Electrically Insulating Overlayer Patents (Class 430/67)
  • Patent number: 4606934
    Abstract: A process for forming an overcoated electrophotographic imaging member comprising applying on an electrophotographic imaging member a coating in liquid form comprising a cross-linkable siloxanol-colloidal silica hybrid material having at least one silicon bonded hydroxyl group per every three --SiO-- units and a catalyst for the cross-linkable siloxanol-colloidal silica hybrid material, the coating in liquid form having an acid number less than about 1 and curing the cross-linkable siloxanol-colloidal silica hybrid material until the siloxanol-colloidal silica hybrid material forms a hard cross-linked solid organosiloxane-silica hybrid polymer layer.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: August 19, 1986
    Assignee: Xerox Corporation
    Inventors: Lieng-Huang Lee, Deborah J. Nichol-Landry, Christine J. Tarnawskyj
  • Patent number: 4600670
    Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.
    Type: Grant
    Filed: March 23, 1984
    Date of Patent: July 15, 1986
    Inventor: Shunpei Yamazaki
  • Patent number: 4600673
    Abstract: A photoconductive assembly comprising a conductive substrate, a photoconductive layer and a topcoat comprised of a cured film-forming silicone polymer. The topcoat has a thickness of between 5 and 300 nm and a melting point above 100.degree. C.
    Type: Grant
    Filed: April 22, 1985
    Date of Patent: July 15, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: William A. Hendrickson, Jack L. Evans, Kenneth R. Paulson, Robert W. Wilson
  • Patent number: 4598031
    Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.
    Type: Grant
    Filed: March 29, 1984
    Date of Patent: July 1, 1986
    Inventor: Shunpei Yamazaki
  • Patent number: 4595602
    Abstract: A process for forming an overcoated electrophotographic imaging member comprising applying on an electrophotographic imaging member a coating in liquid form comprising a cross-linkable siloxanol-colloidal silica hybrid material having at least one silicon bonded hydroxyl group per every three --SiO-- units on the electrophotographic imaging member and a hydrolyzed ammonium salt of an alkoxy silane having the formula ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are independently selected from the group consisting of aliphatic and substituted aliphatic radicals having 1 to 4 carbon atoms, R.sub.4 is selected from the group consisting of aliphatic radicals, substituted aliphatic radicals and the group ##STR2## wherein y is a number from 2 to 4, and R.sub.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: June 17, 1986
    Assignee: Xerox Corporation
    Inventor: Richard L. Schank
  • Patent number: 4592979
    Abstract: A photoconductive member comprises a substrate for photoconductive member and a light receiving layer having photoconductivity comprising an amorphous material containing silicon atoms and germanium atoms, said light receiving layer containing nitrogen atoms and having a first layer region, a third layer region and a second layer region with the nitrogen atom content in the layer thickness direction of C(1), C(3) and C(2), respectively, in the order from the substrate side (with the proviso that when C(3) cannot solely be the maximum and either one of C(1) and C(2) is zero, the other two are not zero and not equal to each other, or when C(3) is zero, the other two are not zero, or when none of C(1), C(2) and C(3) is zero, the three of C(1), C(2) and C(3) cannot be equal at the same time and C(3) cannot solely be the maximum).
    Type: Grant
    Filed: September 6, 1984
    Date of Patent: June 3, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keishi Saitoh, Yukihiko Ohnuki, Shigeru Ohno
  • Patent number: 4587187
    Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.
    Type: Grant
    Filed: March 29, 1984
    Date of Patent: May 6, 1986
    Inventor: Shunpei Yamazaki
  • Patent number: 4584253
    Abstract: An electrophotographic imaging member is disclosed comprising a charge generation layer, a contiguous charge transport layer comprising an aromatic amine or hydrazone charge transport molecule in a continuous polymeric binder phase, and a cellulosic hole trapping material located on the same side of the charge transport layer as the charge generation layer, the cellulosic hole trapping material being free of electron withdrawing groups and having the structural formula ##STR1## wherein R is independently selected from the group consisting of hydrogen and a substituted or unsubstituted group selected from the group consisting of an alkyl group containing 1 to 20 carbon atoms, a hydroxyalkyl group containing 1 to 20 carbon atoms, a hydroxyether group containing 1 to 20 carbon atoms and an aminoalkyl group containing 1 to 20 carbon atoms, and n is the number of cellulose repeating units from 1 to 3,000. A process for using this electrophotographic imaging member is also disclosed.
