Organic Material Patents (Class 429/249)
  • Patent number: 11929531
    Abstract: A substrate for a composite membrane includes a microporous polyolefin membrane for carrying a hydrophilic resin compound within the pores of the microporous membrane wherein: the average pore diameter is 1 nm to 50 nm; the porosity is 50% to 78%; the membrane thickness is 1 ?m to 12 ?m; and, when a mixed solution of ethanol and water (volume ratio 1/2) is dripped onto a surface of the microporous polyolefin membrane which has not undergone hydrophilization treatment, the contact angle ?1 between the droplet and the surface is 0 to 90 degrees 1 second after the dripping, and the contact angle ?2 between the droplet and the surface is 0 to 70 degrees 10 minutes after the dripping, and the rate of change of the contact angle ((?1??2)/?1×100) is 10 to 50%.
    Type: Grant
    Filed: March 15, 2022
    Date of Patent: March 12, 2024
    Assignee: TEIJIN LIMITED
    Inventors: Takeo Yamaguchi, Yuhei Oshiba, Hidenori Ohashi, Jin Tomatsu, Koji Furuya, Takao Ohno, Mami Nanbu
  • Patent number: 11870037
    Abstract: Energy storage devices, battery cells, and batteries may include a battery cell component that may be or include a ceramic layer produced by methods including admixing a ceramic with a water-soluble dispersant to form a first mixture. The methods may include admixing an organic polymeric dispersant with the first mixture to form a second mixture. The methods may include admixing a binder with the second mixture to form a slurry. The methods may also include depositing the slurry on a substrate.
    Type: Grant
    Filed: July 10, 2018
    Date of Patent: January 9, 2024
    Assignee: Apple Inc.
    Inventors: Lin Ma, Mikyong Yoo, Richard M. Mank
  • Patent number: 11695117
    Abstract: In a non-aqueous electrolyte secondary battery according to one exemplary embodiment, a separator includes a substrate, a first filler layer containing phosphate particles and formed on at least one surface of the substrate, and a second filler layer containing inorganic particles and formed on a surface of the first filler layer on the side of the at least one surface of the substrate. The phosphate particles have a BET specific surface area of 5 m2/g or more and 100 m2/g or less.
    Type: Grant
    Filed: December 14, 2018
    Date of Patent: July 4, 2023
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Natsumi Goto, Masanori Sugimori, Yasunori Baba, Katsunori Yanagida, Nobuhiro Hirano
  • Patent number: 11411281
    Abstract: A multi-layer composite functional separator for lithium ion battery includes four layers. Layer A is a base separator. Layer B is a porous structural layer composed of insulating inorganic compounds or high temperature resistant polymers. Layer C is a porous layer composed of polymer microspheres with temperature-induced expansion characteristics. Layer D is a thermoplastic resin with a melting point of 80-110° C. and a crystallinity of <50%. Layer B, Layer C and Layer D are sequentially attached on either or both sides of Layer A. Compared with the existing lithium-ion battery separator, the multi-Layer Composite functional separator has excellent heat resistance. The thermal shrinkage rate is less than 1% when heated for less than one hour at 200° C. Inclusion of organic polymer microspheres produces thermal closure of the batteries, which improves the safety of the batteries.
    Type: Grant
    Filed: November 14, 2016
    Date of Patent: August 9, 2022
    Assignee: Shanghai Dinho New Material Technology Co., Ltd.
    Inventors: Jianhua Li, Suzhen Cheng, Zhengqiang Wang, Meihua Yu, Qingling Zhi, Xin Zhang, Shaojun Yan
  • Patent number: 11316232
    Abstract: A composite separator, a method of preparing the composite separator, and a secondary battery including the composite separator are provided. The composite separator includes a heat-resistant nonwoven fabric, and a porous coating film on at least one surface of the heat-resistant nonwoven fabric and including a multi-phase polymer including a stationary phase segment and a reversible phase segment, wherein an amount of the stationary phase segment is larger than an amount of the reversible phase segment.
    Type: Grant
    Filed: May 7, 2018
    Date of Patent: April 26, 2022
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Boksoon Kwon, Youngsuk Jung, Seungrim Yang, Dongsu Ko, Youngnam Kwon, Hyoungwoo Choi
  • Patent number: 11223049
    Abstract: A method of producing a powder mass for a lithium battery, the method comprising: (a) providing a solution containing a sulfonated elastomer dissolved in a solvent or a precursor in a liquid form or dissolved in a solvent; (b) dispersing a plurality of particles of a cathode active material in the solution to form a slurry; and (c) dispensing the slurry and removing the solvent and/or polymerizing/curing the precursor to form the powder mass, wherein the powder mass comprises multiple particulates and at least a particulate comprises one or a plurality of particles of a cathode active material being encapsulated by a thin layer of sulfonated elastomer having a thickness from 1 nm to 10 ?m, a fully recoverable tensile strain from 2% to 800%, and a lithium ion conductivity from 10?7 S/cm to 5×10?2 S/cm at room temperature.
