Hypersensitizing Or Latensifying Ingredient Containing Patents (Class 430/599)
  • Patent number: 5273871
    Abstract: A silver halide emulsion comprising a dispersing medium and light-sensitive silver halide grains wherein said silver halide grains each comprise:(a) a high silver iodide-containing phase having a silver iodide content of not less than 15 mol % in the internal portion,(b) a low silver iodide-containing phase locating outside the phase (a) and having a silver iodide content lower than that of the phase (a), and(c) a surface phase having a silver iodide content higher than that of an inner phase adjacent thereto,and wherein a part or all of the phase (c) and a part or all of the phase (a) or the phase (b) are formed by supplying a fine silver halide grain emulsion prepared in the presence of protective colloid.
    Type: Grant
    Filed: October 1, 1991
    Date of Patent: December 28, 1993
    Assignee: Konica Corporation
    Inventors: Hiroshi Takada, Sadayasu Ishikawa, Shoji Matsuzaka
  • Patent number: 5238806
    Abstract: There is disclosed a silver, halide photographic light-sensitive material having a high sensitivity and gradation as well as a low fog while exhibiting an excellent aging stability. The light-sensitive material has at least one silver halide emulsion layer on a support, wherein the emulsion is spectrally sensitized at a pH of 5.3 to 6.0 by adding at least one of an oxacarbocyanine dye represented by the following formula (I) to the emulsion before the addition of a chemical sensitizer and thereafter chemically sensitized by adding a chemical sensitizer. A compound represented by the following formula (II) is present in the emulsion layer or a layer adjacent thereto: ##STR1## wherein the substituents are as defined in the specifications.
    Type: Grant
    Filed: October 8, 1991
    Date of Patent: August 24, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshihisa Hashi
  • Patent number: 5229248
    Abstract: A silver halide photographic light-sensitive material is disclosed, which is capable of forming an extremely high contrast image with high dot quality and is inhibited in formation of pepper spots. The light-sensitive material comprises a support, and provided thereon, a photographic layer including a silver halide emulsion layer, wherein the pH value of the surface of said photographic layer is 5.9 or more and said emulsion layer or a layer adjacent to said emulsion layer contains a specified hydrazine compound, and an amine compound or a quaternary onium compound.
    Type: Grant
    Filed: August 13, 1991
    Date of Patent: July 20, 1993
    Assignee: Konica Corporation
    Inventors: Takeshi Sanpei, Kenji Goto
  • Patent number: 5213952
    Abstract: A method of forming a direct positive color image by imagewise exposing a photographic material having at least one emulsion layer which contains previously non-fogged internal latent image-type silver halide grains, on a support, followed by color-developing the exposed material during or after fogging thereof, wherein the photographic material contains a color sensitizing dye and at least one compound or salt thereof which satisfies the condition-1 as defined in the specification. With the image formed by the method having an elevated maximum image density with a lowered minimum image density, and with the iamge-forming method displaying extremely excellent color reproducibility.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: May 25, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Kuwashima, Akihiko Ikegawa
  • Patent number: 5196291
    Abstract: A silver halide photographic material which comprises a support having provided thereon at least one light-sensitive emulsion layer, and which contains in said emulsion layer, or at least one other layer, at least one hydrazine derivative, at least one contrast enhancing agent and at least one redox compound capable of releasing a development inhibitor upon being oxidized. The hydrazine derivative is exemplified by compounds represented by the following formula: ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a carbamoyl group or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## or an iminomethylene group; and A.sub.1 and A.sub.2 both represent a hydrogen atom, or, alternatively, one of them represents a hydrogen atom and the other represents an alkylsulfonyl group, an arylsulfonyl group, or an acyl group.
    Type: Grant
    Filed: July 30, 1991
    Date of Patent: March 23, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Kazunobu Katoh
  • Patent number: 5190855
    Abstract: A silver halide light-sensitive material comprising a support having thereon at least one negative silver halide emulsion layer is disclosed, in which a coating weight of the total binder on one side of the support is not more than 4.2 g/m.sup.2 and silver halide grains in the emulsion layer have been subjected to reduction sensitization. The light-sensitive material has improved pressure resistance while exhibiting high sensitivity and suitability for ultra-rapid processing.
