Chemically Specified Frit Compositions Patents (Class 501/21)
  • Patent number: 4554258
    Abstract: Glass frit compositions for use in glazes or enamels have a fiber softening point of 535.degree. C. or more and are free of cadmium, lead and arsenic and consist essentially of Bi.sub.2 O.sub.3 --B.sub.2 O.sub.3 --SiO.sub.2 with R.sub.2 O being 2-8% and RO being 0-9% by weight.
    Type: Grant
    Filed: June 28, 1984
    Date of Patent: November 19, 1985
    Assignee: Owens-Illinois, Inc.
    Inventor: Josef Francel
  • Patent number: 4547467
    Abstract: A composition for a dielectric ink used in a screening process including a lead-free glass frit binder, silica, and a vehicle. The dielectric composition is particularly suited for use in gas plasma display panels.
    Type: Grant
    Filed: June 22, 1983
    Date of Patent: October 15, 1985
    Assignee: Burroughs Corporation
    Inventors: Edward G. Barth, Ruvim Braude, Nicholas W. Kay
  • Patent number: 4539509
    Abstract: A lead-free sealing glass consisting essentially of, in parts by weight, 8-25 BaO, 20-35 B.sub.2 O.sub.3, and 45-72 Sb.sub.2 O.sub.3 except for incidental impurities, residual fluxes and refining agents provides an improved molten sealing action especially useful for high temperature electric lamp envelopes and other electrical devices. More particularly, a protective molten seal utilizing said sealing glass is formed between a refractory metal inlead which extends into a larger sized opening of a fused quartz member by filling the free space between said opening in the fused quartz member and the refractory metal inlead with the aforementioned sealing glass composition and thereafter converting the sealing glass to a molten condition during device operation.
    Type: Grant
    Filed: December 17, 1982
    Date of Patent: September 3, 1985
    Assignee: General Electric Company
    Inventor: Arun K. Varshneya
  • Patent number: 4537862
    Abstract: Glass frit compositions are shown that are lead-free, cadmium-free, and zinc-free, the compositions having improved chemical resistance, especially acid resistance (acetic acid) of a loss of generally less than about 1.9% by weight. The compositions contain B.sub.2 O.sub.3, SiO.sub.2, ZrO.sub.2 and rare earth oxides, the weight ratio of ZrO.sub.2 to rare earth oxides being critical and being about 1/1 to 1.4/1.
    Type: Grant
    Filed: April 27, 1984
    Date of Patent: August 27, 1985
    Assignee: Owens-Illinois, Inc.
    Inventors: Josef Francel, Uriah Horn, Daniel R. Stewart
  • Patent number: 4537703
    Abstract: The invention is directed to a barium borosilicate glass which is free of Bi, Cd and Pb. The glass, which also contains small amounts of NiO, is especially useful as a binder for thick film resistor compositions to be used for making low end resistors.
    Type: Grant
    Filed: December 19, 1983
    Date of Patent: August 27, 1985
    Assignee: E. I. Du Pont De Nemours and Company
    Inventor: Jacob Hormadaly
  • Patent number: 4536329
    Abstract: The invention is directed to a barium borosilicate glass which is free of Bi, Cd and Pb. The glass, which also contains small amounts of CoO, is especially useful as a binder for thick film resistor compositions to be used for making high-end resistors.
    Type: Grant
    Filed: December 19, 1983
    Date of Patent: August 20, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Jacob Hormadaly
  • Patent number: 4507392
    Abstract: This invention is directed to the production of glass-ceramic materials designed for application as glazes to low expansion ceramic bodies. The inventive glass-ceramics exhibit average coefficients of thermal expansion (25.degree.-100.degree. C.) of less than -15.times.10.sup.-7 /.degree.C., demonstrate excellent resistance to attack by acids and bases, contain beta-quartz solid solution as the predominant crystal phase, and consist essentially, in weight percent, of______________________________________ SiO.sub.2 50-67 Al.sub.2 O.sub.3 22-32 Li.sub.2 O 4.5-7 TiO.sub.2 and/or ZrO.sub.2 4.
