Separator, Retainer, Spacer Or Materials For Use Therewith Patents (Class 429/247)
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Patent number: 11469476Abstract: A separator which includes: a porous polymer substrate having a plurality of pores; a separator base including a porous coating layer formed on at least one surface of the porous polymer substrate; and an adhesive layer formed on at least one surface of the separator base, said adhesive layer comprising a plurality of second inorganic particles and adhesive resin particles, wherein the weight ratio of the second inorganic particles to the adhesive resin particles is 5:95-60:40, and the diameter of the adhesive resin particles is 1.1-3.5 times the diameter of the second inorganic particles. An electrochemical device including the separator is also disclosed. The separator shows improved adhesion between an electrode and the separator, maintains the pores of the adhesive layer even after a process of electrode lamination, and improves the resistance of an electrochemical device.Type: GrantFiled: October 18, 2018Date of Patent: October 11, 2022Assignee: LG ENERGY SOLUTION, LTD.Inventors: Hye-Jin Kwon, In-Hyouk Sung, Myeong-Soo Kim, Su-Jin Yoon
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Patent number: 11450921Abstract: A method for manufacturing a separator, including the steps of: (S1) preparing a dispersion containing inorganic particles dispersed in a first solvent and a first binder polymer dissolved in the first solvent; (S2) preparing a binder polymer solution containing a second binder polymer dissolved in a second solvent, and mixing the binder polymer solution with the dispersion so that a combined weight of the inorganic particles and the first binder polymer in the dispersion may be 1.5-8 times of a weight of the second binder polymer in the binder polymer solution; and (S3) applying the resultant mixture to at least one surface of a porous polymer substrate, followed by drying, to form a porous coating layer on the porous polymer substrate. Also, a separator obtained by the method and an electrochemical device including the same.Type: GrantFiled: November 23, 2018Date of Patent: September 20, 2022Assignee: LG ENERGY SOLUTION, LTD.Inventors: Hye-Jin Kwon, Su-Jin Yoon, Myeong-Soo Kim, Je-An Lee
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Patent number: 11417889Abstract: A pasting carrier for a lead-acid battery. The pasting carrier includes a nonwoven fiber mat having a thickness between 5 and 50 mils, the nonwoven fiber mat being composed of a plurality of entangled glass microfibers.Type: GrantFiled: February 27, 2020Date of Patent: August 16, 2022Assignee: Johns ManvilleInventors: Heath H Himstedt, Souvik Nandi, John Scherlein
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Patent number: 11289730Abstract: Flexible batteries, comprising at least two cells, wherein at least two cells are connected by flexible connectors, such that the battery can be bent. The batteries can be incorporated into clothing and gear.Type: GrantFiled: October 2, 2013Date of Patent: March 29, 2022Inventors: Louise Brooks, John S. Lettow
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Patent number: 11264675Abstract: The present application relates to an ink composition for a secondary battery separator, a separator for a secondary battery including the same, and a method for preparing the same.Type: GrantFiled: August 11, 2017Date of Patent: March 1, 2022Assignee: LG CHEM, LTD.Inventors: Kun Seok Lee, Jungyeon Lee, Seung Heon Lee
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Patent number: 11251414Abstract: According to one embodiment, an electrode group includes a positive electrode active material-containing layer, a negative electrode active material-containing layer, a lithium ion conductive layer, and a porous layer. The lithium ion conductive layer includes lithium-containing inorganic particles. The lithium ion conductive layer covers at least part of the positive electrode active material-containing layer. The porous layer covers at least part of the negative electrode active material-containing layer. The positive electrode active material-containing layer and the negative electrode active material-containing layer face each other via the lithium ion conductive layer and the porous layer.Type: GrantFiled: March 6, 2018Date of Patent: February 15, 2022Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Norio Takami, Kazuomi Yoshima, Takuya Iwasaki, Tomoko Sugizaki, Tomoe Kusama, Yasuhiro Harada
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Patent number: 11245158Abstract: Disclosed are a separator and an electrochemical device including the same. The separator includes: a porous substrate having a plurality of pores; and a pair of porous coating layers formed on at least one surface of the porous substrate, and including a plurality of inorganic particles and a binder disposed partially or totally on the surface of the inorganic particles to connect and fix the inorganic particles with each other, wherein the binder is used in an amount of 5-40 wt % based on the total weight of the porous coating layer, the inorganic particles include boehmite particles, the binder includes a fluorine-based binder and a rubber-based binder, and the fluorine-based binder and the rubber-based binder are used at a weight ratio of 80:20-99.9:0.1.Type: GrantFiled: June 8, 2017Date of Patent: February 8, 2022Assignee: LG ENERGY SOLUTION, LTD.Inventors: Dong-Wook Sung, Min-Ji Gu
