Abstract: A non-aqueous rechargeable electrochemical cell includes an electrolyte composition produced through the dissolution of a thermally stable lithium salt in a lactone solvent. The resulting cell has stable performance in a wide temperature range between ?40° C. and 80° C. The resulting cell operates across this wide temperature range with a commercially acceptable capacity retention, power loss characteristics, and safety characteristics across this temperature range.

Abstract: An additive for a sodium ion secondary battery of the present invention includes a compound of at least one of a saturated cyclic carbonate having a fluoro group and a chain carbonate having a fluoro group. A sodium ion secondary battery (1) of the present invention includes: a non-aqueous electrolytic solution including the additive for a sodium ion secondary battery and a non-aqueous solvent containing a saturated cyclic carbonate or a non-aqueous solvent containing a saturated cyclic carbonate and a chain carbonate; a positive electrode (11); and a negative electrode (12) that includes a coating formed in a surface of the negative electrode, the coating containing a composite material having carbon, oxygen, fluorine and sodium in the surface and includes a negative-electrode active material containing a hard carbon.

Abstract: Disclosed is a lithium secondary battery with improved rate characteristics. More particularly, disclosed is a lithium secondary battery including a cathode, an anode, a separator disposed between the cathode and the anode, and an electrolyte, wherein the electrolyte includes a mixed solvent of a cyclic carbonate-based material and a propionate-based material, the cathode includes a lithium manganese composite oxide represented by Formula 1 below as a cathode active material, and the anode includes a lithium metal oxide represented by Formula 2 below as an anode active material: LixMyMn2?yO4?zAz??(1) wherein 0.9?x?1.2, 0<y<2, and 0?z<0.2, M is at least one element selected from the group consisting of Al, Mg, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Zr, Nb, Mo, Sr, Sb, W, Ti, and Bi; and A is at least one monovalent or divalent anion, LiaM?bO4?xAc??(2) wherein M? is at least one element selected from the group consisting of Ti, Cu, Pb, Sb, Zn, Fe, In, Al, and Zr; 0.1?a?4 and 0.

Abstract: The disclosed subject matter relate to a di-tert-butylphenyl alkylsulfonate compound, tertbutylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tertbutylphenyl arylsulfonate compound useful as an intermediate raw material of a pharmaceutical, agricultural chemical, electronic material or polymer material and the like, or as a battery material, and also provides a nonaqueous electrolytic solution for a lithium secondary battery having superior cycle performance and other battery properties through the use thereof, and a lithium secondary battery. The disclosed embodiments further relate to a nonaqueous electrolytic solution for use as in a lithium secondary battery containing, in a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, 0.

Abstract: A non-aqueous electrolyte in which the proportion of diethyl carbonate is reduced, and a nonaqueous electrolyte secondary battery using the same that has high safety are provided. The non-aqueous electrolyte of the invention for use in secondary batteries includes ethylene carbonate, propylene carbonate, diethyl carbonate, and an additive, as a non-aqueous solvent. The additive is at least one of a fluorinated aromatic compound having a molecular weight of 90 to 200 and a fatty acid alkyl ester having a molecular weight of 80 to 240. A weight ratio WEC ethylene carbonate, a weight ratio WPC of propylene carbonate, a weight ratio W DEC of diethyl carbonate, and a weight ratio WLV of the additive are 5 to 30 wt %, 15 to 60 wt %, 10 to 50 wt %, and 5 to 35 wt %, respectively, to the total of the non-aqueous electrolyte.

Abstract: A non-aqueous electrolyte and a lithium secondary battery using the same are provided, which satisfy both flame retardancy and charge-discharge cycle characteristics, and attain a longer lifetime of the battery. A mixture of a chain carbonate, vinylene carbonate, a fluorinated cyclic carbonate and a phosphate ester is used as the non-aqueous electrolyte. It is desirable that the phosphate ester includes trimethyl phosphate and a fluorinated phosphate ester. Further, it is desirable that ethylene carbonate is further contained.