    Type: Grant
    Filed: August 24, 2018
    Date of Patent: January 11, 2022
    Assignee: Global Graphene Group, Inc.
    Inventors: Baofei Pan, Hui He, Bor Z. Jang
  • Patent number: 11205821
    Abstract: The present invention provides a method for preparing an aromatic polyamide porous membrane and an aromatic polyamide porous membrane prepared by the above method. The method for preparing an aromatic polyamide porous membrane includes the following steps: mixing an ionic liquid with an aromatic polyamide into a solvent to form a mixed solution; the mixed solution forming a membrane in a coagulation bath; and extracting with an extractant to remove the solvent and the ionic liquid from the membrane to yield a porous membrane. In the method of the present invention, the application of the ionic liquid would greatly reduce the application of additives; further, the ionic liquid has a high stability and is easy to be separated from other solvents and be recycled, which assures the safety during the usage and recycle thereof.
    Type: Grant
    Filed: January 5, 2017
    Date of Patent: December 21, 2021
    Assignee: MICROVAST POWER SYSTEMS CO., LTD.
    Inventors: Qingjin Sun, Dawei Shen, Zuliang Shen, Hui Wu, Xiang Li
  • Patent number: 11145897
    Abstract: Systems and methods of providing an electrolyte membrane for metal batteries are described. According to aspects of the disclosure, a method includes preparing a mixture including an electrolyte portion and a matrix precursor portion, forming an electrolyte membrane by initiating polymerization of the gel-forming precursor and the gel-forming initiator to thereby form a polymer matrix, and disposing the electrolyte membrane between an anode and a cathode. The matrix precursor portion includes a gel-forming precursor and a gel-forming initiator. The electrolyte portion is disposed substantially throughout the polymer matrix.
    Type: Grant
    Filed: February 1, 2019
    Date of Patent: October 12, 2021
    Assignee: GM Global Technology Operations LLC
    Inventors: Fang Dai, Mahmoud Abd Elhamid, Mei Cai, Anne M. Dailly, Robert M. Lapierre
  • Patent number: 11124622
    Abstract: A functionalized microporous, mesoporous, or nanoporous membrane, material, textile, composite, laminate, or the like, and/or a method of making or using such functionalized membranes. The functionalized porous membrane may be a functionalized microporous, mesoporous, or nanoporous membrane that has a functional molecule attached, such as a functional polymer, to the surface and/or internal fibrillar structure of the membrane.
    Type: Grant
    Filed: January 18, 2019
    Date of Patent: September 21, 2021
    Assignee: Celgard, LLC
    Inventors: Kristoffer K. Stokes, Karl F. Humiston
  • Patent number: 11121432
    Abstract: Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic substituents. Also provided are electrochemical cells comprising such separators.
    Type: Grant
    Filed: September 14, 2020
    Date of Patent: September 14, 2021
    Assignee: Optodot Corporation
    Inventors: Steven A. Carlson, Ifenna Kingsley Anakor, Greg Robert Farrell
  • Patent number: 10992009
    Abstract: Provided is a nonaqueous electrolyte battery separator including a porous film (I) containing a polyolefin resin; and a porous layer (II) containing an inorganic filler, a water-soluble polymer having a structure represented by the following general formula (1), a water-insoluble polymer and a basic compound. The nonaqueous electrolyte battery separator is excellent in shape stability under a high temperature condition of 160 to 200° C.
    Type: Grant
    Filed: October 23, 2017
    Date of Patent: April 27, 2021
    Inventors: Kohei Ideta, Mitsuru Sugihara, Natsuko Chayama, Takanobu Omori
  • Patent number: 10930911
    Abstract: Provided is a separator which can make the electric field on the surface of a negative electrode for a metal secondary battery homogeneous to thereby prevent the formation of dendrites. A porous separator for metal secondary batteries, which has a polymer electrolyte layer formed on the surface layer of at least one main surface of a porous polyimide film. It is preferred that the polymer electrolyte layer is composed of both a polymer electrolyte material which is supported on at least one main surface of the porous polyimide film and a polymer electrolyte material which is supported in voids in a layered region that extends from the main surface.
    Type: Grant
    Filed: August 27, 2015
    Date of Patent: February 23, 2021
    Assignees: TOKYO OHKA KOGYO CO., LTD., TOKYO METROPOLITAN UNIVERSITY, 3DOM INC
    Inventors: Hiroyoshi Sago, Kiyoshi Kanamura, Hirokazu Munakata, Kazuhiro Imazawa
  • Patent number: 10923713
    Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode contains a lithium transition metal oxide, at least one element of a group 5 element and group 6 element in the periodic table, and a phosphoric acid compound. The nonaqueous electrolyte contains a lithium salt containing a P—O bond and a P—F bond.
