Altering Composition Of Conductor Patents (Class 438/658)
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Patent number: 11837468Abstract: A method of manufacturing a stacked structure includes forming a first metal buffer layer including crystal grains on a base substrate, forming a second metal buffer material layer on the first metal buffer layer, and crystallizing the second metal buffer material layer to form a second metal buffer layer, wherein the second metal buffer material layer includes crystal grains, and a density of the crystal grains of the second metal buffer material layer is lower than a density of the crystal grains of the first metal buffer layer.Type: GrantFiled: September 8, 2021Date of Patent: December 5, 2023Assignees: SAMSUNG DISPLAY CO., LTD., INDUSTRY-ACADEMIC COOPERATION FOUNDATION, YONSEI UNIVERSITYInventors: Mann Ho Cho, Kwang Sik Jeong, Hyeon Sik Kim, Hyun Eok Shin, Byung Soo So, Ju Hyun Lee
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Patent number: 11694912Abstract: Embodiments of the disclosure relate to an apparatus and method for annealing one or more semiconductor substrates. In one embodiment, a processing chamber is disclosed. The processing chamber includes a chamber body enclosing an internal volume, a substrate support disposed in the internal volume and configured to support a substrate during processing, a gas panel configured to provide a processing fluid into the internal volume, and a temperature-controlled fluid circuit configured to maintain the processing fluid at a temperature above a condensation point of the processing fluid. The temperature-controlled fluid circuit includes a gas conduit fluidly coupled to a port on the chamber body at a first end and to the gas panel at a second end.Type: GrantFiled: May 25, 2021Date of Patent: July 4, 2023Assignee: Applied Materials, Inc.Inventors: Jean Delmas, Steven Verhaverbeke, Kurtis Leschkies
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Patent number: 11688601Abstract: A method of forming a composite crystalline nitride structure is provided. The method includes depositing a first crystalline nitride layer on a substrate, patterning the first crystalline nitride layer to form a patterned crystalline nitride layer having a top surface and that includes undulations, annealing the patterned crystalline nitride layer at a temperature between 300° C. to 850° C. to form an annealed patterned crystalline nitride layer, and depositing a second crystalline nitride layer on the annealed patterned crystalline nitride layer. The second crystalline nitride layer is lattice-matched to the underlying annealed patterned crystalline nitride layer to within 2%, thereby forming the composite crystalline nitride structure.Type: GrantFiled: November 30, 2020Date of Patent: June 27, 2023Assignee: International Business Machines CorporationInventor: Aakash Pushp
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Patent number: 10978572Abstract: Embodiments of the present invention are directed to techniques for forming a self-aligned contact liner using metal-insulator transition materials. The self-aligned contact architecture described herein prevents a short between the gate and the source/drain, even when the self-aligned contact (SAC) cap has eroded to the point where the gate is exposed. In a non-limiting embodiment of the invention, a dielectric cap is formed over a conductive gate. A source or drain region is formed adjacent to the conductive gate. A dielectric liner is formed over the dielectric cap and the source or drain region such that a first portion of the dielectric liner is on a surface of the source or drain region. The dielectric liner includes a metal-insulator transition material. The first portion of the dielectric liner is metalized via germanium oxide sublimation.Type: GrantFiled: November 18, 2019Date of Patent: April 13, 2021Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Choonghyun Lee, Kangguo Cheng, Juntao Li, Peng Xu
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Patent number: 10879366Abstract: Techniques for reducing the specific contact resistance of metal—semiconductor (group IV) junctions by interposing a monolayer of group V or group III atoms at the interface between the metal and the semiconductor, or interposing a bi-layer made of one monolayer of each, or interposing multiple such bi-layers. The resulting low specific resistance metal—group IV semiconductor junctions find application as a low resistance electrode in semiconductor devices including electronic devices (e.g., transistors, diodes, etc.) and optoelectronic devices (e.g., lasers, solar cells, photodetectors, etc.) and/or as a metal source and/or drain region (or a portion thereof) in a field effect transistor (FET). The monolayers of group III and group V atoms are predominantly ordered layers of atoms formed on the surface of the group IV semiconductor and chemically bonded to the surface atoms of the group IV semiconductor.Type: GrantFiled: December 6, 2019Date of Patent: December 29, 2020Assignee: Acorn Semi, LLCInventors: Walter A. Harrison, Paul A. Clifton, Andreas Goebel, R. Stockton Gaines
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Patent number: 10822714Abstract: A method of growing a crystal in a recess in a substrate on which an insulating film having the recess is formed, includes: forming a first film on the insulating film at a thickness as not to completely fill the recess; etching the first film by an etching gas to remain the first film only in a bottom portion of the recess; annealing the substrate such that the first film in the bottom portion is modified into a crystalline layer; forming a second film on the insulating film and a surface of the crystalline layer at a thickness as not to completely fill the recess; annealing the substrate such that the second film is crystallized from the bottom portion through a solid phase epitaxial growth to form an epitaxial crystal layer; and etching and removing the second film remaining on the substrate by an etching gas.Type: GrantFiled: March 6, 2017Date of Patent: November 3, 2020Assignee: TOKYO ELECTRON LIMITEDInventors: Yoichiro Chiba, Daisuke Suzuki, Kazuhide Hasebe
