Hypersensitizing Or Latensifying Ingredient Containing Patents (Class 430/599)
  • Patent number: 6740483
    Abstract: A process for incorporating dopants in a silver halide emulsion is described comprising precipitating silver halide emulsion grains in a reaction vessel, wherein at least one gallium dopant, at least one Group 8 metal dopant, and at least one selenium dopant are introduced into the reaction vessel during precipitation of the silver halide grains; where the gallium dopant is introduced in the form of a gallium halide coordination complex of the formula (I): [RxNHy]3GaX6 wherein R represents a lower alkyl group of from 1-3 carbon atoms; X is Cl, Br, or I; and x is from 1-3, y is from 1-3, and x+y=4; and the Group 8 metal dopant satisfies the formula (II): [ML6]n wherein n is −2, −3 or −4; M is a Fe+2, Ru+2, or Os+2 ion; and L6 represents bridging ligands which can be independently selected, provided that at least four of the ligands are anionic ligands, and at least one of the ligands is a cyano ligand or a ligand more electronegative than a c
    Type: Grant
    Filed: April 30, 2003
    Date of Patent: May 25, 2004
    Assignee: Eastman Kodak Company
    Inventor: Tommie L. Royster, Jr.
  • Patent number: 6727054
    Abstract: A silver halide photographic emulsion is disclosed, comprising silver chloroiodide grains or silver chloroiodobromide grains, having 90 mol % or more of a silver chloride content, wherein the silver chloroiodide grains or silver chloroiodobromide grains have a layer having a silver iodide content of decreasing in the depth direction from the grain surface.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: April 27, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satoshi Aiba, Osamu Yonekura, Genichi Furusawa, Naoto Ohshima
  • Patent number: 6727055
    Abstract: A radiation-sensitive emulsion is disclosed comprised of cubic silver iodochlorobromide grains comprising 0.25 to about 1.5 mol % iodide, 1 to about 25 mol % chloride, and from about 73.5 to 98.75 mol % bromide, each based on total silver in the emulsion, wherein the grains have an average equivalent circular diameter of greater than 0.6 micrometers and contain from 10−7 to 10−3 mole per silver mole of a metal ion coordination complex dopant of Formula (I) in an internal region of the grains formed after 10 percent and before 95 percent of the total grain silver has been precipitated: [ML6]n  (I) wherein n is zero, −1, −2, −3 or −4, M is a filled frontier orbital polyvalent metal ion, other than iridium, and L6 represents bridging ligands which can be independently selected, provided that at least four of the ligands are anionic ligands, and at least one of the ligands is a cyano ligand or a ligand more electronegative than a cyano ligand.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: April 27, 2004
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, Richard E. Beal, Anthony D. Gingello, Stephen A. Hershey, John D. Mee, Myra T. Olm
  • Publication number: 20040058282
    Abstract: A method of processing, with a developer in which a solution physical development arises, a silver halide photosensitive material containing a compound capable of undergoing a one-electron oxidation to thereby form a one-electron oxidation product thereof which belongs to the following types 1 to 4:
    Type: Application
    Filed: September 10, 2003
    Publication date: March 25, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Kimiyasu Mor imura, Kohzaburoh Yamada
  • Patent number: 6696215
    Abstract: Disclosed is a silver halide photographic light-sensitive material comprising at least one silver halide emulsion layer on a support, which contains a compound of which one-electron oxidized derivative produced by one electron oxidation of the compound is capable of releasing two or more electrons with a bond cleavage and has a characteristic curve drawn in orthogonal coordinates of logarithm of light exposure (x-axis) and optical density (y-axis) using equal unit lengths for the both axes, on which gamma is 5.0 or more for the optical density range of 0.3-3.0. This silver halide photographic light-sensitive material shows high contrast and high sensitivity.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: February 24, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shoji Yasuda, Kohzaburoh Yamada
  • Patent number: 6696236
    Abstract: Disclosed are a silver halide emulsion and a silver halide photosensitive material copmrising a support and at least one photosensitive layer comprising the silver halide emulsion. The photosensitive emulsion comprises silver halide grains, wherein the silver chloride content is 90 mole % or more; the silver halide grains contain (I) at least one member of a six-coordinated complex in which iridium (Ir) is a central metal having halogen atom and O, H2O, thiazole or substituted thiazole as ligands and (II) at least one member of a six-coordinated complex in which iridium (Ir) is a central metal having halogen atom as a ligand; and the iridium compound (II) is present in a localized silver bromide phase.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: February 24, 2004
    Assignee: Fuji Photo Film Co. Ltd.
