At Least One Layer Forms A Diffusion Barrier Patents (Class 438/643)
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Publication number: 20120295435Abstract: In one embodiment, a pattern transfer method includes forming a photoreactive resin on a substrate to be processed. The method further includes pressing a mold against the photoreactive resin, the mold including a transparent substrate having a concave-convex pattern, and a light-blocking film provided on a part of surfaces of the concave-convex pattern. The method further includes irradiating the photoreactive resin with light through the mold in a state in which the mold is pressed against the photoreactive resin. The method further includes baking the photoreactive resin in a state in which the mold is pressed against the photoreactive resin after irradiating the photoreactive resin with the light. The method further includes releasing the mold from the photoreactive resin after baking the photoreactive resin. The method further includes rinsing the photoreactive resin with a rinsing solution after releasing the mold.Type: ApplicationFiled: February 17, 2012Publication date: November 22, 2012Inventor: Ikuo Yoneda
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Publication number: 20120289043Abstract: A method for fabricating a damascene trench structure, wherein the method comprises steps as follows: A semiconductor structure having an inner layer dielectric (ILD) and a patterned hard mask stacked in sequence is firstly provided, in which a trench extends from the patterned hard mask downwards into the ILD. Subsequently, the patterned hard mask is etched in an atmosphere essentially consisting of nitrogen (N2) and carbon-fluoride compositions (CxFy).Type: ApplicationFiled: May 12, 2011Publication date: November 15, 2012Applicant: UNITED MICROELECTRONICS CORP.Inventors: Ming-Da HSIEH, Yu-Tsung Lai, Jiunn-Hsiung Liao
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Publication number: 20120273948Abstract: An integrated circuit structure including a copper-aluminum interconnect with a barrier layer including a titanium nitride layer and a method for fabricating the same are disclosed. The method for fabricating an integrated circuit structure including a copper-aluminum interconnect according to the present invention comprises the steps of providing a copper (Cu) layer; forming a barrier layer connected to the copper layer, wherein the barrier layer comprises a first layer including a tantalum layer and a tantalum nitride layer and a second layer including a titanium nitride layer, the first layer contacts the copper layer and is disposed between the copper layer and the second layer, and the barrier layer has a recess correspondingly above the copper layer; and forming an aluminum (Al) layer disposed in the recess.Type: ApplicationFiled: April 27, 2011Publication date: November 1, 2012Applicant: NANYA TECHNOLOGY CORPORATIONInventors: Kuo Hui Su, Yi Nan Chen, Hsien Wen Liu
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Patent number: 8299567Abstract: Structures of electronic fuses (e-fuse) are provided. An un-programmed e-fuse includes a via of a first conductive material having a bottom and sidewalls with a portion of the sidewalls being covered by a conductive liner and the bottom of the via being formed on top of a dielectric layer, and a first and a second conductive path of a second conductive material formed on top of the dielectric layer with the first and second conductive paths being conductively connected through, and only through, the via at the sidewalls. A programmed e-fuse includes a via; a first conductive path at a first side of the via and being separated from sidewalls of the via by a void; and a second conductive path at a second different side of the via and being in conductive contact with the via through sidewalls of the via.Type: GrantFiled: November 23, 2010Date of Patent: October 30, 2012Assignee: International Business Machines CorporationInventors: Ping-Chuan Wang, Chunyan E Tian, Ronald Filippi, Wai-kin Li
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Publication number: 20120267785Abstract: Methods of forming integrated circuit devices include forming an interlayer insulating layer having a trench therein, on a substrate and forming an electrical interconnect (e.g., Cu damascene interconnect) in the trench. An upper surface of the interlayer insulating layer is recessed to expose sidewalls of the electrical interconnect. An electrically insulating first capping pattern is formed on the recessed upper surface of the interlayer insulating layer and on the exposed sidewalls of the electrical interconnect, but is removed from an upper surface of the electrical interconnect. A metal diffusion barrier layer is formed on an upper surface of the electrical interconnect, however, the first capping pattern is used to block formation of the metal diffusion barrier layer on the sidewalls of the electrical interconnect. This metal diffusion barrier layer may be formed using an electroless plating technique.Type: ApplicationFiled: June 26, 2012Publication date: October 25, 2012Inventors: Hyeok-Sang Oh, Woo-Jin Jang, Bum-Ki Moon, Ji-Hong Choi, Minseok Oh, Tien-Jen Cheng
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Patent number: 8293643Abstract: A semiconductor device or a photovoltaic cell having a contact structure, which includes a silicon (Si) substrate; a metal alloy layer deposited on the silicon substrate; a metal silicide layer and a diffusion layer formed simultaneously from thermal annealing the metal alloy layer; and a metal layer deposited on the metal silicide and barrier layers.Type: GrantFiled: June 21, 2010Date of Patent: October 23, 2012Assignee: International Business Machines CorporationInventors: Cyril Cabral, Jr., John M. Cotte, Kathryn C. Fisher, Laura L. Kosbar, Christian Lavoie, Zhu Liu, Kenneth P. Rodbell, Xiaoyan Shao