    Type: Grant
    Filed: December 24, 1984
    Date of Patent: April 22, 1986
    Assignee: Xerox Corporation
    Inventors: John W. Lin, Lesley P. Dudek
  • Patent number: 4582770
    Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.
    Type: Grant
    Filed: May 7, 1985
    Date of Patent: April 15, 1986
    Inventor: Shunpei Yamazaki
  • Patent number: 4572881
    Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.
    Type: Grant
    Filed: April 24, 1984
    Date of Patent: February 25, 1986
    Inventor: Shunpei Yamazaki
  • Patent number: 4569891
    Abstract: A multi-layered photoconductive material which comprises first layers containing at least one VIb chalcogen element chosen from S, Se and Te and second layers containing at least one IIb element chosen from Zn, Cd and Hg and acting as electric potential barriers, said first layers and said second layers being alternatively arranged and the total number of said first layers and said second layers being not less than 5 and has a high response speed and an excellent sensitivity to long wavelength light with a great dark resistance.
    Type: Grant
    Filed: March 30, 1984
    Date of Patent: February 11, 1986
    Assignee: Kanegafuchi Chemical Industry Co., Ltd.
    Inventors: Isamu Shimizu, Minori Yamaguchi
  • Patent number: 4569893
    Abstract: A photoconductive member comprises a substrate for photoconductive member and a light receiving layer provided on said substrate having a layer consititution in which a first layer region (G) comprising an amorphous material containing germanium atoms and a second layer region (S) exhibiting photoconductivity comprising an amorphous material containing silicon atoms are successively provided from the substrate side, said light receiving layer containing oxygen atoms together with a substance for controlling conductivity (C) in a distributed state such that, in said light receiving layer, the maximum value C(PN).sub.max of the content of said substance (C) in the layer thickness direction exists within said second layer region (S) or at the interface with said first layer region (G) and, in said second layer region(S), said substance (C) is distributed in greater amount on the side of said substrate.
    Type: Grant
    Filed: August 27, 1984
    Date of Patent: February 11, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keishi Saitoh, Yukihiko Ohnuki, Shigeru Ohno
  • Patent number: 4565731
    Abstract: An image-forming member for electro-photography has a photoconductive layer comprising a hydrogenated amorphous semiconductor composed of silicon and/or germanium as a matrix and at least one chemical modifier such as carbon, nitrogen and oxygen contained in the matrix.
    Type: Grant
    Filed: September 15, 1982
    Date of Patent: January 21, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Toshiyuki Komatsu, Yutaka Hirai, Katsumi Nakagawa, Tadaji Fukuda
  • Patent number: 4565760
    Abstract: A photoresponsive imaging member with acceptable residual voltages at from about 20 percent to about 80 percent relative humidities consisting of inorganic or organic photoconductive substances, and as a release protective coating thereover a dispersion of colloidal silica and a hyroxylated silsesquixone in an alcoholic medium, which overcoating is of a thickness of from about 0.2 micron to about 1.5 microns.
    Type: Grant
    Filed: November 13, 1984
    Date of Patent: January 21, 1986
    Assignee: Xerox Corporation
    Inventor: Richard L. Schank
  • Patent number: 4565759
    Abstract: A plate for use in lithographic printing which comprises providing a photoconductive layer on an electrically conductive substrate and further providing thereon a surface layer (a hydrophilicable layer) consisting essentially of a reaction product of a resin having an acid anhydride group with a crosslinking agent.
    Type: Grant
    Filed: June 8, 1984
    Date of Patent: January 21, 1986
    Assignee: Ricoh Co., Ltd.