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Patent number: 10358737Abstract: A method includes providing a plurality of particles of an energetic material suspended in a dispersion liquid to an EPD chamber or configuration; applying a voltage difference across a first pair of electrodes to generate a first electric field in the EPD chamber; and depositing at least some of the particles of the energetic material on at least one surface of a substrate, the substrate being one of the electrodes or being coupled to one of the electrodes.Type: GrantFiled: May 13, 2015Date of Patent: July 23, 2019Assignee: Lawrence Livermore National Security, LLCInventors: Kyle Sullivan, Alexander E. Gash, Joshua Kuntz, Marcus A. Worsley
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Patent number: 9666439Abstract: A method of manufacturing a semiconductor device includes forming a seed layer containing a metal element on a substrate by performing a first process and a second process in a time-division manner. The first process supplying and exhausting organic metal-containing gas containing the metal element to the substrate. The second process supplying and exhausting inorganic metal-containing gas containing the metal element to the substrate, and forming a metal-containing nitride film on the substrate on which the seed layer is formed using the seed layer as a seed by performing a third process and a fourth process in a time-division manner. The third process supplying and exhausting the inorganic metal-containing gas to the substrate. The fourth process supplying and exhausting nitrogen-containing gas to the substrate.Type: GrantFiled: March 15, 2016Date of Patent: May 30, 2017Assignee: HITACHI KOKUSAI ELECTRIC INC.Inventor: Arito Ogawa
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Patent number: 9595449Abstract: Oxidation treatment of a Si1-xGex (0<x<1) substrate forms on the substrate an interfacial layer comprised of silicon oxide and germanium oxide. The presence of germanium oxide in the interfacial layer is deleterious to the quality of the interfacial layer/Si1-xGex conducting channel as evidenced by an increase in charge interface states and a decrease in carrier mobility. Germanium oxide is scavenged from the interfacial layer in a scavenging step comprising heating the interfacial layer/substrate in a hydrogen-containing reducing atmosphere at a temperature of from about 450° C. to about 800° C. to reduce the germanium oxide content of the interfacial layer to not more than about 10% by weight, for example, not more than about 1% by weight, of the weight of the scavenged interfacial layer.Type: GrantFiled: December 21, 2015Date of Patent: March 14, 2017Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Hemanth Jagannathan, ChoongHyun Lee
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Patent number: 9190480Abstract: A semiconductor body has a first surface, a second opposing surface, an edge, an active device region, and an edge termination region. A trench extends from the first surface into the semiconductor body in the edge termination region and includes sidewalls and an insulated electrode. A first conductivity type doped region extends from the first surface into the semiconductor body in the edge termination region and has a planar outer surface along the first surface that adjoins the trench at a corner of the trench sidewall and the first surface and has a side surface extending from the corner along the trench sidewall. A first interconnect contacts the trench electrode. A second interconnect contacts the outer surface and the side surface. A contact couples the first doped region to the trench electrode and has a bottom surface coplanar with the first surface from a contact edge to the corner.Type: GrantFiled: December 20, 2013Date of Patent: November 17, 2015Assignee: Infineon Technologies Austria AGInventors: Ralf Siemieniec, Li Juin Yip, Oliver Blank
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Patent number: 9159667Abstract: An e-fuse device disclosed herein includes an anode and a cathode that are conductively coupled to the doped region formed in a substrate, wherein the anode includes a first metal silicide region positioned on the doped region and a first conductive metal-containing contact that is positioned above and coupled to the first metal silicide region, and the cathode includes a second metal silicide region positioned on the doped region and a second conductive metal-containing contact that is positioned above and conductively coupled to the second metal silicide region. A method disclosed herein includes forming a doped region in a substrate for an e-fuse device and performing at least one common process operation to form a first conductive structure on the doped region of the e-fuse device and a second conductive structure on a source/drain region of a transistor.Type: GrantFiled: July 26, 2013Date of Patent: October 13, 2015Assignee: GLOBALFOUNDRIES Inc.Inventors: Xiaoqiang Zhang, O Sung Kwon, Jianghu Yan, Wen-Hu Hung, Roderick Miller, HongLiang Shen
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Patent number: 9029260Abstract: The present disclosure provides a method of fabricating a semiconductor device. The method includes forming a patterned dielectric layer having a plurality of first openings. The method includes forming a conductive liner layer over the patterned dielectric layer, the conductive liner layer partially filling the first openings. The method includes forming a trench mask layer over portions of the conductive liner layer outside the first openings, thereby forming a plurality of second openings, a subset of which are formed over the first openings. The method includes depositing a conductive material in the first openings to form a plurality of vias and in the second openings to form a plurality of metal lines. The method includes removing the trench mask layer.Type: GrantFiled: June 16, 2011Date of Patent: May 12, 2015Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Chun Chieh Lin, Hung-Wen Su, Minghsing Tsai, Syun-Ming Jang
