Additional Substituent On Benzene Nucleus Patents (Class 430/185)
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Patent number: 7118844Abstract: A diazonium salt represented by the following general formula (1) and a thermal recording material using the diazonium salt: General Formula (1) wherein R1 and R2 each independently represents an alkyl group, an aryl group, an acyl group, an alkoxycarbonyl group or a carbamoyl group, and R1 and R2 may be linked each other to form a ring; and R3 to R6 each independently represents a hydrogen atom, a hydroxyl group, a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an arylsulfonyl group or a diazonio group, and at least one of R3, R4, R5 and R6 represents the diazonio group.Type: GrantFiled: September 3, 2003Date of Patent: October 10, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Akinori Fujita, Kimiatsu Nomura, Yoshihiro Jimbo, Hisato Nagase, Toshihide Aoshima, Yasuhiro Mitamura, Tatsuo Kawabuchi
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Publication number: 20030082474Abstract: The present invention provides a thermally imageable composition, which includes an acid curable composition, an acid generator, a strong acid and optionally an infrared absorber. The present invention further provides an imageable element, which includes a substrate and a thermally imageable composition according to the present invention coated on a surface of the substrate. Also provided are methods of producing an imaged element according to the present invention.Type: ApplicationFiled: August 21, 2001Publication date: May 1, 2003Applicant: Kodak Polychrome Graphics, L.L.CInventors: Neil Haley, John Kalamen
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Patent number: 6245476Abstract: The present invention provides a photo-sensitive and heat-sensitive recording material comprising a substrate supporting thereon a photo-sensitive and heat-sensitive recording layer containing a diazo compound and a coupler, wherein the diazo compound is a compound represented by the following general formula (1) and the diazo compound is enclosed in a microcapsule: wherein, R1 and R2 may be the same or different, and represent an alkyl group having 1 to 5 carbon atoms; R1 and R2 may be bonded to each other to form a ring; R3 and R4 may be the same or different, and represent an alkyl group; and R3 and R4 may be bonded to each other to form a ring. This photo-sensitive and heat-sensitive recording material reveals less change in the base concentration between before and after storage before use.Type: GrantFiled: June 9, 1999Date of Patent: June 12, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Tomohiro Kodama, Yohsuke Takeuchi, Kimiatsu Nomura, Yoshihiro Jimbo, Ken Iwakura
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Patent number: 6060206Abstract: Disclosed is a photo- and heat-sensitive recording material comprising a substrate and a photo- and heat-sensitive recording layer formed thereon containing a diazo compound and a coupler, wherein the coupler is a compound represented by the general formula (1) or the general formula (2): ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each independently a hydrogen atom or a substituent group; and R.sup.1 and R.sup.2 may join with each other to form a ring. The reaction between the coupler represented by the general formula (2) and a specific diazo compound produces a magenta colorant having very sharp absorption characteristics. In short, the present invention provides a photo- and heat-sensitive recording material which does not inhibit the fixing and which exhibits excellent color formation, color reproduction, and image durability. Further, the present invention provides a magenta colorant which exhibits excellent absorption characteristics.Type: GrantFiled: October 1, 1998Date of Patent: May 9, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Hanaki, Yasuhiro Mitamura, Atsuhiro Ohkawa
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Patent number: 5543260Abstract: A diazo heat-sensitive recording material containing a support having provided thereon a recording layer containing a diazo compound, a coupler, and an organic base, wherein the diazo compound is a compound represented by formula (I): ##STR1## wherein R.sub.1 represents --C(Z.sub.1)(Z.sub.2)--CH.sub.2 --A, --CH.sub.2 --C(Z.sub.1)(Z.sub.2)--A or --{C(Z.sub.1)(Z.sub.2)}.sub.m --A,wherein Z.sub.1 represents an alkyl group, an aralkyl group or an aryl group; Z.sub.2 represents a hydrogen atom, an alkyl group, an aralkyl group or an aryl group; A represents a halogen atom, an acyl group, a cyano group, or a group containing at least one oxygen, nitrogen, phosphorus or sulfur atom through which A is bonded to --CH.sub.2 -- or Z.sub.2 ; and m represents an integer of 1 to 5;R.sub.2 and R.sub.3, which may be the same or different, each represent an alkyl group, an aralkyl group or an aryl group; R.sub.1 and R.sub.Type: GrantFiled: November 8, 1994Date of Patent: August 6, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiichi Tateishi, Sadao Ishige, Hiroshi Kamikawa
