Developing Patents (Class 430/434)
  • Patent number: 5618657
    Abstract: A photographic element comprises a polyester support bearing a light-sensitive silver halide photographic emulsion layer, the support having adjacent thereto a polymer-containing subbing layer, the subbing layer having adjacent thereto a layer comprising a hydrophilic binder containing dispersed droplets of a high boiling organic liquid, the liquid being selected form the group consisting of oleyl alcohol and esters of organic or inorganic acids which have a value for the logarithm of their octanol/water partition coefficient (Log P) of from 2.6 to 6.7.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: April 8, 1997
    Assignee: Eastman Kodak Company
    Inventors: John B. Rieger, Paul L. Zengerle, John W. Boettcher
  • Patent number: 5618661
    Abstract: A method for processing a silver halide photographic light-sensitive material by an automatic processor is disclosed. The processing method comprises the steps of (1) developing a silver halide photographic light-sensitive material with a developer being in a developing tank of said automatic processor while replenishing a developer replenisher in a rate of from 50 ml to 330 ml per square meter of the light-sensitive material processed and (2) fixing said developed silver halide photographic light-sensitive material with a fixer being in a fixing tank of said automatic processor while replenishing a fixer replenisher in a rate of from 50 ml to 330 ml per square meter of the light-sensitive material. The light-sensitive material comprises a support and at least one silver halide emulsion layer provided on a surface of a support which is a stretched film composed of a styrene copolymer having a syndiotactic structure or a composition containing said styrene copolymer.
    Type: Grant
    Filed: October 31, 1995
    Date of Patent: April 8, 1997
    Assignee: Konica Corporation
    Inventor: Takeshi Sampei
  • Patent number: 5607815
    Abstract: Disclosed are silver halide elements that contain an arylhydrazine compound useful in producing high contrast images. The elements can be handled in bright light room conditions for extended periods of time without increasing minimum density of the element.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: March 4, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Julie C. Bishop, John R. Shock
  • Patent number: 5582959
    Abstract: An image-forming method comprising processing an imagewise exposed silver halide photographic material for a laser scanner comprising a transparent support having thereon at least one silver halide emulsion layer comprising a silver halide emulsion having a silver chloride content of .gtoreq.90 mol % spectrally sensitized to a range of .gtoreq.600 nm. Processing comprises developing in a developing bath and fixing in a fixing bath, wherein the photographic material contains one or both of a conductive metal oxide and a conductive polymer; the developing bath and the fixing bath are each replenished in an amount of .ltoreq.200 ml per m.sup.2 of the photographic material processed; the processing is carried out in an automatic developing machine. Further, an image-forming method, wherein the photographic material contains a polyoxyethylene nonionic surface active agent and a fluorine-containing surface active agent each having a solubility of .ltoreq.0.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 10, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadashi Ito
  • Patent number: 5571660
    Abstract: A method of forming an image is disclosed, comprising imagewise-exposing a silver halide photographic light sensitive material and developing the exposed photographic material to form a high contrast image, wherein said silver halide photographic material contains a spectral sensitizing dye represented by the following formula [S], and wherein said photographic material is developed with a developer having a pH of 10.9 or less, said developer being replenished by a developer-replenishing solution having a pH value of 10.9 or less in an amount of 300 ml or less per m.sup.2 of the photographic material. The photographic material further contains a hydrazine compound and a nucleation-accelerating agent.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: November 5, 1996
    Assignee: Konica Corporation
    Inventors: Hirohide Ito, Takeo Arai
  • Patent number: 5565307
    Abstract: Disclosed are a silver halide photographic material containing at least one merocyanine color-sensitizing dye having a particular structure of formula (I) ##STR1## wherein R.sub.1 and R.sub.2 each represent an alkyl group having a residue capable of making the compound soluble in water as a free acid or salt; V.sub.1, V.sub.2, V.sub.3 and V.sub.4 each represent a hydrogen atom or a monovalent substituent, provided that these substituents (V.sub.1, V.sub.2, V.sub.3, V.sub.4) are not bonded to each other to form a ring and that the sum of the molecular weights of V.sub.1, V.sub.2, V.sub.3 and V.sub.4 is from 4 to 50; L.sub.1, L.sub.2, L.sub.3 and L.sub.4 each represent an optionally substituted methine group; M.sub.1 represents a charge-neutralizing pair ion; and m.sub.1 represents a number of from 0 to 4 that is necessary for neutralizing the intramolecular charge.