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Patent number: 9012323Abstract: A method of manufacturing a semiconductor device, includes: alternately performing (i) a first step of alternately supplying a first raw material containing a first metal element and a halogen element and a second raw material containing a second metal element and carbon to a substrate by a first predetermined number of times, and (ii) a second step of supplying a nitridation raw material to the substrate, by a second predetermined number of times, wherein alternating the first and second steps forms a metal carbonitride film containing the first metal element having a predetermined thickness on the substrate.Type: GrantFiled: February 26, 2014Date of Patent: April 21, 2015Assignee: Hitachi Kokusai Electric Inc.Inventors: Arito Ogawa, Tsuyoshi Takeda
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Patent number: 8975182Abstract: A method for manufacturing a semiconductor device is carried out by readying each of a semiconductor element, a substrate having Cu as a principal element at least on a surface, and a ZnAl solder chip having a smaller shape than that of the semiconductor element; disposing the semiconductor element and the substrate so that respective bonding surfaces face each other, and sandwiching the ZnAl eutectic solder chip between the substrate and the semiconductor element; increasing the temperature of the ZnAl solder chip sandwiched between the substrate and the semiconductor element while applying a load to the ZnAl solder chip such that the ZnAl solder chip melts to form a ZnAl solder layer; and reducing the temperature of the ZnAl solder layer while applying a load to the ZnAl solder layer.Type: GrantFiled: July 27, 2012Date of Patent: March 10, 2015Assignees: Nissan Motor Co., Ltd., Sumitomo Metal Mining Co., Ltd., Sanken Electric Co., Ltd., Fuji Electric Co., Ltd.Inventors: Satoshi Tanimoto, Yusuke Zushi, Yoshinori Murakami, Takashi Iseki, Masato Takamori, Shinji Sato, Kohei Matsui
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Patent number: 8969197Abstract: A structure with improved electromigration resistance and methods for making the same. A structure having improved electromigration resistance includes a bulk interconnect having a dual layer cap and a dielectric capping layer. The dual layer cap includes a bottom metallic portion and a top metal oxide portion. Preferably the metal oxide portion is MnO or MnSiO and the metallic portion is Mn or CuMn. The structure is created by doping the interconnect with an impurity (Mn in the preferred embodiment), and then creating lattice defects at a top portion of the interconnect. The defects drive increased impurity migration to the top surface of the interconnect. When the dielectric capping layer is formed, a portion reacts with the segregated impurities, thus forming the dual layer cap on the interconnect. Lattice defects at the Cu surface can be created by plasma treatment, ion implantation, a compressive film, or other means.Type: GrantFiled: May 18, 2012Date of Patent: March 3, 2015Assignee: International Business Machines CorporationInventors: Daniel C. Edelstein, Takeshi Nogami, Christopher Parks, Tsong-Lin Tai
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Patent number: 8962466Abstract: A metal oxide formed by in situ oxidation assisted by radiation induced photo-acid is described. The method includes depositing a photosensitive material over a metal surface of an electrode. Upon exposure to radiation (for example ultraviolet light), a component, such as a photo-acid generator, of the photosensitive material forms an oxidizing reactant, such as a photo acid, which causes oxidation of the metal at the metal surface. As a result of the oxidation, a layer of metal oxide is formed. The photosensitive material can then be removed, and subsequent elements of the component can be formed in contact with the metal oxide layer. The metal oxide can be a transition metal oxide by oxidation of a transition metal. The metal oxide layer can be applied as a memory element in a programmable resistance memory cell. The metal oxide can be an element of a programmable metallization cell.Type: GrantFiled: May 15, 2013Date of Patent: February 24, 2015Assignee: Macronix International Co., Ltd.Inventors: Feng-Min Lee, Erh-Kun Lai, Wei-Chih Chien, Ming-Hsiu Lee, Chih-Chieh Yu
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Patent number: 8951912Abstract: A method of manufacturing a semiconductor device, includes: alternately performing (i) a first step of alternately supplying a first raw material containing a first metal element and a halogen element and a second raw material containing a second metal element and carbon to a substrate by a first predetermined number of times, and (ii) a second step of supplying a nitridation raw material to the substrate, by a second predetermined number of times, wherein alternating the first and second steps forms a metal carbonitride film containing the first metal element having a predetermined thickness on the substrate.Type: GrantFiled: September 14, 2012Date of Patent: February 10, 2015Assignee: Hitachi Kokusai Electric Inc.Inventors: Arito Ogawa, Tsuyoshi Takeda