    Inventors: Shinichi Nakahira, Tatsuya Ishizaka
  • Patent number: 6686140
    Abstract: A silver halide photosensitive material comprises at least one light sensitive silver halide emulsion layer on a support. The silver halide photosensitive material contains at least one compound capable of undergoing a one-electron oxidation to thereby form a one-electron oxidation product thereof, the one-electron oxidation product being capable of releasing further one or more electrons, and at least one reducing compound having a C/H value of 3 or less; and another reducing compound having a C/H value of more than 3, the C/H value representing a ratio of (the number of Group IV elements)/(the sum of Groups III, V, VI and VII elements).
    Type: Grant
    Filed: March 10, 2003
    Date of Patent: February 3, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoki Asanuma, Kohzaburoh Yamada, Yasuhiro Shimada
  • Patent number: 6664037
    Abstract: Disclosed is a method for chemical sensitization of a silver halide emulsion comprising a sensitization step of subjecting the silver halide emulsion to chemical sensitization with a chalcogen compound or a chalcogen compound and a gold compound to produce silver chalcogenide or gold silver chalcogenide, wherein the chemical sensitization is performed under such conditions that at least a part of the silver chalcogenide or gold silver chalcogenide produced in the sensitization step can be amorphized. This method can provide a silver halide emulsion showing high sensitivity without increasing fog and degrading storability and such a silver halide emulsion.
    Type: Grant
    Filed: June 12, 2002
    Date of Patent: December 16, 2003
    Assignee: Fuji Photo Film Co., LTD
    Inventor: Masafumi Mizuno
  • Patent number: 6660464
    Abstract: This invention comprises a silver halide photographic element comprising a support with low oxygen permeability and at least one silver halide emulsion layer containing a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is present in the emulsion layer, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y′; and, optionally, 3) the radical X• has an oxidation potential≦−0.7V (that is, equal to or more negative than about −0.7V).
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: December 9, 2003
    Assignee: Eastman Kodak Company
    Inventors: Annabel A. Muenter, Steven P. Szatynski
  • Publication number: 20030215756
    Abstract: A photothermographic material comprising a support and having thereon an image forming layer containing an organic silver salt, light-sensitive silver halide grains, binder and a reducing agent, wherein the reducing agent comprises: a reducing agent A containing at least a bisphenol derivative represented by following Formula (A-1); and a reducing agent B containing at least a bisphenol derivative not represented by the Formula (A-1), and the amount of reducing agent A is 5 to 45 weight % of the total weight of the reducing agent A and reducing agent B.
    Type: Application
    Filed: December 27, 2002
    Publication date: November 20, 2003
    Inventors: Kiyokazu Morita, Narito Goto, Ayumu Nishijima
  • Patent number: 6649334
    Abstract: A silver halide photographic emulsion wherein a variation coefficient of an equivalent-circle diameter of all the silver halide grains is 40% or less, and 50% or more of the total projected area is occupied by tabular grains satisfying requirements (i) to (v): (i) silver iodobromide having (111) faces as principal surfaces; (ii) the equivalent-sphere diameter of 0.5 &mgr;m or less, a thickness of 0.20 &mgr;m or less, and an average aspect ratio of 3 or more; (iii) a silver iodide content of 2 mol % or more and 6 mol % or less; (iv) a multiple-structure having a quintuple structure or more in which a silver iodide distribution has at least two maximums from a center to an edge, the first maximum is in a range of 3 to 25% by a silver amount constituting grains, and the second maximum is in a range of 50 to 80%; and (v) ten or more of dislocation lines per grain are present at a fringe portion.
