Organic Heavy Metal, Aluminum, Or Silicon Compound Adjuvant Patents (Class 430/108.3)
  • Patent number: 8298741
    Abstract: An image forming apparatus includes plural developing units separately containing a toner A and a toner B that satisfy relationships (1) and (2) and have similar colors. The toner A and the toner B each contain a binder resin containing a polyester about 90 mass % or more of the binder resin, and about 90 mass % of the binder resin of the toner A and about 90 mass % of the binder resin of the toner B are the same resin. The polyester contains an amorphous polyester having an alkyl side chain and a crystalline polyester. The relationship (1) is Ta (toner A)>Tb (toner B) in terms of flow tester ½ effluent temperature. The relationship (2) is Aa (toner A)>Ab (toner B) in terms of an amount of an aluminum (with reference to net intensity) measured with fluorescent X-ray.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: October 30, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Satoshi Yoshida, Eisuke Iwazaki, Shintaro Anno
  • Patent number: 8298736
    Abstract: Provided is a toner comprising toner particles containing a binder resin and coloring matters, wherein the coloring matters comprise a dye represented by Formula (X-1), a metal compound represented by Formula (1) and a quinacridone pigment represented by Formula (2):
    Type: Grant
    Filed: May 15, 2009
    Date of Patent: October 30, 2012
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Naohiro Hirose, Hiroyuki Yasukawa, Natsuko Kusaka, Miyuki Murakami, Yohei Ohno
  • Patent number: 8293442
    Abstract: Disclosed is a resin particle having a volume average particle diameter of 10 nm to 500 nm, obtained by polymerizing an addition polymerizable monomer containing a silsesquioxane (a) represented by Formula (I) or by copolymerizing the silsesquioxane (a) with an addition polymerizable monomer (b), where R1 to R7 each independently represent a group selected from the group consisting of hydrogen, alkyl having 1 to 40 carbon atoms, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl; any hydrogen in the alkyl group is optionally substituted by fluorine and any —CH2— is optionally substituted by —O—, —CH?CH—, cycloalkylene or cycloalkenylene; any hydrogen in alkylene in the arylalkyl group is optionally substituted by fluorine and any —CH2— is optionally substituted by —O— or —CH?CH—; and A1 represents an addition polymerizable functional group.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: October 23, 2012
    Assignees: Ricoh Company, Ltd., JNC Corporation
    Inventors: Masaki Watanabe, Naohito Shimota, Hiroshi Yamashita, Naohiro Watanabe, Tsuneyasu Nagatomo, Tsuyoshi Sugimoto, Shinichi Wakamatsu, Kenya Itoh, Mikio Yamahiro
  • Publication number: 20120233929
    Abstract: Presently described are methods of inhibiting water vapor adsorption of a powder and methods of storing a powder at increased humidity level. The methods comprise providing adding discrete hydrophobic nanoparticles to a plurality of particles.
    Type: Application
    Filed: November 29, 2010
    Publication date: September 20, 2012
    Inventors: Jimmie R. Baran, JR., Roxanne A. Boehmer
  • Patent number: 8252493
    Abstract: Single component toners are provided with at least one surface additive including a large polymeric spacer, and processes for producing the same. In embodiments, the toner is a non-magnetic single component toner produced by emulsion aggregation methods. The large polymeric spacer additives provide excellent flow characteristics to the resulting toners, and reduce the incidence of clogging failure and print defects such as ghosting, white bands, and low toner density compared with conventionally produced toners.
    Type: Grant
    Filed: October 15, 2008
    Date of Patent: August 28, 2012
    Assignee: Xerox Corporation
    Inventors: Samir Kumar, Grazyna L. Kmiecik-Lawrynowicz, Maura A. Sweeney, Michael L. Grande, Julie C. Pickering, Timothy L. Lincoln
  • Patent number: 8227162
    Abstract: To provide a toner excellent in low-temperature fixability, releasing performance, and development stability in long-term use under a high-temperature and high-humidity environment, provided is a magnetic toner including: magnetic toner particles each containing at least a binder resin and a magnetic particles; and an inorganic fine powder, in which: the magnetic particles is a treated magnetic particles treated with a silane compound; the treated magnetic particles has a water adsorption per unit area based on a BET specific surface area of 0.300 mg/m2 or less; portion of styrene extractables constitutes 25 mass % or less among the silane compound in the treated magnetic particles; and the silane compound with which the treated magnetic particles is treated contains a compound having a hydrocarbon group having 2 or more and 4 or less carbon atoms as a main component.