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Patent number: 8946667Abstract: A method for forming a resistive switching device. The method includes providing a substrate having a surface region and forming a first dielectric material overlying the surface region of the substrate. A first wiring structure overlies the first dielectric material. The method forms a first electrode material overlying the first wiring structure and a resistive switching material comprising overlying the first electrode material. An active metal material is formed overlying the resistive switching material. The active metal material is configured to form an active metal region in the resistive switching material upon application of a thermal energy characterized by a temperature no less than about 100 Degree Celsius. In a specific embodiment, the method forms a blocking material interposing the active metal material and the resistive switching material to inhibit formation of the active metal region in the resistive switching material during the subsequent processing steps.Type: GrantFiled: April 13, 2012Date of Patent: February 3, 2015Assignee: Crossbar, Inc.Inventors: Mark Harold Clark, Steven Maxwell, Harry Gee, Natividad Vasquez
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Patent number: 8937013Abstract: A method for easily forming a region with conductivity and high wettability without a step for removing a photocatalytic reaction layer, which is formed over a conductive layer, is proposed. The photocatalytic reaction layer is formed over a photocatalytic conductive layer, and the photocatalytic conductive layer is irradiated with ultraviolet light to form a region with conductivity and higher wettability than the photocatalytic reaction layer on a surface of the photocatalytic conductive layer which is irradiated with ultraviolet light. Note that for the photocatalytic conductive layer, a layer having a photocatalytic property of which resistivity is lower than or equal to 1×10?2 ? cm can be used.Type: GrantFiled: October 12, 2007Date of Patent: January 20, 2015Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Masafumi Morisue
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Patent number: 8932911Abstract: Integrated circuits and methods for fabricating integrated circuits are provided. In an exemplary embodiment, a method for fabricating integrated circuits includes forming a metal contact structure that is electrically connected to a device. A capping layer is selectively formed on the metal contact structure, and an interlayer dielectric material is deposited over the capping layer. A metal hard mask is deposited and patterned over the interlayer dielectric material to define an exposed region of the interlayer dielectric material. The method etches the exposed region of the interlayer dielectric material to expose at least a portion of the capping layer. The method includes removing the metal hard mask with an etchant while the capping layer physically separates the metal contact structure from the etchant. A metal is deposited to form a conductive via electrically connected to the metal contact structure through the capping layer.Type: GrantFiled: February 27, 2013Date of Patent: January 13, 2015Assignee: GLOBALFOUNDRIES, Inc.Inventors: Torsten Huisinga, Carsten Peters, Andreas Ott, Axel Preusse
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Patent number: 8918152Abstract: Disclosed are devices comprising multiple nanogaps having a separation of less than about 5 nm. Also disclosed are methods for fabricating these devices.Type: GrantFiled: February 13, 2008Date of Patent: December 23, 2014Assignee: The Trustees Of The University Of PennsylvaniaInventors: Douglas R. Strachan, Danvers E. Johnston, Beth S. Guiton, Peter K. Davies, Dawn A. Bonnell, Alan T. Johnson, Jr.
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Patent number: 8871107Abstract: A method of forming at least one metal or metal alloy feature in an integrated circuit is provided. In one embodiment, the method includes providing a material stack including at least an etch mask located on a blanker layer of metal or metal alloy. Exposed portions of the blanket layer of metal or metal alloy that are not protected by the etch mask are removed utilizing an etch comprising a plasma that forms a polymeric compound and/or complex which protects a portion of the blanket layer of metal or metal alloy located directly beneath the etch mask during the etch.Type: GrantFiled: March 15, 2013Date of Patent: October 28, 2014Assignee: International Business Machines CorporationInventors: Nicholas C. M. Fuller, Eric A. Joseph, Hiroyuki Miyazoe, Mark Hoinkis, Chun Yan
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Publication number: 20140295213Abstract: The invention relates to a method for functionalizing an electrically conductive substrate, which is not a substrate made of gold, via a layer of chemical compounds, said method comprising the following steps: a step in which the electrically conductive substrate is placed in contact with chemical compounds comprising at least a disulfide terminal group; a step in which the disulfide terminal group of said chemical compounds is electro-oxidized, causing said chemical compounds to form a layer at the surface of the electrically conductive substrate.Type: ApplicationFiled: October 5, 2012Publication date: October 2, 2014Applicants: UNIVERSITE JOSEPH FOURIER, Commissariat a l'energie atomique et aux ene altInventors: Eric Jalaguier, Julien Buckley, Xavier Chevalier, Guy Royal
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Publication number: 20140264920Abstract: Presented herein is a method for electrolessly forming a metal cap in a via opening, comprising bringing a via into contact with metal solution, the via disposed in an opening in a substrate, and forming a metal cap in the opening and in contact with the via, the metal cap formed by an electroless chemical reaction. A metal solution may be applied to the via to form the metal cap. The metal solution may comprises at least cobalt and the cap may comprise at least cobalt, and may optionally further comprise tungsten, and wherein the forming the cap comprises forming the cap to further comprise at least tungsten. The metal solution may further comprise at least hypophosphite or dimethlyaminoborane.Type: ApplicationFiled: March 25, 2013Publication date: September 18, 2014Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.Inventor: Taiwan Semiconductor Manufacturing Company, Ltd.