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Patent number: 11098408Abstract: An environment control system utilizes oxygen and humidity control devices that are coupled with an enclosure to independently control the oxygen concentration and the humidity level within the enclosure. An oxygen depletion device may be an oxygen depletion electrolyzer cell that reacts with oxygen within the cell and produces water through electrochemical reactions. A desiccating device may be g, a dehumidification electrolyzer cell, a desiccator, a membrane desiccator or a condenser. A controller may control the amount of voltage and/or current provided to the oxygen depletion electrolyzer cell and therefore the rate of oxygen reduction and may control the amount of voltage and/or current provided to the dehumidification electrolyzer cell and therefore the rate of humidity reduction. The oxygen level may be determined by the measurement of voltage and a limiting current of the oxygen depletion electrolyzer cell. The enclosure may be a food or artifact enclosure.Type: GrantFiled: November 30, 2018Date of Patent: August 24, 2021Assignee: Xergy Inc.Inventors: Bamdad Bahar, Jacob Zerby, Xhefei Li, William Parmelee
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Patent number: 11056901Abstract: A method of charging a secondary battery, including first, second and third charging sections in which a CC-charging performed as first, second, and third Crate (C1, C2, C3), respectively, is supplied until the voltage of the secondary battery reaches a respective first, second and third charging cutoff voltage (V1), (V2), (V3) and a CV-charging is performed as the respective charging C-rate gradually decreases in response to reaching the respective charging cutoff voltage (V1), (V2), (V3), wherein the charging cutoff voltage satisfies the V1=n?(0.25˜0.15), V2 n?(0.2˜0.1), and V3=n (here, ‘n’ is an electric potential at the full charge of the secondary battery), and V1<V2<V3.Type: GrantFiled: March 9, 2018Date of Patent: July 6, 2021Assignee: LG CHEM, LTD.Inventors: Jun Hyuk Song, Joo Sung Lee
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Patent number: 11031655Abstract: A nonaqueous electrolyte secondary battery separator is provided in which thickness unevenness caused by wrinkles is reduced. The nonaqueous electrolyte secondary battery separator includes a polyolefin porous film, and when a test piece cut out from the nonaqueous electrolyte secondary battery separator is immersed in propylene carbonate, the test piece exhibits an elongation percentage difference of not more than 0.20%; the elongation percentage difference being a difference between (i) an elongation percentage in a longitudinal direction of the test piece as observed after 30 minutes of immersion in propylene carbonate and (ii) an elongation percentage in the longitudinal direction of the test piece as observed after 24 hours of immersion in propylene carbonate.Type: GrantFiled: May 31, 2019Date of Patent: June 8, 2021Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Tomoaki Ozeki
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Patent number: 10930970Abstract: Disclosed are a composite electrolyte, including: a network web formed of a fiber containing a polymer and inorganic particles, wherein a content of the inorganic particles is 5 wt % or less based on a total weight of the composite electrolyte, a preparing method thereof, and a lithium metal battery including the same.Type: GrantFiled: September 28, 2016Date of Patent: February 23, 2021Assignee: Samsung SDI Co., Ltd.Inventors: Hoon Seok, Junghyun Nam, Bokkyu Jeon, Yeonjoo Choi
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Patent number: 10923758Abstract: There is provided an electrode assembly including a first electrode laminate having at least one or more electrode units having a first area, stacked therein, a second electrode laminate having at least one or more electrode units having a second area smaller than the first area, stacked therein, and a step portion provided by stacking the first electrode laminate and the second electrode laminate in a direction perpendicular to a plane and having a step formed due to a difference in areas of the first and second electrode laminates, the electrode assembly being characterized in that, the electrode unit is wound by a rectangular-shaped separation film such that at least a portion of the rectangular-shaped separation film covers the step portion of the electrode assembly, and a step having a shape identical to the step portion is formed.Type: GrantFiled: September 19, 2018Date of Patent: February 16, 2021Inventors: Sung-Jin Kwon, Dong-Myung Kim, Ki-Woong Kim, Soon-Ho Ahn
