pyrolyzing the mixture, thereby forming a coat of conductive carbon on at least part of the surface of the particles. The particulate material can be used in fabrication of an anode in an electrochemical cell or electrochemical storage energy apparatus.
    Type: Grant
    Filed: September 19, 2012
    Date of Patent: August 9, 2016
    Assignee: HYDRO-QUEBEC
    Inventors: Karim Zaghib, Abdelbast Guerfi, Dominic Leblanc
  • Patent number: 9269937
    Abstract: Disclosed are a separator for a battery, which comprises a gel polymer layer formed on a substrate, the gel polymer layer including a plurality of three-dimensional open pores interconnected with each other, and an electrochemical device comprising the same separator. Also, disclosed is a method for preparing the gel polymer layer including a plurality of three-dimensional open pores interconnected with each other on a substrate.
    Type: Grant
    Filed: June 22, 2012
    Date of Patent: February 23, 2016
    Assignees: LG Chem, Ltd., Toray Battery Seperator Film Co., Ltd.
    Inventors: Je-Young Kim, Pil-Kyu Park, Soon-Ho Ahn, Ki-Chul Hong, Oh Young Hyun
  • Patent number: 9190648
    Abstract: A lead-acid battery separator comprised of a porous membrane substrate having a front surface and a back surface and said front surface having a plurality of ribs. To enhance the substrate's stiffness, one or more coatings of a stiffening material may be adhered to the ribs on the substrate's surface.
    Type: Grant
    Filed: May 30, 2008
    Date of Patent: November 17, 2015
    Assignee: Daramic LLC
    Inventors: J. Kevin Whear, Jeffrey K. Chambers, Mohammed Naiha, Tejas R. Shah
  • Patent number: 9166250
    Abstract: The separator for a battery according to the present invention is a separator for a battery including an insulator layer containing a fibrous material having a heat resistant temperature of equal to or higher than 150° C., insulating inorganic fine particles and a binder, or a separator for a battery including a porous layer formed of a thermal melting resin and an insulator layer containing insulating inorganic fine particles and a binder, wherein water content per unit volume is equal to or smaller than 1 mg/cm3 when the separator is held for 24 hours in an atmosphere with a relative humidity of 60% at 20° C. The use of the separator for a battery according to the present invention makes it possible to provide a lithium secondary battery that has favorable reliability and safety and is excellent in storage characteristics and charge-discharge cycle characteristics.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: October 20, 2015
    Assignee: HITACHI MAXELL, LTD.
    Inventors: Hideaki Katayama, Eri Kojima, Shigeo Aoyama, Yoshinori Sato
  • Patent number: 9070935
    Abstract: Provided is a multilayer porous film having a porous film comprised of a resin composition comprising a polypropylene and one or more polyolefins other than polypropylenes and an inorganic filler-containing porous layer stacked on at least on one side of the porous film. The multilayer porous film is capable of preventing short circuit between two electrodes even when a heat generation amount is large at the time of abnormal heat generation and therefore satisfying both excellent heat resistance and good shutdown function.
    Type: Grant
    Filed: June 6, 2008
    Date of Patent: June 30, 2015
    Assignee: ASAHI KASEI E-MATERIALS CORPORATION
    Inventors: Hiroshi Murata, Hidenori Iwasawa, Hirosuke Naruto
  • Patent number: 9040202
    Abstract: A composite material tape and a lithium secondary battery using the same are provided. The composite material tape includes an organic base and at least one inorganic element dispersed within the organic base. The composite material tapes of the present invention exhibit improved Insulative and heat-resistant characteristics.
    Type: Grant
    Filed: February 22, 2012
    Date of Patent: May 26, 2015
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Cheon Soo Kim, Hong Sup Lim, Sang Won Lee
  • Patent number: 9005820
    Abstract: The lithium secondary battery of the present invention is a lithium secondary battery including a positive electrode, a negative electrode, a separator provided between the positive electrode and the negative electrode, and a non-aqueous electrolyte containing a lithium salt, wherein the non-aqueous electrolyte includes, as a solvent, an ionic liquid containing a bis(fluorosulfonyl)imide anion as an anion component; and the separator is a nonwoven fabric comprising at least one member selected from an organic fiber and a glass fiber and has a porosity of 70% or more.