    Type: Grant
    Filed: April 6, 2010
    Date of Patent: July 24, 2012
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tomohisa Sano, Michihisa Magome, Takashi Matsui, Akira Sakakibara, Shuichi Hiroko, Yoshitaka Suzumura, Shotaro Nomura
  • Patent number: 8227160
    Abstract: A toner for electrophotography comprising a charge control agent comprising a specified iron-azo complex or a specified metal compound of a benzilic acid derivative, a colorant, and a resin binder comprising a polyester, the polyester being a polyester obtained by polycondensing an alcohol component containing a propylene oxide adduct of bisphenol A and a carboxylic acid component, wherein the propylene oxide adduct of bisphenol A has an average mole of propylene oxide added of from 2.4 to 4.0, and wherein an adduct with 2 mol of propylene oxide is contained in an amount of 60% by mol or less, and an adduct with 4 mol of propylene oxide is contained in an amount of 10% by mol or more, of the propylene oxide adduct of bisphenol A, and wherein the propylene oxide adduct of bisphenol A has a content ratio of primary hydroxyl groups of 10% by mol or less of the entire hydroxyl groups.
    Type: Grant
    Filed: October 16, 2007
    Date of Patent: July 24, 2012
    Assignee: Kao Corporation
    Inventors: Yasuhiro Hidaka, Kouhei Katayama, Yasuki Ohtawa
  • Patent number: 8227161
    Abstract: An electrophotographic toner includes a latex, a coloring agent, a wax and 3 to 1,000 ppm of each of Si and Fe, wherein a mole ratio of Si to Fe is from 0.1 to 5.
    Type: Grant
    Filed: May 13, 2008
    Date of Patent: July 24, 2012
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Yoda Shin, Kyung-yol Yon, Tac-hoe Koo
  • Patent number: 8211605
    Abstract: There is provided a toner which contains at least a binder resin, and filler including a layered inorganic compound, wherein the layered inorganic compound is cleaved to form particles in the toner, and the particles have a breadth of 0.5 nm to 4 nm, and a length of 10 nm to 90 nm.
    Type: Grant
    Filed: March 18, 2008
    Date of Patent: July 3, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Yamada, Satoshi Mochizuki, Fumihiro Sasaki, Yasuo Asahina, Hisashi Nakajima
  • Patent number: 8202676
    Abstract: A toner for developing electrostatic latent images, including a binder resin; and a colorant, wherein the toner further includes propyleneglycolmonomethylether in an amount of from 30 to 200 ppm.
    Type: Grant
    Filed: January 5, 2009
    Date of Patent: June 19, 2012
    Assignee: Ricoh Company, Limited
    Inventor: Kumi Hasegawa
  • Publication number: 20120148948
    Abstract: An electrostatic image developing toner contains a binder resin and at least two different kinds of white pigments, wherein from about 10% by weight to about 30% by weight of the at least two kinds of white pigments is porous titanium oxide having a volume average particle diameter of from about 0.01 ?m to about 1 ?m, a particle size distribution (volume average particle size distribution index GSDv) of from 1.1 to 1.3 and a BET specific surface area of from about 250 m2/g to about 500 m2/g.
    Type: Application
    Filed: May 12, 2011
    Publication date: June 14, 2012
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Yusuke IKEDA, Yukiaki NAKAMURA, Kiyohiro YAMANAKA, Satoshi KAMIWAKI
  • Publication number: 20120129089
    Abstract: A toner composition with a novel surface additive package for developing images. The additive package includes sol-gel silica, a PDMS silica, an organic spacer such as PMMA and two HMDS silicas. The toner composition exhibits improved control of voltage, higher print density, lower toner amount remaining on the roll, lower toner usage, and reduced drum contamination. The toner composition also exhibits improved dry rheological properties and improved fix properties. These improved properties make this toner composition useful for higher speed printing while using less toner.
    Type: Application
    Filed: November 24, 2010
    Publication date: May 24, 2012
    Applicant: XEROX CORPORATION
    Inventors: Grazyna E. KMIECIK-LAWRYNOWICZ, Maura A. SWEENEY, Daniel W. ASARESE, Robert CORLETO, Samir KUMAR, Juan A. MORALES-TIRADO, Michael F. ZONA
  • Publication number: 20120129088
    Abstract: A toner composition with a novel surface additive package for developing images. The additive package includes sol-gel silica, a PDMS silica, an organic spacer such as PMMA and HMDS silica. The toner composition exhibits improved control of voltage, higher print density, lower toner amount remaining on the roll, lower toner usage, and reduced drum contamination. The toner composition also exhibits improved dry theological properties. These improved properties make this toner composition useful for higher speed printing while using less toner.
