And Acyclic Carbonate Or Acyclic Carboxylic Acid Ester Solvent Patents (Class 429/332)
  • Patent number: 7718307
    Abstract: A negative electrode material for a high input/output currant-type non-aqueous electrolyte secondary battery, comprising a carbon material having an average (002) interlayer spacing d002 of 0.355-0.400 nm determined by X-ray diffractometry and a true density of 1.50-1.60 g/cm3, and exhibiting a capacity (A) of at least 50 mAh/g in a battery voltage range of 0.3-1.0 V and a ratio ((A)/(B)) of at least 0.3 between the capacity (A) and a capacity (B) in a battery voltage range of 0-1.0 V when measured as discharge capacities with a counter electrode of lithium. The negative electrode material is non-graphitizable and has properties suitable for a negative electrode material for high input/output current non-aqueous electrolyte secondary batteries as used in HEV, etc.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: May 18, 2010
    Assignee: Kureha Corporation
    Inventors: Kazuhiko Shimizu, Mariko Maeda, Syuji Morinishi, Aisaku Nagai, Akiko Hoshi
  • Publication number: 20100119954
    Abstract: A non-aqueous electrolyte for a secondary battery includes a solvent and an electrolyte containing a lithium salt. The solvent contains 4-fluoroethylene carbonate and a chain carboxylic ester represented by the formula R1COOR2, where R1 and R2 are alkyl groups having 3 or less carbon atoms. The amount of the 4-fluoroethylene carbonate is 7 volume % or greater with respect to the total amount of the solvent.
    Type: Application
    Filed: January 21, 2010
    Publication date: May 13, 2010
    Applicant: SANYO ELECTRIC CO., LTD.
    Inventors: Takanobu CHIGA, Yoshinori KIDA
  • Publication number: 20100119953
    Abstract: In a rechargeable non-aqueous electrolyte secondary battery using positive electrodes, negative electrodes and a non-aqueous electrolytic solution, additives to the electrolytic solution are used in combination, preferably in combination of at least two compounds selected from o-terphenyl, triphenylene, cyclohexylbenzene and biphenyl, and thus there are provided batteries excellent in safety and storage characteristics.
    Type: Application
    Filed: December 3, 2009
    Publication date: May 13, 2010
    Applicant: PANASONIC CORPORATION
    Inventors: Shoichiro Watanabe, Shusaku Goto, Masaru Takagi, Sumihito Ishida, Toshikazu Hamamoto, Akira Ueki, Koji Abe
  • Patent number: 7709142
    Abstract: A battery capable of obtaining a high energy density and obtaining superior cycle characteristics is provided. The thickness of a cathode active material layer is from 100 ?m to 130 ?m. The thickness of an anode active material layer is from 85 ?m to 120 ?m, and the volume density of the anode active material layer is from 1.7 g/cm3 to 1.85 g/cm3. An electrolytic solution contains 4-fluoro-1,3-dioxolane-2-one. Thereby, even when the thicknesses of the cathode active material layer and the anode active material layer are increased, the diffusion and acceptance of lithium in an anode are improved, and superior cycle characteristics can be obtained.
    Type: Grant
    Filed: December 7, 2006
    Date of Patent: May 4, 2010
    Assignee: Sony Corporation
    Inventors: Shinya Wakita, Izaya Okae, Yosuke Ushio, Yoshiaki Takeuchi, Saori Tokuoka
  • Patent number: 7709154
    Abstract: Disclosed is an electrolyte of a lithium secondary battery comprising a lithium salt, an organic solvent, and at least one additive compound selected from the group consisting of compounds represented by the following formula (1) and derivatives thereof: where R1 is selected from the group consisting of hydrogen radicals, alkyls, aryls, cycloalkyls, alkenyls, alkynyls, ester radicals, and aliphatic carbonate radicals. The electrolyte improves both swelling inhibition properties at high temperature and capacity characteristics of a lithium secondary battery.
    Type: Grant
    Filed: February 13, 2009
    Date of Patent: May 4, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Hyung-Gon Noh
  • Patent number: 7709156
    Abstract: A non-aqueous electrolyte secondary battery includes a positive electrode containing a positive electrode active material; a negative electrode containing a negative electrode active material; and a non-aqueous electrolyte containing a non-aqueous solvent and an electrolyte salt. In order to improve the high-temperature storage characteristics and safety against overcharge due to high-rate charging of the battery, the positive electrode active material contains a layered lithium-transition metal composite oxide containing at least one of Mg, Al, Ti, and Zr. Furthermore, the non-aqueous electrolyte contains 3 to 80% by mass of a tertiary carboxylic acid ester expressed by Chemical Formula 2 below, based on the total mass of the non-aqueous solvent: where R1 to R4 are independent of each other and each represents an alkyl group having 4 or less carbon atoms and being able to be branched.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: May 4, 2010
    Assignee: Sanyo Electric Co., Ltd.