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Patent number: 10916763Abstract: The present application describes the use of a solid electrolyte interphase (SEI) fluorinating precursor and/or an SEI fluorinating compound to coat an electrode material and create an artificial SEI layer. These modifications may increase surface passivation of the electrodes, SEI robustness, and structural stability of the silicon-containing electrodes.Type: GrantFiled: June 3, 2019Date of Patent: February 9, 2021Assignee: Enevate CorporationInventors: Liwen Ji, Benjamin Yong Park, Robert A. Rango, Dong Sun, Frederic C. Bonhomme
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Patent number: 10892519Abstract: The present invention relates to a solid polymer electrolyte formed of a polymer matrix including a lithium ion conductor, and a method of preparing the same. The solid polymer electrolyte of the present invention can be molded in the form of a film and used in an electrochemical device such as a lithium polymer secondary battery or the like.Type: GrantFiled: March 30, 2017Date of Patent: January 12, 2021Inventors: Kyoung Ho Ahn, Sol Ji Park, Chul Haeng Lee, Jeong Woo Oh, Jung Hoon Lee, Yi Jin Jung
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Patent number: 10892456Abstract: A separator for an electrochemical element interposed between a pair of electrodes, capable of holding an organic electrolytic solution contains an electrolyte. The separator is a wet-laid nonwoven fabric containing 10-50 mass % of thermoplastic synthetic fibers and 50-90 mass % of beaten regenerated cellulose fibers having a mean fiber length of 0.2-2.0 mm, the separator has a thickness of 10-70 ?m and a density of 0.25-0.90 g/cm3, including two parts obtained by bisecting a cross-section of the separator in a thickness direction. Two A-parts with a small number of the thermoplastic synthetic fibers and B-part with a large number of the thermoplastic synthetic fibers, and the A and B parts are formed into a single layer in an integrated manner; a value obtained by dividing the number of thermoplastic synthetic fibers in the A part by the number of the thermoplastic synthetic fibers in the B part is 0.85 or less.Type: GrantFiled: June 27, 2016Date of Patent: January 12, 2021Assignee: NIPPON KODOSHI CORPORATIONInventors: Norihiro Wada, Atsushi Igawa, Masahiko Ueta
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Patent number: 10886584Abstract: This invention is related to a type of Air Metal Fuel Cell. The Air Metal Fuel Cell in this invention is made of a positive air electrode, metal negative electrode, membrane/membrane bag, siphon material, electrolyte, mandrel, shockproof buffer layer, cathode electrolyte, positive electrolyte, battery shell and supporting fixing device. There is a hydrophobic structure layer between the positive and negative electrodes. The advantages of the invented cell include high energy density, low production costs, and superior safety and reliability.Type: GrantFiled: December 7, 2015Date of Patent: January 5, 2021Assignees: LANZHOU JINFULE BIOTECHNOLOGY CO. LTD., KIN STAR INTERNATIONAL LIMITED, SPRING POWER LIMITED, JIN JIN PACIFIQUE COMPAGNIEInventor: Jifan Jin
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Patent number: 10862090Abstract: The present disclosure relates to a composite separator, a preparation method of the composite separator, and an electrochemical device containing the composite separator. The composite separator includes a substrate and an inorganic layer disposed on at least one surface of the substrate. The substrate is a porous substrate, and the inorganic layer is an inorganic dielectric layer which is a continuous dense film layer with porosity lower than 10% and contains no binder. A thickness of the inorganic layer is 20 nm-1000 nm. An interfacial peeling force between the inorganic layer and the substrate is no less than 30 N/m. The separator of the present application has high wettability with respect to electrolyte, almost no thermal shrinkage, relatively high mechanical strength, and favorable corrosion resistance and durability performances, and thus, a battery using the separator has relatively high thermal stability and nailing strength.Type: GrantFiled: December 6, 2018Date of Patent: December 8, 2020Inventors: Huafeng Huang, Qisen Huang, Shiwen Wang, Chengdu Liang
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Patent number: 10833307Abstract: Provided are separators for use in batteries and capacitors comprising (a) at least 50% by weight of an aluminum oxide and (b) an organic polymer, wherein the aluminum oxide is surface modified by treatment with an organic acid to form a modified aluminum oxide, and wherein the treatment provides dispersibility of the aluminum oxide in aprotic solvents such as N-methyl pyrrolidone. Preferably, the organic acid is a sulfonic acid, such as p-toluenesulfonic acid. Also preferably, the organic polymer is a fluorinated polymer, such as polyvinylidene fluoride. Also provided are electrochemical cells and capacitors comprising such separators.Type: GrantFiled: June 7, 2017Date of Patent: November 10, 2020Assignees: Optodot Corporation, Sihi GmbHInventors: Zhong Xu, Steven A. Carlson