    Type: Application
    Filed: November 24, 2010
    Publication date: May 24, 2012
    Applicant: XEROX CORPORATION
    Inventors: Grazyna E. KMIECIK-LAWRYNOWICZ, Maura A. SWEENEY, Daniel W. ASARESE, Samir KUMAR, Juan A. MORALES-TIRADO, Michael F. ZONA
  • Patent number: 8168360
    Abstract: To a toner used in an image forming apparatus is added an external additive whose main components are oxide fine particles in which dimethylsilyl groups are introduced to surfaces thereof, and whose volatilizing amount of octamethylcyclotetrasiloxane in a first volatilizing test is 0.2 ?g or less. Consequently, it is possible to prevent foreign matters from attaching to a discharging electrode included in the image forming apparatus. The first volatilizing test is performed in such a manner that 2 g of the external additive is put in a sealing container and the inside of the sealing container is kept at 120° C. for 10 minutes so that octamethylcyclotetrasiloxane volatilizes from the external additive.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: May 1, 2012
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Toshiaki Ino, Shinya Mimura, Yasuhiro Nishimura
  • Patent number: 8163450
    Abstract: A toner including toner particles; and external additives including a fatty acid metal salt having an average primary particle diameter of from 0.5 to 1.5 ?m; a positively chargeable particulate inorganic material; and a negatively chargeable particulate inorganic material. An image forming apparatus including a photoreceptor bearing an electrostatic image, and a center feed developing device configured to develop the electrostatic image with a developer including the toner to form a toner image, and a transfer device configured to transfer the toner image onto a receiving material preferably fed at a speed of from 500 to 1700 mm/s. An image forming method including forming an electrostatic image, developing the electrostatic image with the center feed developing device using the toner to form a toner image, and transferring the toner image onto a receiving material preferably fed at a speed of from 500 to 1700 mm/s.
    Type: Grant
    Filed: February 9, 2009
    Date of Patent: April 24, 2012
    Assignee: Ricoh Company Limited
    Inventor: Hiroyuki Kishida
  • Patent number: 8142970
    Abstract: A toner having a core with a first latex having a specific glass transition temperature, and further having a shell surrounding the core with a second latex having a specific glass transition temperature and possessing functional groups, and processes for producing the same.
    Type: Grant
    Filed: August 24, 2010
    Date of Patent: March 27, 2012
    Assignee: Xerox Corporation
    Inventors: Zhen Lai, Yuhua Tong, Chieh-Min Cheng, Peter V. Nguyen, Jon T. Owens
  • Publication number: 20120070773
    Abstract: The present invention provides a toner for developing an electrostatic charge image including toner particles having residual ammonium ions and silica particles containing a chlorine compound as an external additive.
    Type: Application
    Filed: February 9, 2011
    Publication date: March 22, 2012
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Hiroko KOBAYASHI, Yasuhiro ARIMA
  • Publication number: 20120070771
    Abstract: Disclosed is an electrophotographic toner, comprising: toner base particles having a volume average particle diameter of 3 ?m or more and 7 ?m or less; OTES-treated silica particles which are treated with octyltriethoxysilane (OTES) and are externally added to the toner base particles; and silica-coated titanium oxide particles which are coated with silica and are externally added to the toner base particles along with the OTES-treated silica particles, wherein the ratio (A) of the amount of the OTES-treated silica particles to the amount of the toner base particles, the ratio (B) of the amount of the silica-coated titanium oxide particles to the amount of the toner base particles, and the ratio (C) of the amount of particles to be externally added to the toner base particles to the amount of the toner base particles satisfy the following relations: 1% by mass?(A)?6.9% by mass; 0.1% by mass?(B)?2% by mass; 3% by mass?(C)?7% by mass; and 0.15?(A)/(C)<1.
    Type: Application
    Filed: August 31, 2011
    Publication date: March 22, 2012
    Applicant: TOSHIBA TEC KABUSHIKI KAISHA
    Inventors: Satoshi Araki, Junichi Ishikawa
  • Patent number: 8114560
    Abstract: The present invention provides a toner containing at least a binder resin, a releasing agent, and a colorant, wherein the binder resin contains at least a polyester resin (A) having a softening point Tm (A) of 120° C. to 160° C., a polyester resin (B) having a softening point Tm (B) of 80° C. or more and less than 120° C. and a composite resin (C) containing a condensation polymerization monomer and an addition polymerization monomer, at least any one of the polyester resins (A) and (B) is a polyester resin prepared by condensation-polymerizing an alcohol component substantially composed of only aliphatic alcohol with a carboxylic acid component, and 65% or more of the alcohol component is 1,2-propanediol.
