Abstract: A method for mineralizing siloxane derivatives from a liquid organic phase by adding a base in the form of an alkaline hydroxide.

Abstract: A process for separating furfural from a liquid aqueous phase comprising furfural and one or more organic acids, which process comprises a step a) extracting furfural from the liquid aqueous phase into a liquid aromatic phase comprising one or more aromatic hydrocarbon compounds to obtain a liquid organic phase comprising furfural and one or more aromatic hydrocarbon compounds.

Abstract: The present invention is directed generally to a method of production of biobased chemicals, biofuels, and lignin residues from lignin sources, including waste lignin. This method may allow for selectively producing biobased chemicals, biofuels, and lignin residues from lignin sources using certain processing methods. The methods for production of these biobased chemicals, biofuels, and lignin residues may be provided by chemical-induced processing, catalytic oxidative lignin depolymerisation processing, and catalytic hydroprocessing. Further, the catalytic hydroprocessing from processes including catalytic reduction processing, catalytic hydrodeoxygenation processing, and/or catalytic/dehydrogenation processing may also be used. The method described herein also provides a means in which waste from the process(es) may be reduced and/or recycled.

Abstract: A two-stage reactor/process is disclosed for the conversion of solid particulate biomass material and includes: a first stage, in which solid particulate biomass material is pyrolyzed to primary reaction products, and a second stage in which the primary reaction products are catalytically converted in a second stage which is operated at a temperature higher than that of the first stage.

Abstract: A process for the production of fuels and chemicals from biomass feedstock is provided. The process includes (a) drying the biomass feedstock using heated dry carbon monoxide gas; (b) devolatilizing the feedstock by reductive torrefaction with heated dry carbon monoxide gas; (c) pulverizing the feedstock; and (d) pyrolyzing the feedstock by reductive pyrolysis with high pressure or high temperature carbon monoxide gas. An integrated system for producing fuels and chemicals from biomass feedstock is also provided.

Abstract: The present invention is directed generally to a method of production of value-added, biobased chemicals from lignin sources, including waste lignin. A method of using a depolymerization of lignin to create a tiered production of biobased aromatic chemicals and biofuels is also described herein. The method described herein may also allow for the selective production of the biobased aromatic chemicals and biofuels. Additionally, a reduction of waste products may also be provided from the present method.

Abstract: The present invention relates to production of fuels or fuel blendstocks from renewable sources. Various embodiments provide a method of producing a hydrocarbon product by hydrotreating a feedstock including at least one of a renewable triacylglyceride (TAG), renewable free fatty acid (FFA), and renewable fatty acid C1-C5 alkyl ester (C1-C5 FAE) in the presence of a nonsulfided hydrotreating catalyst to produce a first product including hydrocarbons. In some examples, the first product can be subjected to further chemical transformations such as aromatization, cracking, or isomerization to produce a second product including hydrocarbons. In various embodiments, the first or second hydrocarbon product with minimal or substantially no further processing can be suitable as a liquid transportation fuel or fuel blendstock, including fuels such as gasoline, naptha, kerosene, jet fuel, and diesel fuels.

Abstract: The invention relates to a method for producing a pyrolysis liquid, wherein the pyrolysis liquid is formed by means of pyrolysis from a raw material by forming, in a pyrolysis reactor, a gaseous pyrolysis product by pyrolysis and condensing it in a condenser into a pyrolysis liquid, and feeding circulation gas into the pyrolysis reactor. According to the invention, the circulation gas is conducted by means of a liquid ring compressor into the pyrolysis reactor and purified before being conducted into the pyrolysis reactor, and the pyrolysis liquid is used as the liquid layer in the liquid ring compressor. Further, the invention relates to a corresponding apparatus.

Abstract: The present invention relates to a process for the hydrotreatment of a vegetal biomass. Specifically, the present invention relates to a process for the hydrotreatment of a vegetal biomass comprising: a) subjecting said vegetal biomass to a hydrotreatment in a first reactor, said hydrotreatment comprises contacting said vegetal biomass in an aqueous medium and a metal oxide, a mixed metal oxide, or a metal-metalloid oxide catalyst comprising at least 35% by weight of metal oxide, mixed metal oxide, or metal-metalloid oxide relative to the total weight of the catalyst, with hydrogen at a pressure in the range of 10 to 400 bar and at a temperature in the range of 50° C. to 300° C. until a predetermined level of the hydrotreatment of said biomass is obtained and wherein the metal oxide, a mixed metal oxide, or a metal-metalloid oxide catalyst comprises nickel. Further, the present invention relates to a metal oxide, mixed metal oxide or metal-metalloid oxide catalyst.

Abstract: Low water-containing biomass-derived pyrolysis oils and processes for producing them are provided. The process includes condensing pyrolysis gases including condensable pyrolysis gases and non-condensable gases to separate the condensable pyrolysis gases from the non-condensable gases, the non-condensable gases having a water content, drying the non-condensable pyrolysis gases to reduce the water content of the-non-condensable gases to form reduced-water non-condensable pyrolysis gases, and providing the reduced-water non-condensable pyrolysis gases to a pyrolysis reactor for forming the biomass-derived pyrolysis oil.

Abstract: In one aspect, a method for rendering biomass-derived pyrolysis oil miscible with refinery hydrocarbons comprises mixing a high oxygen content bio-oil having an oxygen content of at least about 10 wt. % with a low oxygen content bio-oil having an oxygen content of less than about 8 wt. % to produce a blended oil. The blended oil may be hydrotreated to produce a deoxygenated hydrotreated mixture from which water is removed using a separator, resulting in a low oxygen content hybrid bio-oil intermediate miscible in refinery process streams. A portion of the low oxygen content hybrid bio-oil intermediate may be recycled with the high oxygen content bio-oil or removed for use in a refinery process stream for further hydroprocessing.

Abstract: The invention relates to nucleic acids encoding a feruloyl-CoA:monolignol transferase and the feruloyl-CoA:monolignol transferase enzyme that enables incorporation of monolignol ferulates, for example, including p-coumaryl ferulate, coniferyl ferulate, and sinapyl ferulate, into the lignin of plants.

Abstract: The object of the present invention is to neutralize acidity of bio-oil so as to allow practical use of bio-oil as fuel. Neat liquid of acidic bio-oil is flow in the treatment bath 1. Magnesium powder is added to the liquid from the input chute 3 and the mixture is stirred in the stirrer 7 until the magnesium powder is completely dissolved. The treated oil is taken from the outlet tube 4. The hydrogen gas generated is collected by the suction duct 5, and the reaction heat generated is collected by the heat exchanger 6.

Abstract: The present invention describes a process for the production of biofuel, said process comprising, pretreating a feedstock, mixing a catalyst with said feedstock, transferring the mixture of catalyst and feedstock into a reactor,and subjecting said mixture to a heating sequence by applying microwave energy thereto, wherein the catalyst comprises an aluminosillicate mineral, the percentage of aluminosillicate mineral in the catalyst-feedstock mixture is less than 10% (w/w), and the temperature of the mixture of catalyst and feedstock is no higher than 450° C. during the process.

Abstract: The invention relates to a method for producing fuel from organic waste or biomass in a gasification process comprising the burning of organic waste or biomass and the recovery of the gasification residue. The method comprises at least the following steps: organic aqueous waste or biomass (M; M1) is fed in a combustion chamber (1); oxygen-bearing pressurized regeneration gas (G) is also fed in said combustion chamber (1); a continuous, pressurized combustion process is maintained in the combustion chamber, without adding an external oxygen source or heat in the process, so that the combustion of organic waste or biomass is carried out with the oxygen content of 0.

Abstract: The invention relates generally to the field of biofuel synthesis. More specifically, the invention relates to processes for the synthesis of biofuels from organic materials including lignocellulosic biomass and coal. Also provided are biofuel products obtained from processes of the invention.

Abstract: A wheat cultivar, designated BZ6W07-458, is disclosed. The invention relates to the seeds, plants, and hybrids of wheat cultivar BZ6W07-458, and to methods for producing a wheat plant produced by crossing plants from wheat cultivar BZ6W07-458 with themselves or with plants from another wheat variety. The invention also relates to methods for producing a wheat plant containing in its genetic material one or more transgenes and to the transgenic wheat plants and plant parts produced by those methods. The invention also relates to wheat varieties or breeding varieties and plant parts derived from wheat cultivar BZ6W07-458, to methods for producing other wheat varieties, lines or plant parts derived from wheat cultivar BZ6W07-458, and to the wheat plants, varieties, and their parts derived from the use of those methods. The invention further relates to hybrid wheat seeds and plants produced by crossing wheat cultivar BZ6W07-458 with another wheat cultivar.

Abstract: A multi-stage process and system for converting solid particulate biomass in a riser reactor having at least two different reaction zones. A lower reaction zone is configured to optimize pyrolysis of the biomass into pyrolysis products, while an upper reaction zone is configured to efficiently crack the pyrolysis products. The relative residence times and/or temperatures of the upper and lower reaction zones can be controlled to optimize product quality and yield.

Abstract: A wheat cultivar, designated BZ6W07-427, is disclosed. The invention relates to the seeds, plants, and hybrids of wheat cultivar BZ6W07-427, and to methods for producing a wheat plant produced by crossing plants from wheat cultivar BZ6W07-427 with themselves or with plants from another wheat variety. The invention also relates to methods for producing a wheat plant containing in its genetic material one or more transgenes and to the transgenic wheat plants and plant parts produced by those methods. The invention also relates to wheat varieties or breeding varieties and plant parts derived from wheat cultivar BZ6W07-427, to methods for producing other wheat varieties, lines or plant parts derived from wheat cultivar BZ6W07-427, and to the wheat plants, varieties, and their parts derived from the use of those methods. The invention further relates to hybrid wheat seeds and plants produced by crossing wheat cultivar BZ6W07-427 with another wheat cultivar.

Abstract: The system and method described herein provide for the higher production rate fractionation of biomass for the purpose of selectively separating specific volatile components, which may subsequently be used in the production of a renewable liquid fuel, such as gasoline. Increased production rates of processing of biomass or other feedstock is achieved through the use of sealed reaction chambers, which may be transferred in a sealed configuration between stations in a multi-station processing system. Also, the present invention considers the use of piston assemblies for the dual functions of controlling fluid intake and exhaust (in combination with valves) and for providing a more robust and more cost effective sealing mechanism. The present invention may also achieve improved uniformity of biomass processing through the introduction of a mechanical agitator designed to mix the biomass during processing.

Abstract: A process and system for separating a light fraction, a bio-distillate fraction, and a heavy fraction from a bio-oil, and for producing a renewable distillate including at least in part the bio-distillate fraction and a stabilizing additive, is provided. The process comprises separating bio-oil into light, bio-distillate, and heavy fractions based on their boiling points. At least a portion of the bio-distillate fraction and a stabilizing additive are blended with a petroleum-derived-diesel-range stream, without any prior hydrotreatment, to thereby provide a renewable distillate composition.

Abstract: Methods for the production of an intergeneric hybrid plants and plants produced thereby. In certain aspects, intergeneric hybrid plants are produced by crossing a sorghum parent plant comprising a mutant sorghum iap allele with a second moncot plant. Methods for the use of such plants and products obtained therefrom are also provided.

Abstract: This invention refers to a procedure for obtaining a biocrude from greenhouse gases, a procedure which is advantageous industrially and continuous. By means of said procedure it is possible to capture, convert and revalue CO2, among other greenhouse gases, in an efficient manner, in such a way that a net negative balance is obtained, which in other words means that with this procedure it is possible to capture more CO2 than is generated which makes it beneficial and sustainable in the environment.

Abstract: A lignocellulosic biomass material is converted into precursors for liquid hydrocarbon transportation fuels by contacting the biomass material with water and carbon monoxide at elevated temperature, typically from 280 to 350° C., an elevated pressure, typically a total system pressure of 12 to 30 MPa and a CO partial pressure from 5 to 10 MPa and a weight ratio of water:biomass material from 0.5:1 to 5.0:1, to dissolve the biomass material into the reaction mixture and depolymerize, deoxygenate and hydrogenate the lignocellulose biomass material, so converting the biomass material into liquid transportation fuel precursors.

Abstract: A pyrolysis oil derived from a lignocellulosic biomass material is converted into precursors for liquid hydrocarbon transportation fuels by contacting the oil with water and carbon monoxide at elevated temperature, typically from 280 to 350° C., an elevated pressure, typically a total system pressure of 12 to 30 MPa and a CO partial pressure from 5 to 10 MPa and a weight ratio of water:biomass oil from 0.5:1 to 5.0:1, to dissolve the oil into the reaction mixture and depolymerize, deoxygenate and hydrogenate the oil, so converting it into liquid transportation fuel precursors.

Abstract: The present invention relates to a process for preparing a bio-diesel, comprising the steps of, in the presence of an additional free fatty acid source, reacting a raw oil-fat with C1-C6 monohydric alcohol in a reactor, and separating fatty acid esters from the reacted materials, so as to produce the bio-diesel, wherein the amount of the free fatty acid in the free fatty acid source ranges from 2-100 wt % and is higher than the amount of the free fatty acid in the raw fat-oil. The present process can increase the fatty acid ester yield and purity of raw oil-fats having a low reaction activity, and has a high adaptability to raw materials.

Abstract: The present invention relates to methods of fueling an internal combustion engine, and composition, that provide improved nitrogen-free detergency in the engine, particularly in the area of injector deposit control. The present invention also provides methods of providing both improved detergency and improved corrosion inhibition, while avoiding compatibility problems with fuels and/or while limiting the amount of nitrogen delivered to the fuel from the deposit control additive.

Abstract: The present invention applies to the field of plant improvements, in particular to the modification of the blooming date thereof, by manipulation of the Prec31 gene.

Abstract: The invention relates generally to methods for the production of biofuels from organic matter, the methods comprising treating the organic matter with an aqueous solvent and at least one additional catalyst under conditions of heat and pressure. The invention also relates to biofuel products obtainable by the methods.

Abstract: In some embodiments, the present disclosure provides a method for producing biofuel from a feedstock that includes one or more coffee sources, such as green coffee beans, whole roasted coffee beans, ground coffee, or spent coffee grounds. Triglycerides and other materials, such as antioxidants, are extracted from the coffee source. In some example, the triglycerides are then transesterified to produce a fatty acid ester biofuel product. In further examples, the method includes obtaining spent coffee grounds from one or more sources, such as residences or businesses that generate spent coffee grounds. The present disclosure also provides biofuels produced using the disclosed method, including mixtures of such biofuels with other fuels, such as other biofuels or petroleum based fuels. Materials obtained from the disclosed method may be put to other uses, such as cosmetics, medicinal products, food products, or combustible materials.

Abstract: A flow improver for biodiesel fuels, comprising an ?-olefin polymer with a weight average molecular weight of 50,000 to 500,000 that is obtained by polymerization of an ?-olefin mixture (C), wherein the mole ratio (A)/(B) of an ?-olefin (A) with 10 carbon atoms and an ?-olefin (B) with 14 to 18 carbon atoms is (A)/(B)=10/90 to 60/40.

Abstract: The present disclosure refers to a fuel free of emulsifiers, wherein the fuel may be an emulsion of (a) at least one of a mineral oil, synthetic oil, or natural oil in (b) a pyrolysis oil with a percent weight ratio, (a):(b), of 1 to 15:99 to 85. The Sauter Mean Diameter of droplets of (a) in the emulsion may be 1 micrometer to 15 micrometers. An internal combustion engine system may comprise a reservoir for pyrolysis oil and a reservoir for at least one of a mineral oil, synthetic oil, or natural oil, and a homogenizer configured to provide an emulsion from said oils. The homogenizer may include an inlet connected with said reservoirs and an outlet. The system may also comprise an internal combustion engine which may include at least one combustion chamber, wherein the outlet of the homogenizer may be connected to the internal combustion engine.

Abstract: Biomass based feeds are processed under hydrothermal treatment conditions, e.g., to produce a hydrocarbon liquid product and a solids portion. The hydrothermal treatment can be performed in the presence of heterogeneous catalyst particles that can optionally include a catalyst metal or metal salt. The presence of the heterogeneous catalyst can modify the nature of the hydrocarbon products produced from the hydrothermal treatment.

Abstract: Lighter fluid having a smoky aroma can be prepared by combining liquid smoke with aliphatic petroleum solvent. The smoke-scented lighter fluid imparts a pleasant scent while it is applied to charcoal briquets and ignited.

Abstract: Fungible bio-oil compositions with enhanced processability are provided. A process to produce the fungible bio-oil composition is also provided that involves combining a biomass-derived liquid, at least one petroleum-derived composition, and, optionally, one or more additives in order to produce the fungible bio-oil composition.

Abstract: Disclosed is a method for producing a renewable fuel using a supercritical fluid. The method includes charging a supported catalyst into a continuous reactor and adding a catalyst activating material thereto to activate the supported catalyst, feeding an oil or fat, hydrogen and a supercritical fluid into the continuous reactor and allowing hydrogenation and hydrodeoxygenation reactions of the oil or fat in the supercritical fluid to proceed, and collecting a renewable fuel as the reaction product. The method enables the production of an oxygen-free renewable fuel in a higher yield at a lower hydrogen pressure and a lower reaction temperature than conventional methods for producing renewable fuels.

Abstract: Processes for producing biodiesel compositions are disclosed. FFAs present in the triglycerides can be removed by reaction with isobutylene, or by Kolbe electrolysis. The Kolbe electrolysis can be performed on the starting material, or on the crude glycerol. The triglycerides are transesterified to form alkyl esters of the fatty acids and glycerol. The transesterification reaction can be catalyzed by an alkoxide, rather than a hydroxide, to help keep the glycerol by-product dry. The alkoxide salt can be neutralized by reaction with a dry acid, such as gaseous hydrogen chloride or sulfuric acid, and the resulting alcohol removed by distillation, and at least a portion of the neutralized salt can be removed by filtration or decantation. The process can provide improved biodiesel yields, and glycerol pure enough for use directly in glycerol ether manufacture.

Abstract: Biomass pyrolysis oil is converted into precursors for hydrocarbon transportation fuels by contacting the oil with liquid superheated water or supercritical water to depolymerize and deoxygenate the components of the oil and form the transportation fuel precursors. Temperatures above 200° C. and preferably above 300° C. are preferred with supercritical water at temperatures above 374° C. and pressures above 22 MPA providing the capability for fast conversion rates.

Abstract: A process for converting a solid biomass material comprising (a) mixing the solid biomass material with a fluid to form a fluidized biomass stream; and (b) propagating the fluidized biomass stream into the riser reactor via one or more delivery aperture(s); wherein the solid biomass material has a particle size distribution with a mean particle size diameter, and wherein the delivery aperture has a diameter equal to or more than three times the mean particle size diameter of the particle size distribution of the solid biomass material.

Abstract: This invention relates to a new system for controlling temperature and pressure in, at least, one chemical reactor, characterized in that it includes, at least, the following devices: a) a deposit with at least one pressure regulation device; b) a connecting duct between said deposit and the reactor; c) a device for injecting condensates into the reactor. Moreover, the invention relates to the use of said control system to control the pressure and temperature of at least one chemical reactor, being especially applicable to a chemical reactor in which a hydrothermal biomass carbonization reaction takes place.

Abstract: In processing of biomass by catalytic cracking in a fluidized catalytic cracker having a reaction zone, a separation zone, a stripping zone, and a regeneration zone, the feedstock oil containing the biomass is processed in the reaction zone using a catalyst containing 10 to 50 mass % of ultrastable Y-type zeolite under the conditions: outlet temperature of the reaction zone 580 to 680° C., catalyst/oil ratio 10 to 40 wt/wt, reaction pressure 1 to 3 kg/cm2 G, and contact time of the feedstock oil with the catalyst in the reaction zone 0.1 to 1.0 sec, and the catalyst is then treated in the regeneration zone under the conditions: regeneration zone temperature 640 to 720° C., regeneration zone pressure 1 to 3 kg/cm2 G, and exhaust gas oxygen concentration at the regeneration zone outlet 0 to 3 mol %.

Abstract: Disclosed herein are oils, including fatty acid triglyceride and fatty acid ester compositions suitable for the production of biofuel, biofuels, and methods for producing such materials and compositions. These materials and compositions comprise substantially no sterol glycosides.

Abstract: The present invention relates to processes for producing industrial products such as hydrocarbon products from non-polar lipids in a vegetative plant part. Preferred industrial products include alkyl esters which may be blended with petroleum based fuels.

Abstract: Digestion of cellulosic biomass to produce a hydrolysate may be accompanied by the formation of cellulosic fines which may be damaging to system components. Biomass conversion systems that may address the issue of cellulosic fines may comprise a fluid circulation loop comprising: a hydrothermal digestion unit; a solids separation unit that is in fluid communication with an outlet of the hydrothermal digestion unit; where the solids separation unit comprises a plurality of filters and the filters are in fluid communication with the fluid circulation loop in both a forward and a reverse flow direction; and a catalytic reduction reactor unit that is in fluid communication with an outlet of the solids separation unit and an inlet of the hydrothermal digestion unit; where at least one of the plurality of filters is in fluid communication with an inlet of the catalytic reduction reactor unit.

Abstract: Methods for deoxygenating a biomass-derived pyrolysis oil are provided. In an embodiment, a method for deoxygenating a biomass-derived pyrolysis oil comprises the steps of combining a biomass-derived pyrolysis oil stream with a heated low-oxygen-pyoil diluent recycle stream to form a heated diluted pyoil feed stream. The heated diluted pyoil feed stream has a feed temperature of about 150° C. or greater. The heated diluted pyoil feed stream is contacted with a first deoxygenating catalyst in the presence of hydrogen at first hydroprocessing conditions effective to form a low-oxygen biomass-derived pyrolysis oil effluent.

Abstract: When processing cellulosic biomass, it may be desirable for a digestion unit to operate without being fully depressurized for process efficiency purposes. Methods for processing cellulosic biomass may comprise providing a biomass conversion system comprising a pressurization zone and a digestion unit that are operatively connected to one another; providing cellulosic biomass at a first pressure; introducing at least a portion of the cellulosic biomass into the pressurization zone and pressurizing the pressurization zone to a second pressure higher than the first pressure; after pressurizing the pressurization zone, transferring at least a portion of the cellulosic biomass from the pressurization zone to the digestion unit, which is at a third pressure that is less than or equal to the second pressure but higher than the first pressure; and digesting at least a portion of the cellulosic biomass in the digestion unit to produce a hydrolysate comprising soluble carbohydrates.

Abstract: When processing cellulosic biomass, it may be desirable for a digestion unit to operate without being fully depressurized for process efficiency purposes. A biomass conversion system can comprise a first digestion unit and a second digestion unit that are operatively connected to one another; a valve separating the first digestion unit from the second digestion unit; a fluid circulation loop establishing fluid communication between an outlet of the first digestion unit and an inlet of the second digestion unit; and a bypass line establishing fluid communication between an outlet of the second digestion unit and the fluid circulation loop.

Abstract: Methods and apparatuses for forming a low-metal biomass-derived pyrolysis oil are provided. In an embodiment, a method for forming a low-metal biomass-derived pyrolysis oil includes washing biomass comprising a water-soluble metal component therein with wash water that is substantially free of water-soluble metals. The washed biomass and water containing water-soluble metal are separated after washing the biomass. The washed biomass is pyrolyzed in a pyrolysis process to form a pyrolysis vapor stream. A portion of the pyrolysis vapor stream is condensed to form a condensate. The wash water is derived from the washed biomass. In an embodiment of an apparatus, the apparatus comprises a washing stage, a biomass dryer, a pyrolysis reactor, a quenching system comprising a primary condenser and a secondary condenser, and a return line that connects the quenching system to the washing stage.

Abstract: The present invention is a process and apparatus for forming various bio-products from cellulosic plant material. The plant material is subjected to a pulping step in which lignin is extracted from the material by an aqueous lignin solvent to form a lignin-solvent mixture and purified cellulose. The lignin-solvent mixture can be separated from the water to form a high energy density fuel that can be used independently or combined with biodiesel. The purified cellulose can be used in conventional processes, e.g., paper making, or can be converted to fermentable sugars with a cellulase enzyme to produce other bio-products depending on the operating conditions of the fermenter. The bio-products produced by the fermenter can include the solvent that may be recycled for use in extracting the lignin.

Abstract: A reactive distillation process is disclosed for converting aquatic biomass to a bio-oil. In the process a slurry of aquatic biomass is contacted with a particulate inorganic material. The mixture is heated to or above its boiling point. During the heating step biomass is converted to bio-oil. In a preferred embodiment water vapors emanating from the slurry are collected and condensed. The fresh water obtained may be used for irrigation, in human domestic uses, and for human consumption.