P-amino Or P-thio Benzene Diazonium Compound Patents (Class 430/183)
  • Patent number: 7118844
    Abstract: A diazonium salt represented by the following general formula (1) and a thermal recording material using the diazonium salt: General Formula (1) wherein R1 and R2 each independently represents an alkyl group, an aryl group, an acyl group, an alkoxycarbonyl group or a carbamoyl group, and R1 and R2 may be linked each other to form a ring; and R3 to R6 each independently represents a hydrogen atom, a hydroxyl group, a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an arylsulfonyl group or a diazonio group, and at least one of R3, R4, R5 and R6 represents the diazonio group.
    Type: Grant
    Filed: September 3, 2003
    Date of Patent: October 10, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akinori Fujita, Kimiatsu Nomura, Yoshihiro Jimbo, Hisato Nagase, Toshihide Aoshima, Yasuhiro Mitamura, Tatsuo Kawabuchi
  • Patent number: 6927007
    Abstract: A heat-sensitive recording material including a substrate having disposed thereon a heat-sensitive recording layer containing a diazo compound and a coupler compound capable of reacting with the diazo compound to develop color, wherein the coupler compound includes at least one of anilide derivatives represented by the following formula (1) or tautomers thereof: wherein R1 represents an alkyl group or an aryl group; R2, R3 and R4 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an acyl group, an alkoxy group, an alkoxycarbonyl group, a hydroxycarbonyl group, an aminocarbonyl group, an acylamino group, a cyano group, a nitro group, an arylthio group or an alkylthio group; L represents a group which can leave upon coupling with the diazo compound; m represents 1 or 2; and n represents 1 or 2.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: August 9, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yohsuke Takeuchi, Akinori Fujita, Daisuke Arioka, Tetsunori Matsushita
  • Publication number: 20040086798
    Abstract: A heat-sensitive recording material including a substrate having disposed thereon a heat-sensitive recording layer containing a diazo compound and a coupler compound capable of reacting with the diazo compound to develop color,
    Type: Application
    Filed: October 27, 2003
    Publication date: May 6, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Yohsuke Takeuchi, Akinori Fujita, Daisuke Arioka, Tetsunori Matsushita
  • Publication number: 20040048185
    Abstract: A heat-sensitive recording material containing a support and a heat-sensitive recording layer formed on the support, the heat-sensitive recording layer including a diazonium salt and a coupler that thermally reacts with the diazonium salt to develop color.
    Type: Application
    Filed: August 29, 2003
    Publication date: March 11, 2004
    Applicant: FUJI PHOTO FILM CO., LTD
    Inventors: Hisao Yamada, Hiroshi Sato, Yoshimitsu Arai, Kimi Ikeda
  • Patent number: 6245476
    Abstract: The present invention provides a photo-sensitive and heat-sensitive recording material comprising a substrate supporting thereon a photo-sensitive and heat-sensitive recording layer containing a diazo compound and a coupler, wherein the diazo compound is a compound represented by the following general formula (1) and the diazo compound is enclosed in a microcapsule: wherein, R1 and R2 may be the same or different, and represent an alkyl group having 1 to 5 carbon atoms; R1 and R2 may be bonded to each other to form a ring; R3 and R4 may be the same or different, and represent an alkyl group; and R3 and R4 may be bonded to each other to form a ring. This photo-sensitive and heat-sensitive recording material reveals less change in the base concentration between before and after storage before use.
    Type: Grant
    Filed: June 9, 1999
    Date of Patent: June 12, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tomohiro Kodama, Yohsuke Takeuchi, Kimiatsu Nomura, Yoshihiro Jimbo, Ken Iwakura
  • Patent number: 6060206
    Abstract: Disclosed is a photo- and heat-sensitive recording material comprising a substrate and a photo- and heat-sensitive recording layer formed thereon containing a diazo compound and a coupler, wherein the coupler is a compound represented by the general formula (1) or the general formula (2): ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each independently a hydrogen atom or a substituent group; and R.sup.1 and R.sup.2 may join with each other to form a ring. The reaction between the coupler represented by the general formula (2) and a specific diazo compound produces a magenta colorant having very sharp absorption characteristics. In short, the present invention provides a photo- and heat-sensitive recording material which does not inhibit the fixing and which exhibits excellent color formation, color reproduction, and image durability. Further, the present invention provides a magenta colorant which exhibits excellent absorption characteristics.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: May 9, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Hanaki, Yasuhiro Mitamura, Atsuhiro Ohkawa
  • Patent number: 5952477
    Abstract: The present invention is concerned with a novel azo compound represented by formula (1), (2) or (3), a water-soluble dye comprising this azo compound, and a polarizing film containing this azo compound. The obtained polarizing film has high hydrothermoresistance and a high polarization degree and is excellent in optical characteristics: ##STR1## wherein each of the groups is defined.