    Type: Grant
    Filed: May 9, 2008
    Date of Patent: February 14, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinya Nakayama, Akihiro Kotsugai, Akiyoshi Sabu, Hiroshi Yamashita, Hiroshi Yamada, Junichi Awamura, Tsuyoshi Sugimoto
  • Patent number: 8107863
    Abstract: A developing device and an image forming apparatus which can form a printing image having high resolution and a high quality level, while resolving various problems resulted from the use of small particle size toner particles are provided. The developing device includes a toner constituted of resin base particles containing a coloring agent and a binder resin, and silicone oil and/or fluoro oil added to the resin base particles, a toner receiving portion for receiving the toner, and a developing roller having an outer peripheral surface and an irregularity section for carrying the toner, the irregularity section formed on the outer peripheral surface and including a plurality of depression portions and/or protrusion portions provided regularly and uniformly, wherein an average particle size of the resin base particles in volume basis is in the range of 2 to 4 ?m, and an added amount of the silicone oil and/or fluoro oil to the resin base particles is in the range of 0.05 to 2 mass %.
    Type: Grant
    Filed: February 29, 2008
    Date of Patent: January 31, 2012
    Assignee: Seiko Epson Corporation
    Inventors: Soichi Yamazaki, Ken Ikuma
  • Patent number: 8105743
    Abstract: The present invention provides an organic silicone fine particle for latent electrostatic image developing toners, wherein the organic silicone fine particle has a volume average particle diameter of 0.05 ?m to 6.0 ?m which is obtained by measurement based on Coulter principle, and has a hemispherical polysiloxane cross-linked structure. By mixing an appropriate amount of an organic silicone resin particle formed in a deformed shape (a hemispherical shape) in a toner or developer, the present invention prevents movement of the organic silicone resin particle from surface functional sites, the movement caused by a phenomenon such as detachment thereof from a toner surface or rolling movement on the toner surface, by the effect of its shape, and makes it possible to effectively achieve the expected function.
    Type: Grant
    Filed: March 12, 2008
    Date of Patent: January 31, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Masayuki Ishii, Ryota Inoue, Yoshihiro Moriya, Shingo Sakashita
  • Patent number: 8088933
    Abstract: Discussed herein are a charge control agent and toner comprising said charge control agent. Said toner of the invention is comprised of a resin, a colorant, and the charge control agent, wherein, said charge control agent is comprised of a specific type of metal complexes. In the invention, the charge control agent has excellent charge control properties and the characteristics of uniform crystalline size, high charge speed, high thermo stability, low moisture absorption, and good compatibility with resin. The toner of the invention has excellent electrical characteristics and produces stable image of high quality under a wide range of environmental conditions without dusting and fogging.
    Type: Grant
    Filed: January 10, 2008
    Date of Patent: January 3, 2012
    Assignee: Hubei Dinglong Chemical Co., Ltd.
    Inventors: Xiaorong Qin, Lin Wu, Zeguan Lan
  • Patent number: 8084177
    Abstract: Disclosed is a toner composition comprising toner particles which comprise a resin, an optional colorant, and a polyhedral oligomeric silsesquioxane compound.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: December 27, 2011
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Karen A. Moffat, Maria N V. McDougall, Richard P N. Veregin, Edward G. Zwartz
  • Patent number: 8039186
    Abstract: A toner for developing an electrostatic image comprises: a binder resin; and a releasing agent, wherein the binder resin comprises a polycondensation resin obtained by polycondensing a polycondensation monomer in the presence of a polycondensation catalyst, the releasing agent comprises a condensation compound obtained by condensing a condensation monomer in the presence of a condensation catalyst, the toner contains a metallic element derived from the polycondensation catalyst and the condensation catalyst in an amount of from 0 to 10 ppm, and the toner contains a sulfur component in an amount of from 100 to 20,000 ppm.
    Type: Grant
    Filed: August 18, 2006
    Date of Patent: October 18, 2011
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yuki Sasaki, Fumiaki Mera, Satoshi Hiraoka, Hirotaka Matsuoka, Yasuo Matsumura
  • Patent number: 8029959
    Abstract: Taught herein is a charge control agent comprising a specific type of gallic acid metal complex represented by the following Chemical Formula (1) or Chemical Formula (2): In the formula (1), R1 represents an alkyl group containing 1-12 carbon atoms, an alkenyl group containing 1-12 carbon atoms, a substituted or unsubstituted aryl group containing 6-12 carbon atoms, or a hydrogen atom; R2 and R4 can independently represent an alkyl group containing 1-12 carbon atoms, an alkenyl group containing 2-12 carbon atoms, an alkoxy group containing 1-12 carbon atoms, a substituted or unsubstituted aryl group containing 6-12 carbon atoms, a halogen atom, or a hydrogen atom; R3 represents an alkyl group containing 1-12 carbon atoms, a substituted or unsubstituted aryl group containing 6-12 carbon atoms, a potassium atom, a sodium atom or a hydrogen atom. M represents a divalent to tetravalent metal atom, A is a counterion, m is a number from 1 to 3, and n is 1 or 2.
