Having Methine Linkage Patents (Class 430/270.18)
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Publication number: 20040086803Abstract: A non-resonant two-photon absorbing material is provided, comprising a methine dye undergoing a non-resonant two-photon absorption, in which the methine dye is preferably a cyanine dye, a merocyanine dye or an oxonol dye, and a non-resonant two-photon absorbing material is provided, comprising a non-resonant two-photon absorbing compound undergoing non-resonant two-photon absorption in the intermolecular aggregation state.Type: ApplicationFiled: October 6, 2003Publication date: May 6, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Hiroo Takizawa, Takeharu Tani, Naoki Morinaga
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Publication number: 20040048195Abstract: A heat-sensitive lithographic printing plate precursor is disclosed which comprises a hydrophilic support and a coating provided thereon, wherein the coating comprises an infrared light absorbing cyanine dye, the dye containing a bridged methine chain and from three to five groups which are anionic or which become anionic in an aqueous alkaline solution having a pH of at least 9. Such dyes provide high sensitivity and low dye stain after processing.Type: ApplicationFiled: September 3, 2003Publication date: March 11, 2004Applicant: AGFA-GEVAERTInventors: Geert Deroover, Marc Van Damme, Joan Vermeersch
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Publication number: 20040043326Abstract: An optical information recording medium has a recording layer composed essentially of an oxonol compound of the following formula: 1Type: ApplicationFiled: June 6, 2003Publication date: March 4, 2004Applicant: FUJI PHOTO FILM CO. , LTD.Inventors: Naoki Saito, Koji Wariishi, Michihiro Shibata
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Patent number: 6682799Abstract: A dye-in-polymer composition for in fluorescent WORM discs comprises about 0.1 to 10% by weight of a fluorescent dye capable of absorbing laser radiation and transforming the absorbed light into heat; about 10 to 80% by weight of nitrocellulose and a film forming polymer. The dye containing solution is applied to substrate of an optical reading medium by a spin, roller or dip coating. The method utilizes a focused laser beam for scanning the recording layer.Type: GrantFiled: April 20, 2001Date of Patent: January 27, 2004Assignee: Valdas Ltd. (A British Virgin Island Corp.)Inventors: Mark Alperovich, Irene Zuhl, Eugene Levich, Arkady Khaikin
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Patent number: 6667087Abstract: An optical information recording medium with a recording layer enables a recording and reproducing to be effected with a 650 nm (or further) laser beam, and the recording layer contains at least one kind of the trimethine-cyanine dye which is a compound represented by the following general formula [1], [2], [3], [4]. The “EWG” represents any electron-withdrawing substituted group such as cyano or nitro group.Type: GrantFiled: November 30, 2001Date of Patent: December 23, 2003Assignee: CMC Magnetics CorporationInventors: Sue-Min Yeh, Kao-Ming Chang, Wen-Pin Chiu, Lii-Chyuan Tsai
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Patent number: 6646132Abstract: An information recording medium is disclosed, comprising a substrate having provided thereon a recording layer capable of recording information by a laser ray, wherein the recording layer contains a dye compound represented by formula (I-1): wherein R1, R2, R3 and R4 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aralkyl group or a substituted or unsubstituted heterocyclic group, L1, L2 and L3 each independently represents a methine group which may have a substituent, m represents 0, 1, 2 or 3, Xk+ represents a cation and k represents an integer of from 1 to 10, provided that when m is 2 or 3, the plurality of L2 and L3 groups may be the same or different. Also disclosed is an information recording method using the above-described information recording medium.Type: GrantFiled: February 1, 2001Date of Patent: November 11, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Shin-ichi Morishima, Michihiro Shibata, Yoshihisa Usami
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Publication number: 20030162124Abstract: The present invention provides a two-photon light-emitting compound represented by formula (1), an optical data recording medium capable of recording data with a laser beam comprising a compound represented by formula (1) and a two-photon polymerizable composition photopolymerizable by two-photon absorption comprising a polymerizable monomer or polymerizable oligomer and at least a two-photon absorption material being a compound represented by formula (1):Type: ApplicationFiled: September 4, 2002Publication date: August 28, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Masaharu Akiba, Jun Kawamata
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Patent number: 6589706Abstract: A cyanine dye (I) for using in high density optical disc recording medium, having the following structure: in which R1 represents R2 represents and alkyl with C1-C18 or X− represents an acid anion. This cyanine dye is suitable for use as a &lgr;=500 nm−650 nm visible light-absorbing organic dye useful as a high density optical disc recording medium.Type: GrantFiled: November 22, 2000Date of Patent: July 8, 2003Assignees: Industrial Technology Research Institute, National Tsing-Hua UniversityInventors: Wen-Yih Liao, Andrew Teh Hu, Chien-Liang Huang, Huei-Wen Yang, Der-Ray Huang, Ding-Yih Hu, Ming-Chia Lee, Hong-Ji Lee
