Multilayer Patents (Class 430/14)
  • Patent number: 5674583
    Abstract: An optical tape including an optical recording layer for permitting information to be optically recorded thereon and a light-reflective magnetic layer; the light-reflective magnetic layer which reflects light projected onto the recording layer, also permits magnetic recording or magneto-optical recording to be performed thereon, thereby increasing a storage capacity of the optical tape remarkably; further, the optical tape is provided with a layer to form guiding grooves for tracking control, which layer to form guiding grooves is made up of ultraviolet-hardening resin, photo-resist, or a photochromic material.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: October 7, 1997
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Junichiro Nakayama, Hiroyuki Katayama, Akira Takahashi, Kenji Ohta, Kazuo Van
  • Patent number: 5639580
    Abstract: An integral image element, comprising:an integral lens sheet with opposed front and back surfaces, the front surface carrying convex surfaces of a plurality of lens elements;an integral image positioned behind the back surface; anda non-specular reflective layer positioned behind the integral image which layer reflects more than 80% of visible light reaching the reflective layer from in front of the layer, before penetrating the reflective layer a distance of 10 microns.A method of making the foregoing type of integral image element is also provided.
    Type: Grant
    Filed: February 13, 1996
    Date of Patent: June 17, 1997
    Assignee: Eastman Kodak Company
    Inventor: Roger Roy Adams Morton
  • Patent number: 5622795
    Abstract: Unique laser ablation transfer ("LAT") imaging technique presenting options of flexibility and versatility hitherto alien to LAT imaging science ("LATIS"), comprises LAT imaging onto special or conventional intermediate receptor elements, characteristically onto adhesive face surface thereof, and then laminating, notably hot laminating under pressure, the intermediate receptor thus imaged onto any one of a very wide variety of ultimate receptor substrates; thus produced are, e.g., original full-color prints or proofs, photomasks, monochrome or multichrome transparencies, and the like, having smooth or matte protective durable overcoatings.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: April 22, 1997
    Assignee: Rexham Graphics Inc.
    Inventor: Ernest W. Ellis
  • Patent number: 5620548
    Abstract: The present invention relates to a silver halide photographic transfer element which comprises a support having a front and rear surface, a transfer coating on the front of the support comprising a material capable of holding an image that can be transferred to a receptor surface upon the application of energy to the rear surface of the support, and at least one silver halide light sensitive emulsion layer on said front surface of the support. The invention is also directed to a method for applying a photographic image to a receptor element by the steps of exposing imagewise and then developing the above-described silver halide photographic transfer element, positioning the developed photographic element against a receptor element, and applying energy to the rear surface of the silver halide photographic element to transfer a photographic image to the receptor element.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 15, 1997
    Assignee: Foto-Wear, Inc.
    Inventor: Donald S. Hare
  • Patent number: 5620819
    Abstract: A binary image comprising a plurality of first areas, at which a porous or particulate image-forming substance is adhered to a substrate, and a plurality of second areas, at which the substrate is free from the image-forming substance, is protected by laminating thereto a laminating sheet comprising a barrier layer, a durable layer and a support layer with the barrier layer facing the image, so that the barrier and durable layers adhere to both the first and second areas of the image. The support layer is then displaced away from the image such that the barrier and durable layers remain attached to the image. Both the barrier and durable layers are substantially transparent and the barrier layer comprises a polymeric organic material substantially impervious to the passage of hexane, isopropanol or water.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: April 15, 1997
    Assignee: Polaroid Corporation
    Inventors: Robert M. Conforti, Sun-Wook Kim, Being-Kung Yao
  • Patent number: 5604073
    Abstract: In a bi-layer lift-off process, the adhesion characteristics of a PMGI release layer are substantially improved by the use of ortho-hydroxy substituted 4-phenylazo compounds (azo dyes), a class of nonactinic dyes, as an adhesion promoter additive. These azo dyes, due to their chemical structure, exhibit selective binding to various metals by acting as a chelating ligand to the metal surface. Formulations of a specific azo dye, Sudan Orange G, at concentrations from 0.25 to 1.0 percent (by weight) in PMGI exhibits no loss of adhesion at prebake temperature in the range of 120 to 160 degrees C.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: February 18, 1997
    Assignee: International Business Machines Corporation
    Inventors: Mohamad T. Krounbi, Alfred F. Renaldo, Douglas J. Werner
  • Patent number: 5593814
    Abstract: A device for controlling cell arrangement having a pattern composed of a cell adhesive surface and a cell non-adhesive surface, which has a good selectivity of cell adhesion and which can provide a fine pattern of cells in high resolution by culturing cells in a usual manner.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: January 14, 1997
    Assignee: Kanegafuchi kagaku kogyo Kabushiki Kaisha
    Inventors: Takehisa Matsuda, Kazuhiko Inoue, Nobutaka Tani
  • Patent number: 5576137
    Abstract: The invention relates to a non-continuous matte layer that can be used with a recording material having a substrate and a radiation-sensitive layer which contains a 1,2-naphthoquinone-2-diazide and an organic, polymeric binder which is insoluble in water but soluble in aqueous alkaline solutions. This matte layer comprises 100 to 10,000 particles per square centimeter which have a mean diameter of less than 40 .mu.m and a maximum diameter of less than 80 .mu.m and a mean height of 2 to 6 .mu.m and a maximum height of 10 .mu.m, and contains a resin which has up to 0.80 mmol of acid groups and/or salt groups per gram. The matte layer is obtained by spraying on and drying an aqueous, anionically or anionically/nonionically stabilized dispersion of the resin.