    Type: Grant
    Filed: May 23, 2007
    Date of Patent: October 4, 2011
    Assignee: Hubei Dinglong Chemical Co., Ltd.
    Inventors: Lin Wu, Zhilin Xia, Shuangquan Zhu
  • Patent number: 8026031
    Abstract: Toner and a developer which are excellent in cleaning property and fixing property at low temperature, and capable of forming images with high quality are provided. A toner prepared by dispersing and/or emulsifying an oil phase or a monomer phase comprising a toner composition and/or a toner composition precursor in a water-based medium to granulate, wherein the toner has an average circularity of 0.925 to 0.970, and the toner composition and/or the toner composition precursor has a layered inorganic material in which at least a part of interlayer ions in the layered inorganic material has been exchanged with organic ions.
    Type: Grant
    Filed: March 5, 2007
    Date of Patent: September 27, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Naohiro Watanabe, Shigeru Emoto, Yohichiroh Watanabe, Masahide Yamada, Tsunemi Sugiyama, Masahiro Ohki, Akinori Saitoh, Ryota Inoue, Osamu Uchinokura, Junichi Awamura
  • Publication number: 20110229814
    Abstract: A toner containing a mother toner particle containing a binder resin, a releasing agent, and a coloring agent and an external additive comprising an inorganic particulate, which is mixed with the mother toner particle in a mixing process by a mixer, wherein the external additive is isolated from the mother toner particle by ultrasonic vibration and collected, in an aqueous solution comprising a polyoxyethylene lauryl ether compound serving as a surface active agent, in an amount of from 0.1 ppm to 10 ppm/(toner 4 g/100 ml) as measured by atomic absorption spectrometry.
    Type: Application
    Filed: March 11, 2011
    Publication date: September 22, 2011
    Inventors: Masayuki KAKIMOTO, Akio MATSUI, Yoshikatsu MATSUDA, Masanori RIMOTO
  • Publication number: 20110229815
    Abstract: A light fixable toner which is not containing an infrared absorbent and fixed by light irradiation, and a two-component developer containing the light fixable toner are provided. The light fixable toner contains a binder resin, a colorant and an internal additive having an average particle size of 0.50 ?m or more and 1.40 ?m or less, and a shape factor SF-2 is 105 or more and 120 or less, a relative refractive index nb/na which is a ratio of an absolute refractive index nb of the internal additive to an absolute refractive index na of the binder resin is 0.90 or more and 0.97 or less.
    Type: Application
    Filed: March 15, 2011
    Publication date: September 22, 2011
    Inventor: Masahiko KUBO
  • Patent number: 8007974
    Abstract: A toner that is excellent in low-temperature fixing property, offset resistance, storage stability, charge rising property, charge stability with time and pulverizability and allows for forming high-quality images over a long period of time. The toner contains at least a binder resin, a colorant and a charge controlling agent, wherein the charge controlling agent contains an aromatic oxycarboxylic acid metal compound having a trivalent or more central metal, the binder resin comprises a polyester resin (A) having a softening point Tm (A) of 120° C. to 160° C. and a polyester resin (B) having a softening point Tm (B) of 80° C. to less than 120° C., and at least any one of the polyester resins (A) and (B) contains 1,2-propane diol at 65 mol % or more in a divalent alcohol component and can be obtained by condensation polymerizing an alcohol component substantially composed of only an aliphatic alcohol with a carboxylic acid component.
    Type: Grant
    Filed: November 21, 2007
    Date of Patent: August 30, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinya Nakayama, Akihiro Kotsugai, Yasuaki Iwamoto, Yasutada Shitara
  • Publication number: 20110177444
    Abstract: An additive package is provided for use with toners. The additive package may be utilized with ultra low melt toners formed by emulsion aggregation processes. The additive package of the present disclosure provides toners with a low minimum fusing temperature to enable high speed printing. Toners possessing the additive package of the present disclosure also possess wide fusing latitude, good release, high gloss, high blocking temperature, robust particles, excellent triboelectric charge properties, and the like.
    Type: Application
    Filed: January 19, 2010
    Publication date: July 21, 2011
    Applicant: XEROX CORPORATION
    Inventors: Dennis A. Mattison, JR., Chieh-Min Cheng, Zhen Lai, Christopher D. Blair, Zhaoyang Ou, Philip J. Dale
  • Publication number: 20110142893
    Abstract: Organosilicone fine particles of size in the range of 0.1-20 ?m, each having 20 or more faces with indefinite shapes and a network of convex parts that surround these faces with indefinite shapes on its surface, and being spherical as a whole respond to highly advanced requirements of recent years including improvements in optical characteristics of resin compounds, usability and feeling of cosmetics and maintainability of fluidity of development toners. The invention further provides methods of producing such organosilicone fine particles.