Abstract: In a lithium ion secondary battery using a positive electrode active material made of a lithium manganese based oxide that contains Li and tetravalent Mn and having a crystal structure known as a layered rock salt structure, oxidative and reductive degradation of the non-aqueous electrolyte solution is reduced. The battery uses a non-aqueous electrolyte solution containing fluorine in one or both of the non-aqueous solvent and the electrolytic salt. For the negative electrode active material, SiOx (0.3?x?1.6) is used. The combined use of the non-aqueous electrolyte solution containing fluorine and SiOx in the negative electrode active material reduces oxidative and reductive degradation of the non-aqueous electrolyte solution.

Abstract: An object is to provide a nonaqueous electrolyte and a nonaqueous-electrolyte secondary battery which have excellent discharge load characteristics and are excellent in high-temperature storability, cycle characteristics, high capacity, continuous-charge characteristics, storability, gas evolution inhibition during continuous charge, high-current-density charge/discharge characteristics, discharge load characteristics, etc. The object has been accomplished with a nonaqueous electrolyte which comprises: a monofluorophosphate and/or a difluorophosphate; and further a compound having a specific chemical structure or specific properties.

Abstract: An electrochemical cell provided with a positive electrode, a negative electrode, and an electrolyte. The positive electrode comprises a stabilized lithium metal oxide material, the lithium metal oxide material comprising one or more transition metal ions. The electrolyte is prepared by mixing ingredients comprising a solvent, a lithium salt, and a sultone.

Abstract: A rechargeable lithium battery including a negative electrode made by depositing a noncrystalline thin film composed entirely or mainly of silicon on a current collector, a positive electrode and a nonaqueous electrolyte, characterized in that said nonaqueous electrolyte contains carbon dioxide dissolved therein.

Abstract: A non-aqueous electrolyte solution for a lithium secondary battery and a lithium secondary battery including the same are provided. The non-aqueous electrolyte solution includes an organic solvent, an ionizable lithium salt, a dinitrile compound including an ether bond represented by Chemical Formula 1, and an aliphatic dinitrile compound represented by Chemical Formula 2. The lithium secondary battery including the non-aqueous electrolyte solution having the possibility of generating a swelling phenomenon while storing or charging/discharging at a high temperature may be restrained. In addition, a cycle life of the charging/discharging may be improved.

Abstract: A nonaqueous electrolytic solution for a secondary battery containing an electrolyte, a solvent and methyl difluoroacetate as an additive in an amount of not less than 0.05 part by mass and not more than 10 parts by mass based on 100 parts by mass of the whole solvent.

Abstract: In certain embodiments, a battery component comprises an electrode and a separator deposited on a surface of the electrode is provided. The separator comprises a porous poly(para-xylylene) film. In some embodiments, the electrode can include at least one cavity or protrusion, and the separator layer can be gas phase deposited directly on the electrode. In certain embodiments, methods of making a battery component are also provided.

Abstract: The present invention is aimed at providing a nonaqueous electrolyte secondary battery capable of improving cycling characteristics by improving a positive electrode active material when particles with a structure in which primary particles are aggregated to front, secondary particles are used as the positive electrode active material of the nonaqueous electrolyte secondary battery, thereby permitting preferred use as a power supply of a hybrid electric car or the like. The positive electrode active material includes secondary particles 20 composed of aggregated primary particles 21, the primary particles 21 have an aspect ratio of 2.0 or more and 10.0 or less, and in powder X-ray diffraction measurement using CuK? ray, the positive electrode active material satisfies 0.10°?FWHM110 ?0.30° wherein FWHM110 represents a full width at half maximum of a 110 diffraction peak present within a range of diffraction angle 2? of 64.5°±1.0°.

Abstract: A nonaqueous electrolyte solution for secondary batteries, which maintains small internal resistance and high electrical capacitance in long-term use in a nonaqueous electrolyte secondary battery uses, as an active material, a crystalline carbon material having a high crystallinity, and a negative electrode produced using a polymeric carboxylic compound as a binding agent. The nonaqueous electrolyte solution contains: (A) at least one compound selected from a group consisting of an unsaturated phosphate ester compound represented by a general formula (1) and an unsaturated phosphate ester compound represented by a general formula (2); (B) at least one compound selected from a group consisting of a sulfite ester compound, a sulfonate ester compound, an alkali metal imide salt compound, a fluorosilane compound, an organic disilane compound or an organic disiloxane compound; (C) an organic solvent, and (D) an electrolyte salt. A secondary battery using such nonaqueous electrolyte solution is also described.