    Type: Grant
    Filed: December 19, 2016
    Date of Patent: February 16, 2021
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Fumiharu Niina, Takashi Ko, Katsunori Yanagida
  • Patent number: 10897063
    Abstract: This application provides an electrolyte and an electrochemical device, in which the electrolyte comprises an additive A and an additive B, wherein the additive A is present in an amount of 0.01% to 10% by mass in the electrolyte and the additive B is present in an amount of 0.1% to 10% by mass in the electrolyte and the electrolyte has a conductivity of 6 mS/cm to 10 mS/cm at 25° C. The present invention can improve the cycle performance and storage performance of the electrochemical device, in particular, improve the cycle performance and storage performance of the electrochemical device under high temperature and high voltage conditions while keeping the low temperature performance.
    Type: Grant
    Filed: April 2, 2019
    Date of Patent: January 19, 2021
    Assignee: Contemporary Amperex Technology Co., Limited
    Inventors: Yao Jiang, Chunhua Hu, Tiancheng Yi, Lu Miao, Chengdu Liang
  • Patent number: 10804517
    Abstract: The present invention provides a separator for alkaline batteries and an alkaline battery improving reliability of prevention in internal short-circuits, and having good liquid retention and shielding property. To achieve this, the separator for alkaline batteries is made from a wet nonwoven fabric which contains at least alkali-resistant cellulose fibers and alkali-resistant synthetic fibers bound using a binder component; wherein an average pore diameter of the wet nonwoven fabric is 1 to 10 ?m. Moreover, the separator for alkaline batteries uses the wet nonwoven fabric having a maximum pore diameter of 20 to 60 ?m, a liquid retention rate of 400 to 700% during immersion in a 40% by mass KOH solution, and a swelling ratio of 30 to 45% during immersion in a 40% by mass KOH solution.
    Type: Grant
    Filed: February 27, 2017
    Date of Patent: October 13, 2020
    Assignee: Nippon Kodoshi Corporation
    Inventors: Kentaro Ogawa, Naoya Kawazawa, Masahiro Kuroiwa
  • Patent number: 10714725
    Abstract: Provided is a separator that is used in a nonaqueous electrolyte secondary battery, and that exhibits high impregnation ability with respect to a nonaqueous electrolyte solution. The separator for a nonaqueous electrolyte secondary battery disclosed herein is provided with: a porous substrate; a first coat layer formed on a pair of main surfaces and on an inner surface of the porous substrate; and a second coat layer formed on the first coat layer, at least on one main surface of the porous substrate. The first coat layer has higher hydrophilicity than the porous substrate. The second coat layer has higher hydrophobicity than the porous substrate. The hydrophilicity of an inner surface of the separator for a nonaqueous electrolyte secondary battery is higher than the hydrophilicity of the second coat layer, in a central region of the separator for a nonaqueous electrolyte secondary battery in the thickness direction thereof.
    Type: Grant
    Filed: August 30, 2018
    Date of Patent: July 14, 2020
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Yuji Yamamoto, Ryuta Sugiura
  • Patent number: 10707465
    Abstract: A method of producing a film is provided. The film includes a base material layer which is shrunk by heat and a functional layer which is dried while being restricted by the base material layer. The method involves heating the film while applying a tensile force in a direction of a length of the film so as to convey the film, and subjecting the film to a heat treatment while, in a distribution along a width of the film, a center part is higher in temperature than end parts. A center part sample of the film is smaller in curling amount with respect to the width of the film than an end part sample, or a standard deviation in curling amount with respect to the width is not more than 1 mm between two samples from respective end parts and a sample from the center part of the film.
    Type: Grant
    Filed: October 31, 2016
    Date of Patent: July 7, 2020
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Akihiko Shin, Atsuhiro Takata
  • Patent number: 10700358
    Abstract: A composition for preparing a porous insulating layer for a non-aqueous electrolyte rechargeable battery, the composition including a polyolefin-based polymer particle, a binder, an insulating inorganic particle, and a solvent including water and an organic solvent.
    Type: Grant
    Filed: November 5, 2018
    Date of Patent: June 30, 2020
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Tomoyuki Fukatani, Koji Hoshiba
  • Patent number: 10644289
    Abstract: Battery separators are generally provided. In some embodiments, the battery separators may comprise a non-woven web including a plurality of inorganic particles (e.g., silica). The non-woven web may include, in some embodiments, a plurality of relatively coarse glass fibers (e.g., having an average diameter of greater than about 1.5 microns), e.g., such that the non-woven web has a particular largest pore size and median pore size. The combination of inorganic particles with a non-woven web having features described herein may exhibit enhanced electrolyte stratification distance and/or reduced electrolyte filling time. In some embodiments, such improvements may be achieved while having relatively minimal or no adverse effects on another property of the battery separator and/or the overall battery.