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: November 18, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hideo Ikeda
  • Patent number: 6649336
    Abstract: A silver halide photographic light-sensitive material is disclosed, including at least one silver halide emulsion layer, wherein the silver halide grain contained in the emulsion layer is silver chloroiodide or silver chloroiodobromide having a silver chloride content of 90 mol % or more and a silver iodide content of 0.01 to 1.0 mol %, at least one hexacyano complex is doped in an amount of at least 1×10−7 mol % based on the total silver amount, and the emulsion layer contains a methine dye represented by the formula (I) as defined.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: November 18, 2003
    Assignee: Fuji Photo Film Co., LTD
    Inventors: Katsuhisa Ohzeki, Tetsuo Nakamura
  • Publication number: 20030203329
    Abstract: A silver halide photosensitive material containing a compound selected from Types 1-4 below which is capable of undergoing a one-electron oxidation to form a one-electron oxidation product (OEOP), and a reducing compound (Type 1) the OEOP is capable of releasing further two or more electrons accompanying a subsequent bond cleavage reaction, (Type 2) the OEOP is capable of releasing further one electron accompanying a subsequent bond cleavage reaction, and the compound having, in its molecule, two or more groups adsorptive to silver halide, (Type 3) the OEOP is capable of releasing further one or more electrons after going through a subsequent bond forming process, and (Type 4) the OEOP is capable of releasing further one or more electrons after going through a subsequent intramolecular ring cleavage reaction.
    Type: Application
    Filed: February 7, 2003
    Publication date: October 30, 2003
    Applicant: Fuji Photo Film Co., Ltd.
    Inventors: Kohzaburoh Yamada, Naoki Asanuma
  • Patent number: 6638706
    Abstract: A photothermographic recording material comprising on one side of a support an image recording layer comprising a light-insensitive organic silver salt, a photosensitive silver halide, a reducing agent for silver ions and a binder, wherein the difference in specular glossiness at an angle of 60° between a thermally developed exposed area of the image recording layer and the bottom support surface opposite the exposed area of the recording material is at least 15.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: October 28, 2003
    Assignee: Konica Corporation
    Inventor: Toshiyuki Matsumura
  • Publication number: 20030194666
    Abstract: A silver halide emulsion comprising a silver halide grain having a high silver iodide-containing phase, the surface of the silver halide grain being adsorbed with a substance capable of reducing by 50% or more the light emission intensity at 460 nm attributable to the high silver iodide-containing phase at 77° K.
    Type: Application
    Filed: March 27, 2003
    Publication date: October 16, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Seiji Yamashita
  • Patent number: 6627375
    Abstract: A silver halide photographic material is disclosed, comprising a support having provided thereon at least a silver halide emulsion layer, which contains at least one compound represented by the following formula (I), and has a characteristic curve of gamma value being 5.0 or more in optical density of from 0.3 to 3.0 on the characteristic curve shown on the orthogonal axis of coordinates having equal unit length expressed by logarithmic exposure amount (x axis) and optical density (y axis): (X)l—(L)m—(A—B)n  (I) wherein X represents a silver halide-adsorptive group having at least one of N, S, P, Se and Te atom, or a light absorptive group; L represents a divalent linking group having at least one of C, N, S and O atom; A represents an electron donative group; B represents a releasing group or a hydrogen atom, which forms radical A. by releasing or deproton after oxidation; l and m each represents an integer of from 0 to 3; and n represents 1 or 2.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: September 30, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shoji Yasuda
  • Patent number: 6623917
    Abstract: A silver halide photographic emulsion is disclosed, comprising silver halide grains wherein at least 80% of a total grain projected area is accounted for by tabular grains, the tabular grains having an average aspect ratio of at least 12, a variation coefficient of grain diameter of less than 30%, an average overall surface iodide content of 5 to 15 mol % and an average surface iodide content in the vicinity of corners of the grains of less than 3 mol %; and the tabular grains further having a shallow electron trap center in the peripheral region of the grain.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: September 23, 2003
    Assignee: Konica Corporation
    Inventors: Katsuhiko Suzuki, Hiroshi Takada, Sadayasu Ishikawa
  • Publication number: 20030157445
    Abstract: In accordance with one embodiment of the invention, a photographic element is described comprising a support bearing one or more hydrophilic colloid layers including at least one photographic silver halide emulsion layer, wherein sequestered silver ions are incorporated into at least one hydrophilic colloid layer in the form of a silver ion containing material which sequesters silver ions prior to photographic processing and releases silver ions upon exposure to photographic processing solutions. Method for preparing and processing such photographic element are also described. In accordance with particular embodiments of the invention, the silver ion containing material comprises a silver ion-exchanged zeolite material or an intercalation composition comprising a layered host material having silver ions inserted as guest ions between the layers of the host material.