    Type: Grant
    Filed: September 14, 1994
    Date of Patent: November 19, 1996
    Assignee: Agfa-Gevaert AG
    Inventors: Werner Frass, Otfried Gaschler, Klaus Joerg, Guenter Hultzsch, Andreas Elsaesser
  • Patent number: 5547534
    Abstract: A binary image comprising a plurality of first areas, at which a porous or particulate image-forming substance is adhered to a substrate, and a plurality of second areas, at which the substrate is free from the image-forming substance, is protected by laminating thereto a laminating sheet comprising a barrier layer, a durable layer and a support layer with the barrier layer facing the image, so that the barrier and durable layers adhere to both the first and second areas of the image. The support layer is then displaced away from the image such that the barrier and durable layers remain attached to the image. Both the barrier and durable layers are substantially transparent and the barrier layer comprises a polymeric organic material substantially impervious to the passage of hexane, isopropanol or water.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: August 20, 1996
    Assignee: Polaroid Corporation
    Inventors: Robert M. Conforti, Sun-Wook Kim, Being-Kung Yao
  • Patent number: 5534373
    Abstract: A photosensitive material comprising (A) a flexible transparent film support, (B) a colored photosensitive layer which contains an organic binder (B1) a dye or a colored pigment (B2), a compound (B3), which forms a strong acid on exposure to radiation, and a compound (B4) which has at least one group cleavable by the acid, and (C) an adhesion-promoting layer which contains a thermoplastic polymer which has a softening temperature in the range from 40.degree. to 200.degree. C., wherein the adhesion (a.sub.1) of the unexposed photosensitive layer (B) to the adhesion-promoting layer (C) is less than the adhesion (a.sub.3) of the unexposed photosensitive layer (B) to the film support (A) and than the cohesions of the layers (B) and (C), and the adhesion (a.sub.3 ') of the exposed photosensitive layer (B) to the film support (A) is less than the adhesion (a.sub.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: July 9, 1996
    Assignee: Agfa-Gevaert AG
    Inventors: Stephan J. W. Platzer, Andrea Buchmann, Gerhard Buhr
  • Patent number: 5534372
    Abstract: An IC card in which an IC chip is incorporated between a first and second base boards, comprises an image receiving layer on which an ink image is transferred by a thermal transfer method and a cushion layer provided between the IC chip and the image receiving layer so that the cushion layer smooths irregularity caused by the IC chip and improves a flatness of the image receiving layer.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: July 9, 1996
    Assignee: Konica Corporation
    Inventors: Kunihiro Koshizuka, Shigehiro Kitamura, Masataka Takimoto, Tomonori Kawamura
  • Patent number: 5525400
    Abstract: There are disclosed laminated structures which are bonded with a UV-/VIS-curable composition and which consist of a main foil A) which is substantially impervious to light, at least one interlayer B) which is substantially impervious to light in the absence of the adhesive and which carries on the side with its back to the main foil information in the form of a color pattern, and of a substantially light-permeable covering foil C). The laminated structures can be used as identity cards.
    Type: Grant
    Filed: October 23, 1991
    Date of Patent: June 11, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Aloysius H. Manser, Jacques Francois
  • Patent number: 5518857
    Abstract: A method for engraving and/or etching comprising the steps of: (a) a process for exposing, to light, a layer of a water-soluble resin composition of a laminated photo-sensitive film which comprises a supporting sheet, a image mask-protection layer peelablly adhered to the supporting sheet and a layer of a water-soluble resin composition having photocrosslinkability to thus cause crosslinking of the exposed area of the resin layer to thereby form a predetermined pattern on the resin layer; (b) a process for dissolving out the non-crosslinked portion of the layer of the water-soluble photo-sensitive resin composition by developing the layer with water to thus from an image-carrying mask which is constituted from the crosslinked area of the photo-sensitive resin composition remaining on the image mask-protection layer; (c) a process for adhering the photo-sensitive laminate film on which the images are formed to the surface of a material to be processed; (d) a process for peeling off the supporting sheet from th
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: May 21, 1996
    Assignee: Aicello Chemical Co., Ltd.
