Hypersensitizing Or Latensifying Ingredient Containing Patents (Class 430/599)
-
Patent number: 4755448Abstract: A negative type silver halide photographic material and a method for forming a super high contrast negative image using the photographic material are disclosed. The photographic material comprises a support, at least one silver halide emulsion layer on the support, and at least one light-insensitive colloid layer on the support, said emulsion layer or light-insensitive hydrophilic colloid layer containing a hydrazine derivative, and further contains the tertiary amine salt of an acid polymer.Type: GrantFiled: September 4, 1986Date of Patent: July 5, 1988Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazunobu Katoh
-
Patent number: 4755449Abstract: A negative type silver halide photographic material and a method for processing the photographic material to form a super high contrast negative image are disclosed. The photographic material comprises a support and at least one emulsion layer on the support, said emulsion layer comprising silver halide grains comprising a core of silver halide containing silver iodide and a shell covering the core, said shell consisting essentially of silver bromide, silver chloride, or silver chlorobromide and having a thickness of from 0.01 to 0.08 .mu.m, wherein the emulsion layer or a hydrophilic colloid layer other than the emulsion layer of the photograpic material contains a hydrazine derivative.Type: GrantFiled: September 4, 1986Date of Patent: July 5, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Senzo Sasaoka
-
Patent number: 4746601Abstract: A silver halide photographic light-sensitive material comprising a support having provided thereon at least one photographic layer including at least one silver halide emulsion layer, whereinat least one silver halide emulsion layer contains silver halide grains whose average value of the diameter corresponding to the projected area of a group of silver halide grains that take 40% of the total projected area of whole silver halide grains present in said silver halide emulsion layer is at least 1.5 .mu.m andat least one photographic layer contains at least one compound capable of imagewise releasing a fogging agent or a precursor thereof or a development accelerator or a precursor thereof corresponding to a quantity of developed silver upon development, is disclosed. This material is of very high sensitivity and, furthermore, has a high developing speed and has reduced for formation irrespective of its high sensitivity.Type: GrantFiled: March 9, 1987Date of Patent: May 24, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiji Mihayashi, Hidetoshi Kobayashi, Shunji Takada
-
Patent number: 4737442Abstract: A silver halide photographic material for use in the field of graphic arts and a process for forming a high-contrast negative image using the same, wherein the silver halide emulsion layer or another layer of the silver halide photographic material provided on the support contains at least one compound represented by the formula (I) and at least one blocked development restrainer compound represented by the formula (II): ##STR1##Type: GrantFiled: April 18, 1986Date of Patent: April 12, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Morio Yagihara, Tetunori Matusita, Nobuaki Inoue
-
Patent number: 4728600Abstract: A heat-developable light-sensitive material is described, comprising a support having thereon at least (1) a light-sensitive silver halide, (2) a silver salt oxidizing agent, (3) silver salt particles having adsorbed thereon at least one compound selected from a cyclic imino compound represented by formula (I) described below and a mercapto compound represented by formula (II) described below, (4) a reducing agent, and (5) a binder.Formula (I) is represented by ##STR1## wherein Z represents a non-metallic atomic group forming a heterocyclic ring containing an imino group together with the nitrogen atom of formula (I).Formula (II) is represented byR--S--M (II)wherein M represents a hydrogen atom or an alkali metal atom; and R represents a substituted or unsubstituted aliphatic hydrocarbon group, a substituted or unsubstituted aromatic hydrocarbon group, or a substituted or unsubstituted heterocyclic group.Type: GrantFiled: April 17, 1986Date of Patent: March 1, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Hara, Toshiaki Aono
-