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Patent number: 8293637Abstract: A method of manufacturing a semiconductor device, includes burying a conductive pattern in an insulating film made of SiOH, SiCOH or organic polymer, treating surfaces of the insulating film and the conductive pattern with plasma which includes a hydrocarbon gas as a treatment gas, and forming a diffusion barrier film, which is formed of an SiCH film, an SiCHN film, an SiCHO film or an SiCHON film, over the insulating film and the conductive pattern with performing a plasma CVD by adding an Si-containing gas to the treatment gas while increasing the addition amount gradually or in a step-by-step manner.Type: GrantFiled: April 27, 2011Date of Patent: October 23, 2012Assignee: Renesas Electronics CorporationInventor: Tatsuya Usami
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Publication number: 20120261823Abstract: A method for forming an interconnect structure with nanocolumnar intermetal dielectric is described involving the construction of an interconnect structure using a solid dielectric, and introducing a regular array of vertically aligned nanoscale pores through stencil formation and etching to form a hole array and subsequently pinching off the tops of the hole array with a cap dielectric. Variations of the method and means to construct a multilevel nanocolumnar interconnect structure are also described.Type: ApplicationFiled: June 23, 2012Publication date: October 18, 2012Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Matthew E. Colburn, Satya V. Nitta, Sampath Purushothaman, Charles Black, Kathryn Guarini
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Patent number: 8288276Abstract: Interconnect structures having improved electromigration resistance are provided that include a metallic interfacial layer (or metal alloy layer) that is present at the bottom of a via opening. The via opening is located within a second dielectric material that is located atop a first dielectric material that includes a first conductive material embedded therein. The metallic interfacial layer (or metal alloy layer) that is present at the bottom of the via opening is located between the underlying first conductive material embedded within the first dielectric and the second conductive material that is embedded within the second dielectric material. Methods of fabricating the improved electromigration resistance interconnect structures are also provided.Type: GrantFiled: December 30, 2008Date of Patent: October 16, 2012Assignee: International Business Machines CorporationInventors: Chih-Chao Yang, Veeraraghavan S. Basker, William Tonti, Keith Kwong Hon Wong
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Patent number: 8288273Abstract: A method is disclosed for forming a patterned thick metallization atop a semiconductor chip wafer. The method includes fabricating a nearly complete semiconductor chip wafer ready for metallization; depositing a bottom metal layer of sub-thickness TK1 together with its built-in alignment mark using a hot metal process; depositing a top metal layer of sub-thickness TK2 using a cold metal process thus forming a stacked thick metallization of total thickness TK=TK1+TK2; then, use the built-in alignment mark as reference, patterning the stacked thick metallization. A patterned thick metallization is thus formed with the advantages of better metal step coverage owing to the superior step coverage nature of the hot metal process as compared to the cold metal process; and lower alignment error rate owing to the lower alignment signal noise nature of the cold metal process as compared to the hot metal process.Type: GrantFiled: October 17, 2011Date of Patent: October 16, 2012Assignee: Alpha & Omega Semiconductor Inc.Inventor: Il Kwan Lee
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Patent number: 8288275Abstract: Provided are methods of forming a contact plug of a semiconductor device. Methods of forming a contact plug of a semiconductor device may include forming an interlayer insulating layer on a semiconductor substrate on which a lower structure is formed, forming a contact hole in the interlayer insulating layer, the contact hole exposing the lower structure, and forming a W layer and then a WN layer to form a W/WN barrier layer in the contact hole. Methods may include H2 remote plasma treating the W/WN barrier layer, forming a W-plug on the H2 remote plasma treated W/WN barrier layer to fill the contact hole, and chemical mechanical polishing (CMP) the W-plug and then the W/WN barrier layer in order to expose the interlayer insulating layer.Type: GrantFiled: November 14, 2008Date of Patent: October 16, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Jin-ho Park, Gil-heyun Choi, Sang-woo Lee, Jun-ho Park, Ho-ki Lee
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Patent number: 8283237Abstract: A through-silicon via fabrication method comprises forming a substrate by bonding the front surface of a silicon plate to a carrier using an adhesive layer therebetween to expose the back surface of the silicon plate. A silicon nitride passivation layer is deposited on the exposed back surface of the silicon plate of the substrate. A plurality of through holes are etched in the silicon plate, the through holes comprising sidewalls and bottom walls. A metallic conductor is deposited in the through holes to form a plurality of through-silicon vias.Type: GrantFiled: December 23, 2010Date of Patent: October 9, 2012Assignee: Applied Materials, Inc.Inventors: Nagarajan Rajagopalan, Ji Ae Park, Ryan Yamase, Shamik Patel, Thomas Nowak, Li-Qun Xia, Bok Hoen Kim, Ran Ding, Jim Baldino, Mehul Naik, Sesh Ramaswami