    Inventors: Tsutomu Suzuki, Ikuo Suzuki
  • Patent number: 5503902
    Abstract: A light control material for displaying black-and-white and color images by forming light traps in a layer of photopolymer at selected locations. The photopolymer layer constitutes a master from which embossments can be produced. An embossment which displays the image can be produced from the master by a soft embossing procedure. The light traps are formed in the master by reactively ion etching a layer of cured photopolymer at selected locations to create fields of tapered structures. An embossment generated from the master contains fields of tapered structures which correspond to those created in the master. The surface of the embossment which includes the fields of tapered structures is coated with a reflective material such as metal. Light which enters the fields is reflected within the fields of tapered structures until substantially all of the light has been absorbed. Light which does not enter the fields is reflected.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: April 2, 1996
    Assignee: Applied Physics Research, L.P.
    Inventors: Richard A. Steenblik, Mark J. Hurt
  • Patent number: 5500314
    Abstract: A process for the optical recording and storage of information in the form of bits by irradiating a recording material comprising a substrate coated with at least one layer of a pigment selected from the group of the dithiopyrrolopyrroles, dithioquinacridones, phthalocyanines or mixtures of several of these pigments as recording layer dotwise or linearly with laser light in the near infrared range (NIR range), which pigment (a) has a crystal modification having an absorption band in the NIR range, and (b) is in contact with a solid organic compound that changes the crystal modification of the pigment upon irradiation with laser light, so that (c) after irradiation the absorption in the NIR range is reduced, while the organic compound exhibits no absorption in the NIR range before and after irradiation.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: March 19, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Jin Mizuguchi, Gerald Giller
  • Patent number: 5496668
    Abstract: In the formation of microstructures, a preformed sheet of photoresist, such as polymethylmethacrylate (PMMA), which is strain free, may be milled down before or after adherence to a substrate to a desired thickness. The photoresist is patterned by exposure through a mask to radiation, such as X-rays, and developed using a developer to remove the photoresist material which has been rendered susceptible to the developer. Micrometal structures may be formed by electroplating metal into the areas from which the photoresist has been removed. The photoresist itself may form useful microstructures, and can be removed from the substrate by utilizing a release layer between the substrate and the preformed sheet which can be removed by a remover which does not affect the photoresist. Multiple layers of patterned photoresist can be built up to allow complex three dimensional microstructures to be formed.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: March 5, 1996
    Assignee: Wisconsin Alumni Research Foundation
    Inventors: Henry Guckel, Todd R. Christenson, Kenneth Skrobis
  • Patent number: 5486442
    Abstract: An alternating copolymer comprising a repeating unit of the formula:-Z-(X-Y).sub.n - (I)wherein n is at least 2, X is O, S, Se or Te, and Y and Z are independently an aromatic or substituted aromatic group, and at least one other repeating unit, which is useful as a photosensitive material used in a spatial light modulator.
    Type: Grant
    Filed: July 13, 1993
    Date of Patent: January 23, 1996
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Akio Takimoto, Hirofumi Wakemoto, Eiichiro Tanaka, Masanori Watanabe, Junko Asayama, Hisahito Ogawa, Shigehiro Sato, Fumiko Yokotani
  • Patent number: 5480748
    Abstract: A conductive layer in a semiconductor device is protected against chemical attack by a photoresist developer by forming a protective film overlying the conductive layer. The protective film is formed using a chemical reaction that occurs through defects in a passivation layer that was previously formed overlying the conductive layer. The chemical reaction substantially occurs at the surface of the conductive layer and chemically converts portions thereof in forming the protective film. Preferably, the conductive layer is aluminum or an alloy thereof containing copper and/or silicon, and the protective film is aluminum oxide formed on the aluminum layer to protect it from corrosion by tetramethyl ammonium hydroxide (TMAH). The passivation layer is TiN, and the chemical reaction used is oxidation of the aluminum layer through defects in the overlying TiN layer by placing in an ozone asher.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: January 2, 1996
    Assignee: International Business Machines Corporation
    Inventors: Paul E. Bakeman, Jr., Hyun K. Lee, Stephen E. Luce
  • Patent number: 5474844
    Abstract: A polyester film for an image-forming transfer material, wherein a difference .DELTA..alpha..sub.t between the maximum coefficient of thermal expansion and the minimum coefficient of thermal expansion in the film plane is not larger than 1.0.times.10.sup.-5 /.degree.C., and the maximum coefficient of thermal expansion .alpha..sub.tmax is not larger than 2.5.times.10.sup.-5 /.degree.C., which can form a high quality color image having less deviation and a high image density.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: December 12, 1995
    Assignees: Diafoil Hoechst Company, Limited, Mitsubishi Chemical Corporation
    Inventors: Yoshinori Sato, Tetsuya Masuda
  • Patent number: 5472815
    Abstract: A coated material comprising a substrate which is coated with a layer of a pyrrolopyrrole of formula I ##STR1## wherein R.sub.1 and R.sub.2 may be 4-pyridyl and X.sub.1 and X.sub.2 are O, said compound of formula I being at least partially in the form of a salt of a strong acid, is suitable for use as an optical recording material and, owing to its electrical conductivity and photoconductivity, as antistatically treated material, as sensor, photoreceptor and solar battery.