Patent number: 4722884Abstract: A negative silver halide photographic light-sensitive material is provided, having a silver halide emulsion layer, which layer comprises silver haloiodide grains prepared in the presence of an iridium salt in an amount of 1.times.10.sup.-8 to 1.times.10.sup.-5 mole per one mole of silver, wherein the silver iodide content in the surface part of said grain is larger than the average silver iodide content in said grain, and additionally containing in said emulsion layer or in some other hydrophilic colloid layer, a compound of formula (I):R.sub.1 --NHNH--CHO (I)wherein R.sub.1 represents an aliphatic group or an aromatic group. Said photographic light-sensitive material is, after being exposed imagewise, developed with a developer containing 0.15 mole/l or more sulfite ion and having a pH value of 9.5-12.3, to form negative images having ultra-high contrast.Type: GrantFiled: July 23, 1985Date of Patent: February 2, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Senzo Sasaoka, Kenichi Kuwabara, Kimitaka Kameoka
-
Patent number: 4713321Abstract: A process for preparing a silver halide photographic emulsion to be used for a photographic material is provided. Therein, additives such as dyes, sensitizers, auxiliary agents to be used upon gold sensitization, and so on are utilized within a period from at the silver halide grain forming time to just before the emulsion coating, and oxidizing agents are added at the time when the functions of the additives become substantially needless to result in conversion of the additives to those having no bad influences on photographic characteristics of the emulsion prepared, or to those having such chemical structures as to facilitate their removal with a washing treatment or the like.Silver halide emulsions prepared by the described process are also disclosed.Type: GrantFiled: February 14, 1986Date of Patent: December 15, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Mifune, Tadao Shishido, Yoshiaki Suzuki
-
Patent number: 4699873Abstract: A negative silver halide photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer is disclosed. At least one of the silver halide emulsion layers or another hydrophilic colloidal layer of the material contains a hydrazine derivative and a compound represented by the formula:R.sub.1 --S--S--R.sub.2wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an aliphatic group, an aromatic group or a heterocyclic group, or when R.sub.1 and R.sub.2 are both aliphatic groups they may together form a ring. The material can rapidly form a superhigh contrast image using a stable processing solution.Type: GrantFiled: January 29, 1986Date of Patent: October 13, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiro Takahashi, Shigeo Hirano
-
Patent number: 4693956Abstract: A process is disclosed for forming a high-contrast photographic image by developing a silver halide photographic element, including at least a silver halide emulsion layer, with an aqueous alkaline developing solution containing a dihydroxybenzene developing agent, a superadditive developing agent and an antioxidant at a pH of less than 12 in the presence of a hydrazine compound, an organic antifogging and contrast promoting agent selected within the class including a benzotriazole compound and a benzimidazole compound and a non polymeric hydroxymethylidyne group containing compound of formula: ##STR1## wherein R.sub.1 and R.sub.2 each independently represent a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, or R.sub.1 and R.sub.2 together complete a non aromatic cyclic group.Type: GrantFiled: November 15, 1985Date of Patent: September 15, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventor: Carlo Marchesano
-
Patent number: 4684604Abstract: Photographic elements and processes are described which employ a compound containing a hydrazide moiety attached by a linking group, comprising an acidic group or an active methylene group adjacent to an acidic group, to a heteroatom of a moiety containing a photographically useful group comprising a photographic dye or precursor thereof or a photographic reagent; wherein:(a) the hydrazide moiety is capable of being oxidized to an azo group by an oxidized developing agent,(b) the azo group formation causes the release of the photographically useful group, and(c) the released photographically useful group does not contain the linking group or the nitrogen atoms of the hydrazide moiety.Type: GrantFiled: April 24, 1986Date of Patent: August 4, 1987Assignee: Eastman Kodak CompanyInventor: John W. Harder
-
Patent number: 4681838Abstract: A silver halide emulsion and a process for producing the same are disclosed. In the process, at least one compound selected from hydrogen peroxide or an adduct or precursor thereof, a peroxy acid salt, and ozone is added to an emulsion in the step prior to the end of chemical ripening. The emulsion exhibits reduced fog, improved stability with time, and improved sensitivity.Type: GrantFiled: June 14, 1985Date of Patent: July 21, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Mifune, Tadao Shishido, Yoshiaki Suzuki
-