    Type: Grant
    Filed: June 8, 2010
    Date of Patent: April 14, 2015
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Toshinori Sugimoto, Eriko Ishiko, Tetsuya Higashizaki, Michiyuki Kono
  • Patent number: 8993646
    Abstract: A porous polymer separator for use in a lithium ion battery is formed by a temperature-induced phase separation method. The porous polymer separator includes a polymer matrix having opposed major faces and a network of pore openings that extends between the major faces and permits intrusion of a lithium-ion conducting electrolyte solution. As part of the temperature-induced phase separation method, a single phase polymer solution that includes a polymer material dissolved in a miscible mixture of a real polymer solvent and a polymer non-solvent is prepared at an elevated temperature above room temperature. A film is then formed from the single phase polymer solution and cooled to phase-separate the polymer material into a solid polymer precipitate. Additional polymer non-solvent is then used to remove the real polymer solvent from the solid polymer precipitate followed by drying.
    Type: Grant
    Filed: November 18, 2011
    Date of Patent: March 31, 2015
    Assignee: GM Global Technology Operations LLC
    Inventor: Xiaosong Huang
  • Patent number: 8986888
    Abstract: A material for a battery or an accumulator, especially for a negative electrode of an accumulator, for example, a lithium ion secondary battery, the use of such a material, an electrode that includes such a material, a battery having such an electrode, and a process for producing such a material. The material includes carbon, an alloy and/or a mixture of silicon with at least one element of main group 1 of the Periodic Table of the Elements excluding lithium, and optionally at least one further metallic element and production-related impurities, the elements being distributed within a silicon phase in the case of a mixture, and a binder which binds carbon and the alloy and/or the mixture to give a solid material.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: March 24, 2015
    Assignee: MAGNA STEYR Battery Systems GmbH & Co OG
    Inventors: Cornelia Bayer, Christoph Stangl, Colin God, Stefan Koller, Nikolaus Hochgatterer, Heimo Kreimaier, Gabriel Stabentheiner
  • Publication number: 20150079479
    Abstract: Provided are a separator for a nonaqueous cell that has air permeability and is small in thickness while maintaining strength properties; and a nonaqueous cell having this separator. The separator includes a fiber sheet in which a polyvinyl alcohol fiber is incorporated in a proportion of 30% or more by mass (based on the fiber sheet). The fiber has a fiber breaking temperature in heated water of lower than 100° C. and higher than 85° C.
    Type: Application
    Filed: November 25, 2014
    Publication date: March 19, 2015
    Applicant: KURARAY CO., LTD.
    Inventors: Tomohiro HAYAKAWA, Hiroyuki KAWAI, Hideo HAYASHI, Koichi KAMBE
  • Publication number: 20140363738
    Abstract: A coated method for the preparation of a separator comprising multiple layers of glass or glass and ceramic particles for use in an electrochemical cell, an electrochemical cell comprising such a separator and the use of such an electrochemical cell. The method comprises the steps of providing a mixture of an organic polymeric material, glass or glass and ceramic particles and at least one solvent, and preparing a multilayer by phase inversion.
    Type: Application
    Filed: June 6, 2014
    Publication date: December 11, 2014
    Inventors: Pierre Blanc, Hilmi Buqa
  • Patent number: 8900740
    Abstract: A multilayer porous film, comprising a porous layer including inorganic particles and a resin binder on at least one surface of a porous film containing a polyolefin resin as a main component, wherein the inorganic particles contain an aluminum silicate compound as a main component.
    Type: Grant
    Filed: May 21, 2010
    Date of Patent: December 2, 2014
    Assignee: Asahi Kasei E-materials Corporation
    Inventors: Hiroshi Murata, Hidenori Iwasawa, Daisuke Inagaki, Masaki Ishikawa
  • Patent number: 8883297
    Abstract: A method for bonding a porous flexible membrane to a rigid material is disclosed. In some embodiments, the method includes applying, at a bonding site of the porous membrane, a pre-treatment solvent solution, drying the bonding site of the porous membrane, applying, at a bonding site of the rigid structure, a first solvent that is capable of dissolving a surface of the rigid material, applying, at the bonding site of the porous membrane, a second solvent that is capable of dissolving the polymeric residue material dissolved in the pre-treatment solvent solution, and pressing the porous membrane to the rigid material at their respective bonding sites. In some embodiments, the pre-treatment solvent solution may include a solvent carrying dissolved polymeric residue material configured to fill the pores of the porous membrane at the bonding site of the porous membrane.
    Type: Grant
    Filed: October 9, 2009
    Date of Patent: November 11, 2014
    Assignee: Imergy Power Systems, Inc.
