And Divalent Metal Oxide (e.g., Oxides Of Zinc, Cadmium, Beryllium, Alkaline Earth Metal, Magnesium, Etc.) Patents (Class 501/69)
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Patent number: 8895461Abstract: Provided are: a glass substrate for p-Si TFT flat panel displays that is composed of a glass having high characteristic temperatures in the low-temperature viscosity range, typified by the strain point and glass transition point, having a small heat shrinkage rate, and being capable of avoiding the occurrence of the problem regarding the erosion/wear of a melting tank at the time of melting through direct electrical heating; and a method for manufacturing same. The present glass substrate is composed of a glass comprising 52-78 mass % of SiO2, 3-25 mass % of Al2O3, 3-15 mass % of B2O3, 3-25 mass % of RO, wherein RO is total amount of MgO, CaO, SrO, and BaO, 0.01-1 mass % of Fe2O3, and 0-0.3 mass % of Sb2O3, and substantially not comprising As2O3, the glass having a mass ratio (SiO2+Al2O3)/B2O3 in a range of 7-30 and a mass ratio (SiO2+Al2O3)/RO equal to or greater than 6.Type: GrantFiled: June 29, 2012Date of Patent: November 25, 2014Assignee: AvanStrate Inc.Inventors: Akihiro Koyama, Satoshi Ami, Manabu Ichikawa
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Patent number: 8895463Abstract: A glass substrate for a CIGS solar cell, having high cell efficiency and high glass transition temperature is provided. The glass substrate for a vapor-deposited CIGS film solar cell has a glass transition temperature of at least 580° C. and an average thermal expansion coefficient of from 70×10?7 to 100×10?7/° C., wherein the ratio of the average total amount of Ca, Sr and Ba within from 10 to 40 nm in depth from the surface of the glass substrate to the total amount of Ca, Sr and Ba at 5,000 nm in depth from the surface of the glass substrate is at most 0.35, and the ratio of the average Na amount within from 10 to 40 nm in depth from the surface of the glass substrate after heat treatment to such average Na amount before the heat treatment is at least 1.5.Type: GrantFiled: January 28, 2013Date of Patent: November 25, 2014Assignee: Asahi Glass Company, LimitedInventors: Yutaka Kuroiwa, Yuichi Yamamoto, Tomomi Abe, Tetsuya Nakashima, Yasushi Kawamoto, Shigeru Niki, Shogo Ishizuka
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Publication number: 20140323286Abstract: Fusion-formable sodium-containing aluminosilicate and boroaluminosilicate glasses are described. The glasses are particularly useful for controlled release of sodium—useful in semiconductor applications, such as thin film photovoltaics where the sodium required to optimize cell efficiency is to be derived from the substrate glass.Type: ApplicationFiled: April 24, 2014Publication date: October 30, 2014Applicant: CORNING INCORPORATEDInventors: Bruce Gardiner Aitken, Adam James Ellison, James Patrick Hamilton, Timothy James Kiczenski
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Patent number: 8859079Abstract: A glass having excellent resistance against surface damages is provided. The glass includes a content of alkaline earth oxides of at least 0.3% by weight and of P2O5 of 0.1 to 4% by weight; the glass has at least one surface that has precipitations with a mean size of 1 to 20 ?m. A method is further provided and includes melting a glass batch, yielding a glass melt, and casting the glass melt onto a float bath. The glass melt is maintained on the float bath at a temperature of above 1000° C. for at least 5 minutes, and yields glass. The glass has a content of alkaline earth oxides of at least 0.3% by weight and of P2O5 of 0.1 to 4% by weight, and the glass has at least one surface that has precipitations with a mean size of 1 to 20 ?m.Type: GrantFiled: July 8, 2011Date of Patent: October 14, 2014Assignee: Schott AGInventors: Friedrich Siebers, Bernd Ruedinger, Andreas Langsdorf, Markus Heiss
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Patent number: 8853113Abstract: A flat panel display glass substrate according to the present invention includes a glass comprising, as expressed in mol %, 55-80% SiO2, 3-20% Al2O3, 3-15% B2O3, 3-25% RO (the total amount of MgO, CaO, SrO, and BaO), and substantially no As2O3 and Sb2O3. The devitrification temperature of the glass is 1250° C. or less. The glass substrate has a heat shrinkage rate of 75 ppm or less. The heat shrinkage rate is calculated from the amount of shrinkage of the glass substrate measured after a heat treatment which is performed at a temperature rising and falling rate of 10° C./min and at 550° C. for 2 hours by the heat shrinkage rate (ppm)={the amount of shrinkage of the glass substrate after the heat treatment/the length of the glass substrate before the heat treatment}×106.Type: GrantFiled: June 29, 2012Date of Patent: October 7, 2014Assignee: AvanStrate Inc.Inventors: Akihiro Koyama, Satoshi Ami, Manabu Ichikawa