    Type: Application
    Filed: December 28, 2001
    Publication date: August 21, 2003
    Inventors: Joseph F. Bringley, Kenneth J. Lushington, Tiecheng A. Qiao, James S. Honan
  • Publication number: 20030148233
    Abstract: A radiation sensitive imaging element is described comprising a support bearing one or more hydrophilic colloid layers, wherein a photographically useful compound is incorporated into at least one hydrophilic colloid layer in the form of a self-assembled composition comprising a substantially homogeneous and ordered array of the photographically useful compound and silver and halide atoms, wherein the average minimum distance from each Ag atom in the composition to an atom of the photographically useful compound in the composition is less than 50 Å.
    Type: Application
    Filed: December 21, 2001
    Publication date: August 7, 2003
    Applicant: Eastman Kodak Company
    Inventors: Joseph F. Bringley, Manju Rajeswaran
  • Patent number: 6593072
    Abstract: A process of sensitizing a tabular grain emulsion containing the steps of (i) providing a tabular grain host emulsion comprised of a dispersing medium and silver halide grains including tabular grains having {111} major faces and an aspect ratio of at least 2, which contain greater than 50 mole percent bromide, based on silver, and which account for greater than 50 percent of total grain projected area; (ii) adding a thiosulfonate compound of the following Formula I at the surface of the tabular grains of the host emulsion: Z1SO2SZ2  (I) where Z1 represents is a substituted or unsubsituted aliphatic, aromatic, or heterocyclic group, and Z2 represents a substituted or unsubsituted aliphatic, aromatic, or heterocyclic group, or a monovalent metal or organic cation, where Z1 and Z2 may combine together to form a ring structure or either of Z1 or Z2 may comprise a polymeric backbone wherein the thiosulfonate group may be repeated; and (iii) adding silver and halide ions, where the halide
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: July 15, 2003
    Assignee: Eastman Kodak Company
    Inventor: Tommie L. Royster, Jr.
  • Patent number: 6593073
    Abstract: A silver halide photographic element comprises at least one silver halide emulsion layer comprising a silver halide emulsion comprising core/shell silver halide grains wherein the core region comprises silver bromide with from about 5 to about 20% silver iodide and the shell region comprises silver bromide with about 0.1 to about 10% silver iodide and said layer contains a fragmentable electron donor compound of the formula X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: July 15, 2003
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, Yun C. Chang
  • Patent number: 6582895
    Abstract: A silver halide photographic emulsion which comprises at least one methine compound represented by the following formula (I): wherein X1 and X2 each represents an oxygen atom, a sulfur atom, a selenium atom, or N—R3, wherein R3 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a heterocyclic group; V1 and V2 each represents a monovalent substituent; n1 and n2 each represents 0, 1, 2, 3 or 4; L1, L2 and L3 each represents a methine group; l represents an integer of 0 to 3; M represents a counter ion for balancing electric charge; m represents a necessary number for balancing electric charge; and R1 and R2 each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group, but at least either R1 or R2 represents the alkyl group represented by any of the following formulae: Ra=(Qa)rCO{overscore (N)}SO2Raa Rb=(Qb)sSO2{o
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: June 24, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoyuki Hanaki, Takanori Hioki, Kiyoshi Morimoto
  • Patent number: 6579670
    Abstract: The present invention provides a silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide emulsion contained in the silver halide emulsion layer comprises silver halide grains having a silver chloride content of 90 mol % or more, and the silver halide emulsion further contains a metal complex having H2O as a ligand. It also provides a silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide emulsion contained in the silver halide emulsion layer contains a metal complex having O2− as a ligand.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: June 17, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tomonori Owaki, Tadanobu Sato, Takahiro Matsuno
  • Patent number: 6558891
    Abstract: A silver halide emulsion is disclosed, comprising tabular silver halide grains having an average iodide content of 3 to 15 mol % and comprising silver halide phases differing in halide composition, at least 50% of the total projected area of the tabular silver halide grains being accounted for by grains having an aspect ratio of not less than 12, wherein the first silver halide phase (A) has an average iodide content of not more than 3 mol % and accounting for 50 to 85% of total silver, the second phase (B) locating outside the phase (A), having an average iodide content of 8 to 25 mol % and accounting for 10 to 35% of total silver, and the third outermost phase having an average iodide content of not more than 4 mol % 0.5 to 15% of total silver.