    Type: Grant
    Filed: October 15, 1997
    Date of Patent: September 14, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tsutami Misawa, Akira Ogiso, Rihoko Imai, Hisato Itoh
  • Patent number: 5807707
    Abstract: An increased level of translation of a selected mRNA molecule is effected by coupling specific nucleotide sequences at the 5'- and 3' -ends of a nucleic acid molecule transcribable to or which itself is the mRNA molecule. The nucleotide sequence at the 5'-end is effective to increase the rate of translation initiation of the mRNA molecule in a cell while the nucleotide sequence at the 3'-end is effective to increase the period of translation of the mRNA molecule in a cell. The nucleotide sequence of the 3'-end is provided by a 3'-untranslated region (3'-UTR) of a gene, particularly that of .beta.-prolactin, or an effective fragment thereof. A polyadenylation sequence preferably is provided at the 3'-end of the 3'-UTR sequence. The 3'-UTR sequence provides mRNA stabilization independent of the poly A tail.
    Type: Grant
    Filed: February 12, 1996
    Date of Patent: September 15, 1998
    Assignee: McMaster University
    Inventors: David W. Andrews, Martin John Glenton Hughes, Akaterini Vassilakos
  • Patent number: 5683850
    Abstract: A diazo heat-sensitive recording material having excellent raw stock storability and image storage characteristics, which comprises a support having thereon a recording layer comprising a diazo compound, a coupling component and an organic base. The diazo compound is a 4-disubstituted amino-2-alkoxybenzenediazonium salt and the coupling component is a compound represented by the following general formula: ##STR1## wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 each represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, an alkyloxy group, an aryloxy group, an alkylthio group, an arylthio group, an acyl group, an alkoxycarbonyl group, an acyloxy group, a carbamoyl group, a sulfamoyl group, a halogen atom, a cyano group or a nitro group.
    Type: Grant
    Filed: December 2, 1996
    Date of Patent: November 4, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetunori Matushita, Hiroshi Sato, Sadao Ishige, Kimiatsu Nomura, Mitsuyuki Tsurumi
  • Patent number: 5213939
    Abstract: A light- and heat-sensitive recording material is disclosed which includes a support having thereon a recording layer containing a diazo compound, a coupling component, and an organic base compound, wherein the diazo compound is a 1-substituted amino-3-alkoxybenzene-4-diazonium salt and the coupling component is a compound prepared from any of cyclohexane-1,3-dione, 3-cyclohexenone, or 2-cyclohexenone. The light- and heat-sensitive recording material according to the present invention can develop an excellent magenta color hue and has excellent storage properties before recording use (shelf life).
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: May 25, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takekatsu Sugiyama, Sadao Ishige, Naoto Yanagihara, Hiroshi Kamikawa, Keiichi Tateishi
  • Patent number: 4618561
    Abstract: A record memory medium comprises a recording layer comprising a monomolecular film or monomolecular layer built-up film of a photosensitive organic compound having a hydrophilic moiety and a hydrophobic moiety. The medium can be used for recording/reading-out of information and light recording.
    Type: Grant
    Filed: November 29, 1984
    Date of Patent: October 21, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hirohide Munakata, Yoshinori Tomida, Masahiro Haruta, Yutaka Hirai, Yukuo Nishimura, Takashi Hamamoto
  • Patent number: 4590263
    Abstract: Novel diazonium salts which possess excellent photo speed, good thermal stability, exceptional resistance to discoloration in the D.sub.min areas, rapid development, and allow a wide range of azo dye colors are provided. The diazonium salts are of the following formula: ##STR1## wherein R.sub.1 is tertiary butyl or tertiary amyl; Y is hydrogen, alkyl, hydroxyalkyl, cyanoalkyl, cycloalkyl, aralkyl, alkoxy, aryloxy, aralkoxy, aralkylthio, arylthio, alkylthio, halogen, allyl, allyloxy, allylthio, cyanoalkoxy, hydroxyalkoxy, methoxyalkoxy, trifluoroalkyl, alkylacetylamino, morpholino, or dialkyl carbonamido;R.sub.2 and R.sub.3 are the same or different, and are alkyl, aralkyl, allyl, cyanoalkyl, hydroxyalkyl, hydrogen, acyl, cycloalkyl, beta-chloroalkyl, branched alkyl, or a structure wherein R.sub.2 and R.sub.3 may be linked together to form a heterocyclic structure; andX is an anion.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: May 20, 1986
    Assignee: James River Graphics, Inc.
