Organic Heavy Metal, Aluminum, Or Silicon Compound Adjuvant Patents (Class 430/108.3)
  • Patent number: 7153353
    Abstract: A carnuba silicone wax which does not contain free silicone oil. This wax is obtained by reacting a silicone compound having a substituent with reactivity to the hydroxyl group in natural carnuba wax, with this hydroxyl group. A carboxyl group may be introduced into the molecule by reacting this hydroxyl group with a cyclic acid anhydride, and a silicone compound having a group which can react directly with this carboxyl group is made to react. Alternatively, a hydrogen silicone may be hydrosilylated by a double bond introduced by reacting an epoxy compound having a double bond with this carboxyl group.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: December 26, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Shoji Ichinohe
  • Patent number: 7150953
    Abstract: A developer capable of providing an excellent image without causing a charging failure even after a long-term and repeated use contains a toner particle having a binder resin and a colorant, an inorganic fine particle, and a conductive fine particle, in which a volume average particle diameter Da of the conductive fine particle and an number average primary particle diameter Db of the inorganic fine particle satisfy the expression (1) below, and a rate of liberation “a” of the conductive fine particle from the toner particle is 40 to 95% and a rate of liberation “b” of the inorganic fine particle from the toner particle is 0.1 to 5% Da?10Db.
    Type: Grant
    Filed: September 12, 2003
    Date of Patent: December 19, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Katsuhisa Yamazaki, Takashige Kasuya, Tsuyoshi Takiguchi, Kaori Hiratsuka
  • Patent number: 7150954
    Abstract: An image forming method, comprising passing a toner image-bearing sheet through a nip defined between two rollers including a heater roller to fix the toner image on the sheet, wherein the toner image is formed from a toner comprising a binder resin, and a colorant, wherein the toner image before the passage through the nip has a toner volume V1 and a toner image area S1, wherein the toner image after the passage through the nip has a toner volume V2 and a toner image area S2, and wherein a volume change Vt and an area change St defined by the formulas shown below are 30% or less and 20% or less, respectively: Vt(%)=(V1?V2)/V1×100 St(%)=(S2?S1)/S1×100. Alternatively, the toner image before the passage through the nip has a surface roughness of 2.5 ?m or less.
    Type: Grant
    Filed: December 3, 2004
    Date of Patent: December 19, 2006
    Assignee: Ricoh Company, Ltd.
    Inventors: Mitsuo Aoki, Kumi Hasegawa, Toshiaki Higaya, Yasushi Koichi, Yutaka Takahashi, Tadashi Kasai
  • Patent number: 7144628
    Abstract: Spherical silica-titania-based fine particles surface-treated with silane are provided. The fine particles have a titanium atom content of 0.001 to 5% by weight, a frictional electrification with iron powder of ?100 to ?300 ?C/g, a bulk density of 0.2 to 0.4 g/ml, and a particle diameter of 0.01 to 5 ?m. The particles are useful as a material for an external additive for an electrostatically charged image developing toner. The toner is unlikely to cause degeneration or scratching of organic photoreceptors, displays excellent dispersibility and favorable flowability and consequently does not cause adhesion to the photoreceptor.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: December 5, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Muneo Kudo, Masaaki Yamaya
  • Patent number: 7142804
    Abstract: A toner is used in an image-forming apparatus that incorporates a toner-collecting member. The toner-collecting member collects residual toner on a surface of an image-bearing body. The toner includes a spherical toner having at least a binder resin, and an irregularly-shaped particles mixed with the spherical toner. The irregularly shaped particle has an average diameter in the range of 1–50 ?m. The average diameter is 14 to 10% of the diameter of a spot printed by the image-forming apparatus. The irregularly shaped particle is a toner having the same color as the spherical toner. The irregularly shaped particle is a colorless toner. The irregularly shaped particle is charged opposite in polarity to the spherical toner. The irregularly has a roundness of 0.85 or less.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: November 28, 2006
    Assignee: Oki Data Corporation
    Inventors: Takuya Goto, Hiroaki Sato, Katsuyuki Ito
  • Patent number: 7141185
    Abstract: Conductive ink compositions which can be cured to highly conductive metal traces by means of “chemical welding” include additives which reduce the curing temperatures for use with low-temperature substrates. Conductive ink compositions can be deposited on a substrate coated with a cure temperature reducing agent to reduce the curing temperatures.
    Type: Grant
    Filed: January 29, 2003
    Date of Patent: November 28, 2006
    Assignee: Parelec, Inc.
    Inventors: Brian F. Conaghan, Paul H. Kydd, David L. Richard
  • Patent number: 7135263
    Abstract: In a toner having toner particles which have toner base particles having at least a colorant and a binder resin, and an inorganic fine powder; the inorganic fine powder has a primary-particle average particle diameter of from 30 nm to 300 nm, and has particles having at least one of a cubic particle shape, a cube-like particle shape, a rectangular particle shape and a rectangle-like particle shape and having perovskite type crystals; and the inorganic fine powder has particles and agglomerates both having particle diameters of 600 nm or more, in a content of 0% to 1% by number.