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Patent number: 10797286Abstract: An insulating (nonconductive) microporous nonwoven polymeric battery separator comprised of a single layer of enmeshed microfibers and nanofibers and supercalendered to extremely thin dimensions and high densities is provided. Such a separator accords the ability to not only attune the porosity and pore size to any desired level through a single nonwoven fabric, but provide further benefits in terms of further reduced pore size, reduced electrolyte level requirements, and reduced total volume of the subject battery cell itself. As a result, the inventive separator permits a high strength material with low porosity and low pore size to levels previously unattained. The separator, a battery including such a separator, the method of manufacturing such a separator, and the method of utilizing such a separator within a battery device, are all encompassed within this invention.Type: GrantFiled: February 25, 2016Date of Patent: October 6, 2020Assignees: Dreamweaver International Inc., Glatfelter Gernsbach, GMBHInventors: Brian G. Morin, Testa Mattia, Giovanni Schnelle
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Patent number: 10784532Abstract: Chemical additives are disclosed to increase solubility of salts in liquefied gas electrolytes.Type: GrantFiled: October 28, 2019Date of Patent: September 22, 2020Assignees: South 8 Technologies, Inc., The Regents of the University of CaliforniaInventors: Cyrus Sam Rustomji, Yangyuchen Yang, Daniel Davies, Jungwoo Lee, Ying Shirley Meng
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Patent number: 10770743Abstract: A method for manufacturing an electrode having a laminated body including an insulating layer laminated on an electrode active material layer, said method comprising: a step of laminating an insulating layer on an electrode active material layer formed on a base, such that a thickness value of the insulating layer is at least twice a surface roughness Rz value of the electrode active material layer, the surface roughness Rz value being a ten point average roughness as measured in accordance with JIS B0601 1994.Type: GrantFiled: December 25, 2015Date of Patent: September 8, 2020Assignee: SEKISUI CHEMICAL CO., LTD.Inventors: Rie Teranishi, Kenichi Shinmei, Masashi Kanoh, Akio Shokaku, Shinichiro Ito
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Patent number: 10756395Abstract: A battery has an integrated flame retardant device, wherein the battery has: a cathode layer, a separating layer, and an anode layer, wherein the separating layer is arranged between the cathode layer and the anode layer, wherein the separating layer is impermeable to electrons and permeable to at least one positive type of ion, wherein the separating layer has a flame retardant device having at least one glass fibre, which includes a closed cavity, and wherein a flame retardant is arranged in the cavity. The battery has increased fire resistance.Type: GrantFiled: September 7, 2018Date of Patent: August 25, 2020Assignee: Airbus Operations GmbHInventor: Peter Linde
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Patent number: 10756319Abstract: Disclosed is a method for manufacturing a separator for an electrochemical device. The method contributes to formation of a separator with good bondability to electrodes and prevents inorganic particles from detaching during an assembling process of an electrochemical device.Type: GrantFiled: December 11, 2013Date of Patent: August 25, 2020Assignees: LG Chem, Ltd., TORAY INDUSTRIES, INC.Inventors: Joo-Sung Lee, Jang-Hyuk Hong, Jong-Hun Kim
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Patent number: 10700332Abstract: A separator having a first polymer diaphragm and a second polymer diaphragm and a layer between the first polymer diaphragm and the second polymer diaphragm including particles featuring low elasticity, the first polymer diaphragm and the second polymer diaphragm being interconnected, which may be periodically, by first support elements. In addition, a galvanic cell and a battery having such a separator are provided.Type: GrantFiled: October 15, 2015Date of Patent: June 30, 2020Assignee: Robert Bosch GmbHInventors: Bernd Schumann, Jean Fanous
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Patent number: 10658643Abstract: A positive electrode plate includes a front positive electrode active material layer on a front surface of a positive electrode metal foil, and having a positive electrode large tapered portion that extends at an incline from one edge of the front surface of the positive electrode metal foil at a positive electrode large inclination angle. A negative electrode plate includes a front negative electrode active material layer on a front surface of a negative electrode metal foil, and having a negative electrode large tapered portion that extends at an incline from one edge of the front surface of the negative electrode metal foil at a negative electrode large inclination angle. The positive and negative electrode plates are alternately laminated with a separator interposed therebetween such that each of their front surfaces is oriented in the same direction in the rear-to-front directional axis along the thickness of the plates.Type: GrantFiled: October 29, 2015Date of Patent: May 19, 2020Assignee: KABUSHIKI KAISHA TOYOTA JIDOSHOKKIInventors: Atsushi Minagata, Masato Ogasawara, Yasuyuki Goda