    Type: Grant
    Filed: February 26, 1991
    Date of Patent: March 2, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ichizo Toya, Rikio Inoue, Tadashi Ito
  • Patent number: 5158856
    Abstract: A silver halide photographic light-sensitive material having a support and provided thereon, at least one silver halide emulsion layer containing Compound [I] or Compound [II] represented by Formula [I] or [II] is disclosed; ##STR1##
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: October 27, 1992
    Assignee: Konica Corporation
    Inventors: Yasushi Usagawa, Fumio Ishii
  • Patent number: 5156946
    Abstract: A silver halide photographic material comprising at least one silver halide emulsion layer on a support, wherein the latent image distribution of silver halide grains contained in the at least one emulsion layer has at least one peak value within the grains, the location of the peak value is at a depth of less than 0.01 .mu.m from the surface of the grains, and the average silver iodide content of the grains is about 15 mol % or less.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: October 20, 1992
    Assignee: Fuji Photo Film Co., Ltd
    Inventors: Katsuro Nagaoka, Shinsuke Bando, Takefumi Hara
  • Patent number: 5130212
    Abstract: A process for producing a silver halide photographic material that has at least one silver halide emulsion layer on a support, in which process at least 10 mg of a calcium salt per mole of silver halide is added during the period from the completion of physical ripening a silver halide emulsion to the completion of its chemical ripening together with at least one compound represented by the following general formula (I) and at least one compound represented by the following general formula (II): ##STR1## where R.sub.1 is a hydrogen atom or an alkyl group; R.sub.2 and R.sub.3 which may be the same or different are each a substituted or unsubstituted alkyl group; A.sub.1 -A.sub.6 are each a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom or a phenyl group, provided that adjacent atoms or groups may combine to form a ring; X is an anion; and n is 0 or 1, provided that n =0 when an intramolecular salt is formed; ##STR2## wherein Z.sub.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: July 14, 1992
    Assignee: Konica Corporation
    Inventors: Isamu Morimoto, Kaoru Hattori, Koichi Ueda, Hiroyuki Ushiroyama
  • Patent number: 5102782
    Abstract: Photographic, gelatino, silver halide emulsions exhibiting improved speed/fog ratio and good hardening are described. These emulsions are made by sensitizing with 1-naphthol-4-sulfonic acid and by adding an aliphatic polyol thereto.
    Type: Grant
    Filed: December 11, 1990
    Date of Patent: April 7, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Raymond J. LeStrange
  • Patent number: 5079138
    Abstract: A silver halide photographic light-sensitive material includes a support and at least one layer of silver halide emulsion formed on the support. The emulsion layer contains silver halide grains which have been subjected both to reduction sensitization while growing and to at least one chemical sensitization selected from the group consisting of gold sensitization, sulfur sensitization, and noble-metal sensitization. Each of the silver halide grains has at least 5 mol % of silver iodide on a surface thereof.
    Type: Grant
    Filed: May 30, 1991
    Date of Patent: January 7, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shunji Takada
  • Patent number: 5077189
    Abstract: Light-sensitive silver halide photographic materials are disclosed comprising a support and silver halide emulsion layer or layers, wherein at least one of said silver halide emulsion layers contains tabular silver halide grains having an average diameter:thickness ratio of at least 3:1 and at least one resorcinol.The light-sensitive materials can be advantageously used in high temperature processing without causing serious fog problems.
    Type: Grant
    Filed: October 22, 1990
    Date of Patent: December 31, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Luigi Cellone, Mario Mariotti
  • Patent number: 5073479
    Abstract: There is described a process for the production of a silver halide emulsion wherein the chemical sensitization is carried out in the presence of N-methyl formamide.
    Type: Grant
    Filed: October 15, 1990
    Date of Patent: December 17, 1991
    Assignee: Ilford AG
    Inventor: Jean F. Reber
  • Patent number: 5059516
    Abstract: A silver halide photographic material that contains at least one compound represented by the general formula (2) shown below and at least one compound selected from the group consisting of the compounds represented by the general formulas (3) and (4) shown below: ##STR1## The constituents in the above formulas are clearly defined in the instant specification and claims.
    Type: Grant
    Filed: October 30, 1990
    Date of Patent: October 22, 1991
    Assignee: Konica Corporation
    Inventors: Kiyoshi Sato, Kouji Ono
  • Patent number: 5030552
    Abstract: The present invention provides (1) a method for preparation of a photographic silver halide emulsion containing tabular silver halide particles having a particle diameter larger than the particle thickness by three times or more, wherein least one oxidizing agent selected from a hydrogen peroxide, a salt of a peroxy acid and an ozone is added to the emulsion before the termination of chemical ripening thereof and then a reducing agent is added thereto, and (2) a silver halide photographic material which has at least one or more layers comprising a tabular silver halide particle-containing emulsion wherein tabular silver halide particles are those prepared by method (1). The present tabular silver halide particle-containing emulsion has high sensitivity and good granularity and is substantially free from fog.