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Patent number: 8815728Abstract: A semiconductor device and a method for manufacturing the semiconductor device are provided. The semiconductor device uses an aluminum alloy, rather than aluminum, for a metal gate. Therefore, the surface of the high-k metal gate after the CMP is aluminum alloy rather than pure aluminum, which can greatly reduce defects, such as corrosion, pits and damage, in the metal gate and improve reliability of the semiconductor device.Type: GrantFiled: June 1, 2012Date of Patent: August 26, 2014Assignee: Semiconductor Manufacturing International (Shanghai) CorporationInventors: Li Jiang, Mingqi Li, Pulei Zhu
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Patent number: 8802560Abstract: A method for forming a semiconductor interconnect structure includes forming a dielectric layer on a substrate and patterning the dielectric layer to form an opening therein. A metal layer fills the opening and covers the dielectric layer. The metal layer is planarized so that it is co-planar with a top of the dielectric layer. A treating process is performed on the metal layer to convert a top surface thereof into a metal oxide layer. A copper-containing layer is then formed over the metal oxide layer and the dielectric layer. The copper-containing layer is etched to form interconnect features, wherein the etching stops at the metal oxide layer and does not etch into the underlying metal layer. A radiation exposure process is thereafter performed on the metal oxide layer to convert it into a non-oxidized metal layer.Type: GrantFiled: May 23, 2013Date of Patent: August 12, 2014Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Chih Wei Lu, Chung-Ju Lee
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Publication number: 20140187039Abstract: A method for tuning the effective work function of a gate structure in a semiconductor device is described. The semiconductor device is part of an integrated circuit and the gate structure has a metal layer and a high-k dielectric layer separating the metal layer from an active layer of the semiconductor device. The method includes providing an interconnect structure of the integrated circuit on top of the gate structure, the interconnect structure comprising a layer stack comprising at least a pre-metal dielectric layer comprising a metal filled connecting via connected to the gate structure through the pre-metal dielectric layer, and the interconnect structure having an upper exposed metal portion; and, thereafter, exposing at least a portion of the upper exposed metal portion to a plasma under predetermined exposure conditions, to tune the effective work function of the gate structure.Type: ApplicationFiled: December 18, 2013Publication date: July 3, 2014Applicant: IMECInventors: Thomas Kauerauf, Alessio Spessot, Christian Caillat
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Patent number: 8741783Abstract: A method of cleaning an inside of a processing chamber is provided according to an embodiment of the present disclosure. The method includes supplying a fluorine-based gas and a nitrogen oxide-based gas as the cleaning gas, into the processing chamber heated to a first temperature, and removing a deposit by a thermochemical reaction. The method further includes changing a temperature in the processing chamber to a second temperature higher than the first temperature, and supplying the fluorine-based gas and the nitrogen oxide-based gas as the cleaning gas, and removing extraneous materials, remaining on the surface of the member in the processing chamber, by a thermochemical reaction.Type: GrantFiled: September 14, 2012Date of Patent: June 3, 2014Assignee: Hitachi Kokusai Electric Inc.Inventors: Kenji Kameda, Yuji Urano
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Patent number: 8716129Abstract: A method for manufacturing a silicon carbide semiconductor device includes the step of forming a silicon dioxide film. The step of forming an electrode includes the steps of forming a metal film containing Al and Ti on the silicon carbide substrate, and heating the metal film. The step of heating the metal film has the steps of increasing temperature of the metal film from a temperature of less than 300° C. to a temperature of not less than 300° C. and not more than 450° C. with a first temperature gradient, holding the metal film within a temperature range of not less than 300° C. and not more than 450° C. with a second temperature gradient, and increasing the temperature of the metal film to a temperature of not less than 500° C. with a third temperature gradient. The second temperature gradient is smaller than the first temperature gradient and the third temperature gradient.Type: GrantFiled: July 9, 2013Date of Patent: May 6, 2014Assignee: Sumitomo Electric Industries, Ltd.Inventor: Hideto Tamaso
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Patent number: 8716098Abstract: A method for forming a non-volatile memory device includes providing a substrate having a surface region, forming a first wiring structure overlying the surface region, depositing a first dielectric material overlying the first wiring structure, forming a via opening in the first dielectric material to expose a portion of the first wiring structure, while maintaining a portion of the first dielectric material, forming a layer of resistive switching material comprising silicon, within the via opening, forming a silver material overlying the layer of resistive switching material and the portion of the first dielectric material, forming a diffusion barrier layer overlying the silver material, and selectively removing a portion of the silver material and a portion of the diffusion barrier layer overlying the portion of the first dielectric material while maintaining a portion of the silver material and a portion of the diffusion barrier material overlying the layer of silicon material.Type: GrantFiled: March 9, 2012Date of Patent: May 6, 2014Assignee: Crossbar, Inc.Inventors: Scott Brad Herner, Natividad Vasquez
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Patent number: 8647959Abstract: A method of fabricating a semiconductor device includes forming a bottom electrode material layer containing aluminum and copper over the substrate. An insulating material layer and a top electrode material layer are sequentially formed on the surface of the bottom electrode material layer. A photoresist pattern is formed on the top electrode material layer, and then the top electrode material layer is patterned to form a top electrode by using the photoresist pattern as mask. The photoresist pattern is removed by plasma ash and then an alloy process is performed to the bottom electrode material layer. Thereafter, the insulating material layer, and the bottom electrode material layer are patterned to form a patterned insulating layer and a patterned bottom electrode layer.Type: GrantFiled: September 8, 2011Date of Patent: February 11, 2014Assignee: United Microelectronics Corp.Inventor: Chun-Chen Hsu