Patent number: 4681836Abstract: A silver halide photographic material having at least one silver halide emulsion layer which contains silver halide grains containing from 1.times.10.sup.-8 to 8.times.10.sup.-6 mole of a rhodium salt per mole of silver, and containing in said emulsion layer or another hydrophilic colloidal layer a compound represented by formula (I)R.sup.1 -NHNH-G-R.sup.2 (I)wherein R.sup.1 represents an aliphatic group or an aromatic group; R.sup.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted imino group; is exposed to imagewise pattern of light and then development-processed with a developer containing 0.15 mole/liter or more of sulfite ion and having a pH adjusted to from 9.5 to 12.Type: GrantFiled: November 20, 1986Date of Patent: July 21, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Yoshio Inagaki, Kimitaka Kameoka
-
Patent number: 4680253Abstract: A silver halide color photographic material which comprises a support having coated thereon at least one blue-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one red-sensitive silver halide emulsion layer, characterized in that the gradation of each of the blue-, green- and red-sensitive layers satisfies the following relation: ##EQU1## wherein .gamma..sub.B (10.sup.-4), .gamma..sub.G (10.sup.-4) and .gamma..sub.R (10.sup.-4) represent gradation of the blue-, green- and red- sensitive layers upon 1/10,000 second exposure, respectively and .gamma..sub.B (10.sup.-2), .gamma..sub.G (10.sup.-2) and .gamma..sub.R (10.sup.-2) represent those upon 1/100 second exposure, respectively, which provides a color picture having good color and tone reproduction in both regular and flash photography.Type: GrantFiled: February 25, 1986Date of Patent: July 14, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshihiko Shibahara, Hideto Ikoma
-
Patent number: 4678745Abstract: A process for producing a tabular silver halide emulsion by using a sulfur-containing silver halide solvent that promotes growth of silver halide grains, and a light-sensitive material containing the emulsion are disclosed. The grain growth effect of the silver halide solvent is reduced or eliminated by using an oxidizing agent thereby excluding the adverse effect of the silver halide solvent upon chemical ripening.Type: GrantFiled: June 14, 1985Date of Patent: July 7, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Sumito Yamada, Hiroyuki Mifune, Shigeharu Urabe
-
Patent number: 4668614Abstract: An improvement in silver halide photographic light-sensitive materials having at least one silver halide emulsion layer on a support is disclosed. The improvement is that chemically sensitized silver halide grains contained in at least one of the emulsion layers have a distinct stratiform structure having substantially two parts comprising an inside core part and a shell part of the uppermost layer, wherein the inside core part of said grains is composed of silver halide containing 10 to 45% by mol of silver iodide, the shell part of the uppermost layer of the grains is composed of silver halide containing 5% by mol or less of silver iodide, and the emulsion containing silver halide grains having the distinct stratiform structure have an average silver iodide content of 7% by mol or more. The materials have high sensitivity, low fog and excellent graininess.Type: GrantFiled: October 10, 1986Date of Patent: May 26, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Shunji Takada, Naoto Ohshima, Shingo Ishimaru
-
Patent number: 4661438Abstract: Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by quaternized aromatic oxatellurazinium salts. The aromatic oxatellurazinium salts can be initially incorporated in the photographic element as manufactured or during processing.Type: GrantFiled: January 31, 1986Date of Patent: April 28, 1987Assignee: Eastman Kodak CompanyInventors: Rosemary Przyklek-Elling, Wolfgang H. H. Gunther, Roger Lok
-
Patent number: 4659654Abstract: A silver halide photographic light-sensitive emulsion contains silver halide particles, chemically sensitized, the average concentration of the silver iodide of which is from 0.5 to 10 mole % and which have inside part wherein not less than 20 mole percent silver iodide is present locally; and at least one cyanine dyes having the Formulas [I], [II] and [III] as herein described.Type: GrantFiled: September 26, 1985Date of Patent: April 21, 1987Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Iku Metoki, Akio Suzuki, Eiji Yoshida, Kiyoshi Sato, Masumi Hosaka
-