    Type: Grant
    Filed: September 8, 2004
    Date of Patent: November 14, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroaki Kawakami, Fumihiro Arahira, Masayuki Hama, Noriyoshi Umeda
  • Patent number: 7115349
    Abstract: Provided is toner which is excellent in developing property, transferring property, and fixing property, hardly affected by its surrounding, and has good endurance. The toner has a peak temperature of maximum endothermic peak in the range of 60 to 100° C. in an endothermic curve of differential scanning calorimetry (DSC) measurement; silica particles in the toner contain a titanium element; and the silica particles satisfy the following expressions. 0.7?(Ia1/Ib1)?2.0 0.7?(Ia2/Ib2)?2.0 where Ia1 represents a maximum intensity in the case of 2?=25.3 deg, Ib1 represents a mean intensity in the cases of 2?=25.3 deg+2.0 deg. and of 2?=25.3 deg.?2.0 deg., Ia2 represents a maximum intensity in the case of 2?=27.5 deg and Ib2 represents a mean intensity in the cases of 2?=27.5. deg+2.0 deg. and of 2?=27.5 deg.?2.0 deg.
    Type: Grant
    Filed: November 28, 2003
    Date of Patent: October 3, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Wakashi Iida, Kazuhiko Hayami, Takayuki Itakura, Yojiro Hotta
  • Patent number: 7097951
    Abstract: A toner of the present invention comprises at least a binder resin comprising as a main component a polyester resin, a wax, and a colorant, in which in case of measuring a wettability of the toner with respect to a mixed solvent of methanol and water in terms of an optical transimittance at an optical wavelength of 780 nm, a methanol concentration of the mixed solvent is in a range of 45 to 65% by volume when an optical transmittance is 80% and 10%, respectively; a melt index (MI) is of 0.1 to 10 g/10 min at a temperature of 125° C.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: August 29, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Syuhei Moribe, Hiroshi Yusa, Takashige Kasuya, Yoshihiro Ogawa
  • Patent number: 7083888
    Abstract: An external additive for electrostatically charged image developing toner is provided. The additive includes spherical hydrophobic fine silica particles having primary particles with a particle diameter of from 0.01 to 5 ?m and having been treated with a compound selected from the group consisting of a quaternary ammonium salt compound, a fluoroalkyl-group- or fluoroalkenyl-group- containing betaine compound and a silicone oil. The fine silica particles fulfill conditions (i) and (ii), as described in the disclosure. The external additive does not react or has no interaction with an organic photoreceptor and therefore change in quality does not occur or the photoreceptor is not scraped. Furthermore, it has a good flowability and therefore adhesion of a toner to the photoreceptor does not occur.
    Type: Grant
    Filed: September 6, 2001
    Date of Patent: August 1, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Muneo Kudo, Masaki Tanaka
  • Patent number: 7041420
    Abstract: A toner of the invention includes toner particles comprising a styrene acrylate binder and at least one colorant, and wherein the toner particles, in the absence of external additives, have a mean circularity of from about 0.94 to about 0.98 and a particle size distribution with a lower number ratio geometric standard deviation (GSD) of approximately 1.28 to approximately 1.31 and an upper volume GSD of approximately 1.24 to approximately 1.27. Also included is a set of toners for forming a color image, comprising a cyan toner, a magenta toner, a yellow toner and a black toner, wherein each of the cyan toner, the magenta toner, the yellow toner and the black toner, wherein each of about 70 to about 95% by weight, dry basis, of a styrene acrylate binder, about 5 to about 15% by weight, dry basis, of a wax dispersion, and at least one colorant.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: May 9, 2006
    Assignee: Xerox Corporation
    Inventors: Judith M. Vandewinckel, Vincenzo G. Marcello, Grazyna E. Kmiecik-Lawrynowicz, Tie Hwee Ng, Chieh-Min Cheng
  • Patent number: 7005223
    Abstract: A toner composition including toner particles including a binder resin; and a colorant, and a charge controlling agent which is at least located on a surface of the toner particles, wherein the toner composition has a spherical degree of from 0.96 to 0.99, and wherein the toner composition satisfies the relationship: 10?M/T?1,000 wherein M represents a quantity of an element on a surface of the toner particles in units of % by weight, wherein the element is included only in the charge controlling agent, and is one of elements of second to fifth periodical elements in the long form periodic table other than hydrogen, carbon, oxygen and rare gas elements; and T represents a quantity of the element in the toner composition in units of % by weight.