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Patent number: 8633101Abstract: A manufacturing method of a semiconductor device including an electrode having low contact resistivity to a nitride semiconductor is provided. The manufacturing method includes a carbon containing layer forming step of forming a carbon containing layer containing carbon on a nitride semiconductor layer, and a titanium containing layer forming step of forming a titanium containing layer containing titanium on the carbon containing layer. A complete solid solution Ti (C, N) layer of TiN and TiC is formed between the titanium containing layer and the nitride semiconductor layer. As a result, the titanium containing layer comes to be in ohmic contact with the nitride semiconductor layer throughout the border therebetween.Type: GrantFiled: September 2, 2010Date of Patent: January 21, 2014Assignee: Toyota Jidosha Kabushiki KaishaInventors: Masahiro Sugimoto, Akinori Seki, Akira Kawahashi, Yasuo Takahashi, Masakatsu Maeda
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Publication number: 20130313687Abstract: [Aim of Invention] Providing the effective semiconductor miniaturization and its higher-dense fine wiring with the through-hole and the buried via electrode structure of the lower resistivity and higher reliability material at the low cost manufacturing method. [Solution] Preparing the sedimentation layer 57 buried at first the dried-sintered-porous metal material of paste 56 in the through-hole 51 having a insulation layer 54 on the board structure 50, fully covered over the porous area top of the sedimentation layer 57 with the second metal paste and then full-filling the second metal into the porous area of the sedimentation layer 57.Type: ApplicationFiled: January 14, 2013Publication date: November 28, 2013Applicant: ZyCube Co., Ltd.Inventors: Manabu Bonkohara, Hirofumi Nakamura, Qiwei He
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Patent number: 8592308Abstract: A method of forming a semiconductor device includes forming a silicide contact region of a field effect transistor (FET); forming a shallow impurity region in a top surface of the silicide contact region; and forming a stressed liner over the FET such that the shallow impurity region is located at an interface between the silicide contact region and the stressed liner, wherein the shallow impurity region comprises one or more impurities, and is configured to hinder diffusion of silicon within the silicide contact region and prevent morphological degradation of the silicide contact region.Type: GrantFiled: July 20, 2011Date of Patent: November 26, 2013Assignee: International Business Machines CorporationInventors: Javier Ayala, Christian Lavoie, Ahmet S. Ozcan
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Patent number: 8501600Abstract: Methods for depositing germanium-containing layers on silicon-containing layers are provided herein. In some embodiments, a method may include depositing a first layer atop an upper surface of the silicon-containing layer, wherein the first layer comprises predominantly germanium (Ge) and further comprises a lattice adjustment element having a concentration selected to enhance electrical activity of dopant elements, wherein the dopant elements are disposed in at least one of the first layer or in an optional second layer deposited atop of the first layer, wherein the optional second layer, if present, comprises predominantly germanium (Ge). In some embodiments, the second layer is deposited atop the first layer. In some embodiments, the second layer comprises germanium (Ge) and dopant elements.Type: GrantFiled: July 25, 2011Date of Patent: August 6, 2013Assignee: Applied Materials, Inc.Inventors: Errol Sanchez, Yi-Chiau Huang, David K. Carlson
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Patent number: 8501621Abstract: Three-dimensionally spatially localized artificial filament in the active layer of the memristive device formed by means of ion implantation through the top electrode structure provide the means to achieve high repeatability and high reliability of the memristive devices, leading to significantly improved manufacturing yield. The memristive devices fabricated according to the disclosed method of fabrication can be used in data storage, signal processing and sensing applications.Type: GrantFiled: January 26, 2012Date of Patent: August 6, 2013Assignee: MicroXact, Inc.Inventor: Vladimir Kochergin
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Patent number: 8486759Abstract: A semiconductor chip module having high degree of freedom in assignment of a circuit to each semiconductor chip and in position of a connection terminal of each semiconductor chip is provided. The present invention relates to a semiconductor chip module in which a plurality of semiconductor chips, each provided on the side face thereof with a part of a connection terminal coupled with a circuit pattern formed on the front face, have been stacked and bonded. Connection terminal portions on the side faces of the respective semiconductor chips are interconnected by a wiring pattern. The connection terminal on the semiconductor chip is led from the front face to the side face and formed by applying spraying of a conductive material in a mist state.Type: GrantFiled: September 23, 2011Date of Patent: July 16, 2013Assignee: Kabushiki Kaisha Nihon MicronicsInventor: Masato Ikeda
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Publication number: 20130143402Abstract: The disclosure provides a method for forming a dense Cu thin film by atomic layer deposition, comprising the following steps of: (A) providing an additive gas; (B) choosing a copper-containing metal-organic complex as a precursor; (C) using a carrier gas to introduce the additive gas into the precursor cell mixing with the precursor; (D) pre-depositing the precursor on the surface of the substrate with a TaNx thin film at a first temperature; (E) removing the excess copper-containing metal-organic complex and the excess additive gas; (F) introducing a reducing gas into the reactive system and annealing at a second temperature to reduce the Cu2O thin film to form a Cu thin film on the substrate and (G) removing the excess reducing gas from the reactive system.Type: ApplicationFiled: February 15, 2013Publication date: June 6, 2013Applicant: NANMAT TECHNOLOGY CO., LTD.Inventor: Nanmat Technology Co., Ltd.
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Patent number: 8450208Abstract: In a semiconductor device manufacturing method according to an exemplary embodiment, a sulfur-containing film containing sulfur is deposited on an n-type semiconductor, a first metal film containing a first metal is deposited on the sulfur-containing film, a heat treatment is performed to form a metal semiconductor compound film by reacting the n-type semiconductor and the sulfur-containing film, and to introduce sulfur to an interface between the n-type semiconductor and the metal semiconductor compound film being formed.Type: GrantFiled: April 7, 2011Date of Patent: May 28, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Yoshifumi Nishi, Atsuhiro Kinoshita, Hirotaka Nishino, Masamichi Suzuki
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Patent number: 8450209Abstract: A method of forming a non-volatile memory device includes providing a substrate having a surface and forming a first dielectric overlying the surface, forming a first wiring comprising aluminum material over the first dielectric, forming a silicon material over the aluminum material to form an intermix region consuming a portion of the silicon material and aluminum material, annealing to formation a first alloy from the intermix region, forming a p+ impurity polycrystalline silicon over the first alloy material, forming a first wiring structure from at least a portion of the first wiring, forming a resistive switching element comprising an amorphous silicon material formed over the p+ polycrystalline silicon, and forming a second wiring structure comprising at least a metal material over the resistive switching element.Type: GrantFiled: December 8, 2011Date of Patent: May 28, 2013Assignee: Crossbar, Inc.Inventor: Scott Brad Herner
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Publication number: 20130065391Abstract: A method of manufacturing a semiconductor device, includes: alternately performing (i) a first step of alternately supplying a first raw material containing a first metal element and a halogen element and a second raw material containing a second metal element and carbon to a substrate by a first predetermined number of times, and (ii) a second step of supplying a nitridation raw material to the substrate, by a second predetermined number of times, wherein alternating the first and second steps forms a metal carbonitride film containing the first metal element having a predetermined thickness on the substrate.Type: ApplicationFiled: September 14, 2012Publication date: March 14, 2013Applicant: HITACHI KOKUSAI ELECTRIC INC.Inventors: Arito Ogawa, Tsuyoshi Takeda
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Publication number: 20130062768Abstract: A method for producing a substrate with a copper or a copper-containing coating is disclosed. The method comprises a first step wherein a first precursor, a second precursor and a substrate are provided. The first precursor is a copper complex that contains no fluorine and the second precursor is selected from a ruthenium complex, a nickel complex, a palladium complex or mixtures thereof. In the second step, a layer is deposited at least on partial regions of a surface of the substrate by using the first precursor and the second precursor by means of atomic layer deposition (ALD). The molar ratio of the first precursor:second precursor used for the ALD extends from 90:10 to 99.99:0.01. The obtained layer contains copper and at least one of ruthenium, nickel and palladium. Finally, a reduction is performed step in which a reducing agent acts on the substrate obtained after depositing the copper-containing layer.Type: ApplicationFiled: September 14, 2011Publication date: March 14, 2013Applicants: TECHNISCHE UNIVERSITAET CHEMNITZ, FRAUNHOFER-GESELLSCHAFT ZUR FOERDERUNG DER ANGEWANDTEN FORSCHUNG E.V.Inventors: Thomas WAECHTLER, Stefan SCHULZ, Thomas GESSNER, Steve MUELLER, André TUCHSCHERER, Heinrich LANG
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Patent number: 8373069Abstract: An electronic component mounting substrate including a support layer made of resin with first and second surfaces, an organic insulation layer on the first surface of the support layer with a first surface on opposite side of the first surface of the support layer and a second surface in contact with the first surface of the support layer, an inorganic insulation layer on the first surface of the organic layer, a conductor on the second surface of the support layer, and a first conductive circuit on the second surface of the organic layer. The inorganic layer has a second conductive circuit and a pad for mounting an electronic component inside the inorganic layer. The organic layer has a via conductor inside the organic layer and connecting the first and second circuits. The support layer has a conductive post inside the support layer and connecting the first circuit and the conductor.Type: GrantFiled: December 24, 2009Date of Patent: February 12, 2013Assignee: Ibiden Co., Ltd.Inventors: Takashi Kariya, Daiki Komatsu
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Publication number: 20130020616Abstract: A method of forming a semiconductor device includes forming a silicide contact region of a field effect transistor (FET); forming a shallow impurity region in a top surface of the silicide contact region; and forming a stressed liner over the FET such that the shallow impurity region is located at an interface between the silicide contact region and the stressed liner, wherein the shallow impurity region comprises one or more impurities, and is configured to hinder diffusion of silicon within the silicide contact region and prevent morphological degradation of the silicide contact region.Type: ApplicationFiled: July 20, 2011Publication date: January 24, 2013Applicant: International Business Machines CorporationInventors: Javier Ayala, Christian Lavoie, Ahmet S. Ozcan
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Patent number: 8357607Abstract: A nitride-based semiconductor light-emitting device 100 includes a GaN substrate 10, of which the principal surface is an m-plane 12, a semiconductor multilayer structure 20 that has been formed on the m-plane 12 of the GaN-based substrate 10, and an electrode 30 arranged on the semiconductor multilayer structure 20. The electrode 30 includes an Mg alloy layer 32 which is formed of Mg and a metal selected from a group consisting of Pt, Mo, and Pd. The Mg alloy layer 32 is in contact with a surface of a p-type semiconductor region of the semiconductor multilayer structure 20.Type: GrantFiled: March 9, 2010Date of Patent: January 22, 2013Assignee: Panasonic CorporationInventors: Mitsuaki Oya, Toshiya Yokogawa, Atsushi Yamada, Ryou Kato
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Publication number: 20130005142Abstract: Provided is a method and apparatus for forming a silicon film, which are capable of suppressing generation of a void or seam. The method includes performing a first film-forming process, performing an etching process, performing a doping process, and performing a second film-forming process. In the first film-forming process, a non-doped silicon film that is not doped with an impurity is formed so as to embed a groove of an object. In the etching process, the non-doped silicon film formed via the first film-forming process is etched. In the doping process, the non-doped silicon film etched via the etching process is doped with an impurity. In the second film-forming process, an impurity-doped silicon film is formed so as to embed the silicon film doped via the doping process.Type: ApplicationFiled: June 29, 2012Publication date: January 3, 2013Applicant: TOKYO ELECTRON LIMITEDInventors: Akinobu Kakimoto, Satoshi Takagi, Kazuhide Hasebe
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Patent number: 8338291Abstract: A method of producing a transistor includes providing a substrate including in order a first electrically conductive material layer and a second electrically conductive material layer. A resist material layer is deposited over the second electrically conductive material layer. The resist material layer is patterned to expose a portion of the second electrically conductive material layer. Some of the second electrically conductive material layer is removed to create a reentrant profile in the second electrically conductive material layer and to expose a portion of the first electrically conductive material layer. The second electrically conductive material layer is caused to overhang the first electrically conductive material layer by removing some of the first electrically conductive material layer.Type: GrantFiled: January 7, 2011Date of Patent: December 25, 2012Assignee: Eastman Kodak CompanyInventors: Lee W. Tutt, Shelby F. Nelson
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Patent number: 8334199Abstract: A nitride-based semiconductor light-emitting device 100 includes: a GaN substrate 10 with an m-plane surface 12; a semiconductor multilayer structure 20 provided on the m-plane surface 12 of the GaN substrate 10; and an electrode 30 provided on the semiconductor multilayer structure 20. The electrode 30 includes a Zn layer 32 and an Ag layer 34 provided on the Zn layer 32. The Zn layer 32 is in contact with a surface of a p-type semiconductor region of the semiconductor multilayer structure 20.Type: GrantFiled: March 17, 2010Date of Patent: December 18, 2012Assignee: Panasonic CorporationInventors: Mitsuaki Oya, Toshiya Yokogawa, Atsushi Yamada, Akihiro Isozaki
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Patent number: 8324099Abstract: A method of fabricating a landing plug in a semiconductor memory device, which in one embodiment includes forming a landing plug contact hole on a semiconductor substrate having an impurity region to expose the impurity region; forming a landing plug by filling the landing plug contact hole with a polysilicon layer, wherein the landing plug comprises a first region, a second region, a third region, and a fourth region, wherein the first region is disposed beneath the second region and doped with a first doping concentration, the second region is disposed above the first region and below the third region and is not doped, the third region is disposed above the second region and below the fourth region and is doped with a second doping concentration that is lower than the first doping concentration, and the fourth region is disposed above the third region and is doped with a third doping concentration that is higher than the first doping concentration; and annealing the resulting product formed with the landingType: GrantFiled: January 3, 2012Date of Patent: December 4, 2012Assignee: Hynix Semiconductor Inc.Inventor: Kyoung Bong Rouh
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Patent number: 8318594Abstract: A nitride-based semiconductor light-emitting device 100 includes: a GaN substrate 10 with an m-plane surface 12; a semiconductor multilayer structure 20 provided on the m-plane surface 12 of the GaN substrate 10; and an electrode 30 provided on the semiconductor multilayer structure 20. The electrode 30 includes an Mg layer 32 and an Ag layer 34 provided on the Mg layer 32. The Mg layer 32 is in contact with a surface of a p-type semiconductor region of the semiconductor multilayer structure 20.Type: GrantFiled: March 17, 2010Date of Patent: November 27, 2012Assignee: Panasonic CorporationInventors: Mitsuaki Oya, Toshiya Yokogawa, Atsushi Yamada, Akihiro Isozaki