    Type: Grant
    Filed: December 8, 1983
    Date of Patent: March 26, 1985
    Assignee: Corning Glass Works
    Inventor: Hermann L. Rittler
  • Patent number: 4467009
    Abstract: Improved medium and high value resistor inks are disclosed. The subject inks comprise indium oxide, a barium calcium borosilicate glass frit, a suitable organic vehicle and a temperature coefficient of resistance modifier selected from the group consisting of ferric oxide and vanadium oxide.
    Type: Grant
    Filed: January 21, 1983
    Date of Patent: August 21, 1984
    Assignee: RCA Corporation
    Inventors: Ashok N. Prabhu, Kenneth W. Hang
  • Patent number: 4455383
    Abstract: There is disclosed a single-frit porcelain powder, suitable for use as a porcelain layer on metal-base dental restorations, and having a fired coefficient of thermal expansion within the range of from about 12 to about 14.times.10.sup.-6 in./in. .degree.C., wherein said single frit porcelain is of the following composition:______________________________________ Component Weight Percent ______________________________________ SiO.sub.2 651/2 .+-. 4 Al.sub.2 O.sub.3 15 .+-. 2 K.sub.2 O 121/2 - 1, + 2 Flux 4 .+-. 1 MO 2 .+-. 1 ______________________________________wherein M represents calcium, magnesium, or a mixture thereof, and Flux represents sodium oxide or lithium oxide, or a mixture thereof, and, optionally, may also contain boron oxide.
    Type: Grant
    Filed: April 4, 1983
    Date of Patent: June 19, 1984
    Assignee: Johnson & Johnson Dental Products Company
    Inventor: Carlino Panzera
  • Patent number: 4446241
    Abstract: Glass frits for use in glazes or enamels have fiber softening point about 535.degree.-609.degree. C. are free of lead, cadmium and zinc and consist essentially of Li.sub.2 O-B.sub.2 O.sub.3 -SiO.sub.3 plus 2-23% SnO.sub.2 +CaO and 2-23% ZrO.sub.2 +La.sub.2 O.sub.3 ; also, Al.sub.2 O.sub.3, SrO, BaO, Na.sub.2 O, F.Low expansion filler, e.g., B-eucryptite, may be used at 4 to 15% by weight of glass frit.
    Type: Grant
    Filed: June 28, 1982
    Date of Patent: May 1, 1984
    Assignee: Owens-Illinois, Inc.
    Inventors: Josef Francel, Daniel R. Stewart, Uriah Horn
  • Patent number: 4437192
    Abstract: A biologically active glass and class-ceramic composition useful for making surgical and dental implants comprising, by mol %,:______________________________________ SiO.sub.2 35.about.60 B.sub.2 O.sub.3 5.about.15 Na.sub.2 O 10.about. 30 CaO 5.about. 40 TiO.sub.2 0.5.about. 10 P.sub.2 O.sub.5 0.about. 15 K.sub.2 O 0.about. 20 Li.sub.2 O 0.about. 10 MgO 0.about. 5 Al.sub.2 O.sub.3 + ZrO.sub.2 + Nb.sub.2 O.sub.5 0.about. 8 La.sub.2 O.sub.3 + Ta.sub.2 O.sub.5 + Y.sub.2 O.sub.3 0.about.8 and F.sub.2 0.about.15.
    Type: Grant
    Filed: March 16, 1983
    Date of Patent: March 20, 1984
    Assignee: Nippon Kogaku K.K.
    Inventors: Takamitsu Fujiu, Makoto Ogino, Michio Kariya, Takeo Ichimura
  • Patent number: 4431451
    Abstract: Dentures, dental glazes or coatings, reconstructive jacket-crowns and inlays and restorative constructions over metal or preformed alumina substrates are fabricated from a dental porcelain frit prepared by a gel route.
    Type: Grant
    Filed: January 22, 1982
    Date of Patent: February 14, 1984
    Assignee: American Dental Association Health Foundation
    Inventors: Curtis P. Mabie, Daniel L. Menis
  • Patent number: 4392180
    Abstract: Thick film dielectric compositions suitable for screen-printing comprising a substituted perovskite, an inorganic dopant, and a low temperature-devitrifiable frit or glass. Upon firing the dielectric composition is highly hermetic.
    Type: Grant
    Filed: April 29, 1982
    Date of Patent: July 5, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Kumaran M. Nair
  • Patent number: 4369254
    Abstract: Novel thick-film crossover dielectric inks useful in constructing multilayer circuits on suitable substrates are provided. The subject inks comprise a barium magnesium borosilicate glass powder, a pinhole reducing component comprising silicon dioxide, an alkaline earth aluminum borosilicate glass having a high softening point or mixtures thereof and a suitable organic vehicle.
    Type: Grant
    Filed: July 6, 1981
    Date of Patent: January 18, 1983
    Assignee: RCA Corporation
    Inventors: Ashok N. Prabhu, Kenneth W. Hang
  • Patent number: 4361654
    Abstract: A porcelain enamel frit for sheet iron ground coat is disclosed, which contains neither fluorine nor fluorine compound, but has excellent firing property, and can be worked into sheet iron enamel having high gloss and adherence and low surface roughness. The frit consists of 100 parts of a main component and 7-42 parts of an auxiliary component, said main component consisting of 30-73 parts of SiO.sub.2 or a mixture of SiO.sub.2 and at least one of TiO.sub.2, ZrO.sub.2 and SnO.sub.2, 8-45 parts of B.sub.2 O.sub.3, and 8-41 parts of Na.sub.2 O or a mixture of Na.sub.2 O and at least one of Li.sub.2 O and K.sub.2 O, and said auxiliary component consisting of not more than 12 parts of Al.sub.2 O.sub.3, 1-22 parts of at least one of CaO, Bao, ZnO, MgO and SrO, from more than 0 part to 7 parts of MoO.sub.3 or a mixture of MoO.sub.3 and at least one of V.sub.2 O.sub.5, P.sub.2 O.sub.5 and Sb.sub.2 O.sub.3, and 0.5-10 parts of at least one of CoO, NiO, CuO, MnO.sub.2 and Fe.sub.2 O.sub.3.
    Type: Grant
    Filed: August 5, 1981
    Date of Patent: November 30, 1982
    Assignee: NGK Insulators, Ltd.
    Inventors: Akira Ohmura, Tadashi Nakano
  • Patent number: 4358544
    Abstract: The coatings are glass compositions which consist essentially of from 18 to 45 mol % of the alkaline oxides CaO and one or both of Na.sub.2 O and K.sub.2 O and from 5 to 22 mol % of Al.sub.2 O.sub.3, the balance being B.sub.2 O.sub.3 and SiO.sub.2 in such amounts that the molar ratio of B.sub.2 O.sub.3 : (B.sub.2 O.sub.3 +SiO.sub.2) lies in the range from 0.575:1 to 0.85:1. The molar ratio of K.sub.2 O: (K.sub.2 O+Na.sub.2 O) is from 0.4:1 to 0.6:1 and CaO is 48 to 52 mole % of the alkaline oxides.These compositions are particularly suitable for use during the heat-treatment and hot-working of titanium and its alloys.
    Type: Grant
    Filed: July 1, 1981
    Date of Patent: November 9, 1982
    Assignee: Daniel Doncaster & Sons Limited
    Inventor: Anthony N. Skedgell
  • Patent number: 4355115
    Abstract: Borosilicate glass frit with MgO as a major component for forming partially devitrified porcelain compositions are provided which are comprised of a mixture, based on its oxide content, of barium oxide (BaO), magnesium oxide (McO) or a mixture of magnesium oxide with certain other oxides, boron trioxide (B.sub.2 O.sub.3) and silicon dioxide (SiO.sub.2). In accordance with this invention the porcelain compositions are applied to the metal core and fired to provide a partially devitrified porcelain coating on the metal core. The coating has a very low viscosity at its initial fusion point and then almost instantaneous high viscosity due to partial devitrification. The fired coating has a deformation temperature of at least 700.degree. C. and a high coefficient of thermal expansion of at least about 110.times.10.sup.-7 /.degree.C.
    Type: Grant
    Filed: October 3, 1980
    Date of Patent: October 19, 1982
    Assignee: RCA Corporation
    Inventors: Kenneth W. Hang, Wayne M. Anderson
  • Patent number: 4342553
    Abstract: A range of borosilicate glass compositions which are capable of sealing effectively to nickel iron alloys containing up to approximately 52% nickel to form a hermetic seal resistant to thermal shock breakage. The glass is in the composition range percent by weight of:SiO.sub.2 : 55-66Al.sub.2 O.sub.3 : 4.5-10Na.sub.2 O: 0-4K.sub.2 O: 3.5-7B.sub.2 O.sub.3 : 19.0-26.0TiO.sub.
    Type: Grant
    Filed: September 29, 1981
    Date of Patent: August 3, 1982
    Assignee: General Electric Company
    Inventors: William A. Graff, George L. Thomas
  • Patent number: 4337316
    Abstract: A process for producing feldspathic sanitary ware and the end product are disclosed in which a fluxing amount of a glass frit is used in the ceramic slip used to cast the sanitary ware. The frit contains both deflocculent oxides and flocculent alkaline earths which are leachable from the frit when it is placed in the ceramic slip. The deflocculent oxides counterbalance the effect of the flocculent alkaline earths to the extent they are respectively leached from the frit upon dispersal in a ceramic slip and maintain the slip at a workable viscosity. Upon casting and firing the slip, the present frit precipitates fine crystals of diopside having an average particle size of less than one micron which are particularly useful in lowering the firing temperature of feldspathic bodies by promoting the required degree of vitrification at lower temperatures than heretofore possible.
    Type: Grant
    Filed: September 19, 1980
    Date of Patent: June 29, 1982
    Assignee: Ferro Corporation
    Inventor: Werner F. Votava
  • Patent number: 4332618
    Abstract: A thermal barrier coating adapted to provide a thermally insulating protective barrier on a component, the coating being capable of being applied to the components by spraying methods and being ductile when exposed to high temperatures. The coating comprises a mixture containing constituents of finely divided hollow glass microspheres; a ceramic frit of finely divided particles of alkali silicate titanate glass; and a refractory filler material of finely divided partiles such as micronized mica; aluminum oxide of mullite. All of the constituents of the mixture are suspended in a high temperature resistant binder material such as potassium silicate, sodium silicate or aluminum orthophosphate.
    Type: Grant
    Filed: May 8, 1981
    Date of Patent: June 1, 1982
    Assignee: Rolls-Royce Limited
    Inventor: Norman E. Ballard
  • Patent number: 4323484
    Abstract: A glaze resistor composition composed of a glass frit, molybdenum disilicide, tantalum disilicide, magnesium silicide and aluminum. This glaze resistor composition has a small temperature coefficient of resistivity, a high resistivity stability and small current noises, and can be used in a wide resistivity range.
    Type: Grant
    Filed: November 23, 1979
    Date of Patent: April 6, 1982
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Masumi Hattori, Toru Ishida, Shinichi Tanaka
  • Patent number: 4316963
    Abstract: A leadless glaze composition having properties that make lead oxide containing glazes so widely used as ceramic glazes. The glazes according to this invention are prepared to analyze more than about 0.53 to about 1.5 weight percent molybdenum trioxide with the source of the molybdenum trioxide either in the frit or as a mill addition being alkaline earth molybdenate, for example, calcium molybdenate (CaMoO.sub.4).
    Type: Grant
    Filed: February 6, 1981
    Date of Patent: February 23, 1982
    Assignee: The O. Hommel Company
    Inventors: Richard O. Hommel, David Klimas
  • Patent number: 4313900
    Abstract: A process for forming a glazed ceramic substrate, more particularly for forming a particular surface finish and/or surface pattern in the glass. The process consists of preparing a ceramic mixture which includes a basic oxide, such as Al.sub.2 O.sub.3, and a glass, forming the substrate as by molding, pressing, or doctor blading and lamination, and sintering in a non-reactive atmosphere on a setter tile that is non-wettable by the glass. During the sintering operation the glass becomes molten and flows downwardly under the influence of gravity through the ceramic particles. The glass flows to the setter plate to conform to its surface configuration, forming a glazed surface on the substrate.
    Type: Grant
    Filed: June 26, 1980
    Date of Patent: February 2, 1982
    Assignee: International Business Machines Corp.
    Inventors: Frank Gonzales, Jr., Joseph Sobon
  • Patent number: 4309507
    Abstract: An improved sealing glass composition for making compression glass electrical feedthroughs in semiconductor device packages is described wherein the improved sealing glass consists essentially of (by weight percent) 63-68% SiO.sub.2, 3-6% Al.sub.2 O.sub.3, 8-9% K.sub.2 O, 5-6% Na.sub.2 O, 0.5-1.5% Li.sub.2 O, 2-4% BaO, 5-7% SrO, 2-4% CaO, 0.5-1.5% MgO, 0.5-1.5% TiO.sub.2, and 0.5-1.5% B.sub.2 O.sub.3.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: January 5, 1982
    Assignee: Motorola, Inc.
    Inventors: Earl K. Davis, Robert W. Hey
  • Patent number: 4306913
    Abstract: A microporous filler for dental composite resin restorations has been developed which gives greatly improved finishability, system non-toxicity and x-ray opacification. These fillers are prepared from frits obtained by the low temperature calcination of gelled inorganic "polymers" followed by a pulsed high-heat treatment.
    Type: Grant
    Filed: June 6, 1980
    Date of Patent: December 22, 1981
    Assignee: American Dental Association Health Foundation
    Inventors: Curtis P. Mabie, Daniel L. Menis
  • Patent number: 4298388
    Abstract: SiO.sub.2 -Al.sub.2 O.sub.3 -alkaline earth oxides glass compositions suitable for glass/molybdenum sealings with high thermal load capability, having coefficients of thermal expansion in the temperature range of 20.degree.-300.degree. C. of 4.6-5.1.times.10.sup.-6 /.degree. C., glass transformation temperatures (Tg) of 775.degree.-810.degree. C., softening temperatures (Ew) greater than 930.degree. C., processing temperatures (V.sub.A) of 1232.degree.-1273.degree. C. and at length of V.sub.A -Ew greater than 300.degree. C. as regards processing technology of these glasses in the mixture, which consist essentially of the following components, computed as percent by oxide weight:______________________________________ SiO.sub.2 57.00-64.00 wt % Al.sub.2 O.sub.3 12.50-16.50 wt % ZrO.sub.2 1.00-5.50 wt % Al.sub.2 O.sub.3 + ZrO.sub.2 15.00-19.00 wt % CaO 11.50-19.20 wt % BaO 0-6.50 wt % CeO.sub.2 0-8.00 wt % TiO.sub.2 0-4.50 wt % CaO + BaO + CeO.sub.2 + TiO.sub.2 18.60-25.70 wt % and As.sub.2 O.sub.3 0-0.
    Type: Grant
    Filed: October 8, 1980
    Date of Patent: November 3, 1981
    Assignee: Jenaer Glaswerk Schott & Gen.
    Inventor: Werner Sack
  • Patent number: 4288713
    Abstract: An incandescent lamp has on a portion of the lamp envelope a dark coating comprising manganese dioxide and aluminum phosphate.
    Type: Grant
    Filed: November 23, 1979
    Date of Patent: September 8, 1981
    Assignee: GTE Products Corporation
    Inventor: Richard C. Marlor