    Type: Grant
    Filed: September 6, 2001
    Date of Patent: May 6, 2003
    Assignee: Konica Corporation
    Inventors: Hiroshi Takada, Katsuhiko Heki
  • Patent number: 6537740
    Abstract: A silver halide color negative photographic lightsentive material comprises at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer on a support. The lightsensitive material has an ISO speed of 640 or more, the total silver content of 3.0 to 9.0 g/m2. Each of the red-sensitive emulsion layer, green-sensitive emulsion layer and blue-sensitive emulsion layer comprises two or more silver halide emulsion sub-layers having the same color sensitivity but different in speed to each other, and each of the red-sensitive sub-layer having the highest speed, green-sensitive sub-layer having the highest speed and blue-sensitive emulsion sub-layer having the highest speed has a silver content of 0.3 to 1.3 g/m2.
    Type: Grant
    Filed: September 15, 2000
    Date of Patent: March 25, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Norihiro Omae, Shunichi Aida
  • Patent number: 6534226
    Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: March 18, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owczarczyk, David T. Southby, Xiqiang Yang
  • Patent number: 6531274
    Abstract: A radiation-sensitive emulsion comprised of silver halide grains (a) containing greater than 50 mole percent chloride, based on silver, (b) having greater than 50 percent of their surface area provided by {100} crystal faces, and (c) having a central portion accounting for up to 99 percent of total silver and containing a first dopant of Formula (I) and a second dopant of Formula (II): [RuL6]n  (I) wherein n is zero, −1, −2, −3 or −4, and L6 represents bridging ligands which can be independently selected, provided that at least four of the ligands are anionic ligands, and at least one of the ligands is a cyano ligand or a ligand more electronegative than a cyano ligand; [TE4(NZ)E′]r  (II) wherein T is Os or Ru; E4 represents bridging ligands which can be independently selected; E′ is E or NZ; r is zero, −1, −2 or −3; and Z is oxygen or sulfur; wherein the dopant of Formula (II) is selected from hexacoor
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: March 11, 2003
    Assignee: Eastman Kodak Company
    Inventors: Jerzy Z. Mydlarz, Woodrow G. McDugle, Raymond S. Eachus
  • Patent number: 6514682
    Abstract: The invention relates to an emulsion comprising chemically and spectrally sensitized silver halide grains having formate on the surface of said grams.