    Inventor: Kyoji Tsutsui
  • Patent number: 4559289
    Abstract: An electrophotographic light-sensitive material is described, comprising an electrically conductive support, an amorphous silicon photoconductive layer on the support, and a layer of amorphous material containing at least carbon and halogen atoms is provided on the photoconductive layer. This material is free from a serious reduction in resolving power as is encountered in conventional electrophotographic light-sensitive materials when they are exposed to corona discharge, particularly negative corona discharge under high temperature/humidity conditions.
    Type: Grant
    Filed: July 3, 1984
    Date of Patent: December 17, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Sunagawa, Kazuhiro Kawajiri, Keishiro Kido, Toshio Iijima, Nobuharu Nozaki
  • Patent number: 4557987
    Abstract: A photoconductive member having a support, amorphous charge generation and charge transport layers and a barrier layer between the support and the charge generation layer. The charge generation layer contains from 0.1 to 10 atomic percent of a conduction controlling impurity. Intermediate and surface barrier layers are also employed and additional transport layers are utilized.
    Type: Grant
    Filed: December 8, 1981
    Date of Patent: December 10, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda
  • Patent number: 4555462
    Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.
    Type: Grant
    Filed: July 21, 1983
    Date of Patent: November 26, 1985
    Inventor: Shunpei Yamazaki
  • Patent number: 4555464
    Abstract: An electrophotographic photosensitive material comprising a conductive support having thereon, in succession, a photoconductive layer composed of an amorphous material containing silicon atom and a barrier layer mainly composed of carbon and silicon, nitrogen and silicon, or oxygen and silicon, and further on the barrier layer a surface improvement layer having a composition of carbon and silicon of from 0.70/1 to 0.95/1 by atomic ratio in carbon/carbon+silicon, and the composition ratio being larger than that of the barrier layer.
    Type: Grant
    Filed: July 6, 1984
    Date of Patent: November 26, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keishiro Kido, Hiroshi Sunagawa, Kazuhiro Kawajiri, Toshio Iijima, Nobuharu Nozaki
  • Patent number: 4552824
    Abstract: A layer of amorphous silicon containing H, preferably 10-40 atomic % H, is used as a photoconductive layer for electrophotographic photosensitive member.
    Type: Grant
    Filed: January 28, 1985
    Date of Patent: November 12, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yutaka Hirai, Toshiyuki Komatsu, Katsumi Nakagawa, Teruo Misumi, Tadaji Fukuda
  • Patent number: 4544617
    Abstract: Disclosed is an electrophotographic photoresponsive device comprised of a supporting substrate, an amorphous silicon charge transport layer, a trapping layer comprised of doped amorphous silicon, and a top insulating overcoating layer.
    Type: Grant
    Filed: November 2, 1983
    Date of Patent: October 1, 1985
    Assignee: Xerox Corporation
    Inventors: Joseph Mort, Frank Jansen, Steven J. Grammatica, Michael A. Morgan
  • Patent number: 4539283
    Abstract: A photoconductive member, comprises a support for a photoconductive member and an amorphous layer which is constituted of silicon atoms as matrix containing at least one of hydrogen atom and halogen atom and exhibits photoconductivity, said amorphous layer having a layer region containing carbon atoms in at least a part thereof, the content of the carbon atoms in said layer region being distributed unevenly in the direction of the thickness of said layer.
    Type: Grant
    Filed: December 29, 1981
    Date of Patent: September 3, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda
  • Patent number: 4537846
    Abstract: In an electrophotographic photosensitive device including a conductive layer, a selenium based photoconductive layer and a transparent insulating layer which are sequentially laminated, the conductive layer is formed of an aluminum substrate conductive layer, a zinc conductive layer a copper conductive layer, and silver conductive layer which are sequentially laminated to each other. As a result of this structure, the charge injection characteristic of the photosensitive device during primary charging is improved, and the charge injection preventing characteristic during the simultaneous secondary charging and image exposure steps is sufficiently maintained. The conductive layers contact each other intimately. The electrophotographic photosensitive device is highly humidity durable and exhibits a long life and can obtain high electrostatic contrast.