Abstract: A method of preparing a tricyanoalkoxy alkane compound is disclosed. The tricyanoalkoxy alkane compound is prepared by reacting an alcohol compound including at least three hydroxyl groups and a nitrile compound in the presence of a potassium alkoxide catalyst. A non-aqueous electrolyte solution comprising the tricyanoalkoxy alkane compound and a lithium secondary battery also are disclosed. The swelling of the battery may be prevented.

Abstract: A non-aqueous electrolyte secondary battery that has a battery element including a positive electrode member, a negative electrode member, and a non-aqueous electrolyte solution. The negative electrode member contains graphitizable carbon. With respect to 100 parts by weight of the non-aqueous electrolyte solution, fluoroethylenecarbonate is added at 0.5 parts by weight or more and 1.0 parts by weight or less, and lithium difluorobis(oxalato)phosphate is added at 0.5 parts by weight or more and 1.0 parts by weight or less, or fluoroethylenecarbonate and lithium difluorobis(oxalato)phosphate are added at 0.5 parts by weight or more and 2.0 parts by weight or less in total.

Abstract: Disclosed are (1) a nonaqueous electrolytic solution for lithium battery comprising an electrolyte dissolved in a nonaqueous solvent, which contains at least one hydroxy acid derivative compound represented by the formulae (I) and (II) in an amount of from 0.

Abstract: The present invention provides non-aqueous electrolyte solution for a lithium secondary battery, comprising an ester-based compound having a branched-chain alkyl group and an ester-based compound having a straight-chain alkyl group; and a lithium secondary battery using the same.

Abstract: (1) A container for a nonaqueous electrolytic solution, containing a material containing an aluminum or aluminum alloy layer, and storing a nonaqueous electrolytic solution containing a nonaqueous solvent having dissolved therein an electrolyte salt, the container having a cap and a plug each formed of a resin, and maintaining the nonaqueous electrolytic solution to have a water content of 50 ppm or less after storing in the container for 30 days, (2) a nonaqueous electrolytic solution placed in the container, and (3) a method for storing a nonaqueous electrolytic solution. The container for a nonaqueous electrolytic solution is a light weight container that prevents the nonaqueous electrolytic solution from being decomposed on storing to maintain the high quality, and facilitates and ensures the handling of the nonaqueous electrolytic solution.

Abstract: The present invention provides a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, containing 0.01% to 30% by weight of a 1,2-cyclohexanediol derivative having a specific structure; and a lithium secondary battery using the nonaqueous electrolytic solution. The lithium secondary battery exhibits excellent battery characteristics such as electrical capacity, cycle property, and storage property and can maintain excellent long-term battery performance.

Abstract: The present invention provides a non-aqueous electrolyte solution that can be used as an electrolyte solution of a non-aqueous secondary battery to improve the discharge rate performance of the battery. The non-aqueous electrolyte solution comprises a non-aqueous solvent and a BF3-cyclic ether complex. The BF3-cyclic ether complex content is greater than zero part by mass, but less than 1 part by mass relative to 100 parts by mass of the total amount of other electrolyte solution components. Preferable examples of the BF3-cyclic ether complex include BF3-tetrahydropyran complex and BF3-dioxane complex.

Abstract: [Problem] To provide a nonaqueous electrolyte secondary battery exhibiting superior stability characteristics and having charge/discharge characteristics exhibiting a high-rate discharge stroke, even when a lithium-nickel-cobalt manganate and a spinel-type lithium manganate are used as the positive electrode active material. [Solution] A mixture having a specific ratio of a tungsten- and zirconium-modified lithium-nickel-cobalt manganate and a spinel-type lithium manganate is used as the positive electrode active material. Furthermore, a nonaqueous electrolyte having a specific ratio of the content of dimethyl carbonate and the content of a cyclic carbonate is used.