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Patent number: 8846218Abstract: A method of smoothing the surface of a ceramic matrix composite material part that presents a surface that is undulating and rough. The method includes depositing a refractory vitreous coating on the surface of the part, the vitreous coating essentially containing silica, alumina, baryte, and lime.Type: GrantFiled: March 31, 2010Date of Patent: September 30, 2014Assignees: Herakles, SNECMAInventors: Eric Bouillon, Nicolas Eberling-Fux, Serge Chateigner
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Patent number: 8828898Abstract: A glass plate made of soda lime silica glass containing at least MgO, CaO, Na2O and Al2O3 produced by a float process or a downdraw method, wherein [MgO] is at least 4.5%, [MgO]/[CaO] is larger than 1, and Q=([MgO]/[CaO])×([CaO]+[Na2O]?[Al2O3]) is at least 20, wherein [MgO] is the content of MgO, [CaO] is the content of CaO, [Na2O] is the content of Na2O, and [Al2O3] is the content of Al2O3 (each being as represented by mass percentage based on oxide) and a process for the glass plate.Type: GrantFiled: March 15, 2013Date of Patent: September 9, 2014Assignee: Asahi Glass Company, LimitedInventors: Yusuke Arai, Tomoyuki Kobayashi, Yuki Kondo
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Publication number: 20140243183Abstract: A down-drawable glass ceramic. The glass ceramic has a composition which yields a liquidus viscosity that enables formation of the parent glass by down-draw techniques such as fusion-draw and slot-draw methods. The resulting glass ceramic is white or translucent in appearance with high strength achieved through heat treatment of the fusion-formed glass.Type: ApplicationFiled: February 20, 2014Publication date: August 28, 2014Applicant: Corning IncorporatedInventors: George Halsey Beall, Heather Debra Boek, Alexandre Michel Mayolet, Mark Owen Weller
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Publication number: 20140235425Abstract: A glass substrate contains specific contents of SiO2, Al2O3, B2O3, MgO, CaO, SrO, BaO, ZrO2, Na2O, K2O and Li2O. The glass substrate has a glass transition temperature of 580 to 720° C., an average coefficient of thermal expansion at 50 to 350° C. of 65×10?7 to 85×10?7/° C., a compaction (C) of 15 ppm or less, a glass surface devitrification temperature Tc of 900 to 1,300° C., a glass internal devitrification temperature Td of 900 to 1,300° C., a temperature T4 at which a viscosity reaches 104 dPa·s of 1,100 to 1,350° C., a relationship (T4?Tc) of ?50 to 350° C. and a relationship (T4?Td) of ?50 to 350° C.Type: ApplicationFiled: April 30, 2014Publication date: August 21, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventor: Manabu NISHIZAWA
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Publication number: 20140226090Abstract: To provide chemically tempered glass which is less likely to break even if scratched. Chemically tempered glass, which comprises, as represented by mole percentage based on the following oxides, from 56 to 72% of SiO2, from 8 to 20% of Al2O3, from 9 to 25% of Na2O, from 0 to 2% of K2O, and from 0 to 15% of MgO, and which has a surface compressive stress of at least 900 MPa and an internal tensile stress of at most 30 MPa. Glass for chemical tempering, which comprises, as represented by mole percentage based on the following oxides, from 56 to 69% of SiO2, from 8 to 16% of Al2O3, from 9 to 22% of Na2O, from 0 to 1% of K2O, from 5.5 to 14% of MgO, from 0 to 2% of ZrO2, and from 0 to 6% of B2O3.Type: ApplicationFiled: April 17, 2014Publication date: August 14, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Shusaku AKIBA, Shigeki SAWAMURA, Suguru MURAYAMA, Hiroyuki OHKAWA, Yusuke KOBAYASHI, Kazutaka ONO, Tetsuya NAKASHIMA
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Patent number: 8802581Abstract: A glass that is down-drawable and ion exchangeable. The glass has a temperature T35kp at which the viscosity is 35 kilopoise. T35kp is less than the breakdown temperature Tbreakdown of zircon.Type: GrantFiled: August 16, 2010Date of Patent: August 12, 2014Assignee: Corning IncorporatedInventors: Matthew John Dejneka, Adam James Ellison, Benjamin Zain Hanson
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Patent number: 8791036Abstract: The present invention relates to a glass plate for a substrate contains, as a glass matrix composition, in mol % on the oxide basis, SiO2: 67 to 72, Al2O3: 1 to 7, B2O3: 0 to 4, MgO: 11 to 15, CaO: 0 to 3, SrO: 0 to 3, BaO: 0 to 4, ZrO2: 0 to 4, Na2O: 8 to 15, and K2O: 0 to 7, with SiO2+Al2O3: 71 to 77, MgO+CaO+SrO+BaO: 11 to 17, Na2O+K2O: 8 to 17, and satisfying K2O/(Na2O+K2O)?0.13×(SiO2+Al2O3+0.5B2O3+0.3BaO)?9.4, in which the glass plate has a ?-OH value (mm?1) of 0.05 to 0.5, and a heat shrinkage ratio (C) of 16 ppm or less.Type: GrantFiled: March 30, 2012Date of Patent: July 29, 2014Assignee: Asahi Glass Company, LimitedInventors: Tomoyuki Tsujimura, Yuichi Kuroki, Manabu Nishizawa