    Type: Grant
    Filed: March 8, 2002
    Date of Patent: February 28, 2006
    Assignee: Ricoh Company Limited
    Inventors: Hiroshi Yamashita, Kazuhito Watanabe, Chiaki Tanaka, Tsunemi Sugiyama, Shigeru Emoto, Masami Tomita
  • Patent number: 6994942
    Abstract: A non-magnetic single-component toner 8 of the present invention has toner mother particles 8a, and external additives 12 comprising: two hydrophobic silicas 13, 14 of which particle diameters are different from each other, i.e. a mean primary particle diameter of 7 nm to 12 nm and a mean primary particle diameter of 40 nm to 50 nm, and a hydrophobic rutile/anatase type titanium oxide 15 having a spindle shape of which major axial diameter is in a range from 0.02 nm to 0.10 nm and the ratio of the major axial diameter to the minor axial diameter is set to be 2 to 8, wherein the external additives 12 adhere to the toner mother particles 8a. By the hydrophobic silicas 13, 14 having work function smaller than the work function of the toner mother particles 8a, the negative charging property is imparted to the toner mother particles 8a and the fluidity is also insured.
    Type: Grant
    Filed: May 13, 2004
    Date of Patent: February 7, 2006
    Assignee: Seiko Epson Corporation
    Inventors: Nobuhiro Miyakawa, Takuya Kadota, Hidehiro Takano, Shinji Yasukawa, Masanao Kunugi
  • Patent number: 6991884
    Abstract: A chemically prepared toner for electrophotographic printers and method therefor using a unique polymeric dispersant. The chemically prepared toner includes agglomerated polymeric dispersant stabilized pigment particles, a fuser release agent, a charge control agent dispersion, and a self-stabilized essentially surfactant free latex binder. The polymeric dispersant includes at least three segments, a hydrophilic polymeric segment, a hydrophobic polymeric segment, and a protective colloid or reactive surfactant segment. The weight average molecular weight range of the dispersant ranges from about 5,000 to about 30,000, and a hydrophobicity ranging from about 10 to about 90 percent by weight. The chemically prepared toner includes agglomerated toner particles have a unimodal particles size distribution with a number average particle size (N) ranging from about 5.0 to about 8.5 microns and a volume average particle size (V) ranging from about 5.0 to about 8.5 microns.
    Type: Grant
    Filed: November 6, 2003
    Date of Patent: January 31, 2006
    Assignee: Lexmark International, Inc.
    Inventors: Jing X. Sun, Bradley Leonard Beach
  • Patent number: 6990306
    Abstract: An image is formed by using in combination a photoreceptor having a surface roughness Rz not larger than 1.0 and a developing agent comprising a toner containing toner particles containing a binder resin and a coloring agent, silica particles, and a metal soap, the weight ratio of the silica particles to the metal soap falling within a range of between 10 and 60.
    Type: Grant
    Filed: June 12, 2003
    Date of Patent: January 24, 2006
    Assignees: Kabushiki Kaisha Toshiba, Toshiba Tec Kabushiki Kaisha
    Inventor: Takahiro Mochizuki
  • Patent number: 6964835
    Abstract: A toner including a at least a binder resin; a colorant; and a zirconium compound including zirconium and at least one of an aromatic oxycarboxylic acid and a salt thereof, wherein the zirconium compound having a main diffraction peak (A) at a Bragg (2?) angle of 5.5±0.3° and a diffraction intensity of from 2,000 to 15,000 cps when irradiated with a specific X-ray of CuK?.
    Type: Grant
    Filed: July 21, 2003
    Date of Patent: November 15, 2005
    Assignee: Ricoh Company, Ltd.
    Inventors: Kumi Hasegawa, Mitsuo Aoki
  • Patent number: 6936391
    Abstract: An electrostatic image developing toner is disclosed. The toner particle conrains a silanol compound represented by formula of RmSi(OH)n in an amount of 1 to 20 ppm which is measured based on a head space method: wherein R represents a hydrocarbon group containing an alkyl group, a vinyl group, a glycidyloxy group, or a methacrylic acid, m and n each represents an integer of 1 to 3, and when m is 2 or 3, R may be the same of different.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: August 30, 2005
    Assignee: Konica Corporation
    Inventors: Tomoe Kitani, Hiroshi Yamazaki, Ken Ohmura
  • Patent number: 6929893
    Abstract: An electrostatic image dry toner composition comprising a binding resin, a colorant, a releasing agent, and two or more kinds of inorganic oxide powders having different volume average primary particle diameters. A surface of at least one kind of the inorganic oxide powders is covered with a coating material selected from the group of 1) a fatty acid metal salt, 2) a wax having a melting point of 40° C. or higher, and 3) a resin having a glass transition temperature of 40° C. or higher.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: August 16, 2005
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Susumu Yoshino, Motoko Sakai, Yoshifumi Iida, Seiichi Takagi
  • Patent number: 6929894
    Abstract: A toner is disclosed which is composed of toner particles containing at least a binder resin, a colorant and a wax, and an external additive. The wax has, in its DSC endothermic curve, a maximum endothermic peak at 55° C. to 80° C. within the temperature range from 30° C. to 160° C., the maximum endothermic peak having a half width of from 2° C. to 7° C., and the binder resin is composed chiefly of a polyester resin. The toner has a dynamic elastic modulus from 5×102 to 1×105 dN/m2 at 140° C., and its ratio to a dynamic elastic modulus at 170° C. is from 0.05 to 50, and the toner contains 10 to 20% by weight of THF-insoluble matter A of a binder resin component after 8 hours from the start of extraction and 1 to 10% by weight of THF-insoluble matter B of the binder resin component after 24 hours from the start of extraction, the ratio of A to B, B/A, being from 0.1 to 0.8. Also disclosed is a fixing method making use of this toner.
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: August 16, 2005
    Assignee: Canon Kabushiki Kaisha
    Inventors: Nobuyoshi Sugahara, Masaaki Taya, Junko Yoshikawa, Takayuki Itakura, Yojiro Hotta
  • Patent number: 6911289
    Abstract: A toner including toner particles including a binder resin and a release agent, wherein when the toner is molded into a plate upon application of a pressure of 478 kg/cm2, the toner plate has a surface having a coefficient of static friction of from 0.20 to 0.40. An image forming apparatus including an image bearing member, an image developer to form a toner image on the image bearing member, an image transferer configured to transfer the toner image on a receiving material and a fixer configured to fix the toner image thereon, wherein the apparatus has a waiting time not longer than 15 seconds, and a maximum power consumption not greater than 1.5 KW and 30 W in an image forming state and in a standby state, respectively, wherein the toner is the toner mentioned above.
    Type: Grant
    Filed: October 1, 2001
    Date of Patent: June 28, 2005
    Assignee: Ricoh Company Limited
    Inventors: Hiroto Higuchi, Fumihiro Sasaki, Yasuaki Iwamoto, Hiroshi Nakai, Bing Shu, Hiroaki Matsuda, Maiko Kondo
  • Patent number: 6838218
    Abstract: A black toner comprises a binder resin and black composite particles having an average particle diameter of 0.005 to 0.30 ?m, and comprising: extender pigments as core particles; a gluing agent-coating layer formed on surface of the respective core particles; and a black pigment coat uniformly formed on the gluing agent-coating layer in an amount of 1 to 500 parts by weight based on 100 parts by weight of the extender pigments. Such a black toner using black composite particles having not only excellent blackness, fluidity and light resistance, but also an excellent dispersibility in binder resins, which toner also exhibits excellent blackness, fluidity and light resistance.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: January 4, 2005
    Assignee: Toda Kogyo Corporation
    Inventors: Kazuyuki Hayashi, Hiroko Morii, Keisuke Iwasaki
  • Patent number: 6835517
    Abstract: A toner including at least a binder resin; a colorant; a charge controlling agent; and a wax (B), in which the charge controlling agent comprises a compound selected from the group consisting of: an aromatic oxycarboxylic acids, derivatives of aromatic oxycarboxylic acid, salts of aromatic oxycarboxylic acids and salts of derivatives of aromatic oxycarboxylic acids; and a zirconium compound (A), and in which the zirconium compound (A) and the wax (B) have a weight ratio (A/B) satisfying the following relationship: 3.0≦(A/B)×100≦60.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: December 28, 2004
    Assignee: Ricoh Company, Ltd.
    Inventors: Maiko Kondo, Yasuaki Iwamoto, Fumihiro Sasaki, Hiroto Higuchi, Bing Shu, Yasushi Koichi
  • Patent number: 6830859
    Abstract: A charge control agent containing a barium salt of a sulfoisophthalic acid compound and optionally a metal salt of a salicylic acid compound. A toner for developing an electrostatic latent image comprising such a charge control agent, a binder resin and a colorant.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: December 14, 2004
    Assignees: Ricoh Company, Ltd., Takemoto Yushi Kabushiki Kaisha
    Inventors: Keiko Shiraishi, Masanori Suzuki, Yohichiroh Watanabe, Toyoshi Sawada, Takuya Saito, Tatsuhiko Osaki, Satoshi Aratani, Hiroki Ogiso
  • Publication number: 20040248025
    Abstract: The present invention provides toners of different colors in which coloring agents of at least four unicolors are internally added to, respectively, and hydrophobic silica particles and metallic soap particles are externally added to toner mother particles, wherein color superposition of the toners is conducted during development of latent images on a latent image carrier or during transfer to a recording medium after the development, being characterized in that the difference (absolute value) between the work functions of two of said toners is 0.02 eV or more, the color superposition is conducted with the toners sequentially from the toner having the largest work function in descending order of work function of the toners, and the difference (absolute value) between the work function of the toner mother particles and the work function of the metallic soap particles is 0.
    Type: Application
    Filed: February 5, 2004
    Publication date: December 9, 2004
    Applicant: SEIKO EPSON CORPORATION
    Inventor: Nobuhiro Miyakawa
  • Patent number: 6824944
    Abstract: A toner process involving, for example, contacting a toner surface with a reducing agent and a metal halide.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: November 30, 2004
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Valerie M. Farrugia, Michael S. Hawkins
  • Patent number: 6824943
    Abstract: The present invention provides a toner for electrostatic image development which employs a black colorant free from a toxic substance and exhibits stable charge behavior even after extended use or printing of a large number of sheets, thus making it possible to provide printed images having sufficient image density without causing toner dispersion, fogging, and variation in image density. This is a toner for electrostatic image development comprising a binder resin and a colorant, wherein the colorant is made of black fine particles obtained by coating the surface of titanium dioxide particles with a complex oxide of titanium and iron.
    Type: Grant
    Filed: February 25, 2003
    Date of Patent: November 30, 2004
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventor: Hideki Gambayashi
  • Publication number: 20040234879
    Abstract: A toner for electrophotography contains a binder resin, a charge control agent, and a colorant. The colorant is a black iron oxide compound containing 10 to 45% by weight of titanium component calculated in terms of Ti atom in relation to Fe atom when measured by wavelength dispersive X-ray fluorescence spectrometry. Peaks at Bragg angle 2&thgr; of the toner to Cu&kgr;&agr; X-ray are peak A at 32.9 degrees±0.3 degrees and peak B at 35.5 degrees±0.3 degrees, and X ray intensity ratio between peaks A and B (A/B) is in the range of 0.3 to 2.0 at a scan speed of 0.5 to 4 degrees/min.
    Type: Application
    Filed: March 16, 2004
    Publication date: November 25, 2004
    Inventors: Kumi Hasegawa, Mitsuo Aoki, Bing Shu, Toyoshi Sawada, Keiko Shiraishi, Masashi Nagayama, Shinichi Kuramoto
  • Publication number: 20040229040
    Abstract: Spherical silica-titania-based fine particles surface-treated with silane are provided. The fine particles have a titanium atom content of 0.001 to 5% by weight, a frictional electrification with iron powder of −100 to −300 &mgr;C/g, a bulk density of 0.2 to 0.4 g/ml, and a particle diameter of 0.01 to 5 &mgr;m. The particles are useful as a material for an external additive for an electrostatically charged image developing toner. The toner is unlikely to cause degeneration or scratching of organic photoreceptors, displays excellent dispersibility and favorable flowability and consequently does not cause adhesion to the photoreceptor.
    Type: Application
    Filed: April 22, 2004
    Publication date: November 18, 2004
    Inventors: Muneo Kudo, Masaaki Yamaya
  • Publication number: 20040219448
    Abstract: The present invention provides a toner containing toner mother particles containing a binder resin and a colorant having added thereinto external additives, e.g., positively electrifiable silica fine particles, negatively electrifiable silica fine particles, titanium oxide fine particles and a long chain fatty acid or a salt thereof, wherein the external additives are added by multistage process, thereby is low in desorption of external additives, has the electrification property for a long period of time, shows high flowability and transfer efficiency, and is not accompanied by the reduction of image density.
    Type: Application
    Filed: January 16, 2004
    Publication date: November 4, 2004
    Applicant: SEIKO EPSON CORPORATION
    Inventors: Hiroshi Kato, Nobuhiro Miyakawa
  • Patent number: 6808852
    Abstract: A toner characterized by improved fixing performances with no or minimum oil application is formed of: (i) a binder resin, (ii) a colorant, (iii) a hydrocarbon wax, (iv) a resin composition formed by copolymerization of a styrenic monomer together with at least one of nitrogen-containing vinyl monomers, carboxyl group-containing monomers, hydroxyl group-containing monomers and (meth)acrylate ester monomers, in the presence of a hydrocarbon unit; and (v) an organometallic compound. The binder resin (i) comprises a polyester component in a proportion of at least 60 wt. % of the binder resin. The toner has a GPC molecular weight distribution including a weight-average molecular weight (Mw) of at least 4.0×104 an a ratio Mw/Mn of at least 50 between the Mw and a number-average molecular weight (Mn).
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: October 26, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yojiro Hotta, Wakashi Iida, Tetsuya Ida, Takayuki Itakura, Nozomu Komatsu
  • Patent number: 6800413
    Abstract: A silylated silica having an SiOH density per nm2 of less than 0.6, based on the BET-method surface area (DIN 66131 and 66132), is prepared by silylating silica in a process where loading, reacting, and purifying are performed in separate steps.
    Type: Grant
    Filed: September 9, 2002
    Date of Patent: October 5, 2004
    Assignee: Wacker-Chemie GmbH
    Inventors: Herbert Barthel, Mario Heinemann, Franz Grünwald, Helmut Maginot, Ute Völkel
  • Patent number: 6797447
    Abstract: By simultaneously atomizing a siloxane and two organometallic compounds of different metals M1 and M2 exclusive of silicon in a flame for combustion, spherical amorphous ternary complex oxide fine particles are obtained which are substantially free of chlorine, have a particle size of 10-500 nm, and have a silica content A of 1-99 wt %, a M1 oxide content B of 1-90 wt % and a M2 oxide content C of 1-90 wt %, all based on the weight of oxides excluding carbon, provided that A+B+C≈100. An electrostatic image developer comprising the fine particles is improved in fluidity and cleanability and bears a uniform and stable quantity of electric charge.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: September 28, 2004
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshiharu Konya, Koichiro Watanabe, Susumu Ueno
  • Publication number: 20040175642
    Abstract: To provide a color toner which is effective in mitigating contamination of a charging member, which is good at low temperature fixing in high-speed copying, and which is excellent in blocking resistance and electrification stability in continuous copying. Provided is a color toner containing at least a binder resin, a colorant, and a releasing agent, in which: (i) the binder resin contains at least a polyester unit; (ii) a weight average particle diameter of the color toner is greater than 6.5 &mgr;m and equal to or less than 11 &mgr;m; (iii) an average circularity A of particles in the color toner each having a circle-equivalent diameter of 3 &mgr;m or more satisfies the relationship of 0.915≦A≦0.
    Type: Application
    Filed: March 5, 2004
    Publication date: September 9, 2004
    Inventors: Tetsuya Ida, Yasuhiro Ichikawa, Hirohide Tanikawa, Nozomu Komatsu
  • Publication number: 20040175643
    Abstract: The present invention provides a toner: comprising a binder resin comprising a polyester unit, a colorant, a releasing agent, and inorganic fine particles; has a weight average particle diameter of 3.0-6.5 &mgr;m; has an average circularity of particles in the toner each having a circle-equivalent diameter of 2 &mgr;m or more of 0.920-0.945; has a BET specific surface area of 2.1-3.5 m2/g; and has a permeability of light of a wavelength of 600 nm in a liquid having dispersed the toner in a 45 vol % methanol aq. of 30-80%. The present invention also provides a two-component developer: comprising the toner and a magnetic carrier comprising magnetic core particles coated by a coating layer; and has a number average particle diameter of 15-80 &mgr;m. Using the toner and the two-component developer enables a high-quality image to be formed at a high speed even in an oilless fixing system.
    Type: Application
    Filed: March 5, 2004
    Publication date: September 9, 2004
    Inventors: Yoshinobu Baba, Yuko Sato, Ryoichi Fujita, Takaaki Kotaki, Nobuyoshi Sugahara, Kazuo Terauchi, Takayuki Itakura
  • Patent number: 6783908
    Abstract: An electrostatographic toner composition consists essentially of noncrosslinked linear polymeric toner particles, about 0.7 wt. % to about 4 wt. % of hydrophobic silica particles disposed on the surface of the toner particles, and about 0.1 wt. % to about 2 wt. % of particles of a fatty acid metal salt disposed on the surface of the toner particles, wherein the weight percentages of the hydrophobic silica particles and the particles of a fatty acid metal salt are based on the weight of the polymeric toner particles. An electrostatographic developer is formed by mixing the toner composition so prepared with hard magnetic carrier particles. A process for forming an electrostatographic toner composition comprises: providing noncrosslinked polymeric toner particles of a selected particle size, and dry blending the polymeric toner particles with a mixture consisting essentially of about 0.7 wt. % to about 4 wt. % of hydrophobic silica particles and about 0.1 wt. % to about 2 wt.
    Type: Grant
    Filed: May 20, 2002
    Date of Patent: August 31, 2004
    Assignee: NexPress Solutions, LLC
    Inventors: Satyanarayan Ayangar Srinivasan, Dinesh Tyagi
  • Publication number: 20040166428
    Abstract: A toner including toner particles including a binder resin and a release agent, wherein when the toner is molded into a plate upon application of a pressure of 478 kg/cm2, the toner plate has a surface having a coefficient of static friction of from 0.20 to 0.40. An image forming apparatus including an image bearing member, an image developer to form a toner image on the image bearing member, an image transferer configured to transfer the toner image on a receiving material and a fixer configured to fix the toner image thereon, wherein the apparatus has a waiting time not longer than 15 seconds, and a maximum power consumption not greater than 1.5 KW and 30 W in an image forming state and in a standby state, respectively, wherein the toner is the toner mentioned above.
    Type: Application
    Filed: February 26, 2004
    Publication date: August 26, 2004
    Inventors: Hiroto Higuchi, Fumihiro Sasaki, Yasuaki Iwamoto, Hiroshi Nakai, Bing Shu, Hiroaki Matsuda, Maiko Kondo
  • Publication number: 20040166429
    Abstract: A toner including toner particles including a binder resin and a release agent, wherein when the toner is molded into a plate upon application of a pressure of 478 kg/cm2, the toner plate has a surface having a coefficient of static friction of from 0.20 to 0.40. An image forming apparatus including an image bearing member, an image developer to form a toner image on the image bearing member, an image transferer configured to transfer the toner image on a receiving material and a fixer configured to fix the toner image thereon, wherein the apparatus has a waiting time not longer than 15 seconds, and a maximum power consumption not greater than 1.5 KW and 30 W in an image forming state and in a standby state, respectively, wherein the toner is the toner mentioned above.
    Type: Application
    Filed: February 26, 2004
    Publication date: August 26, 2004
    Inventors: Hiroto Higuchi, Fumihiro Sasaki, Yasuaki Iwamoto, Hiroshi Nakai, Bing Shu, Hiroaki Matsuda, Maiko Kondo
  • Patent number: 6780556
    Abstract: An external additive for a toner, having an average primary particle diameter not greater than 100 nm and including at least inorganic fine particles and a hydrophobizing agent applied to the surface of the inorganic fine particles, wherein after the external additive is treated with chloroform, pyrolysates of the residual components include a compound having at least one structure selected from organopolysiloxane structures and ring siloxane structures.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: August 24, 2004
    Assignee: Ricoh Company Limited
    Inventors: Hideki Sugiura, Tomio Kondou
  • Patent number: 6770411
    Abstract: A toner including a binder resin, a colorant, and a product of an iron compound containing an aromatic hydroxylcarboxylic acid as a ligand and represented by the formula (I) described in the specification, wherein the product has such a characteristic that a filtrate obtained by filtering a dispersion of 10 g of the product dispersed in 200 ml of purified water provides an electric conductivity of not greater than 600 &mgr;S/cm.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: August 3, 2004
    Assignee: Ricoh Company, Ltd.
    Inventors: Minoru Masuda, Satoshi Mochizuki, Yasuo Asahina, Kazuhiko Umemura, Hideki Sugiura, Kohsuke Suzuki, Tomomi Tamura
  • Publication number: 20040137352
    Abstract: A toner composition includes toner particles having at least one spacer of latex particles or polymer particles attached to the toner particles, in which the latex or polymer particles have an average particle size of from about 60 nm to about 500 nm. The presence of the spacer enables improved toner transfer efficiency maintainability while maintaining excellent tribo level, tribo stability with aging, charge through performance and cohesion behavior with aging and includes forming toner particles with grinding, and following completion of the grinding step, attaching to the toner particles at least one spacer selected from the group consisting of latex particles and polymer particles, wherein the latex particles or polymer particles have an average particle size of from about 60 nm to about 500 nm.
    Type: Application
    Filed: January 15, 2003
    Publication date: July 15, 2004
    Applicant: XEROX CORPORATION
    Inventors: Mary L. MC STRAVICK, Sue E. BLASZAK, Paul C. JULIEN, Susan J. KREMER
  • Publication number: 20040137344
    Abstract: The method of manufacturing toner for electrophotography includes the steps of dissolving or dispersing a toner composition containing a resin and a coloring agent into polymerizable monomers to provide a solution or a dispersed system, emulsifying the solution or the dispersed system with a first surface active agent in an aqueous medium to provide an emulsion, and polymerizing the polymerizable monomers in the emulsion to obtain toner. A second surface active agent having polarity opposite to polarity of the first surface active agent is added after the emulsifying step.
    Type: Application
    Filed: July 22, 2003
    Publication date: July 15, 2004
    Inventors: Hiroshi Yamashita, Takuya Saito, Tsunemi Sugiyama, Yohichiroh Watanabe
  • Publication number: 20040137348
    Abstract: A chemically prepared toner for electrophotographic printers and method therefor using a unique polymeric dispersant. The chemically prepared toner includes agglomerated polymeric dispersant stabilized pigment particles, a fuser release agent, a charge control agent dispersion, and a self-stabilized essentially surfactant free latex binder. The polymeric dispersant includes at least three segments, a hydrophilic polymeric segment, a hydrophobic polymeric segment, and a protective colloid or reactive surfactant segment. The weight average molecular weight range of the dispersant ranges from about 5,000 to about 30,000, and a hydrophobicity ranging from about 10 to about 90 percent by weight. The chemically prepared toner includes agglomerated toner particles have a unimodal particles size distribution with a number average particle size (N) ranging from about 5.0 to about 8.5 microns and a volume average particle size (V) ranging from about 5.0 to about 8.5 microns.
    Type: Application
    Filed: November 6, 2003
    Publication date: July 15, 2004
    Inventors: Jing X. Sun, Bradley Leonard Beach
  • Publication number: 20040137353
    Abstract: Provided is toner which is excellent in developing property, transferring property, and fixing property, hardly affected by its surrounding, and has good endurance. The toner has a peak temperature of maximum endothermic peak in the range of 60 to 100° C.
    Type: Application
    Filed: November 28, 2003
    Publication date: July 15, 2004
    Inventors: Wakashi Iida, Kazuhiko Hayami, Takayuki Itakura, Yojiro Hotta
  • Publication number: 20040137358
    Abstract: An electrophotographic toner is formed as a blend of toner particles and external additives. The external additives include (1) first inorganic fine particles having an average primary particle size of 80-800 nm of oxide of a metal selected from the group consisting of titanium, aluminum, zinc and zirconium, (2) second inorganic fine particles other than silica having an average primary particle size of below 80 nm and (3) silica fine particles having an average primary particle size of below 30 nm. As a result, the toner can be made free from difficulties, such as melt-sticking onto an image-bearing member in a low humidity environment, roughening of halftone images in a low humidity environment, toner blot-down after storage at high temperatures or in continuous image formation on a large number of sheets, fog in continuous formations of images of low color area percentage in a low humidity environment, and re-transfer in multi-color image formation.
    Type: Application
    Filed: December 23, 2003
    Publication date: July 15, 2004
    Inventors: Keita Nozawa, Atsushi Kubo, Masanori Ito, Tomoaki Igarashi, Kiyokazu Suzuki
  • Patent number: 6762004
    Abstract: Charge control agent and toner for developing electrostatic images containing said charge control agent. The active ingredient of the charge control agent is a metal compound obtainable by reacting one or two or more molecules of a compound having a phenolic hydroxy group and one or two or more molecules of a metal alkoxide.
    Type: Grant
    Filed: September 11, 2002
    Date of Patent: July 13, 2004
    Assignee: Orient Chemical Industries, Ltd.
    Inventors: Shun-ichiro Yamanaka, Akihide Isoda
  • Publication number: 20040091803
    Abstract: Provided is a developer capable of providing an excellent image without causing a charging failure even after a long-term and repeated use.
    Type: Application
    Filed: September 12, 2003
    Publication date: May 13, 2004
    Inventors: Katsuhisa Yamazaki, Takashige Kasuya, Tsuyoshi Takiguchi, Kaori Hiratsuka
  • Patent number: 6733940
    Abstract: The present invention provides a toner for MICR suitable for use in a printer for a non-magnetic monocomponent developing system, which does not produce scratches on a developing sleeve when used in the printer for the non-magnetic monocomponent developing system and has a resistance against sliding friction with a magnetic head, and also causes no reading errors because of a proper signal strength and imparts satisfactory image characteristics (for example, with respect to image density and fogging). The toner comprises a binder resin, a magnetic material and a wax, and has a BET specific surface area within a range from 0.70 to 1.00 m2/g.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: May 11, 2004
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Masamoto Terao, Akira Fujiwara
  • Publication number: 20040081905
    Abstract: A toner of the present invention comprises at least a binder resin comprising as a main component a polyester resin, a wax, and a colorant, in which in case of measuring a wettability of the toner with respect to a mixed solvent of methanol and water in terms of an optical transimittance at an optical wavelength of 780 nm, a methanol concentration of the mixed solvent is in a range of 45 to 65% by volume when an optical transmittance is 80% and 10%, respectively; a melt index (MI) is of 0.1 to 10 g/10 min at a temperature of 125° C.
    Type: Application
    Filed: September 25, 2003
    Publication date: April 29, 2004
    Inventors: Syuhei Moribe, Hiroshi Yusa, Takashige Kasuya, Yoshihiro Ogawa
  • Publication number: 20040058258
    Abstract: An electrostatic image dry toner composition comprising a binding resin, a colorant, a releasing agent, and two or more kinds of inorganic oxide powders having different volume average primary particle diameters. A surface of at least one kind of the inorganic oxide powders is covered with a coating material selected from the group of 1) a fatty acid metal salt, 2) a wax having a melting point of 40° C. or higher, and 3) a resin having a glass transition temperature of 40° C. or higher.
    Type: Application
    Filed: April 9, 2003
    Publication date: March 25, 2004
    Applicant: Fuji Xerox Co., Ltd.
    Inventors: Susumu Yoshino, Motoko Sakai, Yoshifumi Iida, Seiichi Takagi
  • Publication number: 20040058260
    Abstract: A toner composition including toner particles; and an external additive located on the surface of the toner particles and including Si, wherein the toner composition satisfies the following relationship, (PSi2p (1 min)−PSi2p (30 min))≦0.8 eV, wherein PSi2p (1 min) and PSi2p (30 min) represent positions of the Si2p peaks of the Si element of the toner composition when the toner composition is subjected to an X-ray photoelectron spectroscopy analysis after the toner composition is mixed with a carrier for 1 minute or 30 minutes using a TURBULA mixer at a revolution of 20 rpm, respectively.
    Type: Application
    Filed: July 1, 2003
    Publication date: March 25, 2004
    Inventors: Kohichi Katoh, Masahiko Ishikawa, Yohta Sakon, Tomoyuki Ichikawa, Hiroshi Nakai, Kazuhiko Umemura, Minoru Masuda, Hideki Sugiura, Kazumi Suzuki