    Inventors: Suresh Kumar Surapalan Nair, Majid Keshavarz, Saroj Kumar Sahu
  • Patent number: 8841031
    Abstract: Disclosed is a porous film comprising: (a) a porous substrate having pores; and (b) a coating layer formed on at least one region selected from the group consisting of a surface of the substrate and a part of the pores present in the substrate, wherein the coating layer comprises styrene-butadiene rubber. An electrochemical device using the porous film as a separator is also disclosed. The porous film is coated with a styrene-butadiene polymer, whose rubbery characteristics can be controlled, and thus provides improved scratch resistance and adhesion to other substrates. When the porous film is used as a separator for an electrochemical device, it is possible to improve the safety of the electrochemical device and to prevent degradation in the quality of the electrochemical device.
    Type: Grant
    Filed: December 7, 2005
    Date of Patent: September 23, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Seok Koo Kim, Sang Young Lee, Soon Ho Ahn, Jung Don Suk, Hyun Hang Yong
  • Publication number: 20140272526
    Abstract: A porous separator for a lithium ion battery is disclosed herein. The porous separator includes a non-woven membrane and a porous polymer coating. The porous polymer coating is formed on a surface of the non-woven membrane, or is infused in pores of the non-woven membrane, or is both formed on the surface of the non-woven membrane and infused in pores of the non-woven membrane.
    Type: Application
    Filed: March 14, 2013
    Publication date: September 18, 2014
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventor: Xiaosong Huang
  • Publication number: 20140255790
    Abstract: A polymeric porous substrate is described. The substrate may be used as battery separator or in other industrial applications. The polymeric porous substrate is formed from a polymer such as a polyimide or polyetherimide that, in the absence of porous particles, forms a skin when cast into a substrate. The polymeric porous substrate also includes porous particles.
    Type: Application
    Filed: November 9, 2012
    Publication date: September 11, 2014
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Scott Matteucci, Brian Nickless, Beata Kilos, Hao Ju
  • Patent number: 8822083
    Abstract: A negative electrode for a lithium-ion secondary battery, has a current collector and an active-material layer bound on a surface of the current collector. The active-material layer includes active materials, binders, conductive additives, and buffer materials. The active materials include Si and/or Sn, and the buffer materials comprise a silicone composite powder in which a spherical silicone-rubber powder is covered with a silicone resin.
    Type: Grant
    Filed: September 1, 2010
    Date of Patent: September 2, 2014
    Assignee: Kabushiki Kaisha Toyota Jidoshokki
    Inventors: Manabu Miyoshi, Hitotoshi Murase, Keiichi Hayashi, Shinji Suzuki
  • Patent number: 8795870
    Abstract: A lithium ion secondary battery includes a cathode and an anode being opposed to each other with a separator in between, and an electrolytic solution. One or more of the cathode, the anode, and the separator contain an organic silicon compound including a compound having a polysilsesquioxane skeleton.
    Type: Grant
    Filed: March 14, 2012
    Date of Patent: August 5, 2014
    Assignee: Sony Corporation
    Inventors: Ichiro Yamada, Tadahiko Kubota
  • Patent number: 8771859
    Abstract: A separator for batteries according to the present invention includes a multilayer porous film having a resin porous film containing a thermoplastic resin as a main component and a heat resistant porous layer containing heat resistant particles as a main component, and the heat resistant porous layer has a thickness of 1 to 15 ?m, and the 180° peel strength between the resin porous film and the heat resistant porous layer is 0.6 N/cm or more.
    Type: Grant
    Filed: March 10, 2010
    Date of Patent: July 8, 2014
    Assignee: Hitachi Maxell, Ltd.
    Inventors: Nobuaki Matsumoto, Hideaki Katayama, Yoshinori Sato
  • Patent number: 8741488
    Abstract: An electrode which has a Si-containing material layer and a porous film, and a lithium battery employing the same. In the electrode, the Si-containing material layer is applied on an electrode current collector and/or an electrode active material to protect the surface of the electrode current collector from oxidation. Also, the applied Si-containing material layer enhances the adhesion between the electrode current collector and the electrode active material to improve cycle life characteristics. Also, it increases the adhesion between the electrode active material and the porous film to reduce resistance, and to improve ohmic contacts and to lower the Shottkey barrier. In addition, the electrode includes the porous film functioning as a separator, and thus can provide a battery which is safe under conditions of overcharge and heat exposure without needing an additional separator.