    Type: Grant
    Filed: January 25, 1994
    Date of Patent: December 5, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Jin Mizuguchi, Gerald Giller, Alain C. Rochat
  • Patent number: 5462823
    Abstract: Disclosed is a magnetic recording element comprising a support having coated on at least one major surface thereof a layer of a magnetic recording medium and a photosensitive layer which may be separate from or integral with the magnetic recording layer and which contains an infrared absorbing dye or its precursors. Information can be imparted to the photosensitive layer by imagewise exposure to actinic radiation which will either promote or inhibit generation or destruction of the infrared absorbing dye.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: October 31, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Christopher M. Evans, Mark R. Buckingham, Colin F. Norman
  • Patent number: 5419988
    Abstract: A phase shift photomask and a photomask blank used to produce the same. A dry etching stopper layer, which is disposed between a substrate and a light-shielding layer or between the substrate and a phase shifter layer, is made of either a film mainly composed of tin oxide nitride, which has high etching selectivity and high permeability, or an alumina film formed by sputtering, followed by heat treatment carried out in an oxidizing atmosphere, thereby enabling the required overetching to be satisfactorily performed during etching of the phase shifter layer, and thus making it possible to effect precise phase control. In addition, it is possible to eliminate the occurrence of an in-plane transmittance distribution.
    Type: Grant
    Filed: August 5, 1993
    Date of Patent: May 30, 1995
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Hiroshi Mohri, Keiji Hashimoto, Masahiro Takahashi, Wataru Goto, Yukio Iimura
  • Patent number: 5413863
    Abstract: Holographic films are disclosed that contain a binder having the following formula:(M).sub.w (VAc).sub.x (VOH).sub.y (VOS).sub.zwherein M is a fluoromonomer; VAc is vinyl acetate; VOH is vinyl alcohol; and VOS is vinyl trimethylsilyl ether; and wherein w, x, y, and z are percentages by weight; w is 5 to 30, x is 40 to 80, y is 0 to 20, and z is 2 to 30; said copolymers containing 3 to 23% by weight fluorine. These imaged films are particularly suited for lamination to glass in head-up display applications.
    Type: Grant
    Filed: November 4, 1993
    Date of Patent: May 9, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Andrew M. Weber, Aleksander Beresniewicz
  • Patent number: 5407781
    Abstract: A photosensitive element comprising (a) a support, (b) a thermally hardened layer containing the reaction product of (i) either an organic polymer having reactive segments and nonreactive segments or a blend of organic polymers wherein at least one polymer has reactive segments and at least one polymer has nonreactive segments (ii) a crosslinking agent and (iii) a catalyst and (c) a photohardenable layer is described.
    Type: Grant
    Filed: December 6, 1993
    Date of Patent: April 18, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Bernard Feinberg, Richard P. Pankratz
  • Patent number: 5403685
    Abstract: Sub-micron features are defined photo-lithographically by combining phase-shifting techniques with conventional photo lithographic techniques. In a first step, phase-shifting edges are defined in a photoresist layer. Dark-bands develop at the phase-shifting edges due to wavefront interference of an illuminating radiation in a subsequent exposure step. Development leaves behind sub-micron sections of photoresist which were covered by the dark-band regions. The dark-band sections are hardened and overcoated with a new layer of photoresist. A second pattern is projected onto the second layer of photoresist using conventional techniques. The second pattern is developed so as to create features having dimensions reduced by parts of the dark-band sections previously developed.
    Type: Grant
    Filed: September 29, 1992
    Date of Patent: April 4, 1995
    Assignees: Sharp Kabushiki Kaisha, Sharp Microelectronics Technology, Inc.