    Type: Grant
    Filed: April 18, 1995
    Date of Patent: October 15, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Toyohisa Oya, Seiichi Yamamoto
  • Patent number: 5561028
    Abstract: Provided is a silver halide photographic photosensitive material excellent in rapid processability and having high processing stability which contains at least one compound represented by the following formula (I) and (II): ##STR1## wherein L.sup.1 and L.sup.2 each represent a divalent linkage group, G.sup.1 and G.sup.2 each represent a carbonyl group, a sulfonyl group, a sulfinyl group, an oxalyl group or a phosphoryl group, R.sup.1 and R.sup.2 each represent a hydrogen atom, an alkyl group, an aralkyl group, an alkenyl group or an aryl group, R.sup.3 and R.sup.5 each represent an alkyl group, an aralkyl group or an alkenyl group, R.sup.4 and R.sup.6 each represent a hydrogen atom, an alkyl group, an alkoxy group, an aryloxy group, an aryl group or an amino group, Z represents a group of atoms necessary to form a nitrogen-containing 5- to 18-membered ring, X represents a counter ion, and m and n each represent 0 or 1, and the isothioureido group may be a salt of a protonic acid.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: October 1, 1996
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Ko-ichi Sumioka, Akira Tanaka
  • Patent number: 5492799
    Abstract: The invention provides a photographic element comprising a support bearing a light-sensitive photographic silver halide layer having associated therewith a masking coupler comprising:(1) a parent group containing a -1-phenyl-3-anilinopyrazolin-5-one having electron-withdrawing substituents on the phenyl and anilino rings of a type and number sufficient to provide a combined Hammett sigma(para) value for such substituents of at least 1.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: February 20, 1996
    Assignee: Eastman Kodak Company
    Inventors: Daniel L. Kapp, Robert J. Ross, Stephen P. Singer, Bernard A. Clark
  • Patent number: 5478696
    Abstract: A silver halide photographic light-sensitive material is disclosed. the light-sensitive material comprises a support bearing on the same side thereof a silver halide emulsion layer and optionally a hydrophilic colloid layer, and at least one of the silver halide emulsion layer or the hydrophilic colloid layer contains a hydrazine derivative in a form of dispersion of solid particles and at least one of the silver halide emulsion layer or the hydrophilic colloid layer contains a nucleation accelerator represented by the following formula 1; ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently a hydrogen atom, a substituted or unsubstituted alkyl group, an substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group, provided that R.sub.1, R.sub.2 and R.sub.3 are not a hydrogen atom at the same time and two of R.sub.1, R.sub.2 and R.sub.3 may link to form a ring.
    Type: Grant
    Filed: November 21, 1994
    Date of Patent: December 26, 1995
    Assignee: Konica Corporation
    Inventor: Takeo Arai
  • Patent number: 5478704
    Abstract: i) A method of forming color images improved in color reproducibility and sharpness, which comprises providing a silver halide color photographic material which has on a support at least one emulsion layer unit constituted of at least two silver halide emulsion layers having the same color sensitivity and different photographic speeds, and which contains at least one DIR compound represented by the following general formula (II) in at least one layer selected from said emulsion layer unit and other constituent layers; exposing said color photographic material, and processing said color photographic material with a color developer containing at least one compound represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an alkyl group or a hydroxyalkyl group containing; R.sub.2 represents an alkylene group containing, or a straight-chain or branched hydroxyalkyiene group containing 3 to 6 carbon atoms; R.sub.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: December 26, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masato Taniguchi, Nobutaka Ohki, Mitsuru Yamamoto, Akimitsu Haijima
  • Patent number: 5464730
    Abstract: Disclosed is a method of developing a transmission black-and-white silver halide photographic material with an automatic processor, in which a developer having a bromide ion concentration of 0.01 mol/liter or less and having a pH value of 9.8 or less is used with replenishment of the developer being in an amount of about 200 ml or less per m.sup.2 of the material being processed. Though the amount of the replenisher to the developer used is small in the method, the photographic properties of the processed material are stable and the processed material is fogged little.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: November 7, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Okutsu, Takashi Toyoda, Tadashi Ito
  • Patent number: 5462831
    Abstract: To eliminate the "pi-line" artifact after processing a method of image formation is disclosed in a silver halide industrial X-ray photographic material, comprising on at least one side of a support, at least one gelatin silver halide emulsion layer and a total amount of silver halide, corresponding to from 6 to 20 g of silver nitrate per square meter and per side, and at least one non-sensitive protective antistress coating, wherein said material further comprises a hardening agent different from a vinyl sulphone compound, preferably formaldehyde, and at least one polyoxyalkylene compound as a surfactant in at least one of its hydrophilic layers, and wherein after exposure to direct X-rays said material is subjected in an automatic processing machine to the steps of developing in a developer comprising at least one anionic alkylphenoxy polyalkyleneoxy phosphate ester surfactant, fixing in a fixer which may comprise at least one alpha-ketocarboxylic acid, rinsing and drying.