    Type: Grant
    Filed: July 12, 2017
    Date of Patent: May 5, 2020
    Assignee: Hollingsworth & Vose Company
    Inventor: Zhiping Jiang
  • Patent number: 10490793
    Abstract: Disclosed is a separator for a lithium battery, which includes a first polymer and a second polymer, has an interchain distance of 2.8 ? or less, and is free from pores, wherein the second polymer has higher polarity than the first polymer.
    Type: Grant
    Filed: June 1, 2016
    Date of Patent: November 26, 2019
    Assignee: Korea Advanced Institute of Science and Technology
    Inventors: Jang Wook Choi, Byung Gon Kim, Joo Seong Kim
  • Patent number: 10243187
    Abstract: A method for preparing a high temperature melt integrity separator, the method comprising spinning a polymer by one or more of a mechanical spinning process and an electro-spinning process to produce fine fibers.
    Type: Grant
    Filed: August 9, 2016
    Date of Patent: March 26, 2019
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Roy Martinus Adrianus l'Abee, Richard Peters, Erich Otto Teutsch, Huiqing Wu, Yanju Wang, Qunjian Huang, Wujun Rong, Jacob Scott LaBelle
  • Patent number: 10205148
    Abstract: A rechargeable lithium battery includes an electrode assembly including a positive electrode including a positive current collector, a first separator on the positive electrode, a negative electrode including a negative current collector on the first separator, and a second separator on the negative electrode. The positive current collector and the negative current collector each have respective uncoated regions at two sides thereof. The first separator includes a first substrate including a polyolefin-based resin particle, and a coating layer on a side of the first substrate the coating layer being an inorganic layer or an organic layer. The second separator includes a second substrate including a polyolefin-based resin particle, and an outermost region and/or a central region of the electrode assembly includes one of the uncoated regions of the positive current collector, the first separator, one of the uncoated regions of the negative current collector and the second separator.
    Type: Grant
    Filed: April 14, 2014
    Date of Patent: February 12, 2019
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Cheon-Soo Kim, Kyeong-Min Jeong
  • Patent number: 10158110
    Abstract: In an aspect, the invention provides separator systems for electrochemical systems providing electronic, mechanical and chemical properties useful for a range of electrochemical storage and conversion applications. Separator systems of some embodiments, for example, provide structural, physical and electrostatic attributes useful for managing and controlling dendrite formation in lithium and zinc based batteries. In an embodiment, for example, separator systems of the invention have a multilayer, porous geometry supporting excellent ion transport properties while at the same time providing a barrier effective to prevent dendrite initiated mechanical failure, shorting and/or thermal runaway.
    Type: Grant
    Filed: July 10, 2012
    Date of Patent: December 18, 2018
    Assignee: California Institute of Technology
    Inventor: Farshid Roumi
  • Patent number: 10059085
    Abstract: A roll is made of a porous film in a belt-like shape, the porous film having a width of not smaller than 20 mm. In a case where a roughness along a width direction of an outermost surface of the roll is measured at 1 mm intervals across an entire width of the outermost surface, a difference between a maximum roughness value and a minimum roughness value in a distance of 20 mm in the width direction of the outermost surface is less than 25 ?m.
    Type: Grant
    Filed: August 28, 2015
    Date of Patent: August 28, 2018
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Takahiro Okugawa, Yutaka Suzuki, Tomoaki Ozeki, Chikara Murakami
  • Patent number: 10056595
    Abstract: A battery separator includes a porous membrane A including a polyolefin resin, and a porous membrane B laminated thereon including a fluororesin and inorganic particles or cross-linked polymer particles, wherein the particles are contained in an amount of 80 wt % to 97 wt % of the porous membrane B and have an average diameter being not less than 1.5 times and less than 50 times the average pore size of the porous membrane A, and a specific expression 1 and a specific expression 2 are satisfied.
    Type: Grant
    Filed: March 28, 2013
    Date of Patent: August 21, 2018
    Assignee: Toray Industries, Inc.
    Inventors: Naoki Mizuno, Michihiko Irie, Ken Shimizu
  • Patent number: 10050313
    Abstract: A lithium ion battery includes a positive and a negative electrode, and a nanoporous or microporous polymer separator soaked in electrolyte solution and disposed between the electrodes. At least two different chelating agents are included and selected to complex with: i) two or more different transition metal ions; ii) a transition metal ion in two or more different oxidation states; or iii) both i) and ii). The at least two different selected chelating agents are to complex with transition metal ions in a manner sufficient to not affect movement of lithium ions across the separator during operation of the battery. The chelating agents are: dissolved or dispersed in the electrolyte solution; grafted onto the polymer of the separator; attached to the binder material of the negative and/or positive electrode; disposed within pores of the separator; coated on a surface of the separator; and/or coated on a surface of an electrode.