    Type: Grant
    Filed: October 19, 1983
    Date of Patent: August 27, 1985
    Assignee: Olympus Optical Company, Ltd.
    Inventors: Yoshiyuki Mimura, Takao Okada, Akitoshi Toda
  • Patent number: 4537845
    Abstract: In an electrophotographic photosensitive device including a conductive layer, a selenium based photoconductive layer and a transparent insulating layer which are sequentially laminated, the conductive layer is formed by an aluminum substrate conductive layer, a zinc conductive layer (or a zinc conductive layer and a copper conductive layer), and a nickel conductive layer which are sequentially laminated to each other. As a result of this structure, the charge injection characteristic during the primary charging step is improved, and the charge injection preventing characteristic during the simultaneous secondary charging and image exposure steps is sufficiently maintained. The conductive layers contact each other intimately. The electrophotographic photosensitive device exhibits a high humidity durability and a long life and can obtain high electrostatic contrast.
    Type: Grant
    Filed: October 19, 1983
    Date of Patent: August 27, 1985
    Assignee: Olympus Optical Company Ltd.
    Inventors: Yoshiyuki Mimura, Takao Okada, Akitoshi Toda
  • Patent number: 4536457
    Abstract: An imaging method comprising providing a migration imaging member comprising a substrate and an electrically insulating softenable layer on the substrate, the softenable layer comprising migration marking material located at least at or near the surface of the softenable layer spaced from the substrate and a charge transport material in the softenable layer, electrostatically charging the member, exposing the member to activating radiation in an imagewise pattern, decreasing the resistance to migration of marking material in the softenable layer sufficiently to allow slight migration in depth of marking material towards the substrate in image configuration, and further decreasing the resistance to migration of marking material in the softenable layer sufficiently to allow nonmigrated marking material to agglomerate.
    Type: Grant
    Filed: January 3, 1984
    Date of Patent: August 20, 1985
    Assignee: Xerox Corporation
    Inventor: Man C. Tam
  • Patent number: 4536458
    Abstract: This invention relates to a migration imaging member comprising a substrate and an electrically insulating softenable layer on said substrate, said softenable layer comprising migration marking material located at least at or near the surface of said softenable layer spaced from said substrate and a charge transport molecule.
    Type: Grant
    Filed: January 3, 1984
    Date of Patent: August 20, 1985
    Assignee: Xerox Corporation
    Inventor: Dominic S. Ng
  • Patent number: 4532198
    Abstract: A photoconductive member is provided, which comprises a support for photoconductive member and a light receiving layer with a layer constitution, comprising a first layer region containing at least germanium atoms of which at least a portion is crystallized, a second region comprising an amorphous material containing at least silicon atoms and germanium atoms, a third layer region comprising an amorphous material containing at least silicon atoms and exhibiting photoconductivity, and a fourth layer region comprising an amorphous material containing silicon atoms and carbon atoms, provided successively in the order mentioned from the said support side.
    Type: Grant
    Filed: May 7, 1984
    Date of Patent: July 30, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keishi Saitoh, Kozo Arao
  • Patent number: 4518671
    Abstract: An electrophotographic photosensitive member has a selenium type photoconductive layer containing 8000 ppm or less oxygen based on selenium. The member is free from a fatigue due to repeated use.
    Type: Grant
    Filed: September 19, 1983
    Date of Patent: May 21, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Teruo Misumi, Yoichi Osato
  • Patent number: 4496642
    Abstract: An imaging member comprising a substrate, an electrically insulating swellable, softenable layer on the substrate, the softenable layer having particulate migration marking material located at least at or near the surface of the softenable layer spaced from the substrate, and a protective overcoating comprising a film-forming resin, a portion of which extends beneath the surface of the softenable layer. This migration imaging member may be prepared with the aid of a material which swells at least the surface of the softenable layer to allow the film-forming resin to penetrate beneath the surface of the softenable layer.