    Inventors: Robert C. Desjarlais, Everett W. Bennett
  • Patent number: 4520094
    Abstract: A photosensitive composition turning shicky by light exposure, which comprises a salt or p-aminobenzenediazonium compound and at least one of salts of o- and m-aminobenzenediazonium compounds, has a distinguished effect in forming a phosphor screen of a color picture tube.
    Type: Grant
    Filed: October 19, 1982
    Date of Patent: May 28, 1985
    Assignee: Hitachi, Ltd.
    Inventors: Hajime Morishita, Motoo Akagi, Nobuaki Hayashi, Saburo Nonogaki, Shoichi Uchino, Takahiro Kohashi
  • Patent number: 4411979
    Abstract: A diazo type thermosensitive recording material comprising a support material and a thermosensitive recording layer formed thereon, wherein the thermosensitive recording layer comprises a diazo compound, a coupler, a thermo-fusible or thermo-softening binder agent and a thermo-fusible material. The weight ratio of the diazo compound and the thermo-fusible material is in the range of 1:2 to 1:30, and both the diazo compound and the coupler exist as separate particles in the thermosensitive recording layer.
    Type: Grant
    Filed: January 6, 1982
    Date of Patent: October 25, 1983
    Assignee: Ricoh Company, Ltd.
    Inventors: Masanaka Nagamoto, Yoshihiro Koseki, Susumu Iwata
  • Patent number: 4401744
    Abstract: Disclosure is made of a light-sensitive diazo coating composition and a light-sensitive diazotype reproduction material comprising a base with at least one coating layer comprising a light sensitive diazo compound, coupling component, a stabilizing acid and salt, and a development accelerating and stabilizing composition of 1,3-dimethylurea with urea or with thiourea, which also improves sensitizing solution compatibility and increases printing speed.
    Type: Grant
    Filed: May 6, 1981
    Date of Patent: August 30, 1983
    Assignee: Andrews Paper & Chemical Co., Inc.
    Inventor: Peter Muller
  • Patent number: 4400458
    Abstract: It is the purpose and object of the present invention to make better use of the emission range of light sources and to create the diazonium salts necessary for such purpose. The diazonium salts of the present invention of the general formula ##STR1## wherein Y is ##STR2## R.sub.1, R.sub.2 are equal or different and are, alkyl having 1 to 10 carbon atoms, aryl having 6 to 10 carbon atoms in a mono or polycylic ring;R.sub.3 is hydrogen, halogen, alkyl, alkoxy, cyano;R.sub.4 is hydrogen, halogen, alkyl, alkoxy; andX.sup.e is an anion,can be employed with all known couplers and additives in diazotype materials. They have an absorption range of 480 to 550 nm.
    Type: Grant
    Filed: September 14, 1981
    Date of Patent: August 23, 1983
    Assignee: VEB Filmfabrik Wolfen
    Inventors: Fred Walkow, Peter Czerney, Horst Hartmann, Jorg Marx
  • Patent number: 4343884
    Abstract: One component diazotype material is imagewise exposed and developed odorless and curlfree with 0.6-4.5 g/m.sup.2 per square meter of a substantially water free liquid developer in a pressure development or transfer roller apparatus.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: August 10, 1982
    Assignee: Andrews Paper & Chemical Co., Inc.
    Inventors: Peter Muller, Henry Mustacchi
  • Patent number: 4334004
    Abstract: This invention relates to 2-hydroxy-3-naphthoic acid amides of the general formula: ##STR1## wherein R.sub.1 is hydrogen, a substituted or unsubstituted alkyl, cycloalkyl, aralkyl, or aryl group, and R.sub.2 and R.sub.3 are identical or different and are hydrogen, a substituted or unsubstituted alkyl, cycloalkyl, aralkyl, or aryl group, or, together with the nitrogen atom to which they are attached, a substituted or unsubstituted heterocyclic group.