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Patent number: 10637063Abstract: A binder composition for a non-aqueous secondary battery porous membrane comprises: a polymer; and an organic solvent, wherein a boiling point of the organic solvent is 30° C. or more and 100° C. or less, and an absolute difference |SPdiff|=|SPp?SPs| between a solubility parameter SPp of the polymer and a solubility parameter SPs of the organic solvent is 1.5 or more and 6.0 or less.Type: GrantFiled: December 15, 2016Date of Patent: April 28, 2020Assignee: ZEON CORPORATIONInventor: Junnosuke Akiike
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Patent number: 10637097Abstract: Provided are an organic/inorganic composite electrolyte, an electrode-electrolyte assembly and a lithium secondary battery including the organic/inorganic composite electrolyte, and a manufacturing method of the electrode-electrolyte assembly. The porous organic/inorganic composite electrolyte, includes a first pore peak in a pore size range of about 100 nm to about 300 nm in a total pore distribution chart, and 50% or more of pores having a pore size range of about 100 nm to about 300 nm based on a total pore volume.Type: GrantFiled: June 26, 2015Date of Patent: April 28, 2020Assignees: Samsung SDI Co., Ltd., Hanyang University Cooperation Foundation Hanyang UniversityInventors: Manseok Han, Woocheol Shin, Duckhyun Kim, Moonsung Kim, Jeonghye Lee, Dongwon Kim, Yunchae Jung, Seulki Kim
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Patent number: 10622639Abstract: A pasting carrier for a lead-acid battery. The pasting carrier includes a nonwoven fiber mat having a thickness between 5 and 50 mils, the nonwoven fiber mat being composed of a plurality of entangled glass microfibers.Type: GrantFiled: February 22, 2017Date of Patent: April 14, 2020Assignee: Johns ManvilleInventors: Heath H Himstedt, Souvik Nandi, John Scherlein
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Patent number: 10615390Abstract: An electrode-composite separator assembly for a lithium battery, the electrode-composite separator assembly including an electrode; and a composite separator, wherein the composite separator includes a separator, and a coating film disposed on a surface of the separator, wherein the coating film includes a copolymer including an electrolyte-insoluble repeating unit and a repeating unit represented by Formula 1; and at least one selected from an inorganic particle and an organic-inorganic particle, wherein the electrode-composite separator assembly does not have an exothermic peak between 400° C. to 480° C. when analyzed by differential scanning calorimetry, wherein Formula 1 is wherein, in Formula 1, R3 is hydrogen or a C1-C5 alkyl group, and R4 is a C1-C10 alkyl group. Also, a lithium battery including the electrode-composite separator assembly.Type: GrantFiled: May 31, 2016Date of Patent: April 7, 2020Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Jeongkuk Shon, Junhwan Ku, Minsang Song, Sangmin Ji, Hana Kim, Myungkook Park, Byungmin Lee, Jaeman Choi
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Patent number: 10581127Abstract: An anaerobic aluminum-water electrochemical cell is provided. The electrochemical cell includes: a plurality of electrode stacks, each electrode stack comprising an aluminum or aluminum alloy anode, and at least one cathode configured to be electrically coupled to the anode and having a surface characterized by an electrochemical roughness factor of at least 5 and a mean pore diameter of at least 50 ?m; one or more physical separators between each electrode stack adjacent to the cathode; a housing configured to hold the electrode stacks, an electrolyte, and the physical separators; and a water injection port, in the housing, configured to introduce water into the housing.Type: GrantFiled: August 7, 2018Date of Patent: March 3, 2020Assignee: Massachusetts Institute of TechnologyInventors: Ian Salmon McKay, Ruaridh R. Macdonald, Thomas B. Milnes
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Patent number: 10483513Abstract: A separator for a battery includes a base having an anode side configured to contact an anode of the battery and a cathode side configured to contact a cathode of the battery. The anode side has a different material consistency than the cathode side.Type: GrantFiled: March 29, 2010Date of Patent: November 19, 2019Assignee: CARL FREUDENBERG KGInventors: Christoph Weber, Michael Roth
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Patent number: 10439249Abstract: Provided is a lithium ion secondary battery including, as components accommodated in a container, a positive electrode that intercalates and deintercalates lithium, a negative electrode that intercalates and deintercalates lithium, a nonaqueous electrolytic solution that contains a lithium salt, and a separator that is interposed between the positive electrode and the negative electrode. The separator includes a porous resin layer containing polyolefin as a main component.Type: GrantFiled: February 3, 2016Date of Patent: October 8, 2019Assignee: Envision AESC Energy Devices Ltd.Inventor: Akihiro Modeki