    Type: Grant
    Filed: May 12, 1983
    Date of Patent: January 29, 1985
    Assignee: Xerox Corporation
    Inventors: Man C. Tam, Gregory J. Kovacs
  • Patent number: 4492745
    Abstract: A photosensitive member for electrophotography basically comprises a conductive support, on the surface of which a photoconductive layer and a transparent insulating layer are sequentially laminated. The photosensitive member is adapted to be used in a process for forming an electrostatic latent image including sequential steps of a primary corona charging concurrent with imagewise exposure, a secondary corona charging and a flush irradiation. The surface of the conductive support is treated to a mirror finish, based on experimental finding that the contrast voltage of the latent image depends on the degree of surface roughness of the support.
    Type: Grant
    Filed: October 31, 1983
    Date of Patent: January 8, 1985
    Assignee: Olympus Optical Co., Ltd.
    Inventors: Yoshiyuki Mimura, Takao Okada, Akitoshi Toda
  • Patent number: 4489148
    Abstract: This invention is directed to an improved photoresponsive device comprised of a substrate, a hole transport layer, an adhesive layer, an organic photoconductive layer sensitive to infrared radiation, an inorganic photogenerating layer, and an optional polymeric overcoating layer.
    Type: Grant
    Filed: April 25, 1983
    Date of Patent: December 18, 1984
    Assignee: Xerox Corporation
    Inventor: Anthony M. Horgan
  • Patent number: 4486088
    Abstract: A novel method and apparatus for electrophotography is disclosed which enables selection the mode of image formation among positive-positive, negative-positive and combinations thereof without any need of changing the polarity of developing toner. The present invention is made on the basis of a known electrophotographic system in which a photosensitive member composed of essentially an electrically conductive substrate, a photoconductive substance layer and an insulating surface layer and which comprises the steps of charging the insulating surface layer, image-wise exposing it to light so as to form a first image almost simultaneously with or some time after the charging step, subjecting it to corona discharge with nearly simultaneous image-wise exposure so as to form a second image and uniformly exposing the whole surface of the photosensitive medium to light so as to form an electrostatic latent image corresponding to a composite image resulting from the first and second images.
    Type: Grant
    Filed: May 28, 1982
    Date of Patent: December 4, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashi Kitamura, Michio Ito
  • Patent number: 4481234
    Abstract: The surface properties of solid substrates are improved by the formation of discrete sites of inorganic materials on one surface of the substrate.
    Type: Grant
    Filed: February 3, 1982
    Date of Patent: November 6, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Vasant V. Kolpe, Dudley M. Sherman, William A. Hendrickson, Hsin-hsin Chou
  • Patent number: 4472491
    Abstract: An electrophotographic recording material comprised of an electrically conductive support, an optional insulating interlayer, a photoconductive system comprised of at least one layer of organic material containing a charge carrier-producing compound and a charge-transporting compound, and a radiation-cured, transparent protective layer, wherein the protective layer has been applied onto the surface of the photoconductive system with the aid of a removable auxiliary support and is comprised of an acrylated binder which is cured by irradiation with ultraviolet light. Also disclosed is a process for the production of the recording material.
    Type: Grant
    Filed: May 26, 1982
    Date of Patent: September 18, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Wolfgang Wiedemann
  • Patent number: 4471042
    Abstract: An image-forming member for electrophotography has a photoconductive layer comprising a hydrogenated amorphous semiconductor composed of silicon and/or germanium as a matrix and at least one chemical modifier such as carbon, nitrogen and oxygen contained in the matrix.
    Type: Grant
    Filed: May 4, 1979
    Date of Patent: September 11, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Toshiyuki Komatsu, Yutaka Hirai, Katsumi Nakagawa, Tadaji Fukuda
  • Patent number: 4469767
    Abstract: This invention provides a process for making image overlay through the steps constituting an electrophotographic process, and also an apparatus adapted for conducting such process. The process, based on an electrophotographic process utilizing a three-layered photosensitive member having an insulating cover layer, comprising exposing the photosensitive member to a first image-forming irradiation to be overlaid substantially simultaneously with or subsequent to a charging on the surface of the insulating layer, then exposing the photosensitive member to a second image-forming irradiation to be overlaid substantially simultaneously with an AC or DC corona discharge given to the photosensitive member, and subsequently giving a uniform exposure to the surface of said photosensitive member thereby obtaining an electrophotographic overlay image of the first and second irradiations.
    Type: Grant
    Filed: January 15, 1982
    Date of Patent: September 4, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashi Kitamura, Michio Ito
  • Patent number: 4464451
    Abstract: An electrophotographic image-forming member comprises a substrate for electrophotography and an amorphous layer which is laid on said substrate and constituted of silicon atoms as matrix containing at least one of hydrogen atom and halogen atom and exhibits photoconductivity, said substrate being constituted of aluminum oxide containing chemi-structurally water at least on the surface thereof, and said amorphous layer having a layer region containing at least one member selected from the group consisting of oxygen atom, nitrogen atom and carbon atom in at least a part thereof, the content of said member in said layer region being distributed unevenly in the direction of the thickness of said layer.
    Type: Grant
    Filed: January 29, 1982
    Date of Patent: August 7, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda
  • Patent number: 4444862
    Abstract: An electrophotographic photosensitive material is disclosed. The material is comprised of a conductive support base. On the surface of the base is a photoconductive layer. On a surface of the photoconductive layer is an interlayer comprised of organic metal compound as its main component. On top of the interlayer is a low-resistant protective layer. The material can achieve electrostatic contrast greatly superior to that of conventional photosensitive materials.
    Type: Grant
    Filed: July 28, 1982
    Date of Patent: April 24, 1984
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Shigeru Yagi, Koichi Yamamoto, Yasutoshi Okugawa
  • Patent number: 4443529
    Abstract: A photoconductive member comprising a support for photoconductive member, a photoconductive layer constituted of an amorphous material comprising silicon atom as a matrix and a barrier layer between said support and said photoconductive layer, said barrier layer having a double-layer structure of a first barrier layer constituted of an amorphous material comprising silicon atom as a matrix and containing impurities which control the property of conductivity and a second barrier layer constituted of an electrically insulating material different from said amorphous material constituting said first barrier layer.
    Type: Grant
    Filed: April 14, 1982
    Date of Patent: April 17, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Junichiro Kanbe, Shigeru Shirai, Tadaji Fukuda
  • Patent number: 4439258
    Abstract: The present invention relates to a method for covering a substrate with a cylindrically shaped heat-shrinkable film, particularly to a method for covering a cylindrically shaped heat-shrinkable film so as to fit the contour of a substrate by conducting the heat treatment in multiple steps at different temperatures.
    Type: Grant
    Filed: May 13, 1982
    Date of Patent: March 27, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hitoshi Toma, Tomohiro Kimura, Hideyo Kondo
  • Patent number: 4439509
    Abstract: A process for forming an overcoated electrophotographic imaging member by applying a coating of a cross-linkage siloxanol-colloidal silica hybrid material on an electrophotographic imaging member and thereafter contacting the coating with a fugitive ammonia gas condensation catalyst until the siloxanol-colloidal silica hybrid material forms a cross-linked solid layer. The cross-linkable siloxanol-colloidal silica hybrid material may be prepared by hydrolyzing trifunctional organosilanes and stabilizing the hydrolyzed silanes with colloidal silica. The electrophotographic imaging member may comprise inorganic or organic photoconductive components in one or more layers.
    Type: Grant
    Filed: June 1, 1982
    Date of Patent: March 27, 1984
    Assignee: Xerox Corporation
    Inventor: Richard L. Schank
  • Patent number: 4430404
    Abstract: An electrophotographic photosensitive material having a long lifetime can be provided by forming an amorphous silicon layer having a thickness of 0.01-0.08 .mu.m on the photoconductive layer on the electrically conductive substrate in the said material without changing the characteristics of the photoconductive layer.
    Type: Grant
    Filed: April 26, 1982
    Date of Patent: February 7, 1984
    Assignees: Hitachi, Ltd., Hitachi Koki Co., Ltd.
    Inventors: Akira Hosoya, Kunihiro Tamahashi, Shigeharu Onuma, Atsushi Kakuta, Yasuki Mori, Katsuhito Suzuki, Hirosada Morishita
  • Patent number: 4424267
    Abstract: An image-holding member for holding electrostatic images or toner images comprising a support and an image-holding layer contains a curable rubber layer.
    Type: Grant
    Filed: March 26, 1982
    Date of Patent: January 3, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hideyo Kondo, Naoto Fujimura
  • Patent number: 4423131
    Abstract: This invention is directed to an improved photoresponsive device containing as a protectant overcoating a top layer of a crosslinked polyvinylsilicate resulting from the reaction of polysilicic acid with a polyvinyl alcohol having a number average molecular weight of from about 10,000 to about 100,000.
    Type: Grant
    Filed: May 3, 1982
    Date of Patent: December 27, 1983
    Assignee: Xerox Corporation
    Inventors: William W. Limburg, John M. Pochan, Charles L. Beatty
  • Patent number: 4423132
    Abstract: An image-holding member for holding electrostatic images and/or toner images comprising an insulating layer on the surface, the insulating layer being composed mainly of a fluorine-containing surface active agent, a lubricant and a resin.
    Type: Grant
    Filed: October 20, 1980
    Date of Patent: December 27, 1983
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hideyo Kondo, Hitoshi Touma
  • Patent number: 4420547
    Abstract: A photosensitive member for electrophotography comprises a first and a second photoconductive layer sequentially formed on a conductive layer. The first photoconductive layer has a spectral sensitivity extending over a range of light rays from ultraviolet rays to visible light. The second photoconductive layer is of light transmissibility, which is formed with a single or a compound layer and has a filtering action to transmit only light of longer wavelengths than a given one so as to define a range of light incident upon the first photoconductive layer, and a spectral sensitivity only to rays of shorter wavelengths than the given one.
    Type: Grant
    Filed: September 21, 1981
    Date of Patent: December 13, 1983
    Assignee: Olympus Optical Company Ltd.
    Inventor: Masaji Nishikawa
  • Patent number: 4418132
    Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.
    Type: Grant
    Filed: June 23, 1981
    Date of Patent: November 29, 1983
    Inventor: Shunpei Yamazaki
  • Patent number: 4409309
    Abstract: An electrophotographic light-sensitive element which is useful in the Carlson electrophotographic process is disclosed, comprising an electrically conductive support having provided thereon a photoconductive layer and a protective layer wherein said protective layer has a thickness of from 1 to 30 .mu.m and contains a powder of a metal oxide having a volume intrinsic resistance of 10.sup.11 .OMEGA..multidot.cm or less and a mean particle size of 0.3 .mu.m or less dispersed in a binder resin.
    Type: Grant
    Filed: July 31, 1981
    Date of Patent: October 11, 1983
    Assignee: Fuji Xerox Co., Ltd.
    Inventor: Kozo Oka
  • Patent number: 4395474
    Abstract: In an electrophotographic photosensitive member having a photoconductive layer composed of a photoconductive material and a binder, improvement wherein said binder is a curable rubber.
    Type: Grant
    Filed: October 22, 1980
    Date of Patent: July 26, 1983
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hideyo Kondo, Naoto Fujimura
  • Patent number: 4394425
    Abstract: A photoconductive member comprises a support, a photoconductive layer constituted of an amorphous material containing silicon atoms as matrix and containing hydrogen atoms or halogen atoms, and an intermediate layer provided between them, said intermediate layer having a function to bar penetration of carriers from the side of the support into the photoconductive layer and to permit passage from the photoconductive layer to the support of photocarriers generated in the photoconductive layer by projection of electromagnetic waves and movement of the photocarriers toward the side of the support, and said intermediate layer being constituted of an amorphous material containing silicon atoms and carbon atoms a constituents.
    Type: Grant
    Filed: September 4, 1981
    Date of Patent: July 19, 1983
    Assignee: Canon Kabushiki Kaisha
    Inventors: Isamu Shimizu, Shigeru Shirai, Eiichi Inoue