    Type: Application
    Filed: September 17, 2010
    Publication date: June 16, 2011
    Inventors: Fumiyoshi Ishikawa, Mamoru Yasui, Chiaki Saito
  • Publication number: 20110136056
    Abstract: The present disclosure relates to a toner including a core comprising at least one amorphous resin, at least one crystalline resin and one or more optional ingredients such as optional colorants, optional waxes, gels, and combinations thereof. The toner also includes a shell having an environmentally friendly charge control agent co-emulsified with at least one amorphous shell resin.
    Type: Application
    Filed: December 9, 2009
    Publication date: June 9, 2011
    Applicant: Xerox Corporation
    Inventors: Ke Zhou, Karen Ann Moffat, Richard P.N. Veregin, Cuong Vong
  • Publication number: 20110129774
    Abstract: A process for making a resin emulsion suitable for use in forming toner particles including an oil component incorporated into the latex core of the toner particles.
    Type: Application
    Filed: December 2, 2009
    Publication date: June 2, 2011
    Applicant: XEROX CORPORATION
    Inventors: Valerie M. Farrugia, Kimberly D. Nosella, Edward Graham Zwartz, Barkev Keoshkerian
  • Publication number: 20110117486
    Abstract: The present disclosure provides polyesters suitable for use in forming toners. In embodiments, a polyester may be subjected to phase inversion emulsification, in which charge control agents are added so that the polyester emulsion includes charge control agents therein. The resulting polyester emulsion with charge control agents may then be utilized to form toner particles.
    Type: Application
    Filed: November 16, 2009
    Publication date: May 19, 2011
    Applicant: XEROX CORPORATION
    Inventors: Robert D. Bayley, Yuhua Tong, Timothy L. Lincoln, Grazyna Kmiecik-Lawrynowicz, Maura A. Sweeney
  • Patent number: 7943279
    Abstract: A copper complex compound represented by Formula (1) is disclosed. in the formula, groups represented by R is a substituent, n is an integer of from 1 to 5 and the total carbon number contained in (R) n is 14 or more. A toner for electrophotography containing the compound is also disclosed.
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: May 17, 2011
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Koji Daifuku, Ryohei Iwamoto, Keiko Ishidai, Kimihiko Ookubo, Kaori Ono, Issei Nakahara
  • Patent number: 7943280
    Abstract: A toner containing a colorant, a binder resin and a laminar inorganic mineral in which part or all of the ions present between layers are modified by organic ions. The toner can be prepared by a method including dispersing or emulsifying a toner constituent mixture liquid containing the colorant, the binder resin and/or a precursor thereof, and the laminar inorganic mineral, in an aqueous medium. The density of the laminar inorganic mineral measured by XPS for the toner surface before (A) and after (B) mixing and kneading satisfies the following relationship: A>B.
    Type: Grant
    Filed: March 14, 2007
    Date of Patent: May 17, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Osamu Uchinokura, Naohiro Watanabe, Junichi Awamura
  • Patent number: 7939237
    Abstract: A method for making toners to include clay composites. The clay composites are incorporated into emulsion of toner and used in making toner via emulsion aggregation. Such toners may have a core and/or a shell and the clay composites may be included with the core, the shell or both.
    Type: Grant
    Filed: August 17, 2007
    Date of Patent: May 10, 2011
    Assignee: Xerox Corporation
    Inventors: Maria N. V. McDougall, Richard P. N. Veregin, Guerino G. Sacripante, Valerie M. Farrugia
  • Publication number: 20110091802
    Abstract: The carrier is used for a two-component developer for developing an electrostatic latent image, and includes a particulate magnetic core material; and a cover layer located on a surface of the core material and including a crosslinked material and barium sulfate. The cover layer is formed by applying a coating medium including barium sulfate, a copolymer including a unit (A) having a specific acrylic siloxane structure including a tris(trialkylsiloxy)silanyl group and a unit (B) having a specific acrylic silicone structure having a crosslinking ability, and a condensation reaction catalyst, heating the applied medium to a temperature of from 100° C. to 230° C. so that the copolymer is hydrolyzed to produce a material having a silanol group, and the material and the catalyst are subjected to a condensation reaction to form the crosslinked material.
    Type: Application
    Filed: October 4, 2010
    Publication date: April 21, 2011
    Inventors: Yutaka TAKAHASHI, Minoru Masuda, Kimitoshi Yamaguchi, Hisashi Nakajima, Koichi Sakata, Hitoshi Iwatsuki, Saori Yamada, Toyoaki Tano, Mariko Takii
  • Publication number: 20110086306
    Abstract: A toner having charge control agents which impart excellent triboelectric charging characteristics. In embodiments, the charge control agents include copolymers formed by an emulsion polymerization process.