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Patent number: 10381625Abstract: A composite membrane includes: an organic layer having a plurality of through holes; and ion conductive inorganic particles disposed in the through holes, wherein a hydrophobic coating layer is disposed on a surface of the ion conductive inorganic particles.Type: GrantFiled: March 12, 2015Date of Patent: August 13, 2019Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Wonsung Choi, Dongmin Im, Soonchul Kwon, Sungcheol Kim, Taeyoung Kim
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Patent number: 10361461Abstract: A cable type secondary battery includes an inner electrode support; and a sheet-like inner electrode—separation layer—outer electrode complex which is spirally wound around the outer side of the inner electrode support. The inner electrode—separation layer—outer electrode complex is formed such that an inner electrode, a separation layer, and an outer electrode are compressed integrally. According to one embodiment, an electrode and a separation layer are bonded integrally so that the separation layer in close contact with the electrode absorbs electrolyte so as to induce a uniform supply of the electrolyte to an outer electrode active material layer, thereby increasing the stability and performance of a cable type secondary battery. In addition, the cable type secondary battery has a sheet-like electrode, whereby the resistance of the cable type secondary battery is reduced and the performance of the battery may be improved.Type: GrantFiled: February 11, 2016Date of Patent: July 23, 2019Assignee: LG Chem, Ltd.Inventors: In-Sung Uhm, Je-Young Kim, Yo-Han Kwon
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Patent number: 10355257Abstract: Provided herein are a variety of porous separator materials, particularly those prepared by gas-assisted electrospray and electrospinning processes.Type: GrantFiled: May 16, 2018Date of Patent: July 16, 2019Assignee: Cornell UniversityInventors: Yong Lak Joo, Joseph M. Carlin, Soshana Smith
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Patent number: 10242807Abstract: Provided is a lithium ion capacitor that is capable, during internal short circuiting, of suppressing an increase in capacitor temperature and controlling the onset of gasification, smoking and ignition, and of having preferably both low resistance (i.e., high output density) and high cycle characteristics. The lithium ion capacitor comprises an electrode laminated body stored in a casing together with a non-aqueous electrolytic solution containing a lithium ion-containing electrolyte; wherein the electrode laminated body is laminated so that a negative electrode collector having a negative electrode active material comprised of a carbon material, and a positive electrode body having a positive electrode active material face each other through a laminated separator where a polyolefin porous membrane and an insulating porous membrane are laminated; and characterized in that the insulating porous membrane is in contact with the negative electrode body.Type: GrantFiled: January 21, 2014Date of Patent: March 26, 2019Assignee: Asahi Kasei Kabushiki KaishaInventors: Nobuhiro Okada, Osamu Saito, Kensuke Niimura
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Patent number: 10205170Abstract: Electrodeposited copper foils having adequate puncture strength to withstand both pressure application during consolidation with negative electrode active materials during manufacture, as well as expansion/contraction during repeated charge/discharging cycles when used in a rechargeable secondary battery are described. These copper foils find specific utility as current collectors in rechargeable secondary batteries, particularly in lithium secondary battery with high capacity. Methods of making the copper foils, methods of producing negative electrode for use in lithium secondary battery and lithium secondary battery of high capacity are also described.Type: GrantFiled: December 4, 2017Date of Patent: February 12, 2019Assignee: CHANG CHUN PETROCHEMICAL CO., LTD.Inventors: Huei-Fang Huang, Kuei-Sen Cheng, Yao-Sheng Lai, Jui-Chang Chou
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Patent number: 10066032Abstract: The present invention includes a process for producing treated filler that includes (a) treating a slurry that includes untreated filler where the untreated filler has not been previously dried, with a treating composition that includes a treating agent, thereby forming a treated filler slurry, and (b) drying the treated filler slurry to produce treated filler. The treating agent can include an unsaturated fatty acid, derivative of an unsaturated fatty acid, or salt thereof. The present invention also is directed to treated filler prepared by the process, as well as rubber compounding compositions and tires including the treated filler.Type: GrantFiled: October 7, 2014Date of Patent: September 4, 2018Assignee: PPG Industries Ohio, Inc.Inventors: Peter Lawrence Votruba-Drzal, Justin Jonathan Martin, Timothy Allen Okel, Raphael O. Kollah, Truman Wilt, Clint Steven Edelman, Brittany Smith, Luke Andrew Wolfe