    Inventor: Kentaro Takahashi
  • Publication number: 20100104950
    Abstract: Provide are fluorinated cyclic and acyclic carbonate solvent compositions such as various fluorine substituted 1,3-dioxolane-2-one compounds and fluorine substituted 1,3-dioxane-2-one compounds, which are useful as electrolyte solvents for lithium ion batteries.
    Type: Application
    Filed: December 12, 2007
    Publication date: April 29, 2010
    Inventors: William M. Lamanna, Michael J. Bulinski, Michael G. Castello, Jeffrey R. Dahn, Richard M. Flynn, Yadong Wang, Jing Li, Lee Moshurchak
  • Patent number: 7704640
    Abstract: A non-aqueous electrolyte secondary cell excellent in cycle characteristics is provided. This purpose is achieved by the following structure. A non-aqueous electrolyte secondary cell has a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, and a non-aqueous electrolyte having a non-aqueous solvent and an electrolytic salt. The positive electrode active material has a lithium-cobalt compound oxide having added therein at least zirconium. The non-aqueous electrolyte has LiBF4 at from 0.05 to 1.0 mass % of a total mass of the non-aqueous electrolyte and unsaturated cyclic carbonate at from 1.0 to 4.0 mass %. The true density ratio of the positive electrode is 0.72 or greater, the true density ratio being represented by formula 1 shown below: (Formula 1) True density ratio=active material apparent density of electrode active material layer÷true density of active material.
    Type: Grant
    Filed: February 27, 2006
    Date of Patent: April 27, 2010
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Keisuke Ooga, Masato Iwanaga, Hideyuki Inomata, Ryuji Ohshita
  • Patent number: 7700242
    Abstract: This invention discloses a type of mixed additives for electrolyte of lithium-ion secondary batteries, having the following characteristics: in weight percentage: biphenyl series: 0.5% to 95.4%; cyclohexylbenzene series: 1.1% to 93.8%; vinylene carbonate: 0.4% to 93.2%; phenyl vinyl sulfone: 0.5% to 96.5%; ethenyl sulfonyl benzene: 0.5% to 95.8%. This invention also discloses an electrolyte for lithium-ion secondary batteries comprising organic solvents and lithium saline, wherein the special characteristic is that it comprises 2% to 20% weight percentage of said mixed additives. The distinctive advantage of the mixed additives for lithium-ion secondary batteries of this invention is to effectively enhance the overcharging, low-temperature, and cycle properties of lithium-ion batteries. A lithium-ion battery having the mixed additives of this invention remains explosion-free, ignition-free and reliably safe when the lithium-ion secondary battery is overcharging.
    Type: Grant
    Filed: October 18, 2006
    Date of Patent: April 20, 2010
    Assignee: BYD Company Limited
    Inventors: Feng Xiao, Mingxia Wang, Guishu Zhou, Huaying You
  • Patent number: 7695863
    Abstract: The present invention provides a lithium secondary battery having excellent battery cycle property, electrical capacity, storage characteristic and other battery characteristics for a long period of time, and a nonaqueous electrolytic solution which is usable for the lithium secondary battery. A nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, comprising (i) a dicarbonyl compound represented by the general formula (I), or (ii) a dicarbonyl compound represented by the general formula (II) and vinylene carbonate and the like in the nonaqueous electrolytic solution. (wherein R1 represents a hydrogen atom, an alkyl group, an alkenyl group, a phenyl group or the like; and X represents a hydrogen atom, an R2 group or an OR2 group. R2 represents an alkyl group, an alkenyl group, a phenyl group or the like.
    Type: Grant
    Filed: November 24, 2005
    Date of Patent: April 13, 2010
    Assignee: Ube Industries, Ltd.
    Inventors: Koji Abe, Takaaki Kuwata, Hirofumi Takemoto
  • Patent number: 7691537
    Abstract: An electrolyte for a lithium secondary battery and a lithium secondary battery having the electrolyte, the electrolyte including a lithium salt; a non-aqueous organic solvent including ?-butyrolactone; and succinic anhydride.
    Type: Grant
    Filed: July 7, 2006
    Date of Patent: April 6, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Cheonsoo Kim
  • Patent number: 7691538
    Abstract: In a nonaqueous electrolyte secondary battery according to an embodiment of the invention, a nonaqueous electrolyte contains: a tertiary carboxylate ester represented by the following general formula (1) in an amount of a range of 3% by mass or more and 80% by mass or less based on the total mass of the nonaqueous solvent: where R1, R2, R3, R4 represent a (C1 to 4) alkyl group, respectively, and one or more acid anhydride selected from succinic anhydride, glutaric anhydride, and glycolic anhydride in an amount of a range of 0.1% by mass or more and 5% by mass or less based on the total mass of the nonaqueous electrolyte. By containing such a constitution, in other words, by containing a nonaqueous solvent capable of stabilizing the coating film of the negative electrode, a nonaqueous electrolyte secondary battery in which not only can satisfactory cycle performance and retention characteristics be obtained, but also the overcharging performance is largely improved, can be provided.