    Type: Application
    Filed: October 8, 2009
    Publication date: April 14, 2011
    Applicant: XEROX CORPORATION
    Inventors: Robert D. Bayley, Yuhua Tong, Timothy L. Lincoln, Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Daniel W. Asarese, Susan J. LaFica, Mark E. Mang
  • Patent number: 7923189
    Abstract: The invention relates to hydrophobic salts of layer-like metal hydroxides, which are obtainable by adding to a layer-like metal hydroxide salt, which contains trivalent, divalent and optionally monovalent metal cations and one or more organic anions A of the formula (1) X—R—Y??(1), wherein X denotes hydrogen, hydroxyl, carboxyl, sulfato or sulfo; Y denotes carboxyl, sulfato or sulfo, and R denotes an aliphatic, cycloaliphatic, heterocycloaliphatic, olefinic, cycloolefinic, heterocycloolefinic, aromatic, heteroaromatic, araliphatic or heteroaraliphatic radical having 2 to 50 C atoms, wherein one or more substituents from the group consisting of hydroxyl, amino, halogen, C1-C22-alkyl, C1-C22-alkoxy, C1-C22-alkylene-(CO)—O—(CH2CH2O)0-50-alkyl, C1-C22-alkylene-(CO)—O—(CH2CH2O)0-50-haloalkyl, carboxyl, sulfo, nitro or cyano can be present, in dispersion, with intensive thorough mixing, one or more hydrophobic compounds from the group consisting of waxes and metal soaps in an amount of from 0.2 to 200 wt.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: April 12, 2011
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventor: Eduard Michel
  • Publication number: 20110070535
    Abstract: A toner for electrostatic latent image development is disclosed comprising colored particles containing a binder resin and a colorant and external-additive particles attached to the surfaces of the colored particles, wherein the external-additive particles comprise resin particles covered with an inorganic layer, and the resin particles are bound to the inorganic layer by a siloxane bond. A preparation method of the toner is also disclosed.
    Type: Application
    Filed: September 16, 2010
    Publication date: March 24, 2011
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Yukio HOSOYA, Mikio KOUYAMA, Kenji HAYASHI, Hiroaki OBATA, Koji SHIBATA
  • Publication number: 20110065037
    Abstract: A latent electrostatic image developing carrier including a carrier core material, and a coating layer containing a resin and provided on a surface of the carrier core material, wherein the coating layer includes a particulate material containing at least first fine conductive particles and second fine conductive particles, and wherein the first fine conductive particles and the second fine conductive particles satisfy the relationships expressed by Expressions 1 and 2, 3?D1/D2?15 . . . Expression 1, where D1 denotes a dispersed particle diameter of the first fine conductive particles and D2 denotes a dispersed particle diameter of the second fine conductive particles, and ?7E?R1×R2?8E . . . Expression 2, where R1 denotes a powder specific resistance of the first fine conductive particles and R2 denotes a powder specific resistance of the second fine conductive particles.
    Type: Application
    Filed: September 10, 2010
    Publication date: March 17, 2011
    Inventors: Hitoshi Iwatsuki, Kimitoshi Yamaguchi, Minoru Masuda, Yutaka Takahashi, Koichi Sakata, Toyoaki Tano
  • Publication number: 20110052882
    Abstract: The present disclosure provides white toner compositions and processes for making same. In embodiments, a desirable white toner may be produced without having to resort to excessive pigment loading, having desirable gloss characteristics.
    Type: Application
    Filed: August 25, 2009
    Publication date: March 3, 2011
    Applicant: XEROX CORPORATION
    Inventors: Yi Xin Gong, Daryl W. Vanbesien, Shigang Qiu, Edward Graham Zwartz, Karen Ann Moffat, Richard P.N. Veregin, Cuong Vong, C. Geoffrey Allen
  • Publication number: 20110053073
    Abstract: A toner is provided which is excellent in development stability in both a low-temperature, low-humidity environment and a high-temperature, high-humidity environment over a long time period. The toner includes toner particles containing at least a binder resin and a colorant, and a fatty acid metal salt. The fatty acid metal salt has a volume-based median diameter (D50s) of 0.15 ?m or more and 0.65 ?m or less, and the liberation ratio of the fatty acid metal salt in the toner is 1.0% or more and 25.0% or less.