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Patent number: 10069171Abstract: Disclosed is a method for manufacturing an all-solid-state lithium ion battery in which a laminated battery is coated with a thermosetting resin, capable of preventing the thermosetting resin from cracking due to charge and discharge of the all-solid-state lithium ion battery after the battery is coated with the thermosetting resin, the method including a first step of laminating a cathode layer, a solid electrolyte layer and an anode layer to form a laminated battery having both end faces in a lamination direction and side faces, a second step of charging the laminated battery until the laminated battery has 100% to 112% of state of charge, a third step of coating at least the side faces of the laminated battery that is charged with a thermosetting resin in an uncured state, and a fourth step of heating to cure the thermosetting resin.Type: GrantFiled: December 11, 2017Date of Patent: September 4, 2018Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Masashi Kodama
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Patent number: 9979002Abstract: Disclosed are a separator for an electrochemical device substantially comprising inorganic particles to provide an excellent mechanical strength, an electrochemical device comprising the same, and a method of manufacturing the separator using a high internal phase emulsion (HIPE).Type: GrantFiled: July 31, 2014Date of Patent: May 22, 2018Assignees: LG Chem, Ltd., TORAY INDUSTRIES, INC.Inventors: Jin-Woo Kim, Joo-Sung Lee, Jong-Hun Kim
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Patent number: 9954248Abstract: An object of the present invention is to provide a solid lithium secondary battery in which occurrence of short-circuit is suppressed during charging. The object is attained by providing a solid lithium secondary battery comprising an anode current collector, a solid electrolyte layer, a cathode active material layer, and a cathode current collector in this order, wherein the solid electrolyte layer is provided on a surface of the anode current collector, the solid electrolyte layer contains a sulfide solid electrolyte particle, a surface shape of the solid electrolyte layer, which faces the anode current collector, is formed in correspondence with a surface shape of the anode current collector, and 10-point average roughness (Rz) of the surface of the anode current collector on a solid electrolyte layer side, and 10-point average roughness (Rz) of a surface of the solid electrolyte layer on an anode current collector side are in a range of 1.8 ?m to 2.5 ?m, respectively.Type: GrantFiled: July 27, 2015Date of Patent: April 24, 2018Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Takamasa Ohtomo, Yuki Kato
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Patent number: 9905882Abstract: A positive active material layer for a rechargeable lithium battery including a positive active material and a protection film-forming material is disclosed. A separator for a rechargeable lithium battery including a substrate and a porous layer positioned at least one side of the substrate and including a protection film-forming material is also disclosed. A rechargeable lithium battery can include at least one of the positive active material layer and the separator.Type: GrantFiled: April 19, 2017Date of Patent: February 27, 2018Assignee: Samsung SDI Co., Ltd.Inventors: Hironari Takase, Hokuto Yokotsuji
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Patent number: 9843048Abstract: Embodiments of the invention provide batteries, electrodes, and methods of making the same. According to one embodiment, a battery may include a positive plate having a grid pasted with a lead oxide material, a negative plate having a grid pasted with a lead based material, a separator separating the positive plate and the negative plate, and an electrolyte. A nonwoven glass mat may be in contact with a surface of either or both the positive plate or the negative plate to reinforce the plate. The nonwoven glass mat may include a plurality of first coarse fibers having fiber diameters between about 6 ?m and 11 ?m and a plurality of second coarse fibers having fiber diameters between about 10 ?m and 20 ?m.Type: GrantFiled: July 19, 2016Date of Patent: December 12, 2017Assignee: Johns ManvilleInventors: Zhihua Guo, Souvik Nandi, Jawed Asrar, Albert G Dietz, III
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Patent number: 9825269Abstract: A method for manufacturing a polyolefin separator, including forming a sheet including a polyolefin resin and a plasticizer; stretching the sheet E1 times in a longitudinal direction at a temperature of T1, followed by stretching the sheet E2 times in a transverse direction at a temperature of T2, wherein T1<115° C., T2<115° C., and T2?T1, and E1×E2=55 to 80, E1?7, and E2?7; and extracting the plasticizer from the stretched sheet.Type: GrantFiled: December 22, 2014Date of Patent: November 21, 2017Assignee: SAMSUNG SDI CO., LTD.Inventors: Kee Wook Kim, Sang Ho Lee, Yong Bae Lee, Jung Seong Lee, Jung Sue Jang, Jae Hyun Cho, Dae Hyun Hong