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Patent number: 5296329Abstract: A diazo heat-sensitive recording material which comprises a support having thereon a heat-sensitive recording layer comprising a diazo compound, a coupling component, a basic substance, and a binder; wherein the coupling component is an acylacetanilide represented by the formula (I): ##STR1## wherein R.sub.1 is substituted or unsubstituted alkyl or aryl; R.sub.2 is substituted or unsubstituted alkyl or aralkyl; R.sub.3 is substituted of unsubstituted alkyl, alkoxy, aralkyloxy, alkylthio, or aralkylthio, substituted amino, or halogeno; the total number of carbon atoms in R.sub.2 and (R.sub.3).sub.n is 5 or more; n is zero or an integer of from 1 to 4; and the R.sub.3 's may be the same or different when n is 2 or more, which is useful for forming a yellow color image and providing a developed color image with higher light-fastness, less soiling of a non-image area, and improved uniformity in color-developing layer due to the use of a more oil-soluble coupling component.Type: GrantFiled: July 26, 1993Date of Patent: March 22, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Takekatsu Sugiyama, Akira Igarashi
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Patent number: 5213939Abstract: A light- and heat-sensitive recording material is disclosed which includes a support having thereon a recording layer containing a diazo compound, a coupling component, and an organic base compound, wherein the diazo compound is a 1-substituted amino-3-alkoxybenzene-4-diazonium salt and the coupling component is a compound prepared from any of cyclohexane-1,3-dione, 3-cyclohexenone, or 2-cyclohexenone. The light- and heat-sensitive recording material according to the present invention can develop an excellent magenta color hue and has excellent storage properties before recording use (shelf life).Type: GrantFiled: September 23, 1991Date of Patent: May 25, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Takekatsu Sugiyama, Sadao Ishige, Naoto Yanagihara, Hiroshi Kamikawa, Keiichi Tateishi
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Patent number: 4849323Abstract: Disclosed is a pattern forming method using contrast enhanced material for enhancing the resolution and contrast when forming patterns in fabrication of semiconductors or the like. This pattern forming method comprises a step of applying a contrast enhanced material for pattern forming on a photoresist, a step of exposing and a step of developing.The contrast enhanced material is a water-soluble material using a novel diazo compound so that the coefficient A of the contrast may be 10 or more, and when it is combined with g-line exposure to be used in pattern formation, a pattern of 0.5 .mu.m or less may be formed.Type: GrantFiled: August 10, 1987Date of Patent: July 18, 1989Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Masayuki Endo, Masaru Sasago, Kazufumi Ogawa
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Patent number: 4590263Abstract: Novel diazonium salts which possess excellent photo speed, good thermal stability, exceptional resistance to discoloration in the D.sub.min areas, rapid development, and allow a wide range of azo dye colors are provided. The diazonium salts are of the following formula: ##STR1## wherein R.sub.1 is tertiary butyl or tertiary amyl; Y is hydrogen, alkyl, hydroxyalkyl, cyanoalkyl, cycloalkyl, aralkyl, alkoxy, aryloxy, aralkoxy, aralkylthio, arylthio, alkylthio, halogen, allyl, allyloxy, allylthio, cyanoalkoxy, hydroxyalkoxy, methoxyalkoxy, trifluoroalkyl, alkylacetylamino, morpholino, or dialkyl carbonamido;R.sub.2 and R.sub.3 are the same or different, and are alkyl, aralkyl, allyl, cyanoalkyl, hydroxyalkyl, hydrogen, acyl, cycloalkyl, beta-chloroalkyl, branched alkyl, or a structure wherein R.sub.2 and R.sub.3 may be linked together to form a heterocyclic structure; andX is an anion.Type: GrantFiled: September 30, 1982Date of Patent: May 20, 1986Assignee: James River Graphics, Inc.Inventors: Robert C. Desjarlais, Everett W. Bennett
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Patent number: 4411979Abstract: A diazo type thermosensitive recording material comprising a support material and a thermosensitive recording layer formed thereon, wherein the thermosensitive recording layer comprises a diazo compound, a coupler, a thermo-fusible or thermo-softening binder agent and a thermo-fusible material. The weight ratio of the diazo compound and the thermo-fusible material is in the range of 1:2 to 1:30, and both the diazo compound and the coupler exist as separate particles in the thermosensitive recording layer.Type: GrantFiled: January 6, 1982Date of Patent: October 25, 1983Assignee: Ricoh Company, Ltd.Inventors: Masanaka Nagamoto, Yoshihiro Koseki, Susumu Iwata