    Type: Grant
    Filed: June 19, 2016
    Date of Patent: August 14, 2018
    Assignees: GM GLOBAL TECHNOLOGY OPERATIONS LLC, BAR-ILAN UNIVERSITY
    Inventors: Shalom Luski, Doron Aurbach, Bob R. Powell, Jr., Ion C. Halalay, Timothy J. Fuller, Anjan Banerjee, Baruch Ziv, Yuliya Shilina
  • Patent number: 10002719
    Abstract: The present disclosure provides a separator comprising a porous substrate, a porous coating layer and a binder layer, the binder comprising at least one homopolymer of polyvinylidene fluoride and at least one copolymer of polyvinylidene fluoride (PVDF)-co-hexafluoropropylene (HFP) so that a content difference of hexafluoropropylene (HFP) present in the two compounds is about 3 wt % or higher.
    Type: Grant
    Filed: April 20, 2015
    Date of Patent: June 19, 2018
    Assignees: LG Chem, Ltd., TORAY INDUSTRIES, INC.
    Inventors: Jeong-Min Ha, Su-Jin Yoon, Jong-Hun Kim, Byoung-Jin Shin, Joo-Sung Lee, Jin-Woo Kim, Da-Kyung Han
  • Patent number: 9960454
    Abstract: Examples of the present technology may include a method of making a non-woven fiber mat. The wet nonwoven fiber mat may include a first plurality of first glass fibers and a second plurality of second glass fibers. The first plurality of first glass fibers may have nominal diameters of less than 5 ?m, and the second plurality of second glass fibers may have nominal diameters of greater than 6 ?m. The method may further include curing the binder composition to produce the nonwoven fiber mat. The nonwoven fiber mat may have an average 40 wt. % sulfuric acid wick height of between about 1 cm and about 5 cm after exposure to 40 wt. % sulfuric acid for 10 minutes conducted according to method ISO8787, and the nonwoven fiber mat may have a total normalized tensile strength greater than 2 (lbf/in)/(lb/sq) fora sq (100 ft2).
    Type: Grant
    Filed: May 19, 2017
    Date of Patent: May 1, 2018
    Assignee: Johns Manville
    Inventors: Zhihua Guo, Souvik Nandi, Jawed Asrar, Albert G Dietz, III
  • Patent number: 9954211
    Abstract: A separator includes a porous substrate, a porous organic-inorganic coating layer formed on at least one surface of the porous substrate, and an organic coating layer formed on the surface of the organic-inorganic coating layer. The porous organic-inorganic coating layer includes a mixture of inorganic particles and a first binder polymer. The first binder polymer contains a copolymer including (a) a first monomer unit including either at least one amine group or at least one amide group or both in the side chain thereof and (b) a (meth)acrylate having a C1-C14 alkyl group as a second monomer unit. The organic coating layer is formed by dispersing a second binder polymer on the surface of the organic-inorganic coating layer, leaving scattered uncoated areas. The porous organic-inorganic coating layer of the separator has a high packing density, enabling the fabrication of a thin battery in an easy manner without losing stability.
    Type: Grant
    Filed: August 6, 2015
    Date of Patent: April 24, 2018
    Assignees: LG CHEM, LTD., TORAY INDUSTRIES, INC
    Inventors: Jeong-Min Ha, No-Ma Kim, Byeong-Gyu Cho, Kee-Young Kim, Sun-Mi Jin
  • Patent number: 9905825
    Abstract: Provided is a separator for a nonaqueous electrolyte battery, including a porous substrate and an adhesive porous layer that is provided on one side or both sides of the porous substrate and contains an adhesive resin. The ratio of the standard deviation of the areal weight of the adhesive porous layer to the mean of the areal weight of the adhesive porous layer (g/m2) (standard deviation/mean) is 0.3 or less.
    Type: Grant
    Filed: July 30, 2013
    Date of Patent: February 27, 2018
    Assignee: TEIJIN LIMITED
    Inventors: Satoshi Nishikawa, Takashi Yoshitomi
  • Patent number: 9882189
    Abstract: Provided is a separator for a nonaqueous electrolyte battery, which includes a porous substrate and an adhesive porous layer that is provided on at least one side of the porous substrate and contains an adhesive resin. The separator has a pore size distribution such that, as measured by a pore size distribution measurement test, the pore size at the maximum value of the maximum peak is within a range of 0.02 ?m to 0.1 ?m, and the pore size distribution range value ? defined as follows is 0.4 or less. The pore size distribution range value ? herein is a value calculated by the following equation from pore sizes D90, D10, and D50 corresponding to cumulative pore size distributions of 90%, 10%, and 50%, respectively: pore size distribution range value ?=(D90?D10 )/D50.
    Type: Grant
    Filed: July 30, 2013
    Date of Patent: January 30, 2018
    Assignee: TEIJIN LIMITED
    Inventors: Ayumi Iwai, Satoshi Nishikawa, Takashi Yoshitomi
  • Patent number: 9728756
    Abstract: Disclosed is a battery separator, comprising two fiber regions comprising glass fibers, and a middle fiber region disposed between them comprising larger average diameter fibers and specified amounts of silica, or fine fibers, or both; and processes for making the separator. Also disclosed is a battery separator, comprising a fiber region and either one or two silica-containing region(s) adjacent thereto, each of the regions containing a specified amount of silica; and processes for making the separator. Such separators are useful, e.g., in lead-acid batteries.