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Patent number: 9748604Abstract: Electrolyte compositions for batteries such as lithium ion and lithium air batteries are described. In some embodiments the compositions are liquid compositions comprising (a) a homogeneous solvent system, said solvent system comprising a perfluropolyether (PFPE) and polyethylene oxide (PEO); and (b) an alkali metal salt dissolved in said solvent system. In other embodiments the compositions are solid electrolyte compositions comprising: (a) a solid polymer, said polymer comprising a crosslinked product of a crosslinkable perfluropolyether (PFPE) and a crosslinkable polyethylene oxide (PEO); and (b) an alkali metal ion salt dissolved in said polymer. Batteries containing such compositions as electrolytes are also described.Type: GrantFiled: October 17, 2013Date of Patent: August 29, 2017Assignee: The University of North Carolina at Chapel HillInventors: Joseph M. DeSimone, Ashish Pandya, Dominica Wong, Alessandra Vitale
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Patent number: 9711771Abstract: A membrane includes a porous membrane or layer made of a polymeric material having a plurality of surface treated (or coated) particles (or ceramic particles) having an average particle size of less than about 1 micron dispersed therein. The polymeric material may be selected from the group consisting of polyolefins, polyamides, polyesters, co-polymers thereof, and combinations thereof. The particles may be selected from the group consisting of boehmite (AlOOH), SiO2, TiO2, Al2O3, BaSO4, CaCO3, BN, and combinations thereof, or the particles may be boehmite. The surface treatment (or coating) may be a molecule having a reactive end and a non-polar end. The particles may be pre-mixed in a low molecular weight wax before mixing with the polymeric material. The membrane may be used as a battery separator.Type: GrantFiled: September 17, 2014Date of Patent: July 18, 2017Assignee: Celgard, LLCInventors: C. Glen Wensley, Lie Shi
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Patent number: 9711774Abstract: The present application provides a lithium ion battery including a thermal sensitive layer comprising polymer particles. The thermal sensitive layer may be disposed between the electrodes and the separator. When the lithium ion battery is under thermal runaway condition and the internal temperature rises to a critical temperature, the polymer particles undergo a thermal transition process (melting) to form an insulating barrier on the electrodes, which blocks lithium ion transfer between the electrodes and shuts down the internal current of the battery.Type: GrantFiled: December 3, 2015Date of Patent: July 18, 2017Assignee: NANO AND ADVANCED MATERIALS INSTITUTE LIMITEDInventors: Chenmin Liu, Yeming Xu, Chi Ho Kwok, Ning Tu
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Patent number: 9692040Abstract: A method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.Type: GrantFiled: February 3, 2016Date of Patent: June 27, 2017Assignee: HYDRO-QUEBECInventors: Karim Zaghib, Michel Armand, Abdelbast Guerfi, Michel Perrier, Elisabeth Dupuis, Patrick Charest
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Patent number: 9683101Abstract: In accordance with at least certain embodiments of the present invention, a novel concept of utilizing PIMS minerals as a filler component within a microporous lead-acid battery separator is provided. In accordance with more particular embodiments or examples, the PIMS mineral (preferably fish meal, a bio-mineral) is provided as at least a partial substitution for the silica filler component in a silica filled lead acid battery separator (preferably a polyethylene/silica separator formulation). In accordance with at least selected embodiments, the present invention is directed to new or improved batteries, separators, components, and/or compositions having heavy metal removal capabilities and/or methods of manufacture and/or methods of use thereof.Type: GrantFiled: September 22, 2011Date of Patent: June 20, 2017Assignee: Daramic, LLCInventors: Jeffrey K. Chambers, Tejas R. Shah
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Patent number: 9666851Abstract: The present invention refers to a separator and an electrochemical device having the same. The separator of the present invention comprises a non-woven fabric substrate obtained from fibers and having multiple pores formed between the fibers; and a polymer coating layer formed on a part or the whole of the surface of the fibers, wherein the polymer coating layer comprises a polymer having a tensile strength of 80 MPa or more, a tensile modulus of 3,000 MPa or more and a flexural modulus of 3,000 MPa or more. The separator of the present invention can reduce costs for manufacturing electrochemical devices, and it can control the size of pores present in the non-woven fabric substrate to prevent the generation of a leak current and provide improved mechanical strength.Type: GrantFiled: June 5, 2014Date of Patent: May 30, 2017Assignee: LG Chem, Ltd.Inventors: Jeong-Min Ha, Jong-Hun Kim, Su-Jin Yoon, Byeong-Gyu Cho, Jang-Hyuk Hong, Da-Kyung Han