    Type: Grant
    Filed: June 20, 2001
    Date of Patent: February 4, 2003
    Assignee: Eastman Kodak Company
    Inventor: Jon N. Eikenberry
  • Publication number: 20030008248
    Abstract: This invention comprises a photographic element comprising at least one light-sensitive silver halide emulsion layer containing a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein
    Type: Application
    Filed: January 5, 2001
    Publication date: January 9, 2003
    Applicant: Eastman Kodak Company
    Inventors: Annabel A. Muenter, Steven P. Szatynski, Sharon G. Johnston
  • Patent number: 6500607
    Abstract: A silver halide photographic material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer, wherein the silver halide emulsion layer contains, in the dispersion medium phase of the emulsion, one or more kinds of inorganic fine particles having a refractive index the total weight of the fine particles contained in the unit volume of the dispersion medium phase is from 1.0 to 95 wt %, the dispersion medium phase containing the fine particles is substantially transparent to the photosensitive peak wavelength light of the emulsion layer, and the photographic material is exposed and processed in the development process comprising at least a developing step and a fixing step.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: December 31, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsuo Saitou, Yoichi Maruyama, Toshiyuki Nabeta, Masaaki Miki, Keiichi Miyazaki, Mikio Ihama, Shunji Takada, Norihiro Omae, Yasushi Tanabe
  • Patent number: 6498004
    Abstract: This invention provides a photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula (a): &Dgr;−(t)m−XY′  (a) XY′−(t)m−&Dgr;  (b) &Dgr;−(t)m−XY′−(t)m−&Dgr;  (c) wherein &Dgr; is protective group that is eliminated during development of the photographic element, t is a timing group, m is an integer from 0 to 3, and XY′ is a fragmentable electron donor moiety in which X is an electron donor group and Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is present in the emulsion or is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.
    Type: Grant
    Filed: December 28, 2000
    Date of Patent: December 24, 2002
    Assignee: Eastman Kodak Company
    Inventors: Jerome R. Lenhard, Annabel A. Muenter, Stephen A. Godleski, Paul A. Zielinski, Deepak Shukla, Donald R. Diehl
  • Patent number: 6492102
    Abstract: A red or infrared sensitive silver halide emulsion is disclosed, comprising at least a compound represented by the following formula. A photographic material containing the emulsion is also disclosed.
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: December 10, 2002
    Assignee: Konica Corporation
    Inventors: Nobuaki Kagawa, Noriyasu Kita
  • Patent number: 6472132
    Abstract: There is disclosed a silver halide photographic light-sensitive material comprising at least one compound selected from the group consisting of the compounds represented by the following formula (1), (2) or (3): wherein R1 represents a phenyl, aromatic heterocyclic or aliphatic group, having at least one electron-withdrawing group as a substituent, PUG represents a residue of a development inhibitor, Y1 and Z1 respectively represent a substituent which is substitutable on a benzene ring, and n1 and p1 denote integers from 0 to 4, Ar represents an aryl group or an aromatic heterocyclic group, PUG represents a residue of a development inhibitor, TIME represents a timing group and t denotes 0 or 1, A represents a connecting group, m denotes an integer from 2 to 6.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: October 29, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kohzaburoh Yamada, Hirokazu Kyota, Masahiko Taniguchi, Takashi Hoshimiya, Tetsuo Yamaguchi, Ken-ichi Kuwabara, Toshihide Ezoe
  • Publication number: 20020150848
    Abstract: A silver halide photographic emulsion which contains silver halide grains having light absorption strength of 100 or more.
    Type: Application
    Filed: November 14, 2001
    Publication date: October 17, 2002
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Katsuhiro Yamashita, Katsumi Kobayashi
  • Patent number: 6461803
    Abstract: A silver halide color photographic lightsensitive material comprising at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer on a support, wherein the lightsensitive material has an ISO speed of 640 or more, and has a variation, in terms of a SNGR ratio, of magenta and cyan colors of 0 dB or more when the lightsensitive material is subjected to each of white light exposure, white fluorescent lamp exposure and three band fluorescent lamp exposure.