    Type: Grant
    Filed: April 5, 1994
    Date of Patent: October 31, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Benedictus Jansen, Andre Roefs, Francis Sels, Pieter Perdieus, Raymond Florens
  • Patent number: 5455146
    Abstract: A method for forming a color image of a color negative photographic material which comprises subjecting a color negative photographic material to a color development processing, said color negative photographic material comprising a support having provided thereon at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer, having a specific photographic sensitivity of 100 or more and having each of the gradients .gamma..sub.AR, .gamma..sub.AG and .gamma..sub.AB of 0.5 to 0.9 after standard color development processing within the range of from 3 minutes to 4 minutes of the color development time, said gradients .gamma..sub.AR, .gamma..sub.AG and .gamma..sub.AB each being a gradient of the red-sensitive, green-sensitive and blue-sensitive silver halide emulsion layers, respectively, obtained after conducting the standard color development processing, wherein each of the gradients .gamma..sub.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: October 3, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihiro Nishikawa, Hiroshi Fujimoto
  • Patent number: 5447817
    Abstract: To eliminate the "pi-line" artefact after processing a method of image formation in a silver halide industrial X-ray photographic material is disclosed wherein said material comprises on at least one side of a support, at least one gelatino silver halide emulsion layer and a total amount of silver halide, corresponding to from 6 to 20 g of silver nitrate per square meter and per side, and at least one non-sensitive protective antistress coating and wherein said method proceeds by the steps of exposing said material to direct X-rays and processing the material in an automatic processing machine by development, fixing, rinsing and drying, characterized in that said material further comprises at least one vinyl sulphone compound as a hardening agent in at least one of its hydrophilic layers, that development occurs in a developer comprising as a surfactant at least one anionic alkylphenoxy and/or alkoxy polyalkyleneoxy phosphate ester, sulphate ester, alkyl carboxylic, sulphonic or phosphonic acid and/or a salt
    Type: Grant
    Filed: April 5, 1994
    Date of Patent: September 5, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Raymond Florens, Pieter Perdieus, Peter Willems, Freddy Henderickx
  • Patent number: 5447827
    Abstract: A photographic processing method for developing a film having been photographed, printing the developed film on a photographic paper and developing the photographic paper, the film being accommodated in a cartridge and set in a predetermined position of a photographic processing apparatus. The method includes the steps of: (a) providing the film or the cartridge with an ID number for identifying the film; (b) making an index print in which respective images of a plurality of frames of the film are arranged in numeral order of the film; and (c) providing the index print with the ID number read from the film or the cartridge. With this method, one is able to find out in which film and in which frame of the film an image desired to be copy-printed is present.
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: September 5, 1995
    Assignee: Noritsu Koki Co., Ltd.
    Inventors: Masazumi Ishikawa, Toru Tanibata
  • Patent number: 5437733
    Abstract: A plane of a treatment liquid holder having a number of through holes faces a treatment surface of a substrate. A treatment liquid is held between the treatment surface and the liquid holder by utilizing a surface tension of the treatment liquid. Since the treatment liquid is applied only to the treatment surface, an extremely small amount of treatment liquid suffices for the treatment. In addition, since a fresh treatment liquid can be used in every treatment, cross-contamination is suppressed and the treatment can be performed with safety at a low cost.
    Type: Grant
    Filed: October 17, 1991
    Date of Patent: August 1, 1995
    Assignee: Kabushiki Kaisha Toshiba
    Inventor: Katsuya Okumura
  • Patent number: 5427897
    Abstract: A method for processing an imagewise exposed silver halide color photographic material comprising a support having thereon at least a silver halide emulsion layer containing a cyan dye-forming coupler, a silver halide emulsion layer containing a magenta dye-forming coupler, and a silver halide emulsion layer containing a yellow dye-forming coupler: wherein the silver halide color photographic material contains at least one cyan dye-forming coupler represented by the following general formula (I) or (II) in the silver halide emulsion layer containing the cyan dye-forming coupler: and wherein the processing comprises color developing the imagewise exposed silver halide color photographic material with a color developer containing a p-phenylenediamine derivative represented by the following general formula (III): ##STR1## wherein the substituents are defined herein the specification.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: June 27, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Nakamura, Masato Taniguchi
  • Patent number: 5422224
    Abstract: A photographic material comprises a support and at least one photosensitive layer which comprises a non-chemically sensitized silver halide emulsion containing at least 80 mol % silver chloride based upon the total amount of silver halide in the emulsion. The photosensitive layer or another hydrophilic colloid layer comprises a hydrazine derivative represented by the following General Formula (I): ##STR1## In this formula A.sub.1 and A.sub.2 both represent hydrogen atoms, or one represents a hydrogen atom and the other represents a sulfinic acid group or an acyl group; R.sup.1 represents an aliphatic group, an aromatic group or a heterocyclic group, and R.sup.1 may or may not be substituted; G represents --CO--, --SO.sub.2 --, --SO--, --COCO--, thiocarbonyl, iminomethylene or --P(O)(R.sup.4) group; R.sup.2 represents a substituted or unsubstituted alkyl group, aryl group, heterocyclic group, amino group, alkoxy group or aryloxy group; at least one of R.sup.1 and R.sup.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: June 6, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazunobu Katoh
  • Patent number: 5405732
    Abstract: A process for processing a black-and-white silver halide photographic light-sensitive material is disclosed, the material comprising a photographic component layer containing a hydrazine compound, and the process comprising the step of exposing the light-sensitive material, and developing the exposed material with developer having a pH of not more than 10.7, the developer being prepared from a solid developing composition and the developer being replenished with developer replenisher in an amount of not more than 250 cc per m.sup.2 of the light-sensitive material to be developed.
    Type: Grant
    Filed: January 5, 1994
    Date of Patent: April 11, 1995
    Assignee: Konica Corporation
    Inventors: Akira Shimizu, Shoji Nishio, Takeshi Sanpei, Hiroyuki Ushiroyama
  • Patent number: 5397687
    Abstract: The preparation of x-ray materials, especially suitable for non-destructive testing applications, is described. The emulsion layers of said material are comprising silver halide emulsion grains containing at least 75 mole % of silver chloride and less than 25 mole % of silver bromide and are characterized by a ratio between the amount of gelatin and the amount of silver halide, being expressed as the equivalent amount of silver nitrate, of less than 0.6. Hardening of said material is performed in such a way that the amount of demineralized water of 25.degree. C. absorbed in 3 minutes is less than 2.5 g per gram of gelatin present in said material. A rapid processing system is available with a total processing time of less than 3 minutes with a developer and fixer being substantially free from hardening agents and the fixer being substantially free from ammonium ions.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: March 14, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Peter Willems, Freddy Henderickx, Gino De Rycke, Romain Bollen
  • Patent number: 5395742
    Abstract: There is disclosed a novel diaminostilbene series compound, a method for forming an image using the same, and a composition comprising the same. The diaminostilbene compound is represented by the following formula (I): ##STR1## wherein L.sup.1 and L.sup.2, which are the same or different, each represent --OR.sup.1 or --N--R.sup.2 (R.sup.3), wherein the four substituents L.sup.1 and L.sup.2 have four or more substituents in total selected from substituents represented by the following formula (II);R.sup.1 and R.sup.2 each represent a hydrogen atom, an alkyl group, or an alkyl group having a substituent selected from substituents represented by the formula (II);R.sup.3 represents an alkyl group or an alkyl group having a substituent selected from substituents represented by the formula (II); andM represents a hydrogen atom, an alkali metal, an ammonium, or a pyridinium:formula (II)--SO.sub.3 M, --OSO.sub.3 M, --COOM, and --NR.sub.
    Type: Grant
    Filed: May 16, 1994
    Date of Patent: March 7, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuaki Deguchi, Toshiaki Kubo
  • Patent number: 5391467
    Abstract: A method for continuously processing a silver halide color photographic photosensitive material by treating this material with a color developer containing at least one aromatic primary amine color developing agent, comprises the steps of covering the surface of a color developer replenisher in a color developer replenisher tank with a layer of a floating fluid and replenishing 20 to 100 ml of the color developer replenisher per m.sup.2 of the photosensitive material to a color developing tank. This method makes it possible to inhibit the formation of the precipitate in the color developer replenisher caused when the amount of the replenisher is considerably reduced and also to inhibit the change of the photographic characteristics by change of the amount of the processed photosensitive material so that the amount of the color developer replenisher can be remarkably reduced to the range of 20 to 100 ml per square meter of the photosensitive material and that of the waste water can be also remarkably reduced.
    Type: Grant
    Filed: June 8, 1994
    Date of Patent: February 21, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuaki Yoshida, Akira Abe
  • Patent number: 5389506
    Abstract: A process of producing a viewable photographic image is disclosed wherein an imagewise exposed photographic element containing at least two silver halide emulsion layers capable of recording within the same region of the spectrum and having differing threshold sensitivities produces during photographic processing spectrally distinguishable images. Separate image records are obtained from the emulsion layers, and the image record corresponding to the photographically superior image is preferentially employed in producing a viewable image.
    Type: Grant
    Filed: August 25, 1993
    Date of Patent: February 14, 1995
    Assignee: Eastman Kodak Company
    Inventor: James E. Sutton
  • Patent number: 5382496
    Abstract: There is disclosed a silver halide light-sensitive material and a method for forming image using thereof, in which a high contrast negative image useful in a photographic plate making process can be obtained in a processing solution with a pH lower than 11.0. The silver halide light-sensitive material comprises a support having provided thereon at least one silver halide emulsion layer and containing a hydrazine derivative in the above emulsion layer and/or a layer adjacent thereto. At least one compound represented by the following Formula (I) or (II) is contained in the above emulsion layer and/or a layer adjacent thereto: ##STR1## wherein A represents an organic group necessary for completing a hereto ring; B and C each represents a group constituted of one or more members selected from the group consisting of an alkylene group, an arylene group, an alkenylene group, --SO.sub.2 --, --SO--, --O--, --S--, and --N(R.sub.5)--, where R.sub.5 represents an alkyl group, an aryl group, or a hydrogen atom; R.sub.
    Type: Grant
    Filed: December 7, 1993
    Date of Patent: January 17, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Sakai, Kazunobu Katoh, Kiyoshi Morimoto
  • Patent number: 5380636
    Abstract: The present invention relates to a symmetrical radiographic assembly comprising:a double side radiographic element which comprises a support and hydrophilic colloid layers coated on each side of said support, andan intensifying screen adjacent to each side of said radiographic element,wherein on each side of said support are coated at least two silver halide emulsion layers having a speed difference of at least 0.5 logE and an average contrast difference of at least 0.
    Type: Grant
    Filed: September 2, 1993
    Date of Patent: January 10, 1995
    Assignee: Minnesota Mining & Manufacturing Company
    Inventors: Pierfiore Malfatto, Sergio Pesce, Elio Cavallo
  • Patent number: 5380637
    Abstract: A silver halide photographic material is disclosed in which a matting agent contained in a coating solution is prevented from settling in solution and peeling off during processing. The silver halide photographic material contains at least one light-sensitive emulsion and at least one surface protective layer on a support. The surface protective layer contains a polymer latex having an average particle size of up to 2 .mu.m and a perticular precipitation amount as measured in a test coating solution or a crosslinked polymer latex having a hydrophilic group.
    Type: Grant
    Filed: October 19, 1993
    Date of Patent: January 10, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Yamashita, Jun Kawagoe, Ichizo Toya
  • Patent number: 5356761
    Abstract: Development of silver halide photosensitive material with a developer containing a developing agent and a free sulfite is accompanied by deposition of silver sludge. Silver sludge is effectively suppressed by adding to the developer (a) a six-membered heterocyclic compound which has a six-membered ring containing two nitrogen atoms and has a mercapto group, a hydroxyl group and one or two substituents having 2 to 20 carbon atoms in total or (a') a six-membered heterocyclic compound which has a six-membered ring containing three nitrogen atoms and has a mercapto group and a hydroxyl group.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: October 18, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyoshi Morimoto, Hiroshi Hayakawa, Takashi Toyoda, Mitsunori Hirano
  • Patent number: 5344750
    Abstract: A color development process for processing an imagewise exposed silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer comprising a color coupler and a silver iodobromide emulsion containing silver iodide in an amount of from 2 to 20 mol %, comprising the step of processing the color photographic material in a color developing solution containing a color developing agent and bromide ion for 40 seconds to 90 seconds, wherein the color developing agent is represented by formula (D'): ##STR1## wherein R.sub.1d, and R.sub.2d, each represents an alkyl group having 1 to 4 carbon atoms; and L.sub.1 represents a straight-chain or branched alkylene group having 3 or 4 carbon atoms, the concentration {Br.sup.- } of bromide ion in the color developing solution is from 30 to 60 mmol/l, the relationship between the concentration {R} of the color developing agent in the color developing solution and the concentration {Br.sup.
    Type: Grant
    Filed: May 11, 1993
    Date of Patent: September 6, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Fujimoto, Masato Taniguchi
  • Patent number: 5342741
    Abstract: A developer composition having improved stability to aerial oxidation, which contains at least one compound represented by formulae (A) and (B): ##STR1## where R.sub.1 and R.sub.2 each represent a hydroxyl group, an amino group, an acylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, an alkoxycarbonylamino group, a mercapto group or an alkylthio group; and X represents a group of atoms selected from carbon and nitrogen which forms a 5-membered or 6-membered ring together with the two vinyl carbons substituted by R.sub.1 and R.sub.2, respectively, and the carbonyl carbon of formula (A); ##STR2## where R.sub.3 and R.sub.
    Type: Grant
    Filed: July 9, 1993
    Date of Patent: August 30, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyoshi Morimoto, Shin-ichi Morishima, Hiroshi Hayakawa
  • Patent number: 5340704
    Abstract: Disclosed is a photographic image forming method. A silver halide photographic material is processed with a developing solution having a pH of 9.6 to 11.0. The silver halide photographic material has at least one light-sensitive layer containing a chemically-sensitized silver halide emulsion comprising silver halide grains having a silver chloride content of at least 60 mol %. At least one of said at least one light-sensitive layer and a light-insensitive hydrophilic colloid layer contains a hydrazine compound represented by the formula (1):R.sup.1 --NHNH--G--R.sup.2 (1).The variables in the formula are defined in the specification.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: August 23, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihide Ezoe, Kazumi Nii, Hisashi Okamura
  • Patent number: 5328801
    Abstract: A method for forming an image is disclosed, which comprises processing with a developer having a pH value of 9 to 12 and comprising 0.2 mol/liter or more of a sulfite an imagewise exposed silver halide photographic material comprising a compound represented by formula (I): ##STR1## wherein Het represents a group represented by formula (II) and the remaining terms are as defined in the specification: ##STR2## wherein the terms are as defined in the specification. In a preferred embodiment, the compound represented by formula (I) is a compound represented by formula (III): ##STR3## wherein the terms are as defined in the specification. The light-sensitive material may comprise a hydrazine derivative in addition to the compound represented by formula (I) or (III).
    Type: Grant
    Filed: March 6, 1992
    Date of Patent: July 12, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shoji Yasuda, Kazunobu Katoh, Hisashi Okamura
  • Patent number: 5324622
    Abstract: The present invention provides a photographic material comprising on a support (i) photosensitive silver halide particles, (ii) substantially light insensitive silver salt particles having a speed at least a factor 10 less than said photosensitive silver halide particles under the same conditions of exposure and development of said photosensitive silver halide particles and (iii) a releasing compound capable of image-wise releasing under the conditions for image-wise development of said photosensitive silver halide to silver a chemical sensitizer, said chemical sensitizer rendering said substantially light insensitive silver salt particles developable. The present invention also provides a method for making an image therewith and a method for making a lithographic printing plate.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: June 28, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ludo L. Van Rompuy, Jean-Marie O. Dewanckele, Jos A. Vaes, Marcel J. Monbaliu
  • Patent number: 5318881
    Abstract: This invention relates to a method of processing an image-wise exposed silver halide photographic material wherein said method comprises the following steps:(a) developing the photographic material for 5 to 15 seconds in an aqueous developing solution,(b) fixing the photographic material for 5 to 15 seconds in an aqueous fixing solution, and(c) washing the photographic material for 5 to 20 seconds,wherein both said developing and fixing solutions are free of gelatin hardeners.The method is particularly intended for use in processing radiographic films which:comprise a support and silver halide emulsion layer or layers, at least one of said silver halide emulsion layers containing tabular silver halide grains having an average diameter to thickness ratio of at least 3:1 and highly deionized gelatin, andshow a swelling index lower than 140% and a melting time of from 45 to 120 minutes.The method shows the advantages of lower environmental pollution and shorter processing times.
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: June 7, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Marco Bucci, Carlo Marchesano, Dino Ferrari, Carlo Illuminati
  • Patent number: 5314794
    Abstract: A process of producing a viewable photographic image is disclosed wherein an imagewise exposed photographic element containing at least two silver halide emulsion layers capable of recording within the same region of the spectrum and having differing threshold sensitivities produces during photographic processing spectrally distinguishable images. Separate image records are obtained from the emulsion layers, and the image record corresponding to the photographically superior image is preferentially employed in producing a viewable image.
    Type: Grant
    Filed: June 26, 1992
    Date of Patent: May 24, 1994
    Assignee: Eastman Kodak Company
    Inventor: James E. Sutton
  • Patent number: 5310630
    Abstract: A silver halide color photographic photosensitive material which has been spectrally sensitized to light of wavelengths greater than of about 670 nm in which are highly sensitive to light of wavelength greater than about 670 nm and sufficiently insensitive to visible light having a shorter wavelength. The photosensitive materials comprises a silver halide photosensitive layer containing the yellow coupler, a silver halide photosensitive layer containing a magenta coupler, a silver halide photosensitive layer containing a cyan coupler and at least one non-photosensitive hydrophilic layer. Each of the photosensitive layers are spectrally sensitized such that they have different peak spectral sensitivities at light wavelengths greater than about 670 nm.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: May 10, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshio Inagaki
  • Patent number: 5298372
    Abstract: A method for processing a transmission type black-and-white photographic material using an automatic processor is disclosed, which comprises processing an imagewise exposed silver halide photographic material comprises silver chlorobromide, silver chloroiodide or silver chloroiodobromide grains having a silver chloride content of at least 90 mol % and a mean grain size of 0.1 to 0.4 .mu.m or silver chloride grains having a mean grain size of 0.1 to 0.4 .mu.m; the processing comprises developing in a developing bath and fixing in a fixing bath and the developing bath contains sodium ion in an amount comprising at least 70 mol % of the entire cation content of the developing bath; the developing bath and the fixing bath are each replenished in an amount of not more than 150 ml per m.sup.2 of the silver halide photographic material processed; and the processing is carried out in an automatic processor.
    Type: Grant
    Filed: July 2, 1993
    Date of Patent: March 29, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Okutsu, Takashi Toyoda, Tadashi Ito
  • Patent number: 5283162
    Abstract: There are described photographic elements containing novel release compounds which release a blocked photographically useful group, such as a blocked development inhibitor. The blocking group is removed during processing as a result of reaction with sulfite ion contained in one of the processing baths.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: February 1, 1994
    Assignee: Eastman Kodak Company
    Inventors: Daniel L. Kapp, Wojciech Slusarek, David T. Southby
  • Patent number: 5283161
    Abstract: A method for rapidly processing a silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and a silver halide photographic material therefor are disclosed. The total amount of binder on one side of the support is not more than 3.0 g/m.sup.2, the photographic materials contains in at least one layer at least one compound selected from the group consisting of compounds represented by formulae (I) and (II): ##STR1## wherein X.sub.1, X.sub.2, A, R.sub.11, R.sub.12, R.sub.13, R.sub.14, R.sub.15, and R.sub.16 are defined in the specification. Processing may be effected in a total processing time of from 15 to 45 seconds. Pressure sensitivity can be reduced without reducing photographic speed.
    Type: Grant
    Filed: September 11, 1991
    Date of Patent: February 1, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ichizo Toya, Mikizo Kuwabara, Hiroshi Kawamoto
  • Patent number: 5278032
    Abstract: A process for the continuous treatment of silver halide color photographic light-sensitive materials comprising the developing of the material while supplying a replenisher to a developing bath, where the amount of the replenisher is 900 m or less per m.sup.2 of the light-sensitive materials, and an average ratio of silver iodide to the whole silver halide included in the light-sensitive material is 8 mol % or less.
    Type: Grant
    Filed: November 20, 1992
    Date of Patent: January 11, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shunichi Aida, Morio Yagihara, Shinzo Kishimoto, Hiroshi Fujimoto
  • Patent number: 5275915
    Abstract: A developer for light-sensitive material capable of processing in common a negative-working light-sensitive lithographic printing plate and a positive-working light-sensitive printing plate as well as a developing agent-containing type silver halide photographic material, is disclosed. The developer comprises an alkali agent, an anionic surface active agent, an antifoggant for a silver halide photographic material, and an alkylene oxide addition product (molecular weight of from 130 to 1200) of an aromatic amine or an aralkyl amine, and has pH of the range of from 11.5 to 13.5.
    Type: Grant
    Filed: June 2, 1992
    Date of Patent: January 4, 1994
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Yasuhiko Kojima, Yasuo Shigemitsu
  • Patent number: 5254452
    Abstract: A light-sensitive silver halide photographic material for x-ray exposure including a transparent support and a silver halide emulsion layer provided thereon. The photographic material exhibits a blue-light density in the unexposed portion of the developed image which does not exceed 0.09 and the red-light density is 0.02 to 0.10 and is less than the blue-light density.
    Type: Grant
    Filed: October 9, 1991
    Date of Patent: October 19, 1993
    Assignee: Konica Corporation
    Inventor: Haruhiko Sakuma
  • Patent number: 5238790
    Abstract: A silver halide photographic light-sensitive material contains a dispersion in which at least one compound represented by formula (I) below and a photographic useful reagent, which is hard to solve in water, are dispersed together. (In formula (I), R.sub.1 and R.sub.2 independently represent amino having 0 to 32 carbon atoms, alkoxy having 1 to 32 carbon atoms, or aryloxy having 6 to 32 carbon atoms, R.sub.3 and R.sub.4 independently represent a group which can be substituted on a benzene ring, and l and m independently represent an integer of 0 to 4. R.sub.3 and/or R.sub.4 may be the same or different when l and/or m is 2 to 4. In a method of processing a silver halide photographic light-sensitive material, the silver halide photographic light-sensitive material is exposed imagewise and then developed with a color developer not essentially containing benzyl alcohol.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: August 24, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Shimura, Hidetoshi Kobayashi, Hideaki Naruse
  • Patent number: 5229249
    Abstract: A silver halide photographic material comprising a support, having thereon one or more hydrophilic colloid layers, wherein at least one of the hydrophilic colloid layers is a silver halide emulsion layer, and wherein the silver halide emulsion layer or another hydrophilic colloid layer contains a compound represented by general formula (I):Y--[(X).sub.n --A.sub.0 --B.sub.0 ].sub.m (I)wherein Y represents a group which is adsorbed on silver halide, X represents a divalent group comprising an atom or group of atoms selected from among a hydrogen atom, a carbon atom, a nitrogen atom, an oxygen atom and a sulfur atom, A.sub.0 represents a divalent linking group which has at least two alkyleneoxy units, B.sub.0 represents an amino group, an ammonium group or a nitrogen containing heterocyclic group, m represents 1, 2 or 3, and n represents 0 or 1, as well as a method for processing a silver halide photographic material in the presence of a compound according to general formula (I).
    Type: Grant
    Filed: September 4, 1991
    Date of Patent: July 20, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Tetsuro Kojima
  • Patent number: 5217842
    Abstract: A process of forming superhigh-contrast negative images is disclosed. The process comprises the steps of imagewise exposing a substantially surface latent image-type silver halide photographic material which is spectrally sensitized with a sensitizing dye and then developing said photographic material with a developer, wherein said photographic material contains a heterocyclic thione compound and said developer comprises (a) an aminophenol derivative developing agent, (b) a reductone compound, (c) a quaternary ammonium salt, and (d) a compound represented by formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents a hydrogen atom, a nitro group, a halogen atom, or a cyano group, and wherein said development processing is carried out in the existence of at least one kind of a polyalkylene oxide or a derivative thereof. The process provides negative images of superhigh contrast having gamma over 10 substantially free from appearance of pepper.
    Type: Grant
    Filed: September 18, 1991
    Date of Patent: June 8, 1993
    Assignee: Dainippon Ink and Chemical, Inc.
    Inventors: Yasuhiko Kojima, Naoki Obi, Yasuo Shigemitsu
  • Patent number: 5215872
    Abstract: A method of processing a silver halide color photographic material is disclosed, comprising a support having provided thereon at least one light-sensitive emulsion layer, which comprises the steps of color developing the material with a developer to which a replenisher is added and bleaching the developed material, wherein the material contains a coupler represented by the following general formula (I) and the amount of replenisher added to the color developer is 600 ml or less per m.sup.2 of the material: ##STR1## wherein A represents a coupler group, and when A is a phenol or naphthol coupler group, n is 1, and when A is any other coupler group, n is 0; and R represents an alkyl group having from 1 to 4 carbon atoms, or a pyridyl group. Images having excellent photographic characteristics are obtained by the method even though the amount of the replenisher is reduced.
    Type: Grant
    Filed: April 16, 1991
    Date of Patent: June 1, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masatoshi Goto, Keiji Mihayashi
  • Patent number: 5210005
    Abstract: A method and an apparatus for developing a photosensitive lithographic plate at least one layer of which has been exposed with an image by a developer with conveying the same with the one layer facing substantially downwards, the method and apparatus being arranged in such a manner that the developer is supplied to the one layer and the thus-supplied developer is retained on the same layer.Therefore, the photosensitive lithographic plate can be developed without any necessity of being dipped in the developer.
    Type: Grant
    Filed: August 14, 1989
    Date of Patent: May 11, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tomoaki Takekoshi, Sho Nakao, Hisao Ohba, Seiji Shigetaka
  • Patent number: 5206121
    Abstract: The present invention relates to a method in which water for preventing the concentration of processing solution in a processing tank from being increased due to evaporation and a replenisher for avoiding a lowering of the effectiveness of the processing solution are added to the processing tank of a photographic processing apparatus. Before the processing tank is replenished with a replenisher, the processing tank is replenished with water by an amount corresponding to the amount of water evaporated therefrom until the liquid surface level reaches the original liquid surface level i.e. replacing evaporated water, and then, the processing tank is replenished with replenisher. Thereafter, the processing solution is discharged by an amount equal to the amount of replenisher added in order to return the liquid surface level to the original liquid surface level. Thus, the performance of the processing solution can be restored while the concentration of the processing solution is kept constant.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: April 27, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Fujita, Chuji Tsukada
  • Patent number: 5200303
    Abstract: A light-sensitive silver halide material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, at least one layer of the light-sensitive silver halide emulsion layer or an adjacent layer thereof containing an oil droplet dispersion in a hydrophilic binder, the oil droplets containing the combination of (a) a polymer insoluble in water and soluble in an organic solvent; (b) a high boiling point organic solvent having a viscosity at 25.degree. C. of at least 500 cp and a boiling point of at least 120.degree. C.; and (c) at least one coupler capable of forming a non-diffusible cyan dye by a coupling reaction with an oxidized form of a primary aromatic amine developing agent.
    Type: Grant
    Filed: February 1, 1991
    Date of Patent: April 6, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Osamu Takahashi, Yoshio Seoka, Hidetoshi Kobayashi, Tsumoru Ishii
  • Patent number: H1508
    Abstract: An image-forming process for silver halide photographic material is disclosed, in which the photosensitive material have at least one silver halide emulsion layer on a support and contains a hydrzaine compound in the emulsion layer or other constitutional layers. The image-forming process comprises developing the photographic material containing the hydrozine compound of formula (I) with the developing agent of formula (II).
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: December 5, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masato Hirano
  • Patent number: H1608
    Abstract: A method of processing with a developer a silver halide photographic light-sensitive material is disclosed, the material comprising a support and provided thereon, a silver halide emulsion layer comprising silver halide grains having not less than 90 mol % chloride, the emulsion layer or a hydrophilic colloid layer adjacent to the emulsion layer containing a tetrazolium compound, or a hydrazine derivative, and replenisher for developer being supplied to the developer in an amount of not more than 200 ml per m.sup.2 of the material processed, wherein the developer contains a carbonate salt in an amount of not less than 0.2 mol/liter.
    Type: Grant
    Filed: September 27, 1994
    Date of Patent: November 5, 1996
    Assignee: Konica Corp.
    Inventors: Shoji Nishio, Hideki Komatsu