    Type: Grant
    Filed: February 8, 2017
    Date of Patent: August 8, 2017
    Assignee: Hollingsworth & Vose Company
    Inventors: Akshay Ashirgade, Zhiping Jiang
  • Patent number: 9716293
    Abstract: Examples of the present technology may include a method of making a non-woven fiber mat. The wet nonwoven fiber mat may include a first plurality of first glass fibers and a second plurality of second glass fibers. The first plurality of first glass fibers may have nominal diameters of less than 5 ?m, and the second plurality of second glass fibers may have nominal diameters of greater than 6 ?m. The method may further include curing the binder composition to produce the nonwoven fiber mat. The nonwoven fiber mat may have an average 40 wt. % sulfuric acid wick height of between about 1 cm and about 5 cm after exposure to 40 wt. % sulfuric acid for 10 minutes conducted according to method ISO8787, and the nonwoven fiber mat may have a total normalized tensile strength greater than 2 (lbf/in)/(lb/sq) for a sq (100 ft2).
    Type: Grant
    Filed: March 9, 2015
    Date of Patent: July 25, 2017
    Assignee: Johns Manville
    Inventors: Zhihua Guo, Souvik Nandi, Jawed Asrar, Albert G Dietz, III
  • Patent number: 9666849
    Abstract: A separator may include (A) a porous substrate having pores, and (B) a porous coating layer formed on at least one surface of the porous substrate and made from a mixture of inorganic particles and a binder polymer, and the binder polymer may contain a copolymer of (a) a first monomer unit with at least one of an amine group and an amide group at a side chain, and (b) a second monomer unit of (meth)acrylate with an alkyl group having 1 to 14 carbon atoms. The porous coating layer of the separator may have a high packing density, thereby easily forming a thin film battery without hindering safety, and may have good adhesive strength with the porous substrate, thereby preventing detachment of the inorganic particles in the porous coating layer during assembly of an electrochemical device.
    Type: Grant
    Filed: September 17, 2012
    Date of Patent: May 30, 2017
    Assignees: LG Chem, Ltd., Toray Battery Separator Film Co., Ltd.
    Inventors: Jeong-Min Ha, Kee-Young Kim, Byeong-Gyu Cho, Sun-Mi Jin, No-Ma Kim, Jong-Hun Kim, Byoung-Jin Shin
  • Patent number: 9660238
    Abstract: A secondary battery porous membrane, manufactured by a slurry for secondary battery porous membrane, which is superior in coating priority and dispersibility of non-conductive organic particles, which improves cycle characteristic of the obtained secondary battery, which has high flexibility and can prevent powder falls, and which has less content of moisture amount; and non-conductive organic particles, which can be suitably used as a secondary battery porous membrane and has less content of metallic foreign particles. The slurry for secondary battery porous membrane comprises; a binder including a polymerized unit of vinyl monomer having a hydrophilic acid group, a non-conductive organic particle having a functional group, cross-linkable with the hydrophilic acid group and a solvent.
    Type: Grant
    Filed: October 7, 2011
    Date of Patent: May 23, 2017
    Assignee: Zeon Corporation
    Inventors: Taku Matsumura, Takuya Kaneda, Yasuhiro Wakizaka
  • Patent number: 9627668
    Abstract: Disclosed is a battery separator, comprising two fiber regions comprising glass fibers, and a middle fiber region disposed between them comprising larger average diameter fibers and specified amounts of silica, or fine fibers, or both; and processes for making the separator. Also disclosed is a battery separator, comprising a fiber region and either one or two silica-containing region(s) adjacent thereto, each of the regions containing a specified amount of silica; and processes for making the separator. Such separators are useful, e.g., in lead-acid batteries.
    Type: Grant
    Filed: December 14, 2016
    Date of Patent: April 18, 2017
    Assignee: Hollingsworth & Vose Company
    Inventors: Akshay Ashirgade, Zhiping Jiang
  • Patent number: 9525169
    Abstract: A nickel-hydrogen storage battery includes a positive electrode, a negative electrode using an AB5 based hydrogen-absorbing alloy, and a separator arranged between the positive and negative electrodes. The AB5 based hydrogen-absorbing alloy includes an A element, which is a constituent element of a misch metal, and a B element, which includes nickel and cobalt. The ratio of the amount of substance of the B element to that of the A element is 5.2 or more and 5.4 or less. The ratio of the amount of substance of cobalt to that of the A element is 0.15 or more and 0.4 or less. The liquid retention volume (V1) and the true volume (V2) of the separator, the theoretical capacity of the negative electrode (C1), and the theoretical capacity of the positive electrode (C2) satisfy the following expression. 2.0?V1/V2×C1/C2?3.