    Inventors: David A. Vidusek, Hiroki Tabuchi
  • Patent number: 5395719
    Abstract: A dye transfer receptor sheet suitable for thermal dye transfer imaging is described which can provide a metal background to the transfered image. The receptor sheet comprises an organic polymeric substrate having a vapor deposited metal layer, a primer layer comprising a linear saturated thermoplastic polyester and a thermoset alkyd polyester, and a receiving layer.
    Type: Grant
    Filed: March 24, 1994
    Date of Patent: March 7, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Susan K. Jongewaard, Robert A. Braun
  • Patent number: 5344730
    Abstract: A method of recording information relating to an image photographed on a photographic film in which the photographic film comprises a magnetic track associated with each image frame for magnetically recording the information. Each magnetic track has two or more fields. The information is divided into sections which are each recorded onto any of the fields together with a start signal, an end signal, and an error detection and/or correction signal for each the information section. Consequently, even if the information to be recorded for each image frame is interrupted due to an error in the conveying speed of the film, a portion of the information can be read and utilized.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: September 6, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tatsuji Kitamoto
  • Patent number: 5314772
    Abstract: A high resolution, multi-layer resist for use in microlithography and a method is disclosed. The resist consists of a planarized layer deposited onto a substrate and an active layer, consisting of arsenic sulfide and silver is deposited onto the planarized layer. Irradiation with light, or other source of irradiation causes the silver to ionically diffuse into the arsenic sulfide, thereby creating a non-phase separate ternary chalcogenide glass. Removal of either the reacted or unreacted ternary compound will provide a positive or negative mask which may be used in subsequent processing or left as an intermetal dielectric as part of the underlying circuitry.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: May 24, 1994
    Assignee: Arizona Board of Regents
    Inventors: Michael N. Kozicki, Shao-Wen Hsia
  • Patent number: 5312671
    Abstract: A matte drafting sheet composite at least one side of which comprises a single polymeric matrix layer containing particulates to provide a matte or drafting surface and a quaternary ammonium salt of high charge density at a concentration sufficient to provide a resistivity of said matrix layer of at most about 1.times.10.sup.13 ohms/square.
    Type: Grant
    Filed: May 21, 1991
    Date of Patent: May 17, 1994
    Assignee: Arkwright Incorporated
    Inventors: David Atherton, Morgan E. Gager, Sankar K. Paul
  • Patent number: 5288570
    Abstract: A composite film article which is a flexible, heat resistant polymeric film material having a non-opaque, partially translucent white surface side, having a visible light opacity of from about 0.90 to about 0.99; and a non-opaque, black surface side having a visible light opacity of less than 1.0, a transmission density of less than about 2.0 and a thickness of less than about 5.0 microns. The article may be used as a base for images such that the images have a reduced optical dot gain.
    Type: Grant
    Filed: August 12, 1992
    Date of Patent: February 22, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: Robert J. von Trebra, Dennis J. Bellville
  • Patent number: 5272025
    Abstract: A composite comprising a carrier sheet of photograph size, and having front and back sides, and a camera-produced photographic image on a photographic print at the front side of the carrier sheet, and a graphics-produced image on at least one side of the sheet; a first digitized format on the back side of the carrier sheet, the format corresponding to the photographic image whereby the image is stored in the format, and a second digitized format on the back side of the carrier sheet, the second format corresponding to the graphics-produced image, the formats characterized as machine readable to produce a CRT display on the photographic image, and of the graphics-produced image in association with the photographic image display.
    Type: Grant
    Filed: May 3, 1991
    Date of Patent: December 21, 1993
    Inventor: Douglas E. Wheeler
  • Patent number: 5268259
    Abstract: A process for preparing a toner donor roll having an integral electrode pattern involving: (a) providing a cylindrically shaped insulating member; (b) coating the insulating member with a photoresist; (c) patterning the photoresist by exposure to light, resulting in a first photoresist portion corresponding to the electrode pattern and a second photoresist portion corresponding to the remainder of the photoresist; (d) removing the first photoresist portion, thereby exposing the portion of the insulating member to be overlaid with the electrode pattern; and (e) depositing conductive metal on the portion of the insulating member formerly overlaid with the first photoresist portion, resulting in the electrode pattern.