    Type: Grant
    Filed: June 1, 1989
    Date of Patent: July 9, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuyuki Iwasaki, Sumito Yamada, Hiroyuki Mifune
  • Patent number: 5030542
    Abstract: A light-sensitive material which comprises a light-sensitive layer and a support is disclosed. The light-sensitive layer contains silver halid grains, at least two hydrazine derivatives and a polymerizable compounds. One hydrazine derivative has the following formula [I]: ##STR1## in which one of R.sup.1 and R.sup.2 is hydrogen, and the other is hydrogen, an alkylsulfonyl group, an arylsulfonyl group or an acyl group; R.sup.3 is an aliphatic group, an aromatic group or a heterocyclic group; R.sup.4 is hydrogen, an alkyl group, an aralkyl group, an aryl group, an alkoxy group, an aryloxy group, amino or carbamoyl; at least one hydrogen atom contained in R.sup.3 or R.sup.4 is replaced with a group capable of being adsorbed on silver halide grains; G is carbonyl, sulfonyl, sulfinyl, ##STR2## (R.sup.5 has the same meanings as for R.sup.4); and each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and G may have one or more substituent groups.
    Type: Grant
    Filed: July 27, 1989
    Date of Patent: July 9, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Nakamura, Morio Yagihara
  • Patent number: 5002866
    Abstract: An internal latent image type silver halide photographic emulsion comprising internal latent image type silver halide photographic emulsions containing silver halide grains comprising an internal silver halide nucleus which has been doped with metal ions and/or chemically sensitized and an external silver halide shell which covers at least the light-sensitive sites on the internal nucleus, wherein during production of the silver halide grains the pAg at the end of the surface chemical sensitization stage, which is carried out in the presence of sulfur sensitizing agents, is at least 0.4 higher than the pAg at the beginning of the chemical sensitization stage.
    Type: Grant
    Filed: June 12, 1989
    Date of Patent: March 26, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuo Kashi
  • Patent number: 4999275
    Abstract: A silver halide photographic light-sensitive material is described, comprising a support, at least one light-sensitive silver halide emulsion layer on the support, and at least one light-insensitive top layer provided on the emulsion layer, wherein at least one of the emulsion layer and other constituent layers contains a compound represented by the general formula (I)R.sup.1 --NHNH--G--R.sup.2 (I)wherein R.sup.1 is a substituted or unsubstituted aryl group, R.sup.2 is a hydrogen atom, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group, and G is a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted imino group and wherein said at least one light-insensitive top layer is hardened so as to have a melting time at least 50 seconds longer than that of the emulsion layer.
    Type: Grant
    Filed: October 15, 1986
    Date of Patent: March 12, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuo Kasama, Nobuaki Inoue
  • Patent number: 4990440
    Abstract: The sensitivity/fog ratio can be improved by using photographic silver halide emulsions containing gelatine which has a cysteine content of less than 10 ppm and a gold number of .gtoreq.23 .mu.mol/g.
    Type: Grant
    Filed: August 4, 1989
    Date of Patent: February 5, 1991
    Assignee: Agfa-Gevaert Aktiengessellschaft
    Inventors: Franz Moll, Bruno Mucke, Walter Patzold, Klaus Wagner
  • Patent number: 4985350
    Abstract: A silver halide photographic light-sensitive material includes a support having thereon at least one silver halide light-sensitive emulsion layer, characterized in that at least one of a plurality of emulsions contained in the emulsion layer contains tabular grains having a thickness of less than 0.5 .mu.m, a diameter of at least 0.3 .mu.m, and an average ratio of grain diameter to grain thickness of at least 2, the tabular grains occupy at least 50% of the entire projected area of all the grains contained in the emulsion, the surfaces of the grains are chemically sensitized, and a ratio of surface sensitivity to internal sensitivity of the grains is 0.5 to 2.
    Type: Grant
    Filed: January 25, 1990
    Date of Patent: January 15, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideo Ikeda, Shingo Ishimaru
  • Patent number: 4985351
    Abstract: A color photographic silver halide material of the negative type, in which at least one silver halide emulsion layer contains as compound corresponding to the following formulaA--(Z).sub.n --F* (I)adsorbed on the silver halide grain,A being a grain-active attachment group corresponding to formulae IIa to IId: ##STR1## Z is a difunctional intermediate member, F* is a latent fogging agent group which becomes the active fogging agent (F) during color development andn=0 or 1,is distinguished by improved sensitivity.