    Type: Grant
    Filed: March 26, 2008
    Date of Patent: April 6, 2010
    Assignee: Sanyo Electric Co., Ltd.
    Inventor: Kentaro Takahashi
  • Patent number: 7691539
    Abstract: A method of increasing the discharge capacity retention of a non-aqueous lithium ion secondary battery having a positive electrode active material, a combination of a lithium element and a complex metal oxide, a negative electrode, and a non-aqueous electrolytic solution comprising an electrolyte dissolved in a non-aqueous solvent which is a combination of a cyclic carbonate and a linear carbonate by incorporating a disulfide derivative having the formula: R1—S—S—R2 wherein each of R1 and R2 independently represents a phenyl group, a benzyl group, a tolyl group, a pyridyl group, a pyrimidyl group, an alkyl group having 1 to 12 carbon atom, or a cycloalkyl group having 3 to 6 carbon atoms, in which each group has no substituent groups or has one or more alkyl groups into the non-aqueous electrolytic solution.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: April 6, 2010
    Assignee: UBE Industries, Ltd.
    Inventors: Toshikazu Hamamoto, Koji Abe, Tsutomu Takai, Yasuo Matsumori
  • Publication number: 20100062345
    Abstract: This invention relates to a non-aqueous electrolyte for a battery having high flame retardance and capable of giving high heat resistance to a positive electrode material of a battery, and more particularly to a non-aqueous electrolyte for a battery characterized by comprising a non-aqueous solvent containing a cyclic phosphazene compound represented by the following general formula (I): (NPR2)n ??(I) [wherein Rs are independently fluorine, an alkoxy group or an aryloxy group; and n is 3-4] and at least one methyl ester compound selected from the group consisting of methyl acetate, methyl propionate and methyl butyrate, and a support salt.
    Type: Application
    Filed: April 3, 2008
    Publication date: March 11, 2010
    Applicant: BRIDGESTONE CORPORATION
    Inventor: Yasuo Horikawa
  • Publication number: 20100055575
    Abstract: Disclosed is a lithium secondary battery using a cathode containing a lithium-containing transition metal oxide and an anode containing graphitized carbon, characterized in that an ammonium compound capable of providing ammonium ions is added to a non-aqueous electrolyte. Therefore, the present invention provides a lithium secondary battery having improved high-temperature performance by reducing decreases of residual capacity and recovery capacity resulting from high-temperature storage of the battery, via addition of such an ammonium compound.
    Type: Application
    Filed: November 13, 2009
    Publication date: March 4, 2010
    Applicant: LG CHEM, LTD.
    Inventors: Soo ik JO, Jisang YU, Byungchul CHOI, Changjoo HAN
  • Publication number: 20100028784
    Abstract: A nonflammable electrolyte composition comprises: a homogenous solvent mixture and a lithium salt dissolved therein. The homogenous solvent mixture comprises a cyclic carbonate and a highly fluorinated compound selected from the group consisting of highly fluorinated acyclic carbonates, CF3CFHCF2OCH3, and combinations thereof. If the electrolyte composition has flammable constituents, they are present in a combined amount of less than 5 percent by weight. Lithium-containing electrochemical cells that include the electrolyte composition, and battery packs and devices including the same are also disclosed.
    Type: Application
    Filed: July 29, 2008
    Publication date: February 4, 2010
    Inventors: Phat T. Pham, William M. Lamanna, Michael J. Bulinski, Douglas C. Magnuson
  • Patent number: 7655361
    Abstract: Aspects of the present invention relate to an electrolyte for a high voltage lithium rechargeable battery and a high voltage lithium rechargeable battery employing the electrolyte, and more particularly to an electrolyte for a high voltage lithium rechargeable battery comprising a non-aqueous organic solvent; a lithium salt; and a combination of a halogenated biphenyl and a dihalogenated toluene used as an additive where the combined additive has an oxidation reduction potential of 4.6 to 5.0 V with respect to lithium. The lithium rechargeable battery employing the electrolyte for a high voltage lithium rechargeable battery achieves overcharge stability.
    Type: Grant
    Filed: August 6, 2007
    Date of Patent: February 2, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Yongshik Kim, Jinbum Kim, Jinsung Kim, Narae Park
  • Patent number: 7651820
    Abstract: A gel electrolyte and a gel electrolyte battery are provided. The gel electrolyte includes a matrix polymer; a nonaqueous solvent; and an electrolytic solution having an electrolyte salt containing lithium dissolved in the nonaqueous solvent, in which the matrix polymer is swollen with the electrolytic solution. The matrix polymer comprises polyvinylidene fluoride copolymerized with at least hexafluoropropylene in an amount of 3 wt % or more and 7.5 wt % or less. The nonaqueous solvent comprises ethylene carbonate; and at least one solvent selected from the group consisting of dimethyl carbonate, ethylmethyl carbonate, diethyl carbonate, ethylpropyl carbonate, ethyl butyl carbonate, and dipropyl carbonate. The content of the ethylene carbonate in the nonaqueous solvent is 15 wt % or more and 55 wt % or less, and the total content of the at least one solvent in the nonaqueous solvent is 30 wt % or more and 85 wt % or less.