    Type: Grant
    Filed: March 16, 1979
    Date of Patent: June 8, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Siegfried Scheler
  • Patent number: 4289839
    Abstract: Negative-working diazography material is comprised of (i) at least one diazonium compound, (ii) at least one acid labile enolic, preferably phenolic blocked-coupler adapted to be converted in the presence of acid to an active azo-coupling component, (iii) at least one light-sensitive acid progenitor, and (iv) at least one carboxylic acid anhydride. The diazonium compound can itself concurrently function as the acid progenitor, e.g., when complexed with a Lewis acid. Upon imagewise exposure to light, acid catalyst is photochemically liberated, thus unblocking coupler molecules such that dye image forms under alkaline developing conditions only where the material has been irradiated. Under alkaline developing conditions, the anhydride reacts to render the unused diazo component remaining in the unexposed areas inactive.
    Type: Grant
    Filed: February 15, 1980
    Date of Patent: September 15, 1981
    Assignee: James River Graphics, Inc.
    Inventor: Carmine A. DiPippo
  • Patent number: 4284705
    Abstract: Diazonium compounds particularly useful for the preparation of lithographic printing plates, a process for the preparation of this compound and printing plate, and for the use of the plate; and a lithographic plate presensitized with this compound, are described.
    Type: Grant
    Filed: December 31, 1979
    Date of Patent: August 18, 1981
    Assignee: Eastman Kodak Company
    Inventors: Georges A. Phlipot, Jacques R. G. Haeck, Simone J. Kempen
  • Patent number: 4275138
    Abstract: A photosensitive composition is prepared comprising a diazonium compound and a polymer containing at least 50% by weight of the recurring unit represented by the following general formula (I): ##STR1## wherein R.sub.1 represents hydrogen atom or methyl group, R.sub.2 represents hydrogen atom or a methyl, ethyl or chloromethyl group and n is an integer of 1 to 10.
    Type: Grant
    Filed: September 14, 1976
    Date of Patent: June 23, 1981
    Assignees: Fuji Photo Film Co., Ltd., National Patent Development Corp.
    Inventors: Nobuyuki Kita, Yasuhisa Narutomi
  • Patent number: 4218368
    Abstract: Aromatic nitro compounds are disclosed where the aromatic ring contains electron-withdrawing groups and said aromatic nitro compound is capable of undergoing intramolecular nucleophilic displacement after reduction of the nitro group. The compounds are especially useful in photographic elements where an image dye-providing material or a photographic reagent are released upon cleavage from the compound.
    Type: Grant
    Filed: July 26, 1978
    Date of Patent: August 19, 1980
    Assignee: Eastman Kodak Company
    Inventors: Jerald C. Hinshaw, Richard P. Henzel
  • Patent number: 4215041
    Abstract: Substituted amino-benzene diazonium compounds particularly useful for the preparation of lithographic printing plates, a process for the preparation of this compound and printing plate, and for the use of the plate; and a lithographic plate presensitized with this compound, are described.
    Type: Grant
    Filed: July 12, 1978
    Date of Patent: July 29, 1980
    Assignee: Eastman Kodak Company
    Inventors: Georges A. Phlipot, Jacques R. G. Haeck, Simone J. Kempen
  • Patent number: 4210449
    Abstract: Copolymers of glycidyl methacrylate and allyl glycidyl ether having pendant epoxy groups, having an inherent viscosity of at least about 0.25, preferably within the range of about 0.25 to about 0.38, and an epoxy equivalent of at least about 0.65 epoxide equivalent per 100 g. of polymer are provided which upon admixture with a radiation-sensitive aryldiazonium salt provide compositions which exhibit improved sensitivity, curing rates and other properties. Articles for recording and storing information from a laser source and other articles such as microfilm are derived from such compositions by subjecting a coated substrate to an energy source of sufficient intensity to decompose the radiation-sensitive catalyst and thus effect polymerization via the epoxy groups of the copolymer.
    Type: Grant
    Filed: February 4, 1975
    Date of Patent: July 1, 1980
    Assignee: American Can Company
    Inventors: Sheldon I. Schlesinger, Veronica Cochran