Abstract: A nonaqueous electrolytic solution includes a cyclic carbonate and a chain carbonate, and contains a glycol sulfate derivative represented by formula (I) below and fluoroethylene carbonate: [wherein each of R1 and R2 independently represents at least one selected from the group consisting of a hydrogen atom and a hydrocarbon group having 1 to 5 carbon atoms].

Abstract: A lithium secondary battery has an anode, a cathode, a separator between the anode and the cathode and a non-aqueous electrolyte. The non-aqueous electrolyte includes a lithium salt; and a non-linear carbonate-based mixed organic solvent in which (a) a cyclic carbonate compound, and (b) a propionate-based compound are mixed at a volume ratio (a:b) in the range from about 10:90 to about 70:30, and optionally (c) a vinylene carbonate; and an inhibitor against a reaction between the anode and the propionate-based ester compound. The cathode has a current density in the range from about 3.5 to about 5.5 mA/cm2 and a porosity in the range from about 18 to about 35%. This battery may be manufactured as a high-loading lithium secondary battery.

Abstract: Disclosed is a secondary battery including a cathode, an anode, a separator, and an electrolyte, wherein the electrolyte includes a ternary eutectic mixture prepared by adding (c) a carbonate-based compound to a eutectic mixture containing (a) an amide group-containing compound and (b) an ionizable lithium salt, and the carbonate-based compound is included in an amount of less than 50 parts by weight based on 100 parts by weight of the electrolyte. The use of the disclosed ternary eutectic mixture having flame resistance, chemical stability, high conductivity, and a broad electrochemical window, as the electrolyte material, improves both the thermal stability and quality of the battery.

Abstract: The present invention provides non-aqueous electrolyte solution for a lithium secondary battery, comprising a pyrimidine-based compound, a non-fluorinated solvent and a fluorinated solvent; and a lithium secondary battery using the same.

Abstract: The present invention provides non-aqueous electrolyte solution for a lithium secondary battery, comprising fluoroethylene carbonate and a pyrimidine-based compound; and a lithium secondary battery using the same.

Abstract: A nonaqueous electrolytic solution that provides a lithium secondary battery with excellent electrical capacity, cycling properties, storage properties and other battery characteristics and that maintains the battery characteristics for a long time; and a lithium secondary battery comprising it. A nonaqueous electrolytic solution comprising an electrolytic salt dissolved in a nonaqueous solvent, containing 0.1 to 10% by weight of an ethylene carbonate derivative represented by the general formula (I), and 0.

Abstract: The present invention provides a non-aqueous electrolyte solution for a lithium secondary battery, comprising an ester-based compound having a branched-chain alkyl group; and a lithium secondary battery using the same.

Abstract: Disclosed is a non-aqueous electrolyte including an electrolyte salt and an electrolyte solvent, the non-aqueous electrolyte further including a compound containing both a carboxy group and a (meth)acrylic group, and a secondary battery including the non-aqueous electrolyte. The use of the compound containing both the carboxy group and the (meth)acrylic group as a component for an electrolyte significantly reduces the increase of battery thickness at high temperature storage.

Abstract: The present invention directs to a non-aqueous electrolyte solution, including (I) at least one compound selected from the group consisting of fluorinated linear sulfones and fluorinated linear sulfonic acid esters, and (II) an electrolyte salt. Such a non-aqueous electrolyte solution has high oxidation resistance, minimizes its decomposition even when hydrofluoric acid is produced. Also, the solution is less likely to cause, in the case of being used for a secondary cell, swelling of the cell and lowering of the battery performance.

Abstract: Provide are fluorinated cyclic and acyclic carbonate solvent compositions such as various fluorine substituted 1,3-dioxolane-2-one compounds and fluorine substituted 1,3-dioxane-2-one compounds, which are useful as electrolyte solvents for lithium ion batteries.

Abstract: Provided are (1) a novel phenyl sulfonate compound, (2) a nonaqueous electrolytic solution comprising an electrolyte salt dissolved in a nonaqueous solvent and containing a phenyl sulfonate compound of the following general formula (II) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution, and (3) a lithium battery containing the nonaqueous electrolytic solution and excellent in low-temperature cycle property. (wherein X1 to X5 each independently represents a fluorine atom or a hydrogen atom, and from one to four of these are fluorine atoms; R2 represents a linear or branched alkyl group having from 1 to 6 carbon atoms, a linear or branched alkyl group having from 1 to 6 carbon atoms in which at least one hydrogen atom is substituted with a halogen atom, or an aryl group having from 6 to 9 carbon atoms).