    Type: Grant
    Filed: September 6, 2000
    Date of Patent: October 8, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoichi Suga, Takanori Hioki, Jun Okamoto
  • Patent number: 6458522
    Abstract: A silver halide photographic light-sensitive material includes a compound selected from: (1) a quaternary nitrogen or phosphorus salt compound, having 20 or more of total recurring units consisting of an ethyleneoxy group and/or a propyleneoxy group; (2) a quaternary salt compound represented by formula (A): wherein Q represents nitrogen or phosphorus, R1, R2 and R3 represent an alkyl, aryl, alkenyl, alkynyl, or heterocyclic group, L1 represents an alkylene group, Y represents —C(═O) or —SO2—, L2 represents a divalent connecting group having at least one hydrophilic group, Xn− represents an n-valent counter anion, n being an integer of 1 to 3; and (3) a quaternary salt compound represented by formula (B): wherein A represents an organic moiety necessary to complete a nitrogen-containing aromatic heterocyclic ring. L2 represents a divalent connecting group having at least one hydrophilic group that divides L2.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: October 1, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masahiko Taniguchi, Kohzaburoh Yamada, Ken-ichi Kuwabara, Tetsuo Yamaguchi
  • Patent number: 6451520
    Abstract: A colour photographic silver halide material comprising a support and at least one silver halide emulsion layer which is deposited thereon and which contains at least one colour coupler, characterised in that said layer also contains a compound of formula (I) wherein R1 denotes alkyl, aryl, aralkyl or hetaryl, R2 denotes H or R1, or R1 and R2 together denote the remaining members of a heterocyclic ring, R3, R4, independently of each other, denote aryl or hetaryl or together denote the remaining members of a phenanthrene ring which is condensed-on in the 9,10-position, wherein R1 can also be H if R3 and R4 together form a phenanthrene ring, is distinguished by improved granularity.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: September 17, 2002
    Assignee: Agfa-Gevaert
    Inventors: Heinrich Odenwälder, Hans Langen, Uwe Dahlhaus
  • Patent number: 6440618
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application, wherein B is a six-membered heteroaromatic ring. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: August 27, 2002
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy
  • Patent number: 6428947
    Abstract: This invention comprises multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said red-sensitive or green-sensitive layers comprises a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein the speed gain deriving from addition of said compound to said layer is less than or equal to 0.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: August 6, 2002
    Assignee: Eastman Kodak Company
    Inventors: Sharon G. Johnston, Annabel A. Muenter, Steven P. Szatynski, Jerome R. Lenhard
  • Patent number: 6416941
    Abstract: A color photographic element comprises a support and at least one dye image forming layer unit comprising gelatin-peptized radiation-sensitive silver halide grains, a fragmentable electron donating compound; and an electron transfer agent releasing compound.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: July 9, 2002
    Assignee: Eastman Kodak Company
    Inventors: Kenneth J. Reed, Annabel A. Muenter, Sharon R. Lunt, David T. Southby
  • Patent number: 6403276
    Abstract: A film material has been provided with emulsions comprising {111} tabular silver halide grains rich in silver bromide, spectrally sensitive to irradiation in the wavelength range shorter than 420 nm by the presence of at least one blue spectral sensitizer and of at least one azacyanine dye, the formula of which has been given in the description and in the claims. A radiographic screen/film combination or system has also been provided comprising a duplitized film sandwiched between a pair of supporting or self-supporting X-ray intensifying screens, characterized in that i) said pair of supported or self-supporting X-ray intensifying screens essentially consists of luminescent phosphor particles emitting at least 50% and more preferably at least 80% of their emitted radiation in the wavelength range shorter than 420 nm, ii) said film corresponds with the film material disclosed hereinbefore.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: June 11, 2002
    Assignee: Agfa-Gevaert
    Inventors: Kathy Elst, Paul Callant, Ann Verbeeck
  • Patent number: 6403293
    Abstract: A silver halide color photographic light sensitive material is disclosed, comprising a support having thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layers, wherein at least one of the silver halide emulsion layers contains a coupler represented by the following formula:
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: June 11, 2002
    Assignee: Konica Corporation
    Inventors: Osamu Ishige, Emiko Kataoka, Hiroyuki Hoshino
  • Publication number: 20020058214
    Abstract: A silver halide photographic material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer, wherein the silver halide emulsion layer contains, in the dispersion medium phase of the emulsion, one or more kinds of inorganic fine particles having a refractive index the total weight of the fine particles contained in the unit volume of the dispersion medium phase is from 1.0 to 95 wt %, the dispersion medium phase containing the fine particles is substantially transparent to the photosensitive peak wavelength light of the emulsion layer, and the photographic material is exposed and processed in the development process comprising at least a developing step and a fixing step.