    Type: Grant
    Filed: March 25, 2014
    Date of Patent: December 20, 2016
    Assignee: PRIMEARTH EV ENERGY CO., LTD.
    Inventors: Shinichiro Ito, Yuki Sakito, Hiroyuki Sakamoto, Katsumi Kashiwagi
  • Patent number: 9512307
    Abstract: A polymer composition has homogenous dispersion of a first polymer with a second polymer. The first polymer includes but is not limited to ethylene based homopolymer and ethylene based copolymer. The second polymer has molecular weight higher than the molecular weight of the first polymer and heat of fusion greater than 200 J/g.
    Type: Grant
    Filed: October 4, 2013
    Date of Patent: December 6, 2016
    Assignee: Reliance Industries Limited
    Inventors: Ajit Behari Mathur, Satya Srinivasa Rao Gandham, Uma Sankar Satpathy, Krishna Renganath Sarma, Vijay Shivaji Kadam, Raksh Vir Jasra
  • Patent number: 9431641
    Abstract: An object of the invention is to provide a separator for a nonaqueous secondary battery, which has good adhesion to electrodes and is also capable of ensuring sufficient ion permeability even after attachment to an electrode. The separator for a nonaqueous secondary battery of the invention includes a porous substrate and an adhesive porous layer formed on at least one side of the porous substrate and containing a polyvinylidene-fluoride-based resin. The separator for a nonaqueous secondary battery is characterized in that the polyvinylidene-fluoride-based resin has a weight average molecular weight of 600,000 to 3,000,000.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: August 30, 2016
    Assignee: TEIJIN LIMITED
    Inventor: Satoshi Nishikawa
  • Patent number: 9419259
    Abstract: The invention relates to a battery assembly with high thermal conductivity. The battery assembly comprises a metal case having a hollow accommodation cavity formed therein, a plurality of battery cells installed parallel to one another within the metal case, and a common electrode for connection to the other electrode in each of the battery cells. Each of the battery cells has two electrodes, with one of the electrodes that corresponds to those of the rest of the battery cells being connected in a thermally conductive manner to the metal case. The invention takes advantage of high thermal conductivity of metallic material and dissipates heat by connecting the metal case to the battery electrodes. The invention further comprises fixation troughs formed on the metal case, thereby reducing the size of the assembly.
    Type: Grant
    Filed: April 22, 2012
    Date of Patent: August 16, 2016
    Assignee: Atieva, Inc.
    Inventors: Chia-Ming Chuang, David YuanJei Tse
  • Patent number: 9401505
    Abstract: A polyolefin porous separator includes a polyolefin porous base film, and a coating layer formed on one or both sides of the base film. The coating layer includes inorganic particles. The inorganic particles include first inorganic particles having an average particle size ranging from 150 nm to 600 nm, and second inorganic particles having an average particle size ranging from 5 nm to 90 nm. The separator has a thermal conductivity of 0.3 W/m·K or more.
    Type: Grant
    Filed: February 27, 2013
    Date of Patent: July 26, 2016
    Assignee: CHEIL INDUSTRIES, INC.
    Inventors: Ki Chul Hong, Myung Kook Park, Jae Goo Doh, Jun Ho Chung, Geon Ja Lim
  • Patent number: 9281508
    Abstract: An object of the invention is to provide a separator for a nonaqueous secondary battery, which has good adhesion to electrodes and is also capable of ensuring sufficient ion permeability even after attachment to electrodes. The separator for a nonaqueous secondary battery of the invention includes a porous substrate and an adhesive porous layer that is formed on at least one side of the porous substrate and contains a polyvinylidene-fluoride-based resin. The separator for a nonaqueous secondary battery is characterized in that the adhesive porous layer has a crystal size of 1 to 13 nm.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: March 8, 2016
    Assignee: TEIJIN LIMITED
    Inventor: Satoshi Nishikawa
  • Patent number: 9269938
    Abstract: An object of the invention is to provide a separator for a nonaqueous secondary battery, which has good adhesion to electrodes and is also capable of ensuring sufficient ion permeability even after attachment to an electrode. The separator for a nonaqueous secondary battery of the invention includes a porous substrate and an adhesive porous layer formed on at least one side of the porous substrate and containing a polyvinylidene-fluoride-based resin. The separator for a nonaqueous secondary battery is characterized in that the adhesive porous layer has a crystallinity of 20 to 35%.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: February 23, 2016
    Assignee: TEIJIN LIMITED
    Inventor: Satoshi Nishikawa
  • Patent number: 9203110
    Abstract: A polymer battery is provided with a positive electrode active material layer, a negative electrode active material layer placed in opposition to the positive electrode active material layer, a polymer electrolyte layer disposed between the positive electrode active material layer and the negative electrode active material layer, and a distance defining member included in the polymer electrolyte layer to define a distance between the positive electrode active material layer and the negative electrode active material layer.
    Type: Grant
    Filed: December 21, 2012
    Date of Patent: December 1, 2015
    Assignee: NISSAN MOTOR CO., LTD.