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Publication number: 20030113665Abstract: Optical data medium containing a preferably transparent substrate which is optionally already coated with one or more barrier layers and on the surface of which an information layer which can be recorded on using light, optionally one or more barrier layers, and a cover layer, have been applied, which data medium can be recorded on and read using focused blue light through the cover layer on the information layer, preferably laser light with the wavelength between 360 nm and 460 nm, the information layer containing a light-absorbing compound and optionally a binder, characterized in that at least one dye is used as the light-absorbing compound wherein the cover layer on the top of the information layer including the adhesive layer do have a total thickness of 10 &mgr;m to 177 &mgr;m and the numerical aperture NA of the focusing objective lens setup is greater or equal 0.8.Type: ApplicationFiled: March 20, 2002Publication date: June 19, 2003Inventors: Horst Berneth, Friedrich-Karl Bruder, Wilfried Haese, Rainer Hagen, Karin Hassenruck, Serguei Kostromine, Peter Landenberger, Rafael Oser, Thomas Sommermann, Josef-Walter Stawitz, Thomas Bieringer, Yuichi Sabi, Sakuya Tamada, Masanobu Yamamoto
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Patent number: 6531261Abstract: An optical information recording disc showing good recording characteristics is prepared by the steps of coating a dye solution of a laser light-sensitive dye in a fluorinated cyclic alkane or alkene on a transparent substrate disc and drying the coated dye solution. The fluorinated cyclic alkane or alkene can be employed in combination with other organic solvents.Type: GrantFiled: May 26, 2000Date of Patent: March 11, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshihisa Usami, Yoshio Inagaki
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Patent number: 6525181Abstract: The object of the present invention is to provide organic dye compounds which exert satisfactory optical absorption properties and thermal resistance when used in high density optical recording media. The above object is solved by specific trimethine cyanine dyes, light absorbents and optical recording media which comprise the cyanine dyes, and preparations for the cyanine dyes comprising either reacting a benzoindolium compound having a compatible leaving group with a pyrazinoimidazolium compound having a reactive methyl group; or reacting a benzoindolium compound having a reactive methyl group with a pyrazinoimidazolium compound having a compatible leaving group.Type: GrantFiled: October 23, 2001Date of Patent: February 25, 2003Assignee: Kabushiki Kaisha Hayashibara Seibutsu Kagaku KenkyujoInventors: Chiaki Kasada, Katsumi Orita, Kentaro Yano, Toshio Kawata, Shigeo Yasui
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Patent number: 6524678Abstract: An optical information recording medium comprising a substrate having thereon a recording layer capable of information recording by laser irradiation, wherein said recording layer contains a dye compound represented by the following formula (I), (II) or (III): R11R12N+═L11—L12═L13—NHR13.(1/m)(X1)m− (I) R21R22N—L21═L22—L23═NR23 (II) R31R32N+═L32═L33—NR33R34.(1/n)(X3)n− (III). The meanings of the symbols are defined and explained in the specification. Also discussed is a method for recording information using the optical information recording medium.Type: GrantFiled: February 16, 2001Date of Patent: February 25, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoki Saito, Yoshihisa Usami, Noboru Komori
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Publication number: 20030022105Abstract: The present invention is directed to styryl dyes having the formula: 1Type: ApplicationFiled: November 16, 1999Publication date: January 30, 2003Inventors: PARAS N. PRASAD, JAYANT D. BHAWALKAR, PING CHENG, SHAN JEN PAN
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Publication number: 20030013041Abstract: Optical data carrier comprising a preferably transparent substrate which may, if desired, have previously been coated with one or more reflection layers and to whose surface a light-writeable information layer, if desired one or more reflection layers and if desired a protective layer or a further substrate or a covering layer have been applied, which can be written on or read by means of blue, red or infrared light, preferably laser light, where the information layer comprises a light-absorbent compound and, if desired, a binder, characterized in that at least one cationic aminoheterocyclic dye is used as light-absorbent compound.Type: ApplicationFiled: March 20, 2002Publication date: January 16, 2003Inventors: Horst Berneth, Friedrich-Karl Bruder, Wilfried Haese, Rainer Hagen, Karin Hassenruck, Serguei Kostromine, Peter Landenberger, Rafael Oser, Thomas Sommermann, Josef-Walter Stawitz, Thomas Bieringer
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Publication number: 20030003396Abstract: Optical data carrier comprising a preferably transparent substrate which may, if desired, have previously been coated with one or more reflection layers and to whose surface a light-writeable information layer, if desired one or more reflection layers and if desired a protective layer or a further substrate or a covering layer have been applied, which can be written on or read by means of blue, red or infrared light, preferably laser light, where the information layer comprises a light-absorbent compound and, if desired, a binder, characterized in that at least one merocyanine dye is used as light-absorbent compound.Type: ApplicationFiled: March 20, 2002Publication date: January 2, 2003Inventors: Horst Berneth, Friedrich-Karl Bruder, Wilfried Haese, Rainer Hagen, Karin Hassenruck, Serguei Kostromine, Peter Landenberger, Rafael Oser, Thomas Sommermann, Josef-Walter Stawitz, Thomas Bieringer
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Patent number: 6383722Abstract: An object of the invention is to provide a method for preparing an optical recording medium, featuring a high production yield, a reduced loss and a high utilization of dye solution, and ensuring to produce media of consistent quality even by continuous coating as well as an optical recording medium. The object is achieved by a method for preparing an optical recording medium, comprising the step of applying a solution of a dye in a solvent onto a resin substrate to form a dye film, wherein the solvent of the dye solution is a mixture of tetrafluoropropanol and/or octafluoropentanol with an aliphatic saturated alcohol of 1 to 4 carbon atoms, and a recording layer is formed by applying the dye solution.Type: GrantFiled: May 26, 1999Date of Patent: May 7, 2002Assignee: TDK CorporationInventors: Masahiro Shinkai, Atsushi Monden
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Patent number: 6379768Abstract: An optical information recording medium composed of a substrate and a recording layer having a dye compound of the formula (I): R1R2C═L1—L2═L3—NR3R4 (I) in which each of R1 and R2 is an electron-attracting group (i.e., electron-withdrawing group) having a Hammett's substituent constant &sgr;p in the range of 0.2 to 0.Type: GrantFiled: September 8, 2000Date of Patent: April 30, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoki Saito, Yoshihisa Usami, Noboru Komori
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Publication number: 20020009669Abstract: An information recording medium is disclosed, comprising a substrate having provided thereon a recording layer capable of recording information by a laser ray, wherein the recording layer contains a dye compound represented by formula (I-1): 1Type: ApplicationFiled: February 1, 2001Publication date: January 24, 2002Inventors: Shin-ichi Morishima, Michihiro Shibata, Yoshihisa Usami
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Publication number: 20020001774Abstract: A hemicyanine dye having formula (1) and an optical recording medium using the hemicyanine dye as an optical recording medium are provided: 1Type: ApplicationFiled: April 3, 2001Publication date: January 3, 2002Inventors: Jong-tae Je, Kyu-youn Lee, Young-jae Huh
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Publication number: 20010044074Abstract: Disclosed are novel trimethine cyanine dyes, light absorbents, light-resistant improvers, and optical recording media which comprise the trimethine cyanine dyes. The cyanine dyes exert satisfactory solubility and heat resistance when used in high-density optical recording media.Type: ApplicationFiled: February 12, 2001Publication date: November 22, 2001Inventors: Ayako Hohsaka, Dai Matsuura, Toshio kawata, Shigeo Yasui
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Patent number: 6306478Abstract: An optical recording layer of an optical recording medium comprises a dye material represented by the formula (I), wherein R1 is a hydrogen atom, a methyl group, or an ethyl group, R2 and R3 each is, independent from each other, a substituted or unsubstituted C1 to C12 alkyl group, A⊖ is an anion selected from the group consisting of halogen atoms, ClO4⊖, BF4⊖, PF6⊖, SbF6⊖, CF3SO2⊖, C2F5SO3⊖, CF3COO⊖, and CH3C6H4SO3⊖, X is hydrogen, alkyl, alkoxy, halogen, nitro, or fused benzene, Y is hydrogen, alkoxy, halogen, alkyl, aryl, alkoxycarbonyl, aryloxycarbonyl, alkylamine, arylamine, alkylamide, arylamide, alkylsulfonyl, aryl sulfonyl, alkoxysulfonyl, aryloxysulfonyl, nitro, or cyano groups.Type: GrantFiled: January 6, 2000Date of Patent: October 23, 2001Assignee: Ritek CorporationInventors: Hui-jen Chen, Chang-sheng Huang, Mei-jung Hu, Yi-shiu Lin, Shyh-yeu Wang, Chwei-jin Yeh
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Patent number: 6270940Abstract: A laser ablative recording material having on a support a coloring agent layer containing a fluorine-containing surfactant, in which the fluorine-containing surfactant is a copolymer made of: (Condition I) either or both of acrylate having a fluoroaliphatic group and methacrylate having a fluoroaliphatic group (the fluoroaliphatic group herein includes 3 to 20 carbon atoms and fluorine atoms of 40% or more by weight where a half or above of atoms bonded to three carbon atoms constituting terminal portions are fluorine atoms.); and (Condition II) either or both of poly(oxyalkylene) acrylate and poly(oxyalkylene) methacrylate, wherein monomer units according to Condition I are 20 to 80 percent by weight of the copolymer is disclosed. This laser ablative recording material has features of a uniform surface state and a uniform film thickness profile, a small Dmin of the laser exposure portion, and smaller deviations in a maximum density.Type: GrantFiled: May 11, 1998Date of Patent: August 7, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Takahiro Goto