    Type: Grant
    Filed: August 25, 1989
    Date of Patent: January 15, 1991
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Reinhart Matejec, Heinrich Odenwalder, Hans hlschlager, Erich Wolff
  • Patent number: 4971890
    Abstract: A silver halide photographic material is disclosed, comprising a support having thereon at least one of silver halide photographic emulsion layers and other hydrophilic colloidal layers, wherein said photographic emulsion layers or other hydrophilic colloidal layers contain a hydrazine compound represented by formula (I): ##STR1## wherein at least one of A.sub.1 and A.sub.2 represents a hydrogen atom and the other represents a hydrogen atom, a sulfonyl group or an acyl group; R.sub.1 represents an aliphatic, group, an aromatic group, or a heterocyclic group; Y.sub.1 represents a divalent organic group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## wherein R.sub.2 represents an alkoxy group or an aryloxy group, ##STR3## or an iminomethylene group; Z.sub.1 represents a group suitable for making a nucleophilic attack on G.sub.1 to separate the G.sub.1 --L.sub.1 --Z.sub.1 from the rest of the molecule; and L.sub.
    Type: Grant
    Filed: May 9, 1989
    Date of Patent: November 20, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Kazunobu Katoh
  • Patent number: 4971889
    Abstract: A silver halide photographic emulsion containing at least one compound represented by following formula (I):Dye--L--Hyd (I)wherein Dye represents a chromophore-containing dye residue shown by following formula (II); Hyd represents a hydrazine residue one of the two nitrogen atoms of which is substituted by a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an alkilydene group and L represents a divalent linkage group of bonding Dye and Hyd; ##STR1## wherein R and R.sub.1, which may be the same or different, each represents an alkyl group; Z and Z.sub.1, which may be the same or different, each represents an atomic group necessary for forming a 5- or 6-membered heterocyclic ring; Q represents an atomic group necessary for forming a 5- or 6-membered carbon ring or a 5- or 6-membered heterocyclic ring; A represents an oxygen atom or a sulfur atom; and n, d, and m each represents 0 or 1.
    Type: Grant
    Filed: September 1, 1989
    Date of Patent: November 20, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ikeda, Haruo Takei, Satoru Takimoto, Masaki Okazaki
  • Patent number: 4965184
    Abstract: Photographic, silver halide emulsions can be additionally sensitized without a deleterious increase in fog, by the addition of an alkali metal salt of 1-napthol-4-sulfonic acid. These emulsions are stable, and have good contrast and top density. The 1-napthol-4-sulfonic acid can be added conveniently from an aqueous solution and is totally compatible with conventional silver halide elements.
    Type: Grant
    Filed: February 23, 1989
    Date of Patent: October 23, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Raymond J. LeStrange
  • Patent number: 4960672
    Abstract: A silver halide photographic material is disclosed, comprising a support having thereon at least one of silver halide photographic emulsion layers and other hydrophilic colloidal layers, wherein said photographic emulsion layers or other hydrophilic colloidal layers contain a compound represented by formula (I): ##STR1## wherein at least one of A.sub.1 and A.sub.2 represents a hydrogen atom and the other represents a hydrogen atom, a sulfinic residual group, or ##STR2## wherein R.sub.0 represents an alkyl group, alkenyl group, aryl group, alkoxy group or aryloxy group, and l.sub.1 represents an integer 1 or 2; G represents ##STR3## wherein m.sub.1 represents an integer 1 or 2, sulfonyl group, sulfoxy group, ##STR4## wherein R.sub.
    Type: Grant
    Filed: May 3, 1989
    Date of Patent: October 2, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Kazunobu Katoh
  • Patent number: 4945036
    Abstract: A silver halide photosensitive material is described, comprising two or more monodisperse silver halide emulsions of different average grain size on a support, wherein at least one of the said monodisperse silver halide emulsions has an average grain size of at least 0.7 .mu.m, and at least one of the silver halide emulsions has a smaller average grain size than the other, the average grain size of the silver halide emulsion as a whole being within the range of from 0.33 to 0.54 .mu.m, with a coated silver weight of from 2.3 to 3.8 g/m.sup.2, and which contains a sensitizing dye represented by formula (I) ##STR1## wherein Z and Z.sub.1 each represents a group of non-metallic atoms forming a thiazole nucleus, a benzothiazole nucleus, or a benzoxazole nucleus; R.sub.0 represents an alkyl group having from 1 to 6 carbon atoms, an allyl group, or an aralkyl group; R and R.sub.1 each represents an alkyl group or an aryl group; L, L.sub.1, and L.sub.
    Type: Grant
    Filed: May 31, 1989
    Date of Patent: July 31, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoki Arai, Kazuo Kagawa
  • Patent number: 4925832
    Abstract: A silver halide photographic light sensitive emulsion containing a hydrazine of the general formulaR.sup.3 -NR.sup.4 -NR.sup.5 -G-X (I)in whichR.sup.3 represents an aryl group,one of R.sup.4 and R.sup.5 is a hydrogen and the other is selected from hydrogen, aryl sulphonyl and trifluoroacetyl,G represents carbonyl, sulphonyl, sulphoxy, phosphoryl or an N-substituted or unsubstituted imino group and X is a moiety such that at a pH in the range of 9.5 to 12.5 in the presence of an oxidized hydroquinone a cyclization reaction takes place cleaving the moiety -G-X from the remainder of the molecule and forming a cyclic structure comprising atoms of the moiety -G-X.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: May 15, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kevin P. Hall, Andrew W. Mott
  • Patent number: 4920040
    Abstract: A silver halide light-sensitive photographic material for a laser light exposure is disclosed. The material comprises a support having thereon at least one light-sensitive silver halide emulsion layer containing silver halide grains therein and a layer adjacent thereto, wherein said silver halide grains are spectrally sensitized with a dye represented by the following formula I, at least one layer of said silver halide emulsion layer and said adjacent layer contains a fluorine-containing ionic surfactant, a non-ionic surfactant and an inorganic salt; ##STR1## The material of the invention excels in each of sensitivity, gradation and maximum density, and exhibits good coloration.
    Type: Grant
    Filed: December 1, 1988
    Date of Patent: April 24, 1990
    Assignee: Konica Corporation
    Inventor: Kouzi Ono
  • Patent number: 4920032
    Abstract: A silver halide photosensitive material comprising at least one silver halide photographic emulsion layer provided on at least one side of a support, said photosensitive material containing in the photographic emulsion layer and/or another component layer (i) a polymer having repetitive units represented by formula (II), dextran or mixtures thereof, and (ii) at least one cationic compound containing quaternary nitrogen: ##STR1## wherein R.sup.1 represents hydrogen or an alkyl group with 1 to 6 carbon atoms; R.sup.2, and R.sup.3 each represents hydrogen, or, an unsubstituted or substituted alkyl, aryl or aralkyl group having up to 10 carbon atoms, or R.sup.2 and R.sup.3 are bonded to each other to form a nitrogen-containing heterocyclic ring; m represents 1 or 2; n represents 0 or 1; and L represents a linking group of the valence m+1.
    Type: Grant
    Filed: December 7, 1988
    Date of Patent: April 24, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ichizo Toya, Masakazu Yoneyama
  • Patent number: 4917991
    Abstract: A direct positive silver halide photographic material with an internal latent image-type silver halide emulsion layer that provides a direct positive image by a fogging treatment (for example, an overall exposure, or surface developing treatment in the presence of a fogging agent) after imagewise exposure. The silver halide particles which form the emulsion layer consist essentially of a core portion made of silver halide and having been chemically sensitized or doped with metal ions. There are provided a plural number of shell portions made of silver halide containing silver chloride. The chloride content of an inner shell adjacent to the outmost shell of the particles has a smaller amount of chloride content than that of the outermost shell. The photographic material is used by first imagewise exposing it to light, effecting overall fogging treatment on the silver halide particles and processing the exposed photographic material to produce the image.
    Type: Grant
    Filed: June 23, 1988
    Date of Patent: April 17, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Yasuo Tosaka, Keiji Ogi, Atushi Kamitakahara
  • Patent number: 4916053
    Abstract: A negative-tupe silver halide photographic material is provided, having high sensitivity and good graininess with low fog. The material has at least one silver halide emulsion layer on a support, wherein chemically-sensitized silver halide grains contained in the emulsion of said emulsion layer comprise normal crystalline grains, and said emulsion layer containing said normal crystalline silver halide grains contains a polymer having a repeating unit represented by formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom or an alkyl group; Q represents one group selected from formulae (i), (ii), (iii), and (iv); ##STR2## wherein q is an integer of from 2 to 4; ##STR3## wherein R.sup.2 and R.sup.3 each represents a hydrogen atom or an alkyl group; ##STR4## wherein Z.sup.1 represents an atomic group forming a lactam ring, an oxazolidone ring, or a pyridone ring;A represents a single bond, ##STR5## B represents --O-- or ##STR6## wherein R.sup.
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: April 10, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Ohshima, Toshiaki Hayakawa, Shunji Takada
  • Patent number: 4914003
    Abstract: A novel silver halide photographic material is provided comprising at least one light-sensitive silver halide emulsion layer provided on a support and containing at least one hydrazine compound and at least one amine compound of the general formula (I) in said emulsion layer or at least one of other constituting layers, provided that said hydrazine compound and said amine compound can be present in the same or different layers: ##STR1## wherein R.sup.2 and R.sup.3, which can be the same or different, each represents a substituted or unsubstituted alkyl group or R.sup.2 and R.sup.3 may be linked to each other to form a ring; R.sup.4 represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; A represents a divalent linkage group; X represents --CONR.sup.5 --, --OCONR.sup.5 --, --NR.sup.5 CONR.sup.5 --, --NR.sup.5 COO--, --COO--, --OCO--, --CO--, --NR.sup.5 CO--, --SO.sub.2 NR.sup.5 --, --NR.sup.5 SO.sub.2 --, --SO.sub.2 --, --S-- or --O-- group (in which R.sup.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: April 3, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Nobuaki Inoue
  • Patent number: 4897343
    Abstract: A spectrally sensitized silver halide photographic emulsion is disclosed, which comprises at least one alkali metal sulfite compound and at least one ascorbic acid compound.
    Type: Grant
    Filed: May 11, 1988
    Date of Patent: January 30, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ikeda, Haruo Takei, Shunichi Aida
  • Patent number: 4894323
    Abstract: A novel silver halide photographic material is provided comprising a support having provided thereon at least one silver halide emulsion layer and containing at least one polyoxyethylenic compound in the emulsion layer or at least one other hydrophilic colloid layer, wherein silver halide grains contained in the emulsion layer are chemically sensitized in the presence of a water-soluble sensitizing dye having a solubility in 20.degree. C. water of 0.2 g/100 ml H.sub.2 O or more, or said water-soluble sensitizing dye is added to the silver halide emulsion after chemical sensitization and before coating. Such a water-soluble sensitizing dye is preferably selected from methine dyes and styryl dyes such as a cyanine dye, a merocyanine dye, a hemicyanine dye, a rhodacyanine dye, an oxonol dye, and a hemioxonol dye.
    Type: Grant
    Filed: May 26, 1987
    Date of Patent: January 16, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyoshi Kawai, Mikio Ihama
  • Patent number: 4888272
    Abstract: A method for preparing a silver halide photographic emulsion is disclosed, comprising silver halide grains having silver halide protrusions on the surface of the silver halide grain matrix, wherein the silver halide grain matrix is chemically sensitized and then the silver halide protrusions are formed on the surface of the thus chemically sensitized silver halide grain matrix.
    Type: Grant
    Filed: March 31, 1988
    Date of Patent: December 19, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiichiro Kishida, Minoru Sato
  • Patent number: 4868089
    Abstract: A positive image forming method is disclosed. Said method comprises in sequence the steps of subjecting to imagewise exposure a silver halide photographic material having a silver halide emulsion layer containing a non-prefogged internal image forming silver halide, increasing the surface sensitivity of said silver halide in the substantial absence of water and performing development.
    Type: Grant
    Filed: April 13, 1988
    Date of Patent: September 19, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Tatsuhiko Kobayashi, Sohei Goto, Ken Okauchi
  • Patent number: 4853323
    Abstract: The present invention relates to a silver halide emulsion containing a thiocyanate and having a high sensitivity in particular to light of a low illuminance. According to the present invention, a silver halide emulsion is provided, wherein the IR absorbance at 2052 cm.sup.-1 due to thiocyanate ion contained in the silver halide grain of the emulsion is observed and a tricarboxylic acid or its salt is contained in the emulsion.
    Type: Grant
    Filed: October 15, 1986
    Date of Patent: August 1, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideo Ikeda, Shuzo Suga, Nobuaki Miyasaka
  • Patent number: 4849319
    Abstract: A negative silver halide photographic material comprising a support and at least one silver halide emulsion layer on the support, the emulsion layer or other hydrophilic colloid layer containing a hydrazine derivative, wherein the photographic material further contains an acid polymer and in which the pH of the surface of the photographic material is not more than 5.8. Also, a method for forming a superhigh contrast negative image using the above photographic material is disclosed.
    Type: Grant
    Filed: November 20, 1987
    Date of Patent: July 18, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Senzo Sasaoka, Hiroshi Hayashi
  • Patent number: 4845023
    Abstract: A silver halide photographic light-sensitive material comprising at least one layer of a silver halide emulsion on a support is improved in shelf stability by treating a chemically sensitized silver halide emulsion with an ion-exchange resin or a porous absorbent to remove residue of the chemical sensitizer during and/or after chemical sensitization.
    Type: Grant
    Filed: August 19, 1987
    Date of Patent: July 4, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Mifune
  • Patent number: 4840888
    Abstract: There is disclosed a light-sensitive silver halide photographic material having at least one silver halide emulsion layer on a support, which comprises the light-sensitive photographic material contains light-sensitive silver halide grains, metal salt grains having internal fog and a polyhydric alcohol having at least two hydroxyl groups having a melting point of 40.degree. C. or higher.
    Type: Grant
    Filed: October 27, 1988
    Date of Patent: June 20, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mikio Kawasaki, Hiroaki Shiozawa, Kakujulo Fukuouji, Kouji Ono
  • Patent number: 4839269
    Abstract: A light-sensitive material comprising a dye containing two or more cyclodextrin groups or derivatives thereof wherein the dye may serve as a spectral sensitizer and optionally, a compound which fluoresces light of a wavelength which can be absorbed by the dye.
    Type: Grant
    Filed: September 17, 1987
    Date of Patent: June 13, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaki Okazaki, Junichi Yamanouchi
  • Patent number: 4824764
    Abstract: A silver halide photographic material comprising a support having at least one light-sensitive silver halide emulsion layer on the support, wherein at least one of the emulsion layer and other constituent layers contains at least one compound represented by formula (I) and at least one compound represented by formula (II): ##STR1## wherein R.sub.0 is an organic group having 7 to 30 carbon atoms, A is a substituted or unsubstituted phenylene group, or a substituted or unsubstituted naphthylene group, and X is NH or 0, ##STR2## wherein R.sub.1 is an aliphatic, aromatic or heterocyclic group; R.sub.
    Type: Grant
    Filed: May 20, 1987
    Date of Patent: April 25, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Inagaki, Nobuaki Inoue
  • Patent number: 4818659
    Abstract: A silver halide photographic material for use in a bright room is disclosed comprising a support having thereon at least two silver halide emulsion layers, each of the emulsion layers having a different sensitivity and comprising silver chloride grains or silver chlorobromide grains having at least about 80 mol % silver chloride, each of the silver halide emulsions layers containing from about 1.times.10.sup.-7 mol to about 1.times.10.sup.-4 mol of a rhodium salt per mol of silver, wherein the sensitivity of the lower emulsion layer (the emulsion layer coated nearer to the support) is higher than the sensitivity of the upper emulsion layer (the emulsion layer coated farther from the support) and at least one of the silver halide emulsion layers or different hydrophilic colloid layers contains a hydrazine derivative and at least one of the silver halide emulsion layers of different hydrophilic colloid layers contains a dry compound having a .sup..lambda. max of from about 400 nm to about 550 nm.
    Type: Grant
    Filed: April 7, 1987
    Date of Patent: April 4, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiro Takahashi, Ken-ichi Kuwabara, Kimitaka Kameoka, Masahiro Okada
  • Patent number: 4814264
    Abstract: A silver halide light-sensitive material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer comprising silver halide grains and a binder, at least about 50 wt % of said silver halide grains comprising a silver halide grain matrix having thereon from about 10 to 10,000 protrusions per square micrometer of grain matrix surface, said individual protrusions having an average projected area diameter of up to about 0.15 .mu.m, and a halogen composition of said protrusions differing from that of the grain matrix; said silver halide emulsion being chemically sensitized with at least one compound selected from the group consisting of a sulfur compound, a selenium compound, a reducing compound and a noble metal compound; and said silver halide emulsion being spectrally sensitized with a methine dye.
    Type: Grant
    Filed: December 17, 1987
    Date of Patent: March 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiichiro Kishida, Minoru Sato
  • Patent number: 4801526
    Abstract: A silver halide photographic light-sensitive material comprising a specific silver halide grain is disclosed. The siliver halide grain contains a localized portion containing 20 mol % or more of silver iodide and average content of silver iodide of which grain is from 0.1 to 10.0 mol %, provided that the silver halide grain is prepared by mixing an aqueous solution containing a water soluble halide compound and an aqueous solution containing a water soluble silver salt under a condition that pAg of the mixture is raised at 9.7 or more during a period after a half amount of the silver salt to be used has been added to the mixture. The photographic light-sensitive material has improved photographic characteristics and is suitable for radiographic use.
    Type: Grant
    Filed: February 18, 1988
    Date of Patent: January 31, 1989
    Assignee: Konica Corporation
    Inventors: Eiji Yoshida, Akio Suzuki, Satoru Nagasaki, Masumi Arai, Iku Metoki, Haruhiko Sakuma
  • Patent number: 4798780
    Abstract: A silver halide photographic light sensitive emulsion containing a hydrazine of the general formulaR.sup.3 -NR.sup.4 -NR.sup.5 -G-X (I)in which:R.sup.3 represents an aryl group,one of R.sup.4 and R.sup.5 is a hydrogen and the other is selected from hydrogen, aryl sulphonyl and trifluoroacetyl,G represents carbonyl, sulphonyl, sulphoxy, phosphoryl or an N-substituted or unsubstituted imino group andX is a moiety such that at a pH in the range of 9.5 to 12.5 in the presence of an oxidized hydroquinone a cyclization reaction takes place cleaving the moiety -G-X from the remainder of the molecule and forming a cyclic structure comprising atoms of the moiety -G-X.
    Type: Grant
    Filed: June 29, 1987
    Date of Patent: January 17, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kevin P. Hall, Andrew W. Mott
  • Patent number: 4791053
    Abstract: A silver halide photographic material comprising a support having thereon at least one emulsion layer which contains a silver chlorobromide or silver chloride each having an iodide content of 3 mol % or less. The monodispersed emulsion is prepared in a process comprising the steps of, in sequence, forming silver halide grains which have a grain size distribution represented by a variation coefficient of 0.2 or less, causing halogen replacement in silver halide grains by addition of a water-soluble bromide in a proportion of from 0.6 to 20 mol % with respect to the total silver halide in the presence of at least one sensitizing dye selected from among simple cyanine dyes, carbocyanine dyes, and dicarbocyanine dyes at individual surfaces of the silver halide grains, and then subjecting the resulting silver halide grains to chemical sensitization, thereby achieving enhanced sensitivity and improved pressure characteristics.
    Type: Grant
    Filed: December 3, 1986
    Date of Patent: December 13, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadashi Ogawa
  • Patent number: 4789618
    Abstract: A silver halide photographic material having on a support at least one silver halide emulsion layer is disclosed, wherein the silver halide emulsion layer comprises a silver halide emulsion containing an oxidizing agent added thereto before chemical ripening of the emulsion, and the silver halide emulsion or a hydrophilic colloid layer contains a hydrazine derivative.
    Type: Grant
    Filed: May 7, 1986
    Date of Patent: December 6, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Senzo Sasaoka, Toshiro Takahashi
  • Patent number: 4777113
    Abstract: A negative silver halide photographic material comprising a support having provided thereon at least one light-sensitive silver halide emulsion layer and further provided on the light-sensitive halide layer at least two light-insensitive hydrophilic colloidal layers, the uppermost layer of the light-insensitive hydrophilic colloidal layers containing colloidal silica and the emulsion layer or other hydrophilic colloidal layer containing a hydrazine derivative. The material exhibits super-high contrast and is less susceptible to scratch fog.
    Type: Grant
    Filed: May 28, 1987
    Date of Patent: October 11, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Senzo Sasaoka, Tomoo Murakami
  • Patent number: 4767692
    Abstract: A novel silver halide photographic material is provided comprising a support and at least one silver halide photographic emulsion layer formed thereon and containing in said photographic emulsion layer or at least one hydrophilic colloid layer a compound represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, an aliphatic residual group, an aromatic residual group, or a heterocyclic residual group; R.sup.3 represents a hydrogen atom or an aliphatic residual group; L.sub.1 represents a divalent aliphatic group, a divalent aromatic group, or a divalent heterocyclic group; L.sub.2 represents --O--, --CONR--, --NRCO--, --SO.sub.2 NR--, --NRSO.sub.2 --, --OCO--, --COO--, --S--, --NR--, --CO--, --SO--, --SO.sub.2 --, --OCOO--, --NRCONR'--, --NRCOO--, --OCONR--, or --NRSO.sub.
    Type: Grant
    Filed: January 5, 1987
    Date of Patent: August 30, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Inagaki, Morio Yagihara, Shigeo Hirano