    Inventors: Tatsuhiro Fukuzawa, Kouichi Nemoto
  • Patent number: 9077038
    Abstract: A lithium ion battery includes a positive electrode, a negative electrode, and a microporous polymer separator soaked in an electrolyte solution. The microporous polymer separator is disposed between the positive electrode and the negative electrode. An ion exchange polymer material is any of i) incorporated as a binder in any of the positive electrode or the negative electrode, ii) deposited onto a surface of any of the positive electrode or the negative electrode, iii) incorporated into the microporous polymer separator, or iv) deposited onto a surface of the microporous polymer separator. Examples of methods for making the ion exchange polymer material for use in the lithium ion batteries are also disclosed herein.
    Type: Grant
    Filed: November 6, 2012
    Date of Patent: July 7, 2015
    Assignee: GM Global Technology Operations LLC
    Inventors: Ion C. Halalay, Timothy J. Fuller, Lijun Zou, Thomas C. Jackson
  • Patent number: 9065119
    Abstract: An object of the invention is to provide a separator for a nonaqueous secondary battery, which has good adhesion to electrodes, is capable of ensuring sufficient ion permeability even after attachment to electrodes, and further includes an adhesive porous layer having dynamic physical properties sufficient to withstand heat pressing and a uniform porous structure. The separator for a nonaqueous secondary battery of the invention includes a porous substrate and an adhesive porous layer that is formed on at least one side of the porous substrate and contains a polyvinylidene-fluoride-based resin. The separator for a nonaqueous secondary battery is characterized in that the adhesive porous layer has a porosity of 30 to 60% and an average pore size of 1 to 100 nm.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: June 23, 2015
    Assignee: TEIJIN LIMITED
    Inventor: Satoshi Nishikawa
  • Patent number: 9023534
    Abstract: The present invention provides a fiber having a nano-order fiber diameter, which is produced by without a process of dehydration and cyclization by a heat treatment after fiber spinning and has excellent heat resistance and mechanical strength, and a non-woven fabric composed of the fiber, and discloses the polyamide-imide fiber and the non-woven fabric having an average fiber diameter of from 0.001 ?m to 1 ?m and also discloses the process for producing threrof. The present invention also provides a separator for an electronic component which has a high conductivity and a small separator thickness and is improved in safety during reflow soldering or short-circuiting, and discloses the separator composed of a non-woven fabric obtained by an electro-spinning method.
    Type: Grant
    Filed: July 27, 2006
    Date of Patent: May 5, 2015
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Masahiko Nakamori, Yasuo Ohta, Hisato Kobayashi, Syoji Oda, Nobuyuki Taniguchi, Daisuke Sakura, Katsuya Shimeno
  • Publication number: 20150118540
    Abstract: A separator according to the present disclosure is a separator for a non-aqueous electrolyte secondary battery that includes a porous layer that contains cellulose fibers and resin particles. The ratio of the amount of the resin particles to the total amount of the cellulose fibers and the resin particles increases with decreasing distance from one surface of the porous layer.
    Type: Application
    Filed: October 17, 2014
    Publication date: April 30, 2015
    Inventors: ISAO FUJIWARA, NOBUHIRO HIRANO, MASARU WATANABE
  • Patent number: 9017878
    Abstract: Disclosed is an electrode whose surface includes an organic/inorganic composite porous coating layer comprising heat-absorbing inorganic particles and a binder polymer, wherein the heat-absorbing inorganic particle is at least one particle selected from the group consisting of antimony-containing compounds, metal hydroxides, guanidine-based compounds, boron-containing compounds and zinc tartrate compounds. A separator using the heat-absorbing inorganic particles as a component for forming or coating the separator, and an electrochemical device including the electrode and/or the separator are also disclosed. The separator using the heat-absorbing inorganic particles as a component for forming or coating the separator can ensure excellent thermal safety and minimizes degradation of the quality of a battery.
    Type: Grant
    Filed: February 16, 2007
    Date of Patent: April 28, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Seok-Koo Kim, Hyun-Min Jang, Sang-Young Lee, Jang-Hyuk Hong
  • Patent number: 9012058
    Abstract: Disclosed is a lithium secondary battery. The lithium secondary battery includes a cathode, an anode, a separator and a non-aqueous electrolyte solution. The separator includes a porous substrate, and a coating layer coated on at least one surface of the porous substrate and including a mixture of inorganic particles and a binder polymer. The non-aqueous electrolyte solution contains an ionizable lithium salt, an organic solvent, and a dinitrile compound having a specific structure. The lithium secondary battery is very safe without side reactions of the electrolyte solution. Therefore, the lithium secondary battery exhibits excellent cycle life and output performance characteristics.
    Type: Grant
    Filed: April 16, 2012
    Date of Patent: April 21, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Jong-Ho Jeon, Doo-Kyung Yang, Sung-Hoon Yu, Min-Hyung Lee