    Type: Grant
    Filed: November 3, 2006
    Date of Patent: January 26, 2010
    Assignee: Sony Corporation
    Inventor: Mashio Shibuya
  • Publication number: 20100015521
    Abstract: A rechargeable battery and associated methods, the rechargeable battery including an anode, a cathode, wherein the cathode includes a ternary cathode-active material, a separator interposed between the cathode and the anode, an electrolyte, and a housing enclosing the electrolyte, the anode, and the cathode, wherein the electrolyte includes a lithium salt, a non-aqueous organic solvent, about 0.5 weight % to about 5 weight % of succinonitrile, and at least one of about 1 weight % to about 10 weight % of halogenated ethylene carbonate and about 1 weight % to about 5 weight % of vinyl ethylene carbonate.
    Type: Application
    Filed: July 6, 2009
    Publication date: January 21, 2010
    Inventor: Jinhee Kim
  • Publication number: 20090311608
    Abstract: A secondary battery capable of improving the cycle characteristics and the voltage retention characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolyte. The anode includes an anode current collector, an anode active material layer formed on the anode current collector and including an anode active material containing silicon as an element, and a coat formed on the anode active material layer and having an integral structure of three-dimensional network.
    Type: Application
    Filed: June 10, 2009
    Publication date: December 17, 2009
    Applicant: SONY CORPORATION
    Inventors: Takakazu Hirose, Kenichi Kawase, Kazunori Noguchi, Takayuki Fujii, Masaki Kawata
  • Publication number: 20090305144
    Abstract: There is provided an electrochemical device provided with an electrolytic solution comprising (I) a solvent for dissolving an electrolyte salt comprising (A) a fluorine-containing ether represented by the formula (1): Rf1—O—Rf2 wherein Rf1 and Rf2 are the same or different and each is a fluorine-containing alkyl group having 3 to 6 carbon atoms, (B) a cyclic carbonate, and (C) a chain carbonate being compatible with both of the fluorine-containing ether (A) and the cyclic carbonate (B), and (II) an electrolyte salt, in which the solvent (I) for dissolving an electrolyte salt comprises 30 to 60% by volume of the fluorine-containing ether (A), 3 to 40% by volume of the cyclic carbonate (B) and 10 to 67% by volume of the chain carbonate (C) based on the whole solvent (I), and when the electrochemical device is provided with such an electrolytic solution, no phase separation occurs even at low temperature, flame retardancy and heat resistance are excellent, solubility of an electrolyte salt is high, discharge
    Type: Application
    Filed: July 12, 2007
    Publication date: December 10, 2009
    Applicant: DAIKIN INDUSTRIES , LTD.
    Inventors: Meiten Koh, Hideo Sakata, Hitomi Nakazawa, Michiru Tanaka, Akiyoshi Yamauchi
  • Publication number: 20090305143
    Abstract: This invention relates to a non-aqueous electrolyte secondary battery including a positive electrode including a positive electrode mixture, a negative electrode, a separator, and a non-aqueous electrolyte. The positive electrode mixture includes a positive electrode active material, and the positive electrode active material includes a lithium nickel composite oxide. The non-aqueous electrolyte includes a non-aqueous solvent and a lithium salt dissolved in the non-aqueous solvent. The amount of moisture contained in the positive electrode mixture is greater than 1000 ppm and equal to or less than 6000 ppm. By adjusting the amount of moisture contained in the positive electrode mixture in the above range, it is possible to improve the cycle characteristics of the non-aqueous electrolyte secondary battery including the lithium nickel composite oxide as the positive electrode active material.
    Type: Application
    Filed: May 9, 2007
    Publication date: December 10, 2009
    Inventors: Hiroshi Matsuno, Takaharu Morikawa, Akihiro Maeda, Takeshi Yao
  • Patent number: 7615312
    Abstract: A rechargeable lithium-ion cell contains a positive electrode, negative electrode, charge-carrying electrolyte containing charge carrying medium and lithium salt, and an N-substituted or C-substituted phenothiazine compound dissolved in or dissolvable in the electrolyte. The substituted phenothiazine compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: November 10, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Jeffrey R. Dahn, Claudia Buhrmester, Richard L. Wang, William M. Lamanna
  • Patent number: 7615316
    Abstract: In order to manufacture a lithium secondary battery having excellent performances in safety under overcharge condition, cycle property, electric capacity, and storage endurance, 0.1 wt. % to 10 wt. % of a tert-alkylbenzene compound is favorably incorporated into a non-aqueous electrolytic solution comprising a non-aqueous solvent and an electrolyte, preferably in combination with 0.1 wt. % to 1.5 wt. % of a biphenyl compound.
    Type: Grant
    Filed: October 24, 2007
    Date of Patent: November 10, 2009
    Assignee: UBE Industries, Ltd.
    Inventors: Koji Abe, Yasuo Matsumori, Akira Ueki
  • Patent number: 7615317
    Abstract: A rechargeable lithium-ion cell contains a positive electrode, negative electrode, charge-carrying electrolyte containing charge carrying medium and lithium salt, and cycloaliphatic N-oxide compound dissolved in or dissolvable in the electrolyte. The N-oxide compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: November 10, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Jeffrey R. Dahn, Claudia Buhrmester
  • Patent number: 7601463
    Abstract: A nonaqueous electrolyte secondary battery includes: an outer housing; a nonaqueous electrolyte filled in the outer housing, a positive electrode housed in the outer housing, a negative electrode housed in the outer housing and a separator disposed between the negative electrode and the positive electrode. The nonaqueous electrolyte comprises a nonaqueous solvent including diethyl carbonate and at least one of ethylene carbonate and propylene carbonate, and the nonaqueous electrolyte has a content of the diethyl carbonate of from 80 to 95% by volume. The positive electrode comprises a positive electrode active substance having a positive electrode potential in a full charged state of 4.4 V or higher with respect to a potential of metallic lithium. The negative electrode comprises a negative electrode active substance having a negative electrode potential in a full charged state of 1.0 V or higher with respect to a potential of metallic lithium.
    Type: Grant
    Filed: June 9, 2005
    Date of Patent: October 13, 2009
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hiroki Inagaki, Hideaki Morishima, Yoshinao Tatebayashi, Yuji Sato, Norio Takami
  • Patent number: 7595130
    Abstract: A separator is disclosed which enables to inject a non-aqueous electrolytic solution easily during production of batteries such as lithium ion secondary batteries and also enables to produce a battery which is excellent in various battery performances. The battery separator comprises a long porous film in which plural non-porous linear regions are arranged in a width direction of the film, at least one surface of the linear regions being a concave or convex surface is advantageously used as a battery separator for lithium secondary batteries or the like.
    Type: Grant
    Filed: August 30, 2004
    Date of Patent: September 29, 2009
    Assignee: UBE Industries, Ltd.
    Inventors: Kenji Kawabata, Koji Abe
  • Patent number: 7592102
    Abstract: An electrolyte for a lithium ion secondary battery includes a non-aqueous organic solvent; lithium salt; and difluoro oxalato borate and fluoro ethylene carbonate (FEC). The capacity retention property and durability of a lithium ion secondary battery including the electrolyte is excellent even when the battery is left at a high temperature.
    Type: Grant
    Filed: October 23, 2008
    Date of Patent: September 22, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jinsung Kim, Narae Park, Jinhyunk Lim, Suhee Han, Jinburn Kim, Jungkang Oh
  • Publication number: 20090226818
    Abstract: An organic electrolytic solution including a lithium salt; an organic solvent including a high dielectric solvent and a low boiling point solvent; and an additive compound containing an electron withdrawing group and hydrocarbon-based substituents. A lithium battery using the organic electrolytic solution can have improved cycle characteristics and cycle life through preventing decomposition of the electrolyte.
    Type: Application
    Filed: August 22, 2008
    Publication date: September 10, 2009
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Seok-soo LEE, Dong-joon LEE, Young-gyoon RYU
  • Patent number: 7585590
    Abstract: Provided is a rechargeable lithium-ion cell that contains a positive electrode, a negative electrode, a charge-carrying electrolyte containing a charge carrying medium and a lithium salt, and a triphenylamine compound dissolved in or dissolvable in the electrolyte. The triphenylamine compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection. Also provided are methods for manufacturing a rechargeable lithium-ion cell.
    Type: Grant
    Filed: February 5, 2007
    Date of Patent: September 8, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Richard L. Wang, Claudia Buhrmester, William M. Lamanna, Jeffrey R. Dahn, Lee Moshurchak
  • Patent number: 7582389
    Abstract: A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode and a non-aqueous electrolyte, wherein the non-aqueous electrolyte includes an onium compound, a lithium salt and a chain carbonate having a C?C unsaturated bond. The onium compound is preferably at least one selected from the group consisting of a chain quaternary ammonium compound, a pyrrolidinium compound and a piperidinium compound. The chain carbonate having a C?C unsaturated bond is preferably at least one selected from the group consisting of diallyl carbonate and allyl phenyl carbonate.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: September 1, 2009
    Assignee: Panasonic Corporation
    Inventors: Tooru Matsui, Masaki Deguchi, Hiroshi Yoshizawa
  • Patent number: 7560195
    Abstract: An electrolyte for a lithium battery and a lithium battery thereof are provided. The electrolyte includes a non-aqueous organic solvent; lithium salt; and an additive selected from the group consisting of the compounds represented by formulas (1) to (3), and combinations thereof: where X is selected from the group consisting of hydrogen, halogen, alkyl groups having from 1 to 6 carbon atoms, and aryl groups having from 6 to 8 carbon atoms, and R is an alkyl group having from 1 to 6 carbon atoms or an aryl group having from 6 to 10 carbon atoms. The lithium battery including the electrolyte suggested in the present invention has superior overcharge characteristics and superior safety characteristics compared to conventional batteries including a non-aqueous electrolyte.