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Publication number: 20120248612Abstract: The invention relates to an electronic component having a GaAs semiconductor substrate (HS), semiconductor components (BE) being implemented on the front side thereof, and the back side thereof having a multilayer backside metallization (RM), wherein an advantageous construction of the layer sequence of the backside metallization is proposed, the backside metallization in particular comprising an Au layer as a bonding layer.Type: ApplicationFiled: December 21, 2010Publication date: October 4, 2012Applicant: UNITED MONOLITHIC SEMICONDUCTORS GMBHInventors: Guenter Jonsson, Hermann Stieglauer
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Patent number: 8278207Abstract: A semiconductor device can include an insulation layer on that is on a substrate on which a plurality of lower conductive structures are formed, where the insulation layer has an opening. A barrier layer is on a sidewall and a bottom of the opening of the insulation layer, where the barrier layer includes a first barrier layer in which a constituent of a first deoxidizing material is richer than a metal material in the first barrier layer and a second barrier layer in which a metal material in the second barrier layer is richer than a constituent of a second deoxidizing material. An interconnection is in the opening of which the sidewall and the bottom are covered with the barrier layer, the interconnection is electrically connected to the lower conductive structure.Type: GrantFiled: January 15, 2010Date of Patent: October 2, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Jin-Ho Park, Gil-Heyun Choi, Byung-Lyul Park, Jong-Myeong Lee, Zung-Sun Choi, Hye-Kyung Jung
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Patent number: 8278215Abstract: Processes for minimizing contact resistance when using nickel silicide (NiSi) and other similar contact materials are described. These processes include optimizing silicide surface cleaning, silicide surface passivation against oxidation and techniques for diffusion barrier/catalyst layer deposition. Additionally, processes for generating a noble metal (for example platinum, iridium, rhenium, ruthenium, and alloys thereof) activation layer that enables the electroless barrier layer deposition on a NiSi-based contact material are described. The processes may be employed when using NiSi-based materials in other end products. The processes may be employed on silicon-based materials.Type: GrantFiled: May 2, 2011Date of Patent: October 2, 2012Assignee: Intermolecular, Inc.Inventors: Zhi-Wen Sun, Bob Kong, Igor Ivanov, Tony Chiang
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Patent number: 8268721Abstract: There are provided a semiconductor device and a semiconductor device manufacturing method capable of preventing electrical leakage while suppressing increase of wiring resistance and deterioration of productivity. The semiconductor device manufacturing method for forming on a substrate a semiconductor device having a porous low-k film serving as an interlayer insulating film. Further, the semiconductor device manufacturing method includes forming the low-k film on the substrate; etching the low-k film to form a trench or a hole therein; reforming a surface of the low-k film exposed by etching the low-k film by allowing plasma of a nitro compound to act on the exposed surface within the trench or the hole; and filling the trench or the hole with a conductor.Type: GrantFiled: June 29, 2011Date of Patent: September 18, 2012Assignee: Tokyo Electron LimitedInventor: Ryuichi Asako
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Patent number: 8252692Abstract: A semiconductor device according to one embodiment includes: a substrate having an element region where a semiconductor element is formed; a via hole formed in a portion of the substrate adjacent to the element region; a conducting portion provided in the via hole via an insulating layer; and a buffer layer provided between the substrate and the insulating layer, wherein the buffer layer is made of a material in which a difference in thermal expansion coefficient between the substrate and the buffer layer is smaller than that between the substrate and the insulating layer.Type: GrantFiled: June 27, 2011Date of Patent: August 28, 2012Assignee: Kabushiki Kaisha ToshibaInventor: Masahiro Inohara
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Patent number: 8252680Abstract: An apparatus includes an interconnect in a recess. The interconnect includes a liner structure and the liner structure in the recess. The liner structure is breached at the recess bottom feature and a bottom interconnect makes a single-interface contact with a subsequent interconnect through the breach.Type: GrantFiled: September 24, 2010Date of Patent: August 28, 2012Assignee: Intel CorporationInventor: Adrien R. Lavoie
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Publication number: 20120214302Abstract: A method of fabricating a semiconductor device is provided. The method may include preparing a substrate having a first surface and a second surface, forming a via hole exposing at least a portion of the substrate from the first surface of the substrate, forming a first insulating film on an inner wall of the via hole, forming a conductive connection part filling an inside of the via hole including the first insulating film, polishing the second surface of the substrate until the conductive connection part is exposed, and selectively forming a second insulating film on the second surface of the substrate using an electrografting method to expose the conductive connection part.Type: ApplicationFiled: January 6, 2012Publication date: August 23, 2012Inventors: SEYOUNG JEONG, Taeje Cho, Hogeon Song, Kyu-Ha Lee
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Patent number: 8247321Abstract: When a barrier film is formed on an exposed surface of an interlayer insulation film on a substrate, the interlayer insulation film having a recess formed therein, and a metal wiring to be electrically connected to a metal wiring in a lower layer is formed in the recess, a barrier film having an excellent step coverage can be formed and increase of a wiring resistance can be restrained. An oxide film on a surface of the lower copper wiring exposed to a bottom surface of the interlayer insulation film is reduced or edged so as to remove oxygen on the surface of the copper wiring. Then, by supplying an organic metal compound containing manganese and containing no oxygen, generation of manganese oxide as a self-forming barrier film is selectively allowed on an area containing oxygen, such as a sidewall of the recess and a surface of the interlayer insulation film, while generation of the manganese oxide is not allowed on the surface of the copper wiring. Thereafter, copper is embedded in the recess.Type: GrantFiled: January 20, 2009Date of Patent: August 21, 2012Assignees: Tokyo Electron Limited, National University Corporation Tohoku UniversityInventors: Kenji Matsumoto, Hitoshi Itoh, Hiroshi Sato, Junichi Koike, Koji Neishi
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Publication number: 20120205804Abstract: Techniques formation of high purity copper (Cu)-filled lines and vias are provided. In one aspect, a method of fabricating lines and vias filled with high purity copper with is provided. The method includes the following steps. A via is etched in a dielectric. The via is lined with a diffusion barrier. A thin ruthenium (Ru) layer is conformally deposited onto the diffusion barrier. A Cu layer is deposited on the Ru layer by a sputtering process. A reflow anneal is performed to eliminate voids in the lines and vias.Type: ApplicationFiled: February 11, 2011Publication date: August 16, 2012Applicant: International Business Machines CorporationInventors: Fenton Read McFeely, Chih-Chao Yang
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Patent number: 8242016Abstract: A method for fabricating an integrated circuit structure and the resulting integrated circuit structure are provided. The method includes forming a low-k dielectric layer; form an opening in the low-k dielectric layer; forming a barrier layer covering a bottom and sidewalls of the low-k dielectric layer; performing a treatment to the barrier layer in an environment comprising a treatment gas; and filling the opening with a conductive material, wherein the conductive material is on the barrier layer.Type: GrantFiled: May 14, 2007Date of Patent: August 14, 2012Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Hsien-Ming Lee, Minghsing Tsai, Syun-Ming Jang
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Patent number: 8242600Abstract: A redundant metal diffusion barrier is provided for an interconnect structure which improves the reliability and extendibility of the interconnect structure. The redundant metal diffusion barrier layer is located within an opening that is located within a dielectric material and it is between a diffusion barrier layer and a conductive material which are also present within the opening. The redundant diffusion barrier includes a single layered or multilayered structure comprising Ru and a Co-containing material including pure Co or a Co alloy including at least one of N, B and P.Type: GrantFiled: May 19, 2009Date of Patent: August 14, 2012Assignee: International Business Machines CorporationInventors: Chih-Chao Yang, Thomas M. Shaw
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Patent number: 8242017Abstract: A method for forming an integrated circuit device including an interconnect structure, e.g., copper dual damascene. The method includes providing a substrate and forming an interlayer dielectric layer overlying the substrate. The method also includes patterning the interlayer dielectric layer to form a contact structure and forming a barrier metal layer overlying the contact structure. The method includes forming a seed layer comprising copper bearing species overlying the barrier metal layer and applying an oxygen bearing species to treat the seed layer to cause an oxide layer of predetermined thickness to form on the seed layer. The method protects the seed layer from contamination using the oxide layer while the substrate is transferred from the step of applying the seed layer and contacts a copper bearing material in liquid form overlying the oxide layer to dissolve the oxide layer while forming a thickness of copper bearing material using a plating process to begin filling the contact structure.Type: GrantFiled: March 7, 2008Date of Patent: August 14, 2012Assignee: Semiconductor Manufacturing International (Shanghai) CorporationInventors: Yang Hui Xiang, Qing Tang Jiang
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Publication number: 20120199980Abstract: Integrated circuits and methods for fabricating an integrated circuit are provided. A conductive feature is formed in a semiconductor substrate. A layer of ULK or LK dielectric material is formed overlying the conductive feature. An opening having a sidewall surface is etched through the layer of ULK or LK dielectric material. Damage on the sidewall surface resulting from the etching is removed. An ULK or LK dielectric liner is formed overlying the sidewall surface. The ULK or LK dielectric liner along the bottom of the opening is removed to expose the conductive feature. The opening is filled with a metal fill material contacting the conductive feature.Type: ApplicationFiled: February 7, 2011Publication date: August 9, 2012Applicant: GLOBALFOUNDRIES INC.Inventors: Egon R. PFUETZNER, Torsten HUISINGA, Jens HAHN
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Publication number: 20120202344Abstract: To provide a technology capable of preventing corrosion of a Cu wiring and thereby improving a production yield of a semiconductor device, a manufacturing method of a semiconductor device includes the steps of: removing a portion of a Cu film other than that in a wiring trench in a semiconductor substrate by CMP using a polishing slurry, removing a portion of a barrier metal film other than that in the, wiring trench by CMP using a polishing slurry containing an anticorrosive, polishing the surface of the Cu film and the surface of the barrier metal film by CMP using pure water, thereafter cleaning the semiconductor substrate with pure water without applying an anticorrosive thereto or without cleaning it with a chemical liquid, and thereafter cleaning the semiconductor substrate with a chemical liquid without applying an anticorrosive thereto.Type: ApplicationFiled: February 2, 2012Publication date: August 9, 2012Inventors: Masaru NOZUE, Hiroshi OSHITA, Hiroyuki MASUDA, Hiroki TAKEWAKA
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Publication number: 20120193787Abstract: A rewiring is formed by forming a Cu seed layer of copper over an opening and insulating films, forming a photoresist film over the Cu seed layer, a step of forming copper film by plating-growth over the Cu seed layer, and forming a Ni film. After forming an Au film in an opening (pad region) over the rewiring, the photoresist film is removed and passivation processing is performed on the Ni film. Then, the Cu seed layer other than the formation region of the rewiring is etched. According to these steps, a passivation film is formed on the surface of the Ni film and the reduction in film thickness of the Ni film by the etching can be reduced. Furthermore, it is possible to reduce trouble due to distortion of a substrate resulting from an increase in thickness of the Ni film in view of reduction in film thickness.Type: ApplicationFiled: January 27, 2012Publication date: August 2, 2012Applicant: RENESAS ELECTRONICS CORPORATIONInventors: Tota MAITANI, Yutaro EBATA
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Patent number: 8232200Abstract: Methods of forming integrated circuit devices include forming an interlayer insulating layer having a trench therein, on a substrate and forming an electrical interconnect (e.g., Cu damascene interconnect) in the trench. An upper surface of the interlayer insulating layer is recessed to expose sidewalls of the electrical interconnect. An electrically insulating first capping pattern is formed on the recessed upper surface of the interlayer insulating layer and on the exposed sidewalls of the electrical interconnect, but is removed from an upper surface of the electrical interconnect. A metal diffusion barrier layer is formed on an upper surface of the electrical interconnect, however, the first capping pattern is used to block formation of the metal diffusion barrier layer on the sidewalls of the electrical interconnect. This metal diffusion barrier layer may be formed using an electroless plating technique.Type: GrantFiled: March 18, 2011Date of Patent: July 31, 2012Assignees: International Business Machines Corporation, Samsung Electronics Co., Ltd., Advanced Micro Devices, Inc., Infineon Technologies AGInventors: Hyeok-Sang Oh, Woo-Jin Jang, Bum-Ki Moon, Ji-Hong Choi, Minseok Oh, Tien-Jen Cheng
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Patent number: 8232201Abstract: A method of forming a semiconductor structure includes providing a substrate; forming a low-k dielectric layer over the substrate; embedding a conductive wiring into the low-k dielectric layer; and thermal soaking the conductive wiring in a carbon-containing silane-based chemical to form a barrier layer on the conductive wiring. A lining barrier layer is formed in the opening for embedding the conductive wiring. The lining barrier layer may comprise same materials as the barrier layer, and the lining barrier layer may be recessed before forming the barrier layer and may contain a metal that can be silicided.Type: GrantFiled: May 25, 2011Date of Patent: July 31, 2012Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Chen-Hua Yu, Hai-Ching Chen, Tien-I Bao
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Publication number: 20120190191Abstract: An integrated circuit includes a semiconductor substrate, a low-k dielectric layer over the semiconductor substrate, a first opening in the low-k dielectric layer, and a first diffusion barrier layer in the first opening covering the low-k dielectric layer in the first opening, wherein the first diffusion barrier layer has a bottom portion connected to sidewall portions, and wherein the sidewall portions have top surfaces close to a top surface of the low-k dielectric layer. The integrated circuit further includes a conductive line filling the first opening wherein the conductive line has a top surface lower than the top surfaces of the sidewall portions of the diffusion barrier layer, and a metal cap on the conductive line and only within a region directly over the conductive line.Type: ApplicationFiled: April 5, 2012Publication date: July 26, 2012Applicant: Taiwan Semiconductor Manufaturing Company, Ltd.Inventors: Chien-Hsueh Shih, Minghsing Tsai, Chen-Hua Yu, Ming-Shih Yeh
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Publication number: 20120190190Abstract: Semiconductor structures and methods of manufacture semiconductors are provided which relate to heterojunction bipolar transistors. The method includes forming two devices connected by metal wires on a same wiring level. The metal wire of a first of the two devices is formed by selectively forming a metal cap layer on copper wiring structures.Type: ApplicationFiled: April 3, 2012Publication date: July 26, 2012Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: James S. DUNN, Alvin J. JOSEPH, Anthony K. STAMPER
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Patent number: 8227340Abstract: A method for producing an electrically conductive connection between a first surface of a semiconductor substrate and a second surface of the semiconductor substrate includes producing a hole, forming an electrically conductive layer that includes tungsten, removing the electrically conductive layer from the first surface of the semiconductor substrate, filling the hole with copper and thinning the semiconductor substrate. The hole is produced from the first surface of the semiconductor substrate into the semiconductor substrate. The electrically conductive layer is removed from the first surface of the semiconductor substrate, wherein the electrically conductive layer remains at least with reduced thickness in the hole. The semiconductor substrate is thinned starting from a surface, which is an opposite surface of the first surface of the semiconductor substrate, to obtain the second surface of the semiconductor substrate with the hole being uncovered at the second surface of the semiconductor substrate.Type: GrantFiled: April 30, 2009Date of Patent: July 24, 2012Assignee: Infineon Technologies AGInventors: Uwe Seidel, Thorsten Obernhuber, Albert Birner, Georg Ehrentraut
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Publication number: 20120178253Abstract: The inventive concept provides porous, low-k dielectric materials and methods of manufacturing and using the same. In some embodiments, porous, low-k dielectric materials are manufactured by forming a porogen-containing dielectric layer on a substrate and then removing at least a portion of said porogen from the layer.Type: ApplicationFiled: September 23, 2011Publication date: July 12, 2012Inventors: Sang-Hoon Ahn, Kyu-Hee Han, Kyoung-Hee Kim, Gil-Heyun Choi, Byung-Hee Kim, Sang-Don Nam
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Patent number: 8216932Abstract: The present invention relates to semiconductor devices and a method of fabricating the same. According to a method of manufacturing semiconductor devices, there is first provided a semiconductor substrate in which a first pre-metal dielectric layer including trenches is formed. A diffusion barrier layer is formed on the entire surface including the trenches. A metal layer is formed on the diffusion barrier layer including the trenches, thereby gap-filling the trenches. A polish etching process is performed on the metal layer and the diffusion barrier layer so that the diffusion barrier layer and the metal layer remain within the trenches. An etching process of lowering a height of the metal layer is performed in order to increase a distance between metal lines. A capping layer is formed on the entire surface including exposed sidewalls of the first pre-metal dielectric layer. A second pre-metal dielectric layer is formed over the capping layer.Type: GrantFiled: December 29, 2008Date of Patent: July 10, 2012Assignee: Hynix Semiconductor Inc.Inventors: Cheol Mo Jeong, Eun Soo Kim, Seung Hee Hong
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Patent number: 8211794Abstract: In accordance with the invention, there are diffusion barriers, integrated circuits, and semiconductor devices and methods of fabricating them. The method of fabricating a diffusion barrier can include providing a dielectric layer, forming a first silicon enriched layer over the dielectric layer by exposing the dielectric layer to a silicon-containing ambient, and forming a barrier layer over the first silicon enriched layer.Type: GrantFiled: May 25, 2007Date of Patent: July 3, 2012Assignee: Texas Instruments IncorporatedInventors: Valli Arunachalam, Satyavolu Srinivas Papa Rao, Sanjeev Aggarwal, Stephan Grunow
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Patent number: 8211740Abstract: To arrange diffusion-inhibitory films 5a, 5b, and 5c for inhibiting the diffusion of a wiring material absent in a region on or above a light receiving unit 2, the diffusion-inhibitory films 5a, 5b, and 5c formed on a region above the light receiving unit 2 are selectively removed. Alternatively, the diffusion-inhibitory films are arranged only on top surfaces of wirings 4a, 4b, and 4c, and only a passivation film 12 and interlayer insulating films 3a, 3b, and 3c are arranged in the region on or above the light receiving unit 2. Thus, with less interface between different insulation films and less reflection of incident light in an incident region, the incident light 13 highly efficiently passes through these insulating films and comes into the light receiving unit 2. The light receiving unit 2 can thereby receive a sufficient quantity of the incident light 13.Type: GrantFiled: February 9, 2010Date of Patent: July 3, 2012Assignee: Sony CorporationInventor: Ikuhiro Yamamura
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Patent number: 8211776Abstract: A method for fabricating an integrated circuit comprising an electromigration barrier in a line of the integrated circuit includes forming a spacer; forming a segmented line adjacent to opposing sides of the spacer, the segmented line formed from a first conductive material; removing the spacer to form an empty line break; and filling the empty line break with a second conductive material to form an electromigration barrier that isolates electromigration effects within individual segments of the segmented line. An integrated circuit comprising an electromigration barrier includes a line, the line comprising a first conductive material, the line further comprising a plurality of line segments separated by one or more electromigration barriers, wherein the one or more electromigration barriers comprise a second conductive material that isolates electromigration effects within individual segments of the line.Type: GrantFiled: January 5, 2010Date of Patent: July 3, 2012Assignee: International Business Machines CorporationInventors: David V. Horak, Takeshi Nogami, Shom Ponoth, Chih-Chao Yang
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Publication number: 20120161320Abstract: Electrical interconnects for integrated circuits and methods of fabrication of interconnects are provided. Devices are provided comprising copper interconnects having metal liner layers comprising cobalt and a metal selected from the group consisting of Ru, Pt, Ir, Pd, Re, or Rh. Devices having barrier layers comprising ruthenium and cobalt are provided. Methods include providing a substrate having a trench or via formed therein, forming a metal layer, the metal being selected from the group consisting of Ru, Pt, Ir, Pd, Re, and Rh, onto surfaces of the feature, depositing a copper seed layer comprising a cobalt dopant, and depositing copper into the feature.Type: ApplicationFiled: December 23, 2010Publication date: June 28, 2012Inventors: Rohan N. Akolkar, James S. Clarke
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Publication number: 20120153479Abstract: In metallization systems of complex semiconductor devices, an intermediate interface layer may be incorporated into the interconnect structures in order to provide superior electromigration performance. To this end, the deposition of the actual fill material may be interrupted at an appropriate stage and the interface layer may be formed, for instance, by deposition, surface treatment and the like, followed by the further deposition of the actual fill metal. In this manner, the grain size issue, in particular at lower portions of the scaled inter-connect features, may be addressed.Type: ApplicationFiled: July 25, 2011Publication date: June 21, 2012Applicant: GLOBALFOUNDRIES INC.Inventors: Oliver Aubel, Christian Hennesthal, Frank Feustel, Thomas Werner
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Publication number: 20120156872Abstract: Methods for depositing materials in high aspect ratio features are disclosed herein. In some embodiments, a method of processing a substrate may include providing a substrate having an opening formed in a first surface of the substrate and extending into the substrate towards an opposing second surface of the substrate, the opening having an aspect ratio of height to width of at least 3:1, forming a barrier layer atop the first surface of the substrate and along sidewalls and a bottom surface of the opening, the barrier layer having a first thickness atop the first surface of the substrate, and forming a seed layer atop the barrier layer, wherein a ratio of the second thickness to the first thickness ranges from about 2:1 to about 5:1.Type: ApplicationFiled: November 30, 2011Publication date: June 21, 2012Applicant: APPLIED MATERIALS, INC.Inventor: ZHITAO CAO
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Publication number: 20120153490Abstract: The disclosure relates to a method of fabricating an interconnection structure of an integrated circuit, comprising the steps of: forming a first conductive element within a first dielectric layer; depositing a first etch stop layer above the first conductive element and the first dielectric layer; forming an opening in the first etch stop layer above the first conductive element, to form a first connection area; depositing a second dielectric layer above the etch stop layer and above the first conductive element in the connection area; etching the second dielectric layer to form at least one hole which is at least partially aligned with the connection area; and filling the hole with a conductive material to form a second conductive element in electrical contact with the first conductive element.Type: ApplicationFiled: December 15, 2011Publication date: June 21, 2012Applicant: STMICROELECTRONICS (CROLLES 2) SASInventor: Patrick Vannier
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Publication number: 20120149191Abstract: An interconnect structure is provided that has enhanced electromigration reliability without degrading circuit short yield, and improved technology extendibility. The inventive interconnect structure includes a dielectric material having a dielectric constant of about 3.0 or less. The dielectric material has at least one conductive material embedded therein. A noble metal cap is located directly on an upper surface of the at least one conductive region. The noble metal cap does not substantially extend onto an upper surface of the dielectric material that is adjacent to the at least one conductive region, and the noble cap material does not be deposited on the dielectric surface. A method fabricating such an interconnect structure utilizing a low temperature (about 300° C. or less) chemical deposition process is also provided.Type: ApplicationFiled: February 16, 2012Publication date: June 14, 2012Applicant: International Business Machines CorporationInventors: Chih-Chao Yang, Daniel C. Edelstein
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Publication number: 20120139114Abstract: A copper interconnect structure has an intrinsic graphene cap for improving back end of line (BEOL) reliability of the interconnect by reducing time-dependent dielectric breakdown (TDDB) failure and providing resistance to electromigration. Carbon atoms are selectively deposited onto a copper layer of the interconnect structure by a deposition process to form a graphene cap. The graphene cap increases the activation energy of the copper, thus allowing for higher current density and improved resistance to electromigration of the copper. By depositing the graphene cap on the copper, the dielectric regions remain free of conductors and, thus, current leakage within the interlayer dielectric regions is reduced, thereby reducing TDDB failure and increasing the lifespan of the interconnect structure. The reduction of TDDB failure and improved resistance to electromigration improves BEOL reliability of the copper interconnect structure.Type: ApplicationFiled: December 6, 2010Publication date: June 7, 2012Applicant: STMicroelectronics, Inc.Inventors: John Hongguang Zhang, Cindy Goldberg, Walter Kleemeier, Ronald Kevin Sampson
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Patent number: 8193089Abstract: Various embodiments of the present invention are generally directed to a method of forming a conductive via plug in a semiconductor device. A first and second metal layer are electrically connected by a via plug that is formed by depositing a tungsten seed layer on a plurality of metal barrier layers within a recess using atomic layer deposition. The recess is then filled with tungsten using chemical vapor deposition.Type: GrantFiled: July 13, 2009Date of Patent: June 5, 2012Assignee: Seagate Technology LLCInventors: Antoine Khoueir, Yongchul Ahn, Peter Nicholas Manos, Shuiyan Huang, Ivan Petrov Ivanov
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Patent number: 8193032Abstract: A method for formation of a carbon-based field effect transistor (FET) includes depositing a first dielectric layer on a carbon layer located on a substrate; forming a gate electrode on the first dielectric layer; etching an exposed portion of the first dielectric layer to expose a portion of the carbon layer; depositing a second dielectric layer over the gate electrode to form a spacer, wherein the second dielectric layer is deposited by atomic layer deposition (ALD), and wherein the second dielectric layer does not form on the exposed portion of the carbon layer; forming source and drain contacts on the carbon layer and forming a gate contact on the gate electrode to form the carbon-based FET.Type: GrantFiled: June 29, 2010Date of Patent: June 5, 2012Assignee: International Business Machines CorporationInventors: Zhihong Chen, Dechao Guo, Shu-jen Han, Kai Zhao
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Patent number: 8193087Abstract: An integrated circuit includes a semiconductor substrate, a low-k dielectric layer over the semiconductor substrate, a first opening in the low-k dielectric layer, and a first diffusion barrier layer in the first opening covering the low-k dielectric layer in the first opening, wherein the first diffusion barrier layer has a bottom portion connected to sidewall portions, and wherein the sidewall portions have top surfaces close to a top surface of the low-k dielectric layer. The integrated circuit further includes a conductive line filling the first opening wherein the conductive line has a top surface lower than the top surfaces of the sidewall portions of the diffusion barrier layer, and a metal cap on the conductive line and only within a region directly over the conductive line.Type: GrantFiled: November 28, 2006Date of Patent: June 5, 2012Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.Inventors: Chien-Hsueh Shih, Minghsing Tsai, Chen-Hua Yu, Ming-Shih Yeh
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Publication number: 20120132984Abstract: A contact plug 40 electrically connected to an impurity diffusion region between sidewalls of an adjacent pair of memory cells 1 is provided to pass through an interlayer dielectric film 18. A side wall of a contact hole 41 is covered with a sealing film 42 denser than the interlayer dielectric film 18. The contact plug 40 includes a barrier metal film 43 formed to cover a surface of the sealing film 42 and a bottom surface portion of the contact hole 41 and a metal plug 44 embedded in the contact hole 41 in a state surrounded by the barrier metal film 43.Type: ApplicationFiled: February 2, 2012Publication date: May 31, 2012Applicant: ROHM CO., LTD.Inventors: Michihiko Mifuji, Yuichi Nakao, Toshikazu Mizukoshi, Bungo Tanaka, Taku Shibaguchi, Gentaro Morikawa
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Patent number: 8183552Abstract: A semiconductor memory device having a first wiring layer which is provided on a first insulator, and which extends in a first direction, and a non-volatile memory cell which is provided in a pillar shape on the first wiring layer, and which includes a non-ohmic element and variable resistance element connected in series. The resistance value of the variable resistance element changes in accordance with a voltage or current applied thereto. A barrier layer is provided on the memory cell and is configured in an in-plane direction. A conductive layer is provided on the barrier layer and is configured in an in-plane direction. A second insulator is provided on the first insulator and covers side surfaces of the memory cell, the barrier layer, and the conductive layer. A second wiring layer is provided on the conductive layer and extends in a second direction.Type: GrantFiled: August 13, 2009Date of Patent: May 22, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Shingo Nakajima, Eiji Ito, Mitsuhiro Noguchi
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Patent number: 8183153Abstract: Disclosed is a method for manufacturing a semiconductor device which is decreased in resistance of a copper wiring containing a ruthenium-containing film and a copper-containing film, thereby having improved reliability. Also disclosed is an apparatus for manufacturing a semiconductor device. Specifically, an Ru film is formed on a substrate having a recessed portion by a CVD method using a raw material containing an organic ruthenium complex represented by the general formula and a reducing gas (step S12). Then, a Cu film is formed on the Ru film by a CVD method using a raw material containing an organic copper complex represented by the general formula and a reducing gas, thereby forming a copper wiring containing the Ru film and the Cu film in the recessed portion (step S14).Type: GrantFiled: September 3, 2008Date of Patent: May 22, 2012Assignee: Ulvac, Inc.Inventors: Hideaki Zama, Michio Ishikawa, Takumi Kadota, Chihiro Hasegawa
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Patent number: 8178436Abstract: Interconnect structures having improved adhesion and electromigration performance and methods to fabricate thereof are described. A tensile capping layer is formed on a first conductive layer on a substrate. A compressive capping layer is formed on the tensile capping layer. Next, an interlayer dielectric layer is formed on the compressive capping layer. Further, a first opening is formed in the ILD layer using a first chemistry. A second opening is formed in the tensile capping layer and the compressive capping layer using a second chemistry. Next, a second conductive layer is formed in the first opening and the second opening.Type: GrantFiled: December 21, 2006Date of Patent: May 15, 2012Assignee: Intel CorporationInventors: Sean King, Jason Klaus