    Type: Grant
    Filed: July 21, 2006
    Date of Patent: June 3, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jin-Hee Kim, Won-Chull Han, Jae-Yun Min
  • Publication number: 20140147710
    Abstract: Subject-matter of the invention is a separator for a lithium ion battery which separates the positive and the negative electrode of the lithium ion battery from one another and which is permeable to lithium ions, characterized in that the separator comprises at least one silica, preferably in the form of a xerogel, and at least one carbon component, as well as a lithium ion battery containing said separator.
    Type: Application
    Filed: November 26, 2013
    Publication date: May 29, 2014
    Applicant: Li-Tec Battery GmbH
    Inventor: Tim Schaefer
  • Patent number: 8715862
    Abstract: A lithium secondary battery includes a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, a separator separating the positive electrode from the negative electrode, and an electrolyte. The negative electrode active material includes a graphite core particle, at least one metal particle located on the graphite core particle, and a polymer film coating the graphite core particle and the at least one metal particle. The polymer includes a polyimide- or polyacrylate-based polymer.
    Type: Grant
    Filed: May 22, 2009
    Date of Patent: May 6, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Cheol-Hee Hwang, Bong-Chull Kim, Jong-Chan Kim, Se-Ho Park, Na-Rae Won
  • Patent number: 8696949
    Abstract: A particulate mixture which can be used as a precursor of lithium transition metal silicate-type compound of small particle size and low crystallinity, is provided. It is a mixture of silicon oxide particulates, transition metal oxide particulates, and lithium transition metal silicate particulates, and its powder X-ray diffraction measurement shows diffraction peaks near 2?=33.1° and near 2?=35.7°, and said silicon oxide particulates and said transition metal oxide particulates are amorphous, and said lithium transition metal silicate particulates are in a microcrystalline or amorphous state.
    Type: Grant
    Filed: August 28, 2012
    Date of Patent: April 15, 2014
    Assignee: Furukawa Electric Co., Ltd.
    Inventors: Michio Ohkubo, Takeshi Yagi, Michihiro Shimada, Naoki Uno, Yosuke Hirayama, Takeshi Nishimura, Toshio Tani
  • Patent number: 8697290
    Abstract: Electrodes with a multilayer or monolayer composite separator are described. The multilayer composite separator comprises multiple individual composite separator layers. Each individual composite separator layer comprises inorganic particulate material(s) and organic polymer(s) with different inorganic particulate material/polymer weight ratios. The multilayer composite separator layer is constructed in a way such that the composite separator layer adjacent to the electrode active material contains a higher weight percentage of the inorganic particulate material and lower weight percentage of the organic polymer than the composite separator layer outermost from the electrode current collector. Laminated cells comprising a positive electrode, a negative electrode, a laminated multilayer or monolayer composite separator layer are described, wherein at least one of the electrodes has a multilayer or monolayer composite separator disposed onto the surface of the electrode.
    Type: Grant
    Filed: January 12, 2010
    Date of Patent: April 15, 2014
    Assignee: A123 Systems LLC
    Inventors: Susan J. Babinec, Gregory B. Less, Dave Vieau
  • Patent number: 8628873
    Abstract: A separator for a lithium ion secondary battery with an alloy based negative electrode, wherein a dynamic friction coefficient of at least one surface is 0.1 or more and 0.4 or less, and a method for manufacturing the same.
    Type: Grant
    Filed: November 12, 2007
    Date of Patent: January 14, 2014
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Shinya Kawasoe, Hiroshi Hatayama, Takashi Ikemoto
  • Patent number: 8597836
    Abstract: An object of this invention is to improve battery performance such as a rate capability of a nonaqueous electrolyte solution secondary battery using a separator constituting a thermoplastic resin-based porous film containing a filler. This invention provides a nonaqueous electrolyte solution secondary battery separator which is formed from a porous film containing a thermoplastic resin and a filler contained in the thermoplastic resin and has a content of chlorine of 10 ppm or less or a content of iron of 100 ppm or less as well as relates to a nonaqueous electrolyte solution secondary battery using this separator.
    Type: Grant
    Filed: March 14, 2011
    Date of Patent: December 3, 2013
    Assignees: Mitsubishi Chemical Corporation, Mitsubishi Plastics, Inc.
    Inventors: Satoshi Nakashima, Yasushi Usami, Kazutaka Sakaki
  • Patent number: 8592070
    Abstract: A lithium rechargeable battery including a cathode, an anode, a separator for separating the cathode from the anode, and a non-aqueous electrolyte is provided. Each of the cathode and the anode includes an electrode collector and an electrode active material layer formed on the electrode collector. The separator comprises a porous membrane including a ceramic material and a binder. The peel strength of the electrode active material layer to the electrode collector is greater than the peel strength of the porous membrane to the electrode collector. Particularly, the peel strength of the active material layer to the electrode collector is 2 gf/mm or higher when measured before battery assembly, and the peel strength of the porous membrane to the electrode collector is 0.2 gf/mm or higher when measured before battery assembly.