    Type: Grant
    Filed: May 12, 2008
    Date of Patent: July 14, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Kyoung-Han Yew, Eui-Hwan Song
  • Publication number: 20090169985
    Abstract: A battery capable of improving the cycle characteristics is provided. The battery includes a cathode and an anode oppositely arranged with a separator in between, and an electrolytic solution. At least one of the cathode, the anode, the separator, and the electrolytic solution contains a sulfone compound having an acid anhydride group and a sulfonyl group.
    Type: Application
    Filed: December 12, 2008
    Publication date: July 2, 2009
    Applicant: SONY CORPORATION
    Inventors: Hiroyuki Yamaguchi, Masayuki Ihara, Tadahiko Kubota
  • Patent number: 7553588
    Abstract: An electrolyte for a lithium secondary battery includes lithium salts, a non-aqueous organic solvent, and additive compounds. The additive compounds added to the electrolyte of the present invention decompose earlier than the organic solvent to form a conductive polymer layer on the surface of a positive electrode, and prevent decomposition of the organic solvent. Accordingly, the electrolyte inhibits gas generation caused by decomposition of the organic solvent at initial charging, and thus reduces an increase of internal pressure and swelling during high temperature storage, and also improves safety of the battery during overcharge.
    Type: Grant
    Filed: September 10, 2003
    Date of Patent: June 30, 2009
    Assignees: Samsung SDI Co., Ltd., Cheil Industries Inc.
    Inventors: Jin-Hee Kim, Jin-Sung Kim, Sang-Moon Hwang, Meen-Seon Paik, Hak-Soo Kim
  • Publication number: 20090117473
    Abstract: A negative electrode for a nonaqueous electrolyte secondary battery having a small surface film resistance and a high negative electrode strength, wherein the negative electrode includes a collector and an active material layer formed thereon, wherein the active material layer contains an active material and a binder composition, wherein the active material is a material in which metal oxide fine particles having an average particle diameter of 250 nm or less are attached to the surface thereof, and wherein the binder composition contains a binder having an olefinic unsaturated bond.
    Type: Application
    Filed: January 7, 2009
    Publication date: May 7, 2009
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Hideharu Satoh, Masakazu Yokomizo, Tadashi Ishihara
  • Publication number: 20090111031
    Abstract: A battery capable of improving the cycle characteristics is provided. The battery includes a cathode, an anode, and an electrolytic solution. The anode has an anode active material layer that contains an anode active material containing silicon on an anode current collector, and intensity ratio I1/I2 between peak intensity I1 originated in (220) crystalline plane of silicon obtained by X-ray diffraction and peak intensity I2 originated in (111) crystalline plane of silicon obtained by X-ray diffraction is 0.05 or more.
    Type: Application
    Filed: October 30, 2008
    Publication date: April 30, 2009
    Applicant: SONY CORPORATION
    Inventors: Takakazu Hirose, Takayuki Fujii, Kazunori Noguchi, Kenichi Kawase
  • Patent number: 7524579
    Abstract: A method for enhancing the performance characteristics of a battery through the use of the electrolyte composition comprised of a non-aqueous solvent, and a salt mixture. The salt mixture includes an alkali metal electrolyte salt and an additive salt having an anion of a mixed anhydride of oxalic acid and boric acid. Specific additive salts include lithium bis(oxalato) borate and lithium oxalyldifluoroborate. Particular electrolyte salts comprise LiPF6 and LiBF4. The additive salt is present in an amount of 0.1-60 mole percent of the total of the additive salt and electrolyte salt content of the electrolyte.
    Type: Grant
    Filed: December 21, 2006
    Date of Patent: April 28, 2009
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: T. Richard Jow, Shengshui Zhang, Kang Xu
  • Patent number: 7514182
    Abstract: An organic electrolytic solution and a rechargeable lithium battery comprising the same is provided. The organic electrolytic solution contains a lithium salt and an organic solvent mixture. The organic solvent mixture is comprised of a solvent with high permittivity, a solvent with a low boiling point, and a cyclic organic compound having at least an oxy-carbonyl group and having a ring structure of 6 units or more. The organic electrolytic solution helps to increase reduction decomposition stability in the lithium battery using the same. As a result, the irreversible capacity of the lithium battery at a first cycle decreases and charge/discharge efficiency and lifespan of the lithium battery increases. In addition, the battery thickness is maintained within a specific range at room temperature after formation and standard charging, which improves the reliability of the lithium battery.
    Type: Grant
    Filed: February 3, 2005
    Date of Patent: April 7, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Han-Su Kim, Jin-Sung Kim, Myung-Dong Cho, Hyo-Sug Lee, Dong-Min Im
  • Patent number: 7510807
    Abstract: Disclosed is an electrolyte of a lithium secondary battery comprising a lithium salt, an organic solvent, and at least one additive compound selected from the group consisting of compounds represented by the following formula (1) and derivatives thereof: where R1 is selected from the group consisting of hydrogen radicals, alkyls aryls, cycloalkyls, alkenyls, alkynyls, ester radicals, and aliphatic carbonate radicals. The electrolyte improves both swelling inhibition properties at high temperature and capacity characteristics of a lithium secondary battery.