Abstract: Disclosed is a rechargeable lithium battery that includes a positive electrode having an active mass density of about 3.4 g/cc to about 4.0 g/cc, a negative electrode, and an electrolyte including a non-aqueous organic solvent including a compound represented by Chemical Formula 1 in an amount of about 10 volume % to about 50 volume % based on the total amount of the non-aqueous organic solvent. Chemical Formula 1: CH3COO—R1, wherein R1 is a C1 to C4 linear or branched alkyl group.

Abstract: An additive typified by tris(trimethylsilyl)phosphate, tris(trimethylsilyl)borate, and tetrakis(trimethylsiloxy)titanium (Chem. 3) are applied to a nonaqueous electrolyte containing a chain carbonate and/or a chain carboxylate as a main solvent (contained at a ratio of 70 volume % or higher). It is preferable that 0?a<30 is satisfied, in which “a” denotes the volume of a cyclic carbonate among carbonates having no carbon-carbon double bond in the entire volume, defined as 100, of the carbonates having no carbon-carbon double bond and chain carboxylates in a nonaqueous solvent contained in the nonaqueous electrolyte (0<a<30 in the case no chain carboxylate is contained).

Abstract: A mixture useful as an electrolyte in lithium ion batteries and use thereof are provided. Lithium ion batteries with good performance, especially good cyclability after prolonged operation are obtained. The mixture contains an aprotic organic solvent, a cyclic compound containing C1-C10-alkyl, C3-C10-cycloalkyl, benzyl or C6-C14-aryl, water, optionally an additive and a lithium salt.

Abstract: Electrolytes for lithium based batteries are described with good temperature tolerance over appropriate temperature ranges for uses in vehicles. In particular, the electrolytes are suitable for high voltage operation over 4.4V and can provide high rate performance. The electrolytes generally comprise a solvent that is a mixture of ethylene carbonate, dimethyl carbonate and ethylmethyl carbonate. Alternatively, a solvent combination of fluoroethylene carbonate and dimethyl carbonate was used. A primary lithium salt is includes at a concentration greater than about 1.05M. The electrolyte generally also comprises a lithium salt additive. The electrolytes can provide some battery capacity down to at least ?40° C. while providing good performance also at elevated temperatures of 45° or more, and the corresponding batteries can be cycled to several thousand cycles.

Abstract: Disclosed is a non-aqueous electrolyte for a lithium secondary battery and a lithium secondary battery comprising the same. The non-aqueous electrolyte including an ionizable lithium salt and an organic solvent may further include (a) 1 to 10 parts by weight of a compound having a vinylene group or vinyl group per 100 parts by weight of the non-aqueous electrolyte, and (b) 10 to 300 parts by weight of a dinitrile compound having an ether bond per 100 parts by weight of the compound having the vinylene group or vinyl group. The lithium secondary battery comprising the non-aqueous electrolyte may effectively suppress the swelling and improve the charge/discharge cycle life.

Abstract: A non-aqueous electrolyte can suppress decomposition of a solvent, improve the cycle life of a secondary battery, suppress the rise of resistance of a secondary battery and improve the capacity maintenance ratio of a secondary battery.

Abstract: A non-aqueous electrolyte solution for a lithium ion secondary battery includes a lithium salt and an organic solvent. The organic solvent includes a carbonate compound, a linear ester compound and a linear ester decomposition inhibitor. This non-aqueous electrolyte solution restrains swelling while improving low temperature charging/discharging characteristics of the secondary battery in comparison to a conventional electrolyte since it contains the linear ester compound and the linear ester decomposition inhibitor. The non-aqueous electrolyte solution may be used in making a lithium ion secondary battery.

Abstract: A lithium/oxygen battery includes a lithium anode, an air cathode, and a non-aqueous electrolyte soaked in a microporous separator membrane, wherein non-aqueous electrolyte comprises a lithium salt with a general molecular formula of LiBF3X (X?F, Cl, or Br, respectively) and a non-aqueous solvent mixture.