    Type: Application
    Filed: February 24, 2009
    Publication date: March 3, 2011
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Naoya Isono, Satoshi Handa, Katsuyuki Nonaka, Koji Abe, Yasuhiro Hashimoto, Akira Sugiyama, Yuhei Terui
  • Publication number: 20110045396
    Abstract: The present invention discloses a charge control agent which comprises a metal compound of a cyclic phenol sulfide of the following formula (1) as an active ingredient: wherein at least one of several Y is a metal atom. The present invention also discloses a toner which comprises one or more kinds of said metal compound, a coloring agent and a binder resin. The charge control agent of the present invention overcomes disadvantages such as lack of sharpness of first copied images and instability of the quality of the copied images in continuously copying, and it is those applicable to recent high speed printers, which have a quick charging rise time, an excellent environmental stability since the charge amount thereof less varies depending on the changes of temperature and humidity, and a high frictional charge amount. In addition, by using said charge control agent, a toner having a negative electric with high charging performance can be provided.
    Type: Application
    Filed: May 8, 2009
    Publication date: February 24, 2011
    Inventors: Masateru Yasumura, Masami Ito, Yoshikazu Aoki, Masaki Okubo, Hideyuki Otsuka, Jun Watanabe
  • Patent number: 7892714
    Abstract: A toner comprising toner particles, a polymer binder, at least one colorant and clay composites distributed in the polymer binder, wherein the clay composites comprise a polymer modified clay.
    Type: Grant
    Filed: August 17, 2007
    Date of Patent: February 22, 2011
    Assignee: Xerox Corporation
    Inventors: Maria N. V. McDougall, Richard P. N. Veregin, Guerino G. Sacripante, Valerie M. Farrugia
  • Publication number: 20110027714
    Abstract: Toner particles are provided which may, in embodiments, include an additive package possessing both a silica that has been treated with polydimethyl siloxane and a titanium dioxide that has been subjected to a fluorine treatment. The silica that has been treated with polydimethyl siloxane has low levels of free polydimethyl siloxane. The combined additives provide toners with excellent charging characteristics and good blocking performance.
    Type: Application
    Filed: July 29, 2009
    Publication date: February 3, 2011
    Applicant: XEROX CORPORATION
    Inventors: Maria N.V. McDougall, Richard P.N. Veregin, Wafa Bashir, Michael S. Hawkins, Eric Rotberg, Sonja Hadzidedic
  • Publication number: 20110020745
    Abstract: The present invention relates to, in the toner including toner particles having a biding agent resin, colorings and a release agent, an electrostatic image developing toner, its composition, and a preparation method thereof. The electrostatic image developing toner is prepared by the method comprising: (1) preparing an inorganic dispersion medium; (2) dispersing/dissolving a polymerizable monomer mixture; (3) micronizing the liquid obtained in step (2) in the liquid obtained in step (1) with high shear force in order to create droplets; (4) performing radical polymerization of the micronized droplets obtained in step (3); (5) aggregating particles obtained in step (4); (6) fusing the aggregate obtained in step (5); (7) cleaning and drying the toner obtained by step (6); and (8) adding additives to impart electrification and fluidity to a toner obtained by step (7).
    Type: Application
    Filed: March 12, 2009
    Publication date: January 27, 2011
    Inventors: Jae-Goang Yu, Ho-Geun Jo
  • Patent number: 7875412
    Abstract: A positive electrified charge control agent comprising a silicon complex compound of an effective component represented by the following chemical formula (I) and/or chemical formula (II) (in the formula (I) and formula (II), [D-(SO3)2]2? is a bivalent anion of an organic acid having at least two sulfonic acid groups, p is 0 or 1, B is a bonding line when p is 0, B is a carbon atom or a nitrogen atom when p is 1, J is a carbon atom or a nitrogen atom, A is an organic group which forms a ring with (B)p and J, both of R are same or different to each other and are an organic group, and these both of R are independent or form a heterocyclic ring). A positive electrified toner for developing an electrostatic image comprises the positive electrified charge control agent. A charge control method of the positive electrified toner for developing the electrostatic image comprises a step for making the toner positively electrified by friction.
    Type: Grant
    Filed: April 2, 2007
    Date of Patent: January 25, 2011
    Assignee: Orient Chemical Industries, Ltd.
    Inventors: Osamu Yamate, Masashi Yasumatsu
  • Publication number: 20100330482
    Abstract: A toner for electrostatic charge image development includes toner particles and fatty acid metal salt particles. The content of the fatty acid metal salt particles is from 0.2 parts by weight to 5 parts by weight with respect to 100 parts by weight of the toner particles; the weight of fatty acid metal salt particles remaining on a sieve having an opening of 25 ?m when the toner is sieved with the sieve having an opening of 25 ?m is from 0.015% by weight to 0.300% by weight with respect to the total weight of the toner; and the weight of fatty acid metal salt particles remaining on a sieve having an opening of 45 ?m when the toner is sieved with the sieve having an opening of 45 ?m is 0.030% by weight or less with respect to the total weight of the toner.
    Type: Application
    Filed: December 9, 2009
    Publication date: December 30, 2010
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Masahiro OKITA, Yutaka SAITO, Yasuaki HASHIMOTO