    Type: Grant
    Filed: April 28, 2004
    Date of Patent: March 31, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Hyung-Gon Noh
  • Patent number: 7510803
    Abstract: A battery with a high battery voltage at charging and improved energy density is provided. A cathode (12) and an anode (14) are laminated with a separator (15) sandwiched therebetween which is impregnated with an electrolyte. The cathode (12) has a cathode active material including a lithium composite oxide which contains lithium, at least either cobalt or nickel, and oxygen. The battery voltage at charging is 4.25 V or more. The total amount of lithium carbonate and lithium sulphate in the cathode (12) to the cathode active material is 1.0 wt % or less, a concentration of protic impurities in the electrolyte, which is converted to a mass ratio of protons to the electrolyte, is 20 ppm or less, or moisture content in the electrolyte is 20 ppm mass ratio or less to the electrolyte. This inhibits metal eluting from the lithium composite oxide even at high voltages.
    Type: Grant
    Filed: August 23, 2002
    Date of Patent: March 31, 2009
    Assignee: Sony Corporation
    Inventors: Momoe Adachi, Shigeru Fujita, Takuya Endo, Yasunobu Iwakoshi, Goro Shibamoto
  • Publication number: 20090068564
    Abstract: Provided is a method of designing an electrolyte composition including a nonaqueous organic solvent mixture and a lithium salt to obtain an optimal composition ratio of components of the electrolyte composition for a high charging/high-output discharging secondary battery. The method includes: selecting components of the nonaqueous organic solvent mixture; determining composition ratio ranges of the selected components satisfying such conditions that an average dielectric constant, an average viscosity, and an average boiling point satisfy predetermined boundary values; dividing the ranges of the composition ratios into a plurality of groups; selecting a representative composition ratio of each of the groups; adding a lithium salt to a nonaqueous organic solvent mixture having the representative composition ratio to prepare an electrolyte composition; and measuring properties of the electrolyte composition to determine a composition ratio of an electrolyte composition having predetermined properties.
    Type: Application
    Filed: February 28, 2008
    Publication date: March 12, 2009
    Applicant: Electronics and Telecommunications Research Institute
    Inventors: Young-Gi Lee, Kwang Man Kim, Mangu Kang, Jongdae Kim
  • Patent number: 7498101
    Abstract: A nonaqueous electrolyte secondary battery is provided with a positive electrode including a positive-electrode active material, a negative electrode including a negative-electrode active material, and a nonaqueous electrolyte solution. The negative electrode further includes carbon fibers and carbon flakes. The synergistic effects of the improved retention of the electrolyte solution by the carbon fibers and the improved conductivity between the active material particles by the carbon flakes facilitate doping/undoping of lithium in a high-load current mode and increase the capacity of the battery in the high-load current mode.
    Type: Grant
    Filed: November 29, 2006
    Date of Patent: March 3, 2009
    Assignee: Sony Corporation
    Inventors: Akira Yamaguchi, Shinji Hatake, Masayuki Nagamine, Atsuo Omaru
  • Patent number: 7494746
    Abstract: An electrolyte for a rechargeable lithium battery includes a compound represented by Formula 1, a lithium salt, and a non-aqueous organic solvent: A[OSi(CmH2m+1)3]3??(1) wherein A is P or B, and m is an integer ranging from 0 to 6.
    Type: Grant
    Filed: August 2, 2007
    Date of Patent: February 24, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Vasily Tarnopolsky
  • Patent number: 7494745
    Abstract: An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes: a lithium salt; an organic solvent containing a high dielectric constant solvent and a low boiling point solvent; and a carbonate or oxalate derivative having at least one substituted or unsubstituted cyano group. The organic electrolytic solution and the lithium battery employing the same have improved reductive decomposition stability, thereby decreasing an irreversible capacity after a first cycle and improving the charge/discharge efficiency and lifespan of the battery. The lithium battery has non-varying chemical properties at room temperature and a uniform thickness after standard charging, and thus has high reliability.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: February 24, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Han-Su Kim, Myung-Dong Cho, Dong-Min Im, Boris A. Trofimov, Albina Mikhalev
  • Patent number: 7491470
    Abstract: The electrolyte for a lithium battery includes a non-aqueous organic solvent, a lithium salt, and an additive of the following Formula 1: wherein, X is O or S, Y1, Y2, and Y3 are the same or different from each other and selected from the group consisting of O, S, CR2, and NR, where here R is H, a halogen, or an alkyl having a carbon number of less than or equal to 8, or neighboring alkyl groups are combined to each other to form a cycle or hetero cycle, and Ra to Rd are the same or different from each other and selected from H, a halogen, an alkoxy group having a carbon number of less than or equal to 8, or an unsaturated or saturated alkyl group having a carbon number of less than or equal to 8, or neighboring alkyl groups are combined to each other to form a cycle or hetero cycle.
    Type: Grant
    Filed: October 26, 2005
    Date of Patent: February 17, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Dae-Yup Shin, Dong-Hyun Jung, Soo-Jin Park, Kyoung-Han Yew, Hyun-Jeong Lim
  • Patent number: 7482099
    Abstract: The electrolyte for a lithium battery includes a non-aqueous organic solvent, a lithium salt, and an additive of the following Formula 1: wherein, X is O, S, CR2 or NR, where here R is H, a halogen, or an alkyl having a carbon number of less than or equal to 8, or neighboring alkyl groups are combined to each other to form a cycle or hetero cycle, Y1, and Y2 are the same or different from each other and selected from O, S, CR2, and NR, where here R is H, a halogen, or an alkyl having a carbon number of less than or equal to 8, or neighboring alkyl groups are combined to each other to form a cycle or hetero cycle, Y3 is S, CR2, or NR, where here R is H, a halogen, or an alkyl having a carbon number of less than or equal to 8, or neighboring alkyl groups are combined to each other to form a cycle or hetero cycle, and Ra to Rd are the same or different from each other and selected from H, a halogen, an alkoxy group having a carbon number of less than or equal to 8, or an unsaturated or saturated alkyl group
    Type: Grant
    Filed: October 26, 2005
    Date of Patent: January 27, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Dae-Yup Shin, Dong-Hyun Jung, Soo-Jin Park, Kyoung-Han Yew, Hyun-Jeong Lim
  • Patent number: 7482100
    Abstract: The electrolyte for a lithium battery includes a non-aqueous organic solvent, a lithium salt, and an additive of the following Formula 1: wherein, X is O or S, Y1, Y2, and Y3 are the same or different from each other and selected from O, S, CR2, and NR, where here R is H, a halogen, or an alkyl having a carbon number of less than or equal to 8, or neighboring alkyl groups are combined to each other to form a cycle or hetero cycle, and Ra to Rd are the same or different from each other and selected from H, a halogen, an alkoxy group having a carbon number of less than or equal to 8, and an unsaturated or saturated alkyl group having a carbon number of less than or equal to 8, or neighboring alkyl groups are combined to each other to form a cycle or hetero cycle.
    Type: Grant
    Filed: October 26, 2005
    Date of Patent: January 27, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Dae-Yup Shin, Dong-Hyun Jung, Soo-Jin Park, Kyoung-Han Yew, Hyun-Jeong Lim
  • Publication number: 20090023076
    Abstract: A polymer electrolyte with the superior chemical stability and the high ion conductivity and a battery using it are provided. A polymer electrolyte (23) contains a polymer compound having a structure in which polyvinyl acetal is polymerized and an electrolytic solution containing a solvent and an electrolyte salt. The solvent contains 80 wt % or more of carbonate ester in which a cyclic compound such as ethylene carbonate and a chain compound such as methyl ethyl carbonate are mixed. The weight ratio between the cyclic compound and the chain compound in carbonate ester is in the range from 2:8 to 5:5. Thereby, high ion conductivity can be obtained. In addition, even when the ratio of carbonate ester in the solvent is increased, the solubility of polyvinyl acetal can be improved.
    Type: Application
    Filed: March 8, 2006
    Publication date: January 22, 2009
    Applicant: SONY CORPORATION
    Inventors: Yukifumi Takeda, Yoshiaki Naruse
  • Publication number: 20090017386
    Abstract: Non-aqueous electrolyte solutions capable of protecting negative electrode materials such as lithium metal and carbonaceous materials in energy storage electrochemical cells (e.g., lithium metal batteries, lithium ion batteries and supercapacitors) include an electrolyte salt, a non-aqueous electrolyte solvent mixture, an unsaturated organic compound 4-methylene-1,3-dioxolan-2-one or 4,5-dimethylene-1,3-dioxolan-2-one, and other optional additives. The 1,3-dioxolan-2-ones help to form a good solid electrolyte interface on the negative electrode surface.
    Type: Application
    Filed: July 11, 2007
    Publication date: January 15, 2009
    Applicant: FERRO CORPORATION
    Inventors: Wu Xu, Pascal Bolomey, Martin W. Payne
  • Publication number: 20090011340
    Abstract: An organic electrolytic solution comprising a nonaqueous solvent and a lithium salt, wherein the organic electrolytic solution comprises a compound of Formula 1 and at least one selected from compounds of Formulas 2 through 5: wherein R1, a C1˜C10 alkoxy group, wherein R2 and R3 are independently unsubstituted C1˜C5 alkyl group or C1˜C5 alkyl group substituted with halogen atom, wherein n is an integer between 1 and 6.
    Type: Application
    Filed: August 8, 2008
    Publication date: January 8, 2009
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Doo-yeon Lee, Hyo-sug Lee