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Patent number: 6242067Abstract: In an optical recording medium using writing and reading light having a wavelength of up to 690 nm and having a recording layer and preferably a reflective layer, the recording layer contains a chelate compound having an azo compound of specific structure as a ligand (i.e., azo metal complex dye). This results in an optical recording medium of the heat mode having advantages including the dye's sufficient solubility in a coating solvent which does not attack polycarbonate substrates and improved write/read characteristics with light having a wavelength of up to 690 nm.Type: GrantFiled: October 19, 1999Date of Patent: June 5, 2001Assignee: TDK CorporationInventors: Emiko Kambe, Atsushi Monden
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Patent number: 6228440Abstract: A perishable media information storage mechanism, including a substrate, a data layer for recording data thereon the information storage mechanism, a reflective layer, and a protective lacquer coating. The data layer includes a material responsive to at least one predetermined data elimination factor and includes one of a decayable dye material, a liquid crystal material, a photosensitive material or a plurality of magnetoresistive memory cells. The data layer is characterized as recording data and eliminating access to data in response to at least one of a predetermined use or time factor. In addition, included is a method for fabricating a perishable media information storage mechanism including the steps of providing a substrate, forming a data layer on a surface of the substrate, forming a reflective layer on an uppermost surface of the data layer, and forming a protective coating on an uppermost surface of the reflective layer.Type: GrantFiled: July 28, 1998Date of Patent: May 8, 2001Assignee: Motorola, Inc.Inventors: Conan B. Dailey, Michael S. Lebby
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Patent number: 6228455Abstract: A structure of an optical recording medium that mainly includes a first dielectric layer, a dye layer, a second dielectric layer, and a reflective layer formed on a substrate in sequence, and a method for fabricating an optical recording medium of the foregoing structure. The additional dielectric layers of the optical recording medium, instead of a quencher used in a conventional optical recording medium, increase the lifetime of a dye layer and reduce the fabrication cost. Furthermore, the additional dielectric layers are capable of isolating the dye layer from oxygen and moisture to enhance the lightfastness of the dye layer.Type: GrantFiled: February 12, 1999Date of Patent: May 8, 2001Assignees: Industrial Technology Research Institute, CMC Magnetics Co.Inventors: Chien-Liang Huang, Wen-Yih Liao, Chin-Sen Chen, Don-Yau Chiang, Der-Ray Huang, Lii-Chyuan Tsai, Tsai-Chu Hsiao
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Patent number: 6225024Abstract: An information recording medium is disclosed, comprising a substrate having provided thereon a recording layer capable of recording information by a laser ray, wherein the recording layer contains a dye compound represented by formula (I-1): wherein R1, R2, R3 and R4 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aralkyl group or a substituted or unsubstituted heterocyclic group, L1, L2 and L3 each independently represents a methine group which may have a substituent, m represents 0, 1, 2 or 3, Xk+ represents a cation and k represents an integer of from 1 to 10, provided that when m is 2 or 3, the plurality of L2 and L3 groups may be the same or different. Also disclosed is an information recording method using the above-described information recording medium.Type: GrantFiled: June 2, 1999Date of Patent: May 1, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Shin-ichi Morishima, Michihiro Shibata, Yoshihisa Usami
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Patent number: 6168844Abstract: By keeping the imaginary number portion k of the complex index of refraction of the film of the light absorbing layer 3, the mean film thickness dav of the light absorbing layer 3, and the absorbency A related thereto within an appropriate range, the present invention provides an optical information recording medium with good recording sensitivity and playback properties, which makes possible high speed recording by increasing the sensitivity to the recording beam and stable recording with sufficient reflectivity, and which can reduce jitter. In the present invention, 0.13≦A≦0.21 where A (Abs) is the absorbency of the light absorbing layer at the wavelength of the recording beam; and 6.0≦k.dav≦12.0 where k is the imaginary number portion of the complex index of refraction of the film in the light absorbing layer and dav (nm) is the mean film thickness of the light absorbing layer, at the wavelength of the recording beam.Type: GrantFiled: August 3, 1998Date of Patent: January 2, 2001Assignee: Taiyo Yuden Co., Ltd.Inventors: Yoshikazu Takagishi, Takanori Yoshizawa, Emiko Hamada