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Patent number: 8778075Abstract: Lithium silicate glass ceramics and glasses are described which can advantageously be applied to zirconium oxide ceramics in particular by pressing-on in the viscous state and form a solid bond with these.Type: GrantFiled: August 5, 2013Date of Patent: July 15, 2014Assignee: Ivoclar Vivadent AGInventors: Christian Ritzberger, Ricardo Dellagiacomo, Marcel Schweiger, Harald Bürke, Wolfram Höland, Volker Rheinberger
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Publication number: 20140193643Abstract: A method of bonding a first substrate to a second substrate includes providing a glass, applying the glass in a layer between the first and second substrates to form an assembly, and heating the assembly to a bonding temperature above a glass transition temperature of the devitrifying glass, selected to cause the glass to bond the first substrate to the second substrate. The devitrifying glass has constituents that include various amounts of group A in a molar concentration of 70-95%, group B in a molar concentration of 5-20%, group C in a molar concentration of 1-20%, group D in a molar concentration of 0-6%; and group E in a molar concentration of 0-10%. The group A, B, C, D and E groups are disclosed herein.Type: ApplicationFiled: January 4, 2014Publication date: July 10, 2014Applicant: LILLIPUTIAN SYSTEMS, INC.Inventors: Mohammad Masyood Akhtar, Samuel B. Schaevitz, Michael C. Bradford, Zachary Byars, Joseph C. Tucker
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Patent number: 8765262Abstract: Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P2O5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.Type: GrantFiled: November 15, 2012Date of Patent: July 1, 2014Assignee: Corning IncorporatedInventor: Timothy Michael Gross
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Patent number: 8759239Abstract: Transparent, essentially colorless ?-quartz glass-ceramic materials, the composition of which is free of As2O3 and of Sb2O3, where said composition contains a specific combination of three nucleating agents: TiO2, ZrO2 and SnO2; TiO2 being present in low quantity.Type: GrantFiled: October 25, 2012Date of Patent: June 24, 2014Assignee: EurokeraInventors: Marie Jacqueline Monique Comte, Lothar Wondraczek
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Publication number: 20140150867Abstract: Sodium containing aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates or superstrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points ?535° C., for example, ?570° C., thermal expansion coefficients of from 8 to 9 ppm/° C., as well as liquidus viscosities in excess of 50,000 poise. As such they are ideally suited for being formed into sheet by the fusion process.Type: ApplicationFiled: February 10, 2014Publication date: June 5, 2014Applicant: Corsam Technologies LLCInventors: Bruce Gardiner AITKEN, James Edward Dickinson, JR., Timothy J. Kiczenski
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Publication number: 20140147679Abstract: The invention relates to a sheet of extra-clear glass, that is to say a sheet of glass having high energy transmission, which can be used in particular in the field of solar energy. More specifically, the invention relates to a sheet of float glass having a composition which comprises, in a content expressed as percentages of the total weight of glass: SiO2 60-75%; Al2O3: 0-10%; B2O3: 0-5%; CaO: 0-15%; MgO: 0-10%; Na2O: 5-20%; K2O: 0-10%; BaO: 0-5%; total iron (expressed as Fe2O3): 0.001 to 0.06%; antimony (expressed as Sb2O3): 0.02 to 0.07%.Type: ApplicationFiled: June 15, 2012Publication date: May 29, 2014Applicant: AGC Glass EuropeInventors: Audrey Dogimont, Nicolas Fedullo, Sebastien Hennecker
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Publication number: 20140141285Abstract: It is an object of the present invention to provide a crystallized glass which has various properties required for employing the substrate for information recording medium of the next generation, and also has significantly low specific gravity; and a crystallized glass substrate for information recording medium. A crystallized glass containing, as a crystal phase, one or more selected from RAl2O4 and R2TiO4 (wherein R is one or more selected from Mg and Fe), the crystallized glass comprising the components of SiO2 of 50% to 70%, Al2O3 of 10% to 26%, TiO2 of 1 to 15%, MgO of 2.5% to 25%, FeO of 0% to 8%, and ZnO of 0% to less than 2%, expressed in terms of mass percentage on an oxide basis, wherein the value of (Al2O3+MgO)/SiO2 is 0.30 or more and 0.65 or less, and a specific gravity is less than 2.63.Type: ApplicationFiled: November 15, 2013Publication date: May 22, 2014Applicant: OHARA INC.Inventors: Kiyoyuki Momono, Katsuhiko Yamaguchi, Toshitaka Yagi, Naoyuki Goto