    Type: Grant
    Filed: August 22, 2006
    Date of Patent: November 26, 2013
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Jinhee Kim
  • Patent number: 8592088
    Abstract: An electrode assembly for a battery that can improve safety of the ceramic layer and increase lifetime capacity and high rate charge/discharge capacity and low temperature charge/discharge capacity of the electrode assembly. The electrode assembly having a porous ceramic layer coated on at least one surface of the positive electrode plate or the negative electrode plate to prevent an electrical short between the positive electrode plate and the negative electrode plate, where a main peak of pore size of the ceramic layer is in the range of 20 nm to 80 nm, and a secondary battery including the electrode assembly.
    Type: Grant
    Filed: January 2, 2008
    Date of Patent: November 26, 2013
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Jinhee Kim
  • Patent number: 8592072
    Abstract: A battery separator (13) of the present invention includes a porous film (12) serving as a substrate and a crosslinked polymer layer (11) supported on the porous film (12). The crosslinked polymer layer (11) contains a crosslinked polymer and inorganic particles, and is non-porous. The crosslinked polymer is obtained by reacting a reactive polymer having a functional group in its molecule with a polyfunctional compound reactive with the functional group so as to crosslink at least a part of the reactive polymer. A lithium ion secondary battery of the present invention includes a positive electrode (14), a negative electrode (15), the battery separator (13) of the present invention disposed between the positive electrode (14) and the negative electrode (15), and a non-aqueous electrolyte solution. The battery separator (13) is disposed so that the porous film (12) faces the negative electrode (15) and the crosslinked polymer layer (11) faces the positive electrode (14).
    Type: Grant
    Filed: September 7, 2009
    Date of Patent: November 26, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Hiroyoshi Take, Shunsuke Noumi, Chiharu Odane, Takuji Shintani
  • Patent number: 8592089
    Abstract: A microporous polyethylene battery separator material (212), for use in a flooded-cell type lead-acid battery, benefits from increased porosity, enhanced wettability, and exceptionally low electrical resistance when an electrolyte-soluble pore former is employed in the manufacturing process. The pore former (210) is soluble in electrolytic fluid and therefore dissolves in-situ in sulfuric acid during battery assembly. The dissolution of the pore former leaves behind additional, larger voids (220) in the separator material and thereby enhances ionic diffusion and improves battery performance.
    Type: Grant
    Filed: May 15, 2008
    Date of Patent: November 26, 2013
    Assignee: Amtek Research International, LLC
    Inventors: Chi Thuong-Le La, Robert R. Waterhouse, Richard W. Pekala
  • Publication number: 20130295441
    Abstract: Provide is a separator for a power storage device, which reliably prevents short circuits between positive and negative electrode layers while maintaining the permeating ions function, and effectively suppresses shrinkage, and a power storage device using the separator. The separator is composed of a composite material including inorganic microparticles and an organic binder, the composite material has a pigment volume concentration of 55% or more, and the inorganic microparticles have an average particle size in the range of 0.2 to 3.0 ?m, and a general particle shape index in the range of 0.50 to 0.85. The composite material can have a pigment volume concentration in the range of 55 to 80%, or 55 to 65%.
    Type: Application
    Filed: July 11, 2013
    Publication date: November 7, 2013
    Inventors: Norihiro Yoshikawa, Ichiro Nakamura, Hisao Kawamura
  • Patent number: 8563158
    Abstract: A lithium secondary battery includes a negative electrode, a positive electrode, and an electrolyte. The negative electrode includes a negative electrode current collector and a negative electrode active material layer. The negative electrode active material layer is provided on the negative electrode current collector. The negative electrode active material layer contains silicon and oxygen. A low oxygen content layer is provided in a portion of the negative electrode active material layer on the negative electrode current collector side, the low oxygen content layer having an oxygen content lower than that of the remaining portion of the negative electrode active material layer. The thickness of the low oxygen content layer is 25% or less of the thickness of the negative electrode active material layer.
    Type: Grant
    Filed: April 1, 2011
    Date of Patent: October 22, 2013
    Assignee: SANYO Electric Co., Ltd.
    Inventor: Masaki Hirase