Patent number: 4649104Abstract: A heat developable light-sensitive material is described, comprising a polymer containing as a constituent a repeating unit represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituted or unsubstituted alkyl group having from 1 to 6 carbon atoms; L represents a divalent connecting group having from 1 to 20 carbon atoms; M represents a cation and x represents a number which is the same as the charge number of the cation represented by M.The polymer containing the repeating unit represented by formula (I) is a base precursor which is stable at normal temperature, but rapidly decomposes to release a base by heating; therefore, the heat developable light-sensitive material containing the base precursor has excellent preservability and provides images having good image quality, i.e., low fog density and high image density, upon a short period of developing time.Type: GrantFiled: October 30, 1985Date of Patent: March 10, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Taku Nakamura, Hiroyuki Hirai
-
Patent number: 4639414Abstract: A heat developable light-sensitive material comprising a support having thereon (1) a light-sensitive silver halide emulsion, (2) at least one of a base and a base precursor, and (3) a binder, wherein the silver halide emulsion is one which is chemically sensitized in the presence of a sensitizing dye. With the heat developable light-sensitive material, decrease in sensitivity and formation of fog during preservation thereof are prevented.Type: GrantFiled: June 13, 1985Date of Patent: January 27, 1987Assignee: Fuji Photo Film Co., Ltd.Inventor: Yukihiko Sakaguchi
-
Patent number: 4636460Abstract: Photographic recording materials which contain a developer substance or a precursor thereof produce better results if in addition they contain a sulphite, a disulphite or a compound capable of releasing sulphite in the photographic material.Type: GrantFiled: June 11, 1985Date of Patent: January 13, 1987Assignee: Agfa Gevaert AktiengesellschaftInventors: Heinz Meckl, Helmut Kampfer, Helmut Haseler
-
Patent number: 4634661Abstract: A negative working photographic element is disclosed capable of producing a high contrast silver image. The photographic element is comprised of surface latent image forming monodispersed silver halide grains having a mean diameter of less than 0.7 .mu.m, a contrast enhancing arylhydrazide, and, in an amount sufficient to stabilize sensitivity, a carboxyalkyl substituted 3H-thiazoline-2-thione.Type: GrantFiled: July 18, 1985Date of Patent: January 6, 1987Assignee: Eastman Kodak CompanyInventor: Anthony Cavallaro
-
Patent number: 4629678Abstract: An internal latent image-type direct positive silver halide light-sensitive material is described, comprising a support having at least one photographic emulsion layer thereon, wherein said layer contains internal latent image-type direct positive silver halide grains, the surfaces of which are chemically sensitized, wherein a compound of the general formula (I) is added as a finish additive to the photographic emulsion layer or at least one hydrophilic colloid layer adjacent to the photographic emulsion layer.General Formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are defined as herein. The light-sensitive material exhibits a very satisfactory reversal performance and is greatly improved in stability over the course of time.Type: GrantFiled: October 29, 1984Date of Patent: December 16, 1986Assignee: Fuji Photo Film Co., Ltd.Inventor: Ashita Murai
-
Patent number: 4623612Abstract: An improved method of developing silver halide photographic light-sensitive materials comprising at least one silver halide emulsion layer on a support is disclosed. In the improvement, said silver halide emulsion layer contains core/shell type silver halide grains having a shell thickness of 25 to 150 .ANG. wherein the surface of the core is subjected to chemical sensitization treatment and the surface of the shell is not subjected to chemical sensitization, and a developing solution contains a solvent for silver halide. It is possible to carry out spectral sensitization without causing a reduction in intrinsic sensitivity and to provide high-speed silver halide light-sensitive materials which are excellent in anti-fading property of latent images and excellent in stabilization with the passage of time using the above-described improved method.Type: GrantFiled: October 21, 1985Date of Patent: November 18, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshihiro Nishikawa, Hatsumi Tanemura
-
Patent number: 4618574Abstract: A negative working photographic element is disclosed capable of producing a high contrast silver image. The photographic element is comprised of surface latent image forming monodispersed silver halide grains having a mean diameter of less than 0.7 .mu.m, a contrast enhancing arylhydrazide, and, in an amount sufficient to reduce pepper fog while maintaining high contrast a polyhydroxybenzene and a carboxyalkyl-3H-thiazoline-2-thione.Type: GrantFiled: July 18, 1985Date of Patent: October 21, 1986Assignee: Eastman Kodak CompanyInventor: Anthony Cavallaro
-
Patent number: 4618570Abstract: A silver halide photographic material having at least one layer of silver halide emulsion layers containing a silver halide having a silver chloride content of not less than 25 molar %, characterized in that at least one of said silver halide emulsion layers contains a silver halide sensitized with a compound having the following formula (Ia), and/or a compound having the following formula (Ib) and is hardened with a compound having the following formula (II) and/or a compound having the formula (III); ##STR1## in the above formulae (Ia), (Ib), (II) and (III), R.sub.1 to R.sub.20, Z.sub.1 and Z.sub.2, n.sub.1 and n.sub.2, Q and Q', L, p and q are defined in the specification.The photographic material of the invention not only shows a higher sensitivity, a lower infrared sensor fogging, a superior sharpness or color reproductivity and a superior whiteness but also exerts a good storage property with time or a lower change in sensitivity after storage.Type: GrantFiled: March 15, 1985Date of Patent: October 21, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Takashi Kadowaki, Kaoru Onodera
-
Patent number: 4609610Abstract: Photographic elements and assemblages are described which employ nondiffusible compounds which release photographically useful groups in an imagewise manner as the result of a .beta.-elimination reaction.Type: GrantFiled: August 1, 1985Date of Patent: September 2, 1986Assignee: Eastman Kodak CompanyInventors: Richard P. Dunlap, Thomas E. Gompf
-
Patent number: 4607001Abstract: Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by aromatic tellurochalcogenides. The aromatic tellurochalcogenides can be initially incorporated in the photographic element as manufactured or during processing.Type: GrantFiled: April 4, 1985Date of Patent: August 19, 1986Assignee: Eastman Kodak CompanyInventors: Roger Lok, Wolfgang H. H. Gunther
-
Patent number: 4607006Abstract: A silver halide photographic light-sensitive material is described containing at least one electron-donative, silver halide-adsorptive compound represented by the following general formula (A) or (B), which is not a spectral sensitizing agent for silver halide or a nucleating agent:D--L--X (A)D--X (B)wherein D represents an electron donative atomic group comprising an aromatic ring or hetero ring, which may be unsubstituted or substituted with at least one substituent; L represents a linkage group containing at least one of C, N, S or O; and X represents a group which is adsorptive with a silver halide-adsorptive group containing at least one of C, N, S, O or Se, said N being optionally quarternized.Type: GrantFiled: October 9, 1984Date of Patent: August 19, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeo Hirano, Yasuhisa Sano, Haruo Takei, Tsutomu Miyasaka, Shinsaku Fujita
-
Patent number: 4607000Abstract: Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by amido substituted aromatic tellurochalcogenides. The amido substituted aromatic tellurochalcogenides can be initially incorporated in the photographic element as manufactured or during processing.Type: GrantFiled: April 4, 1985Date of Patent: August 19, 1986Assignee: Eastman Kodak CompanyInventors: Wolfgang H. H. Gunther, Roger Lok
-
Patent number: 4605610Abstract: A silver halide emulsion rich in chloride is described which has grains having a layered grain structure with a core and at least one layer encasing the core.Type: GrantFiled: March 6, 1985Date of Patent: August 12, 1986Assignee: Agfa-Gevaert AktiengesellschaftInventor: Sieghart Klotzer
-
Patent number: 4581322Abstract: A method for developing a silver halide photographic material in the presence of an amino compound represented by the following general formula (I) or the salt thereof to increase photographic speed and/or gamma without being attended by a concomitant increase in generation of fog: ##STR1## wherein R.sup.1 represents an alkyl group, an aryl group, an aralkyl group or a cycloalkyl group; R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group or an alkylcarbonyl group, or R.sup.2 and R.sup.3 may combine with each other and form a ring; and A represents a divalent aliphatic linkage group.Type: GrantFiled: December 14, 1984Date of Patent: April 8, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Shoji Ishiguro, Hiroyuki Mifune, Morio Yagihara, Yoshio Inagaki, Kanji Meguro
-
Patent number: 4581328Abstract: An internal latent image core/shell silver halide photographic emulsion containing core/shell silver halide grains is disclosed, the grains comprising a silver halide core which is doped with a metal ion or chemically sensitized or is both doped with a metal ion and chemically sensitized, and a silver halide shell which covers at least a sensitivity speck of the core, wherein both added iodine ion and a polymer having a specific repeating unit described in the specification are present on the surface of the core/shell silver halide grains. The emulsion has a high sensitivity even without chemical sensitization of the surface of core/shell silver halide grains.Type: GrantFiled: November 16, 1984Date of Patent: April 8, 1986Assignee: Fuji Photo Film Co., Ltd.Inventor: Junichi Matsuyama
-
Patent number: 4560638Abstract: An unballasted arylhydrazide is disclosed the aryl moiety of which is substituted with a group of the formula ##STR1## where one of X and X' represents --NH--, the other represents a divalent chalcogen, and R represents an aliphatic or aromatic residue. The arylhydrazides, when applied to halftone imaging in conjunction with silver halide emulsions, photographic elements, and imaging processes, produce images of improved dot quality and low levels of pepper fog.Type: GrantFiled: October 9, 1984Date of Patent: December 24, 1985Assignee: Eastman Kodak CompanyInventors: James C. Loblaw, Barbara B. Lussier
-
Patent number: 4529690Abstract: A color photographic element contains a compound of the following formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent hydrogen atom, or an alkyl or aryl group; Ar.sub.1 and Ar.sub.2 each represent an aryl group; and n and m each represent 1 or 2. The color element containing the above compound displays excellent sensitivity, gradation, and color-developability even when developing it with a color developer not substantially containing any benzyl alcohol.Type: GrantFiled: August 23, 1984Date of Patent: July 16, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Keiji Ohbayashi, Shinichi Nakamura
-
Patent number: 4510229Abstract: A lithographic photosensitive material which comprises a support having thereon at least one silver halide emulsion layer and that, contains as a lithographic development accelerating agent a compound represented by the following general formula (I) in its silver halide emulsion layer or another hydrophilic colloidal layer: ##STR1## wherein R.sub.1 to R.sub.5 may be the same or different, and they each represent hydrogen, a halogen atom, an alkyl group, an alkoxy group, an aryl group, ##STR2## (wherein R.sub.6 and R.sub.7 each represents hydrogen or an alkyl group, or they may combine with each other to form a 5- or 6-membered nitrogen containing saturated hetero ring), --NH--CO--R.sub.8 or --NHSO.sub.2 --R.sub.9 (wherein R.sub.8 and R.sub.9 each represents an alkyl group, an aryl group or an aralkyl group), or R.sub.3 and R.sub.4, or R.sub.4 and R.sub.5 may combine with each other to form a benzene ring and that, it is necessary to said compound that at least one of substituents R.sub.1, R.sub.3 and R.sub.Type: GrantFiled: March 19, 1984Date of Patent: April 9, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Yutaka Oka, Naomi Saeki, Yoshiharu Fuseya
-
Patent number: 4504570Abstract: High aspect ratio tabular grain direct reversal silver halide emulsions are disclosed. The emulsions can be incorporated in photographic elements, such as multicolor photographic elements. Image transfer film units incorporating these direct reversal emulsions are specifically disclosed.Type: GrantFiled: December 23, 1983Date of Patent: March 12, 1985Assignee: Eastman Kodak CompanyInventors: Francis J. Evans, Richard L. Daubendiek, Ronald G. Raleigh
-
Patent number: 4495274Abstract: Direct positive silver halide photographic materials comprising a support, a silver halide emulsion layer comprising fogged silver halide particles prepared in the presence of a water soluble iridium salt or a water soluble rhodium salt, and a hydrophilic colloidal layer comprising (a) a compound selected from Formula I and II and (b) at least one compound selected from the group consisting of Formula III and a gold compound, said Formula I being ##STR1## wherein R.sub.1 is hydrogen, alkyl, --SO.sub.3 M, or --COOM, wherein M is selected from hydrogen, alkali metals, and ammonium, and R.sub.2 is selected from hydrogen and lower alkyls, said Formula II being ##STR2## wherein R.sub.3 is selected from hydrogen, alkyl, --SO.sub.3 M, and --COOM, and R.sub.4 is selected from hydrogen, alkyl, and --CH.sub.2 --S--(CH.sub.2).sub.n --Y', wherein n is an integer of from 1 to 3, and Y' is selected from hydrogen and --SO.sub.3 M, and said Formula III beingH.sub.2 N--Y--NH--Y].sub.m NH.sub.Type: GrantFiled: April 21, 1983Date of Patent: January 22, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventor: Kazuhiro Yoshida
-
Patent number: 4478928Abstract: The use of sulfinic acid radical substituted arylhydrazides in producing images in silver halide photographic elements is disclosed. The sulfinic acid radical substituted arylhydrazide can be incorporated in photographic silver halide, emulsions, and photographic elements. The sulfinic acid radical substituent is capable of activating the arylhydrazides, particularly for use at a lower alkaline pH. In negative working surface latent image forming emulsions the sulfinic acid radical substituted arylhydrazides permit higher speed or contrast to be achieved. In direct positive internal latent image forming emulsions increased nucleation activity and reduced rereversal can be achieved.Type: GrantFiled: May 11, 1983Date of Patent: October 23, 1984Assignee: Eastman Kodak CompanyInventors: Thomas C. Hess, Karl E. Wiegers
-
Patent number: 4474872Abstract: A method for producing a photographic emulsion is disclosed. The method includes the process of adding a dispersion of a substantially water-insoluble photographic additive to a photographic emulsion. The dispersion being prepared merely by mechanically grinding and dispersing the photographic additive in a form of fine grain having a size of 1.mu. or less in an aqueous system adjusted to a pH value of 6 to 8 and controlled to a temperature of 60.degree. to 80.degree. C. The additive is included in the photographic emulsion without the need of an organic solvent. The emulsion of the invention can be easily and quickly coated to form a uniform layer.Type: GrantFiled: December 17, 1982Date of Patent: October 2, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Onishi, Kazutoshi Inada, Nobuaki Miyasaka, Naoyasu Deguchi, Masayuki Kuroishi
-
Patent number: 4473636Abstract: A process is disclosed for increasing the sensitivity of photographic film wound on a roll or film cartridge. The film is treated by soaking in a dilute atmosphere of hydrogen mixed with a non-reactive gas, such as nitrogen, at relatively low temperatures for long time periods. The apparatus includes a hermetically sealed chamber for the film, a pressure gauge, and valves together with a vacuum pump and gas source for administering the film treatment. An alternative version includes a heater for the chamber. The treated film exhibits enhanced sensitivity to electromagnetic radiation, reduced low-intensity reciprocity law failure, and improved accuracy of color rendition.Type: GrantFiled: February 28, 1984Date of Patent: September 25, 1984Inventor: John B. Marling
-
Patent number: 4465764Abstract: A photosensitive member having a light-sensitive silver halide emulsion coating as the photosensitive layer and at least one sheet of pryoelectric and photovoltaic polyvinylidene fluoride sheet or copolymer thereof in close proximity (e.g., adjacent) to the photosensitive layer is disclosed. During exposure of the photosensitive member, the pyroelectric and photoelectric sheet produces a voltage across the photosensitive layer, which increases the efficiency of the photoelectrons produced by exposure of the photosensitive layer and therefore increases the sensitivity or speed of the photosensitive member. The at least one sheet can be provided as at least part of the support base for the photosensitive layer and/or as a screen overlying the photosensitive layer.Type: GrantFiled: September 30, 1982Date of Patent: August 14, 1984Assignee: Pennwalt CorporationInventor: Luke R. Ocone
-
Patent number: 4454223Abstract: Small amounts of radical traps resorcylaldehyde oxime and 2,2-diphenyl-1-picrylhydrazyl and organic oxidants 2-chloro-5-nitrobenzylchloride, p-nitro-o-chlorobenzyl thiosulfate and 2-(p-nitrobenzyl)thiopyridinium bromide reduce the fog and stabilize the aging of medical X-ray emulsion with little or no effect on speed.Type: GrantFiled: August 16, 1982Date of Patent: June 12, 1984Assignee: E. I. Du Pont de Nemours and CompanyInventor: James J. Welter
-
Patent number: 4451560Abstract: A method for forming a photosensitive element which comprises contacting silver halide in a plurality of spaced depressions in a surface with a mixture of a silver halide solvent and preformed sensitivity centers.Type: GrantFiled: November 15, 1982Date of Patent: May 29, 1984Assignee: Polaroid CorporationInventors: Arthur M. Gerber, Judith Loucks
-
Patent number: 4450223Abstract: A photographic silver halide material comprising a compound which is capable of being reduced by a silver halide developing agent at a rate slower than that of image-wise developable silver halide and in reduced state is capable of releasing a photographically useful group, characterized in that said compound corresponds to the following formula: ##STR1## wherein: R.sup.10 and R.sup.20 (same or different)(1) represent an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group or an aralkyl group including said groups in substituted form,(2) represent an aryl group including a substituted aryl group, or(3) represent a heterocyclic ring residue including such residue in substituted form, orR.sup.10 and R.sup.20 are ringclosed, either R.sup.10 or R.sup.20 containing a ballasting group conferring diffusion resistance to the compound in hydrophilic colloid media when penetrated by an aqueous alkaline liquid;L.sup.1 and L.sup.2 (same or different) represent a ##STR2## --SO.sub.Type: GrantFiled: February 14, 1983Date of Patent: May 22, 1984Assignee: AGFA-Gevaert, N.V.Inventors: Raphael K. Van Poucke, Christian C. Van de Sande, Andree Verhecken
-
Patent number: 4450229Abstract: The addition of a class of compounds to a photothermographic emulsion reduces latent image fade.Type: GrantFiled: May 13, 1983Date of Patent: May 22, 1984Assignee: Minnesota Mining and Manufacturing CompanyInventor: Jack E. Reece
-
Patent number: 4442202Abstract: A post-activation type dry image forming material comprising (I) a silver salt component reducible to free silver upon light exposure and including silver iodide; (II) a redox reactive composition capable of making a visual change by a redox reaction of said composition, said reaction being initiated by heating in the presence of free silver; (III) an oxidizing agent for free silver which has an oxidizing capacity for free silver but is rendered photosensitive by heating and which, upon light exposure after said heating, is suppressed with respect to the oxidizing capacity for free silver and capable of catalytically promoting the redox reaction of said composition; and (IV) a photoreactive oxidizing agent, upon light exposure, capable of returning the reduced oxidizing agent for free silver to the original state.Type: GrantFiled: February 28, 1983Date of Patent: April 10, 1984Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Tetsuo Shiga, Takeo Kimura, Yoshinobu Ito, Kageyasu Akashi, Minoru Akiyama, Takeki Matsui
-
Patent number: 4439520Abstract: High aspect ratio chemically and spectrally sensitized tabular grain silver halide emulsions, photographic elements incorporating these emulsions, and processes for the use of the photographic elements are disclosed. In the tabular grain emulsions the silver halide grains having a thickness of less than 0.3 micron and a diameter of at least 0.6 micron have a high aspect ratio and account for at least 50 percent of the total projected area of the silver halide grains present.Type: GrantFiled: September 30, 1982Date of Patent: March 27, 1984Assignee: Eastman Kodak CompanyInventors: James T. Kofron, Robert E. Booms, Cynthia G. Jones, John A. Haefner, Herbert S. Wilgus, Francis J. Evans
-
Patent number: 4433050Abstract: A direct positive type light sensitive silver halide photographic material is disclosed. At least one layer containing an unfogged internal latent image type silver halide emulsion, is provided on a support, and an internal latent image type silver halide emulsion having fog centers in silver halide grains, is incorporated in said layer or in another constituent layer of the photographic material. A dye image forming substance may be incorporated in the same layer or in a separate layer to form a color diffusion transfer type light sensitive photograhic material. The photographic materials present a positive image having a high maximum density and a low minimum density.Type: GrantFiled: September 9, 1981Date of Patent: February 21, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Takao Abe, Satoru Hohnishi
-
Radiation-sensitive silver bromoiodide emulsions, photographic elements, and processes for their use
Patent number: 4433048Abstract: Radiation-sensitive emulsions are disclosed comprised of a dispersing medium and silver bromoiodide grains. These emulsions contains tabular silver bromoiodide grains having a lower proportion of iodide in a central region than in a laterally displaced region, a thickness of less than 0.3 micron, and a diameter of at least 0.6 micron. These tubular grains exhibit an average aspect ratio of greater than 8:1 and account for at least 50 percent of the total projected area of the silver bromoiodide grains.Type: GrantFiled: September 30, 1982Date of Patent: February 21, 1984Assignee: Eastman Kodak CompanyInventors: John C. Solberg, Roger H. Piggin, Herbert S. Wilgus -
Patent number: 4431731Abstract: An internal latent image silver halide emulsion is disclosed comprising core/shell silver halide particles having a chemically sensitized surface which are composed of a core of silver halide doped with metal ions and/or subjected to chemical sensitization and a shell which covers said core as far as to do at least the sensitive sites of said core and a binder, wherein said silver halide emulsions contain a polymer containing a repeating unit represented by the following general formula (I) in an amount of 2 mg to 1000 mg per mole of silver as the weight of said repeating units in said polymer: ##STR1## wherein R.sup.1 represents a hydrogen atom or an alkyl group and Q represents a group selected from the group consisting of the following (1)-(4): ##STR2## wherein q represents an integer of 2 to 4, ##STR3## wherein R.sup.2 and R.sup.3 each represents a hydrogen atom or an alkyl group, ##STR4## wherein Z.sup.Type: GrantFiled: February 17, 1982Date of Patent: February 14, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadao Sugimoto, Ichizo Toya, Shigeharu Urabe, Shinji Sakaguchi