    Type: Grant
    Filed: October 16, 1992
    Date of Patent: December 7, 1993
    Assignee: Xerox Corporation
    Inventor: Donald S. Sypula
  • Patent number: 5266427
    Abstract: A display board has a substrate, a transparent photopolymerization resin layer formed on the substrate, and a picture layer formed in a surface of the transparent photopolymerization resin layer. The picture layer is composed of at least one dots-shaped colored photopolymerization resin. This display board is produced by exposing a colored photopolymerization resin film supported by a support member through a negative having a predetermined picture pattern to form a dots-shaped colored photopolymerization resin layer on the support member, transferring the dots-shaped colored photopolymerization resin layer to a surface of a transparent photopolymerization resin layer formed on a substrate to form a picture layer in the surface of the transparent photopolymerization resin layer, and setting the transparent photopolymerization resin layer in which the picture layer is formed to fix the picture layer.
    Type: Grant
    Filed: April 1, 1992
    Date of Patent: November 30, 1993
    Assignee: Nippondenso Co., Ltd.
    Inventors: Teruhiko Iwase, Takeshi Imai, Toshio Koura
  • Patent number: 5258247
    Abstract: A photoimaged article having a protected image composed of a colored image on a support; and a thin, transparent, flexible, nonself supporting, protective layer on the surface of the image. The layer is substantially nontacky at room temperature, and has at least a major amount based on the weight of the layer of one or more thermoplastic resins of a vinyl acetal, vinyl chloride, or acrylic polymer or copolymer having a Tg of from about 35.degree. C. to about 110.degree. C. The layer is capable of being adhesively transferred directly to the image when the layer is first applied on the release surface of a temporary support, and the image and protective layer are laminated together under pressure at temperatures of between about 60.degree. C. to about 180.degree. C. with subsequent removal of the temporary support. The side of said layer opposite to the image is free from additional layers. The adhesive layer is one which does not cohesively block at temperatures of about 50.degree. C. or less.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: November 2, 1993
    Assignee: Hoechst Celanese Corporation
    Inventor: Stephan J. W. Platzer
  • Patent number: 5215837
    Abstract: A direct pigment photographic printing process and composition based on a two-step coating process comprising a first coating applied to a sealed substrate containing between 2 to 8 and 8 to 2 weight parts of gum arabic to gelatin, and then applying a second top coating containing preferred ratios of gum arabic to gelatin. The process is based on heating the first and second coating compositions sufficiently above about 105.degree. F. prior to application to the substrate to assure homogeneous mixtures of each coating at the time of application.
    Type: Grant
    Filed: March 30, 1992
    Date of Patent: June 1, 1993
    Inventor: Arthur T. Chakalis
  • Patent number: 5216543
    Abstract: The present invention relates to an apparatus and method for patterning areas of a radiation absorbent film material. In the preferred embodiment, the film material is at least partially electrically conductive. The radiation is focused onto the film by a lenticular lens having a plurality of optically active elements to provide a radiation pattern on the film and remove or displace portions of the film to form a corresponding pattern, preferably a conductive pattern. The film may have one or more layers or regions, but at least one region must be radiation absorbent in order to allow the formation of patterns in the film in accordance with the present invention. The areas of the film affected by the phenomenon of radiation absorption are non-conductive voids which may separate the film into a plurality of conductive grid lines whereby the film is useful with a conductive lens film to increase the apparent efficiency of a photovoltaic cell.
    Type: Grant
    Filed: March 4, 1987
    Date of Patent: June 1, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Clyde D. Calhoun
  • Patent number: 5213917
    Abstract: This invention describes methods for altering a substrate in a fine line image pattern using a microlithographic process including formation of a metal mask over a photoresist coating to protect the photoresist coating during dry development of the same. The invention also describes a method for formation of the metal mask. Briefly stated, the process of the invention comprises the steps of coating a substrate with a photoresist coating, exposing the photoresist coating so formed to a desired pattern of actinic radiation, catalyzing the entire surface of the photoresist coating with an electroless plating catalyst, developing the photoresist layer to a depth at least sufficient to remove the undesired catalyst layer in an image pattern, forming a metal pattern on the desired (remaining) catalyst layer and dry developing the remaining photoresist coating unprotected by the metal mask.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: May 25, 1993
    Assignee: Shipley Company Inc.
    Inventors: Michael Gulla, Prasit Sricharoenchaikit
  • Patent number: 5213648
    Abstract: In a laminated product wherein at least one supported information-containing hydrophilic colloid layer is adhesively bonded on at least one of its surfaces to a protective hydrophobic resin sheet, improved adherence is achieved by using as the bonding adhesive a cationic crosslinked polymer obtained by:a) condensing a polyalkylenepolyamine containing at least two primary amino groups and at least one secondary or tertiary amino group with a dicarboxylic acid to form a polyamidoamine,b) subjecting the resultant polyamidoamine to a graft reaction in the presence of an acid catalyst with an alkene-1,2-imine, andc) crosslinking the resultant graft polymer with an epihalohydrin, an Alpha-Omega dihalohydrin ether or the ether compound obtained by reaction of epichlorohydrin with a water-soluble polyalkyleneoxide to form the water-soluble cationic polymer. With this adhesive bond, a tamper-proof seal can be obtained between the information-containing colloid layer and the hydrophobic resin protective sheet.
    Type: Grant
    Filed: March 15, 1991
    Date of Patent: May 25, 1993
    Assignee: Agfa-GEVAERT N.V.
    Inventors: Leon L. Vermeulen, Robert S. Pauwels
  • Patent number: 5194347
    Abstract: A sheet, ribbon or web material comprising a support made of a synthetic resin or a paper support coated with a layer of said resin, wherein a resin surface of said support is coated with a subbing layer and the subbing layer itself is coated with a hydrophilic colloid image-receiving layer containing development nuclei for silver image formation by DTR-processing, characterized in that the synthetic resin of said support is a polycarbonate or polypropylene resin, and said subbing layer contains in percent by weight on its total weight following ingredients: 1.3% to 80% of proteinaceous colloid, e.g. gelatin or caseine,0% to 85% of colloidal silica,1.
    Type: Grant
    Filed: November 26, 1991
    Date of Patent: March 16, 1993
    Assignee: Agfa-Gevaert N.V.
    Inventors: Leon L. Vermeulen, Robert S. Pauwels
  • Patent number: 5192630
    Abstract: The invention provides a method for protecting an image which comprises providing a multilayered colored image on a permanent receiver which may be any of a wide range of materials. A photosensitive element on a substrate is laminated to a temporary element and exposed with substrate removal before development. After development, the steps are repeated with another color. A protective element is laminated to the colored image. After removal of the support of the temporary element, the colored image with protective element is laminated to a permanent receiver.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: March 9, 1993
    Assignee: Hoechst Celanese Corporation
    Inventor: Stephan J. W. Platzer
  • Patent number: 5178979
    Abstract: An image transfer type recording method for forming a visible image on a developer medium comprising a base sheet, a thermoplastic resin layer, and a developer material layer which is color-reactable with a chromogenic material laminated in this order, and transferring the visible image on the developer medium to any type of image supporting medium, comprising the steps of forming the visible image on the developer material layer through a color-reaction between the developer material and the chromogenic material, providing an adhesive layer on the developer material layer, superposing the developer material layer and the image supporting medium under pressure and heat to fixedly transfer the developer material layer having the visible image thereon to the image supporting medium, and peeling off only the substrate of the developer medium.
    Type: Grant
    Filed: October 30, 1990
    Date of Patent: January 12, 1993
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Shunichi Higashiyama, Keiko Suzuki
  • Patent number: 5178975
    Abstract: A technique for making a high resolution X-ray mask with high aspect ratio absorber patterns sufficient for use in X-ray lithography wherein a thin resist layer is used to provide a low contrast mask, and then an X-ray exposure is used to increase the aspect ratio of the absorber to increase the contrast of the mask. The mask is first patterned with an e-beam resist exposure and development step, and the plating of the base material is activated by a reactive ion etch followed by electroplating. The resist is removed and the mask is coated with a negative acting X-ray resist. The back of the mask is exposed to X-rays wherein the existing absorber acts as an X-ray mask to expose the desired areas of the resist. The resist is removed after development, reactive ion etching and electroplating resulting in a mask with high contrast.
    Type: Grant
    Filed: January 25, 1991
    Date of Patent: January 12, 1993
    Assignee: International Business Machines Corporation
    Inventors: Kaolin Ng Chiong, David E. Seeger
  • Patent number: 5176971
    Abstract: A technique related to color filters to be arranged on the light-receiving surface of a color liquid crystal display device, color video camera, and the like. The color filter consists of a substrate (10) and a colored filter layer (12) formed thereon. The colored filter layer (12) comprises, for example, three groups of filter picture elements (14R), 14G, 14B) having spectral characteristics respectively corresponding to red, green and blue. Each group of filter picture elements are made of polyimide resin and dye contained therein. Further, each group of the filter picture elements (R, G, B) are arranged in direct contact with one surface of the substrate (10) without using any intermediate protecting film. The first group of filter picture elements patterned on one surface of the substrate (10) are subjected to heat treatment at a high temperature of about 250.degree. C., for example, to increase their resistance against the solvent.
    Type: Grant
    Filed: August 5, 1991
    Date of Patent: January 5, 1993
    Assignee: Kyodo Printing Co., Ltd.
    Inventors: Masayoshi Shimamura, Tadahiro Furukawa, Akiyoshi Murakami, Toshio Haga
  • Patent number: 5176972
    Abstract: An imaging medium comprises means for providing a light-reflecting layer, an image-receiving layer for receiving image-forming components, a transparent layer superposed over the image-receiving layer such that an image in the image-receiving layer can be viewed through the transparent layer against the light-reflecting layer, and an image enhancement layer disposed between the image-receiving layer and the transparent layer, the image enhancement layer having a refractive index less than that of the transparent layer and the image-receiving layer and not greater than about 1.43. The image enhancement layer decreases internal reflections within the medium and thereby improves the quality of the image seen. The imaging medium can be used as the imaging element of a diffusion transfer process film unit.
    Type: Grant
    Filed: September 11, 1991
    Date of Patent: January 5, 1993
    Assignee: Polaroid Corporation
    Inventors: Iris B. K. Bloom, Richard A. Minns, William T. Plummer
  • Patent number: 5176973
    Abstract: An at least two-color low optical dot gain surlay pre-press color proof comprising a base having laminated thereto in the following order, a first adhesive layer, a first single-color image, and then at least one additional pair of thin adhesive layers and comprising a synthetic polymeric binder composition with a Tg of less than 105.degree. and a thickness of 8-30 microns which thickness is at least twice that of any one of said additional thin adhesive layers.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: January 5, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Charles J. Gifford, Jack E. Cook, Bruce W. Weeks, Julien M. Wajs
  • Patent number: 5162179
    Abstract: This invention involves a structure containing a layered imaged configuration with an overcoating layer. The overcoating layer, in addition to encapsulating the toned image, substantially strengthens the dielectric layer after it is removed from the system. Also, a process for producing a product having an image depth perception and the product itself are disclosed. The layered structure may have one or two dielectric layers having a combined thickness of from about 0.2 to about 10.0 mils.
    Type: Grant
    Filed: April 17, 1990
    Date of Patent: November 10, 1992
    Assignee: Armstrong World Industries, Inc.
    Inventors: Walter J. Lewicki, Jr., John H. Bowers
  • Patent number: 5145757
    Abstract: A silicate glass article comprising an amount of SiO.sub.2 effective as a network former and,at least one surface of said article having a substantially continuous silver and hydration content over its area, effective to render said surface darkenable upon exposure to electron beam radiation but substantially not thermoplastic,said article having been substantially darkened by electron beam irradiation over at least a portion of at least one surface thereof,and said article having geometric characteristics suitable for functioning as a photomask reticle, optical disk or similar archival storage medium.
    Type: Grant
    Filed: June 23, 1989
    Date of Patent: September 8, 1992
    Assignee: Schott Glass Technologies, Inc.
    Inventors: Stephen W. Smoot, Joseph S. Hayden
  • Patent number: 5114813
    Abstract: Silicate glasses are provided which when exposed to a silver ion exchange surface treatment are writable with electron beams. These glasses contain OD agents and do not require elements having 1-4 d-electrons in the atomic state.
    Type: Grant
    Filed: February 8, 1990
    Date of Patent: May 19, 1992
    Assignee: Schott Glass Technologies, Inc.
    Inventors: Stephen W. Smoot, Joseph S. Hayden, Marc Clement, Danuta Grabowski, Eva Holzel, Peter Nass, Martin Heming
  • Patent number: 5110697
    Abstract: A photolithographic composition having improved processability and which eliminates the need for inter layering multiple special purpose coatings in the production of micro-electronic devices is surprisingly made possible by selective dissolution of poly(vinylpyridine) and an effective light attenuating material in critical solvents.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: May 5, 1992
    Assignee: Brewer Science Inc.
    Inventors: James E. Lamb, III, Terry Brewer, J. Michael Mori
  • Patent number: 5108857
    Abstract: A light control sheet capable of scattering an incident light of particular incident angle is produced by a method composed of preparing a film of a composition containing at least two photopolymerizable components having different refractive indexes, irradiating on the film a light from a particular direction, and obtaining a cured film of the light control sheet product. Such other light control sheets as capable of scattering a plurality of incident lights each of particular incident angle are obtained by modification of the above-mentioned method.
    Type: Grant
    Filed: April 5, 1990
    Date of Patent: April 28, 1992
    Assignees: Sumitomo Chemical Company, Limited, Nippon Sheet Glass Co., Ltd.
    Inventors: Shinichiro Kitayama, Teruho Adachi, Masahiro Ueda, Yuichi Aoki, Satoshi Shiiki, Akio Takigawa, Motoaki Yoshida, Naoya Imamura, Koichi Maeda, Hisayuki Kayanoki