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Publication number: 20140135201Abstract: Transparent, essentially colorless and non-diffusing ?-quartz glass-ceramics and glass compositions for forming the same have a composition, free of arsenic oxide, antimony oxide and rare earth oxides except for inevitable trace amounts, which contains, expressed as percentages by weight of oxides 62-72% of SiO2, 20-23% of Al2O3, 2.8-5% of Li2O, 0.1-0.6% of SnO2, 1.9-4% of TiO2, 1.6-3% of ZrO2, less than 0.4% of MgO, 2.5-6% of ZnO and/or BaO and/or SrO, less than 250 ppm of Fe2O3; and their crystallites present in the ?-quartz solid solution have an average size of less than 35 nm. The glass-ceramics exhibit low thermal expansion and are easily obtained at an industrial scale.Type: ApplicationFiled: May 15, 2013Publication date: May 15, 2014Applicant: EurokeraInventors: Isabelle Marie Chauvel-Melscoet, Marie Jacqueline Monique Comte
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Patent number: 8715829Abstract: To provide a glass plate for display devices wherein without carrying out a post treatment, the depth of a compression stress layer is increased, while the surface compression stress is prevented from being excess only by chemical tempering. A glass plate for display devices, which is obtained by chemically tempering a glass plate comprising, as represented by mol % based on the following oxides, from 50 to 74% of SiO2, from 1 to 10% of Al2O3, from 6 to 14% of Na2O, from 3 to 15% of K2O, from 2 to 15% of MgO, from 0 to 10% of CaO and from 0 to 5% of ZrO2, wherein the total content of SiO2 and Al2O3 is at most 75%, the total content of Na2O and K2O, i.e. Na2O+K2O, is from 12 to 25%, and the total content of MgO and CaO, i.e. MgO+CaO, is from 7 to 15%.Type: GrantFiled: May 29, 2009Date of Patent: May 6, 2014Assignee: Asahi Glass Company, LimitedInventors: Shusaku Akiba, Kazutaka Hayashi, Kei Maeda
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Publication number: 20140120335Abstract: A float glass, which is produced by a float process, has a bottom surface to contact a molten metal during forming and a top surface facing the bottom surface, and is capable of having, after chemical strengthening, a surface compressive stress of 600 MPa or more and a depth of a compressive stress layer of 15 ?m or more from a surface thereof. Before chemical strengthening, a difference obtained by subtracting a surface compressive stress value ?CB in the bottom surface from a surface compressive stress value ?CT in the top surface is ?0.6 MPa or more and 0.25 MPa or less.Type: ApplicationFiled: January 2, 2014Publication date: May 1, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Kazuhiko YAMANAKA, Hitoshi ONODA, Aya YAMAMOTO, Yusuke FUJIWARA, Tetsushi TAKIGUCHI
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Publication number: 20140113141Abstract: There is provided a glass for chemical strengthening having a gray-based color tone and excelling in characteristics preferred for the purposes of housing or decoration of an electronic device, that is, bubble quality, strength, and light transmittance characteristics. A glass for chemical strengthening contains, in mole percentage based on following oxides, 55% to 80% of SiO2, 3% to 16% of Al2O3, 0% to 12% of B2O3, 5% to 16% of Na2O, 0% to 4% of K2O, 0% to 15% of MgO, 0% to 3% of CaO, 0% to 18% of ?RO (where R represents Mg, Ca, Sr, Ba or Zn), 0% to 1% of ZrO2, 0.01% to 0.2% of Co3O4, 0.05% to 1% of NiO, and 0.01% to 3% of Fe2O3.Type: ApplicationFiled: September 17, 2013Publication date: April 24, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Hiroyuki YAMAMOTO, Kazuhide KUNO
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Patent number: 8697588Abstract: Provided is a mineral wool that includes recycled material. The mineral wool is characterized by an acid to base ratio within a specified range. Also provided is a method of manufacturing the mineral wool that includes selection of post-consumer or post-industrial recyclable materials. Application of the mineral wool to products such as an acoustical ceiling panel is also provided.Type: GrantFiled: April 11, 2011Date of Patent: April 15, 2014Assignee: USG Interiors, Inc.Inventor: Martin W. Brown
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Patent number: 8697592Abstract: Disclosed are a glass substrate for an information recording medium, having excellent scratch resistance and a light weight and having high fracture toughness, the glass substrate having a fragility index value, measured in water, of 12 ?m?1/2 or less or having a fragility index value, measured in an atmosphere having a dew point of ?5° C. or lower, of 7 ?m?1/2 or less, or the glass substrate comprising, by mol %, 40 to 75% of SiO2, 2 to 45% of B2O3 and/or Al2O3 and 0 to 40% of R?2O in which R? is at least one member selected from the group consisting of Li, Na and K), wherein the total content of SiO2, B2O3, Al2O3 and R?2O is at least 90 mol %, and a magnetic information recording medium comprising a magnetic recording layer formed on the glass substrate.Type: GrantFiled: June 7, 2012Date of Patent: April 15, 2014Assignee: Hoya CorporationInventors: Mikio Ikenishi, Atsuko Morita, Xuelu Zou
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Publication number: 20140099501Abstract: There is provided a glass for chemical strengthening having a black color tone and excelling in characteristics preferred for the purposes of housing or decoration of an electronic device, that is, bubble quality, strength, and light transmittance characteristics. A glass for chemical strengthening contains, in mole percentage based on following oxides, 55% to 80% of SiO2, 3% to 16% of Al2O3, 0% to 12% of B2O3, 5% to 16% of Na2O, 0% to 4% of K2O, 0% to 15% of MgO, 0% to 3% of CaO, 0% to 18% of ?RO (where R represents Mg, Ca, Sr, Ba or Zn), 0% to 1% of ZrO2, and 0.1% to 7% of a coloring component having at least one metal oxide selected from the group consisting of oxides of Co, Mn, Fe, Ni, Cu, Cr, V and Bi.Type: ApplicationFiled: September 17, 2013Publication date: April 10, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Hiroyuki YAMAMOTO, Kazuhide KUNO
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Patent number: 8691711Abstract: Glass for a display device, which comprises, as represented by mole percentage based on the following oxides, from 61 to 72% of SiO2, from 8 to 17% of Al2O3, from 6 to 18% of Li2O, from 2 to 15% of Na2O, from 0 to 8% of K2O, from 0 to 6% of MgO, from 0 to 6% of CaO, from 0 to 4% of TiO2, and from 0 to 2.5% of ZrO2, and having a total content R2O of Li2O, Na2O and K2O of from 15 to 25%, a ratio Li2O/R2O of the Li2O content to R2O of from 0.35 to 0.8, and a total content of MgO and CaO of from 0 to 9%.Type: GrantFiled: May 25, 2011Date of Patent: April 8, 2014Assignee: Asahi Glass Company, LimitedInventors: Tetsuya Nakashima, Seiki Ohara, Tatsuo Nagashima
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Patent number: 8679631Abstract: A tempered glass substrate of the present invention is a tempered glass substrate, which has a compression stress layer on a surface thereof, and has a glass composition comprising, in terms of mass %, 40 to 71% of SiO2, 3 to 21% of Al2O3, 0 to 3.5% of Li2O, 7 to 20% of Na2O, and 0 to 15% of K2O.Type: GrantFiled: September 2, 2011Date of Patent: March 25, 2014Assignee: Nippon Electric Glass Co., Ltd.Inventor: Takashi Murata
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Publication number: 20140057092Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit ?-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2 ? O + Na 2 ? O + K 2 ? O + MgO + ZnO ] [ Al 2 ? O 3 + B 2 ? O 3 ] between 0.7 to 1.5; b. a ? ? ratio ? : ? [ TiO 2 + SnO 2 ] [ SiO 2 + B 2 ? O 3 ] greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity ?about 85% over the wavelength range of 400-700 nm for an about 0.Type: ApplicationFiled: October 31, 2013Publication date: February 27, 2014Applicant: CORNING INCORPORATEDInventors: George Halsey Beall, Marie Jacqueline Monique Comte, George Owen Dale, Linda Ruth Pinckney, Charlene Marie Smith, Ronald Leroy Stewart, Steven Alvin Tietje
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Patent number: 8652978Abstract: A silicate glass that is tough and scratch resistant. The toughness is increased by minimizing the number of non-bridging oxygen atoms in the glass. In one embodiment, the silicate glass is an aluminoborosilicate glass in which ?15 mol %?(R2O+R?O—Al2O3—ZrO2)—B2O3?4 mol %, where R is one of Li, Na, K, Rb, and Cs, and R? is one of Mg, Ca, Sr, and Ba.Type: GrantFiled: August 17, 2012Date of Patent: February 18, 2014Assignee: Corning IncorporatedInventors: Matthew John Dejneka, Adam James Ellison, Sinue Gomez, Robert Michael Morena
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Patent number: 8652979Abstract: Provided is a glass substrate satisfying ion exchange performance and devitrification resistance of a glass simultaneously and having higher mechanical strength compared to a conventional glass substrate. A tempered glass substrate which has a compression stress layer on a surface thereof, has a glass composition including, in terms of mole %, 50 to 85% of SiO2, 5 to 30% of Al2O3, 0 to 20% of Li2O, 0 to 20% of Na2O, 0 to 20% of K2O, 0.001 to 10% of TiO2, and 15 to 35% of Li2O+Na2O+K2O+Al2O3, has a (Li2O+Na2O+K2O)/Al2O3 value of 0.7 to 3 in terms of mole fraction, and is substantially free of As2O3 and F.Type: GrantFiled: October 10, 2007Date of Patent: February 18, 2014Assignee: Nippon Electric Glass Co., Ltd.Inventor: Takashi Murata
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Patent number: 8652659Abstract: A glass substrate for information recording medium, said glass substrate being composed of an aluminosilicate glass containing 60-75% by mass of SiO2, 5-18% by mass of Al2O3, 3-10% by mass of Li2O, 3-15% by mass of Na2O and 0.5-8% by mass of ZrO2 relative to the entire glass components. The glass substrate for information recording medium contains neither As (arsenic) nor Sb (antimony), while containing at least one substance selected from the group consisting of SO3 (sulfurous acid), F (fluorine), Cl (chlorine), Br (bromine) and I (iodine), as a refining agent. The molar ratio of the total amount of the refining agent to the amount of Al2O3 is within the range of 0.02-0.20.Type: GrantFiled: July 3, 2009Date of Patent: February 18, 2014Assignee: Konica Minolta Opto, Inc.Inventor: Hideki Kawai
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Patent number: 8647995Abstract: Sodium containing aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates or superstrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points ?535° C., for example, ?570° C., thermal expansion coefficients of from 8 to 9 ppm/° C., as well as liquidus viscosities in excess of 50,000 poise. As such they are ideally suited for being formed into sheet by the fusion process.Type: GrantFiled: July 21, 2010Date of Patent: February 11, 2014Assignee: Corsam Technologies LLCInventors: Bruce Gardiner Aitken, James Edward Dickinson, Jr., Timothy J Kiczenski
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Publication number: 20140023865Abstract: According to one embodiment, a glass article may include SiO2, Al2O3, Li2O and Na2O. The glass article may have a softening point less than or equal to about 810° C. The glass article may also have a high temperature CTE less than or equal to about 27×10?6/° C. The glass article may also be ion exchangeable such that the glass has a compressive stress greater than or equal to about 600 MPa and a depth of layer greater than or equal to about 25 ?m after ion exchange in a salt bath comprising KNO3 at a temperature in a range from about 390° C. to about 450° C. for less than or equal to approximately 15 hours.Type: ApplicationFiled: July 10, 2013Publication date: January 23, 2014Inventors: Marie Jacqueline Monique Comte, Melinda Ann Drake, Karen Leslie Geisinger, Sinue Gomez, Robert Michael Morena, Charlene Marie Smith, Randall Eugene Youngman
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Publication number: 20140017499Abstract: Glass for chemical strengthening, comprising 0.001% to 5% of Se in terms of molar percentage as a coloring component in the glass, wherein the glass has a property configured to provide an absolute value of ?a*m with 1.8 or less, the absolute value of ?a*m being a difference ?a*m between a value of chromaticity a* of reflected light by a D65 light source and a value of chromaticity a* of reflected light by an F2 light source, in a L*a*b* color system, the difference being expressed by the following expression (1), ?a*m=a*value(D65 light source)?a*value(F2 light source) ??(1).Type: ApplicationFiled: July 10, 2013Publication date: January 16, 2014Inventor: Hiroyuki YAMAMOTO
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Patent number: 8623776Abstract: A fusion formable and ion exchangeable silicate glass having a seed concentration of less than about 1 seed/cm3.Type: GrantFiled: June 19, 2013Date of Patent: January 7, 2014Assignee: Corning IncorporatedInventors: Matthew John Dejneka, Sinue Gomez
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Publication number: 20130343166Abstract: An aspect of the present invention relates to glass for a magnetic recording medium substrate, which comprises essential components in the form of SiO2, Li2O, Na2O, and one or more alkaline earth metal oxides selected from the group consisting of MgO, CaO, SrO, and BaO wherein a molar ratio of a content of CaO to a combined content of MgO, CaO, SrO, and BaO (CaO/(MgO+CaO+SrO+BaO)) is equal to or less than 0.20, and which has a glass transition temperature of equal to or higher than 650° C.Type: ApplicationFiled: March 15, 2013Publication date: December 26, 2013Applicant: HOYA CORPORATIONInventor: HOYA CORPORATION
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Patent number: 8609561Abstract: A colorless transparent colloid-former-containing glass that is convertible into a colorless transparent glass ceramic or a metal colloid-colored glass ceramic via respective heat treatments contains a combination of one or more metal colloid formers and one or more redox partners. The metal colloid formers are preferably oxides containing Au, Ag, As, Bi, Nb, Cu, Fe, Pd, Pt, Sb and/or Sn. The redox partners are preferably oxides containing As, Ce, Fe, Mn, Sb, Sn and/or W, with the proviso that the redox partner must be different from the metal colloid former. The glass advantageously contains from 0.97 to 1.9 wt. % SnO2, 0.93 to 3.0 wt. % As2O3, or 1.59 to 6.0 wt. % of Sb2O3 as redox partner.Type: GrantFiled: July 17, 2012Date of Patent: December 17, 2013Assignee: Schott AGInventors: Meike Schneider, Thilo Zachau, Friedrich Siebers, Wolfgang Schmidbauer
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Patent number: 8586491Abstract: Glass batch compositions for the formation of high-modulus, and high-strength glass fibers as well as fibers suitable for use as textile and reinforcements are disclosed. Fibers formed of the composition are especially suitable for use in high-strength, low-weight applications such as windmill blades and high strength and modulus applications where strength and stiffness are required in the composite. The glass composition is up to about 70.5 weight % SiO2, about 24.5 weight % Al2O3, about 22 weight % alkaline earth oxides and may include small amounts of alkali metal oxides and ZrO2. Additionally, glass fibers formed from the inventive composition are non-corrosive or substantially non-corrosive in nature. Due to the non-corrosive nature of the glass fibers, glass fibers made with the inventive composition may be used in applications where the glass fibers or a composite formed from the glass fibers are in contact with a corrosive substance.Type: GrantFiled: January 30, 2007Date of Patent: November 19, 2013Assignee: OCV Intellectual Capital, LLCInventors: Douglas A. Hofmann, Peter B. McGinnis
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Publication number: 20130302617Abstract: To provide glass to be used for chemically tempered glass which is hardly broken even when flawed. Glass for chemical tempering, which comprises, as represented by mole percentage based on the following oxides, from 65 to 85% of SiO2, from 3 to 15% of Al2O3, from 5 to 15% of Na2O, from 0 and less than 2% of K2O, from 0 to 15% of MgO and from 0 to 1% of ZrO2, and has a total content Si02+Al2O3 of SiO2 and Al2O3 of at most 88%.Type: ApplicationFiled: July 16, 2013Publication date: November 14, 2013Applicant: Asahi Glass Company, LimitedInventors: Shusaku Akiba, Kazutaka Ono, Jun Endo, Shigeki Sawamura, Tetsuya Nakashima, Yuichi Kuroki
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Publication number: 20130302618Abstract: A high-strength alkali-aluminosilicate glass, characterized by excellent meltability, fineability. and processibility, exhibits the following formula: SiO2 60.5 to 69.0 weight percent Al2O3 7.0 to 11.8 weight percent B2O3 0 to 4.0 weight percent MgO 2.0 to 8.5 weight percent CaO 0 to 4.0 weight percent ZnO 0 to 5.0 weight percent ZrO2 0 to 3.0 weight percent Na2O 15.0 to 17.5 weight percent K2O 0 to 2.7 weight percent Li2O 0 to 2.0 weight percent and from 0 to 1.5 weight percent of a fining agents such as As2O3, Sb2O3 CeO2, SnO2, Cl?, F?, (SO4)2? and combinations thereof. The glass allows for adequate conditions for an alkali ion exchange treatment in a short time period (4 to 8 hours) and can also be produced according to the established, continuous, vertically downward directed drawing process such as the overflow down-draw method or the fusion method, the die slot or the slot down-draw method, or combinations thereof.Type: ApplicationFiled: January 27, 2012Publication date: November 14, 2013Applicant: Kornerstone Materials Technology Co., Ltd.Inventors: Bernd Kuhnemann, Michael Boettger, Sicco Rathke
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Patent number: 8580411Abstract: To provide glass to be used for a substrate which is, as a substrate, less susceptible to surface roughening even if subjected to cleaning by means of a strongly acidic solution. Glass for a substrate, which comprises, as represented by mol % based on the following oxides, from 62.5 to 69% of SiO2, from 9 to 15.5% of Al2O3, from 8 to 16 of Li2O, from 0 to 8% of Na2O, from 0 to 7% of K2O and from 0 to 3.5% of ZrO2, provided that SiO2—Al2O3 is at least 53.3%, Li2O+Na2O+K2O is from 17 to 24%, and the total of contents of the above six components is at least 97%.Type: GrantFiled: October 12, 2011Date of Patent: November 12, 2013Assignee: Asahi Glass Company, LimitedInventors: Jun Endo, Tetsuya Nakashima, Atsuyoshi Takenaka
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Publication number: 20130288001Abstract: Provided is a tempered glass having a compression stress layer in a surface thereof, the tempered glass comprising, as a glass composition in terms of mol %, 45 to 75% of SiO2, 3 to 15% of Al2O3, 0 to 12% of Li2O, 0.3 to 20% of Na2O, 0 to 10% of K2O, and 1 to 15% of MgO+CaO, and having a molar ratio (Al2O3+Na2O+P2O5)/SiO2 of 0.1 to 1, a molar ratio (B2O3+Na2O)/SiO2 of 0.1 to 1, a molar ratio P2O5/SiO2 of 0 to 1, a molar ratio Al2O3/SiO2 of 0.01 to 1, and a molar ratio Na2O/Al2O3 of 0.1 to 5, wherein the surface is etched partially or entirely before tempering treatment.Type: ApplicationFiled: January 16, 2012Publication date: October 31, 2013Inventors: Takashi Murata, Takako Tojyo
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Patent number: 8563450Abstract: Glass batch compositions for the formation of high-modulus, and high-strength glass fibers as well as fibers suitable for use as textile and reinforcements are disclosed. Fibers formed of the composition are especially suitable for use in high-strength, low-weight applications such as windmill blades and high strength and modulus applications where strength and stiffness are required in the composite. The glass composition is up to about 70.5 weight % SiO2, about 24.5 weight % Al2O3, about 22 weight % alkaline earth oxides and may include small amounts of alkali metal oxides and ZrO2. Fiberglass-reinforced composite articles such as windmill blades are also disclosed.Type: GrantFiled: September 16, 2010Date of Patent: October 22, 2013Assignee: OCV Intellectual Capital, LLCInventors: Douglas A. Hofmann, Peter B. McGinnis
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Publication number: 20130267402Abstract: The present invention provides a glass substrate having high glass transition temperature and small compaction (C) in a heat treatment at a low temperature (150 to 300° C.), the glass substrate including SiO2, Al2O3, B2O3, MgO, CaO, SrO, BaO, ZrO2, Na2O, K2O, and Li2O, wherein each amount of these compounds is specifically limited, Al2O3+K2O is 7 to 27 mass %, Na2O+K2O is 11.5 to 22 mass %, MgO+CaO+SrO+BaO is 0.2 to 14 mass %, MgO+0.357Al2O3?0.239K2O?5.58 is ?3.0 to 1.5, Na2O+0.272Al2O3+0.876K2O?16.77 is ?2.5 to 2.5, a glass transition temperature is 500° C. or higher, and an average thermal expansion coefficient at 50 to 350° C. is 100×10?7/° C. or less.Type: ApplicationFiled: December 3, 2012Publication date: October 10, 2013Applicant: ASAHI GLASS COMPANY, LIMITEDInventor: ASAHI GLASS COMPANY, LIMITED
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Patent number: 8541327Abstract: A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO2; one or more compounds from the group of compounds consisting of La2O3, Al2O3, B2O3, and Ni; the La2O3 less than about 20 mole percent; the Al2O3 less than about 25 mole percent; the B2O3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.Type: GrantFiled: October 21, 2011Date of Patent: September 24, 2013Assignee: U.S. Department of EnergyInventors: Peizhen Kathy Lu, Manoj Kumar Mahapatra
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Publication number: 20130224491Abstract: Glass compositions that may be used to produce chemically strengthened glass sheets by ion exchange. The glass compositions are chosen to promote simultaneously high compressive stress and deep depth of layer or, alternatively, to reduce the time needed to ion exchange the glass to produce a predetermined compressive stress and depth of layer.Type: ApplicationFiled: February 29, 2012Publication date: August 29, 2013Inventors: Morten Mattrup Smedskjaer, Marcel Potuzak, John Christopher Mauro
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Publication number: 20130225388Abstract: Provided is a Li2O—Al2O3—SiO2-based crystallizable glass characterized by comprising, as a glass composition in terms of mass %, 55 to 75% of SiO2, 19 to 24% of Al2O3, 3 to 4% of Li2O, 1.5 to 2.8% of TiO2, 3.8 to 4.8% of TiO2+ZrO2, and 0.1 to 0.5% of SnO2, and satisfying a relationship of 4?Li2O+0.741MgO+0.367ZnO?4.5.Type: ApplicationFiled: November 4, 2011Publication date: August 29, 2013Applicant: Nippon Electric Glass Co., Ltd.Inventors: Shingo Nakane, Kosuke Kawamoto
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Patent number: 8518545Abstract: To provide glass to be used for chemically tempered glass which is hardly broken even when flawed. Glass for chemical tempering, which comprises, as represented by mole percentage based on the following oxides, from 65 to 85% of SiO2, from 3 to 15% of Al2O3, from 5 to 15% of Na2O, from 0 and less than 2% of K2O, from 0 to 15% of MgO and from 0 to 1% of ZrO2, and has a total content SiO2+Al2O3 of SiO2 and Al2O3 of at most 88%.Type: GrantFiled: September 14, 2012Date of Patent: August 27, 2013Assignee: Asahi Glass Company, LimitedInventors: Shusaku Akiba, Kazutaka Ono, Jun Endo, Shigeki Sawamura, Tetsuya Nakashima, Yuichi Kuroki
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Patent number: RE44869Abstract: An alkali aluminosilicate glass that is chemically strengthened and has a down-drawable composition. The glass has a melting temperature less than about 1650° C. and a liquidus viscosity of at least 130 kpoise and, in one embodiment, greater than 250 kpoise. The glass undergoes ion exchange at relatively low temperatures to a depth of at least 30 ?m.Type: GrantFiled: February 23, 2012Date of Patent: April 29, 2014Assignee: Corning IncorporatedInventors: Adam James Ellison, Sinue Gomez