Abstract: Provided are an electrolyte solution for lithium secondary battery, which includes dipentaerythritol hexaacrylate and a (meth)acrylate compound having a C4 to C12 linear or branched alkyl group as electrolyte additives, and a lithium secondary battery including the electrolyte solution. The electrolyte solution can improve the safety of the battery, and the performance characteristics, particularly cycle life characteristics, of the battery.

Abstract: An electrolyte solution for a rechargeable lithium battery that includes a lithium salt; a non-aqueous organic solvent including ethyl acetate; and an additive including a sultone-based compound, wherein the sultone-based compound is included in an amount ranging from 0.1 to 5 wt % based on the total amount of the electrolyte solution is provided.

Abstract: LiPO2F2 is manufactured by the reaction of P4O10 with LiF forming a reaction mixture comprising LiPO2F2. To isolate pure LiPO2F2, the reaction mixture is extracted with water, organic solvents or mixtures thereof, and if desired, pure LiPO2F2 is isolated from the solution. The pure LiPO2F2 can be re-dissolved in suitable organic solvents, e.g. in fluorinated and/or non-fluorinated organic carbonates. Another aspect of the present invention is crystalline LiPO2F2. LiPO2F2 is suitable as electrolyte salt or as electrolyte salt additive for Li ion batteries, for lithium-sulfur batteries and for lithium-oxygen batteries.

Abstract: In a lithium on secondary battery, lithium ions are reversibly absorbed to and released from a negative electrode. A positive electrode includes lithium vanadium phosphate. A non-aqueous electrolytic solution includes fluorinated carbonate as a solvent.

Abstract: Disclosed is an electrolyte for a rechargeable lithium battery that includes a lithium salt, a phosphine compound having at least one trialkylsilyl group and organic solvent, and a rechargeable lithium battery including the electrolyte. The phosphine compound may be tris(trialkylsilyl)phosphine wherein the alkyl groups are the same or different and are each independently selected from C1 to C6 alkyl.

Abstract: There is provided a non-aqueous electrolytic solution assuring good solubility of an electrolyte salt and having enough cell characteristics (charge and discharge cycle characteristic, discharge capacity, and the like), and the non-aqueous electrolytic solution comprises a solvent for dissolving an electrolyte salt comprising (A) at least one fluorine-containing solvent selected from the group consisting of fluorine-containing ethers and fluorine-containing carbonates, (B) a non-fluorine-containing cyclic carbonate and (C) a chain ester represented by the formula (C): R1COOR2, wherein R1 is an alkyl group having 2 to 4 carbon atoms; R2 is an alkyl group having 1 to 4 carbon atoms or a fluorine-containing alkyl group having 1 to 4 carbon atoms, and (II) an electrolyte salt.

Abstract: A lithium secondary battery is intended to suppress deterioration upon storage at high temperature of 50° C. or higher without deteriorating the output characteristics at a room temperature. The battery includes a positive electrode capable of occluding and releasing lithium ions, a negative electrode capable of occluding and releasing lithium ions, a separator disposed between the positive electrode and the negative electrode, and an electrolyte. The electrolyte contains a compound having a double bond in the molecule and a compound having a plurality of polymerizable functional groups in the molecule, and the electrolyte contains a compound represented by formula (4): (in which Z1 and Z2 each represent any one of an allyl group, a methallyl group, a vinyl group, an acryl group, and a methacryl group).

Abstract: The present invention provides (1) a sulfone compounds having a propargyl group, (2) a nonaqueous electrolytic solution for lithium secondary batteries, which comprises an electrolyte salt dissolved in a nonaqueous solvent and contains a sulfone compound having a specific structure that has an SO2 group with a propargyl group or a vinyl group bonding thereto, in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution, and which can prevent gas generation and is excellent in battery characteristics such as cycle property and the like, and (3) a lithium secondary battery comprising a positive electrode, a negative electrode and a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, wherein the nonaqueous electrolytic solution contains a sulfone compound having a specific structure, in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution.