Electrically Insulating Overlayer Patents (Class 430/67)
  • Patent number: 5858592
    Abstract: A thin (<5 .mu.m) charge injection barrier layer is provided on a top surface of an inverse dual layer photoconductor using hole transport or on at least one surface of a single layer photoconductor or on an electrically conductive substrate of a conventional dual layer photoconductor using either hole transport or electron transport. The charge injection barrier layer comprises at least one terpolymer given by the formula ?A.sub.x B.sub.y C.sub.z !.sub.n, where A is a charge injection prohibitor to prevent leakage of charge from the surface, B is a solubility control moiety to control solubility of the polymer and its glass transition temperature, and C is an electron charge moiety for neutralizing surface charge. Each of the moieties A, B, and C contain a vinyl group. The value of x is at least about 0.01, y is within the range of about 0.01 to 0.3, and z is within the range of about 0.01 to 0.4, with the sum of x+y+z=1.
    Type: Grant
    Filed: June 12, 1997
    Date of Patent: January 12, 1999
    Assignee: Hewlett-Packard Company
    Inventors: Khe C. Nguyen, Sivapackia Ganapathiappan
  • Patent number: 5856013
    Abstract: Electrical components comprising a ohmic contact-providing layer and a charge transport layer wherein the ohmic contact-providing layer comprises a fluorinated carbon filled fluoropolymer.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: January 5, 1999
    Inventors: Martin A. Abkowitz, Frederick E. Knier, Jr., Ihor W. Tarnawskyj, Milan Stolka, Joseph Mammino, Kock-Yee Law
  • Patent number: 5849445
    Abstract: A photoconductive element comprising an electrically conductive base; two or more charge generation layers; at least one charge transport layer; and a protective layer comprising diamond-like carbon, having fluorine between 0 and 65 atomic percent of the protective layer.
    Type: Grant
    Filed: February 13, 1998
    Date of Patent: December 15, 1998
    Assignee: Eastman Kodak Company
    Inventors: Susan A. Visser, Donald S. Rimai, Paul M. Borsenberger, Suryadevara V. Babu
  • Patent number: 5849446
    Abstract: A light receiving member comprising a electrically conductive substrate, a photoconductive layer composed of a non-single crystalline material containing at least silicon atoms as a matrix formed on said substrate by decomposing a silicon-containing raw material gas, and a surface protective layer composed of a non-single crystalline carbon material containing hydrogen formed on said photoconductive layer by decomposing a raw material gas comprising at least a hydrocarbon using a high frequency power with an oscillation frequency of 50 MHz to 450 MHz, wherein a 20 .ANG. or more thick surface side layer region of said surface protective layer composed of said non-single crystalline carbon material is etched at an etching speed of 0.1 to 50 .ANG./sec. by means of a fluorine-containing plasma produced by decomposing a fluorine-containing gas using a high frequency power with an oscillation frequency of 50 MHz to 450 MHz such that said surface protective layer has a thickness of 100 to 10000 .ANG.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: December 15, 1998
    Assignee: Canon Kabushiki Kaisha
    Inventors: Junichiro Hashizume, Shigenori Ueda, Makoto Aoki
  • Patent number: 5840455
    Abstract: An electrophotographic photoconductor, having a conductive supporting substrate, a photoconductive layer disposed thereon, and a surface protective layer formed on the photoconductive layer, with the surface protective layer being made of hydrogenated diamond-like carbon or hydrogenated amorphous carbon and containing at least one additional element selected from the group consisting of nitrogen, fluorine, boron, phosphorus, chlorine, bromine and iodine, with the atomic ratio of total additional elements to carbon in the surface protective layer being smaller in close proximity to the photoconductive layer than in the remainder of the surface protective layer, and having a Knoop hardness of more than or equal to 1000 kg/mm.sup.2 in the outermost portion of the surface protective layer is provided which has improved resistance against peeling and scratch, and is thus capable of forming electrophotographic images of high quality for repeated use over an extended period of time.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: November 24, 1998
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Ikuno, Narihito Kojima, Hiroshi Nagame
  • Patent number: 5834147
    Abstract: A photosensitive member for electrophotography having excellent electrophotographic characteristics such as chargeability, photosensitivity and dark attenuation, excellent corona resistance and excellent durability, which comprises an electrically conductive support and a photosensitive layer containing a resin binder and particles of a photoconductive phthalocyanine compound dispersed in said binder, said photosensitive layer containing at least one member selected from the group consisting of an electron acceptive material, a coupling agent, an antioxidant and a hydroxyl group-containing polymer.
    Type: Grant
    Filed: August 2, 1996
    Date of Patent: November 10, 1998
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Suguru Nagae, Kazuko Wakita, Toshio Kobayashi, Yoshimi Sugimoto, Sei Tsunoda, Kikuo Hayama, Koe Enmanji
  • Patent number: 5756246
    Abstract: This invention is a photoreceptor element comprising, in order, an electroconductive support, a photoconductive layer, a barrier, and, preferably, a release layer. The barrier is a two layer system comprising:1) adjacent to the photoconductive layer, a non-conductive, charge blocking layer, and2) over the non-conductive, charge blocking layer, an electrically conductive barrier layer.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: May 26, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Edward J. Woo, David A. Ender
  • Patent number: 5739037
    Abstract: A process for the elimination of labile glycohaemoglobin from a sample comprises adding to the sample a reagent comprising a temperature dependent buffer having a pH/temperature coefficient of -0.011 or less, and a method for measuring the concentration of stable glycohaemoglobin in sample containing stable and labile glycohaemoglobin fractions.
    Type: Grant
    Filed: January 27, 1997
    Date of Patent: April 14, 1998
    Assignee: Drew Scientific Limited
    Inventors: Andrew C. Kenney, Maria D. Adewunmi
  • Patent number: 5731117
    Abstract: Glassy solid electrolytes and charge transporting elements including antistatic elements and charge generating elements. The charge generating element has an electrically conductive layer, a charge generating layer overlying the electrically conductive layer, and a layer of glassy solid electrolyte overlying the electrically conductive layer. The glassy solid electrolyte includes a complex of silsesquioxane and a charge carrier. The complex has a surface resistivity from about 1.times.10.sup.10 to about 1.times.10.sup.17 ohms/sq. The complex has a T.sup.2 -silicon:T.sup.3 -silicon ratio of less than 1 to 1. The complex has a ratio of carbon atoms to silicon atoms of greater than about 1.2 to 1.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: March 24, 1998
    Assignee: Eastman Kodak Company
    Inventors: Wayne Thomas Ferrar, Jane Robin Cowdery-Corvan, Edward T. Miskinis, Catherine Newell, Donald S. Rimai, Louis Joseph Sorriero, John Anthony Sinicropi, David Steven Weiss, Nicholas Zumbulyadis
  • Patent number: 5728498
    Abstract: A flexible electrophotographic imaging member including a supporting substrate coated with at least one imaging layer comprising hole transporting material containing at least two long chain alkyl carboxylate groups dissolved or molecularly dispersed in a film forming binder.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: March 17, 1998
    Assignee: Xerox Corporation
    Inventors: John F. Yanus, William W. Limburg, Dale S. Renfer, Richard L. Schank, Merlin E. Scharfe, Damodar M. Pai, Paul J. DeFeo
  • Patent number: 5728499
    Abstract: An electrophotographic photoreceptors having a protective layer which contains a specially cross-linked phenolic resin. The cross-linked phenolic resin contains both methylene ether linkages and methylene linkages that are provided such that the oxygen element content of the cross-linked phenolic resin contains no greater than 23.5 wt %, or more preferably between about 21 wt % and 23.5 wt %, of oxygen atoms. In a preferred embodiment, the specially cross-linked phenolic resin is formed by (a) raising the cross-linking temperature from 80.degree..+-.10.degree. C. to about 130.degree. C., in a cascading manner involving at least one intermediate treatment temperature; then (b) lowering the cross-linking temperature from about 130.degree. C. to 80.degree..+-.10.degree. C. The protective layer improves the chemical stability and mechanical strength of the electrophotographic photoreceptor while retaining the desired photoelectric properties thereof.
    Type: Grant
    Filed: June 13, 1997
    Date of Patent: March 17, 1998
    Assignee: Sinonar Corp.
    Inventors: Tzea-Ching Hung, Chen-Jen Yang, Kuo-Chu Yeh
  • Patent number: 5723242
    Abstract: This invention is a photoconductive element comprising an electroconductive substrate, a photoconductive layer on a surface of the electroconductive substrate, and a release layer over the photoconductive layer. The release layer comprises a fluoroether polymer which is the reaction product of components comprising: A) a di-functional perfluoroether, B) a diisocyanate, C) an amino functional silane, and D) optionally, a diol chain extender.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: March 3, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Edward J. Woo, Gaye K. Lehman
  • Patent number: 5714248
    Abstract: An imaging member comprised of a supporting substrate with a coating thereover and wherein the coating is comprised of resin, electrically conductive metal oxide particles, and insulative metal oxide particles, wherein each electrically conductive particle is substantially electrically isolated and separated from any other of the electrically conductive particles by the insulative particles.
    Type: Grant
    Filed: August 12, 1996
    Date of Patent: February 3, 1998
    Assignee: Xerox Corporation
    Inventor: Richard B. Lewis
  • Patent number: 5707767
    Abstract: An electrophotographic imaging member having includinga supporting substrate having an electrically conductive surface,a hole blocking layer, an optional adhesive layer,a charge generating layer,a charge transport layer,an optional anticurl back coating,a ground strip layer andan optional overcoating layer,at least one of the charge transport layer, anticurl back coating, ground strip layer and overcoating layer comprising a silica particle clusters homogeneously distributed in a film forming matrix.
    Type: Grant
    Filed: November 19, 1996
    Date of Patent: January 13, 1998
    Assignee: Xerox Corporation
    Inventor: Robert C. U. Yu
  • Patent number: 5702803
    Abstract: The invention provides electrographic imaging sheets comprising a substrate carrying a layer of dielectric material which has abhesive properties suitable for the release of a multicolored toner image from the dielectric surface during image transfer, while also having good toning properties during the several development stages of a multicolor toner imaging process.
    Type: Grant
    Filed: July 16, 1992
    Date of Patent: December 30, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: John F. Eisele, Valdis Mikelsons, Gaye K. Lehman, Paul J. Wang, Patricia J. A. Brandt
  • Patent number: 5695898
    Abstract: An electrophotographic photosensitive member having a protective layer which comprises electroconductive particles and a binding resin, wherein the difference between the reflex indices of the electroconductive particles and binding resin is 0.3 or less.
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: December 9, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shintetsu Go, Koichi Suzuki, Kazuma Sato, Akira Shimada
  • Patent number: 5693442
    Abstract: A charge generating element having an electrically conductive layer, a charge generating layer overlying the electrically conductive layer, and an overcoat overlying the charge generating layer. The overcoat includes dye and a complex of inorganic oxide polymer and a charge carrier. The overcoat has a surface resistivity of from about 1.times.10.sup.10 to about 1.times.10.sup.17 ohms/sq.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: December 2, 1997
    Assignee: Eastman Kodak Company
    Inventors: David Steven Weiss, Wayne Thomas Ferrar, Jane Robin Cowdery-Corvan, John Anthony Sinicropi, Marie B. O'Regan
  • Patent number: 5679488
    Abstract: Disclosed is an electrophotographic photoreceptor comprising a conductive support and provided thereon an intermediate layer, a carrier generation layer and a carrier transport layer, wherein an outermost layer of said electrophotographic photoreceptor contains silica particle each containing an aluminium ingredient of not more than 1000 ppm, a calcium ingredient of not more than 300 ppm and a iron ingredient of not more than 1000 ppm, and said silica particles have a volume average particle size of 0.05 through 5 .mu.m.
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: October 21, 1997
    Assignee: Konica Corporation
    Inventors: Akihiko Itami, Yoshiaki Takei, Chikusa Fukumoto, Takeo Oshiba, Yoshihiko Etoh
  • Patent number: 5665503
    Abstract: A positive charge type organic photoconductor in which the surface of the photoconductor having a film thickness of from 10 to 30 .mu.m and containing at least from 15 to 40% by weight of a phthalocyanine type photoconductive compound in a resin binder, is treated with a reactive monomer or oligomer capable of extinguishing ionic active and radical active parts.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: September 9, 1997
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Sei Tsunoda, Toshio Kobayashi, Shigeo Tsuda, Kikuo Hayama, Hiromi Yamada
  • Patent number: 5656406
    Abstract: An electrophotographic photoconductor includes an electroconductive support; a photoconductive layer formed on the electroconductive support; and a surface protective layer formed on the photoconductive layer, the surface protective layer having a hydrogen-containing diamond-like carbon structure or amorphous carbon structure, which contains at least one additive element selected from the group consisting of nitrogen, fluorine, boron, phosphorus, chlorine, bromine and iodine, with the atomic ratio of the additive element to the carbon in the carbon structure having such a distribution in the direction of the thickness of the surface protective layer that the atomic ratio is smaller in the vicinity of the top surface of the surface protective layer and in the vicinity of the photoconductive layer adjacent to the surface protective layer than in the other portion of the surface protective layer.
    Type: Grant
    Filed: January 11, 1995
    Date of Patent: August 12, 1997
    Assignees: Ricoh Company, Ltd., Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Hiroshi Ikuno, Narihito Kojima, Hiroshi Nagame, Shunpei Yamazaki, Shigenori Hayashi
  • Patent number: 5656404
    Abstract: A light receiving member having a light receiving layer comprising a photoconductive layer and a surface layer disposed on a conductive substrate, wherein the photoconductive layer comprises, from the side of the substrate, a first photoconductive layer constituted by an amorphous material containing silicon atoms as a matrix, carbon atoms, hydrogen atoms and fluorine atoms, and a second photoconductive layer constituted by an amorphous material containing silicon atoms as a matrix, and at least one kind of atoms selected from hydrogen atoms and fluorine atoms, wherein the content of said fluorine atoms in the first photoconductive layer is from 1 to 95 atomic ppm based on the content of said silicon atoms.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: August 12, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroaki Niino, Tetsuya Takei, Ryuji Okamura, Toshiyasu Shirasuna, Shigeru Shirai
  • Patent number: 5652078
    Abstract: This invention is a photoconductive assembly comprising an electroconductive substrate, a photoconductive layer on a surface of the electroconductive substrate, and a release layer over the photoconductive layer wherein the release layer comprises a silicone polymer which has a bimodal distribution of chain lengths between cross-links.
    Type: Grant
    Filed: August 30, 1996
    Date of Patent: July 29, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Claire A. Jalbert, Gaye K. Lehman, James F. Sanders, David J. Schreifels, Edward J. Woo
  • Patent number: 5626998
    Abstract: An overcoating for an electrophotographic imaging member includes an amorphous fluoropolymer overcoating layer.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 6, 1997
    Assignee: Xerox Corporation
    Inventors: Edward F. Grabowski, Anita P. Lynch, Emery G. Tokoli, deceased
  • Patent number: 5591558
    Abstract: An electrostatic image forming method is disclosed. The photoreceptor containing an organic photosensitive material has a layer containing fine particles at the photoreceptor surface; toner has at least binder resin, coloring agent, and releasing agent made of polyolefines in which the ratio, Mz/Mn, is is 3-20, and Mz is 20,000-70,000 wherein Mz is Z-average molecular weight in terms of polypropylene and Mn is the number average molecular weight in terms of polypropylene. No offset phenomenon occurs, and a stable image having no fogging and no black-spots can be formed for a long period of time by the invention.
    Type: Grant
    Filed: February 20, 1996
    Date of Patent: January 7, 1997
    Assignee: Konica Corporation
    Inventors: Hiroshi Yamazaki, Takeo Oshiba, Yoshihiko Etoh
  • Patent number: 5582945
    Abstract: A photoconductive member, comprises a support for a photoconductive member and an amorphous layer which is constituted of silicon atoms as matrix containing at least one of hydrogen atom and halogen atom and exhibits photo-conductivity, said amorphous layer having a layer region containing carbon atoms in at least a part thereof, the content of the carbon atoms in said layer region being distributed unevenly in the direct on of the thickness of said layer.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 10, 1996
    Inventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda
  • Patent number: 5561507
    Abstract: An apparatus and method for producing an electrostatic image is disclosed. A thin layer of hydrophobic particles is coated on the surface of the charge bearing member which can be a photoconductor or a dielectric. The hydrophobic particles may also be used on the developer roller which applies the toner. A liquid toner made substantially of a hydrophilic liquid, such as water, and suspended pigment binders is used. The invention is applicable to both one and multiple color systems.
    Type: Grant
    Filed: July 8, 1994
    Date of Patent: October 1, 1996
    Assignees: Page Station Technology, Inc., Technogenesis, Inc.
    Inventors: Loren Shelffo, Kensuke Fukae
  • Patent number: 5561021
    Abstract: An electrophotographic photosensitive member comprising a substrate, a light receiving layer having a photoconductive layer composed of a non-single crystal material containing silicon atoms as a matrix and having photoconductivity disposed on said substrate, and a surface protective layer disposed on said light receiving layer, characterized in that said surface protective layer comprises a metal oxide film formed by adjusting the surface of said light receiving layer to have a contact angle against water of 80.degree. or more, applying a sol liquid comprising an organometallic compound admixed with water, an alcohol and an acid onto the surface of said light receiving layer, and subjecting the resultant to heat treatment. An electrophotographic apparatus provided with said electrophotographic photosensitive member. A process for the production of said electrophotographic photosensitive member.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: October 1, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koji Yamazaki, Shigenori Ueda, Toshiyuki Ehara, Hiroaki Niino, Masaya Kawada
  • Patent number: 5556730
    Abstract: In organic photoconductors (OPC's) for electrophotography, a barrier layer is placed on top of the OPC. The barrier may have 2 layers--1, an electron withdrawing layer on top of the OPC; and,--2, an electron donating layer on top of the electron withdrawing layer. The barrier layer comprises: 1. a crosslinked polymer binder; 2. a charge injection prohibiter molecule, and optionally; 3. an electron withdrawing molecule. This formulation has resulted in a long-life OPC with more than 50,000 good cycles at high severity test conditions. The OPC had not only long life during continuous use, but also long shelf life and long on-again/off-again operation life.
    Type: Grant
    Filed: November 1, 1995
    Date of Patent: September 17, 1996
    Assignee: Hewlett-Packard Company
    Inventor: Khe C. Nguyen
  • Patent number: 5556729
    Abstract: An electrophotographic photoreceptor comprising: an electrically conductive substrate, a charge injection blocking layer formed on said electrically conductive substrate, a photoconductive layer comprising a single layer formed on said charge injection blocking layer, said photoconductive layer comprising amorphous silicon containing boron, a positive hole capturing layer formed on said photoconductive layer, said positive hole capturing layer being selected from the group comprising amorphous silicon containing less than 50 ppm boron and amorphous silicon being substantially composed of hydrogen and silicon atoms, and a surface layer formed on said positive hole capturing layer. The boron concentration contained in said photoconductive layer is 0.01-1000 ppm. The surface layer is formed by amorphous silicon nitride, amorphous silicon oxide, amorphous silicon carbide or amorphous carbon as a main body. The charge injection blocking layer has amorphous silicon as a main body and contains a group V element.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: September 17, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yuzuru Fukuda, Tsuyoshi Ohta, Masato Ono, Taketoshi Higashi, Shigeru Yagi
  • Patent number: 5554474
    Abstract: A member for electrically cooperating with a conductive support surface to attract charged toner particles from the surface towards the member is disclosed. The member comprises a conductive substrate capable of supporting a uniform bias potential thereon and at least one coating comprising a resilient elastomeric polyurethane.
    Type: Grant
    Filed: June 30, 1994
    Date of Patent: September 10, 1996
    Assignee: Eastman Kodak Company
    Inventors: William B. Vreeland, John C. Wilson, Mark C. Zaretsky
  • Patent number: 5545500
    Abstract: There is provided an improved light receiving member comrpsing a substrate and a light receiving layer formed by laminating a first layer having photoconductivity which is constituted with an amorphous material containing silicon atoms as the main constituent atoms and germanium atoms, and a second layer constituted with an amorphous material containing silicon atoms, carbon atoms and an element for controlling the conductivity. The germanium atoms contained in the first layer are in the state of being unevenly distributed in the entire layer region or in the partial layer region adjacent to the substrate. The first layer may contain one or more kinds selected from an element for controlling the conductivity, oxygen atoms and nitrogen atoms in the entire layer region on in the partial layer region.
    Type: Grant
    Filed: May 19, 1994
    Date of Patent: August 13, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shigeru Shirai, Shigeru Ohno
  • Patent number: 5538826
    Abstract: An electrophotographic photosensitive member having a surface layer comprising a bisphenol Z-type polycarbonate resin is charged by contact charging. The charged electrophotographic photosensitive member is then subjected to imagewise exposure to form an electrostatic latent image on the photosensitive member, the thus formed electrostatic latent image on the electrophotographic photosensitive member is developed. The electrophotographic photosensitive member shows good resistance to wearing and toner sticking when subjected to electrophotographic image formation including a contact charging process.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: July 23, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hideyuki Ainoya, Toshiyuki Yoshihara, Hideki Anayama, Itaru Yamazaki, Hidetoshi Hirano, Mayumi Kimura
  • Patent number: 5536610
    Abstract: The present invention provides a photosensitive member composed of a photosensitive layer and a surface protective layer on an electrically substrate in this order, in which the surface protective layer comprises an amorphous carbon layer which has a specified ratio of absorptivity coefficients of infrared absorption peaks in infrared absorption spectrum.
    Type: Grant
    Filed: December 9, 1994
    Date of Patent: July 16, 1996
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventors: Seishi Ojima, Kenji Masaki, Takeshi Kakutani, Toshiyuki Kobayashi, Isao Doi, Izumi Osawa
  • Patent number: 5534392
    Abstract: There is provided an improved light receiving member comrpsing a substrate and a light receiving layer formed by laminating a first layer having photoconductivity which is constituted with an amorphous material containing silicon atoms as the main constituent atoms and germanium atoms, and a second layer constituted with an amorphous material containing silicon atoms, carbon atoms and an element for controlling the conductivity. The germanium atoms contained in the first layer are in the state of being unevenly distributed in the entire layer region or in the partial layer region adjacent to the substrate. The first layer may contain one or more kinds selected from an element for controlling the conductivity, oxygen atoms and nitrogen atoms in the entire layer region on in the partial layer region.
    Type: Grant
    Filed: June 21, 1994
    Date of Patent: July 9, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shigeru Shirai, Shigeru Ohno
  • Patent number: 5525447
    Abstract: An electrophotographic photoconductor includes an electroconductive support; a photoconductive layer formed on the electroconductive support; and a surface protective layer formed on the photoconductive layer, the surface protective layer having a hydrogen-containing diamond-like carbon structure or amorphous carbon structure, containing therein an additive element selected from the group consisting of nitrogen, fluorine, boron, phosphorous, chlorine, bromine and iodine, with the atomic ratio of the additive element to the carbon contained in the surface protective layer being larger in the vicinity of the top surface of the surface protective layer than in the vicinity of the photoconductive layer adjacent to the surface protective layer.
    Type: Grant
    Filed: October 7, 1994
    Date of Patent: June 11, 1996
    Assignees: Ricoh Company, Ltd., Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Hiroshi Ikuno, Narihito Kojima, Hiroshi Nagame, Shunpei Yamazaki, Shigenori Hayashi
  • Patent number: 5518847
    Abstract: An improved organic photoconductor is disclosed which comprises: (a) a conductive substrate; (b) a charge generation layer; (c) a charge transport layer; and (d) a reinforcing overcoating layer. The reinforcing overcoating layer contains a polymer resin prepared from a reaction mixture comprising: (i) about 87 to 94 wt % of a bifunctional 3,9-divinyl spirobi(m-dioxane) and styrene; (ii) about 5 to 8 wt % of maliec acid di-allyl ester; and (iii) about 1 to 5 wt % of a heat-induced polymerization initiator. The organic photoconductor exhibits light and heat stability and abrasion resistance comparable to those of inorganic photoconductors, but it eliminates many of the shortcomings, such as toxicity and enviromental pollution problems, that have been recognized as being associated with the inorganic photoconductors. Furthermore, the provision of this overcoating layer does not cause any loss of performance, as measured by the residual potential under various test conditions.
    Type: Grant
    Filed: August 14, 1995
    Date of Patent: May 21, 1996
    Assignee: Industrial Technology Research Institute
    Inventor: Chih-Chiang Chen
  • Patent number: 5514507
    Abstract: An electrophotographic photoreceptor for positive electrification comprising at least an electroconductive layer, a charge injection blocking layer, a photoconductive layer and a surface layer. The photoconductive layer comprises a layer having an amorphous silicon layer containing one or more of hydrogen, halogen and a Group III element for controlling electroconductivity and layer having an amorphous silicon germanium layer containing at least hydrogen, halogen and a Group III element. The charge injection blocking layer comprises an amorphous silicon layer containing hydrogen and a Group III element in an amount of equal or less than 1000 ppm. The electrophotographic photoreceptor has excellent electrification characteristics with dark and light sensitivities, stability against repetitive use and may be utilized as a photoreceptor for a semiconductor laser beam printer.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: May 7, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Shigeru Yagi, Tsuyoshi Ohta
  • Patent number: 5504559
    Abstract: The present invention relates to a method for image formation in which an electrostatic latent image is formed on an image supporting member having a carbon-based high-hardness surface coating layer. The electrostatic latent image is developed with a toner which includes resin particles composed of at least a binder resin and a colorant, specific fine particles fixed on the surface of the resin particles and post-treatment fine particles mixed with the resin particles on the surface of which the fine particles are fixed. The fine particles prevent the post-treatment fine particles from being embedded in the resin particles. The developed toner image is then transferred onto a transfer member to form the image.
    Type: Grant
    Filed: August 29, 1994
    Date of Patent: April 2, 1996
    Assignee: Minolta Co., Ltd.
    Inventors: Seishi Ojima, Izumi Osawa
  • Patent number: 5485250
    Abstract: An electrophotographic apparatus is disclosed which has an electrophotographic photosensitive member and a transfer device. The photosensitive member has a conductive support and a photosensitive layer, and further has a surface layer formed of a binder resin, fluorine atom- or silicon atom-containing compound particles incompatible with the binder resin, and a fluorine atom- or silicon atom-containing compound compatible with the binder resin. In the surface layer, the proportion of fluorine atoms and silicon atoms to carbon atoms, (F+Si)/C, as measured by X-ray photoelectron spectroscopy is 0.01 to 1.0. Additionally, the transfer device is a multiple-transfer device.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: January 16, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Noboru Kashimura, Harumi Sakoh, Kazushige Nakamura, Shoji Amamiya, Takashige Kasuya, Haruyuki Tsuji, Masaaki Yamagami, Tatsuya Ikezue
  • Patent number: 5480759
    Abstract: An electrophotographic toner showing a good fixability onto recording paper is constituted by at least a binder resin and a colorant, the binder resin comprising a resin component having a polar group, the binder resin having a molecular weight distribution according to gel permeation chromatography including a peak in a molecular weight region of 5.times.10.sup.3 -5.times.10.sup.4. The toner is used to develop an electrostatic image formed on a electrophotographic photosensitive member including at least an electroconductive support, a charge generation layer and a charge transport layer, and the resultant toner image is transferred onto a recording medium without difficulties such as occurrence of cracks on the photosensitive member or inferior transferability by using a photosensitive member having a surface layer containing a transition metal atom at 0.1-10 ppm.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: January 2, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashige Kasuya, Noboru Kashimura, Tatsuya Nakamura, Tatsuhiko Chiba, Kohji Inaba
  • Patent number: 5462827
    Abstract: A negative-charging electrophotographic photoreceptor comprising an electrically conductive support having consecutively thereon (a) a charge injection prevention layer having a thickness of from 0.15 to 10 .mu.m, (b) a photoconductive layer, and (c) a surface layer, the charge injection prevention layer (a) comprising amorphous silicon containing at least one of a hydrogen atom and a halogen atom, and containing a nitrogen atom in an atomic ratio of from 0.01 to 0.65 to the silicon atom, the photoconductive layer (b) comprising amorphous silicon containing at least one of a hydrogen atom and a halogen atom.
    Type: Grant
    Filed: January 18, 1994
    Date of Patent: October 31, 1995
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Shigeru Yagi, Masato Ono, Taketoshi Higashi, Tsuyoshi Ohta, Yuzuru Fukuda
  • Patent number: 5459009
    Abstract: A process for producing an electrophotographic photoreceptor comprising the steps of forming a photoconductive layer on a conductive substrate in a reaction chamber, and after the photoconductive layer is formed, forming a surface protection layer on the photoconductive layer by introducing into the reaction chamber a gaseous mixture comprising (i) a first component, fluorohydrocarbon gas, and (ii) a second component silicon, hydride gas, or a hydrocarbon gas and/or hydrogen gas and decomposing the gaseous mixture by glow discharge, wherein the surface protection layer thus formed comprises amorphous silicon carbide when the second component is a silicon hydride gas or amorphous carbon when the second component is a hydrocarbon gas and/or hydrogen gas. The surface protection layer exhibits sufficient hardness to protect the photoconductive layer from frictional scratches and other related damage.
    Type: Grant
    Filed: December 10, 1990
    Date of Patent: October 17, 1995
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yuzuru Fukuda, Masayuki Nishikawa, Masato Ono, Noriyoshi Takahashi, Shigeru Yagi, Ken-ichi Karakida
  • Patent number: 5455135
    Abstract: An electrophotographic photosensitive member includes an electroconductive substrate, a photosensitive layer disposed on the electroconductive substrate, and a protective layer disposed on the photosensitive layer, the protective layer containing a resin formed by polymerization of compounds each having two or more ion polymerizable functional groups, and electroconductive particles.
    Type: Grant
    Filed: December 16, 1993
    Date of Patent: October 3, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akio Maruyama, Kazushige Nakamura, Shoji Amamiya, Shin Nagahara, Haruyuki Tsuji, Masaaki Yamagami, Michiyo Sekiya
  • Patent number: 5407768
    Abstract: An electrophotographic light-receiving member comprising a conductive substrate 101 and laminated thereto a non-monocrystalline material photoconductive layer 102 and a surface layer 103. The photoconductive layer 102 is mainly composed of silicon atoms and contains at least carbon atoms and hydrogen atoms. The percentage of carbon atoms having a carbon-carbon bond in the photoconductive layer is controlled to be not more than 60% based on the whole carbon atoms contained therein, and, in an instance in which a blocking layer 104 is provided between the conductive substrate 101 and the photoconductive layer 102, the percentage of carbon atoms having a carbon-carbon bond in the blocking layer is also controlled. This makes it possible to prevent clusters of carbon atoms from being formed in the photoconductive layer or blocking layer.
    Type: Grant
    Filed: April 23, 1993
    Date of Patent: April 18, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuyoshi Akiyama, Masaaki Yamamura, Ryuji Okamura, Koji Hitsuishi
  • Patent number: 5399452
    Abstract: An electrophotographic photoreceptor comprising an electroconductive support having thereon a light-sensitive layer. At least the outermost layer of the light-sensitive layer contains (1) fine grains of at least one of a melamine-formaldehyde condensate and a benzoguanamine-formaldehyde condensate, and, as a binder resin, a polycarbonate resin comprising a constitutive unit represented by formula (II); or (2) fine grains of a benzoguanamine-melamine-formaldehyde condensate having an average grain size of from 0.03 to 4 .mu.m.
    Type: Grant
    Filed: January 26, 1993
    Date of Patent: March 21, 1995
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Ichiro Takegawa, Kazuyuki Nakamura, Kiyokazu Mashimo, Tomoo Kobayashi, Toru Ishii, Yutaka Akasaki
  • Patent number: 5395716
    Abstract: An improved electrophotographic recording material of the type comprising an electrically conductive substrate having a blocking layer composed of an amorphous material including silicon atoms, hydrogen atoms and carbon atoms disposed on the substrate, and a photoconductive layer of hydrogenated amorphous silicon disposed on the blocking layer. The photoconductive layer includes carbon atoms, the blocking layer and the photoconductive layer are doped with an element of Group III of the Periodic Table of Elements, and the ratio of the carbon percentage to the percentage of the element of Group III of the Periodic Table of Elements is the same in the blocking layer and in the photoconductive layer.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: March 7, 1995
    Assignee: Licentia Patent-Verwaltungs-GmbH
    Inventors: Klaus Schade, Alfred Kottwitz, Gunnar Suchaneck, Jens-Peter Monch, Sabine Dreihofer, Manfred Lutz
  • Patent number: 5391446
    Abstract: An image holding member rich in durability and suitably used as an electrophotographic photosensitive member or an electrostatic image-holding dielectric member is prepared by coating a support with a resinous layer formed by polymerization of a phosphazene polyene represented by the following formida: ##STR1## wherein R.sub.1 denotes an ethylenically unsaturated group, preferably an acrylic group represented by --R.sub.2 --OCO--C(R.sub.3)=CH.sub.2, wherein R.sub.2 denotes an alkylene group, arylene group, alkyl-substituted arylene group, alkylamide group or arylamide group, and R.sub.3 denotes a hydrogen atom or a methyl group. The resinous layer may constitute a photosensitive layer, a dielectric layer, or a protective layer covering these layers.
    Type: Grant
    Filed: July 2, 1991
    Date of Patent: February 21, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Noriko Ohtani, Akio Maruyama, Shin Nagahara, Shinya Mayama
  • Patent number: 5385797
    Abstract: An electrophotographic photosensitive member has an electroconductive support, a photosensitive layer, and a protection layer in named order. The protection layer contains a binder resin and a particulate electroconductive material. The particulate electroconductive material has been treated for adhesion of a siloxane compound represented by Formula (1) and subsequently is heat-treated at a temperature of not lower than 120.degree. C.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: January 31, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shin Nagahara, Akio Maruyama, Haruyuki Tsuji
  • Patent number: 5374494
    Abstract: The present invention provides an electrophotographic photosensitive member which has a surface layer of high hardness, high resistance to abrasion and scratching, and high durability. The surface layer of the photosensitive member contains a polymerization product of a monomer compound represented by the formula (1) or (2).
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: December 20, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Noboru Kashimura, Harumi Sakoh
  • Patent number: RE35198
    Abstract: Image-forming member for electrophotography comprising a charge generation layer composed of hydrogenated amorphous silicon.
    Type: Grant
    Filed: September 15, 1993
    Date of Patent: April 2, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Katsumi Nakagawa, Toshiyuki Komatsu, Yutaka Hirai, Teruo Misumi, Tadaji Fukuda