    Type: Application
    Filed: January 6, 2000
    Publication date: May 16, 2002
    Inventors: Mitsuo Saitou, Yoichi Maruyama, Toshiyuki Nabeta, Masaaki Miki, Keiichi Miyazaki, Mikio Ihama, Shunji Takada, Norihiro Omae, Yasushi Tanabe
  • Publication number: 20020048732
    Abstract: A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing compound represented by the following general formula (1), and (d) a binder:
    Type: Application
    Filed: March 16, 2001
    Publication date: April 25, 2002
    Inventors: Toyohisa Oya, Kouta Fukui, Yasuhiro Yoshioka, Kazunobu Katoh
  • Patent number: 6350567
    Abstract: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole-% silver chloride, said emulsion containing an isothiazolone compound represented by the formula wherein R1 is a substituent; and Z contains the carbon atoms necessary to form a substituted or unsubstituted non-aromatic ring, wherein the isothiazolone compound was added before or during precipitation of the emulsion.
    Type: Grant
    Filed: October 7, 1999
    Date of Patent: February 26, 2002
    Assignee: Eastman Kodak Company
    Inventors: Benjamin T. Chen, Roger L. Klaus, Jeri L. Mount
  • Patent number: 6340562
    Abstract: A silver halide photographic emulsion, wherein silver halide grains are prepared by adding a compound capable of forming cross-linkage with gelatin to said silver halide grains in any of processes before the completion of chemical sensitization after the formation of the silver halide grains.
    Type: Grant
    Filed: February 10, 1999
    Date of Patent: January 22, 2002
    Assignee: Konica Corporation
    Inventor: Yasuo Taima
  • Patent number: 6326133
    Abstract: Disclosed is a silver halide photographic material comprising a silver halide emulsion layer containing at least one specific compound, with examples including compounds represented by formula (I), wherein an average aspect ratio of silver halide emulsion grains constituting said silver halide emulsion layer is from 8 to 100: wherein Z1 represents atoms completing a 5- or 6-membered nitrogen-containing heterocyclic ring, L1, L2, L3 and L4 each represent a methine group, V1 represents a monovalent substituent, l1 is an integer of from 0 to 4, p1 is 0 or 1, n1 is 0, 1, 2 or 3, R1 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group, M1 represents a counter ion for adjusting the electric charge balance, m1 is the number of counter ions necessary to render the molecule electrically neutral and ranges from 0 to 10, and La represents a methylene group.
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: December 4, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takanori Hioki
  • Patent number: 6322960
    Abstract: A silver halide emulsion is disclosed, containing silver halide grains having a chloride content of not less than 90 mol %, wherein the silver halide grains each are internally doped with compound (A), compound (B) and compound (C); compounds (A) and (B) each meeting specified requirements and compound (C) being an iridium compound.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: November 27, 2001
    Assignee: Konica Corporation
    Inventors: Shuji Murakami, Koichiro Kuroda, Yumiko Osawa, Junji Ito, Shinichi Suzuki
  • Patent number: 6322961
    Abstract: A color reversal photographic element is disclosed comprising a support having coated thereon a silver halide emulsion layer comprising a silver halide emulsion chemically sensitized in the presence of an organomercapto Au(I) complex having the formula [L—Au—L]M wherein M is a cationic counter ion and each L is an organomercapto ligand which has antifogging, stabilizing or sensitizing properties, and a rapid sulfiding agent represented by structure SS-1 wherein each of the R1, R2, R3, and R4 groups independently represents an alkylene, cycloalkylene, carbocyclic arylene, heterocyclic arylene, alkarylene or aralkylene group; or taken together with the nitrogen atom to which they are attached, R1 and R2 or R3 and R4 can complete a 5- to 7-membered heterocyclic ring; and each of the B1, B2, B3, and B4 groups independently is hydrogen or represents a carboxylic, sulfinic, sulfonic, hydroxamic, mercapto, sulfonamido or primary or secondary amino nucleophilic group, with th
    Type: Grant
    Filed: September 21, 2000
    Date of Patent: November 27, 2001
    Assignee: Eastman Kodak Company
    Inventors: Wai K. Lam, Roger Lok, David W. Sandford
  • Patent number: 6319640
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: November 20, 2001
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy